HERBICIDE MIXTURES COMPRISING ISOXAFLUTOL, PYROXASULFONE AND AN IMIDAZOLINONE HERBICIDE; AND THEIR USES IN SOYBEAN AND COTTON CROPS

Abstract

The present invention relates to herbicide mixtures comprising isoxaflutol, pyroxasulfone, and an imidazolinone herbicide. The herbicide mixtures may comprise at least one additional herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, phenquinetrione, mesotrione, tembotrione, tolpyralate, and topramezone. Furthermore, the invention relates to methods and uses for applying the herbicide mixtures, particularly for controlling unwanted vegetation in soybean and cotton crops.

Description

HERBICIDE MIXTURES COMPRISING ISOXAFLUTOL, PYROXASULFONE AND AN IMIDAZOLINONE HERBICIDE; AND THEIR USES IN SOYBEAN AND COTTON CROPS Description The present invention relates to a herbicide mixture comprising isoxaflutol (Compound I), pyroxasulfone (Compound II), at least one imidazolinone herbicide selected from the group consisting of imazamox, imazapyr, imazapic, imazaquin and imazethapyr and their salts (Compound III) and optionally at least one additional herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, phenquinetrione, mesotrione, tembotrione, tolpyralate and topramezone (Compound IV). The invention also relates to methods and uses for controlling unwanted vegetation in HPPD-tolerant soybeans and HPPD-tolerant cotton. Isoxaflutol is a herbicide that acts by inhibiting the plant's hydroxyphenylpyruvate dioxygenase (HPPD) enzyme. Tolerant or resistant soybean or cotton varieties (e.g., transgenic soybean or cotton varieties) provide the option of using herbicides, which are not inherently selective, on the respective tolerant or resistant cotton or soybean in addition to conventional weed control methods. An example is isoxaflutol, which cannot be used on conventional soybeans or cotton because the crops are not sufficiently tolerant to its herbicidal action. However, effective weed control can be achieved through post-emergence and, in particular, pre-emergence application on HPPD-tolerant soybeans or cotton. Isoflutol is a broad-spectrum herbicide that controls many grass and broadleaf weed species; however, some species are difficult to control, or resistant biotypes are not completely effective. Another challenge is the herbicide's duration of action, or degradation rate.Changes in the sensitivity of weedy plants, which can occur after prolonged herbicide use or within a limited geographic area, must also be considered. The resulting loss of effectiveness against individual plants can sometimes be partially offset by increasing herbicide application rates. However, there is always a demand for methods to achieve the desired herbicidal effect with the lowest possible application rates of the active compounds, in order to reduce not only the amount of active compound required for application but also the amount of formulation aids. Therefore, for both economic and environmental reasons, low application rates are a key objective for improving the environmental performance of herbicide treatment. One way to improve the performance profile of a herbicide is to combine it with one or more other active compounds that have the desired additional properties. However, the combined use of multiple active compounds can lead to chemical, physical, and biological incompatibility (e.g., instability of a co-formulation, decomposition of an active compound, or antagonism in the biological action of the active compounds). Therefore, the discovery of effective combinations of isoxaflutol with an additional herbicide faces the challenge that in many cases the efficacy of such combinations is not satisfactory and high application rates are still required to obtain acceptable weed control. Therefore, an object of the present invention is to discover combinations of active compounds with a favorable action profile, high stability, and ideally and synergistically enhanced activity for application to HPPD-tolerant soybeans or cotton, thereby reducing the application rate compared to prior art mixtures. Furthermore, the herbicidal action of the mixture should be sufficiently long-lasting to achieve weed control for an extended period, thus allowing for more flexible application. The mixtures should also exhibit accelerated action on weeds and not negatively affect the growth of the soybean or cotton plant. Surprisingly, mixtures of isoxaflutol and Herbicide Compounds II, III, and optionally IV were found to show improved herbicidal action against unwanted vegetation when used pre-emergence or post-emergence in HPPD-tolerant soybeans or cotton and / or show superior compatibility with the crop plant, i.e., their use leads to reduced damage to soybean or cotton plants and / or does not cause increased damage to soybean or cotton plants, compared to the individual use of isoxaflutol. Therefore, the present invention relates to herbicidal mixtures of 1) isoxaflutol as Compound I; and 2) pyroxasulfone as Compound II; and 3) an imidazolinone herbicide selected from the group consisting of imazamox, imazapyr, imazapic, imazaquin and imazethapyr and their salts (Compound III); and 4) Optionally, at least one additional herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, phenquinetrione, mesotrione, tembotrione, tolpyralate and topramezone (Compound IV). Compounds I, II, III and IV, as well as their pesticidal action and the methods for producing them, are generally known, for example, in Pesticide Manual V5.2 (ISBN 978 1 901396 85 0) (2008-2011) and the Compendium of Pesticide Common Yams website (http: / / www.alanwood.net / pesticides / ), among other sources. In inventive mixtures, the weight ratio of Compound I to Compound II is preferably from 15:1 to 1:15, more preferably from 10:1 to 1:10, in particular from 5:1 to 1:5. In inventive mixtures, the weight ratio of Compound I to Compound III is preferably from 15:1 to 1:15, more preferably from 10:1 to 1:10, in particular from 5:1 to 1:5. In inventive mixtures, the weight ratio of Compound I to Compound IV is, preferably, from 100:1 to 1:1000, more preferably 10:1 to 1:100. The preferred Compound III compounds are imazamox, imazamox ammonium, imazapyr, imazapyr isopropylammonium, imazapyr ammonium, imazapic, imazapic ammonium, imazaquin, imazaquin ammonium, imazethapyr, and imazethapyr ammonium. Imazamox, imazamox ammonium, imazethapyr, and imazethapyr ammonium are particularly preferred. Los Compuestos IV preferidos son glyphosate, glyphosate dimetilamonio, glyphosate isopropilamonio, glyphosate potassium, glyphosate trimesium (sulfosato), glufosinato, glufosinato ammonio, glufosinato sodio, Lglufosinato, L-glufosinato ammonio, L-glufosinato sodio, dicamba, sal de dicamba ethanolamine, sal de dicamba diglicolamina, dicamba potasio y sal de dicamba BAPMA (es decir, sal de dicamba N,N-bis(3aminoprop¡l)metilam¡na), 2,4-D, sal de colina 2,4-D, biciclopirona, fenquinotriona, mesotriona, tembotriona, tolpiralato y topramezona.Se prefieren en particular, glyphosate, glyphosate dimetilamonio, glyphosate isopropilamonio, glyphosate potassium, glufosinate, glufosinate ammonium, L-glufosinate, L-glufosinate ammonium, L-glufosinate sodium, dicamba, sal de dicamba ethanolamine, sal de dicamba diglicolamina, dicamba potasio y sal de dicamba BAPMA (es decir, sal de dicamba N,Nb¡s(3-aminopropil)met¡lamina), 2,4-D, sal de colina 2,4-D, biciclopirona, fenquinotriona, mesotriona, tembotriona, tolpiralato y topramezona, en particular, glyphosate, glyphosate dimetilamonio, glyphosate isopropilamonio, glyphosate potassium, glufosinato, glufosinato ammonio, dicamba, sal de dicamba etanolamina, sal de dicamba diglicolamina, dicamba potasio y sal de dicamba BAPMA (es decir, sal de dicamba N,N-bis(3-am¡noprop¡l)metilam¡na), 2,4-D, sal de colina 2,4-D, mesotriona, tolpiralato y topramezona. In a particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is not present. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is selected from the group comprising glyphosate, glyphosate dimethylammonium, glyphosate isopropylammonium and glyphosate potassium. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is selected from the group comprising glufosinate and glufosinate ammonium. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is selected from the group comprising L-glufosinate, L-glufosinate ammonium and L-glufosinate sodium. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is selected from the group comprising dicamba, dicamba ethanolamine salt, dicamba diglycolamine salt, dicamba potassium and dicamba BAPMA salt. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and a first Compound IV is selected from the group comprising glyphosate, glyphosate dimethylammonium, glyphosate isopropylammonium and glyphosate potassium and a second Compound IV is selected from the group comprising dicamba, dicamba ethanolamine salt, dicamba diglycolamine salt, dicamba potassium and dicamba BAPMA salt. occi ηη / ι znz / E / v In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is selected from the group comprising 2,4-D and 2,4-D choline salt. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and a first Compound IV is selected from the group comprising glyphosate, glyphosate dimethylammonium, glyphosate isopropylammonium and glyphosate potassium and a second Compound IV is selected from the group comprising 2,4-D and 2,4-D choline salt. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is mesotrione. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is topramezone. In another particularly preferred embodiment of the invention, Compound III is imazethapyr or imazethapyr ammonium and Compound IV is tolpyralate. The preferred terms of the present invention are detailed in Table 2, whereby the abbreviations are shown in Table 1: Tabla 1 occi ηη / ι ζπζ / ε / υιλι Compuesto Abbreviatura imazamox 111-1 imazamox amonio III-2 imazapir III-3 imazapir isopropylamonio III-4 imazapir amonio III-5 imazapic III-6 imazapic amonio III-7 imazaquín III-8 imazaquín amonio III-9 imazetapir 111-10 imazetapir ammonium 111-11 glyphosate IV-1 glyphosate dimethylamonium IV-2 glyphosate isopropylamonium IV-3 glyphosate potassium IV-4 glyphosate trimesium (sulphosate) IV-5 glufosinate IV-6 Compound Abbreviation ammonium glufosinate IV-7 sodium glufosinate IV-8 L-glufosinate IV-9 L-glufosinate ammonium IV-10 L-glufosinate sodium IV-11 dicamba IV-12 dicamba salt ethanolamine IV-13 dicamba salt diglycolamine IV-14 dicamba BAPMA potassium IV-16 2,4-D IV-17 choline salt 2,4-D IV-18 bicyclopyrone IV-19 phenquinonetrione IV-20 mesotrione IV-21 tembothrione IV-22 tolpyrate IV-23 topramezone IV-24 Table 2 N.° I II III IV M-1 I II 111-1 - M-2 I II III-2 - M-3 I II III-3 - M-4 I II III-4 - M-5 I II III-5 - M-6 I II III-6 - N.° I II III IV M-7 I II III-7 - M-8 I II III-8 - M-9 I II III-9 - M-10 I II 111-10 - M-11 I II 111-11 - M-12 I II 111-1 IV-1 N.° I II III IV M-13 I II 111-1 IV-2 M-14 I II 111-1 IV-3 M-15 I II 111-1 IV-4 M-16 I II 111-1 IV-5 M-17 I II 111-1 IV-6 M-18 I II 111-1 IV-7 M-19 I II 111-1 IV-8 M-20 I II 111-1 IV-9 M-21 I II 111-1 IV-10 M-22 I II 111-1 IV-11 M-23 I II 111-1 IV-12 M-24 I II 111-1 IV-13 M-25 I II 111-1 IV-14 M-26 I II 111-1 IV-15 M-27 I II 111-1 IV-16 M-28 I II 111-1 IV-17 M-29 I II 111-1 IV-18 M-30 I II 111-1 IV-19 M-31 I II 111-1 IV-20 M-32 I II 111-1 IV-21 M-33 I II 111-1 IV-22 M-34 I II 111-1 IV-23 M-35 I II 111-1 IV-24 M-36 I II III-2 IV-1 M-37 I II III-2 IV-2 M-38 I II III-2 IV-3 M-39 I II III-2 IV-4 M-40 I II III-2 IV-5 M-41 I II III-2 IV-6 M-42 I II III-2 IV-7 M-43 I II III-2 IV-8 M-44 I II III-2 IV-9 M-45 I II III-2 IV-10 M-46 I II III-2 IV-11 M-47 I II III-2 IV-12 M-48 I II III-2 IV-13 M-49 I II III-2 IV-14 M-50 I II III-2 IV-15 M-51 I II III-2 IV-16 M-52 I II III-2 IV-17 M-53 I II III-2 IV-18 M-54 I II III-2 IV-19 M-55 I II III-2 IV-20 M-56 I II III-2 IV-21 M-57 I II III-2 IV-22 M-58 I IIIII-2 IV-23 M-59 I II III-2 IV-24 M-60 I II III-3 IV-1 M-61 I II III-3 IV-2 M-62 I II III-3 IV-3 M-63 I II III-3 IV-4 M-64 I II III-3 IV-5 M-65 I II III-3 IV-6 N.° I II III IV M-66 I II III-3 IV-7 M-67 I II III-3 IV-8 M-68 I II III-3 IV-9 M-69 I II III-3 IV-10 M-70 I II III-3 IV-11 M-71 I II III-3 IV-12 M-72 I II III-3 IV-13 M-73 I II III-3 IV-14 M-74 I II III-3 IV-15 M-75 I II III-3 IV-16 M-76 I II III-3 IV-17 M-77 I II III-3 IV-18 M-78 I II III-3 IV-19 M-79 I II III-3 IV-20 M-80 I II III-3 IV-21 M-81 I II III-3 IV-22 M-82 I II III-3 IV-23 M-83 I II III-3 IV-24 M-84 I II III-4 IV-1 M-85 I II III-4 IV-2 M-86 I II III-4 IV-3 M-87 I II III-4 IV-4 M-88 I II III-4 IV-5 M-89 I II III-4 IV-6 M-90 I II III-4 IV-7 M-91 I II III-4 IV-8 M-92 I II III-4 IV-9 M-93 I II III-4 IV-10 M-94 I II III-4 IV-11 M-95 I II III-4 IV-12 M-96 I II III-4 IV-13 M-97 I II III-4 IV-14 M-98 I II III-4 IV-15 M-99 I II III-4 IV-16 M-100 I II III-4 IV-17 M-101 I II III-4 IV-18 M-102 I II III-4 IV-19 M-103 I II III-4 IV-20 M-104 I II III-4 IV-21 M-105 I II III-4 IV-22 M-106 I II III-4 IV-23 M-107 I II III-4 IV-24 M-108 I II III-5 IV-1 M-109 I II III-5 IV-2 M-110 I II III-5IV-3 M-111 I II III-5 IV-4 M-112 I II III-5 IV-5 M-113 I II III-5 IV-6 M-114 I II III-5 IV-7 M-115 I II III-5 IV-8 M-116 I II III-5 IV-9 M-117 I II III-5 IV-11 II-10 M-3 occi ηη / ι ζηζ / Ε / γ N.° I II III IV M-119 I II III-5 IV-12 M-120 I II III-5 IV-13 M-121 I II III-5 IV-14 M-122 I II III-5 IV-15 M-123 I II III-5 IV-16 M-124 I II III-5 IV-17 M-125 I II III-5 IV-18 M-126 I II III-5 IV-19 M-127 I II III-5 IV-20 M-128 I II III-5 IV-21 M-129 I II III-5 IV-22 M-130 I II III-5 IV-23 M-131 I II III-5 IV-24 M-132 I II III-6 IV-1 M-133 I II III-6 IV-2 M-134 I II III-6 IV-3 M-135 I II III-6 IV-4 M-136 I II III-6 IV-5 M-137 I II III-6 IV-6 M-138 I II III-6 IV-7 M-139 I II III-6 IV-8 M-140 I II III-6 IV-9 M-141 I II III-6 IV-10 M-142 I II III-6 IV-11 M-143 I II III-6 IV-12 M-144 I II III-6 IV-13 M-145 I II III-6 IV-14 M-146 I II III-6 IV-15 M-147 I II III-6 IV-16 M-148 I II III-6 IV-17 M-149 I II III-6 IV-18 M-150 I II III-6 IV-19 M-151 I II III-6 IV-20 M-152 I II III-6 IV-21 M-153 I II III-6 IV-22 M-154 I II III-6 IV-23 M-155 I II III-6 IV-24 M-156 I II III-7 IV-1 M-157 I II III-7 IV-2 M-158 I II III-7 IV-3 M-159 I II III-7 IV-4 M-160 I II III-7 IV-5 M-161 I II III-7 IV-6 M-162 I IIIII-7 IV-7 M-163 I II III-7 IV-8 M-164 I II III-7 IV-9 M-165 I II III-7 IV-10 M-166 I II III-7 IV-11 M-167 I II III-7 IV-12 M-168 I II III-7 IV-13 M-169 I II III-7 IV-14 M-170 I II III-7 IV-15 M-171 I II III-7 IV-16 N.° I II III IV M-172 I II III-7 IV-17 M-173 I II III-7 IV-18 M-174 I II III-7 IV-19 M-175 I II III-7 IV-20 M-176 I II III-7 IV-21 M-177 I II III-7 IV-22 M-178 I II III-7 IV-23 M-179 I II III-7 IV-24 M-180 I II III-8 IV-1 M-181 I II III-8 IV-2 M-182 I II III-8 IV-3 M-183 I II III-8 IV-4 M-184 I II III-8 IV-5 M-185 I II III-8 IV-6 M-186 I II III-8 IV-7 M-187 I II III-8 IV-8 M-188 I II III-8 IV-9 M-189 I II III-8 IV-10 M-190 I II III-8 IV-11 M-191 I II III-8 IV-12 M-192 I II III-8 IV-13 M-193 I II III-8 IV-14 M-194 I II III-8 IV-15 M-195 I II III-8 IV-16 M-196 I II III-8 IV-17 M-197 I II III-8 IV-18 M-198 I II III-8 IV-19 M-199 I II III-8 IV-20 M-200 I II III-8 IV-21 M-201 I II III-8 IV-22 M-202 I II III-8 IV-23 M-203 I II III-8 IV-24 M-204 I II III-9 IV-1 M-205 I II III-9 IV-2 M-206 I II III-9 IV-3 M-207 I II III-9 IV-4 M-208 I II III-9 IV-5 M-209 I II III-9 IV-6 M-210 I II III-9 IV-7 M-211 I II III-9 IV-8 M-212 I II III-9 IV-9 M-213 I II III-9 IV-10 M-214 I II III-9 IV-11 M-215 I IIIII-9 IV-12 M-216 I II III-9 IV-13 M-217 I II III-9 IV-14 M-218 I II III-9 IV-15 M-219 I II III-9 IV-16 M-220 I II III-9 IV-17 M-221 I II III-9 IV-18 I II III M-392- IV-20 M-224 I II III-9 IV-21 occi ηη / ι ζηζ / Ε / γ N.° I II III IV M-225 I II III-9 IV-22 M-226 I II III-9 IV-23 M-227 I II III-9 IV-24 M-228 I II 111-10 IV-1 M-229 I II 111-10 IV-2 M-230 I II 111-10 IV-3 M-231 I II 111-10 IV-4 M-232 I II 111-10 IV-5 M-233 I II 111-10 IV-6 M-234 I II 111-10 IV-7 M-235 I II 111-10 IV-8 M-236 I II 111-10 IV-9 M-237 I II 111-10 IV-10 M-238 I II 111-10 IV-11 M-239 I II 111-10 IV-12 M-240 I II 111-10 IV-13 M-241 I II 111-10 IV-14 M-242 I II 111-10 IV-15 M-243 I II 111-10 IV-16 M-244 I II 111-10 IV-17 M-245 I II 111-10 IV-18 M-246 I II 111-10 IV-19 M-247 I II 111-10 IV-20 M-248 I II 111-10 IV-21 M-249 I II 111-10 IV-22 M-250 I II 111-10 IV-23 M-251 I II 111-10 IV-24 M-252 I II 111-11 IV-1 M-253 I II 111-11 IV-2 M-254 I II 111-11 IV-3 M-255 I II 111-11 IV-4 M-256 I II 111-11 IV-5 M-257 I II 111-11 IV-6 M-258 I II 111-11 IV-7 M-259 I II 111-11 IV-8 M-260 I II 111-11 IV-9 M-261 I II 111-11 IV-10 M-262 I II 111-11 IV-11 M-263 I II 111-11 IV-12 M-264 I II 111-11 IV-13 M-265 I II 111-11 IV-14 M-266 I II 111-11IV-15 M-267 I II 111-11 IV-16 M-268 I II 111-11 IV-17 M-269 I II 111-11 IV-18 M-270 I II 111-11 IV-19 M-271 I II 111-11 IV-20 M-272 I II 111-11 IV-21 M-273 I II 111-11 IV-22 M-274 I II 111-11 IV-23 M-275 I II 111-11 IV-24 M-276 I II 111-10 IV-1 + IV-12 M-277 I II 111-10 IV-1 + IV-13 N.° I II III IV M-278 I II 111-10 IV-1 + IV-14 M-279 I II 111-10 IV-1 + IV-15 M-280 I II 111-10 IV-1 + IV-16 M-281 I II 111-10 IV-1 + IV-17 M-282 I II 111-10 IV-1 + IV-18 M-283 I II 111-10 IV-2 + IV-12 M-284 I II 111-10 IV-2 + IV-13 M-285 I II 111-10 IV-2 + IV-14 M-286 I II 111-10 IV-2 + IV-15 M-287 I II 111-10 IV-2 + IV-16 M-288 I II 111-10 IV-2 + IV-17 M-289 I II 111-10 IV-2 + IV-18 M-290 I II 111-10 IV-3 + IV-12 M-291 I II 111-10 IV-3 + IV-13 M-292 I II 111-10 IV-3 + IV-14 M-293 I II 111-10 IV-3 + IV-15 M-294 I II 111-10 IV-3 + IV-16 M-295 I II 111-10 IV-3 + IV-17 M-296 I II 111-10 IV-3 + IV-18 M-297 I II 111-10 IV-4 + IV-12 M-298 I II 111-10 IV-4 + IV-13 M-299 I II 111-10 IV-4 + IV-14 M-300 I II 111-10 IV-4 + IV-15 M-301 I II 111-10 IV-4 + IV-16 M-302 I II 111-10 IV-4 + IV-17 M-303 I II 111-10 IV-4 + IV-18 M-304 I II 111-10 IV-5 + IV-12 M-305 I II 111-10 IV-5 + IV-13 M-306 I II 111-10 IV-5 + IV-14 M-307 I II 111-10 IV-5 + IV-15 M-308 I II 111-10 IV-5 + IV-16 M-309 I II 111-10 IV-5+ IV-17 M-310 I II 111-10 IV-5 + IV-18 M-311 I II 111-11 IV-1 + IV-12 M-312 I II 111-11 IV-1 + IV-13 M-313 I II 111-11 IV-1 + IV-14 M-314 II-11-IV-11 M-315 I II 111-11 IV-1 + IV-16 M-316 I II 111-11 IV-1 + IV-17 M-317 I II 111-11 IV-1 + IV-18 M-318 I II 111-11 IV-2 + IV-12 M-319 I II 11-11 IV-21 + IV-23 111-11 IV-2 + IV-14 M-321 I II 111-11 IV-2 + IV-15 M-322 I II 111-11 IV-2 + IV-16 M-323 I II 111-11 IV-2 + IV-17 M-324 I II 111-11 + IV-2 II-121 IV-3 + IV-12 M-326 I II 111-11 IV-3 + IV-13 M-327 I II 111-11 IV-3 + IV-14 M-328 I II 111-11 IV-3 + IV-15 M-329 I II 111-11 IV-3 + IV-16 M-321 IV-13 + IV-13 occi ηη / ι ζπζ / ε / υιλι N.° I II III IV M-331 I II 111-11 IV-3 + IV-18 M-332 I II 111-11 IV-4 + IV-12 M-333 I II 111-11 IV-4 + IV-13 M-334 I II 111-11 IV-4 + IV-14 M-315 II-14 IV-14 M-336 I II 111-11 IV-4 + IV-16 M-337 I II 111-11 IV-4+ IV-17 M-338 I II 111-11 IV-4 + IV-18 N.° I II III IV M-339 I II 111-11 IV-5 + IV-12 M-340 I II 111-11 IV-5 + IV-13 M-341 I II 111-11 IV-5 + IV-14 M-342 I II 111-11 IV-5 + IV-15 M-343 II-11 IV-15 + IV-15 M-344 I II 111-11 IV-5 + IV-17 M-345 I II 111-11 IV-5 + IV-18 occi ηη / ι znz / E / v Por ende, las mezclas de mayor preferencia son M-1, M-2, M-3, M-4, M-5, M-6, M-7, M-8, M-9, M10, M-11, M-12, M-13, M-14, M-15, M-16, M-17, M-18, M-19, M-20, M-21, M-22, M-23, M-24, M-25, M-26, M-27, M-28, M-29, M-30, M-31, M-32, M-33, M-34, M-35, M-36, M-37, M-38, M-39, M-40, M-41, M-42, M43, M-44, M-45, M-46, M-47, M-48, M-49, M-50, M-51, M-52, M-53, M-54, M-55, M-56, M-57, M-58, M-59, M-228, M-229, M-230, M-231, M-232, M-233, M-234, M-235, M-236, M-237, M-238, M-239, M-240, M241, M-242, M-243, M-244, M-245, M-246, M-247, M-248, M-249, M-250, M-251, M-252, M-253, M-254, M-255, M-256, M-257, M-258, M-259, M-260, M-261, M-262, M-263, M-264, M-265, M-266, M-267, M268, M-269, M-270, M-271, M-272, M-273, M-274, M-275, M-276, M-277, M-278, M-279, M-280, M-281, M-282, M-283, M-284, M-285, M-286, M-287, M-288, M-289, M-290, M-291, M-292, M-293, M-294, M295, M-296, M-297, M-298, M-299, M-300, M-301, M-302, M-303, M-304, M-305, M-306, M-307, M-308, M-309, M-310, M-311, M-312, M-313, M-314,M-315, M-316, M-317, M-318, M-319, M-320, M-321, M322, M-323, M-324, M-325, M-326, M-327, M-328, M-329, M-330, M-331, M-332, M-333, M-334, M-335, M-336, M-337, M-338, M-339, M-340, M-341, M-342, M-343, M-344 y M-345., Las mezclas de máxima preferencia son M-10, M-11, M-228, M-229, M-230, M-231, M-232, M233, M-234, M-235, M-236, M-237, M-238, M-239, M-240, M-241, M-242, M-243, M-244, M-245, M-248, M-250, M-251, M-252, M-253, M-254, M-255, M-256, M-257, M-258, M-259, M-260, M-261, M-262, M263, M-264, M-265, M-266, M-267, M-268, M-269, M-272, M-274, M-275, M-276, M-277, M-278, M-279, M-280, M-281, M-282, M-283, M-284, M-285, M-286, M-287, M-288, M-289, M-290, M-291, M-292, M293, M-294, M-295, M-296, M-297, M-298, M-299, M-300, M-301, M-302, M-303, M-304, M-305, M-306, M-307, M-308, M-309, M-310, M-311, M-312, M-313, M-314, M-315, M-316, M-317, M-318, M-319, M320, M-321, M-322, M-323, M-324, M-325, M-326, M-327, M-328, M-329, M-330, M-331, M-332, M-333, M-334, M-335, M-336, M-337, M-338, M-339, M-340, M-341, M-342, M-343, M-344 y M-345. Todas las mezclas antes mencionadas también se denominan, más adelante, “mezclas inventivas”. Inventive mixtures may also contain one or more insecticides, fungicides, and herbicides. The mixtures of the invention can be converted into the usual types of agrochemical mixtures, for example, solutions, emulsions, suspensions, powders, pastes, granules, pressed products, capsules, and mixtures thereof. Examples of mixture types include suspensions (e.g., SC, OD, FS), emulsifiable concentrates (e.g., EC), emulsions (e.g., EW, EO, ES, ME), capsules (e.g., CS, ZC), wettable pastes, tablets, powders, or slurries (e.g., WP, SP, WS, DP, DS), pressed products (e.g., BR, TB, DT), granules (e.g., WG, SG, GR, FG, GG, MG), insecticidal articles (e.g., LN), and gel formulations for treating plant propagation materials such as seeds (e.g., GF). These and other types of mixtures are defined in “Catalogue of pesticide formulation types and International coding System”, technical monograph No. 2, 6th edition, May 2008, CropLife International. The mixtures are prepared in a known way, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. Suitable auxiliaries include solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, food stimulants, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, stickiness enhancers and binders. Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions with a medium to high boiling point, e.g., kerosene, diesel fuel; oils of vegetable or animal origin; aliphatic, cyclic, and aromatic hydrocarbons, e.g., toluene, paraffin, tetrahydronaphthalene, alkylated naphthalenes; alcohols, e.g., ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, e.g., cyclohexanone; esters, e.g., lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, e.g., N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof. Suitable solid carriers or fillers are mineral earths, for example silicates, silica gels, talc, kaolin, limestone, quicklime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, for example cellulose, starch; fertilizers, for example ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, for example cereal flour, tree bark flour, wood flour, nut shell flour and mixtures thereof. Suitable surfactants are surface-active compounds such as anionic, cationic, nonionic, and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. These surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids, or adjuvants. Examples of surfactants are listed in McCutcheon's, vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (international or US edition). Suitable anionic surfactants are alkali, alkaline earth, or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates include alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignin sulfonates, fatty acid and oil sulfonates, ethoxylated alkylphenol sulfonates, alkoxylated arylphenol sulfonates, condensed naphthalene sulfonates, dodecylbenzene and tridecylbenzene sulfonates, naphthalene and alkylnaphthalene sulfonates, sulfosuccinates, and sulfosuccinamates. Examples of sulfates include sulfates of fatty acids and oils, ethoxylated alkylphenols, alcohols, ethoxylated alcohols, or fatty acid esters. Examples of phosphates include phosphate esters. Examples of carboxylates include alkylcarboxylates, and carboxylated or ethoxylated alkylphenol alcohols. Suitable nonionic surfactants include alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids, or fatty acid esters that have been alkoxylated with 1 to 50 equivalents. Ethylene oxide and / or propylene oxide can be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid amides are fatty acid glucoamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters, or monoglycerides. Examples of sugar-based surfactants include sorbitan, ethoxylated sorbitan, sucrose-glucose esters, and alkyl polyglucosides. Examples of polymeric surfactants include vinylpyrrolidone homopolymers or copolymers, vinyl alcohols, and vinyl acetate. Suitable cationic surfactants are quaternary surfactants, for example, quaternary ammonium compounds with one or two hydrophobic groups or salts of long-chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are AB or ABA type block polymers, comprising polyethylene oxide and polypropylene oxide blocks, or ABC type block polymers, comprising alkanol, polyethylene oxide, and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or comb-type polyacid polymers. Examples of polybases are polyvinylamines or polyethyleneamines. Suitable adjuvants are compounds that have little or no pesticidal action and that improve the biological performance of the mixtures of the invention on the target. Examples include surfactants, mineral or vegetable oils, and other auxiliaries. Further examples are listed in Knowles, Adjuvants and Additives, Agrow Reports DS256, T&F Informa UK, 2006, Chapter 5. Suitable thickeners include polysaccharides (e.g., xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates. Suitable bactericides are bronopol and isothiazolinone derivatives, such as alkylisothiazolinones and benzisothiazolinones. Suitable antifreeze agents are ethylene glycol, propylene glycol, urea, and glycerin. Suitable antifoaming agents include silicones, long-chain alcohols, and fatty acid salts. Suitable colorants (e.g., in red, blue, or green) are pigments with low water solubility and water-soluble dyes. Examples include inorganic dyes (e.g., iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (e.g., alizarin, azo, and phthalocyanine dyes). Suitable stickiness enhancers or binders include polyvinylpyrrolidones, polyvinyl acetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers. occi ηη / ι znz / E / v Examples of mixture types and their preparation are: i) Water-soluble concentrates (SL, LS) 10-60% by weight of a mixture of the invention and 5-15% by weight of a wetting agent (e.g., alkoxylated alcohol) are dissolved in water and / or in a water-soluble solvent (e.g., alcohols) up to 100% by weight. The active substance dissolves upon dilution with water. i) Dispersible Concentrates (DC) Dissolving 5-25% by weight of an inventive mixture and 1-10% by weight of dispersant (e.g., polyvinylpyrrolidone) in an organic solvent (e.g., cyclohexanone) to up to 100% by weight is achieved. Dilution with water produces a dispersion. iii) Emulsifiable concentrates (EC) 15-70% by weight of an inventive mixture and 5-10% by weight of emulsifiers (e.g., calcium dodecylbenzenesulfonate and ethoxylated castor oil) are dissolved in a non-water-soluble organic solvent (e.g., aromatic hydrocarbon) to a final volume of 100% by weight. Dilution with water produces an emulsion. iv) Emulsions (EW, EO, ES) 5-40% by weight of a mixture of the invention and 1-10% by weight of emulsifiers (e.g., calcium dodecylbenzenesulfonate and ethoxylated castor oil) are dissolved in 20-40% by weight of a non-water-soluble organic solvent (e.g., aromatic hydrocarbon). This mixture is introduced into up to 100% by weight of water using an emulsifying machine and becomes a homogeneous emulsion. Dilution with water produces an emulsion. v) Suspensions (SC, OD, FS) In a stirred ball mill, 20–60 wt% of an inventive mixture is pulverized with the addition of 2–10 wt% dispersants and wetting agents (e.g., sodium lignosulfonate and ethoxylated alcohol), 0.1–2 wt% of thickener (e.g., xanthan gum), and water up to 100 wt% to obtain a fine suspension of the active substance. Dilution with water produces a stable suspension of the active substance. For the FS-type mixture, up to 40 wt% of binder (e.g., polyvinyl alcohol) is added. vi) Water dispersible granules and water soluble granules (WG, SG) Fifty-eight percent by weight of an inventive mixture is finely ground with the addition of dispersants and wetting agents (e.g., sodium lignosulfonate and ethoxylated alcohol) up to 100% by weight and prepared as water-dispersible or water-soluble granules using technical means (e.g., extrusion, spray tower, fluidized bed). Dilution with water produces a stable dispersion or solution of the active substance. vii) Water dispersible powders and water-soluble powders (WP, SP, WS) 50-80% by weight of a mixture of the invention is ground in a rotor-stator mill with the addition of 1-5% by weight of dispersants (e.g., sodium lignosulfonate), 1-3% by weight of wetting agents (e.g., ethoxylated alcohol), and a solid carrier (e.g., silica gel) to 100% by weight. Dilution with water produces a stable dispersion or solution of the active substance. viii) Gel (GW, GF) In a stirred ball mill, 5-25% by weight of a mixture of the invention is pulverized with the addition of 3-10% by weight of dispersants (e.g., sodium lignosulfonate), 1-5% by weight of a thickener (e.g., carboxymethylcellulose), and up to 100% by weight of water to obtain a fine suspension of the active substance. Dilution with water produces a stable suspension of the active substance. ix) Microemulsion (ME) 5-20% by weight of a mixture of the invention is added to 5-30% by weight of a mixture of organic solvents (e.g., cyclohexanone and fatty acid dimethylamide), 10-25% by weight of a mixture of surfactants (e.g., ethoxylated alcohol and ethoxylated arylphenol), and water to a total of 100% by weight. This mixture is stirred for 1 hour to spontaneously produce a thermodynamically stable microemulsion. x) Microcapsules (OS) An oily phase comprising 5-50 wt% of a mixture of the invention, 0-40 wt% of a non-water-soluble organic solvent (e.g., aromatic hydrocarbon), and 2-15 wt% of acrylic monomers (e.g., methyl methacrylate, methacrylic acid, and a diacrylate or triacrylate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules. Alternatively, an oily phase comprising 5-50 wt% of a mixture according to the invention, 0-40 wt% of a non-water-soluble organic solvent (e.g., aromatic hydrocarbon), and an isocyanate monomer (e.g., diphenylmethen-4,4'-diisocyanate) is dispersed in an aqueous solution of a protective colloid (e.g., polyvinyl alcohol). The addition of a polyamine (e.g., hexamethylenediamine) results in the formation of polyurea microcapsules.Monomers represent 1-10% by weight. The weight percentage refers to the total CS mixture. xi) Powders that can be converted into dust (DP, DS) 1-10% by weight of a mixture of the invention is finely ground and thoroughly mixed with a solid carrier (e.g., finely divided kaolin) to 100% by weight. x) Granules (GR, FG) 0.5–30% by weight of an inventive mixture is finely ground and combined with a solid carrier (e.g., silicate) up to 100% by weight. Granulation is achieved by extrusion, spray drying, or fluidized bed drying. xii) Ultra-low volume (UL) fluids 1-50% by weight of an inventive mixture is dissolved in an organic solvent (e.g., aromatic hydrocarbon) up to 100% by weight. The mixture types i) to xii) may optionally include other auxiliaries, such as 0.1-1% by weight of bactericides, 5-15% by weight of antifreeze agents, 0.1-1% by weight of antifoaming agents and 0.1-1% by weight of colorants. occi ηη / ι znz / E / v In general, the resulting agrochemical mixtures comprise 0.01 to 95%, preferably 0.1 to 90%, and in particular 0.5 to 75% by weight of active substance. The active substances are used at a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectrum). Seed treatment solutions (LS), suspoemulsions (SE), flowable concentrates (FS), dry treatment powders (DS), water dispersible suspension treatment powders (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC), and gels (GF) are frequently used for the treatment of plant propagation materials, particularly seeds. The mixtures in question, after dilution two to ten times, produce active substance concentrations of 0.01 to 60% by weight, preferably 0.1 to 40% in ready-to-use preparations. Application can be carried out before or during sowing. Methods for applying the inventive mixtures and their combinations to plant propagation material, particularly seeds, include application by coating, furrowing, dusting, soaking, and furrowing. Preferably, the inventive mixture or its combinations are applied to the plant propagation material by a method that does not induce germination, for example, by disinfecting, furrowing, coating, or dusting seeds. Various types of oils, wetting agents, adjuvants, fertilizers or micronutrients, and other pesticides (e.g., herbicides, insecticides, fungicides, growth regulators, protectants) may be added to the active substances or inventive mixtures comprising them, either as premixes or, if appropriate, only immediately before use (tank mixing). These agents may be mixed with the inventive mixtures in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1. In general, the user applies the mixture according to the invention using a pre-dosing device, a backpack sprayer, a spray tank, a crop duster, or an irrigation system. The agrochemical mixture is often composed of water, a buffer, and / or other auxiliaries at the desired application concentration, resulting in the ready-to-use spray liquor or the agrochemical mixture according to the invention. Typically, 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of usable agricultural area. The inventive mixtures provide excellent pre- and post-emergence weed control in HPPD-tolerant soybeans and cotton. Therefore, in the methods and uses of the invention, the compounds present in the inventive mixtures can be applied pre-emergence (before the emergence of unwanted vegetation) or post-emergence (i.e., during and / or after the emergence of unwanted vegetation). Therefore, the invention relates to an inventive mixture method for controlling unwanted vegetation in HPPD-tolerant soybeans and cotton, comprising applying the compounds present in the inventive mixtures to the loci of the planted crops where unwanted vegetation occurs or may occur. The application is carried out before, during, and / or after the emergence of unwanted vegetation. The application can be done after sowing the soybeans or during and / or after the emergence of the soybeans. As used herein, the term "locus" means the area where vegetation or plants grow or will grow, generally a field. As used herein, the terms control and combat are synonymous. As used herein, the expressions unwanted vegetation, unwanted species, unwanted plants, harmful plants, unwanted weeds, or harmful weeds are synonymous. When using inventive mixtures in the methods of the present invention, the active compounds present in the inventive mixtures can be applied simultaneously or sequentially, where unwanted vegetation may occur. It is irrelevant whether the compounds present in the inventive mixtures are formulated jointly or separately and applied jointly or separately, and, in the case of separate application, the order in which the application occurs is irrelevant. It is only necessary that the compounds present in the inventive mixtures be applied within a period that allows for the simultaneous action of the active ingredients on the unwanted plants. In the methods mentioned above for weed control using inventive mixtures, these mixtures exhibit remarkable herbicidal action against a broad spectrum of economically important monocotyledonous and dicotyledonous weeds. The inventive mixtures are also effective against perennial weeds that produce shoots from rhizomes, rootstocks, or other perennial organs that are difficult to control. In this context, it makes no difference whether the compounds in the inventive mixtures are applied before sowing, before emergence, or after emergence. Application before emergence is preferred. Inventive mixtures are suitable for controlling a large number of noxious plants in agricultural crops, including monocotyledonous weeds, in particular annual weeds, such as grasses, including species of Echinochloa, such as barnyardgrass (Echinochloa crusgalli var. crus-galli), Echinochloa walteri (Pursh) Heller, barnyardgrass (Echinochloa colona), Echinochloa crus-pavonis, Echinochloa oryzicola, species of Digitaria, such as crabgrass (Digitaria sanguinalis), Digitaria hohzontalis, crabgrass (Digitaria insularis) or crabgrass (Digitaria nuda), species of Setaria, such as green-leaved sagebrush (Setaria viridis), foxtail (Setaria faberii), yellow strawgrass (Setaria glauca or Setaria pumila) or Setaria verticillata, species of Sorghum, such as Aleppo sorghum (Sorghum halepense Pers.), Avena species, such as wild oats (Avena fatua), sterilis Avena Avena strigosa, Cenchrus species, such as cardillo chico (Cenchrus pauciflorus) or Cenchrus echinatus, Bromus species, such as Bromus japonicus Thunb, Bromus sterilis or Bromus tectorum, Lolium species, Phalaris species, such as Phalaris brachystachys, Phalaris minor or Phalaris persicaria, Eriochloa species, Panicum species, such as false millet (Panicum occi ηη / ι znz / E / v dichotomiflorum), Panicum fasciculatum or Panicum maximum, Brachiaria species, annual bluegrass (Poa annua), Alopecurus species, such as blackgrass (Alopecurus myosuroides), Alopecurus aequalis Sobol or Alopecurus japonicus Steud, Aegilops species, such as Aegilops cylindrica or Aegylops tauschii, Apera spica-venti, Eleusine indica, Cynodon dactylon, grass (Agropyron repens or Elymus repens), Agrostis alba, Beckmannia syzigachne (Steud.) Fernald, Chloris species, such as Chloris virgata, Commelina species, such as Commelina benghalensis, Commelina communis, Commelina diffusa or Commelina erecta, Dactyloctenium aegyptium, Hordeum jubatum, Hordeum leporinum, Imperata cylindrica, Ischaemum rogusum, Ixophorus unisetus, Leerisa hexandra, Leersia japonica, Leptochloa species, such as Leptochloa chinensis, Leptochloa fascicularis, Leptochloa filiformis or Leptochloa panicoides, Lolium species, such as Lolium multiflorum, Lolium perenne, Lolium persicum or valley (Lolium rigidum), Luziola subintegra, Murdannia nudiflora (L.) Brenan, Oryza latifolia, Oryza rufipogon, Paspalum distichum, Paspalum species, Pennisetum americanum, Pennisetum purpureum, Phleum paniculatum, Phragmites australia, Ploypogon fugax. N., species of Poa, such as Poa annua or Poa trivialis L., Puccinellia distans, Flottboellía cochinchinensis, Sclerochloa kengiana (Ohwi) Tzvel., Trichloris crinita, Urochloa or species of Brachiaria, such as Brachiaria decumbens, Brachiaria plantaginea, Brachiaria platyphylla, Urochloa panicoides, Urochloa ramosa and similar. Inventive mixtures are also suitable for controlling a large number of dicotyledonous weeds, in particular broadleaf weeds including Polygonum species, such as annual bindweed (Polygonum convolvuus), Polygonum pensilvanicum, Polygonum persicaria or knotweed (Polygonum aviculare), Amaranthus species, such as sagebrush (Amaranthus retroflexus), Palmer amaranth (Amaranthus palmer!), water hemp (Amaranthus tuberculatus or Amaranthus rudis), sorrel (Amaranthus retroflexus), pigweed (Amaranthus hybridus), red amaranth (Amaranthus lividus), spiny amaranth (Amaranthus spinosus) or Amaranthus quitensis, Chenopodium species, such as common purple amaranth (Chenopodium album L.), Chenopodium serotinum or quinoa (Chenopodium quinoa), species of Sida, such as spiny sida (Sida spinosa L.), species of Ambrosia, such as common ragweed (Ambrosia artemisiifolia) or large sagebrush (Ambrosia trifida), species of Acanthospermum,Anthemis species, such as Anthemis arvensis or Anthemis cotula, Atriplex species, Cirsium species, such as Cirsium arvense, Convolvulus species, such as field bindweed (Convolvulus arvensis), Conyza species, such as Canada broom (Conyza canadensis, Erigeron canadensis) or bonariensis broom (Conyza bonariensis, Erigeron bonariensis), Cassia species, Datura species, such as jimsonweed (Datura stramonium), Euphorbia species, such as white poinsettia (Euphorbia dentata), Euphorbia hirta, Euphorbia helioscopia or milkweed (Euphorbia heterophylla), Geranium species, such as Geranium donianum or Geranium pusillum, Galinsoga species, morning glory (Ipomoea species), Lamium species, such as dead-nettle (Lamium amplexicaule), species of Malva, such as round-leaf mallow (Malva neglecta) or small-flowered mallow (Malwa parviflora), species of Matricaria, such as chamomile (Matricaria chamomilla) or Matricaria inodora,species of Sysimbrium, species of Solanum, tales such as tomatillo del occi ηη / ι znz / E / v diablo (Solanum nigrum), species of theophrasti), Sesbania species, such as Sesbania exaltata, Sesbania herbácea or Hemp sesbania (Sesbania exaltata Cory), Anoda cristata, Bidens species, such as Bidens frondosa or Bidens pilosa, Brassica kaber, Capsella species, such as Capsella media or Capsella bursa-pastoris, Centaurea cyanus, Galeopsis tetrahit, Galium aparine, Helianthus annuus, Desmodium tortuosum, Kochia scoparia, Mercurialis annual, Myosotis arvensis, Papaver rhoeas, species of Raphanus, tales such as wild rabe (Raphanus raphanistrum), species of Salsola, tales such as Salsola tragus or Salsola kali, Sinapis arvensis, species of Sonchus, such as Sonchus asper, Sonchus arvensis or Sonchus oleraceus, Thlaspi arvense,Tagetes minuta, Richardia species, such as Richardia scabra or Richardia brasiliensis, Aeschynomene species, such as Aeschynomene denticulata, Aeschynomene indica or Aeschynomene rudis, Alisma species, such as Alisma canaliculatum or Alisma plantago-aquatica, Borreria species, such as Borreria verticillata, Brassica rapa, Carduus acanthoides, Parietaria debilis, Portulaca oleracea, Ipomoea species, such as Ipomoea grandifolia, Ipomoea hederacea, Ipomoea indivisa, Ipomoea ¡acunose, Ipomoea lonchophylla or Ipomoea wrightii, Senna obtusifolia, Sida species, such as escudilla (Sida rhombifolia) or sida espinosa (Sida spinosa), Spermacoce latifolia, Tridax procumbens, Trianthema portulacastrum, Parthenium hysterophorus, Portulaca oleracea, Acalypha australis, Ammi majus, Atriplex species, Orobanche species, Mercurialis annua, Cirsium arvense, Calystegia sepium, Stellaria media, species of Lamium, species of Viola, Celosía argentea,Melampodium divaricatum, Cleome viscosa, Molugo verticilatus, Borhevia erecta, Gomphrena species, Nicandra physalodes, Ricinus communis, Geranium dissectum, Alternanthera species, such as Alternanthera philoxeroides or Alternanthera tenella, Ammannia species, such as Ammania coccinea, Anacamtodon fortune! Mitt., Anagallis arvensis, Aneilema keisak, Arenaria serpyllifolia, Argemone mexicana, Asphodelus tenuifolius, Atriplex patula, Bacopa rotundifolia, Brassica napus, Caperonia species, such as Caperonia castaneifolia or Caperonia palustris, Cephalanoplos segetum, Corynopus didymus, Crepis capillaris, Crepis tectorum, Croton lobatus, Descuminia sophia (L), Descurainia pinnata, Echinodorus grandiflorus, Eclipta alba, Eclipta prostrata, Eichhornia crassipes, Eleocharis species, Equisetum arvense, Fallopia convolvulus, Fallopia convolvulus, Heteranthera limosa, Jussiaea species, Kallstroemia maxima, Lactuca serriola, Lathyrus aphaca, Launea mudicaulis,Leucas chinensis, Limnocharis flava, Lindernia dubia, Lindernia pyxidaria, Litospermum arvense, Ludwigia species, such as Ludwigia octovallis, Macroptilium lathyroides, Malachium aquaticum (L.), Melilotus species, Merremia aegyptia, Momordica charantia, Monochoria hastate, Monochoria vaginalis, Mucuna species, Murdannia nudiflora, Oxalis neaei, Phylanthus species, Physalis species, Pistia stratiotes, Potamogetón distinctus, Rorippa islándica, Rotala indica, Rotala ramosior, Rumex dentatus, Rumex obtusifolius, Sagittaria montevidensis, Sagittaria pygmaea Miq., Sagittaria sagittifolia, Sagittaria trifolia L., Senecio vulgaris, Sicyos polyacanthus, Silene gallica, chenopod species, such as Sisymbrium officinale, Solanum species, Spergula arvensis, Sphenoclea zeylanica, Trianthema spp., Tripleurospermum inodorum, Veronica species, such as occi ηη / ι znz / E / v, Veronica persica or Veronica polita Vicia sativa and the like. The inventive mixtures are also suitable for controlling a wide range of annual and perennial sedge weeds including Cyperus species, such as purple tigernut (Cyperus rotundus L.), yellow coquillo (Cyperus esculentus L.), hime-kugu (Cyperus brevifolius H.), sedge weed (Cyperus microiria Steud), coquito (Cyperus iría L.), Cyperus difformis, Cyperus difformis L, Cyperus esculentus, Cyperus ferax, Cyperus flavus, Cyperus iría, Cyperus lanceolatus, Cyperus odoratus, Cyperus rotundus, Cyperus serotinus Rottb., Eleocharis acicularis, Eleocharis kuroguwai, Fimbristylis dichotoma, Fimbristylis miliacea, Scirpus grossus, Scirpus juncoides, Scirpus juncoides Roxb, Scirpus or Bolboschoenus maritimus, Scirpus or Schoenoplectus mucronatus, Scirpus planiculmis Fr. Schmidt and similar. Inventive mixtures are also suitable for controlling weeds that are resistant to commonly used herbicides, such as weeds that are resistant to glyphosate, weeds that are resistant to auxin-inhibiting herbicides such as 2,4-D or dicamba, weeds that are resistant to photosynthesis inhibitors such as atrazine, weeds that are resistant to ALS inhibitors such as sulfonylureas, imidazolinones, or triazolopyrimidines, weeds that are resistant to ACCase inhibitors such as clodinafop, clethodim, or pinoxaden, or weeds that are resistant to protoporphyrinogen-IX-oxidase inhibitors such as sulfentrazone, flumioxazine, fomesafen, or acifluorfen, for example, the weeds detailed in the International Survey of Resistant Weeds. (http: / / www.weedscience.org / Summary / SDeciesbvSOATable.aspx). In particular, they are suitable for controlling the resistant weeds detailed in the International Survey of Resistant Weeds, for example,Echinochloa crus-galli, Avena fatua, Alopecurus myosuroides, Echinochloa cotona, Alopecurus japónicos, Bromos tectorom, Hordeom morinom, Ischaemom rogosom, Setaria viridis, Sorghum halepense, Alopecoros aeqoalis, Apera spica-venti, Avena sterilis, Beckmannia szygachne, Bromos diandros, Digitaria sangoinalis, Echinocloa oryzoides, Echinochloa phyllopogon, Phalaris minor, Phalaris paradoxa, Setaria faberi, Setaria viridis, Brachypodiom distachyon, Bromos diandros, Bromos sterilis, Cynosoros echinatos, Digitaria insolaris, Digitaria ischaemom, Leptochloa chinensis, Phalaris brachystachis, Rotboellia cochinchinensis, Digitaria ciliaris, Ehrharta longiflora, Eriochloa ponctata, Leptochloa panicoides, Loliom persicom, Polypogon fogax, Sclerochloa kengiana, Snowdenia polystacha, Sorghum sodanese and Brachiaria plantaginea resistant to ACCasa, Echinochloa cros-galli, Poa annoa, Avena fatoa, Alopecoros myosoroides, Echinochloa colona, ​​Amaranthos hybridos, Amaranthos palmeri, Amaranthos rodis,Conyza somatrensis, Amaranthos retroflexos, Ambrosia artemisifolia, Conyza canadensis, Kochia scoparia, Raphanos raphanistrom, Senecio vernalis, Alopecoros japónicos, Bidens pilosa, Bromos tectorom, Chenopodiom albom, Conyza bonariensis, Hordeom morinom, Ischaemom rogosom, Senecio volgaris, Setaria viridis, Sisymbriom orientale, Sorghom halepense, Alopecoros aeqoalis, Amaranthos blitom, Amaranthos powellii, Apera spica-venti, Avena sterilis, Brassica rapa, Bromos diandros, Descorainia sophia, Digitaria sangoinalis, Echinochloa oryzoides, Echinochloa phyllopogon, Eophorbia heterophylla, Lactoca serriola, Phalaris minor, Phalaris paradoxa, Setaria faberi, Setaria viridis, Sinapis arvensis, Solanum ptycanthom, Sonchos oleráceos, Stellaria media, Amaranthos occi ηη / ι znz / E / v blitoides, Amaranthus spinosus, Amaranthus viridis, Ambrosia trifida, Bidens subalternaos, Bromus diandrus, Bromus sterilis, Capsella bursa-pastoris, Centaurea cyanus, Cynosurus echinatus, Cyperus difformis,Fimbristilis miliacea, Galeopsis tetrahit, Galium aparine, Galium spurium, Helianthus annuus, Hirschfeldia incana, Limnocharis flava, Limnophila erecta, Papaver rhoeas, Parthenlum hysterophorus, Phalaris brachystachis, Polygonum convolvulus, Polygonum lapathifolium, Polygonum persicaria, Ranunculus acris, Rottboellia cochinchinensis, Sagittaria montevidensis, Salsola tragus, Schoenoplectus mucronatus, Setaria pumila, Sonchus asper, Xanthium strumarium, Ageratum conyzoides, Alisma canaliculatum, Alisma plantago-aquatica, Ammannia auriculata, Ammannia coccinea, Ammannia arvensis, Anthemis cotula, Bacopa rotundifolia, Bifora radians, Blyxa aubertii, Brassica tournefortii, Bromus japonicus, Bromus secalinus, Lithospermum arvense, Camelina microcarpa, Chamaesyce maculata, Chrysanthemum coronarium, Clidemia hirta, Crepis tectorum, Cuscuta pentagon, Cyperus brevifolis, Cyperus compressus, Cyperus esculentus, Cyperus iría, Cyperus odoratus, Damasonium minus, Diplotaxis erucoides,Diplotaxis tenuifolia, Dopatrum junceum, Echium plantagineum, Elatine triandra, Eleocharis acicularis, Erucaria hispánica, Erysimum repandum, Galium tricornutum, Iva xanthífolia, Ixophorus unisetus, Lamium amplexicaule, Limnophilia sessiliflora, Lindernia dubia, Lindernia micrantha, Lindernia procumbens, Ludwigia prostrata, Matricaria recutita, Mesembryanthemum crystallinum, Monochoria korsakowii, Monochoria vaginalis, Myosoton aquaticum, Neslia paniculata, Oryza sativa var. sylvatica, Pentzia suffruticosa, Picris hieracioides, Raphanus sativus, Rapistrum rugosum, Rorippa indica, Rotala indica, Rotala pusilla, Rumex dentatus, Sagittaria guayensis, Sagittaria pygmaea, Sagittaria trifolia, Schoenoplectus fluviatilis, Schoenoplectus juncoides, Schoenoplectus wallichii, Sida spinosa, Silene gallica, Sinapis alba, Sisymbrium thellungii, Sorghum bicolor, Spergula arvensis, Thlaspi arvense, Tripleurospermum perforatum, Vaccaria hispánica and Vicia sativa resistant to ALS inhibitor,Echinochloa crus-galli, Poa annua, Alopecurus myosuroides, Echinochloa colona, ​​Amaranthus hybridus, Amaranthus palmer!, Amaranthus rudis, Conyza sumatrensis, Amaranthus retroflexus, Ambrosia artemisifolia, Conyza canadensis, Kochia scoparia, Raphanus raphanistrum, Senecio vernalis, Alopecurus japonicus, Bidens pilosa, Bromus tectorum, Chenopodium album, Conyza bonariensis, Ischaemum rugosum, Senecio vulgaris, Setaria viridis, Sisymbrium orientale, Amaranthus blitum, Amaranthus powellii, Apera spica-venti, Beckmannia syzigachne, Brassica rapa, Digitaria sanguinalis, Euphorbia heterophylla, Phalaris minor, Phalaris paradoxa, Setaria faberi, Setaria viridis, Sinapis arvensis, Solanum ptycanthum, Stellaria media, Amaranthus blitoides, Amaranthus viridis, Bidens subalternans, Brachypodium distachyon, Capsella bursa-pastoris, Chloris barbata, Cyperus difformis, Echinochloa erecta, Epilobium ciliatum, Polygonum aviculare, Polygonum convolvulus, Polygonum lapathifolium, Polygonum persicaria,Portulaca olerácea, Schoenoplectus mucronatus, Setaria pumila, Solanum nigrum, Sonchus asper, Urochloa panicoides, Vulpia bromoides, Abutilón theophrasti, Amaranthus albus, Amaranthus cruentus, Arabidopsis thaliana, Arenaria serpyllifolia, Bidens tripartita, Chenopodium album, Chenopodium ficifolium, Chenopodium polyspermum, Crypsis schoenoides, Datura stramonium, Epilobium tetragonum, Galinsoga ciliata, Matricaria discoidea, Panicum capillare, Panicum dichotomiflorum, Plantago lagopus, Polygonum hydopiper, Polygonum pensylvanicum, Polygonum monspeliensis, Postraría, smyrnacea, occi ηη / ι znz / E / v, Rumex acetosella, Setaria verticillata and Urtica urens resistant to the photosynthesis inhibitor, Poa annua, Conyza sumatrensis, Conyza canadensis, Alopecurus japonicus, Bidens pilosa, Conyza bonariensis, Hordeum murinum, Ischaemum rugosum, Amaranthus blitum, Solanum ptycanthum, Arctotheca marigold, Epilobium ciliatum, Hedyotis verticillata, Solanum nigrum, Vulpia bromoides, Convolvulus arvensis, Crassocephalum crepidioides, Cuphea carthagensis, Erigeron philadelphicus, Gamochaeta pensylvanica, Landoltia punctata, Lepidium virginicum, Mazus fauriei, Mazus pumilus, Mitracarpus hirtus, Sclerochloa dura, Solanum americanum and Youngia japonica resistant to the electron diversion inhibitor PS-I, Poa annua, Echinochloa colona, ​​Amaranthus hybridus, Amaranthus palmeri, Amaranthus rudis, Conyza sumatrensis, Ambrosia artemisifolia, Conyza canadensis, Kochia scoparia, Raphanus raphanistrum, Bidens pilosa, Conyza bonariensis, Hordeum murinum, Sorghum halepense, Brassica rapa, Bromus diandrus,Lactuca serriola, Sonchus oleraceus, Amaranthus spinosus, Ambrosia trifida, Digitaria insularis, Hedyotis verticillata, Helianthus annuus, Parthenium hysterophorus, Plantago lanceolata, Salsola tragus, Urochloa panicoides, Brachiaria eruciformis, Bromus rubens, Chloris elata, Chloris truncata, Chloris virgata, Cynodon hirsutos, Lactuca saligna, Leptochloa virgata, Paspalum paniculatum and Tridax procumbens resistant to glyphosate, Echinochloa crus-galli, Poa annua, Avena fatua, Alopecurus myosuroides, Amaranthus palmeri, Setaria viridis, Sorghum halepense, Alopecurus aequalis, Beckmannia syzigachne and Fumaria densifloria resistant to microtubule assembly inhibitor, Echinochloa crus-galli, Echinochloa colona, ​​Amaranthus hybridus, Amaranthus rudis, Conyza sumatrensis, Kochia scoparia, Raphanus raphanistrum, Chenopodium album, Sisymbrium orientale, Descurainia sophia, Lactuca serriola, Sinapis arvensis, Sonchus oleraceus, Stellaria media, Arctotheca calendula, Centaurea cyanus,Digitaria ischaemum, Fimbristylis miliacea, Galeopsis tetrahit, Galium aparine, Galium spurium, Hirschfeldia incana, Limnocharis flava, Limnocharis erecta, Papaver rhoeas, Plantago lanceolata, Ranunculus acris, Carduus nutans, Carduus pycnocephalus, Centaurea soltitialis, Centaurea stoebe ssp. Micranthos, Cirsium arvense, Commelina diffusa, Echinochloa crus-pavonis, Soliva sessilis and Sphenoclea zeylanica resistant to the auxin herbicide, Amaranthus palmeri and Amaranthus rudis resistant to the HPPD inhibitor, Acalypha australis, Amaranthus hybridus, Amaranthus palmeri, Amaranthus retroflexus, Amaranthus rudis, Ambrosia artemisifolia, Avena fatua, Conyza sumatrensis, Descurainia sophia, Euphorbia heterophylla and Senecio vernalis resistant to the PPO inhibitor, Hydrilla verticillata, Raphanus raphanistrum, Senecio vernalis and Sisymbrium orientale resistant to the carotenoid biosynthesis inhibitor, Alopecurus myosuroides,Avena fatua and Echinochloa crus-galli resistant to VLCFA inhibitor. If the compounds of the inventive mixtures are applied to the surface of the soil before germination, the emergence of weed seedlings is completely prevented, or the weeds grow until they have reached the cotyledon stage but their growth is stopped, and eventually, after three to four weeks, they die completely. If the active compounds of the inventive mixtures are applied after emergence on the green parts of the plants, growth is drastically stopped very soon after treatment and the weed plants remain at the growth stage of the time point of application, or die completely after a certain time, so that in this way, weed competition, which is harmful to soybean plants, is eliminated very early and in a sustained manner. When the active compounds in inventive mixtures are used together, superadditive (synergistic) effects are observed. This means that the effect of the combinations exceeds the total expected effects of the individual herbicides used. Synergistic effects allow for a reduced application rate, control of a broader spectrum of broadleaf and grass weeds, faster herbicide action, a longer duration of action, better control of weeds with only one or a few applications, and an extended application period. In some cases, the absorption of the mixtures also reduces the amount of harmful constituents in the crop plant, such as nitrogen or oleic acid. The active compounds in the inventive mixtures can be used together or sequentially. They can also be conveniently combined with other herbicide treatments for treatment combinations that ensure more complete or longer-lasting weed control, or to ensure control of weeds resistant to certain herbicides through the combined action of multiple herbicides with different modes of action. In particular, active compounds from inventive mixtures and other herbicides may be used in any of the soybean treatment combinations detailed below, which consist of pre-burning, pre-emergence, and post-emergence treatments. These treatment combinations may be particularly suitable if the soybean crop, in addition to being HPPD-tolerant, is also tolerant to the action of one or more herbicides present in the treatment combination, including tolerance resulting from breeding and / or genetic modification. Such tolerant plants include glufosinate-tolerant soybeans, glyphosate-tolerant soybeans, and soybeans that are tolerant to auxin herbicides (e.g., 2,4-D, dicamba) and / or PPO herbicides (e.g., carfentrazone-ethyl, saflufenacil, sulfentrazone, trifludimoxazin, pyraflufen-ethyl, thiafenacil). The following active compounds of inventive mixtures and other herbicides are particularly suitable as weed control components in the pre-burning of plants in such soybean treatment combinations: Glufosinate, glufosinate ammonium, glufosinate sodium, L-glufosinate, L-glufosinate ammonium, L-glufosinate sodium, glyphosate, glyphosate dimethylammonium, glyphosate potassium, glyphosate isopropylammonium, paraquat, thiapocenacil, trifludimoxazine, saflufenacil, sulfentrazone, flumioxazine, fomesafen, carfentrazone-ethyl, ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidine-3-yl)phenoxy]-2-pyridyloxy]acetate (CAS 353292-31-6, S-3100), chloransulam-methyl, chlorimuron-ethyl, imazethapyr, imazethapyr ammonium, 2,4-D, choline salt 2,4-D, dicamba, dicamba salt ethanolamine, dicamba salt diglycolamine, dicamba salt potassium and dicamba BAPMA (i.e., dicamba salt N,N-bis(3-aminopropyl)methylamine). The following active compounds of inventive mixtures and other herbicides are particularly suitable as pre-emergence weed control components in such soybean treatment combinations: isoxaflutol, pyroxasulfone, isoxaflutol / pyroxasulfone, isoxaflutol / pyroxasulfone / imazethapyr, isoxaflutol / pyroxasulfone / imazethapyr ammonium, isoxaflutol / pyroxasulfone / imazapic, isoxaflutol / pyroxasulfone / imazapic ammonium, isoxaflutol / pyroxasulfone / imazaquin, isoxaflutol / pyroxasulfone / imazaquin ammonium, isoxaflutol / mesotrione, isoxaflutol / mesotrione / pyroxasulfone, mesotrione / pyroxasulfone, pyroxasulfone / imazethapyr, isoxaflutol / imazethapyr, mesotrione / imazethapyr, acetochlor, metolachlor, (S)-metolachlor, dimethenamid, dimethenamid-P, petoxamid, chloransulam-methyl, chlorimuron-ethyl, tifensulfuron-methyl, imazethapyr, imazethapyr ammonium, trifludimoxazin, saflufenacil, sulfentrazone, flumioxazin, fomesafen, trifluralin, pendimethalin, metribuzin, mesotrione, tembotrionebicyclopyrone and phenquinetrione. The following active compounds of inventive mixtures and other herbicides are particularly suitable as post-emergence weed control components in such soybean treatment combinations: Glufosinate, glufosinate ammonium, glufosinate sodium, L-glufosinate, L-glufosinate ammonium, L-glufosinate sodium, glyphosate, glyphosate dimethylammonium, glyphosate potassium, glyphosate isopropylammonium, imazamox, imazamox ammonium, imazethapyr, imazethapyr ammonium, bentazone, bentazone sodium, isoxaflutol, topramezone, mesotrione, tolpyralate, isoxaflutol / mesotrione, isoxaflutol / topramezone, mesotrione / topramezone, isoxaflutol / tolpyralate, tembotrione, bicyclopyrone, phenquinetrione, carfentrazone-ethyl saflufenacil, sulfentrazone, trifludimoxazine, saflufenacil / trifludimoxazine, pyraflufen-ethyl, thiafenacil, ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidine-3-yl)phenoxy]-2-pyridyloxy]acetate (CAS 353292-31-6, S-3100), pyroxasulfone,isoxaflutol / pyroxasulfone, isoxaflutol / pyroxasulfone / imazethapyr, isoxaflutol / pyroxasulfone / imazethapyr ammonium, isoxaflutol / pyroxasulfone / imazamox, isoxaflutol / pyroxasulfone / imazamox ammonium, isoxaflutol / mesotrione / pyroxasulfone, mesotrione / pyroxasulfone, topramezone / pyroxasulfone, pyroxasulfone / imazamox, pyroxasulfone / imazamox ammonium, 2,4-D, choline salt 2,4-D, dicamba, dicamba ethanolamine salt, dicamba diglycolamine salt, dicamba potassium, and dicamba BAPMA salt., The properties and advantages mentioned above are necessary for practical weed control to free soybeans or cotton from competing unwanted plants and, therefore, ensure and / or increase resistance both qualitatively and quantitatively. These novel combinations significantly exceed the state of the art with respect to the properties described. Although the active compounds in the inventive mixtures have a remarkable herbicidal action against monocotyledonous and dicotyledonous weeds, glufosinate-tolerant, tolerant, or cross-tolerant cotton and soybeans are only slightly damaged or not damaged at all. As mentioned above, inventive mixtures are suitable for controlling a large number of harmful plants in HPPD-tolerant soybeans and cotton. Thus, the expressions “HPPD-tolerant soybeans” and “HPPD-tolerant cotton”, as used herein, also include plants (soybeans or cotton) that have been modified by mutagenesis, genetic engineering, or breeding and mutation selection techniques to provide a new trait to a plant or to modify a trait already present. Mutagenesis includes random mutagenesis techniques using X-rays or mutagenic chemicals, as well as targeted mutagenesis techniques, to create mutations at a specific locus in a plant genome. Mutagenesis techniques commonly use oligonucleotides or proteins, such as CRISPR / Cas, zinc-finger nucleases, TALEN, or meganucleases to achieve the targeted effect. Genetic engineering routinely uses recombinant DNA techniques to create modifications in a plant genome that cannot be easily obtained naturally through crossbreeding, mutagenesis, or natural recombination. Generally, one or more genes are integrated into a plant's genome to add or enhance a trait. These integrated genes are also referred to as transgenes, while the plant containing such transgenes is called a transgenic plant. The process of plant transformation often produces several transformation events, which differ in the genomic locus where a transgene is integrated. Plants containing a specific transgene at a specific genomic locus are often described as containing a specific "event," indicated by a specific event name. HPPD tolerance has been created through mutagenesis as well as genetic engineering. Transgenic soybean events that include HPPD tolerance genes are, for example, FG72 (which confers tolerance to HPPD inhibitors and glyphosate, commercially available as GT27® soybean), FG72xLL55 (which confers tolerance to HPPD inhibitors such as isoxaflutol, as well as glyphosate and glufosinate) and MGI (which confers tolerance to HPPD inhibitors such as isoxaflutol and mesotrione, as well as glufosinate). In other respects, the soybeans of the invention include those plants that have undergone genetic modifications other than HPPD tolerance by breeding, mutagenesis, or genetic engineering, for example, that are considered tolerant to applications of other specific classes of herbicides, such as PPG inhibitors (e.g., saflufenacil, trifludimoxazin), AHAS inhibitors; auxin herbicides, such as dicamba or 2,4-D; bleaching herbicides, such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (e.g., isoxaflutol, mesotrione, tembotrione, topramezone, bicyclopyrone) or phytoene desaturase (PDS) inhibitors; EPSPS inhibitors, such as glyphosate; glutamine synthetase (GS) inhibitors, such as glufosinate;inhibitors of lipid biosynthesis inhibitors, such as acetyl CoA carboxylase (ACCase), such as dim (e.g., cycloxydim, sethoxydim, clethodim, or tepraloxydim), fop (e.g., clodinafop, diclofop, fluazifop, haloxyfop, or quizalofop), and den (such as pinoxaden); or oxynil herbicides (i.e., bromoxynil or oxynil) as a result of conventional breeding methods or genetic engineering; thus, the soybean of the invention can be made resistant to various classes of herbicides through multiple genetic modifications, such as the FG72, FG72xLL55, and MGI soybeans mentioned above; Other examples of such resistance to various classes of herbicides include resistance to glyphosate, glufosinate, dicamba and HPPD inhibitors such as isoxaflutol or mesotrione; glyphosate, PPG inhibitors and HPPD inhibitors; glufosinate, HPPD inhibitors and PPG inhibitors; glyphosate, glufosinate, HPPD inhibitors and PPO inhibitors;glyphosate, dicamba, occi ηη / ι ζπζ / β / υ inhibitors; HPPD and PPO inhibitors; glyphosate, 2,4-D, HPPD inhibitors and PPO inhibitors; glyphosate, dicamba, glufosinate, HPPD inhibitors and PPO inhibitors; glyphosate, 2,4-D, glufosinate, HPPD inhibitors and PPO inhibitors; or any of the above-mentioned soybeans that are tolerant to other classes of herbicides, such as AHAS inhibitors or ACCase inhibitors. These herbicide resistance technologies are described, for example, in Pest Management Science (in volume, year, page): 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108; Australian Journal of Agricultural Research 58, 2007, 708; Science 316, 2007, 1185; and the references cited therein. In addition to these classes of inhibitors, the soybean of the invention can also be tolerant to herbicides that have other modes of action, for example, chlorophyll / carotenoid pigment inhibitors, cell membrane disruptors, photosynthesis inhibitors, cell division inhibitors, root inhibitors, shoot inhibitors, and combinations thereof. These additional tolerance traits can be expressed, for example, as mulant or wild-type PPO proteins, such as mulant AHASL proteins, mulant ACCase proteins, mulant EPSPS proteins, or mulant glutamine synthetase proteins; or as native, inbred, or transgenic mulant aryloxyalkanoate dioxygenase (AAD or DHT) proteins, haloarylnitrilase (BXN), 2,2-dichloropropionic acid dehalogenase (DEH), glyphosate-N-acetyltransferase (GAT), glyphosate decarboxylase (GDC), glyphosate oxidoreductase (GOX), glutathione-S-transferase (GST), phosphinothricin acetyltransferase (PAT or bar), or CYP450 proteins that have herbicide-degrading activity. The glufosinate-tolerant soybean of the present can also be stacked with other traits including, but not limited to, pesticidal traits such as Bt Cry and other proteins that have pesticidal action against beetles, moths, nematodes or other pests; nutritional or nutraceutical traits such as traits with modified oil profiles or oil content, traits with high protein or amino acid concentration, and other types of traits known in the prior art. Transgenic cotton events that include HPPD tolerance events are, for example, GHB811 and GHB814, which confer tolerance to glyphosate and HPPD inhibitors such as isoxaflutol. In other respects, the cotton plants of the invention include those plants that have undergone genetic modifications other than HPPD tolerance by breeding, mutagenesis, or genetic engineering, for example, that are considered tolerant to applications of other specific classes of herbicides, such as PPO inhibitors (e.g., saflufenacil, trifludimoxazin), AHAS inhibitors; auxin herbicides, such as dicamba or 2,4-D; bleaching herbicides, such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors (e.g., isoxaflutol, mesotrione, tembotrione, topramezone, bicyclopyrone) or phytoene desaturase (PDS) inhibitors; EPSPS inhibitors, such as glyphosate; glutamine synthetase (GS) inhibitors, such as glufosinate;inhibitors of lipid biosynthesis, such as acetyl CoA carboxylase (ACCase), such as dim (e.g., cycloxydim, sethoxydim, clethodim, or tepraloxydim), fop (e.g., clodinafop, diclofop, fluazifop, haloxyfop, or quizalofop), and den (such as pinoxaden); or oxynil herbicides (i.e., bromoxynil or ioxynil) as a result of conventional breeding methods or genetic engineering; thereby, the cotton plants of the invention can be made resistant to various classes of herbicides through multiple genetic modifications, such as resistance to glyphosate and HPPD inhibitors such as isoxaflutol; glyphosate, glufosinate and HPPD inhibitors such as isoxaflutole; glufosinate and HPPD inhibitors such as isoxaflutole; glyphosate, glufosinate, dicamba and HPPD inhibitors such as isoxaflutol; glyphosate, PPO inhibitors and HPPD inhibitors; glufosinate, HPPD inhibitors and PPO inhibitors;glyphosate, glufosinate, HPPD inhibitors, and PPO inhibitors; glyphosate, dicamba, HPPD inhibitors, and PPO inhibitors; glyphosate, 2,4-D, glufosinate, HPPD inhibitors, and PPO inhibitors; glyphosate, dicamba, glufosinate, HPPD inhibitors, and PPO inhibitors; or one of the above-mentioned cotton plants that are tolerant to other classes of herbicides, such as AHAS inhibitors or ACCase inhibitors. These herbicide resistance technologies are described, for example, in Pest Management Science (volume, year, page): 61, 2005, 246; 61, 2005, 258; 61, 2005, 277; 61, 2005, 269; 61, 2005, 286; 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108; Australian Journal of Agricultural Research 58, 2007, 708; Science 316, 2007, 1185; and the references cited therein. In addition to these classes of inhibitors, the cotton plants of the invention can also be tolerant to herbicides that have other modes of action, for example, chlorophyll / carotenoid pigment inhibitors, cell membrane disruptors, photosynthesis inhibitors, cell division inhibitors, root inhibitors, shoot inhibitors, and combinations thereof. These additional tolerance traits can be expressed, for example, as mutant or wild-type PPO proteins, such as mutant AHASL proteins, mutant ACCase proteins, mutant EPSPS proteins, or mutant glutamine synthetase proteins; or as mutant native, inbred, or transgenic aryloxyalkanoate dioxygenase (AAD or DHT) proteins, haloarylnitrilase (BXN), 2,2-dichloropropionic acid dehalogenase (DEH), glyphosate-N-acetyltransferase (GAT), glyphosate decarboxylase (GDC), glyphosate oxidoreductase (GOX), glutathione-S-transferase (GST), phosphinothricin acetyltransferase (PAT or bar), or CYP450 proteins that have herbicide-degrading activity. The glufosinate-tolerant cotton plants of the present may also be stacked with other traits including, but not limited to, pesticidal traits such as Bt Cry and other proteins that have pesticidal action against beetles, moths, nematodes or other pests; nutritional or nutraceutical traits such as traits with modified oil profiles or oil content, traits with high protein or amino acid concentration, and other types of traits known in the prior art. In all treatments according to the methods of the present invention, the inventive mixtures can be applied conventionally using techniques known to a person of average skill. Suitable techniques include spraying, atomizing, dusting, dispersing, or watering. The methods of application depend on the intended purpose; in each case, they must ensure that the distribution of the active ingredients according to the invention is as fine as possible. In one embodiment, the inventive mixtures are applied to a locus primarily by spraying, in particular, foliar spraying of an aqueous dilution of the active ingredients of the mixture. Application can be carried out using conventional spraying techniques with, for example, water as a carrier and spray liquor rates of approximately 10 to 2000 L / ha or 50 to 1000 L / ha (e.g., 100 to 500 L / ha). Application of the inventive mixtures by low- and ultra-low-volume methods, such as application in microgranule form, is also possible. The required application rate of the mixture of pure active compounds depends on the density of the unwanted vegetation, the stage of plant development, the climatic conditions of the location where the mixture is used, and the application method. Generally, the application rate of L-glufosinate is normally from 50 g / ha to 3000 g / ha and is preferably in the range of 100 g / ha to 2000 g / ha or from 200 g / ha to 1500 g / ha of active substance (ai), and the application rate of the second compound II of herbicide is from 1 g / ha to 2000 g / ha and is preferably in the range of 5 g / ha to 1500 g / ha, with greater preference, from 25 g / ha to 900 g / ha of the active substance (ai). The following examples illustrate the invention without imposing limitations. Biological examples Biological tests can demonstrate the control efficacy of the compounds, mixtures, or compositions of the present invention against specific weeds. However, the weed control achieved with these compounds, mixtures, or compositions is not limited to these species. The synergy or antagonism between the mixtures or compositions is determined using the Colby equation. Synergy can be described as an interaction in which the combined effect of two or more compounds is greater than the sum of the individual effects of each compound. The presence of a synergistic effect, in terms of percentage control, between two mixture components (X and Y) can be calculated using the Colby equation (Colby, SR, 1967, Calculating Synergistic and Antagonistic Responses in Herbicide Combinations, Weeds. 15,21-22): E = X+Y- — 100 When the effect of the observed combined control is greater than the effect of the expected (calculated) combined control (E), then the combined effect is synergistic. Synergistic weed control by means of mixtures according to the present invention was demonstrated by the following greenhouse experiment: The growing containers used were plastic pots filled with clayey sand containing approximately 3.0% humus as a substrate. The seeds of the test plants were sown separately for each species. For the pre-emergence treatment, the active ingredients, suspended or emulsified in water, were applied directly after sowing using fine-spray nozzles. The containers were gently watered to promote germination and growth, and then covered with transparent plastic domes until the plants rooted. This covering resulted in uniform germination of the test plants, unless the active ingredients had hindered it.For the post-emergence occi ηη / ι ζηζ / B / γ treatment, the test plants were first grown to a height of 3 to 32 cm, depending on the plant's growth habit, and only then treated with the active ingredients, which were suspended or emulsified in water. For this purpose, the test plants were either directly sown and grown in the same containers, or they were first grown separately as seedlings and transplanted into the test containers a few days before treatment. Depending on the species, the plants were maintained at a temperature of 10–25°C or 20–35°C, respectively. The test period lasted 20 days. During this time, the plants were cared for, and their response to the individual treatments was evaluated. The evaluation was performed using a scale of 0 to 100.100 means the absence of plant emergence or the total destruction of at least the aerial parts, and 0 means that there was no damage or that growth continued as normal. The plants used in the following pre-emergence greenhouse experiment belong to the following species: occi ηη / ι ζηζ / Β / γ EPPO Code Scientific Name Common Name GALAP Galium aparine Common name, cleavers The active ingredients used in the following post-emergence greenhouse experiment were formulated as follows: isoxaflutol, 75% WG; pyroxasulfone, 85% WG; imazethapyr, 240 g / L SL. The results shown in the following table demonstrate the synergistic action of isoxaflutol mixtures and the known mixture of pyroxasulfone and imazethapyr. Application rate in g / ha Herbicidal action against GALAP Isoxaflutol Pyroxasulfone + imazethapyr Found Calculated according to Colby (%) 25 g / ha - 0 - - 50 + 5 g / ha 55 - 25 g / ha 50 + 5 g / ha 98 55 g / ha 50 + 5 g / ha g / ha 30 - 12.5 g / ha 25 + 2.5 g / ha 90 30

Claims

CLAIMS 1. A herbicidal mixture comprising 1) isoxaflutol (Compound I), 2) pyroxasulfone (Compound II), 3) at least one imidazolinone herbicide selected from the group consisting of imazamox, imazapyr, imazapic, imazaquin and imazethapyr and their salts (Compound III), and 4) Optionally, at least one additional herbicide selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinate-P) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, bicyclopyrone, phenquinetrione, mesotrione, tembotrione, tolpyralate, and topramezone (Compound IV).

2. The herbicide mixture according to claim 1, wherein Compound IV is not present.

3. The herbicide mixture according to claim 1 or 2, wherein Compound III is selected from the group consisting of imazamox and imazamox ammonium.

4. The herbicide mixture according to claim 1 or 2, wherein Compound III is selected from the group consisting of imazapic, imazapic ammonium, imazapyr, imazapyr ammonium, imazapyr isopropylammonium, imazaquin, imazethapyr, and imazethapyr ammonium. 5.The herbicide mixture according to claim 1 or 2, wherein Compound III is selected from the group consisting of imazethapyr and imazethapyr ammonium.

6. The herbicide mixture according to any one of claims 1 or 3 to 5, wherein at least one Compound IV is present.

7. The herbicide mixture according to claim 6, wherein Compound IV is selected from the group consisting of glyphosate and its salts, glufosinate and its salts, L-glufosinate (glufosinateP) and its salts, dicamba and its salts and esters, 2,4-D and its salts and esters, mesotrione, tolpyralate, and topramezone.

8. The herbicide mixture according to any one of claims 1 to 7, wherein the weight ratio of Compound I to Compound II is 15:1 to 1:15, and the weight ratio of Compound I to Compound III is 15:1 to 1:15, and, if present, the weight ratio of Compound I to Compound IV is 100:1 to 1:1000. 9.A pesticide composition, comprising a liquid or solid carrier and a mixture as defined in any one of claims 1 to 8.

10. A method for controlling unwanted vegetation, comprising applying a mixture according to claims 1 to 8 to a locus where unwanted vegetation is present or is expected to be present, in particular, unwanted vegetation of the genus Amaranthus.

11. The method according to claim 10, comprising applying the mixture as defined in claims 1 to 8 before crop emergence (pre-emergence).

12. The method according to claim 10, comprising applying the mixture as defined in claims 1 to 8 before crop planting.

13. The method according to any one of claims 10 to 13, wherein the crop is selected from soybeans, preferably herbicide-tolerant soybeans. 14.The method according to any of claims 10 to 13, wherein the crop is cotton, preferably herbicide-tolerant cotton.

15. The method according to any of claims 10 to 14, wherein the components of the mixture, as defined in claims 1 to 8, are applied simultaneously, i.e., jointly or separately, or successively.