Compound used for forming high-molecular compound

By using polymer compounds and electron-accepting compounds with specific structural units in organic thin film solar cells, combined with solvents to form a composition, the problem of low photoelectric conversion efficiency in the existing technology is solved and efficient photoelectric conversion performance is achieved.

CN105601662AInactive Publication Date: 2016-05-25SUMITOMO CHEM CO LTD
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Patent Information

Application Number
CN201510737645.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Priority Date
2010-07-14
Filing Date
2010-10-29
Publication Date
2016-05-25
Estimated Expiration
Not applicable · inactive patent

AI Technical Summary

Technical Problem

The short-circuit current density and photoelectric conversion efficiency of polymer compounds used in existing organic thin film solar cells may not be sufficient, making it difficult to meet the demand for efficient photoelectric conversion.

Method used

Provided is a polymer compound with specific structural units, including the structural unit represented by formula (1), used to manufacture efficient photoelectric conversion element films, and combines an electron-accepting compound and a solvent to form a composition to improve photoelectric conversion performance.

Benefits of technology

By using photoelectric conversion elements made of these polymer compounds, the short-circuit current density and photoelectric conversion efficiency are significantly improved, and the photoelectric conversion performance is significantly improved.

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Abstract

The present invention provides a macromolecular compound by which the short-circuit current density and the photoelectric conversion efficiency are enhanced when the macromolecular compound is used in an organic layer contained in a photovoltaic cell. Specifically, the present invention provides a macromolecular compound having a structural unit represented by Formula (5): wherein R52 and R53 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl groups, alkyl oxygen radicals, alkyl sulfonium, aryl groups, aryl oxygen radicals, aryl sulfonium, aryl alkyl, aryl alkyl oxygen radicals, acyl groups, acyloxy, acylamino, imide groups, amidogen, substituted amino, substituted silicyl, substituted silicon alkyl oxygen radicals, substituted silicon alkyl harvard, silicon alkyl amine, univalent heterocyclic radical, heterocyclic oxygen radicals, heterocyclic sulfonium, aryl alkenyl, aryl alkynyl, carboxyl or cyan; W1 and W2 are the same as or different from each other and represent hydrogen atoms, halogen atoms, alkyl sulfonate base, aryl sulfonic acid ester base, aryl alkyl sulfonate base, boric acid ester residues, matte methyl, scales base, Phosphonic acid ester methyl, single halogenated methyl, boric acid residues, formyl groups, vinyl or organic tin residues.
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