Preparation method and application method of pure natural demulsification particles

Abstract

The application discloses a kind of pure natural demulsification granules preparation method and its application method, comprising the following steps: selecting dry lotus, the lotus is segmented, the segmented lotus is sent into pulverizer and broken into powder, the final powder is screened by screen mesh, the raw material of powder passing through screen mesh is obtained, lotus powder is obtained, finally lotus powder is placed in oven and dried, it is demulsification granule, the method utilizes the composition characteristics of dry lotus powder with oil-water amphiphilic, the hydrophobic part of lotus can be combined with the oil-loving group in surfactant, thereby causing the rupture of emulsion interface, so that oil droplets in rolling oil emulsion cannot be stably dispersed in water phase, the balance of oil phase and water phase in emulsion is destroyed, and finally the effect of demulsification is achieved, and after demulsification is completed, the property of plant granule is not easy to change, even if oscillation, it is also not easy to emulsify again, and the use time of the whole demulsification is shorter, and the solution is stable.

Description

Technical Field

[0001] This invention relates to the field of demulsification of rolling oil, and in particular to a method for preparing pure natural demulsifying particles and its application. Background Technology

[0002] The basic components of rolling oil are: base lubricating oil, lubricating additives, emulsifiers, carbon removal additives, and corrosion inhibitors / pH corrosion inhibitors. The volume ratio of the oil phase to the water phase in the rolling oil emulsion used in this paper is 2:98. After mixing, the emulsion is uniformly mixed in an ultrasonic water bath to form a stable emulsion. This type of emulsion can be formed by directly adding the rolling oil to water at room temperature, with a stability index (ESI) above 0.6. The particle size of the prepared emulsion is between 1 and 1.5 micrometers, with a small portion reaching 5 micrometers. The stable emulsion has good annealing and cleaning properties and can be annealed directly without washing. Currently, the domestic methods for treating rolling oil emulsions after use are basically chemical methods and physical filtration to separate the oil phase and water phase for further processing.

[0003] Since the stability of rolling oil emulsion is affected by a large number of surfactants, and based on previous experiments, it has been known that the surfactants in the rolling oil are nonionic surfactants. In order to demulsify the rolling oil emulsion, the existing technology usually adopts the method of purchasing chemical reagents. However, chemical reagents often need to be purchased in large quantities, which is costly. In order to reduce costs and increase efficiency, a new type of demulsifying agent is needed to reduce the procurement costs of enterprises.

[0004] To address these issues, we propose a method for preparing and applying purely natural demulsifying granules. Summary of the Invention

[0005] The purpose of this invention is to provide a method for preparing pure natural demulsifying particles and its application method, in order to solve the problem mentioned in the background art that the chemical reagents used for demulsification are one of the products that need to be purchased in the demulsification environment, which leads to an increase in the demulsification cost for enterprises. The technical solution of this invention provides a solution that is significantly different from the existing technology, which addresses the problem that the existing technical solutions are too simplistic.

[0006] To achieve the above objectives, the present invention provides the following technical solution:

[0007] A method for preparing pure natural demulsifying granules includes the following steps: selecting dried lotus pods, dividing the lotus pods into sections, feeding the divided lotus pods into a pulverizer and crushing them into powder, screening the final powder through a sieve, taking the raw material of the powder that passes through the sieve to obtain lotus pod powder, and finally placing the lotus pod powder in an oven to dry it to obtain dried lotus pod powder, which is the demulsifying granules.

[0008] In a further embodiment, the pulverizer rotates at 25,000 r / min and uses a 200-mesh sieve.

[0009] In a further embodiment, the oven temperature is 45°C.

[0010] In a further embodiment, the lotus seedpod is a lotus seedpod top.

[0011] The present invention also provides a method for applying pure natural demulsifying particles, comprising the following steps: adding pure natural demulsifying particles to an oil-in-water type rolled oil emulsion, then mixing it in an ultrasonic water bath, and finally placing it in a dry and sealed environment to complete the demulsification.

[0012] In a further embodiment, the ultrasonic water bath is mixed for 10 minutes and placed in a dry, sealed environment for 12 hours.

[0013] In a further embodiment, the concentration of pure natural demulsifying particles in the oil-in-water rolling oil emulsion is 7 wt.%-10 wt.%.

[0014] Compared with the prior art, the beneficial effects of the present invention are:

[0015] 1. This method utilizes the amphiphilic composition and structure of pure natural dried lotus seed powder. Amphiphilicity means that pure natural dried lotus seed powder has both water-wetting ability (hydrophilic) and oil-wetting ability (hydrophobic). The hydrophobic structural part can interact with the lipophilic groups in nonionic surfactants and with the stable surfactants in the rolled oil emulsion, thereby disrupting the balance between the oil and water phases in the emulsion and achieving the demulsification effect. After demulsification, the properties of plant particles are not easily changed, and even with shaking, it is not easy to re-emulsify. Furthermore, the entire demulsification process is relatively short and the solution is stable.

[0016] After demulsification is complete, the aqueous phase can be filtered through a filter membrane to remove particles and obtain clean water. Compared with the demulsification schemes using strong acids and alkalis in factories, this scheme only requires filtration and does not require further treatment of strong acids and alkalis. The treatment process is also simpler and the environmental pollution is greatly reduced.

[0017] 2. Secondly, the demulsifier uses pure natural lotus pods as its material. After people consume the lotus seeds, the remaining lotus pods, which would otherwise be discarded, can be used as demulsifier materials, thus achieving the effect of recycling and turning waste into treasure. Moreover, it does not generate other industrial waste. Furthermore, the processing method of this solution is mainly crushing, which is simpler to prepare than traditional chemical reagent synthesis. It is one of the best demulsifiers currently available, demonstrating the effect of energy conservation and emission reduction.

[0018] 3. The solution uses dried lotus seed pods powder. The powder state can increase the contact area, and the dried lotus seed pods powder is more lipophilic than hydrophilic, which can interact with the lipophilic groups in the surfactant, change the tension between the surfactant and the water and oil phases, and thus achieve a better demulsification effect.

[0019] 4. Lotus pods, as a common agricultural waste, are often incinerated as agricultural waste or scrap, resulting in low manufacturing costs. This process transforms waste into valuable resources, contributing to carbon reduction. They also offer good food safety and high biocompatibility. Furthermore, when used in rolling oil emulsions, lotus pod granules maintain long-term oil-water phase separation after demulsification, demonstrating strong stability. As a pure, natural granule, lotus pod granules cause virtually no environmental damage and can be widely applied. In contrast, current factory demulsification methods using large amounts of strong acids and alkalis cause more environmental harm, further highlighting the energy-saving and emission-reduction goals of this solution. Attached Figure Description

[0020] Figure 1 A schematic diagram of the lotus seedpod pulp granule mixture after demulsification, illustrating the preparation and application methods of pure natural demulsifying granules.

[0021] Figure 2 This is a schematic diagram of the lotus seedpod mixture after demulsification in the preparation and application methods of pure natural demulsifying granules.

[0022] Figure 3 This is a schematic diagram of the lotus seedpod top granule mixture after demulsification in the preparation and application methods of pure natural demulsifying granules. Detailed Implementation

[0023] In the description of this invention, it should be understood that the terms "center," "longitudinal," "lateral," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," and "outer," etc., indicating orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, are only for the convenience of describing the invention and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific orientation, or be constructed and operated in a specific orientation, and therefore should not be construed as a limitation of the invention. Furthermore, the terms "first," "second," etc., are used for descriptive purposes only and should not be construed as indicating or implying relative importance or implicitly specifying the number of indicated technical features. Thus, a feature defined with "first," "second," etc., may explicitly or implicitly include one or more of that feature. In the description of this invention, unless otherwise stated, "a plurality of" means two or more.

[0024] In the description of this invention, it should be noted that, unless otherwise explicitly specified and limited, the terms "installation," "connection," and "linking" should be interpreted broadly. For example, they can refer to a fixed connection, a detachable connection, or an integral connection; they can refer to a mechanical connection or an electrical connection; they can refer to a direct connection or an indirect connection through an intermediate medium; and they can refer to the internal connection of two components. Those skilled in the art will understand the specific meaning of the above terms in this invention based on the specific circumstances.

[0025] The technical solutions of the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings. Obviously, the described embodiments are only some embodiments of the present invention, and not all embodiments. Based on the embodiments of the present invention, all other embodiments obtained by those skilled in the art without creative effort are within the scope of protection of the present invention. Example 1

[0026] Please see Figure 1 In this embodiment of the invention, a method for preparing pure natural demulsifying granules and its application method are described.

[0027] A method for preparing demulsifying granules involves selecting dried lotus seedpod pith, dividing the pith into sections, feeding the divided pith into a pulverizer, and crushing it into powder at a speed of 25,000 r / min. The final powder is then sieved through a 200-mesh sieve, and the raw material containing the powder passing through the sieve is collected to obtain lotus seedpod powder. Finally, the lotus seedpod powder is placed in an oven for drying to obtain dried lotus seedpod powder, which is the lotus seedpod pith granules.

[0028] A method for applying demulsifying particles includes the following steps: taking rolling oil and adding it to a test tube, stirring and dissolving it completely to obtain an emulsion, and then adding water to obtain an oil-in-water rolling oil emulsion;

[0029] The dried lotus seed pod inner pulp particles were added to the oil-in-water rolling oil emulsion to prepare five mixed solutions with lotus seed pod inner pulp particle concentrations of 0wt.%, 6wt.%, 7wt.%, 8wt.%, and 10wt.%. The solutions were then mixed in an ultrasonic water bath for 10 minutes and finally placed in a dry, sealed environment to stand for 12 hours and stored at room temperature to complete the demulsification.

[0030] Reference Figure 1The sample AF mass fractions were 0 wt.%, 6 wt.%, 7 wt.%, 8 wt.%, and 10 wt.%. Observation showed that the 0 wt.% and 6 wt.% lotus seed pod granule mixture prepared in Example 1 did not show demulsification, while the 7 wt% lotus seed pod granule mixture showed incomplete demulsification, and the supernatant was easily re-emulsified after slight shaking. The lotus seed pod granule mixture with mass fractions of 8 wt.% and 10 wt.% completely demulsified, and the supernatant was stable and did not emulsify after slight shaking. Example 2

[0031] Please see Figure 2 The difference from Example 1 is that the inner pulp of the lotus seedpod was replaced with the whole lotus seedpod, and all the lotus seedpod particles were obtained and made into five mixed solutions with concentrations of 0wt.%, 6wt.%, 7wt.%, 8wt.%, and 10wt.%.

[0032] Reference Figure 2 The sample AF mass fraction was 0 wt.%, 6 wt.%, 7 wt.%, 8 wt.%, and 10 wt.%. The lotus seed pods mixture with a mass fraction of 0 wt.% and 6 wt.% prepared in Example 2 did not show demulsification. The lotus seed pods mixture with a mass fraction of 7 wt.%, 8 wt.%, and 10 wt.% showed complete demulsification after 12 hours, and the supernatant was stable and not easily re-emulsified. Example 3

[0033] Please see Figure 3 The difference from Example 1 is that the inner pulp of the lotus seedpod is replaced with the top of the lotus seedpod to obtain lotus seedpod top particles, which are then prepared into five mixed solutions with concentrations of 0wt.%, 6wt.%, 7wt.%, 8wt.%, and 10wt.%.

[0034] Reference Figure 3 The sample AF mass fraction was 0wt.%, 6wt.%, 7wt.%, 8wt.%, and 10wt.%. The 0wt.% and 6wt.% lotus seed pod top granule mixture obtained in Example 3 did not show demulsification. The 7wt.%, 8wt.%, and 10wt.% lotus seed pod top granule mixtures all completed demulsification after standing for 12 hours, and the supernatant was stable.

[0035] Conclusion: When the concentration of the three types of lotus seed pods reached 8 wt%, the mixture of the three types of lotus seed pods was completely demulsified and the demulsification effect was stable. This is because dried lotus seed pod powder is amphiphilic, while the rolling oil emulsion stabilizer is the nonionic surfactant. The amphiphilic nature of dried lotus seed pod powder allows it to interact with the lipophilic groups in the nonionic surfactant and the surfactant in the rolling oil emulsion stabilizer, thereby disrupting the balance between the oil and water phases in the emulsion.

[0036] It will be apparent to those skilled in the art that the present invention is not limited to the details of the exemplary embodiments described above, and that the invention can be implemented in other specific forms without departing from its spirit or essential characteristics. Therefore, the embodiments should be considered in all respects as exemplary and non-limiting, and the scope of the invention is defined by the appended claims rather than the foregoing description. Thus, all variations falling within the meaning and scope of equivalents of the claims are intended to be included within the present invention. No reference numerals in the claims should be construed as limiting the scope of the claims.

[0037] Furthermore, it should be understood that although this specification describes embodiments, not every embodiment contains only one independent technical solution. This narrative style is merely for clarity. Those skilled in the art should consider the specification as a whole, and the technical solutions in each embodiment can also be appropriately combined to form other embodiments that can be understood by those skilled in the art.

Claims

1. A method for applying pure natural demulsifying granules, characterized in that, Includes the following steps: Select dried lotus pods, divide them into sections, and then put the divided lotus pods into a pulverizer to be crushed into powder. The final powder is then screened through a sieve, and the raw material that passes through the sieve is taken to obtain lotus pod powder. Finally, the lotus pod powder is placed in an oven to dry, and the dried lotus pod powder is obtained, which is the demulsifying granules. The pulverizer operates at a speed of 25,000 r / min and uses a 200-mesh sieve. The lotus seedpod uses the top of the lotus seedpod; The oven temperature is set at 45℃; The demulsifying particles are added to the oil-in-water rolling oil emulsion, then mixed in an ultrasonic water bath, and finally placed in a dry and sealed environment to complete the demulsification. The ultrasonic water bath machine has a mixing time of 10 minutes and is placed in a dry, sealed environment for 12 hours. The concentration of demulsifying particles in the oil-in-water rolling oil emulsion is 7 wt.%-10 wt.%.

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