Herbicidal compositions

Abstract

The present invention relates to compositions comprising herbicidally active compounds (A) and (B), where (A) represents one or more compounds of the general formula (I) or agrochemically compatible salts thereof [component (A)], and (B) represents one or more herbicides [component (B)]. The application also relates to a process and to the use of the herbicidal composition according to the invention for controlling undesirable plants or regulating plant growth.

Description

[0001] BYC240214- Abroad

[0002] 1

[0003] Herbicide compositions

[0004] Description

[0005] The invention lies in the technical field of plant protection products that can be used against unwanted plant growth in non-cultivated land, for seed preparation or in plant crops and that contain as herbicide active ingredients a combination of at least two herbicides, wherein the compositions contain herbicidal active compounds (A) and (B), wherein (A) is one or more compounds of the general formula (I) or their agrochemically compatible salts [herbicides (A) or component (A)] and (B) is one or more herbicides (component B).

[0006] Compounds from the structural class of substituted N-phenyluracils are known as herbicides (see international application PCT / EP2023 / 077211). These compounds are effective against a broad spectrum of weeds in both pre-emergence and post-emergence applications, allowing for non-selective use to control unwanted plant growth or selective application in crops.

[0007] The efficacy of these herbicides against weeds is high, but generally depends on the application rate, the specific formulation, the spectrum of weeds targeted, the specific weeds being controlled, climatic and soil conditions, etc. Another criterion is the duration of action or the rate of herbicide degradation. Changes in the sensitivity of weeds, which can occur with prolonged herbicide use or in geographically limited areas, must also be considered. Loss of efficacy against individual plants can only be partially compensated for by increasing the application rate of the herbicides, for example, because this often reduces the selectivity of the herbicides or because an improvement in efficacy does not occur even with higher application rates. In general, there is a need for methods to achieve the same herbicide efficacy with lower application rates of active ingredients.A lower application rate not only reduces the amount of active ingredient required for application, but also generally reduces the amount of necessary formulation aids. Both of these factors reduce costs and improve the environmental compatibility of herbicide treatment.

[0008] One way to improve the application profile of a herbicide is to combine the active ingredient with one or more other active ingredients that contribute the desired additional properties. However, when several active ingredients are used together, phenomena of physical and biological incompatibility are not uncommon, such as insufficient stability in a co-formulation, degradation of one active ingredient, or antagonism of the BYC240214- Abroad.

[0009] 2

[0010] Active ingredients. In contrast, combinations of active ingredients with a favorable efficacy profile, high stability, and, if possible, an unexpectedly synergistically enhanced effect are desirable, which allows a reduction in the application rate compared to the individual application of the active ingredients to be combined.

[0011] The object of the present invention is to provide alternative or advantageous herbicidal compositions which have a good biological application profile and, if possible, several of the above-mentioned desired favorable properties.

[0012] Surprisingly, it has now been found that this task can be solved by using a composition containing herbicidally active compounds (A) and (B), where (A) means one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A)] and (B) means one or more herbicides [component (B)] selected from the group of herbicidal active ingredients (Bl) to (B40).

[0013] The compositions according to the invention work together in a particularly advantageous way, e.g. when they are used to control unwanted plant growth in crops such as wheat (durum and common wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as bush bean and broad bean), flax, barley, oats, rye, triticale, potato and millet (sorghum), non-cultivated land, pastureland and green / lawn areas and plantation crops.

[0014] The present invention therefore relates to compositions containing herbicidally active compounds (A) and (B), wherein

[0015] (A) represents one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A)],

[0016]

[0017] wherein

[0018] R 1 for hydrogen, fluorine, chlorine, bromine, iodine, cyano, methyl, ethyl, prop-1-yl, 1-methylethyl, but-1-yl, 1-methylpropyl, 2-methylpropyl, 1,1-dimethylethyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 2,2-Dimethylpropyl, 1-Ethylpropyl, n-Hexyl, 1-Methylpentyl, 2-Methylpentyl, 3-BYC240214- Foreign

[0019] 3

[0020] Methylpentyl, 4-Methylpentyl, 1,1 -Dimethylbutyl, 1,2-Dimethylbutyl, 1,3-Di- methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3-Dimethylbutyl, 1-Ethylbutyl, 2- Ethylbutyl, 1,1,2-Trimethylpropyl, 1,2,2-Trimethylpropyl, 1 -Ethyl- 1 -methylpropyl, 1- Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2,2,2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2- yloxy, 2-Methylprop-1-yloxy, 1,1-Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy, 2,2-Difluorethoxy, 2,2,2-Trifluorethoxy steht,

[0021] R 2 für Wasserstoff, Fluor, Chlor, Brom, Methyl, Trifluormethyl, Methoxy, Ethoxy, Prop-1-yloxy, But-1-yloxy steht,

[0022] R 3 für Wasserstoff, Fluor, Chlor, Brom, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-l-yloxy, 1,1-Dimethyleth-l-yloxy steht,

[0023] R 4represents fluorine, chlorine, bromine, cyano, NO2, C(O)NH2, C(S)NH2, trifluoromethyl, difluoromethyl, pentafluoroethyl, ethynyl, propyn-1-yl, 1-butyn-1-yl, pentyn-1-yl, hexyn-l-yl,

[0024] R 5 , R 6 and R 7unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Iod, Cyano, Methyl, Ethyl, Prop- 1-yl, 1 -Methylethyl, But- 1-yl, 1 -Methylpropyl, 2-Methylpropyl, 1.1 -Dimethylethyl, n-Pentyl, 1 -Methylbutyl, 2-Methylbutyl, 3-Methylbutyl, 1,1- Dimethylpropyl, 1,2-Dimethylpropyl, 2,2-Dimethylpropyl, 1 -Ethylpropyl, n-Hexyl, 1- Methylpentyl, 2-Methylpentyl, 3-Methylpentyl, 4-Methylpentyl, 1,1 -Dimethylbutyl, 1.2-Dimethylbutyl, 1,3-Di-methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3- Dimethylbutyl, 1-Ethylbutyl, 2-Ethylbutyl, 1,1,2-Trimethylpropyl, 1,2,2- Trimethylpropyl, 1 -Ethyl- 1 -methylpropyl, 1-Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2,2,2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-l-yloxy, 1,1- Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy,

[0025] 2.2-Difluorethoxy, 2,2,2-Trifluorethoxy stehen,

[0026] G for methylene, (methyl)methylene, (ethyl)methylene, (prop-1-yl)methylene, (prop-2-yl)methylene, (but-1-yl)methylene, (but-2-yl)methylene, (pent-1-yl)methylene, (pent-2-yl)methylene, (pent-3-yl)methylene, (dimethyl)methylene, (diethyl)methylene, ethylene, n-propylene, (l-methyl)ethyl-l-ene, (2-methyl)ethyl-l-ene, n-butylene, 1-methylpropyl-1-ene, 2-methylpropyl-1-ene, 3-methylpropyl-l-ene, 1,1-dimethylethyl-1-ene, 2,2-dimethylethyl-1-ene, 1-ethylethyl-1-ene, 2-ethylethyl-l-ene 1-(Prop-1-yl)ethyl-1-ene, 2-(Prop-1-yl)ethyl- BYC240214- Foreign

[0027] 4

[0028] 1-ene, l-(Prop-2-yl)ethyl-l-ene, 2-(Prop-2-yl)ethyl-l-ene, 1,1,2-trimethylethyl-l-ene, 1,2,2-trimethylethyl-l-ene, 1,1,2,2-tetramethylethyl-l-ene, n-pentylene, 1-methylbutyl-1-ene, 2- Methylbutyl-l-ene, 3-methylbutyl-l-ene, 4-methylbutyl-l-ene, 1,1-dimethylpropyl-1-ene, 2,2-dimethylpropyl-l-ene, 3,3-dimethylpropyl-l-ene, 1,2-dimethylpropyl-l-ene, 1,3-dimethylpropyl-l-ene, 1 -ethylpropyl-1-ene, n-Hexylene, 1-methylpentyl-1-ene, 2- Methylpentyl-l-ene, 3-methylpentyl-l-ene, 4-methylpentyl-l-ene, 1,1-dimethylbutyl-1-ene, 1,2-dimethylbutyl-l-ene, 1,3-dimethylbutyl-l-ene, 2,2-dimethylbutyl-l-ene, 2,3-dimethylbutyl-l-ene, 3,3-Dimethylbutyl-l-ene, 1-ethylbutyl-1-ene, 2-ethylbutyl-l-ene, 1,1,2-trimethylpropyl-1-ene, 1,2,2-trimethylpropyl-1-ene, 1-ethyl-1-methylpropyl-1-ene, 1-ethyl-2-methylpropyl-1-ene,

[0029] X and Y independently represent O (oxygen) or S (sulfur).

[0030] and

[0031] Q represents one of the following specifically named groupings Q1 to Q-25, where in the structural formulas of the following table the arrow represents a bond of the respective group Q to the carbonyl group in the general formula (I):

[0032]

[0033]

[0034]

[0035] BYC240214- Abroad

[0036]

[0037]

[0038] and

[0039] (B) represents one or more herbicides [component (B)] from the group of herbicidal active substances (B1) to (B40), wherein

[0040] (B) Structure Name CAS-RN B1 Ethyl-{[3-({3-chloro-5-fluoro-6-[3-methyl-2,6-2158274-56-5 dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]pyridin-2-yl}oxy)pyridin-2-yl]oxy}acetate

[0041] B2 Ethyl-[2-( { 3 -chloro-5 -fluoro-6- [3 -methyl-2, 6-dioxo- 2158274-50-9

[0042] 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl] pyridin-2-yl} oxy)phenoxy ] acetat

[0043] B3 2-Ethoxy-2-oxoethyl- 1 - { 2-chlor-4-fluor-5-[3- methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin- 1 (2H) - yl] phenoxy} cyclopropancarboxylat

[0044] B4 { [( 1- { 2-Chlor-4-fluor-5- [3 -methyl-2, 6-dioxo-4- 434334-78-8

[0045] (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl] phenoxy} cyclopropyl)carbonyl] - oxy}essigsäure

[0046] B5 1 -Ethoxy- 1 -oxopropan-2-yl- 1 - { 2-chlor-4-fluor-5 - 3017139-36-2

[0047] [3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin- 1 (2H) - yl] phenoxy} cyclopropan-carboxylat

[0048]

[0049] BYC240214- Ausland

[0050] (B) Struktur Name CAS-RN B6 Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-12-7 4°^ (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat

[0051] B7 Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-14-9

[0052] (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat

[0053] B8 Ethyl-3-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 2669815-00-1 V* sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenyl] - 3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat

[0054] B9 l-(3-Chlor-4,5,6,7-tetrahydropyrazolo[l,5- 1651191-47-7 a]pyridin-2-yl)-5-[(cyclopropylmethyl)amino]- lH-pyrazol-4-carbonitril

[0055] BIO Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 1949837-18-6

[0056] 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- * 0 yl] phenyl} -5 -methyl-4,5 -dihydro- 1,2-oxazol-5 - carboxylat

[0057] Bll Ethyl-3-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 2558200-05-6 sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenyl] - i °

[0058] 5-methyl-4,5-dihydro-l,2-oxazol-5-carboxylat

[0059] B12 3-{2-chlor-4-fluor-5-[3-rnethyl-2,6-dioxo-4- 3000495-74-6 A (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- * 0 yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carbonsäure

[0060] B13 Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 2669821-71-8 A 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- 1 V \ 0 yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat

[0061]

[0062] BYC240214- Ausland

[0063] (B) Struktur Name CAS-RN B14 3-{2-Chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-11-6

[0064] (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carbonsäure

[0065] B15 Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 2669819-07-0 Ä - 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat

[0066] B16 (S)-Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6- 2641255-87-8 dioxo-4-(trifluormethyl)-3,6-dihydropyrimidin- 1 (2H)-yl]phenyl} -5-methyl-4,5-dihydro- 1,2- oxazol-5 -carboxylat

[0067] B17 (R) -Ethyl-3 - { 2-chlor-4-fluor-5 - [3 -methyl-2, 6- 2763291-38-7 dioxo-4-(trifluormethyl)-3,6-dihydropyrimidin- 1 (2H)-yl]phenyl} -5-methyl-4,5-dihydro- 1,2- oxazol-5 -carboxylat

[0068] B18 Ethyl-{[3-({3-chlor-6-[4-(l,l-difluorethyl)-3- ° ö

[0069] X Q<” XA. methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -5 -fluorpyridin-2-yl} oxy)pyridin-2- yl]oxy}acetat

[0070] B19 { [3-({ 3-Chlor-6-[4-(l, l-difluorethyl)-3-methyl- 2,6-dioxo-3,6-dihydropyrimidin- 1 (2H)-yl] -5- fluorpyridin-2-yl} oxy)pyridin-2- yl]oxy}essigsäure

[0071] B20 Ethyl- [2-( { 3-chlor-6- [4- ( 1, 1 -difluorethyl)-3- methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -5 -fluorpyridin-2-yl} oxy)phenoxy ] acetat

[0072] B21 [2-({ 3-Chlor-6-[4-(l, l-difluorethyl)-3-methyl-2,6- dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -5 - fluorpyridin-2-yl}oxy)phenoxy]essigsäure

[0073] B22 Ethyl-[(3- { 2-chlor-5-[4-(l, 1 -difluorethyl)-3- 2892260-46-5

[0074] ■ XA methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -4-fluorphenoxy} pyridin-2-yl)oxy ] acetat

[0075]

[0076] BYC240214- Ausland

[0077] (B) Struktur Name CAS-RN B23 [(3-{2-Chlor-5-[4-(l,l-difluorethyl)-3-methyl-2,6- 2892260-49-8 jJkX 'jjy - dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -4- V

[0078] C>° z - fluorphenoxy}pyridin-2-yl)oxy]essigsäure

[0079] B24 Ethyl-(2- { 2-chlor-5 - [4-( 1, 1 -difluorethyl) -3 - 2892260-47-6 methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -4-fluorphenoxy}phenoxy)acetat

[0080] B25 (2- { 2-Chlor-5-[4-( 1, 1 -difluorethyl)-3-methyl-2,6- 2892260-48-7 dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -4- fluorphenoxy}phenoxy)essigsäure

[0081] B26 2-Ethoxy-2-oxoethyl- 1 - [2-chlor-5 -(3,5 -dimethyl- 3024787-37-6 M 2,6-dioxo-4-sulfanyliden- 1,3,5-triazinan- 1 -yl)-4- fluorphenoxy]cyclopropancarboxylat

[0082] B27 [({ l-[2-Chlor-5-(3,5-dimethyl-2,6-dioxo-4- 3024787-49-0 sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenoxy] cyclopropyl} carbonyl)oxy]essigsäure

[0083] B28 R R 1 - [2-Chlor-5-(3,5-dimethyl-2,6-dioxo-4- 3024787-36-5 o o

[0084] ^ >o°== sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4- o o ö ö

[0085] fluorphenoxy]cyclopropancarbonsäure

[0086] B29 O O U- U- 1 -Ethoxy- 1 -oxopropan-2-yl- 1 - [2-chlor-5 -(3,5 - 3024787-56-9 dimethyl-2,6-dioxo-4-sulfanyliden- 1,3,5- triazinan-l-yl)-4- fluorphenoxy]cyclopropancarboxylat

[0087] B30 Methyl-l-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 3024787-35-4 XCtXx sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4- 1 fluorphenoxy]cyclopropancarboxylat

[0088] B31 (Tetrahydrofuran-2-yl)methyl (2R)-2-[(4-amino- 2445983-82-2

[0089] 3,5-dichlor-6-fluor-2-pyridyl)oxy]propanoat

[0090] B32 N (Tetrahydrofuran-2-yl)methyl (2S)-2-[(4-amino- CI J\ / CI

[0091] 3,5-dichlor-6-fluor-2-pyridyl)oxy]propanoat

[0092] o

[0093] B33 (Tetrahydrofuran-2-yl)methyl (2R / S)-2-[(4- 2374902-16-4 amino-3,5-dichlor-6-fluor-2- pyridyl)oxy]propanoate

[0094]

[0095] BYC240214- Ausland

[0096] (B) Struktur Name CAS-RN B34 (2R)-2-[(4-Amino-3,5-dichlor-6-fluor-2- 2445980-81-2 ° -n pyridyl)oxy]propansäure

[0097] B35 & N o o

[0098] \ a> n (2S)-2-[(4-Amino-3,5-dichlor-6-fluor-2- ^< O

[0099] o pyridyl)oxy]propansäure

[0100] M V

[0101] 0

[0102] B36 N 2- [(4- Amino-3,5-dichlor-6-fluor-2- 50848-50-5 F X - X JUo pyridyl)oxy]propansäure

[0103] 0

[0104] B37 Cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7- 2251111-18-7

[0105] F fluor- 1 H-indol-6-yl)pyridin-2-carboxylat

[0106] N

[0107] B38 Prop-l-in-3-yl 4-amino-3-chloro-5-fluoro-6-(7- 2251111-17-6 fluor- 1 H-indol-6-yl)pyridin-2-carboxylat

[0108] N

[0109] B39 Ethyl-3-{2-chloro-4-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidine-l(2H)-MVyl]phenyl}-3a,4,5,6-tetrahydro-6aH-cyclopenta[d][1,2]oxazole-6a-carboxylate

[0110] B40 Ethyl-3-[2-chloro-5-(3,5-dimethyl-2,6-dioxo-4-sulfanyliden-1,3,5-triazinan-1-yl)-4-fluorophenyl] - i " 5-ethyl-4,5-dihydro-l,2-oxazole-5-carboxylate

[0111]

[0112] mean.

[0113] The names of the herbicides listed above (common name) are supplemented by the listed "CAS RN" (Chemical Abstracts Service Registry Number) (abbreviated "CAS"). The CAS RN is a widely used reference number that allows for the unambiguous identification of the substances, as it distinguishes between isomers, including stereoisomers, as well as salts and esters.

[0114] Compounds Bl and B2 are described in WO2017202768A1.

[0115] Connection B3 is described in WO2022138632A1.

[0116] Connection B4 is described in US6403534 sheet.

[0117] Connection B5 is described in WO2023228935 Al. BYC240214- Abroad

[0118] 10

[0119] Compounds B6, B7, B8, B12, B13, B14, B15 and B39 are described in WO2021143677 Al and WO2023197899.

[0120] Connection B9 is described in WO2015020156 A1.

[0121] The BIO compound is described in WO2016095768 Al.

[0122] Compounds Bll and B40 are described in CN111961041.

[0123] Compounds B16 and B17 are described in CN112679488.

[0124] Compounds B22, B23, B24 and B25 are described in WO2023285222 Al.

[0125] Compounds B26, B27, B28, B29 and B30 are described in WO2023249039 Al.

[0126] Connections B31, B33 and B34 are described in WO2020135235 Al.

[0127] Connection B36 is described in US3761486 A.

[0128] Connections B37 and B38 are described in WO2018208582 Al.

[0129] The compositions according to the invention can contain further components, e.g., other active substances against harmful organisms such as weeds, pests, or fungi, in particular active substances from the group of herbicides, fungicides, insecticides, acaricides, nematicides, and miticides and related substances, or also other types of plant protection active substances (e.g., resistance inducers), crop-protecting active substances (safeners, antidotes), plant growth regulators, and / or additives and / or formulation aids commonly used in plant protection. The components can be formulated and applied together (finished formulation) or they can be formulated separately and applied together, e.g., in a tank mix or in sequential application.

[0130] The individual herbicidal active ingredients of general formula (I) contained as component (A) are hereinafter also referred to as compounds (A), active ingredients (A), components (A), or herbicides (A). Similarly, the individual herbicidal active ingredients contained as component (B) are hereinafter also referred to as compounds (B), active ingredients (B), components (B), or herbicides (B).

[0131] An advantageous feature of the combination of herbicides (A) and (B) according to the invention is that active ingredients (A) and (B) are compatible with each other; that is, they can be used together without significant chemical incompatibilities occurring between active ingredients (A) and / or (B) that would lead to the decomposition of one or more active ingredients. This avoids a reduction in the active ingredient content in formulations or spray solutions. The favorable compatibility also extends to the biological properties of the active ingredients when used in combination. Thus, antagonistic effects are generally not observed in the control of weeds with the active ingredient combinations according to the invention. Therefore, active ingredients (A) and (B) are particularly suitable for use together or additionally with other plant protection product active ingredients or BYC240214- Abroad

[0132] 11

[0133] agrochemicals can be used. The combined application enables the use of beneficial effects, such as expanding the spectrum of weeds to be controlled or managed in a single application, and reducing the application rate of individual herbicides (A) or (B) compared to the respective application rate of the herbicide in a single application. This can influence the degradation behavior of the active ingredients and create more favorable conditions for subsequent crop cultivation. A further advantage is that the development of weed resistance to the active ingredients can often be significantly reduced or avoided by combining active ingredients with different modes of action.

[0134] Surprisingly, the combined application of active ingredients (A) and (B) results in synergistic effects on a large number of economically important weeds. The combined effect is stronger than the expected sum of the effects of the individual herbicides used. These synergistic effects allow for a further reduction in application rate, control of a broader spectrum of weeds and grasses, faster onset of herbicidal action, longer-lasting effect, better weed control with only one or a few applications, and an extension of the possible application period. In some cases, the use of these products also reduces the amount of harmful constituents, such as nitrogen or oleic acid, and their input into the soil.

[0135] The aforementioned properties and advantages are desirable in practical weed control to keep agricultural crops free of unwanted competing plants, thereby securing and / or increasing yields in terms of both quality and quantity. The new combinations significantly exceed the current technical standard with regard to the described properties.

[0136] Synergistic effects are observed when active ingredients (A) and (B) are applied together, but can also frequently occur with staggered application (splitting). It is also possible to apply herbicides (A) and / or (B), or the herbicidal combination (A) and (B), in several applications (sequential application). For example, a post-emergence application can follow one or more pre-emergence applications, or an application can follow an early post-emergence application in mid- or late post-emergence.

[0137] The preferred approach is the simultaneous or near-simultaneous application of the active ingredients of the respective combination, possibly in several doses. However, staggered application of the individual active ingredients of a combination is also possible and can be advantageous in certain cases. Other plant protection products, such as the aforementioned other active ingredients (other herbicides, fungicides, insecticides, acaricides, etc.) and / or various additives, adjuvants, and / or fertilizer applications can also be integrated into the application system. BYC240214- Abroad

[0138] 12

[0139] Depending on the context in which the terms are used, the application of active ingredients in pre-emergence or post-emergence methods refers to the application of the active ingredients before or after the above-ground appearance of the weeds, or to the application of the active ingredients against the weeds before or after the emergence of the crop.

[0140] In formula (I) for compounds of the herbicidal active substances (A) and all subsequent formulas, the following definitions apply:

[0141] The compounds of formula (I) can exist as stereoisomers depending on the type and combination of the substituents. For example, if one or more asymmetrically substituted carbon atoms and / or sulfoxides are present, enantiomers and diastereomers can occur.

[0142] Stereoisomers can be obtained from the mixtures generated during production using conventional separation methods, for example, chromatographic separation techniques. Likewise, stereoisomers can be selectively produced by employing stereoselective reactions using optically active starting materials and / or auxiliary substances.

[0143] The invention also relates to all stereoisomers and their mixtures that are encompassed by formula (I) but are not specifically defined. For the sake of simplicity, however, the following text will always refer to compounds of formula (I), although this includes both the pure compounds and, where applicable, mixtures with varying proportions of isomeric compounds.

[0144] Depending on the type of substituents defined above, the compounds of formula (I) exhibit acidic properties and can form salts, possibly also internal salts or adducts, with inorganic or organic bases or with metal ions. If the compounds of formula (I) bear hydroxy, carboxy, or other acid-inducing groups, these compounds can react with bases to form salts. Suitable bases include, for example, hydroxides, carbonates, and hydrogen carbonates of the alkali and alkaline earth metals, especially those of sodium, potassium, magnesium, and calcium; ammonia; primary, secondary, and tertiary amines with (C1-C4) alkyl groups; mono-, di-, and trialkanolamines of (C1-C4) alkanols; choline and chlorocholine; as well as organic amines such as trialkylamines, morpholine, piperidine, or pyridine.These salts are compounds in which the acidic hydrogen is replaced by a cation suitable for agriculture, for example metal salts, in particular alkali metal salts or alkaline earth metal salts, in particular sodium and potassium salts, or also ammonium salts, salts with organic amines or quaternary ammonium salts, for example with cations of the formula [NRR'R''R''']. + . wherein R to R´´´ each independently comprises an organic residue, in particular alkyl, aryl, BYC240214- Abroad

[0145] 13

[0146] Aralkyl or alkylaryl. Alkylsulfonium and alkylsulfoxonium salts, such as (Ci-C4)-trialkylsulfonium and (Ci-C4)-trialkylsulfoxonium salts, are also possible candidates.

[0147] The compounds of formula (I) can form salts by the addition of a suitable inorganic or organic acid, such as mineral acids like HCl, HBr, H₂SO₄, H₃PO₄, or HNO₃, or organic acids, e.g., carboxylic acids like formic acid, acetic acid, propionic acid, oxalic acid, lactic acid, or salicylic acid, or sulfonic acids like p-toluenesulfonic acid, to a basic group such as amino, alkylamino, dialkylamino, piperidino, morpholino, or pyridino. These salts then contain the conjugate base of the acid as the anion.

[0148] Suitable substituents that exist in deprotonated form, such as sulfonic acids or carboxylic acids, can form internal salts with their own protonatable groups, such as amino groups.

[0149] If a group is substituted multiple times by residues, this means that this group is substituted by one or more identical or different residues of the mentioned residues.

[0150] In all formulas mentioned below, the substituents and symbols, unless otherwise defined, have the same meaning as described under the general formula (I) for herbicides (A). Arrows in a chemical formula indicate the points of attachment to the rest of the molecule.

[0151] The following describes preferred, particularly preferred, and most particularly preferred meanings for each individual substituent of the herbicides (A) according to the general formula (I) as shown above. The remaining substituents of the herbicides (A) according to the general formula (I), which are not mentioned below, have the meanings described above.

[0152] In a first embodiment of the present invention, herbicidal active substances (A) are compounds of formula (I),

[0153]

[0154] wherein

[0155] R 1 stands for hydrogen

[0156] R 2 stands for fluorine, BYC240214- Abroad

[0157] R 3 stands for fluorine,

[0158] R 4 stands for chlorine, bromine, cyano, NO2

[0159] R 5 stands for hydrogen

[0160] R 6 stands for hydrogen, fluorine, chlorine, bromine or cyano,

[0161] R 7 stands for hydrogen

[0162] G stands for methylene or (methyl)methylene,

[0163] X stands for O (oxygen) or S (sulfur),

[0164] Y stands for O (oxygen),

[0165] and

[0166] Q stands for one of the above-mentioned specific groupings Q1 to Q-25.

[0167] In a second embodiment of the present invention, herbicidal active substances (A) are compounds of formula (I),

[0168]

[0169] wherein

[0170] R 1stands for hydrogen

[0171] R 2 stands for fluorine,

[0172] R 3 stands for fluorine, BYC240214- Abroad

[0173] 15

[0174] R 4 stands for chlorine, bromine, cyano

[0175] R 5 stands for hydrogen

[0176] R 6 hydrogen, fluorine stands for,

[0177] R 7 stands for hydrogen

[0178] G stands for methylene

[0179] X stands for O (oxygen),

[0180] Y stands for O (oxygen).

[0181] and

[0182] Q stands for one of the above specifically mentioned groupings Q1, Q2, Q4, Q5, Q6, Q7, Q8, Q9, Q10, Q12, Q13, Q14, Q15, Q16, Q18 or Q19.

[0183] In a third embodiment of the present invention, the herbicidal composition preferably comprises, in addition to at least one component (B) as defined above, a compound [component (A)] of the general formula (I) or its agrochemically compatible salts, wherein

[0184] R 1 stands for hydrogen

[0185] R 2 stands for fluorine,

[0186] R 3 stands for fluorine,

[0187] R 4 stands for chlorine

[0188] R 5 stands for hydrogen

[0189] R 6 stands for hydrogen

[0190] R 7 stands for hydrogen, BYC240214- Abroad

[0191] 16

[0192] G stands for methylene

[0193] X stands for O (oxygen),

[0194] Y stands for O (oxygen).

[0195] and

[0196] Q stands for the group Ql mentioned above.

[0197] This preferred compound (“Al” hereinafter) is listed below by its structural formula and corresponding lUPAC name.

[0198] Compound IUP AC Name Structural Formula No.

[0199] Cyclopropylmethyl-(2- { 2-chloro-4-fluoro-5 - [3 - i YX methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-Al

[0200] dihydropyrimidin-1(2H)-yl]phenoxy}phenoxy)acetate

[0201]

[0202] The compounds of formula (I) are known from the international application with application number PCT / EP2023 / 077211 and can be prepared according to the methods described therein.

[0203] The application rates of the herbicides (A) are in the range of 0.02 to 750 g of active substance per hectare (hereinafter g ai / ha), preferably 0.05 to 400 g ai / ha, and in particular 0.25 to 300 g ai / ha. In the combinations according to the invention, lower application rates of the respective active ingredient are usually required within the aforementioned application rates compared to individual application, preferably 0.02 to 250 g ai / ha, in particular 0.05 to 150 g ai / ha, and most preferably 0.25 to 120 g ai / ha.

[0204] As combination partners (B) [= component (B) or herbicides (B)], all active ingredients (Bl) to (B40) are generally suitable, whereby the herbicidal active ingredients are largely designated by their “common name” (in English spelling) according to the reference body “The Pesticide Manual” 14th Ed., British Crop Protection Council 2006, abbreviated “PM”, or by their chemical name according to the usual nomenclatures (IUP AC or Chemical Abstracts). BYC240214- Abroad

[0205] Within the scope of the present invention, it is possible to combine the individual preferred, particularly preferred, and most preferred embodiments as desired. That is to say, herbicidal compositions comprising (A) one or more compounds of the general formula (I) or their agrochemically compatible salts [component (A)] and (B) one or more herbicides [component (B)] selected from the group of herbicidal active ingredients (Bl) to (40) are included in the present invention, in which any disclosed preferred, particularly preferred, and most preferred embodiments as listed above can be combined with one another.

[0206] Some binary compositions containing (A) one or more herbicidally active compounds (A) of the general formula (I) or their agrochemically compatible salts [herbicides (A)], as well as a herbicide (B), have surprisingly proven to be particularly advantageous.

[0207] The preferred, particularly preferred and most preferred binary systems as further embodiments of the present invention are listed below.

[0208] In a fourth embodiment of the present invention, the composition preferably (A) comprises a compound of the general formula (I) or its agrochemically compatible salts [herbicides (A)]

[0209]

[0210] wherein

[0211] R 1 stands for hydrogen

[0212] R 2 stands for fluorine,

[0213] R 3 stands for fluorine,

[0214] R 4 stands for chlorine, bromine or cyano, BYC240214- Abroad

[0215] R 5 stands for hydrogen

[0216] R 6 hydrogen, fluorine stands for,

[0217] R 7 stands for hydrogen

[0218] G stands for methylene

[0219] X stands for O (oxygen),

[0220] Y stands for O (oxygen),

[0221] Q stands for one of the above-mentioned specific groupings Q1, Q2, Q4, Q5, Q6, Q7, Q8, Q9, Q10, Q12, Q13, Q14, Q15, Q16, Q18 or Q19.

[0222] and

[0223] (B) a herbicide [component (B)] from group (Bl) to (40), means

[0224] In a fifth embodiment of the present invention, the composition preferably (A) contains a compound of the general formula (I) or its agrochemically compatible salts [herbicides (A)]

[0225]

[0226] wherein

[0227] R 1 stands for hydrogen

[0228] R 2 stands for fluorine,

[0229] R 3 stands for fluorine, BYC240214- Abroad

[0230] 19

[0231] R 4 stands for chlorine, bromine or cyano

[0232] R 5 stands for hydrogen

[0233] R 6 hydrogen, fluorine stands for,

[0234] R 7 stands for hydrogen

[0235] G stands for methylene

[0236] X stands for O (oxygen),

[0237] Y stands for O (oxygen),

[0238] and

[0239] Q stands for one of the above-mentioned specific groupings Q1, Q2, Q4, Q5, Q6, Q7, Q8, Q9, Q10, Q12, Q13, Q14, Q15, Q16, Q18 or Q19;

[0240] and

[0241] and

[0242] (B) a herbicide [component (B)] from group (Bl) to (40), means

[0243] Particularly preferred compositions within the meaning of the present invention are the compositions listed in Table 2.1 below:

[0244] Table 2.1: Particularly preferred binary compositions containing (Al)

[0245] Binary

[0246] Verbindung (A) Verbindung (B) Zusammensetzung

[0247] Zl-1 Al Bl

[0248] Zl-2 Al B2

[0249] Zl-3 Al B3

[0250] Zl-4 Al B4

[0251]

[0252] BYC240214- Ausland

[0253] 20

[0254] Binary

[0255] Verbindung (A) Verbindung (B) Zusammensetzung

[0256] Zl-5 To B5 Zl-6 To B6 Zl-7 To B7 Zl-8 To B8 Zl-9 To B9 Zl-10 To BIO Zl-11 To Bll Zl-12 To B12 To B12 To B13 To B14 To B14 To B11 To B17 To B17 To B16 To B16 Zl-19 To B19 ZI -20 To B20 Zl-21 To B21 ZI -22 To B22 ZI -23 To B23 ZI -24 To B24 ZI -25 To B25 ZI -26 To B26 ZI -27 To B29 To Zl-28 To B3 Zl-31 To B31 Zl-32 To B32 Zl-33 To B33 Zl-34 To B34 Zl-35 To B35 Zl-36 To B36 Zl-37 To B37

[0257]

[0258] BYC240214- Ausland

[0259] 21

[0260] Binary

[0261] Compound (A) Compound (B) Composition

[0262] Z1-38 Al B38

[0263] Z1-39 Al B39

[0264] Z1-40 Al B40

[0265]

[0266] Particularly preferred are the combinations Z1-1, Z1-2, Z1-3, Z1-5, Z1-6, Z1-7, Z1-8, Z1-9, Z1-10, Z1-11, Z1-13, Z1-15, Z1-16, Z1-17, Z1-22, Z1-23, Z1-24, Z1-25, Z1-26, Z1-27, Z1-28, Z1-29, Z1-30, Z1-31, Z1-33, Z1-34, Z1-36, Z1-37, Z-38, Z-39 and Z-40.

[0267] In another embodiment, the following combinations are particularly preferred:

[0268] Z1-1, Z1-2, Z1-6, Z1-8; Z1-22, Z1-31 and Z1-38.

[0269] Furthermore, the combinations according to the invention can be used together with other active ingredients such as the aforementioned active ingredients (herbicides, fungicides, insecticides, acaricides, etc.) and / or plant growth regulators or auxiliary substances from the group of additives commonly used in plant protection, such as adjuvants and formulation aids. The combination of plant protection active ingredients, which contains active ingredients (A) and (B) and optionally other active ingredients, is referred to hereinafter as a "herbicide combination". Their application forms, such as formulations or tank mixes, constitute herbicidal products (compositions).

[0270] The invention therefore also relates to herbicidal agents which contain the active ingredient combinations according to the invention with additives commonly used in plant protection, such as adjuvants and formulation aids, and optionally further plant protection active ingredients.

[0271] The invention also relates to the use of the or the application method using the active ingredient combinations according to the invention as herbicides and plant growth regulators, preferably as herbicides and plant growth regulators with a synergistically effective content of the respective active ingredient combination.

[0272] The application rates of the herbicides (B) are known in principle and are generally in the range of 0.01 to 500 g ai / ha, preferably in the range of 0.1 to 500 g ai / ha, particularly in the range of 0.1 to 250 g ai / ha, and most preferably in the range of 0.2 to 200 g ai / ha. BYC240214- Abroad

[0273] 22

[0274] In the mixtures according to the invention, lower application quantities of the respective active ingredient are generally required compared to single application, within the scope of the application quantities mentioned.

[0275] The ratios (A):(B) based on weight are generally in the range of 1:100000 to 3000:1, preferably in the range of 1500:1 to 1:4200, in particular 600:1 to 1:400, depending on the effective application quantities.

[0276] The herbicidal compositions according to the invention can also be combined with other herbicides and plant growth regulators (= active ingredients (C*)) to, for example, expand the spectrum of activity. For example, known active ingredients based on the inhibition of, for example, acetolactate synthase, acetyl-CoA carboxylase, cellulose synthase, enolpyruvylshikimate-3-phosphate synthase, glutamine synthetase, p-hydroxyphenylpyruvate dioxygenase, phytoendesaturase, photosystem I, photosystem II, and protoporphyrinogen oxidase, such as those described in Weed Research 26 (1986) 441-445 or "The Pesticide Manual", 14th edition, The British Crop Protection Council and the Royal Soc. of Chemistry, 2006, can be used as combination partners for the compounds according to the invention in mixture formulations or in tank mixes. corresponding "e-Pesticide Manual Version 4 (2006)" and the literature cited therein are known.Further trade names and "common names" are listed in the "Compendium of Pesticide Common Names" (available online at http: / / www.alanwood.net / pesticides).

[0277] Examples of known herbicides that can be combined with the compounds according to the invention include the following active ingredients (Note: The compounds are designated either by their International Organization for Standardization (ISO) common name or by their chemical name, possibly together with a standard code number) and always encompass all application forms such as acids, salts, esters, and isomers like stereoisomers and optical isomers. One, and in some cases several, application forms are mentioned:

[0278] acifluorfen, allidochlor, amidochlor, 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methylphenyl)-5-fluoropyridine-2-carboxylic acid, ammoniumsulfamate, benfuresate, bensulide, bipyrazone, bromobutide, busoxinone, butenachlor, butylate, cambendichlor, chlorfenac, chlrofenac-ammonium, chlorfenac-sodium, chlorfenprop, chlrofenprop-methyl, chlorflurenol, chlorflurenol-methyl, chlorophthalim, clacyfos, cumyluron, cyanamide, cycloate, cyprazine, dalapon, dalapon-calcium, dalapon-magnesium, dalapon-sodium, dazomet, dazomet-sodium, n-decanol, detosyl-pyrazolate (DTP), 2-(2,4-dichlorobenzyl)-4,4-dimethyl-l,2-oxazolidin-3-one, 2-(2,5-dichlorobenzyl)-4,4-dimethyl-l,2-oxazolidin-3-one, dichlorprop, dichlorprop-butotyl, dichlroprop-dimethylammonium, dichhlorprop-etexyl, dichlorprop-ethylammonium, dichlorprop-isoctyl, dichlorprop-methyl, dichlorprop-postassium, dichlorprop-sodium, dichlorprop-P, dichlorprop-P-dimethylammonium, dichlorprop-P-etexyl, dichlorprop-P-potassium, dichlorprop-sodium, difenzoquat,difenzoquat-methylsulfate, dimepiperate, BYC240214- Abroad,

[0279] 23

[0280] dimesulfazet, dimetrasulfuron, dinoterb, dinoterb-acetate, diphenamid, DNOC, DNOC-ammonium, DNOC-potassium, DNOC-sodium, endothal, endothal-diammonium, endothal-dipotassium, endothal-disodium, Epyrifenacil, EPTC, ethiozin, etobenzanid, F-5231, i.e. N-[2-Chlor-4-fluor-5-[4-(3-fluorpropyl)-4,5-dihydro-5-oxo-lH-tetrazol-l-yl]-phenyl]-ethansulfonamid, F-7967, i.e. 3-[7-Chlor-5-fluor-2-(trifluormethyl)- 1 H-benzimidazol-4-yl] - 1 -methyl-6-(trifluormethyl)pyrimidin-2,4( 1 H,3H)-dion, fenoxasulfone, fenpyrazone, fluchloralin, flurenol, flurenol-butyl, -dimethylammonium und -methyl, flupropanate, flupropanate-sdium, fosamine, fosamine-ammonium, H-9201, i.e. O-(2,4-Dimethyl-6-nitrophenyl)-O-ethyl-isopropylphosphoramidothioat, halosulfuron, HW-02, i.e. 1-(Dimethoxyphosphoryl)-ethyl-(2,4-dichlorphenoxy)acetat, karbutilate, KUH-043, i.e. 3-({ [5-(Difluormethyl)-l-methyl-3-(trifluormethyl)-lH-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-l,2-oxazol, ketospiradox, ketospiradox-potassium,mefluidide, mefluidide-diolamine, mefluidide -potassium, methabenzthiazuron, metam, methiopyrsulfuron, methiozolin, methyl isothiocyanate, molinate, monosulfuron, monosulfuron-methyl, MT-5950, i.e. N-[3-chlor-4-(l-methylethyl)-phenyl]-2-methylpentanamid, NGGC-011, napropamide, NC-310, i.e. 4-(2,4-Dichlorbenzoyl)-l-methyl-5-benzyloxypyrazol, orbencarb, pebulate, pentachlorphenol, petroleum oils, primisulfuron, prodiamine, pyribambenz, pyribambenz-isopropyl, pyribambenz -propyl, pyributicarb, quinoclamine, SL-261, SYP-249, i.e. l-Ethoxy-3-methyl-l-oxobut-3-en-2-yl-5-[2-chlor-4-(trifluormethyl)phenoxy]-2-nitrobenzoat, SYP-300, i.e. l-[7-Fluor-3-oxo-4-(prop-2-in-l-yl)-3,4-dihydro-2H- 1,4-benzoxazin-6-yl] -3-propyl-2-thioxoimidazolidin-4,5-dion, TCA (Trifluoressigsäure), TCA-ammonium, TCA-calcium, TCA-ethdyl, TCA-magnesium, TCA-sodium, terbucarb, thiobencarb, tolpyralate, urea sulfate, vernolate, XDE-848, ZJ-0862, i.e. 3,4-Dichlor-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}anilin,3-(2-chloro-4-fluoro-5-(3-methyl-2,6-dioxo-4-trifluoromethyl-3,6-dihydropyrimidin-1 (2H)-yl)phenyl)-5-methyl-4,5-dihydroisoxazole-5-carboxylic acid ethyl ester, 3-chloro-2-[3-(difluoromethyl)isoxazolyl-5-yl]phenyl-5-chloropyrimidin-2-yl ether, 2-(3,4-dimethoxyphenyl)-4-[(2-hydroxy-6-oxocyclohex-l -en-1 -yl)carbonyl]-6-methylpyridazin-3(2H)-one, 2-( { 2-[(2-methoxyethoxy)methyl]-6-methylpyridin-3-yl} carbonyl)cyclohexane- 1,3-dione, (5-hydroxy- 1 -methyl- 1 H-pyrazol-4-yl)(3,3,4-trimethyl- 1, 1 -dioxido-2,3-dihydro- 1 -benzothiophen-5-yl)methanone, 1 -methyl-4- [(3,3,4-trimethyl- 1, 1 -dioxido-2, 3 -dihydro- 1 -benzothiophen-5 -yl)carbonyl] - 1 H-pyr azol-5 -yl propane- 1 -sulfonate, 1 - { 2-chloro-3-[(3-cyclopropyl-5-hydroxy- 1 -methyl- lH-pyrazol-4-yl)carbonyl] -6-(trifluoromethyl)phenyl} piperidin-2-one, 4- { 2-chloro-3 -[(3,5 -dimethyl- 1 H-pyr azol- 1 -yl)methyl] -4-(methylsulfonyl)benzoyl} - 1 -methyl- 1 H-pyr azol-5 -yl 1,3-dimethyl- lH-pyrazole-4-carboxylate; cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylate, prop-2-yn-l-yl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylate, benzyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylate, ethyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-l-isobutyryl-lH-indol-6-yl)pyridine-2-carboxylate, methyl 6-(l-acetyl-7-fluoro-lH-indol-6-yl)-4-amino-3-chloro-5- BYC240214- Ausland,

[0281] 24

[0282] fluoropyridine-2-carboxylate, methyl 4-amino-3-chloro-5-fluoro-6-[7-fluoro-l-(methoxyacetyl)-lH-indol-6-yl]pyridine-2-carboxylate, potassium 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylates, butyl 4-amino-3-chloro-5-fluoro-6-(7-fluoro-lH-indol-6-yl)pyridine-2-carboxylates, 4-hydroxy-l-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 3-(5-tert-butyl-1,2-oxazol-3-yl)-4-hydroxy-1 -methylimidazolidin-2-one

[0283] If the respective name (common name) includes several forms of the active ingredient, the commercially available form is preferably defined by the name.

[0284] Each of the aforementioned additional active ingredients (= active ingredients (C*), (Cl*), (C2*) etc.) can then preferably be combined with one of the two combinations according to the present invention, according to the scheme (A)+(B)+(C*) or also according to the scheme (A)+(B)+(C1*)+(C2*) etc.

[0285] The quantities specified are application rates (g ai / ha = grams of active substance per hectare) and thus also define the quantity ratios in a co-formulation, a pre-mix, a tank mix or a sequential application of the combined active ingredients.

[0286] These combinations can be applied in both pre-emergence and post-emergence applications. This applies to both pre- and post-emergence control of the weeds and to the selective control of weeds before or after the emergence of the crop. Mixed approaches are also possible, for example, controlling weeds in their pre- or post-emergence stage when treating crops after emergence.

[0287] Of particular interest is the selective control of weeds in crops of useful and ornamental plants. Although herbicides (A) and (B) already exhibit very good to sufficient selectivity in many crops, phytotoxicity can, in principle, occur in some crops, and especially in the case of mixtures with other, less selective herbicides. In this respect, combinations of herbicides (A) and (B) containing the herbicidal active ingredients combined according to the invention and one or more safeners are of particular interest. The safeners, which are used in an antidotally effective concentration, reduce the phytotoxic side effects of the herbicides / pesticides used, e.g., in economically important crops such as cereals (wheat, barley, rye, maize, rice, millet), sugar beet, sugar cane, rapeseed, cotton, and soybeans, preferably cereals. BYC240214- Abroad

[0288] 25

[0289] The following safeners, for example, are suitable as combination partners for the herbicide combinations according to the invention:

[0290] Sl) Compounds from the group of heterocyclic carboxylic acid derivatives:

[0291] Sl a ) Compounds of the dichlorophenylpyrazolin-3-carboxylic acid type (Sl a ), preferably compounds such as

[0292] l-(2,4-Dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3-carboxylic acid,

[0293] 1-(2,4-Dichlorophenyl)-5-(ethoxycarbonyl)-5-methyl-2-pyrazolin-3-carboxylic acid ethyl ester (S 1 - 1) ("Mefenpyr-diethyl"), and related compounds as described in WO-A-91 / 07874;

[0294] Sl b ) Derivatives of dichlorophenylpyrazole carboxylic acid (Sl b ), preferably compounds such as

[0295] l-(2,4-Dichlorophenyl)-5-methylpyrazole-3-carboxylic acid ethyl ester (Sl-2),

[0296] l-(2,4-Dichlorophenyl)-5-isopropylpyrazole-3-carboxylic acid ethyl ester (Sl-3),

[0297] 1-(2,4-Dichlorophenyl)-5-(1,1-dimethylethyl)pyrazole-3-carboxylic acid ethyl ester (S1-4) and related compounds as described in EP-A-333131 and EP-A-269806;

[0298] Sl c ) Derivatives of 1,5-diphenylpyrazole-3-carboxylic acid (Sl c ), preferably compounds such as

[0299] 1 -(2,4-Dichlorophenyl)-5-phenylpyrazole-3-carboxylic acid ethyl ester (S 1 -5),

[0300] l-(2-chlorophenyl)-5-phenylpyrazole-3-carboxylic acid methyl ester (Sl-6) and related compounds as described, for example, in EP-A-268554;

[0301] Sl d ) Compounds of the triazole carboxylic acid type (Sl d), preferably compounds such as fenchlorazole(-ethyl ester), i.e. l-(2,4-dichlorophenyl)-5-trichloromethyl-(lH)-l,2,4-triazol-3-carboxylic acid ethyl ester (Sl-7), and related compounds as described in EP-A-174562 and EP-A-346620;

[0302] Sl e ) Compounds of the type of 5-benzyl or 5-phenyl-2-isoxazoline-3-carboxylic acid, or of 5,5-diphenyl-2-isoxazoline-3-carboxylic acid (Sl e ), preferably compounds such as

[0303] 5-(2,4-Dichlorobenzyl)-2-isoxazoline-3-carboxylic acid ethyl ester (S 1-8) or

[0304] 5-Phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (Sl-9) and related compounds as described in WO-A-91 / 08202, or 5,5-Diphenyl-2-isoxazoline-carboxylic acid (Sl-10) or 5,5-Diphenyl-2-isoxazoline-3-carboxylic acid ethyl ester (Sl-11) ("Isoxadifen-ethyl")

[0305] or -n-propyl ester (Sl-12) or 5-(4-Fluorophenyl)-5-phenyl-2-isoxazoline-3-carboxylic acid ethyl ester (Sl-13), as described in patent application WO-A-95 / 07897.

[0306] Sl f ) Compounds of the triazolyloxyacetic acid type (Sl f ), preferably compounds such as methyl-{[1,5-bis(4-chloro-2-fluorophenyl)-1H-1,2,4-triazol-3-yl]oxy}acetate (Sl-14) or {[1,5- BYC240214- Abroad

[0307] 26

[0308] Bis(4-chloro-2-fluorophenyl)-lH-l,2,4-triazol-3-yl]oxy}-acetic acid (S 1-15) or methyl-{[5-(4-chloro-2-fluorophenyl)- 1 -(2,4-difluorophenyl)- 1H- 1,2,4-triazol-3-yl]oxy} acetate (S 1 - 16) or { [5-(4-chloro-2-fluorophenyl)- 1 -(2,4-difluorophenyl)- 1 H- 1,2,4-triazol-3-yl]oxy} -acetic acid (S 1 - 17) or methyl-{[l-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-lH-l,2,4-triazol-3-yl]oxy}acetate (Sl-18) or {[l-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-lH-l,2,4- triazol-3-yl]oxy}}-acetic acid (S 1 - 19), as described in patent application WO2021105101.

[0309] 52) Compounds from the group of 8-quinoline oxide derivatives (S2):

[0310] S2 a ) Compounds of the type of 8-quinoline oxyacetic acid (S2 a ), preferably

[0311] (5-Chloro-8-quinolinoxy)acetic acid (l-methylhexyl) ester ("Cloquintocet-mexyl") (S2-1), (5-chloro-8-quinolinoxy)acetic acid (l,3-dimethyl-but-l-yl) ester (S2-2),

[0312] (5-Chloro-8-quinolinoxy)acetic acid 4-allyl-oxy-butyl ester (S2-3),

[0313] (5-Chloro-8-quinolinoxy)acetic acid-l-allyloxy-prop-2-yl ester (S2-4),

[0314] (5-Chloro-8-quinolinoxy)acetate ethyl ester (S2-5),

[0315] (5-Chloro-8-quinolinoxy)methyl acetate (S2-6),

[0316] (5-Chloro-8-quinolinoxy)acetic acid allyl ester (S2-7),

[0317] (5-Chloro-8-quinolinoxy)acetic acid 2-(2-propylidene-iminoxy)-l-ethyl ester (S2-8),

[0318] (5-Chloro-8-quinolineoxy)acetic acid 2-oxo-prop-l-yl ester (S2-9) and related compounds as described in EP-A-86750, EP-A-94349 and EP-A-191736 or EP-A-0492366, as well as (5-chloro-8-quinolineoxy)acetic acid (S2-10), its hydrates and salts, for example its lithium, sodium, potassium, calcium, magnesium, aluminum, iron, ammonium, quaternary ammonium, sulfonium, or phosphonium salts as described in WO-A-2002 / 34048;

[0319] S2 b ) Compounds of the type of (5-chloro-8-quinoline oxy)malonic acid (S2 b ), preferably compounds such as (5-chloro-8-quinoline oxy)malonic acid diethyl ester,

[0320] (5-Chloro-8-quinoline oxy)malonic acid diallyl esters,

[0321] (5-Chloro-8-quinoline oxy)malonic acid methyl ethyl ester and related compounds as described in EP-A-0582 198.

[0322] 53) Active ingredients of the dichloracetamide (S3) type, which are frequently used as pre-emergence safeners (soil-active safeners), such as:

[0323] "Dichlormid" (N,N-diallyl-2,2-dichloroacetamide) (S3-1),

[0324] "R-29148" (3-dichloroacetyl-2,2,5-trimethyl-1,3-oxazolidine) from Stauffer (S3-2), "R-28725" (3-dichloroacetyl-2, 2, -dimethyl-1,3-oxazolidine) from Stauffer (S3-3), "Benoxacor" (4-Dichloroacetyl-3,4-dihydro-3-methyl-2H-l,4-benzoxazine) (S3-4), BYC240214- Foreign

[0325] 27

[0326] "PPG-1292" (N-allyl-N-[(l,3-dioxolan-2-yl)-methyl]-dichloroacetamide) from PPG Industries (S3-5),

[0327] "DKA-24" (N-allyl-N-[(allylaminocarbonyl)methyl]-dichloroacetamide) from Sagro-Chem (S3-6),

[0328] "AD-67" or "MON 4660" (3-Dichloroacetyl-l-oxa-3-aza-spiro[4,5]decane) from Nitrokemia or Monsanto (S3-7),

[0329] "TI-35" (1-dichloroacetyl-azepane) from TRI-Chemical RT (S3-8),

[0330] "Diclonon" (Dicyclonon) or "BAS145138" or "LAB145138" (S3-9)

[0331] ((RS)-l-Dichloroacetyl-3,3,8a-trimethylperhydropyrrolo[l,2-a]pyrimidin-6-one) of BASF, "Furilazol" or "MON 13900" ((RS)-3-Dichloroacetyl-5-(2-furyl)-2,2-dimethyloxazolidine) (S3-10), and its (R)-isomer (S3-11).

[0332] S4) Compounds from the class of acylsulfonamides (S4):

[0333] S4 a ) N-acylsulfonamides of the formula (S4 a) and their salts as described in WO-A-97 / 45016,

[0334] O, - k OO! \ / p 2>

[0335]

[0336] H AH - OH X '

[0337] wherein

[0338] RA 1 (Ci-C6)Alkyl, (C3-C6) Cycloalkyl, wherein the last two substituents are substituted by VA substituents from the group halogen, (C1-C4) alkoxy, (Ci-C6) haloalkoxy and (Ci-C4) alkylthio and in the case of cyclic substituents also by (Ci-C4) alkyl and (Ci-C4) haloalkyl;

[0339] RA 2 Halogen, (C1-C4)alkyl, (C1-C4)alkoxy, CF3;

[0340] mA 1 or 2;

[0341] VA means 0, 1, 2 or 3;

[0342] S4 b ) Compounds of the type of 4-(benzoylsulfamoyl)benzamides of formula (S4 b ) and their salts, as described in WO-A-99 / 16744, BYC240214- Abroad

[0343] 28

[0344] (S4b )

[0345]

[0346] wherein

[0347] RB 1 , RB 2 independently hydrogen, (Ci-Ce)alkyl, (C3-Ce)cycloalkyl, (C3-Ce)alkenyl, (C3-Ce)alkynyl,

[0348] RB 3 Halogen, (C1-C4)alkyl, (Ci-C4)haloalkyl or (C1-C4)alkoxy and

[0349] ms 1 or 2 mean,

[0350] e.g. such as those in which

[0351] RB 1 = Cyclopropyl, RB 2 = Hydrogen and (RB 3 ) = 2-OMe ("Cyprosulfamide", S4-1),

[0352] RB 1 = Cyclopropyl, RB 2 = Hydrogen and (RB 3 ) = 5-Cl-2-OMe is (S4-2),

[0353] RB 1 = Ethyl, R B 2 = Hydrogen and (RB 3 ) = 2-OMe is (S4-3),

[0354] RB 1 = Isopropyl, RB 2 = Hydrogen and (RB 3 ) = 5-Cl-2-OMe is (S4-4) and

[0355] RB 1 = Isopropyl, RB 2 = Hydrogen and (RB 3 ) = 2-OMe is (S4-5);

[0356] S4 C ) Compounds from the class of benzoylsulfamoylphenylureas of the formula (S4 C ), as described in EP-A-365484,

[0357] (S4 C )

[0358]

[0359] wherein

[0360] RC 1 , RC 2 independently of each other hydrogen, (Ci-Cs)alkyl, (C3-Cs)cycloalkyl, (C3-Ce)alkenyl, (C3-Ce)alkynyl,

[0361] RC 3 Halogen, (C1-C4)alkyl, (C1-C4)alkoxy, CF3 and

[0362] Me 1 or 2 means; BYC240214- Abroad

[0363] 29

[0364] for example

[0365] l-[4-(N-2-methoxybenzoylsulfamoyl)phenyl]-3-methylurea,

[0366] 1 - [4-(N -2-Methoxybenzoylsulfamoyl)phenyl] -3, 3 -dimethylurea,

[0367] l-[4-(N-4,5-dimethylbenzoylsulfamoyl)phenyl]-3-methylurea;

[0368] S4 d ) Compounds of the type of N-phenylsulfonyl terephthalamides of formula (S4 d ) and their salts, which are known, for example, from CN 101838227,

[0369] (S4 d )

[0370]

[0371] wherein

[0372] RD 4 Halogen, (Ci-C4)alkyl, (Ci-C4)alkoxy, CF 3;

[0373] mo 1 or 2;

[0374] RD 5 hydrogen, (Ci-C6)alkyl, (C3-C6)cycloalkyl, (C2-C6)alkenyl, (C2-C6)alkynyl, (C5-Ce)cycloalkenyl.

[0375] 55) Active substances from the class of hydroxyaromatics and aromatic-aliphatic carboxylic acid derivatives (S5), e.g.

[0376] 3,4,5-Ethyl triacetoxybenzoate, 3,5-Dimethoxy-4-hydroxybenzoic acid, 3,5-Dihydroxybenzoic acid, 4-Hydroxysalicylic acid, 4-Fluorosalicyclic acid, 2-Hydroxycinnamic acid, 2,4-Dichlorocinnamic acid, as described in WO-A-2004 / 084631, WO-A-2005 / 015994, WO-A-2005 / 016001.

[0377] 56) Active substances from the class of 1,2-dihydroquinoxalin-2-one (S6), e.g.

[0378] 1-Methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one, 1-Methyl-3-(2-thienyl)-1,2-dihydroquinoxalin-2-thione, 1-(2-Aminoethyl)-3-(2-thienyl)-1,2-dihydroquinoxalin-2-one hydrochloride, l-(2-Methylsulfonylaminoethyl)-3-(2-thienyl)-l,2-dihydroquinoxalin-2-one, as described in WO-A-2005 / 112630.

[0379] 57) Compounds from the class of diphenylmethoxyacetic acid derivatives (S7), e.g.

[0380] Diphenyl methoxyacetic acid methyl ester (CAS Reg. No. 41858-19-9) (S7-1), diphenyl methoxyacetic acid ethyl ester or diphenyl methoxyacetic acid as described in WO-A-98 / 38856. BYC240214- Abroad

[0381] S8) Compounds of formula (S8) as described in WO-A-98 / 27049,

[0382] 3

[0383] D

[0384] (S8)

[0385] (MnD

[0386]

[0387] where the symbols and indices have the following meanings:

[0388] RD 1 is halogen, (Ci-C4)alkyl, (Ci-C4)haloalkyl, (C1-C4)alkoxy, (Ci-C4)haloalkoxy,

[0389] RD 2 is hydrogen or (Ci-C4)alkyl,

[0390] RD 3is hydrogen, (Ci-Cs)alkyl, (C2-C4)alkenyl, (C2-C4)alkynyl, or aryl, wherein each of the aforementioned C-containing residues is unsubstituted or substituted by one or more, preferably up to three, identical or different residues from the group consisting of halogen and alkoxy; or their salts,

[0391] "no" is an integer from 0 to 2.

[0392] S9) Active substances from the class of 3-(5-tetrazolylcarbonyl)-2-quinolones (S9), e.g.

[0393] l,2-Dihydro-4-hydroxy-l-ethyl-3-(5-tetrazolylcarbonyl)-2-quinolone (CAS Reg. No.: 219479-18-2), l,2-Dihydro-4-hydroxy-l-methyl-3-(5-tetrazolyl-carbonyl)-2-quinolone (CAS Reg. No.

[0394] 95855-00-8), as described in WO-A- 1999 / 000020.

[0395] S10) Connections of the formulas (S10 a ) or (S10 b ),

[0396] as described in WO-A-2007 / 023719 and WO-A-2007 / 023764,

[0397]

[0398] (S10 b )

[0399] wherein

[0400] RE 1 Halogen, (C1-C4)alkyl, methoxy, nitro, cyano, CF3, OCF3

[0401] Y E , Z E independently of each other O or S, BYC240214- Abroad

[0402] 31

[0403] DE an integer from 0 to 4,

[0404] RE 2 (C1-C 16 ) alkyl, (C2-C6)alkenyl, (C3-C6)cycloalkyl, aryl; benzyl, halobenzyl,

[0405] RE 3 hydrogen or (C1-C6)alkyl.

[0406] 511) Active substances of the oxyimino compound (sil) type, known as seed dressings, such as:

[0407] "Oxabetrinil" ((Z)-1,3-Dioxolan-2-ylmethoxyimino(phenyl)acetonitrile) (Sll-1), known as a seed dressing safener for millet against damage from metolachlor,

[0408] "Fluxofenim" (l-(4-chlorophenyl)-2,2,2-trifluoro-l-ethanone-O-(l,3-dioxolan-2-ylmethyl)-oxime) (Sll-2), known as a seed dressing safener for millet against damage from metolachlor, and

[0409] "Cyometrinil" or "CGA-43089" ((Z)-Cyanomethoxyimino(phenyl)acetonitrile) (Sll-3), which is known as a seed dressing safener for millet against damage from metolachlor.

[0410] 512) Active substances from the class of isothiochromanones (S12), such as methyl-[(3-oxo-1H-2-benzothiopyran-4(3H)-ylidene)methoxy]acetate (CAS Reg. No. 205121-04-6) (S12-1) and related compounds from WO-A-1998 / 13361.

[0411] 513) One or more compounds from group (S13):

[0412] "Naphthalic anhydride" (1,8-Naphthalenedicarboxylic anhydride) (S13-1), known as a seed treatment safener for maize against damage from thiocarbama herbicides,

[0413] "Fenclorim" (4,6-Dichloro-2-phenylpyrimidine) (S13-2), known as a safener for pretilachlor in seeded rice,

[0414] "Flurazole" (benzyl-2-chloro-4-trifluoromethyl-1,3-thiazol-5-carboxylate) (S13-3), known as a seed dressing safener for millet against damage from alachlor and metolachlor,

[0415] "CL 304415" (CAS Reg. No. 31541-57-8)

[0416] (4-Carboxy-3,4-dihydro-2H-l-benzopyran-4-acetic acid) (S13-4) of the company American Cyanamid, which is known as a safener for corn against damage from imidazolinones,

[0417] "MG 191" (CAS Reg. No. 96420-72-3) (2-Dichloromethyl-2-methyl-1,3-dioxolane) (S13-5) of the company Nitrokemia, which is known as a safener for maize,

[0418] "MG 838" (CAS Reg. No. 133993-74-5)

[0419] (2-propenyl l-oxa-4-azaspiro[4.5]decane-4-carbodithioate) (S13-6) from Nitrokemia BYC240214- Ausland

[0420] 32

[0421] "Disulfoton" (O,O-Diethyl S-2-ethylthioethyl phosphorus dithioate) (S13-7),

[0422] "Dietholates" (O,O-diethyl-O-phenylphosphorothioate) (S13-8),

[0423] "Mephenate" (4-chlorophenyl methyl carbamate) (S13-9).

[0424] S14) Active substances which, in addition to a herbicidal effect against weeds, also have a safener effect on cultivated plants such as rice, e.g.

[0425] "Dimepiperate" or "MY-93" (S-1-Methyl-1-phenylethyl-piperidine-1-carbothioate), which is known as a safener for rice against damage from the herbicide Molinate,

[0426] "Daimuron" or "SK 23" (l-(l-Methyl-l-phenylethyl)-3-p-tolyl-urea), which is known as a safener for rice against damage caused by the herbicide imazosulfuron,

[0427] "Cumyluron" = "JC-940" (3-(2-chlorophenylmethyl)-l-(l-methyl-l-phenyl-ethyl)urea, see JP-A-60087254), which is known as a safener for rice against damage from some herbicides,

[0428] "Methoxyphenone" or "NK 049" (3,3'-Dimethyl-4-methoxy-benzophenone), which is known as a safener for rice against damage from some herbicides,

[0429] "CSB" (l-Bromo-4-(chloromethylsulfonyl)benzene) from Kumiai, (CAS Reg. No. 54091-06-4), which is known as a safener against damage caused by some herbicides in rice.

[0430] S15) Compounds of formula (S15) or their tautomers,

[0431] (S15)

[0432]

[0433] as described in WO-A-2008 / 131861 and WO-A-2008 / 131860,

[0434] wherein

[0435] RH 1 means a (C1-C6)haloalkyl group and

[0436] RH 2 Hydrogen or halogen means and BYC240214- Abroad

[0437] 33

[0438] RH 3 , RH 4 independently of each other hydrogen, (C1-C 16 )Alkyl, (C2-C 16 )Alkenyl or

[0439] (C2-C 16)Alkynyl,

[0440] wherein each of the last 3 residues is unsubstituted or substituted by one or more residues from the group consisting of halogen, hydroxy, cyano, (C1-C4) alkoxy, (C1-C4)haloalkoxy, (C1-C4)alkylthio, (C1-C4)alkylamino, di[(C1-C4)alkyl]amino, [(C1-C4)alkoxy]carbonyl, [(C1-C4)haloalkoxy]carbonyl, (C3-C6)cycloalkyl, which is unsubstituted or substituted, phenyl, which is unsubstituted or substituted, and heterocyclyl, which is unsubstituted or substituted.

[0441] or (C3-C6)cycloalkyl, (C4-C6)cycloalkenyl, (C3-C6)cycloalkyl condensed on one side of the ring with a 4- to 6-membered saturated or unsaturated carbocyclic ring, or (C4-C6)cycloalkenyl condensed on one side of the ring with a 4- to 6-membered saturated or unsaturated carbocyclic ring,

[0442] wherein each of the latter 4 residues is unsubstituted or replaced by one or more residues from the group halogen, hydroxy, cyano, (C1-C4)alkyl, (C1-C4)haloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C1-C4)alkylthio, (C1-C4)alkylamino, di[(C1-C4)alkyl]amino, [(C1-C4)alkoxy]carbonyl, [(C1-C4)haloalkoxy]carbonyl,

[0443] (C3-C6)Cycloalkyl, unsubstituted or substituted, phenyl, unsubstituted or substituted, and heterocyclyl, unsubstituted or substituted,

[0444] means or

[0445] RH 3 (C1-C4)alkoxy, (C2-C4)alkenyloxy, (C2-C6)alkynyloxy or (C2-C4)haloalkoxy means and

[0446] RH 4 hydrogen or (C1-C4) alkyl means or

[0447] RH 3 and RH 4together with the directly bonded N atom, a four- to eight-membered heterocyclic ring, which in addition to the N atom may also contain further heteroring atoms, preferably up to two further heteroring atoms from the group N, O and S, and which is unsubstituted or substituted by one or more residues from the group halogen, cyano, nitro, (C1-C4)alkyl, (C1-C4)haloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy and (C1-C4)alkylthio.

[0448] S16) Active substances primarily used as herbicides, but which also have a safener effect on crops, e.g. BYC240214- Abroad

[0449] 34

[0450] (2,4-Dichlorophenoxy)acetic acid (2,4-D),

[0451] (4-Chlorphenoxy)acetic acid

[0452] (R, S)-2-(4-chloro-o-tolyloxy)propionic acid (mecoprop),

[0453] 4-(2,4-Dichlorophenoxy)butyric acid (2,4-DB),

[0454] (4-Chloro-o-tolyloxy)acetic acid (MCPA),

[0455] 4-(4-chloro-o-tolyloxy)butyric acid,

[0456] 4-(4-Chlorphenoxy)butyric acid,

[0457] 3,6-dichloro-2-methoxybenzoic acid (dicamba),

[0458] l-(Ethoxycarbonyl)ethyl 3,6-dichloro-2-methoxybenzoate (lactidichloro-ethyl).

[0459] Preferred safeners in combination with the herbicide combinations according to the invention are:

[0460] Cloquintocet-mexyl, cyprosulfamide, fenchlorazole ethyl ester, isoxadifen-ethyl, mefenpyr-diethyl, fenclorim, cumyluron, S4-1 and S4-5, and particularly preferred safeners are: cloquintocet-mexyl, cyprosulfamide, isoxadifen-ethyl and mefenpyr-diethyl.

[0461] The herbicide combinations according to the invention may contain further components, e.g.

[0462] Plant growth regulators or other active substances against harmful organisms such as harmful plants, plant-damaging animals or plant-damaging fungi, in particular active substances from the group of herbicides, fungicides, insecticides, acaricides, nematicides, miticides and related substances.

[0463] Examples of plant growth regulators as possible mixing partners are:

[0464] Acibenzolar, acibenzolar-S-methyl, 5-Aminolävulinsäure, ancymidol, 6-benzylaminopurine, Brassinolid, Catechin, chlormequat chloride, cloprop, cyclanilide, 3-(Cycloprop-l-enyl)propionsäure, daminozide, dazomet, n-decanol, dikegulac, dikegulac-sodium, endothal, endothal-dipotassium, -disodium, und mono(N, N-dimethylalkylammonium), ethephon, flumetralin, flurenol, flurenol-butyl, flurprimidol, forchlorfenuron, gibberellic acid, inabenfide, indol-3-acetic acid (IAA), 4-indol-3-ylbutyric acid, isoprothiolane, probenazole, Jasmonsäure, Jasmonsäuremethylester, maleic hydrazide, mepiquat chloride, 1 -methylcyclopropene, 2-(l-naphthyl)acetamide, 1 -naphthylacetic acid, 2-naphthyloxyacetic acid, nitrophenolate-mixture, 4-Oxo-4[(2-phenylethyl)amino]buttersäure, paclobutrazol, N-phenylphthalamic acid, prohexadione, prohexadione-calcium, prohydrojasmone, Salicylsäure, Strigolacton, tecnazene, thidiazuron, triacontanol, trinexapac, trinexapac-ethyl, tsitodef, uniconazole, uniconazole-P.

[0465] Fungicidal compounds that can be used in combination with the herbicide combinations according to the invention are preferably commercially available active ingredients, for example (analogous to the herbicides, the compounds are generally referred to by their common names, here in the usual English spelling): BYC240214- Abroad

[0466] 35

[0467] 1) Inhibitoren der Ergosterol-Biosynthese, beispielsweise (1.001) Cyproconazol, (1.002) Difenoconazol, (1.003) Epoxiconazol, (1.004) Fenhexamid, (1.005) Fenpropidin, (1.006) Fenpropimorph, (1.007) Fenpyrazamin, (1.008) Fluquinconazol, (1.009) Flutriafol, (1.010) Imazalil, (1.011) Imazalil Sulfat, (1.012) Ipconazol, (1.013) Metconazol, (1.014) Myclobutanil, (1.015) Paclobutrazol, (1.016) Prochloraz, (1.017) Propiconazol, (1.018) Prothioconazol, (1.019) Pyrisoxazol, (1.020) Spiroxamin, (1.021) Tebuconazol, (1.022) Tetraconazol, (1.023) Triadimenol, (1.024) Tridemorph, (1.025) Triticonazol, ( 1.026) ( 1 R,2S,5S)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl- 1 -( 1 H- 1,2,4-triazol- 1 -ylmethyl)cyclopentanol, ( 1.027) ( 1 S,2R,5R)-5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl- 1 -(1H- 1,2,4-triazol- 1 -ylmethyl)cyclopentanol, ( 1.028) (2R)-2-( 1 -Chlorcyclopropyl) -4- [( 1 R)-2,2-dichlorcyclopropyl] -1 -( 1 H- 1,2,4-triazol- 1 -yl)butan-2-ol ( 1.029) (2R)-2-( 1 -Chlorcyclopropyl)-4- [( 1 S)-2,2-dichlorcyclopropyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)butan-2-ol, ( 1.030) (2R)-2- [4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)propan-2-ol, ( 1.031 ) (2S)-2-( 1 -Chlorcyclopropyl)-4-[( 1 R)-2,2-dichlorcyclopropyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)butan-2-ol, ( 1.032) (2S)-2-( 1 -Chlorcyclopropyl) -4- [( 1 S)-2,2-dichlorcyclopropyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)butan-2-ol, ( 1.033) (2S)-2- [4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)propan-2-ol, ( 1.034) (R)-[3-(4-Chlor- 2-fluorphenyl)-5-(2,4-difluorphenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.035) (S)-[3-(4-Chlor-2-fluorphenyl)-5-(2,4-difluorphenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.036) [3-(4-Chlor-2-fluorphenyl)-5-(2,4-difluorphenyl)-l,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) l-({(2R,4S)-2-[2-Chlor-4-(4-chlorphenoxy)phenyl] -4-methyl- 1,3-dioxolan-2-yl} methyl)- 1 H- 1,2,4-triazol, ( 1.038) 1 - ( { (2S,4S)-2- [2-Chlor-4-(4-chlorphenoxy)phenyl] -4-methyl- 1,3-dioxolan-2-yl} methyl)- 1 H- 1,2,4-triazol, ( 1.039) 1 - { [3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl} - 1H- 1,2,4-triazol-5-yl-thiocyanat, (1.040) l-{[rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-lH- 1.2.4-triazol-5-yl-thiocyanat, (1.041) l-{[rel(2R,3S)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl} - 1H- 1,2,4-triazol-5-yl-thiocyanat, ( 1.042) 2-[(2R,4R,5R)- 1 -(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.043) 2-[(2R,4R,5S)-l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.044) 2-[(2R,4S,5R)-l-(2,4-Dichlorophenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.045) 2-[(2R,4S,5S)-l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.046) 2-[(2S,4R,5R)-l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- 1,2,4-triazol-3-thion, ( 1.047) 2- [(2S,4R,5S)- 1 -(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.048) 2-[(2S,4S,5R)-l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol- 3-thion, (1.049) 2-[(2S,4S,5S)-l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl]-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.050) 2-[l-(2,4-Dichlorphenyl)-5-hydroxy-2,6,6-trimethylheptan-4-yl] -2,4-dihydro-3H- 1,2,4-triazol-3-thion, ( 1.051 ) 2- [2-Chlor-4-(2,4-dichlorophenoxy)phenyl] - 1 -( 1 H- 1.2.4-triazol- 1 -yl)propan-2-ol, ( 1.052) 2- [2-Chlor-4-(4-chlorphenoxy)phenyl] - 1 -( 1H- 1,2,4-triazol- 1 -yl)butan-2-ol, ( 1.053) 2- [4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)butan- BYC240214- Ausland.

[0468] 36

[0469] 2-ol, ( 1.054) 2- [4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)pentan-2-ol, ( 1.055) 2- [4-(4-Chlorphenoxy)-2-(trifluormethyl)phenyl] - 1 -( 1 H- 1,2,4-triazol- 1 -yl)propan-2-ol, ( 1.056) 2-{[3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-l,2,4-triazol-3-thion, ( 1.057) 2- { [rel(2R,3R)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl] methyl} -2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.058) 2-{ [rel(2R,3S)-3-(2-Chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-l,2,4-triazol-3-thion, (1.059) 5-(4-Chlorbenzyl)-2-(chlormethyl)-2-methyl-1 -(1H- 1,2,4-triazol- 1 -ylmethyl)cyclopentanol, ( 1.060) 5-(Allylsulfanyl)- 1 - { [3-(2-chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl] methyl} - 1H- 1,2,4-triazol, (1.061) 5-(Allylsulfanyl)- 1 - { [rel(2R,3R)-3-(2-chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl} - 1 H- 1,2,4-triazol, ( 1.062) 5-( Allylsulfanyl)- 1 -{[rel(2R,3S)-3-(2-chlorphenyl)-2-(2,4-difluorphenyl)oxiran-2-yl]methyl}-lH-l,2,4-triazol, (1.063) N'-(2,5-Dimethyl-4-{[3-(l,l,2,2-tetrafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, (1.064) N'-(2,5-Dimethyl-4-{[3-(2,2,2-trifluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, (1.065) N'-(2,5-Dimethyl-4-{ [3-(2, 2,3,3-tetrafluorpropoxy)phenyl] sulfanyl} phenyl) -N-ethyl-N-methylimidoformamid, ( 1.066) N'-(2,5-Dimethyl-4-{ [3-(pentafluorethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methylimidoformamid, (1.067) N'-(2,5-Dimethyl-4-{3-[(l,l,2,2-tetrafluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, (1.068) N'-(2,5-Dimethyl-4-{3-[(2,2,2-trifluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, (1.069) N'-(2,5-Dimethyl-4-{3-[(2,2,3,3-tetrafluorpropyl) sulfanyl] phenoxy} phenyl) -N-ethyl-N-methylimidoformamid, ( 1.070) N'-(2,5-Dimethyl-4- { 3-[(pentafluorethyl)sulfanyl]phenoxy}phenyl)-N-ethyl-N-methylimidoformamid, ( 1.071) N'-(2,5-Dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylimidoformamid, (1.072) N'-(4-{ [3-(Difluormethoxy)phenyl]sulfanyl}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamid, (1.073) N'-(4-{3-[(Difluormethyl)sulfanyl]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methylimidoformamid, (1.074) N'-[5-Brom-6-(2,3-dihydro-lH-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methylimidoformamid, (1.075) N'-{4-[(4,5-Dichlor-l,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methylimidoformamid, ( 1.076) N'- { 5-Brom-6- [( 1 R)- 1 -(3,5-difluorophenyl)ethoxy] -2-methylpyridin- 3 -yl} -N-ethyl-N-methylimidoformamid, (1.077) N'-{5-Brom-6-[(1S)-1-(3,5-difluorphenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, ( 1.078) N'- { 5-Brom-6-[(cis-4-isopropylcyclohexyl)oxy] -2-methylpyridin-3-yl} -N-ethyl-N-methylimidoformamid, ( 1.079) N'- { 5-Brom-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, (1.080) N'-{5-Bromo-6-[l-(3,5-difluorphenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methylimidoformamid, (1.081) Mefentrifluconazole, (1.082) Ipfentrifluconazole.

[0470] 2) Inhibitoren der Atmungskette am Komplex I oder II beispielsweise (2.001) Benzovindiflupyr, (2.002) Bixafen, (2.003) Boscalid, (2.004) Carboxin, (2.005) Fluopyram, (2.006) Flutolanil, (2.007) Fluxapyroxad, (2.008) Furametpyr, (2.009) Isofetamid, (2.010) Isopyrazam (anti-epimeres Enantiomer 1R,4S,9S), (2.011) Isopyrazam (anti-epimeres Enantiomer 1S,4R,9R), (2.012) Isopyrazam (anti- BYC240214- Ausland

[0471] 37

[0472] epimeres Racemat 1RS,4SR,9SR), (2.013) Isopyrazam (Mischung des syn-epimeren Razemates 1RS,4SR,9RS und des anti-epimeren Razemates 1RS,4SR,9SR), (2.014) Isopyrazam (syn-epimeres Enantiomer 1R,4S,9R), (2.015) Isopyrazam (syn-epimeres Enantiomer 1S,4R,9S), (2.016) Isopyrazam (syn-epimeres Racemat 1RS,4SR,9RS), (2.017) Penflufen, (2.018) Penthiopyrad, (2.019) Pydiflumetofen, (2.020) Pyraziflumid, (2.021) Sedaxane, (2.022) l,3-Dimethyl-N-(l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl)-lH-pyrazol-4-carboxamid, (2.023) l,3-Dimethyl-N-[(3R)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazol-4-carboxamid, (2.024) l,3-Dimethyl-N-[(3S)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazol-4-carboxamid, (2.025) l-Methyl-3-(trifluormethyl)-N-[2'-(trifluormethyl)biphenyl-2-yl]-lH-pyrazol-4-carboxamid, (2.026) 2-Fluor-6-(trifluoromethyl)-N-(l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl)benzamid, (2.027) 3-(Difluormethyl)-l-methyl-N-(l,l,3-trimethyl- 2.3-dihydro-lH-inden-4-yl)-lH-pyrazol-4-carboxamid, (2.028) 3-(Difluormethyl)-l-methyl-N-[(3R)- 1.1.3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazol-4-carboxamid, (2.029) 3-(Difluormethyl)-l-methyl-N-[(3S)-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-lH-pyrazol-4-carboxamid, (2.030) 3-(Difluormethyl)-N-(7-fluor- 1, 1,3-trimethyl-2,3-dihydro- lH-inden-4-yl)- 1 -methyl- lH-pyrazol-4-carboxamid, (2.031) 3-(Difluormethyl)-N-[(3R)-7-fluor-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-l-methyl-lH-pyrazol-4-carboxamid, (2.032) 3-(Difluoromethyl)-N-[(3S)-7-fluor-l,l,3-trimethyl-2,3-dihydro-lH-inden-4-yl]-l -methyl- lH-pyrazol-4-carboxamid, (2.033) 5,8-Difluor-N-[2-(2-fluor-4-{ [4-(trifluormethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amin, (2.034) N-(2-Cyclopentyl-5-fluorbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor- 1 -methyl- lH-pyrazol-4-carboxamid, (2.035) N-(2-tert-Butyl-5-methylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.036) N-(2-tert-Butylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.037) N-(5-Chlor-2-ethylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor- 1 -methyl- 1 H-pyrazol-4-carboxamid, (2.038) N-(5 -Chlor-2-isopropylbenzyl) -N -cyclopropyl-3 -(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.039) N-[(lR,4S)-9-(Dichlormethylen)-1,2,3,4-tetrahydro- 1,4-methanonaphthalen-5-yl] -3-(difluormethyl)- 1 -methyl- lH-pyrazol-4-carboxamid, (2.040) N-[(lS,4R)-9-(Dichlormethylen)-l,2,3,4-tetrahydro-l,4-methanonaphthalen-5-yl]-3-(difluormethyl) - 1 -methyl- 1 H-pyr azol-4-carboxamid, (2.041) N-[l -(2,4-Dichlorphenyl)- 1 -methoxypropan-2-yl]-3-(difluormethyl)-l-methyl-lH-pyrazol-4-carboxamid, (2.042) N-[2-Chlor-6-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.043) N-[3-Chlor-2-fluor-6-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.044) N-[5-Chlor-2-(trifluormethyl)benzyl]-N-cyclopropyl-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.045) N-Cyclopropyl-3-(difluormethyl)-5 -fluor- 1 -methyl-N - [5 -methyl-2-(trifluormethyl)benzyl] - 1 H-pyr azol-4-carboxamid, (2.046) N -Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-fluor-6-isopropylbenzyl)-l-methyl-lH-pyrazol-4-carboxamid, (2.047) N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-isopropyl-5-methylbenzyl)- 1 -methyl- lH-pyrazol-4-carboxamid, (2.048) N-Cyclopropyl-3-(difluormethyl)-5-fluor-N-(2-isopropylbenzyl)-l-methyl-lH-pyrazol-4-carbothioamid, (2.049) N-Cyclopropyl-3-(difluoromethyl)-5- BYC240214- Ausland.

[0473] 38

[0474] fluor-N-(2-isopropylbenzyl)- 1 -methyl- lH-pyrazol-4-carboxamid, (2.050) N-Cyclopropyl-3-(difluormethyl) -5 -fluor-N-(5 -fluor-2-isopropylbenzyl) - 1 -methyl- 1 H-pyr azol-4-carboxamid, (2.051) N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluor-l-methyl-lH-pyrazol-4-carboxamid, (2.052) N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-fluorbenzyl)-5-fluor- 1 -methyl- 1H-pyrazol-4-carboxamid, (2.053) N-Cyclopropyl-3-(difluormethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluor-l-methyl-lH-pyrazole-4-carboxamid, (2.054) N-Cyclopropyl-N-(2-cyclopropyl-5-fluorbenzyl)-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazole-4-carboxamid, (2.055) N-Cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl)-3-(difluormethyl)-5-fluor- 1 -methyl- lH-pyrazole-4-carboxamid, (2.056) N-Cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluormethyl)-5-fluor-l-methyl-lH-pyrazole-4-carboxamid.

[0475] 3) Inhibitoren der Atmungskette am Komplex III, beispielsweise (3.001) Ametoctradin, (3.002) Amisulbrom, (3.003) Azoxystrobin, (3.004) Coumethoxystrobin, (3.005) Coumoxystrobin, (3.006) Cyazofamid, (3.007) Dimoxystrobin, (3.008) Enoxastrobin, (3.009) Famoxadon, (3.010) Fenamidon, (3.011) Flufenoxystrobin, (3.012) Fluoxastrobin, (3.013) Kresoxim-Methyl, (3.014) Metominostrobin, (3.015) Orysastrobin, (3.016) Picoxystrobin, (3.017) Pyraclostrobin, (3.018) Pyrametostrobin, (3.019) Pyraoxystrobin, (3.020) Trifloxystrobin (3.021) (2E)-2-{2-[({[(lE)-l-(3-{[(E)-l-Fluor-2-phenyl vinyl] oxy} phenyl)ethyliden] amino} oxy)methyl] phenyl} -2-(methoxyimino) -N -methylacetamid, (3.022) (2E,3Z)-5-{[l-(4-Chlorphenyl)-lH-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamid, (3.023) (2R)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.024) (2S)-2-{2-[(2,5-Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.025) (3S,6S,7R,8R)-8-Benzyl-3-[({3-[(isobutyryloxy)methoxy]-4-methoxypyridin-2-yl}carbonyl)amino]-6-methyl-4,9-dioxo-l,5-dioxonan-7-yl-2-methylpropanoat, (3.026) 2-{2-[(2,5- Dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamid, (3.027) N-(3-Ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamid, (3.028) (2E,3Z)-5- { [ 1 -(4-Chlor-2-fluorphenyl)-lH-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamid, (3.029) Methyl {5-[3-(2,4-dimethylphenyl)- 1 H-pyr azol- 1 -yl] -2-methylbenzyl} carbamate.

[0476] 4) Inhibitoren der Mitose und Zellteilung, beispielsweise (4.001) Carbendazim, (4.002) Diethofencarb, (4.003) Ethaboxam, (4.004) Fluopicolid, (4.005) Pencycuron, (4.006) Thiabendazol, (4.007) Thiophanat-Methyl, (4.008) Zoxamid,, (4.009) 3-Chlor-4-(2,6-difluorphenyl)-6-methyl-5-phenylpyridazin, (4.010) 3-Chlor-5-(4-chlorphenyl)-4-(2,6-difluorphenyl)-6-methylpyridazin, (4.011) 3-Chlor-5-(6-chlorpyridin-3-yl)-6-methyl-4-(2,4,6-trifluorphenyl)pyridazin, (4.012) 4-(2-Brom-4-fluorphenyl)-N-(2,6-difluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.013) 4-(2-Brom-4-fluorphenyl)-N-(2-brom-6-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.014) 4-(2-Brom-4-fluorphenyl)-N-(2-bromphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.015) 4-(2-Brom-4-fluorphenyl)-N-(2-chlor-6-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.016) 4-(2-Brom-4-fluorphenyl)-N-(2-chlorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.017) 4-(2-Brom-4-fluorphenyl)-N-(2-fluorphenyl)- BYC240214- Ausland

[0477] 39

[0478] l,3-dimethyl-lH-pyrazol-5-amin, (4.018) 4-(2-Chlor-4-fluorphenyl)-N-(2,6-difluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.019) 4-(2-Chlor-4-fluorphenyl)-N-(2-chlor-6-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.020) 4-(2-Chlor-4-fluorphenyl)-N-(2-chlorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.021) 4-(2-Chlor-4-fluorphenyl)-N-(2-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.022) 4-(4-Chlorphenyl)-5-(2,6-difluorphenyl)-3,6-dimethylpyridazin, (4.023) N-(2-Brom-6-fluorphenyl)-4-(2-chlor-4-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.024) N-(2-Bromphenyl)-4-(2-chlor-4-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin, (4.025) N-(4-Chlor-2,6-difluorphenyl)-4-(2-chlor-4-fluorphenyl)-l,3-dimethyl-lH-pyrazol-5-amin.

[0479] 5) Compounds capable of multisite activity, for example (5.001) Bordeaux mixture, (5.002) Captafol, (5.003) Captan, (5.004) Chlorothalonil, (5.005) Copper hydroxide, (5.006) Copper naphthenate, (5.007) Copper oxide, (5.008) Copper oxychloride, (5.009) Copper(2+) sulfate, (5.010) Dithianon, (5.011) Dodine, (5.012) Folpet, (5.013) Mancozeb, (5.014) Maneb, (5.015) Metiram, (5.016) Zinc metiram, (5.017) Copper oxine, (5.018) Propineb, (5.019) Sulfur and sulfur preparations including calcium polysulfide, (5.020) Thiram, (5,021) Zineb, (5,022) Ziram, (5,023) 6-Ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][l,4]dithiino[2,3-c][l,2]thiazole-3-carbonitrile.

[0480] 6) Compounds capable of triggering host defense, for example (6.001) Acibenzolar-S-Methyl, (6.002) Isotianil, (6.003) Probenazol, (6.004) Tiadinil.

[0481] 7) Inhibitors of amino acid and / or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinoline-l-yl)quinoline.

[0482] (8) Inhibitors of ATP production, for example (8.001) Silthiofam.

[0483] 9) Inhibitors of cell wall synthesis, for example (9.001) Benthiavalicarb, (9.002) Dimethomorph, (9.003) Flumorph, (9.004) Iprovalicarb, (9.005) Mandipropamid, (9.006) Pyrimorph, (9.007) Valifenalate, (9.008) (2E)-3-(4-tert-Butylphenyl)-3-(2-chloropyridin-4-yl)-l-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-Butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.

[0484] 10) Inhibitors of lipid and membrane synthesis, for example (10.001) Propamocarb, (10.002) Propamocarb hydrochloride, (10.003) Tolclofos methyl.

[0485] 11) Inhibitors of melanin biosynthesis, for example (11.001) tricyclazole, (11.002) 2,2,2-trifluoroethyl- { 3-methyl- 1 - [(4-methylbenzoyl)amino]butan-2-yl} carbamate.

[0486] 12) Nucleic acid synthesis inhibitors, for example (12.001) Benalaxyl, (12.002) Benalaxyl-M (Kiralaxyl), (12.003) Metalaxyl, (12.004) Metalaxyl-M (Mefenoxam). BYC240214- Abroad

[0487] 40

[0488] 13) Inhibitors of signal transduction, for example (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazide, (13.005) quinoxyfen, (13.006) vinclozoline.

[0489] 14) Compounds that can act as uncouplers, for example (14.001) Fluazinam, (14.002) Meptyldinocap.

[0490] 15) Other compounds, for example (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazine, (15.004) capsimycin, (15.005) carvone, (15.006) quinomethionate, (15.007) cufraneb, (15.008) cyflufenamide, (15.009) cymoxanil, (15.010) cyprosulfamide, (15.011) flutianil, (15.012) fosetyl aluminum, (15.013) fosetyl calcium, (15.014) fosetyl sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) Natamycin, (15.019) Nickel dimethyldithiocarbamate, (15.020) Nitrothal isopropyl, (15.021) Oxamocarb, (15.022) Oxathiapiproline, (15.023) Oxyfenthiin, (15.024) Pentachlorophenol and salts, (15.025) Phosphonic acid and its salts, (15.026) Propamocarb fosetylate, (15.027) Pyriofenones (Chlazafenones), (15.028) Tebufloquine, (15.029) Tecloftalam, (15.030) Tolnifanides, (15.031) l-(4-{4-[(5R)-5-(2,6-Difluorophenyl)-4,5-dihydro- 1,2-oxazol-3-yl] - 1,3-thiazol-2-yl Jpiperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.032) 1 -(4- { 4-[(5S)-5-(2,6-Difluorphenyl)-4,5-dihydro- 1,2-oxazol-3-yl] -1,3-thiazol-2-yl} piperidin- 1 -yl)-2-[5-methyl-3-(trifluormethyl)- IH-pyrazol- 1 -yl]ethanon, (15.033) 2-(6-Benzylpyridin-2-yl)quinazolin, (15.034) 2,6-Dimethyl-lH,5H-[l,4]dithiino[2,3-c:5,6-c']dipyrrol- 1,3,5,7(2H,6H)-tetron, ( 15.035) 2- [3,5-Bis(difluormethyl)- 1 H-pyrazol- 1 -yl] - 1 - [4-(4- { 5- [2-(prop-2-in- 1 -yloxy)phenyl]-4,5-dihydro-l,2-oxazol-3-yl}-l,3-thiazol-2-yl)piperidin-l-yl]ethanon, (15.036) 2-[3,5-Bis(difluormethyl)- 1 H-pyrazol- 1 -yl] - 1 - [4- (4- { 5- [2-chlor-6-(prop-2-in- 1 -yloxy)phenyl] -4,5-dihydro- 1,2-oxazol-3-yl}-l,3-thiazol-2-yl)piperidin-l-yl]ethanon, (15.037) 2-[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluor-6-(prop-2-in-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanon, ( 15.038) 2- [6-(3-Fluor-4-methoxyphenyl)-5-methylpyridin-2-yl] quinazolin, (15.039) 2-{(5R)-3-[2-(l-{[3,5-Bis(difluormethyl)-lH-pyrazol-l-yl]acetyl}piperidin-4-yl)-l,3-thiazol-4-yl]-4,5-dihydro-l,2-oxazol-5-yl}-3-chlorphenyl methanesulfonat, (15.040) 2-{ (5S)-3-[2-(l-{ [3,5-Bis(difluormethyl)- IH-pyrazol- 1 -yl] acetyl}piperidin-4-yl)- 1,3-thiazol-4-yl]-4,5-dihydro- 1,2-oxazol-5-yl}-3-chlorphenyl methanesulfonat, (15.041) 2-{2-[(7,8-Difluor-2-methylquinolin-3-yl)oxy]-6-fluorphenyl}propan-2-ol, (15.042) 2-{2-Fluor-6-[(8-fluor-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15.043) 2-{3-[2-(l-{[3,5-Bis(difluormethyl)-lH-pyrazol-l-yl]acetyl}piperidin-4-yl)-l,3-thiazol-4-yl]-4,5-dihydro-l,2-oxazol-5-yl}-3-chlorphenyl-methansulfonat, (15.044) 2-{3-[2-(1-{[3,5-Bis(difluormethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl methanesulfonat, (15.045) 2-Phenylphenol und deren Salze, (15.046) 3-(4,4,5-Trifluor-3,3-dimethyl-3,4-dihydroisoquinolin- 1 -yl)quinolin, ( 15.047) 3-(4,4-Difluor-3,3-dimethyl-3,4-dihydroisoquinolin-l-yl)quinolin, (15.048) 4-Amino-5-fluorpyrimidin-2-ol (Tautomere Form: 4-Amino-5-fluorpyrimidin-2(lH)-on), (15.049) 4-Oxo-4-[(2-phenylethyl)amino]buttersäure, (15.050) 5-Amino- BYC240214- Ausland.

[0491] 41

[0492] 1,3,4-thiadiazol-2-thiol, (15.051) 5-Chlor-N'-phenyl-N'-(prop-2-yn-l-yl)thiophen-2-sulfonohydrazid, (15.052) 5-Fluor-2-[(4-fluorbenzyl)oxy]pyrimidin-4-amin, (15.053) 5-Fluor-2-[(4-methylbenzyl)oxy]pyrimidin-4-amin, (15.054) 9-Fluor-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1,4-benzoxazepin, (15.055) But-3-yn-1-yl {6-[({[(Z)-(l-methyl-lH-tetrazol-5-yl)(phenyl)methylen]amino}oxy)methyl]pyridin-2-yl}carbamat, (15.056) Ethyl (2Z)-3-amino-2-cyano-3-phenylacrylat, (15.057) Phenazin- 1 -carbonsäure, (15.058) Propyl 3,4,5-trihydroxybenzoat, (15.059) Quinolin-8-ol, (15.060) Quinolin-8-ol sulfat (2:1), (15.061) tert-Butyl {6-[({[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamat, (15.062) 5-Fluor-4-imino-3-methyl-1-(2-[[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamat, (15.062) 5-Fluor-4-imino-3-methyl-1)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one.

[0493] Preferred fungicides are selected from the group consisting of benalaxyl, bitertanol, bromuconazole, captafol, carbendazim, carpropamid, cyazofamid, cyproconazole, diethofencarb, edifenphos, fenpropimorph, fentine, fluquinconazole, fosetyl, fluoroimide, folpet, iminoctadine, iprodione, iprovalicarb, kasugamycin, maneb, nabam, pencycuron, prochloraz, propamocarb, propineb, pyrimethanil, sprioxamine, quintozene, tebuconazole, tolylfluanid, triadimefon, triadimenol, trifloxystrobin, and zineb.

[0494] Insecticides, acaricides, nematicides, miticides and related active substances include, for example (analogous to herbicides and fungicides, the compounds are referred to by their common names where possible, here in the usual English spelling):

[0495] (1) Acetylcholinesterase(AChE)-Inhibitoren, vorzugsweise Carbamate ausgewählt aus Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, Isoprocarb, Methiocarb, Methomyl, Metolcarb, Oxamyl, Pirimicarb, Propoxur, Thiodicarb, Thiofanox, Triazamate, Trimethacarb, XMC und Xylylcarb, oder Organophosphate ausgewählt aus Acephat, Azamethiphos, Azinphos-ethyl, Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chlorpyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos / DDVP, Dicrotophos, Dimethoat, Dimethyl vinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazat, Heptenophos, Imicyafos, Isofenphos, Isopropyl-O-(methoxyaminothio-phosphoryl)salicylat, Isoxathion, Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl,Phenthoate, Phorate, Phosalon, Phosmet, Phosphamidone, Phoxim, Pirimiphos-methyl, Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Triclorfon and Vamidothion.

[0496] (2) GABA-gated chloride channel blockers, preferably cyclodiene organochlorines selected from chlordane and endosulfan, or phenylpyrazoles (fiproles) selected from ethiprol and fipronil. BYC240214- Abroad

[0497] 42

[0498] (3) sodium channel modulators, preferably pyrethroids selected from acrinathrin, allethrin, d-cis-trans-allethrin, d-trans-allethrin, bifenthrin, bioallethrin, bioallethrin-S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, Cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin [(1R)-trans isomer], deltamethrin, empenthrin [(EZ)-(1R) isomer], esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau fluvalinate, Halfenprox, Imiprothrin, Kadethrin, Momfluorothrin, Permethrin, Phenothrin [(1R)-trans isomer], Prallethrin, Pyrethrins (pyrethrum), Resmethrin, Silafluofen, Tefluthrin, Tetramethrin, Tetramethrin [(1R)-Isomer], Tralomethrin and Transfluthrin, or DDT or Methoxychlor.

[0499] (4) Competitive modulators of the nicotinic acetylcholine receptor (nAChR), preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sufoximines selected from sulfoxaflor, or butenolides selected from flupyradifurone.

[0500] (5) Allosteric modulators of the nicotinic acetylcholine receptor (nAChR), preferably spinosynes selected from spinetoram and spinosad.

[0501] (6) Allosteric modulators of the glutamate-dependent chloride channel (GluCl), preferably avermectins / milbemycins selected from abamectin, emamectin benzoate, lepimectin and milbemectin.

[0502] (7) Juvenile hormone mimetics, preferably juvenile hormone analogues selected from hydroprene, kinoprene and methoprene, or fenoxycarb or pyriproxyfen.

[0503] (8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfuryl fluoride or borax or tartar emetic or methyl isocyanate generators selected from diazomet and metam.

[0504] (9) TRPV channel modulators of chordotonal organs selected from pymetrozine and pyrifluquinazone. (10) Mite growth inhibitors selected from clofentezine, hexythiazox, diflovidazine, and etoxazole. (11) Microbial disruptors of the insect intestinal membrane selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis, and Bt plant proteins selected from CrylAb, CrylAc, CrylFa, CrylA.105, Cry2Ab, VIP3A, mCry3A, Cry3Ab, Cry3Bb, and Cry34Abl / 35Abl. BYC240214- Abroad

[0505] 43

[0506] (12) Inhibitors of mitochondrial ATP synthase, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin oxide, or propargite or tetradifone.

[0507] (13) Uncouplers of oxidative phosphorylation by disturbance of the proton gradient selected from chlorfenapyr, DNOC and sulfuramide.

[0508] (14) Blockers of the nicotinic acetylcholine receptor channel selected from Bensultap, Cartap hydrochloride, thiocyclam and thiosultap sodium.

[0509] (15) Inhibitors of chitin biosynthesis, type 0, selected from bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron and triflumuron.

[0510] (16) Inhibitors of chitin biosynthesis, type 1 selected from buprofezin.

[0511] (17) Molting disruptor (especially in Diptera, i.e., true flies) selected from cyromazine. (18) Ecdysone receptor agonists selected from chromafenozide, halofenozide, methoxyfenozide, and tebufenozide.

[0512] (19) Octopamine receptor agonists selected from amitraz.

[0513] (20) Mitochondrial complex III electron transport inhibitors selected from hydramethylnone, acequinocyl and fluacrypyrim.

[0514] (21) Mitochondrial complex I electron transport inhibitors, preferably METI acaricides selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad, or rotenone (Derris).

[0515] (22) Voltage-gated sodium channel blockers selected from indoxacarb and metaflumizone. (23) Acetyl-CoA carboxylase inhibitors, preferably tetronic and tetramic acid derivatives selected from spirodiclofen, spiromesifen and spirotetramate.

[0516] (24) Inhibitors of mitochondrial complex IV electron transport, preferably phosphines selected from aluminium phosphide, calcium phosphide, phosphine and zinc phosphide, or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

[0517] (25) Inhibitors of mitochondrial complex II electron transport, preferably beta-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or carboxanilides selected from pyflubumide. BYC240214- Abroad

[0518] 44

[0519] (28) Ryanodine receptor modulators, preferably diamides selected from chloroantraniliprole, cyantraniliprole and flubendiamide.

[0520] (29) Modulators of chordotonal organs (with undefined target structure) selected from flonicamide. (30) further active substances selected from Acynonapyr, Afidopyropene, Afoxolaner, Azadirachtin, Benclothiaz, Benzoximate, Benzpyrimoxane, Bifenazate, Broflanilide, Bromopropylate, Quinomethionate, Chloroprallethrin, Cryolite, Cyclaniliprol, Cycloxapride, Cyhalodiamide, Dicloromezotiaz, Dicofol, epsilon-Metofluthrin, epsilon-Momfluthrin, Flometoquine, Fluazaindolizine, Fluensulfone, Flufenerim, Flufenoxystrobin, Flufiprole, Fluhexafone, Fluopyram, Flupyrimin, Fluralaner, Fluxametamide, Fufenozide, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, kappa-Bifenthrin, kappa-Tefluthrin, Lotilaner, Meperfluthrin Oxazosulfyl, Paichongding, Pyridalyl, Pyrifluquinazone, Pyriminostrobin, Spirobudiclofen, Spiropidion, Tetramethylfluthrin, Tetraniliprol, Tetrachloroantraniliprole, Tigolaner, Tioxazafen, Thiofluoximate, Triflumezopyrim and iodomethane; furthermore, preparations based on Bacillus firmus (1-1582, BioNeem,Votivo), as well as the following compounds: 1-{2-Fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from W02006 / 043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro[indol-3,4'-piperidine]-1(2H)-yl}(2-chloropyridine-4-yl)methanone (known from W02003 / 106457) (CAS 637360-23-7), 2-Chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from W02006 / 003494) (CAS 872999-66-1), 3-(4-Chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-l,8-diazaspiro[4.5]dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3-(4-chloro-2, 6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl ethyl carbonate (known from EP 2647626) (CAS-1440516-42-6), 4-(But-2-yne-l-yloxy)-6-(3,5-dimethylpiperidin-l-yl)-5-fluoropyrimidine (known from W02004 / 099160) (CAS 792914-58-0), PF1364 (known from JP2010 / 018586) (CAS Reg. No. 1204776-60-2),(3E)-3-[l-[(6-Chlor-3-pyridyl)methyl]-2-pyridyliden]-l,l,l-trifluorpropan-2-on (bekannt aus WO2013 / 144213) (CAS 1461743-15-6), N-[3-(Benzylcarbamoyl)-4-chlorphenyl]-1-methyl-3-(pentafluorethyl)-4-(trifluormethyl)-1H-pyrazol-5-carboxamid (bekannt aus WO2010 / 051926) (CAS 1226889-14-0), 5-Brom-4-chlor-N-[4-chlor-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chlor-2-pyridyl)pyrazol-3-carboxamid (bekannt aus CN103232431) (CAS 1449220-44-3), 4-[5-(3,5-Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(cis-l-oxido-3-thietanyl)benzamid, 4-[5-(3,5-Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl] -2-methyl-N-(trans- 1 -oxido-3-thietanyl)benzamid und 4-[(5S)-5-(3,5-Dichlorphenyl)-4,5-dihydro-5-(trifluormethyl)-3-isoxazolyl]-2-methyl-N-(cis-l-oxido-3-thietanyl)benzamid (bekannt aus WO 2013 / 050317 Al) (CAS 1332628-83-7), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid,(+)-N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid und (-)-N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)sulfinyl]propanamid (bekannt aus WO 2013 / 162715 A2, WO 2013 / 162716 A2, US 2014 / 0213448 Al) (CAS 1477923-37-7), BYC240214- Ausland,

[0521] 45

[0522] 5-[[(2E)-3-Chlor-2-propen-1-yl]amino]-1-[2,6-dichlor-4-(trifluormethyl)phenyl]-4-[(trifluormethyl)sulfinyl]-1H-pyrazol-3-carbonitrile (bekannt aus CN 101337937 A) (CAS 1105672-77-2), 3-Brom-N-[4-chlor-2-methyl-6-[(methylamino)thioxomethyl]phenyl]-1-(3-chlor-2-pyridinyl)-1H-pyrazol-5-carboxamid, (Liudaibenjiaxuanan, bekannt aus CN 103109816 A) (CAS 1232543-85-9); N-[4-Chlor-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chlor-2-pyridinyl)-3-(fluormethoxy)-1H-pyrazol-5-carboxamid (bekannt aus WO 2012 / 034403 Al) (CAS 1268277-22-0), N-[2-(5-Amino-1,3,4-thiadiazol-2-yl)-4-chlor-6-methylphenyl]-3-brom-1-(3-chlor-2-pyridinyl)-1H-pyrazol-5-carboxamid (bekannt aus WO 2011 / 085575 Al) (CAS 1233882-22-8), 4-[3-[2,6-Dichlor-4-[(3,3-dichlor-2-propen-l-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluormethyl)pyrimidin (bekannt aus CN 101337940 A) (CAS 1108184-52-6); (2E)- und 2(Z)-2-[2-(4-Cyanophenyl)-l-[3-(trifluormethyl)phenyl]ethyliden]-N-[4-(difluormethoxy)phenyl]hydrazincarboxamid (bekannt aus CN 101715774 A) (CAS 1232543-85-9); Cyclopropancarbonsäure-3-(2,2-dichlorethenyl)-2,2-dimethyl-4-(lH-benzimidazol-2-yl)phenylester (bekannt aus CN 103524422 A) (CAS 1542271-46-4); (4aS)-7-Chlor-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluormethyl)thio]phenyl]amino]carbonyl]indeno[1,2-e][1,3,4]oxadiazin-4a(3H)-carbonsäuremethylester (bekannt aus CN 102391261 A) (CAS 1370358-69-2); 6-Desoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluorethoxy)phenyl]-1H-1,2,4-triazol-3-yl]phenyl]carbamat]-α-L-mannopyranose (bekannt aus US 2014 / 0275503 Al) (CAS 1181213-14-8); 8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octan (CAS 1253850-56-4),(8-anti)-8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octan (CAS 933798-27-7), (8-syn)-8-(2-Cyclopropylmethoxy-4-trifluormethylphenoxy)-3-(6-trifluormethylpyridazin-3-yl)-3-azabicyclo[3.2.1]octan (bekannt aus WO 2007040280 Al, WO 2007040282 Al) (CAS 934001-66-8), N-[3-Chlor-1-(3-pyridinyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluorpropyl)thio]-propanamid (bekannt aus WO 2015 / 058021 Al, WO 2015 / 058028 Al) (CAS 1477919-27-9) und N-[4-(Aminothioxomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazol-5-carboxamid (bekannt aus CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-Dioxan-2-yl)-4-[[4-(trifluormethyl)phenyl]methoxy]-pyrimidin (bekannt aus WO 2013 / 115391 Al) (CAS 1449021-97-9), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dion (bekannt aus WO 2014 / 187846 Al) (CAS 1638765-58-8), 3-(4-Chlor-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl carboxylic acid ethyl ester (known from WO 2010 / 066780 Al, WO 2011151146 Al) (CAS 1229023-00-0), 4-[(5S)-5-(3,5-Dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-benzamide (known from WO 2011 / 067272, WO2013 / 050302) (CAS 1309959-62-3).,

[0523] Examples of insecticides that can be used preferably in combination with herbicides are: BYC240214- Abroad

[0524] 46

[0525] Acetamiprid, Acrinathrin, Aldicarb, Amitraz, Acinphos-methyl, Cyfluthrin, Carbaryl, Cypermethrin, Deltamethrin, Endosulfan, Ethoprophos, Fenamiphos, Fenthion, Fipronil, Imidacloprid, Methamidophos, Methiocarb, Niclosamide, Oxydemeton-methyl, Prothiophos, Silafluofen, Thiacloprid, Thiodicarb, Tralomethrin, Triazophos, Trichlorfon, Triflumuron, Terbufos, Fonofos, Phorate, Chlorpyriphos, Carbofuran, Tefluthrin.

[0526] The active ingredient combinations according to the invention are suitable for controlling a broad spectrum of weeds in non-agricultural land, on roads, railway tracks, industrial areas ("industrial weed control"), or in plantation crops in temperate, subtropical, and tropical climates or geographies. Examples of plantation crops include oil palm, nuts (e.g., almonds, hazelnuts, walnuts, macadamia nuts), coconut, berries, rubber trees, citrus (e.g., oranges, lemons, tangerines), bananas, pineapples, cotton, sugar cane, tea, coffee, cocoa, and similar crops. They are also suitable for use in fruit growing (e.g., pome fruits such as apples, pears, cherries, mangoes, kiwis) and viticulture. The products can also be used for seedbed preparation ("burn-down," "no-till," or "zero-till" methods) or for post-harvest treatment ("chemical fallow"). The application possibilities of the active ingredient combinations also extend to weed control in tree crops, e.g.,young Christmas tree plantations or eucalyptus plantations, either before planting or after transplanting (also with over-top treatment).

[0527] The products can also be used to control unwanted plant growth in economically important crops such as wheat (durum and common wheat), maize, soybeans, sugar beet, sugar cane, cotton, rice, beans (such as bush beans and broad beans), flax, barley, oats, rye, triticale, potatoes and millet (sorghum), pastureland and grass / lawn areas and plantation crops. Plantation crops include pomefruits (apple, pear, quince), Ribes-type fruits (blackberry, raspberry), citrus fruits, Prunus-type fruits (cherries, nectarines, almonds), nuts (walnut, pecan, hazelnut, cashew, macadamia), mango, cocoa, coffee, wine (table grapes, wine grapes), palm trees (such as oil palm, date palm, coconut palm), eucalyptus, persimmon, rubber, pineapple, banana, avocado, lychee, and forest crops (Eucalypteae, Piniaceae, Piceae, Meliaceae, etc.).

[0528] The herbicidal active ingredient combinations according to the invention, in their respective application forms (= herbicidal agents), exhibit synergies with regard to herbicide activity and selectivity, and have a favorable effect on the weed spectrum. They demonstrate excellent herbicidal efficacy against a broad spectrum of economically important monocotyledonous and dicotyledonous annual weeds. Even difficult-to-control perennial weeds that sprout from rhizomes, rootstocks, or other persistent organs are effectively controlled by the active ingredients. BYC240214- Abroad

[0529] 47

[0530] The active ingredient combinations can be applied to the plants (e.g., pest plants such as mono- or dicotyledonous weeds or unwanted cultivated plants), the seed (e.g., grains, seeds or vegetative propagation organs such as tubers or shoot parts with buds) or the area on which the plants grow (e.g., the cultivated area).

[0531] The substances can be applied via pre-sowing (possibly also by incorporation into the soil), pre-emergence, or post-emergence methods. Application is preferred in early reseeding / pre-emergence or post-emergence applications of plantation crops against weeds that have not yet emerged or have already emerged. The application can also be integrated into weed management systems with sequential applications.

[0532] Specifically, some representatives of the mono- and dicotyledonous weed flora that can be controlled by the active ingredient combinations according to the invention are mentioned as examples, without the mention of which is intended to restrict them to specific species.

[0533] On the side of monocotyledonous weed species, for example Aegilops, Agropyron, Agrostis, Alopecurus, Apera, Avena, Brachicaria, Bromus, Cynodon, Dactyloctenium, Digitaria, Echinochloa, Eleocharis, Eleusine, Eragrostis, Eriochloa, Festuca, Fimbristylis, Imperata, Ischaemum, Heteranthera, Imperata, Ischaemum, Leptochloa, Lolium, Monochoria, Panicum, Paspalum, Phalaris, Phleum, Poa, Rottboellia, Sagittaria, Scirpus, Setaria, Sorghum, Sphenoclea and Cyperus species are included in the annual group.

[0534] In the case of dicotyledonous weeds, the spectrum of action extends to species such as Abutilon, Amaranthus, Ambrosia, Anoda, Anthemis, Aphanes, Artemisia, Atriplex, Bellis, Bidens, Capsella, Carduus, Cassia, Centaurea, Chenopodium, Cirsium, Convolvulus, Datura, Desmodium, Emex, Erodium, Erysimum, Euphorbia, Galeopsis, Galinsoga, Galium, Geranium, Hibiscus, Ipomoea, Kochia, Lamium, Lepidium, Lindernia, Matricaria, Mentha, Mercurialis, Mullugo, Myosotis, Papaver, Pharbitis, Plantago, Polygonum, Portulaca, Ranunculus, Raphanus, Rorippa, Rotala, Rumex, Salsola, Senecio, Sesbania, Sida, Sinapis, Solanum, Sonchus, Sphenoclea, Stellaria, Taraxacum, Thlaspi, Trifolium, Urtica, Veronica, Viola, Xanthium.

[0535] If the active ingredient combinations according to the invention are applied to the soil surface before germination, either the emergence of the weed seedlings is completely prevented or the weeds grow up to the cotyledon stage, but then stop growing and finally die completely after three to four weeks.

[0536] When the active ingredients are applied to the green parts of the plants in a post-emergence application, growth stops after treatment and the weeds remain at the size they were at the time of application. BYC240214- Abroad

[0537] 48

[0538] The existing growth stage either stops or dies completely after a certain time, so that in this way harmful weed competition for the cultivated plants is eliminated very early and sustainably.

[0539] The herbicidal agents according to the invention are characterized by a rapid onset and long-lasting herbicidal effect. The rainfastness of the active ingredients in the combinations according to the invention is generally favorable. A particular advantage is that the effective dosages of compounds (A) and (B) used in the combinations can be set so low that their soil activity is optimally minimized. This not only makes their use possible in sensitive crops, but also practically prevents groundwater contamination. The combination of active ingredients according to the invention enables a significant reduction in the required application rate of the active ingredients.

[0540] The combined use of herbicides (A) and (B) achieves application-related properties that exceed what could be expected based on the known properties of the individual herbicides for their combination. For example, the herbicidal effects on a specific weed species surpass the expected value as estimated using standard methods, e.g., according to Colby or other extrapolation methods.

[0541] A synergistic effect occurs whenever the effect, in this case the herbicidal effect, of the combination of active ingredients is greater than the sum of the effects of the individually applied active ingredients. The expected effect for a given combination of two active ingredients can be calculated according to S.R. Colby (“Calculating Synergistic and Antagonistic Responses of Herbicide Combination”, Weeds 15 (1967), 20-22) (see below).

[0542] The synergistic effects therefore allow, for example, a reduction in the application rates of individual active ingredients, a higher efficacy with the same application rate, the control of previously uncontrolled species of weeds (gaps), an increased residual effect, an increased long-term effect, an increased speed of action, an extension of the application period and / or a reduction in the number of necessary individual applications and - as a result for the user - more economically and ecologically advantageous weed control systems.

[0543] Although the combinations according to the invention exhibit excellent herbicidal activity against monocotyledonous and dicotyledonous weeds, many economically important crops are only minimally affected or not affected at all, depending on the structure of the respective active ingredient combinations according to the invention and their application rate. Examples of economically important crops include dicotyledonous crops of the genera Arachis, Beta, Brassica, Cucumis, Cucurbita, Helianthus, and others. BYC240214- Abroad

[0544] 49

[0545] Daucus, Glycine, Gossypium, Ipomoea, Lactuca, Linum, Lycopersicon, Nicotiana, Phaseolus, Pisum, Solanum, Vicia, or monocot cultures of the genera Allium, Ananas, Asparagus, Avena, Hordeum, Oryza, Panicum, Saccharum, Secale, Sorghum, Triticale, Triticum and Zea.

[0546] Furthermore, the agents according to the invention exhibit, in some cases, excellent growth-regulating properties in cultivated plants. They exert a regulatory influence on the plant's own metabolism and can thus be used to selectively influence plant constituents and to facilitate harvesting, for example, by triggering desiccation and growth stunting. They are also suitable for the general control and inhibition of undesirable vegetative growth without killing the plants. Inhibition of vegetative growth plays a significant role in many monocot and dicotyledonous crops, as it can reduce or completely prevent storage.

[0547] Due to their herbicidal and plant growth-regulating properties, these agents can be used to control weeds in known plant crops or in tolerant crops yet to be developed, modified by conventional mutagenesis or genetic engineering. The transgenic plants are generally characterized by particularly advantageous properties, such as resistance to the agents according to the invention, for example, resistance to plant diseases or pathogens of plant diseases, such as certain insects or microorganisms like fungi, bacteria, or viruses. Other special properties relate, for example, to the harvested crop with regard to quantity, quality, storability, composition, and specific constituents. For instance, transgenic plants with increased starch content or altered starch quality, or those with a different fatty acid composition of the harvested crop, are known.Other special properties may include tolerance or resistance to abiotic stressors such as heat, cold, dryness, salt and ultraviolet radiation.

[0548] Preferably, the active ingredient combinations according to the invention can be used as herbicides in crops that are resistant to the phytotoxic effects of the herbicides or have been made resistant by genetic engineering.

[0549] Conventional methods for producing new plants with modified characteristics compared to existing plants include classical breeding techniques and the creation of mutants. Alternatively, new plants with altered characteristics can be produced using genetic engineering techniques (see, for example, EP-A-0221044, EP-A-0131624). Several cases have been described, for example, in BYC240214-Abroad.

[0550] 50

[0551] Genetic engineering of cultivated plants for the purpose of modifying the starch synthesized in the plants (e.g. WO 92 / 11376, WO 92 / 14827,

[0552] WO 91 / 19806),

[0553] transgenic crops that exhibit resistance to other herbicides, for example to sulfonylureas (EP-A-0257993, US-A-5013659),

[0554] transgenic crop plants, with the ability

[0555] to produce Bacillus thuringiensis toxins (Bt toxins), which the

[0556] Making plants resistant to certain pests (EP-A-0142924,

[0557] EP-A-0193259).

[0558] transgenic crops with modified fatty acid composition

[0559] (WO 91 / 13972).

[0560] Genetically modified crops with new ingredients or secondary metabolites, e.g., new phytoalexins that cause increased disease resistance (EPA 309862, EPA0464461); genetically modified plants with reduced photorespiration that have higher yields and higher stress tolerance (EPA 0305398).

[0561] Transgenic crops that produce pharmaceutically or diagnostically important proteins ("molecular pharming")

[0562] Transgenic crops that are characterized by higher yields or better quality; transgenic crops that are characterized by a combination of, for example, the aforementioned new traits ("gene stacking")

[0563] Numerous molecular biological techniques for producing new transgenic plants with altered properties are known in principle; see e.g. BI Potrykus and G.

[0564] Spangenberg (eds.) Gene Transfer to Plants, Springer Lab Manual (1995), Springer Verlag Berlin, Heidelberg, or Christou, "Trends in Plant Science" 1 (1996) 423-431).

[0565] For such genetic engineering manipulations, nucleic acid molecules can be introduced into plasmids, allowing mutagenesis or sequence modification through recombination of DNA sequences. Using standard procedures, for example, base exchanges can be performed, partial sequences removed, or natural or synthetic sequences added. Adaptors or linkers can be attached to the DNA fragments to join them together; see, for example, Sambrook et al., 1989, Molecular Cloning, A Laboratory Manual, 2nd ed. Cold Spring Harbor Laboratory Press, Cold Spring Harbor, NY; or Winnacker, "Genes and Clones", VCH Weinheim, 2nd ed., 1996.

[0566] The production of plant cells with reduced activity of a gene product can be achieved, for example, by expressing at least one corresponding antisense RNA, BYC240214- Abroad

[0567] 51

[0568] a sense RNA to achieve a cosuppression effect or the expression of at least one appropriately constructed ribozyme that specifically cleaves transcripts of the aforementioned gene product.

[0569] This can be achieved using either DNA molecules that comprise the entire coding sequence of a gene product, including any flanking sequences, or DNA molecules that comprise only parts of the coding sequence, provided these parts are long enough to produce an antisense effect in the cells. It is also possible to use DNA sequences that exhibit a high degree of homology to the coding sequences of a gene product, but are not completely identical.

[0570] During the expression of nucleic acid molecules in plants, the synthesized protein can be localized in any compartment of the plant cell. However, to achieve localization in a specific compartment, the coding region can be linked to DNA sequences that ensure localization in that compartment. Such sequences are known to those skilled in the art (see, for example, Braun et al., EMBO J. 11 (1992), 3219-3227; Wolter et al., Proc. Natl. Acad. Sci. USA 85 (1988), 846-850; Sonnewald et al., Plant J. 1 (1991), 95-106). The expression of nucleic acid molecules can also take place in the organelles of plant cells.

[0571] The transgenic plant cells can be regenerated into whole plants using established techniques. In principle, the transgenic plants can be of any plant species, i.e., both monocotyledonous and dicotyledonous plants. Thus, transgenic plants are available that exhibit altered traits through overexpression, suppression, or inhibition of homologous (natural) genes or gene sequences, or through the expression of heterologous (foreign) genes or gene sequences.

[0572] Preferably, the active ingredient combinations according to the invention can be used in transgenic cultures which are tolerant or have been made tolerant to the active ingredients used.

[0573] Preferably, the active ingredient combinations according to the invention can also be used in transgenic cultures that are resistant to growth regulators, such as dicamba, or to herbicides that inhibit essential plant enzymes, e.g., acetolactate synthases (ALS), EPSP synthases, glutamine synthases (GS), hydroxyphenylpyruvate dioxygenases (HPPD), or protoporphyrinogen oxidase (PPO), or to herbicides from the group of sulfonylureas, glyphosates, glufosinates, or benzoylisoxazoles and analogous active ingredients. BYC240214- Abroad

[0574] 52

[0575] The invention therefore also relates to a method for controlling unwanted plant growth, optionally in crop crops, preferably in non-cultivated land or in plantation crops, characterized in that one or more herbicides of type (A) are applied with one or more herbicides of type (B) to the harmful plants, plant parts or plant seeds (seed) thereof or the cultivation area.

[0576] The invention also relates to the use of the new combinations of compounds (A)+(B) for the control of pests, optionally in crop crops, preferably in non-crop land and plantation crops, but also for the control of pests before sowing the following crop, in particular for seed preparation ("burn-down application").

[0577] The active ingredient combinations according to the invention can be in the form of mixtures of the two components, optionally with further active ingredients, additives and / or conventional formulation aids, which are then applied in the usual way after being diluted with water, or as so-called tank mixtures produced by jointly diluting the separately formulated or partially separately formulated components with water.

[0578] Compounds (A) and (B) or combinations thereof can be formulated in various ways, depending on which biological and / or chemical-physical parameters are specified. General formulation options include, for example: sprayable powders (WP), water-soluble powders (SP), emulsifiable concentrates (EC), water-soluble concentrates, aqueous solutions (SE), emulsions (EW) such as oil-in-water and water-in-oil emulsions, sprayable solutions or emulsions, oil- or water-based dispersions, oil dispersions (OD), suspoemulsions, suspension concentrates (SC), oil-miscible solutions, capsule suspensions (CS), dusting agents (DP), pickling agents, granules for soil or broadcast application, granules (GR) in the form of micro-, spray-, lift- and adsorption granules, water-dispersible granules (WG), water-soluble granules (SG), ULV formulations, microcapsules or waxes.

[0579] The invention therefore also relates to herbicides and plant growth regulators which contain the active ingredient combinations according to the invention.

[0580] The individual formulation types are generally known and are described, for example, in: Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th ed. 1986; van Valkenburg, "Pesticides Formulations", Marcel Dekker NY, 1973; K. Martens, "Spray Drying Handbook", 3rd ed. 1979, G. Goodwin Ltd. London. BYC240214- Abroad

[0581] 53

[0582] The necessary formulation aids, such as inert materials, surfactants, solvents, and other additives, are also known and are described, for example, in: Watkins, "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Darland Books, Caldwell NJ; Hv Olphen, "Introduction to Clay Colloid Chemistry"; 2nd Ed., J. Wiley & Sons, NY; Marsden, "Solvents Guide", 2nd Ed., Interscience, NY 1963; McCutcheon's, "Detergents and Emulsifiers Annual", MC Publ. Corp., Ridegewood NJ; Sisley and Wood, "Encyclopedia of Surface Active Egents", Chem. Publ. Co. Inc., NY 1964; Schönfeldt, "Interfacially Active Ethylene Oxide Adducts", Wiss. Publishing company, Stuttgart 1976, Winnacker-Küchler, "Chemical Technology", Volume 7, C. Hanser Verlag Munich, 4th edition 1986.

[0583] Based on these formulations, combinations with other pesticidal substances, such as other herbicides, fungicides, insecticides or other pest control agents (e.g. acaricides, nematicides, molluscicides, rodenticides, aphicides, avicides, larvicides, ovicides, bactericides, virucides, etc.), as well as safeners, fertilizers and / or growth regulators can also be produced, e.g. in the form of a ready-made formulation or as a tank mix.

[0584] Spray powders are preparations that are uniformly dispersible in water and, in addition to the active ingredient, contain a diluent or inert substance as well as ionic and / or non-ionic surfactants (wetting agents, dispersants), e.g., polyoxyethylated alkylphenols, polyoxyethylated fatty alcohols, polyoxyethylated fatty amines, fatty alcohol polyglycol ether sulfates, alkanesulfonates, alkylbenzenesulfonates, sodium ligninsulfonic acid, 2,2'-dinaphthylmethane-6,6'-disulfonic acid sodium, sodium dibutylnaphthalenesulfonic acid, or sodium oleoylmethyltauric acid. To produce the spray powders, the herbicidal active ingredients are finely ground in conventional equipment such as hammer mills, blower mills, and air jet mills and mixed simultaneously or subsequently with the formulation aids.

[0585] Emulsifiable concentrates are produced by dissolving the active ingredient in an organic solvent, e.g., butanol, cyclohexanone, dimethylformamide, xylene, or even higher-boiling aromatics or hydrocarbons, or mixtures of organic solvents, with the addition of one or more ionic and / or non-ionic surfactants (emulsifiers). Examples of emulsifiers include: alkylarylsulfonic acid calcium salts such as calcium dodecylbenzenesulfonate, or non-ionic emulsifiers such as fatty acid polyglycol esters, alkylaryl polyglycol ethers, fatty alcohol polyglycol ethers, propylene oxide-ethylene oxide condensation products, alkyl polyethers, and sorbitan esters such as sorbitan fatty acid esters or polyoxyethylene sorbitan fatty acid esters. BYC240214- Abroad

[0586] 54

[0587] Dusting agents are obtained by grinding the active ingredient with finely divided solid substances, e.g. talc, natural clays such as kaolin, bentonite and pyrophyllite, or diatomaceous earth.

[0588] Suspension concentrates can be water- or oil-based. They can be produced, for example, by wet milling using commercially available bead mills and, if necessary, the addition of surfactants, such as those already listed above for the other formulation types.

[0589] Emulsions, e.g. oil-in-water emulsions (EW), can be produced, for example, using stirrers, colloid mills and / or static mixers, with aqueous organic solvents and, if necessary, surfactants, such as those already listed above for the other formulation types.

[0590] Granules can be produced either by atomizing the active ingredient onto adsorbable, granulated inert material or by applying active ingredient concentrates to the surface of carrier materials such as sand, kaolinite, or granulated inert material using adhesives, e.g., polyvinyl alcohol, sodium polyacrylate, or mineral oils. Alternatively, suitable active ingredients can be granulated in the manner customary for the production of fertilizer granules – optionally in mixture with fertilizers.

[0591] Water-dispersible granules are typically produced using processes such as spray drying, fluidized bed granulation, disc granulation, mixing with high-speed mixers, and extrusion without solid inert material.

[0592] The agrochemical preparations generally contain 0.1 to 99% by weight, in particular 0.2 to 95% by weight, active ingredients of types (A) and / or (B), with the following concentrations being typical depending on the formulation:

[0593] In sprayable powders, the active ingredient concentration is, for example, approximately 10 to 95 wt%, with the remainder to 100 wt% consisting of usual formulation components. In emulsifiable concentrates, the active ingredient concentration can be approximately 1 to 90 wt%, preferably 5 to 80 wt%.

[0594] Powder formulations typically contain 5 to 20 wt% of active ingredient, while sprayable solutions contain approximately 0.05 to 80 wt%, preferably 2 to 50 wt%, of active ingredient. For granules, such as dispersible granules, the active ingredient content depends in part on whether the active compound is liquid or solid and on the granulating agents and fillers used. Generally, the content of water-dispersible granules ranges from 1 to 95 wt%, preferably from 10 to 80 wt%.

[0595] In addition, the aforementioned active ingredient formulations may contain the usual adhesives, wetting agents, dispersants, emulsifiers, penetrating agents, preservatives, antifreeze agents, solvents, fillers, BYC240214- Abroad

[0596] 55

[0597] Dyes and carriers, defoamers, evaporation inhibitors and agents that affect pH or viscosity.

[0598] For application, the commercially available formulations are diluted in the usual manner, e.g., in the case of sprayable powders, emulsifiable concentrates, dispersions, and water-dispersible granules, with water. Powdery preparations, soil-applied or...

[0599] Granular coatings and sprayable solutions are usually not diluted with other inert substances before use.

[0600] The active ingredients can be applied to the plants, plant parts, plant seeds or the cultivated area (arable land), preferably to the green plants and plant parts and, if necessary, additionally to the arable land.

[0601] One application method is the combined application of the active ingredients in the form of tank mixtures, whereby the optimally formulated concentrated formulations of the individual active ingredients are mixed together with water in the tank and the resulting spray solution is applied.

[0602] A common herbicidal formulation of the combination of active ingredients (A) and (B) according to the invention has the advantage of easier application because the amounts of the components are already adjusted to the correct ratio to one another. Furthermore, the excipients in the formulation can be optimally matched to each other, whereas a tank mix of different formulations can result in undesirable combinations of excipients.

[0603] A. General examples of wording

[0604] a) A dusting agent is obtained by mixing 10 parts by weight (= parts by weight) of an active ingredient (A) or (B) or of a mixture of active ingredients (A) + (B) (and optionally further active ingredient components) and / or their salts and 90 parts by weight of talc as an inert material and grinding in a percussion mill.

[0605] b) A readily water-dispersible, wettable powder is obtained by mixing 25 parts by weight of an active ingredient / mixture of active ingredients, 64 parts by weight of kaolin-containing quartz as an inert material, 10 parts by weight of potassium ligninsulfonate, and 1 part by weight of sodium oleoylmethyltauric acid as a wetting and dispersing agent, and grinding in a pin mill. BYC240214- Abroad

[0606] 56

[0607] c) A dispersion concentrate that is easily dispersible in water is obtained by mixing 20 parts by weight of an active ingredient / active ingredient mixture with 6 parts by weight of alkylphenol polyglycol ether (©Triton X 207), 3 parts by weight of isotridecanol polyglycol ether (8 EO) and 71 parts by weight of paraffinic mineral oil (boiling range e.g. approx. 255 to 277 °C) and grinding in a friction ball mill to a fineness of less than 5 microns.

[0608] d) An emulsifiable concentrate is obtained from 15 parts by weight of an active ingredient / mixture of active ingredients, 75 parts by weight of cyclohexanone as solvent and 10 parts by weight of oxyethylated nonylphenol as emulsifier.

[0609] e) A water-dispersible granulate is obtained by

[0610] 75 parts by weight of an active ingredient / active ingredient mixture,

[0611] 10 parts by weight of calcium ligninsulfonate,

[0612] 5 parts by weight sodium lauryl sulfate,

[0613] 3 parts by weight of polyvinyl alcohol and

[0614] 7 parts by weight kaolin

[0615] mixes, grinds on a pin mill and granulates the powder in a fluidized bed by spraying on water as a granulating liquid.

[0616] f) A water-dispersible granulate is also obtained by

[0617] 25 parts by weight of an active ingredient / active ingredient mixture,

[0618] 5 parts by weight of 2,2'-dinaphthylmethane-6,6'-sodium disulfonate,

[0619] 2 parts by weight of sodium oleoylmethyltaurinate,

[0620] 1 part by weight polyvinyl alcohol,

[0621] 17 parts by weight calcium carbonate and

[0622] 50 parts by weight water

[0623] homogenized and pre-crushed on a colloid mill, then ground on a bead mill, and the resulting suspension is atomized and dried in a spray tower using a single-component nozzle.

[0624] B. Biological examples

[0625] When using the combinations according to the invention, herbicidal effects are frequently observed on a pest species that exceed the formal sum of the effects of the individual herbicides when applied alone. Alternatively, in some cases it can be observed that a lower application rate of the herbicide combination is required to achieve the same effect on a pest species compared to the individual preparations. Such BYC240214- Abroad

[0626] 57

[0627] Increases in impact or effectiveness, or savings in input quantity, are a strong indication of a synergistic effect.

[0628] If the observed effect values ​​already exceed the formal sum of the values ​​for the trials with individual applications, then they also exceed the expected value according to Colby, which is calculated using the following formula and is also considered an indication of synergism (cf. S.R. Colby; in Weeds 15 (1967) pp. 20 to 22):

[0629] E C = A+B - (A·B / 100)

[0630] This means:

[0631] A = Effect of the active ingredient (A) in % at an application rate of a [g ai / ha];

[0632] B = Effect of the active ingredient (B) in % at an application rate of b [g ai / ha];

[0633] E C = Expected effect of the combination (A)+(B) in % at the combined application rate a+b [g ai / ha].

[0634] The observed values ​​(E A ) of the experiments show, at suitable low doses, an effect of the combinations that exceeds the expected values ​​according to Colby (E C) lie (Δ).

[0635] Post-emergence weed control

[0636] Seeds of monocotyledonous and dicotyledonous weeds were sown in pots in sandy loam soil, covered with soil, and cultivated in a greenhouse under optimal growing conditions (temperature, humidity, water supply). Two to three weeks after sowing, the experimental plants, at the two- to four-leaf stage, were treated with the inventive agents. The inventive agents, formulated as spray powders or emulsion concentrates, were applied to the green parts of the plants in various dosages with a water volume equivalent to 300 l / ha. After 10 or 21 days of the experimental plants remaining in the greenhouse under optimal growing conditions, the effect of the preparations was visually assessed in comparison to untreated controls.

[0637] In these cases, effects of the combinations according to the invention were frequently observed that exceeded the formal sum of the effects of individual application of the herbicides.

[0638] 100% effectiveness means complete control of the weed being tested.

[0639] 0% efficacy means absolutely no control of the tested weed. BYC240214 - Abroad

[0640] 58

[0641] The compositions according to the invention, at suitable low dosages, show an effect of the combinations according to the invention on a wide variety of weeds Amaranthus palmeri (AMAPA or AMAPA_R = sensitive (AMAPA) or resistant (AMAPA_R) biotype), Avena fatua (AVEFA), Bidens pilosa (BIDPI), Centaurea cyanus (CENCY), Brachiaria platyphylla (BRAPP), Echinochloa crus-galli (ECHCG), Eleusinia indica (ELEIN), Kochia scoparia (KCHSC), Lolium rigidum (LOLRI), Pharbitis purpurea (PHBPU), Sorghum halepense (SORHA) that exceeds the expected values ​​according to Colby.

[0642] Evaluation 10 days after application:

[0643] Application rate Herbicide effect [%] against active ingredient

[0644] g ai / ha AMAPA 10 DAT

[0645] Al 0.0625 60

[0646] B22 0.25 20

[0647]

[0648] Al & B22 0.0625 + 0.25 88 (E = 68) A = 20

[0649] Application rate Herbicide effect [%] against active ingredient

[0650] g ai / ha AMAPA_R 10 DAT

[0651] Al 0.25 40

[0652] B31 0.3 0

[0653]

[0654] Al & B31 0.25 + 0.3 80 (E = 40) A = 40

[0655] Application rate Herbicide effect [%] against active ingredient

[0656] g ai / ha BIDPI 10 DAT

[0657] Al 0.0625 60

[0658] B6 0.25 20

[0659]

[0660] Al & B6 0.0625 + 0.25 75 (E = 68) A = 7

[0661] Application rate Herbicide effect [%] against active ingredient

[0662] g ai / ha BIDPI 10 DAT

[0663] Al 0.0625 60

[0664] B8 0.25 20

[0665]

[0666] Al & B8 0.0625 + 0.25 85 (E =68) Δ = 17

[0667] Application rate Herbicide effect [%] against active ingredient

[0668] g ai / ha BIDPI 10 DAT

[0669] Al 0.0625 60

[0670] B22 0.25 20

[0671]

[0672] Al & B22 0.0625 + 0.25 80 (E = 68) A = 12

[0673] Application rate Herbicide effect [%] against active ingredient

[0674] g ai / ha BRAPP 10 DAT

[0675] Al 0.25 30

[0676] B8 0.0625 0

[0677]

[0678] Al & B8 0.25 + 0.0625 40 (E = 30) Δ = 10 BYC240214- Abroad

[0679] 59

[0680] Application rate Herbicide effect [%] against active ingredient

[0681] g ai / ha ECHCG 10 DAT Al 0.25 20

[0682] 0.0625 10

[0683] B38 1.2 0

[0684] 0.3 0

[0685] Al & B38 0.25 + 1.2 30 (E = 20) Δ = 10 0.25 + 0.3 30 (E = 20) Δ = 10

[0686]

[0687] 0.0625 + 0.3 20 (E = 10) Δ = 10 Application rate Herbicide effect [%] against active ingredient

[0688] g ai / ha ECHCG 10 DAT Al 0.0625 10 B2 0.0625 0

[0689]

[0690] Al & B2 0.0625 + 0.0625 20 (E = 10) Δ = 10 Application rate Herbicide effect [%] against active ingredient

[0691] g ai / ha KCHSC 10 DAT Al 1 70 B2 0.25 20

[0692]

[0693] Al & B2 1.0 + 0.25 85 (E = 76) A = 9 Application rate Herbicide effect [%] against active ingredient

[0694] g ai / ha KCHSC 10 DAT Al 1 70 B6 0.25 10

[0695]

[0696] Al & B6 1.0 + 0.25 85 (E = 73) A = 12 Application rate Herbicide effect [%] against active ingredient

[0697] g ai / ha KCHSC 10 DAT Al 0.0625 30 B31 1.2 20

[0698]

[0699] Al & B31 0.0625 + 1.2 60 (E = 44) Δ = 16 Application rate Herbicide effect [%] against active ingredient

[0700] g ai / ha PHBPU 10 DAT Al 0.0625 70 B6 0.25 30

[0701]

[0702] Al & B6 0.0625 + 0.25 88 (E = 79) A = 9 Application rate Herbicide effect [%] against active ingredient

[0703] g ai / ha PHBPU 10 DAT Al 1 88

[0704] 0.25 85

[0705] B8 0.0625 10 Al & B8 1 + 0.0625 100 (E = 89) A = 11

[0706]

[0707] 0.25 + 0.0625 95 (E = 87) A = 8 BYC240214- Foreign

[0708] 60

[0709] Application rate Herbicide effect [%] against active ingredient

[0710] g ai / ha PHBPU 10 DAT Al 1 88 B31 1.2 0

[0711]

[0712] Al & B31 1.0 + 1.2 95 (E = 88) A = 7 Application rate Herbicide effect [%] against active ingredient

[0713] g ai / ha SORHA 10 DAT Al 1 40 B38 1.2 20

[0714]

[0715] Al & B38 1.0 + 1.2 60 (E = 52) A = 8 Application rate Herbicide effect [%] against active ingredient

[0716] g ai / ha SORHA 10 DAT Al 1 40 B31 0.3 0

[0717]

[0718] Al & B31 1.0 + 0.3 60 (E = 40) Δ = 20

[0719] Evaluation 21 days after application:

[0720] Application rate Herbicide effect [%] against active ingredient

[0721] g ai / ha AMAPA 21 DAT Al 0.0625 10 B2 0.25 20

[0722]

[0723] Al & B2 0.0625 + 0.25 40 (E = 28) Δ = 12

[0724] Application rate Herbicide effect [%] against active ingredient

[0725] g ai / ha AMAPA 21 DAT Al 0.0625 10 Bl 0.25 60

[0726]

[0727] Al & B1 0.0625 + 0.25 85 (E = 64) A = 21

[0728] Application rate Herbicide effect [%] against active ingredient

[0729] g ai / ha AMAPA 21 DAT Al 0.0625 10 B6 0.25 0

[0730]

[0731] Al & B6 0.0625 + 0.25 30 (E = 10) Δ = 20 BYC240214- Abroad

[0732] 61

[0733] Application rate Herbicide effect [%] against active ingredient

[0734] g ai / ha AMAPA 21 DAT Al 0.25 85

[0735] 0.0625 10

[0736] B8 0.25 0

[0737] Al & B8 0.25 + 0.25 100 (E = 85) Δ = 15

[0738]

[0739] 0.0625 + 0.25 30 (E = 10) Δ = 20

[0740] Application rate Herbicide effect [%] against active ingredient

[0741] g ai / ha AMAPA 21 DAT Al 0.0625 10 B31 1.2 0

[0742]

[0743] Al & B31 0.0625 + 1.2 30 (E = 10) Δ = 20

[0744] Application rate Herbicide effect [%] against active ingredient

[0745] g ai / ha AMAPA_R 21 DAT Al 1 60

[0746] 0.0625 10

[0747] B38 0.3 60

[0748] Al & B38 1 + 0.3 90 (E = 84) Δ = 6

[0749]

[0750] 0.0625 + 0.3 70 (E = 64) Δ = 6

[0751] Application rate Herbicide effect [%] against active ingredient

[0752] g ai / ha AMAPA_R 21 DAT Al 1 60

[0753] 0.25 20

[0754] 0.0625 10

[0755] B2 0.25 0

[0756] Al & B2 1 + 0.25 85 (E = 60) Δ = 25 0.25 + 0.25 50 (E = 20) Δ = 30

[0757]

[0758] 0.0625 + 0.25 20 (E = 10) Δ = 10

[0759] Application rate Herbicide effect [%] against active ingredient

[0760] g ai / ha AMAPA_R 21 DAT Al 0.0625 10 B6 0.0625 0

[0761]

[0762] Al & B6 0.0625 + 0.0625 20 (E = 10) Δ = 10

[0763] Application rate Herbicide effect [%] against active ingredient

[0764] g ai / ha AMAPA_R 21 DAT Al 0.25 20

[0765] 0.0625 10

[0766] B8 0.25 0

[0767] Al & B8 0.25 + 0.25 30 (E = 20) Δ = 10

[0768]

[0769] 0.0625 + 0.25 20 (E = 10) Δ = 10 BYC240214- Abroad

[0770] 62

[0771] Application rate Herbicide effect [%] against active ingredient

[0772] g ai / ha AMAPA_R 21 DAT Al 1 60

[0773] 0.25 20

[0774] 0.0625 10

[0775] B22 0.25 0

[0776] 0.0625 0

[0777] Al & B22 1 + 0.25 70 (E = 60) Δ = 10

[0778] 1 + 0.0625 88 (E = 60) Δ = 28 0.25 + 0.0625 60 (E = 20) Δ = 40

[0779]

[0780] 0.0625 + 0.0625 30 (E = 10) Δ = 20

[0781] Application rate Herbicide effect [%] against active ingredient

[0782] g ai / ha AMAPA_R 21 DAT Al 0.25 20

[0783] 0.0625 10

[0784] B31 1.2 0

[0785] 0.3 0

[0786] Al & B31 0.25 + 1.2 60 (E = 20) Δ = 40 0.0625 + 1.2 60 (E = 10) Δ = 50

[0787]

[0788] 0.0625 + 0.3 20 (E = 10) Δ = 10

[0789] Application rate Herbicide effect [%] against active ingredient

[0790] g ai / ha AVEFA 21 DAT Al 0.25 0

[0791] B6 0.0625 0

[0792]

[0793] Al & B6 0.0625 + 0.25 10 (E = 0) Δ = 10

[0794] Application rate Herbicide effect [%] against active ingredient

[0795] g ai / ha BIDPI 21 DAT Al 0.0625 20 B2 0.25 20

[0796]

[0797] Al & B2 0.0625 + 0.25 60 (E = 36) Δ = 24

[0798] Application rate Herbicide effect [%] against active ingredient

[0799] g ai / ha BIDPI 21 DAT Al 0.25 85 B8 0.25 0

[0800]

[0801] Al & B8 0.25 + 0.25 95 (E = 85) Δ = 10 BYC240214- Abroad

[0802] 63

[0803] Application rate Herbicide effect [%] against active ingredient

[0804] g ai / ha BIDPI 21 DAT Al 0.25 85 B31 1.2 0

[0805]

[0806] Al & B31 0.25 + 1.2 98 (E = 85) Δ = 13

[0807] Application rate Herbicide effect [%] against active ingredient

[0808] g ai / ha BRAPP 21 DAT Al 1 30 B38 1.2 10

[0809]

[0810] Al & B38 1 + 1.2 70 (E = 37) Δ = 33

[0811] Application rate Herbicide effect [%] against active ingredient

[0812] g ai / ha BRAPP 21 DAT Al 1 30 B2 0.0625 0

[0813]

[0814] Al & B2 1 + 0.25 40 (E = 30) Δ = 10

[0815] Application rate Herbicide effect [%] against active ingredient

[0816] g ai / ha BRAPP 21 DAT Al 1 30 B1 0.25 20

[0817]

[0818] Al & B1 1 + 0.25 50 (E = 44) Δ = 6

[0819] Application rate Herbicide effect [%] against active ingredient

[0820] g ai / ha BRAPP 21 DAT Al 1 30 B31 0.3 0

[0821]

[0822] Al & B31 1 + 0.3 50 (E = 30) Δ = 20

[0823] Application rate Herbicide effect [%] against active ingredient

[0824] g ai / ha CENCY 21 DAT Al 0.25 20

[0825] 0.0625 0

[0826] B2 0.25 10

[0827] 0.0625 0

[0828] Al & B2 0.25 + 0.25 40 (E = 28) Δ = 12 0.0625 + 0.25 20 (E = 10) Δ = 10

[0829]

[0830] 0.0625 + 0.0625 10 (E = 0) Δ = 10 BYC240214- Abroad

[0831] 64

[0832] Application rate Herbicide effect [%] against active ingredient

[0833] g ai / ha CENCY 21 DAT Al 0.0625 0

[0834] B1 0.0625 0

[0835]

[0836] Al & B1 0.0625 + 0.0625 10 (E = 0) Δ = 10

[0837] Application rate Herbicide effect [%] against active ingredient

[0838] g ai / ha CENCY 21 DAT Al 0.0625 0

[0839] B8 0.25 0

[0840] 0.0625 0

[0841] Al & B8 0.0625 + 0.25 10 (E = 0) Δ = 10

[0842]

[0843] 0.0625 + 0.0625 10 (E = 0) Δ = 10

[0844] Application rate Herbicide effect [%] against active ingredient

[0845] g ai / ha CENCY 21 DAT Al 0.0625 0

[0846] B22 0.0625 0

[0847]

[0848] Al & B22 0.0625 + 0.0625 10 (E = 0) Δ = 10

[0849] Application rate Herbicide effect [%] against active ingredient

[0850] g ai / ha CENCY 21 DAT Al 0.25 20

[0851] 0.0625 0

[0852] B31 1.2 0

[0853] 0.3 0

[0854] Al & B31 0.25 + 1.2 60 (E = 20) Δ = 40 0.0625 + 1.2 20 (E = 0) Δ = 20 0.25 + 0.3 30 (E = 20) Δ = 10

[0855]

[0856] 0.0625 + 0.3 20 (E = 0) Δ = 20

[0857] Application rate Herbicide effect [%] against active ingredient

[0858] g ai / ha ECHCG 21 DAT Al 1 40

[0859] 0.0625 0

[0860] B38 1.2 0

[0861] Al & B38 1 + 1.2 60 (E = 40) Δ = 20

[0862]

[0863] 0.0625 + 1.2 10 (E = 0) Δ = 10

[0864] Application rate Herbicide effect [%] against active ingredient

[0865] g ai / ha ECHCG 21 DAT Al 1 40 B31 0.3 0

[0866]

[0867] Al & B31 1 + 0.3 50 (E = 40) Δ = 10 BYC240214- Abroad

[0868] 65

[0869] Application rate Herbicide effect [%] against active ingredient

[0870] g ai / ha KCHSC 21 DAT Al 1 70 B22 0.25 0

[0871]

[0872] Al & B22 1 + 0.25 80 (E = 70) Δ = 10

[0873] Application rate Herbicide effect [%] against active ingredient

[0874] g ai / ha LOLRI 21 DAT Al 0.25 0

[0875] B38 1.2 0

[0876]

[0877] Al & B38 0.25 + 1.2 10 (E = 0) Δ = 10

[0878] Application rate Herbicide effect [%] against active ingredient

[0879] g ai / ha LOLRI 21 DAT Al 1 10 B2 0.25 0

[0880]

[0881] Al & B2 1 + 0.25 20 (E = 10) Δ = 10

[0882] Application rate Herbicide effect [%] against active ingredient

[0883] g ai / ha LOLRI 21 DAT Al 0.25 0

[0884] B1 0.0625 0

[0885]

[0886] Al & B1 0.0625 + 0.25 10 (E = 0) Δ = 10

[0887] Application rate Herbicide effect [%] against active ingredient

[0888] g ai / ha LOLRI 21 DAT Al 1 10 B8 0.0625 0

[0889]

[0890] Al & B8 1 + 0.0625 20 (E = 10) Δ = 10

[0891] Application rate Herbicide effect [%] against active ingredient

[0892] g ai / ha LOLRI 21 DAT Al 1 10 B22 0.0625 0

[0893]

[0894] Al & B22 1 + 0.0625 20 (E = 10) Δ = 10

[0895] Application rate Herbicide effect [%] against active ingredient

[0896] g ai / ha PHBPU 21 DAT Al 0.0625 30 B38 0.3 10

[0897]

[0898] Al & B38 0.0625 + 0.3 70 (E = 37) Δ = 33 BYC240214- Abroad

[0899] 66

[0900] Application rate Herbicide effect [%] against active ingredient

[0901] g ai / ha PHBPU 21 DAT Al 0.25 60

[0902] 0.0625 30

[0903] B2 0.25 10 Al & B2 0.25 + 0.25 88 (E = 64) Δ = 24

[0904]

[0905] 0.0625 + 0.25 70 (E = 37) Δ = 33

[0906] Application rate Herbicide effect [%] against active ingredient

[0907] g ai / ha PHBPU 21 DAT Al 0.0625 30 B1 0.0625 30

[0908]

[0909] Al & B1 0.0625 + 0.0625 60 (E = 51) Δ = 9

[0910] Application rate Herbicide effect [%] against active ingredient

[0911] g ai / ha PHBPU 21 DAT Al 0.0625 30 B6 0.0625 10

[0912]

[0913] Al & B6 0.0625 + 0.0625 80 (E = 37) Δ = 43

[0914] Application rate Herbicide effect [%] against active ingredient

[0915] g ai / ha PHBPU 21 DAT Al 1 80

[0916] 0.0625 30

[0917] B8 0.25 0

[0918] 0.0625 0

[0919] Al & B8 0.0625 + 0.25 40 (E = 30) Δ = 10

[0920] 1 + 0.0625 100 (E = 90) Δ = 20

[0921]

[0922] 0.0625 + 0.0625 60 (E = 30) Δ = 30

[0923] Application rate Herbicide effect [%] against active ingredient

[0924] g ai / ha PHBPU 21 DAT Al 0.25 60

[0925] 0.0625 30

[0926] B8 0.0625 20 Al & B22 0.25 + 0.0625 85 (E =68) Δ = 17

[0927]

[0928] 0.0625 + 0.0625 60 (E = 44) Δ = 16

[0929] Application rate Herbicide effect [%] against active ingredient

[0930] g ai / ha PHBPU 21 DAT Al 0.25 60

[0931] 0.0625 30

[0932] B31 0.3 0

[0933] Al & B31 0.25 + 0.3 95 (E = 60) Δ = 35

[0934]

[0935] 0.0625 + 0.3 40 (E = 30) Δ = 10 BYC240214- Abroad

[0936] 67

[0937] Application rate Herbicide effect [%] against active ingredient

[0938] g ai / ha SORHA 21 DAT Al 1 30 B38 1.2 10

[0939]

[0940] Al & B38 1 + 1.2 70 (E = 37) Δ = 33

[0941] Application rate Herbicide effect [%] against active ingredient

[0942] g ai / ha SORHA 21 DAT Al 1 30 B22 0.25 0

[0943] 0.0625 0

[0944] Al & B22 1 + 0.25 40 (E = 30) Δ = 10

[0945]

[0946] 1 + 0.0625 50 (E = 30) Δ = 20

[0947] Application rate Herbicide effect [%] against active ingredient

[0948] g ai / ha SORHA 21 DAT Al 1 30 B31 1.2 0

[0949] 0.3 0

[0950] Al & B31 1 + 1.2 40 (E = 30) Δ = 10

[0951]

[0952] 1 + 0.3 80 (E = 30) Δ = 50

Claims

BYC240214- Abroad 68 Patent claims 1. Composition comprising compounds (A) and (B), wherein (A) represents one or more compounds of the general formula (I) or their agrochemically compatible salts, wherein R 1für Wasserstoff, Fluor, Chlor, Brom, Iod, Cyano, Methyl, Ethyl, Prop-1-yl, 1- Methylethyl, But-1-yl, 1-Methylpropyl, 2-Methylpropyl, 1,1 -Dimethylethyl, n-Pentyl, 1- Methylbutyl, 2-Methylbutyl, 3-Methylbutyl, 1,1 -Dimethylpropyl, 1,2-Dimethylpropyl, 2.2-Dimethylpropyl, 1 -Ethylpropyl, n-Hexyl, 1 -Methylpentyl, 2-Methylpentyl, 3- Methylpentyl, 4-Methylpentyl, 1,1 -Dimethylbutyl, 1,2-Dimethylbutyl, 1,3-Di- methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3-Dimethylbutyl, 1-Ethylbutyl, 2- Ethylbutyl, 1,1,2-Trimethylpropyl, 1,2,2-Trimethylpropyl, 1 -Ethyl- 1 -methylpropyl, 1- Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2.2.2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2- yloxy, 2-Methylprop-1-yloxy, 1,1-Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy, 2,2-Difluorethoxy, 2,2,2-Trifluorethoxy steht, R 2stands for hydrogen, fluorine, chlorine, bromine, methyl, trifluoromethyl, methoxy, ethoxy, prop-1-yloxy, but-1-yloxy, R 3 represents hydrogen, fluorine, chlorine, bromine, methoxy, ethoxy, prop-1-yloxy, prop-2-yloxy, but-1-yloxy, but-2-yloxy, 2-methylprop-l-yloxy, 1,1-dimethyleth-l-yloxy, R 4 represents fluorine, chlorine, bromine, cyano, NO2, C(O)NH2, C(S)NH2, trifluoromethyl, difluoromethyl, pentafluoroethyl, ethynyl, propyn-1-yl, 1-butyn-1-yl, pentyn-1-yl, hexyn-l-yl, BYC240214- Abroad 69 R 5 , R 6 and R 7unabhängig voneinander für Wasserstoff, Fluor, Chlor, Brom, Iod, Cyano, Methyl, Ethyl, Prop-l-yl, 1 -Methylethyl, But-1-yl, 1-Methylpropyl, 2-Methylpropyl, 1.1 -Dimethylethyl, n-Pentyl, 1 -Methylbutyl, 2-Methylbutyl, 3-Methylbutyl, 1,1- Dimethylpropyl, 1,2-Dimethylpropyl, 2,2-Dimethylpropyl, 1 -Ethylpropyl, n-Hexyl, 1- Methylpentyl, 2-Methylpentyl, 3-Methylpentyl, 4-Methylpentyl, 1,1 -Dimethylbutyl, 1.2-Dimethylbutyl, 1,3-Di-methylbutyl, 2,2-Dimethylbutyl, 2,3-Dimethylbutyl, 3,3- Dimethylbutyl, 1 -Ethylbutyl, 2-Ethylbutyl, 1, 1,2-Trimethylpropyl, 1,2,2- Trimethylpropyl, 1 -Ethyl- 1 -methylpropyl, 1-Ethyl-2-methylpropyl, Trifluormethyl, Difluormethyl, Pentafluorethyl, 2,2-Difluorethyl, 2,2,2-Trifluorethyl, Methoxy, Ethoxy, Prop-1-yloxy, Prop-2-yloxy, But-1-yloxy, But-2-yloxy, 2-Methylprop-l-yloxy, 1,1- Dimethyleth-1-yloxy, Difluormethoxy, Trifluormethoxy, Pentafluorethoxy, 2.2-Difluorethoxy, 2,2,2-Trifluorethoxy stehen, G für Methylen, (Methyl)methylen, (Ethyl)methylen, (Prop-1-yl)methylen, (Prop-2- yl)methylen, (But-1-yl)methylen, (But-2-yl)methylen, (Pent-1-yl)methylen, (Pent-2- yl)methylen, (Pent-3-yl)methylen, (Dimethyl)methylen, (Diethyl)methylen, Ethylen, n- Propylen, (l-Methyl)ethyl-l-en, (2-Methyl)ethyl-l-en, n-Butylen, 1 -Methylpropyl- 1 -en, 2-Methylpropyl- 1 -en, 3-Methylpropyl-l-en, 1,1 -Dimethylethyl- 1 -en, 2,2-Dimethylethyl- 1-en, 1 -Ethylethyl- 1 -en, 2-Ethylethyl-l-en, 1-(Prop-1-yl)ethyl-1-en, 2-(Prop-1-yl)ethyl- 1-en, l-(Prop-2-yl)ethyl-l-en, 2-(Prop-2-yl)ethyl-l-en, 1,1,2-Trimethylethyl-l-en, 1,2,2- Trimethylethyl-1-en, 1,1,2,2-Tetramethylethyl-1-en, n-Pentylen, 1-Methylbutyl-1-en, 2- Methylbutyl-1-en, 3-Methylbutyl-1-en, 4-Methylbutyl-1-en, 1,1-Dimethylpropyl-1-en, 2,2-Dimethylpropyl-1-en, 3,3-Dimethylpropyl-1-en, 1,2-Dimethylpropyl-1-en, 1,3- Dimethylpropyl-1-en, 1-Ethylpropyl-1-en, n-Hexylen, 1-Methylpentyl-1-en, 2- Methylpentyl-1-en, 3-Methylpentyl-1-en, 4-Methylpentyl-1-en, 1,1-Dimethylbutyl-1-ene, 1,2-Dimethylbutyl-1-ene, 1,3-Dimethylbutyl-1-ene, 2,2-Dimethylbutyl-1-ene, 2,3-Dimethylbutyl-1-ene, 3,3-Dimethylbutyl-1-ene, 1-Ethylbutyl-1-ene, 2-Ethylbutyl-1-ene, 1,1,2-trimethylpropyl-1-ene, 1,2,2-trimethylpropyl-1-ene, 1-ethyl-1-methylpropyl-1-ene, 1-ethyl-2-methylpropyl-1-ene, X and Y independently represent O (oxygen) or S (sulfur). and Q represents one of the following specifically named groupings Q1 to Q-25, where in the structural formulas of the following table the arrow represents a bond of the respective group Q to the carbonyl group in the general formula (I): BYC240214- Abroad 10 (B) for one or more connections selected from (B1) to (B40) contains, in which BYC240214- Abroad 71 (B) Struktur Name CAS-RN Bl Ethyl-{[3-({3-chlor-5-fluor-6-[3-methyl-2,6- 2158274-56-5 dioxo-4-(trifluormethyl)-3,6-dihydropyrimidin- 1 (2H)-yl]pyridin-2-yl} oxy)pyridin-2- yl]oxy}acetat B2 Ethyl- [2-( { 3 -chlor-5 -fluor-6- [3 -methyl-2, 6-dioxo- 2158274-50-9 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl] pyridin-2-yl} oxy)phenoxy ] acetat B3 2-Ethoxy-2-oxoethyl- 1 - { 2-chlor-4-fluor-5-[3- methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin- 1 (2H) - yl] phenoxy} cyclopropancarboxylat B4 { [( 1- { 2-Chlor-4-fluor-5- [3 -methyl-2, 6-dioxo-4- 434334-78-8 (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl] phenoxy} cyclopropyl)carbonyl] - oxy}essigsäure B5 1 -Ethoxy- 1 -oxopropan-2-yl- 1 - { 2-chlor-4-fluor-5 - 3017139-36-2 [3-methyl-2,6-dioxo-4-(trifluormethyl)-3,6- dihydropyrimidin- 1 (2H) - yl] phenoxy} cyclopropan-carboxylat B6 Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-12-7 (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat B7 Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-14-9 (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat B8 Ethyl-3-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 2669815-00-1 X VÄ W> < sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenyl] - 3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat BYC240214- Ausland 72 B9 l-(3-Chlor-4,5,6,7-tetrahydropyrazolo[l,5- 1651191-47-7 a]pyridin-2-yl)-5-[(cyclopropylmethyl)amino]- lH-pyrazol-4-carbonitril BIO Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 1949837-18-6 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl] phenyl} -5 -methyl-4,5 -dihydro- 1,2-oxazol-5 - carboxylat Bll Ethyl-3-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 2558200-05-6 sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenyl] - 5-methyl-4,5-dihydro-l,2-oxazol-5-carboxylat B12 3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 3000495-74-6 A (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carbonsäure B13 Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 2669821-71-8 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-6-methyl-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat B14 3-{2-Chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- 2669819-11-6 (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carbonsäure B15 Methyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo- 2669819-07-0 4-(trifluormethyl)-3,6-dihydropyrimidin-l(2H)- yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat B16 (S)-Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6- 2641255-87-8 dioxo-4-(tifluormethyl)-3,6-dihydropyrimidin- 1 (2H)-yl]phenyl} -5-methyl-4,5-dihydro- 1,2- oxazol-5 -carboxylat B17 (R) -Ethyl-3 - { 2-chlor-4-fluor-5 - [3 -methyl-2, 6- 2763291-38-7 dioxo-4-(trifluormethyl)-3,6-dihydropyrimidin- 1 (2H)-yl]phenyl} -5-methyl-4,5-dihydro- 1,2- oxazol-5 -carboxylat BYC240214- Ausland 73 B18 xXX Ethyl-{[3-({3-chlor-6-[4-(l,l-difluorethyl)-3- X- XX methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -5 -fluorpyridin-2-yl} oxy)pyridin-2- yl]oxy}acetat B19 1» { [3-({ 3-Chlor-6-[4-(l, l-difluorethyl)-3-methyl- 2,6-dioxo-3,6-dihydropyrimidin- 1 (2H)-yl] -5- fluorpyridin-2-yl} oxy)pyridin-2- yl]oxy}essigsäure B20 Ethyl- [2-( { 3-chlor-6- [4-( 1, 1 -difluorethyl)-3- methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -5 -fluorpyridin-2-yl} oxy)phenoxy ] acetat B21 [2-({ 3-Chlor-6-[4-(l, l-difluorethyl)-3-methyl-2,6- ■ X dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -5 - fluorpyridin-2-yl}oxy)phenoxy]essigsäure B22 Ethyl-[(3- { 2-chlor-5-[4-(l, 1 -difluorethyl)-3- 2892260-46-5 X- XX methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -4-fluorphenoxy} pyridin-2-yl)oxy ] acetat B23 x° X [(3-{2-Chlor-5-[4-(l,l-difluorethyl)-3-methyl-2,6- 2892260-49-8 jJ Qk Q< AX ° ö 'jjy - dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -4- fluorphenoxy}pyridin-2-yl)oxy]essigsäure B24 x XX Ethyl-(2- { 2-chlor-5 - [4-( 1, 1 -difluorethyl) -3 - 2892260-47-6 X XX methyl-2,6-dioxo-3,6-dihydropyrimidin-l(2H)- yl] -4-fluorphenoxy}phenoxy)acetat B25 (2- { 2-Chlor-5-[4-( 1, 1 -difluorethyl)-3-methyl-2,6- 2892260-48-7 dioxo-3, 6-dihydropyrimidin- 1 (2H) -yl] -4- X- X Jk fluorphenoxy}phenoxy)essigsäure B26 2-Ethoxy-2-oxoethyl- 1 - [2-chlor-5 -(3,5 -dimethyl- 3024787-37-6 2,6-dioxo-4-sulfanyliden- 1,3,5-triazinan- 1 -yl)-4- fluorphenoxy]cyclopropancarboxylat B27 [({ l-[2-Chlor-5-(3,5-dimethyl-2,6-dioxo-4- 3024787-49-0 jXGyX sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenoxy] cyclopropyl} carbonyl)oxy]essigsäure 1 - [2-Chlor-5-(3,5-dimethyl-2,6-dioxo-4- B28 3024787-36-5 sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4- fluorphenoxy]cyclopropancarbonsäure BYC240214- Ausland 74 B29 1 -Ethoxy- 1 -oxopropan-2-yl- 1 - [2-chlor-5 -(3,5 - 3024787-56-9 dimethyl-2,6-dioxo-4-sulfanyliden- 1,3,5- triazinan-l-yl)-4- fluorphenoxy]cyclopropancarboxylat B30 Methyl-l-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- 3024787-35-4 sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4- fluorphenoxy]cyclopropancarboxylat B31 (Tetrahydrofuran-2-yl)methyl (2R)-2-[(4-amino- 2445983-82-2 3,5-dichlor-6-fluor-2-pyridyl)oxy]propanoat B32 N (Tetrahydrofuran-2-yl)methyl (2S)-2-[(4-amino- CI J^ CI 3,5-dichlor-6-fluor-2-pyridyl)oxy]propanoat o B33 (Tetrahydrofuran-2-yl)methyl (2R / S)-2-[(4- 2374902-16-4 amino-3,5-dichlor-6-fluor-2- pyridyl)oxy]propanoat B34 N (2R)-2-[(4-Amino-3,5-dichlor-6-fluor-2- 2445980-81-2 o o R R ^ ^ >o°= JL issnss / «cc = o pyridyl)oxy]propansäure o o ö ö O B35 N (2S)-2-[(4-Amino-3,5-dichlor-6-fluor-2- O O U- U-. U V pyridyl)oxy]propansäure 0 B36 N Ck l CI 2- [(4- Amino-3,5-dichlor-6-fluor-2- 50848-50-5 F X - NX^O J^UYo pyridyl)oxy]propansäure B37 Cyanomethyl 4-amino-3-chloro-5-fluoro-6-(7- 2251111-18-7 fluor- 1 H-indol-6-yl)pyridin-2-carboxylat B38 €OVXJ^ Prop-l-in-3-yl 4-amino-3-chloro-5-fluoro-6-(7- 2251111-17-6 fluor- 1 H-indol-6-yl)pyridin-2-carboxylat B39 Ethyl-3-{2-chlor-4-fluor-5-[3-methyl-2,6-dioxo-4- (trifluormethyl)-3,6-dihydropyrimidin-l(2H)- U 1 V X-"'^ 0 yl]phenyl}-3a,4,5,6-tetrahydro-6aH- cyclopenta[d] [ 1,2]oxazol-6a-carboxylat BYC240214- Ausland B40 Ethyl-3-[2-chlor-5-(3,5-dimethyl-2,6-dioxo-4- sulfanyliden- 1,3,5 -triazinan- 1 -yl) -4-fluorphenyl] - 5-ethyl-4,5-dihydro-l,2-oxazol-5-carboxylat 2. Composition according to claim 1, wherein (A) is selected from compounds of the formula wherein R 1 stands for hydrogen R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine, bromine, cyano, NO2 R 5 stands for hydrogen R 6 stands for hydrogen, fluorine, chlorine, bromine or cyano, R 7 stands for hydrogen G stands for methylene or (methyl)methylene, X stands for O (oxygen) or S (sulfur), Y stands for O (oxygen), BYC240214- Abroad and Q represents one of the groupings Q1 to Q-25 mentioned in claim 1.

3. The compound according to claim 1, wherein (A) is selected from compounds of formula (I), wherein R 1 stands for hydrogen R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine, bromine, cyano R 5 stands for hydrogen R 6 hydrogen, fluorine stands for, R 7 stands for hydrogen G stands for methylene X stands for O (oxygen), Y stands for O (oxygen). and Q represents one of the groupings Q1, Q2, Q4, Q5, Q6, Q7, Q8, Q9, Q10, Q12, Q13, Q14, Q15, Q16, Q18 or Q19 mentioned in claim 1. BYC240214- Abroad 77 4. Composition according to claim 3, wherein R 1 stands for hydrogen R 2 stands for fluorine, R 3 stands for fluorine, R 4 stands for chlorine R 5 stands for hydrogen R 6 stands for hydrogen R 7 stands for hydrogen G stands for methylene X stands for O (oxygen), Y stands for O (oxygen). and Q stands for the group Ql mentioned in claim 1.

5. Composition according to any one of claims 1 to 4, wherein the compounds (A) and (B) are contained in a weight ratio of 1:100000 to 3000:1, preferably 1500:1 to 1:4200, more preferably 600:1 to 1:

400.

6. Composition according to any one of claims 1 to 5, wherein one or more further components from the group containing plant protection active substances of a different type are included; and / or one or more additives commonly used in plant protection are included. BYC240214- Abroad 78 7. Method for controlling pests or regulating plant growth, wherein the compounds of the composition according to any one of claims 1 to 6 are applied to the plants, plant parts, plant seeds or the cultivation area.

8. Method according to claim 7, wherein the compounds of the herbicidal composition are applied together or separately pre-emergence, post-emergence or pre- and post-emergence to the plants, plant parts, plant seeds or the growing area.

9. Method according to claim 8, wherein the compound (A) is applied in an application rate of 0.02 to 250 g ai / ha; and / or wherein the compound (B) is applied in an application rate of 0.01 to 500 g ai / ha.

10. Method according to any one of claims 7 to 9 for controlling harmful plants by treatment before sowing of the crops and in plantation crops, as well as non-crop land.

11. Method according to any one of claims 7 to 10, wherein the compounds of the composition are applied in the form of a herbicidal agent containing one or more additives commonly used in plant protection, optionally after dilution with water.

12. Use of the composition according to any one of claims 1 to 6 for controlling pest plants or for regulating plant growth.

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