A mild cleansing water and a method for preparing the same

By rationally combining surfactants to form micelles, the problem of existing makeup removers requiring additional rinsing is solved, resulting in a gentle makeup remover that quickly dissolves makeup, has a refreshing and moisturizing effect, and simplifies the usage process.

CN117017807BActive Publication Date: 2025-12-12GUANGDONG BAILICHEN BIOTECHNOLOGY CO LTD
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Patent Information

Application Number
CN202311073991.1
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Priority Date
2022-08-26
Filing Date
2023-08-24
Publication Date
2025-12-12
Estimated Expiration
2043-08-24

AI Technical Summary

Technical Problem

Existing makeup removers require additional rinsing after use, increasing the hassle and cost of use, while failing to achieve a gentle and non-irritating makeup removal effect.

Method used

The product utilizes a well-balanced combination of surfactants such as disodium cocoamphodiacetate, poloxamer, polyglycerol esters, sodium lauroyl sarcosinate, and sodium cocamidopropyl PG-dimethylammonium chloride phosphate to form micelles that quickly dissolve makeup. Sodium cocamidopropyl PG-dimethylammonium chloride phosphate also promotes foam generation. Combined with moisturizers and chelating agents, the product is easy to rinse off and keeps skin moisturized.

Benefits of technology

It achieves a gentle makeup removal effect by quickly dissolving makeup, foundation, and other cosmetics, leaving the skin feeling refreshed and moisturized after use. No additional rinsing is required, reducing the complexity and cost of use.

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Abstract

The application discloses a mild make-up remover and a preparation method thereof, which comprises the following components in percentage by weight: 0.1-1% of disodium cocoamphodiacetate, 1-5% of poloxamer, 0.35-3.5% of polyglycerol ester compounds, 0.01-0.5% of sodium lauroylmethylamide, 0.1-1% of cocamidopropyl PG-dimethyl ammonium phosphate sodium, 1-10% of humectants, 0.02-0.5% of chelating agents, 0-0.5% of preservatives, water, and the balance. The micelles formed by the make-up remover have lipophilic groups capable of dissolving make-up and hydrophilic groups capable of making the product easy to wash, and the make-up remover is mild and non-irritating, can be applied to leave-on make-up removal products, balances make-up removal force and product mildness, and has a fresh and moisturizing skin feeling after use.
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Description

Technical Field

[0001] This invention relates to the field of cosmetics technology, and in particular to a mild makeup remover and its preparation method. Background Technology

[0002] Makeup removers include cleansing oils, cleansing milks, and cleansing waters. Among them, cleansing waters generally don't leave a heavy, greasy feeling and are popular with many consumers. The main cleansing ingredient in cleansing waters is surfactants. A proper combination of surfactants is essential for effective makeup removal while remaining gentle on the skin. After using makeup removers, to avoid residual surfactants and other ingredients causing harm, it's generally necessary to wash the skin with a facial cleanser. This not only increases the hassle of use but also raises costs. Therefore, developing a makeup remover with a well-balanced surfactant combination that effectively removes makeup while being gentle, non-irritating, and requiring no rinsing has a promising market prospect. Summary of the Invention

[0003] In order to overcome the shortcomings of the prior art, one of the objectives of this invention is to provide a gentle makeup remover that can quickly dissolve makeup, foundation, BB cream and other makeup, and is gentle and non-irritating, while being easy to wash off and leaving the skin feeling refreshed and moisturized.

[0004] The second objective of this invention is to provide a simple method for preparing a gentle makeup remover.

[0005] One of the objectives of this invention is achieved through the following technical solution:

[0006] A mild makeup remover comprising the following components by weight percentage: 0.1-1% disodium cocoamphodiacetate, 1-5% poloxamer, 0.35-3.5% polyglycerol ester compound, 0.01-0.5% sodium lauroyl sarcosinate, said polyglycerol ester compound comprising one or any combination of polyglycerol-6 caprylate, polyglycerol-4 caprate, polyglycerol-3 cocoate and polyglycerol-6 ricinoleate; 0.1-1% sodium cocamidopropyl PG-dimethylammonium chloride phosphate, 1-10% humectant, 0.02-0.5% chelating agent, 0-0.5% preservative, water, balance.

[0007] Sodium cocoamphoacetate is a coconut oil-derived surfactant that is mild and non-irritating. It has excellent cleaning properties, making it easy to rinse away mixtures of water, oil, and dirt. It also has foaming properties and can stabilize foam.

[0008] Poloxamer is a cleaning agent and surfactant, primarily used for cleaning.

[0009] Sodium lauroyl methyl amino acid is a kind of surfactant, can make the oil and dirt mixture easy to flush;And it plays a role in penetration, can change the skin structure, help its moisturizing agent and other components penetrate into the skin deep, let the makeup remover water play better moisturizing effect.

[0010] Cocamidopropyl PG-dimethyl ammonium phosphate sodium is a relatively mild surfactant, has cleaning function, can also promote the production of foam.

[0011] As a preferred embodiment of the present application, the polyglycerol ester compound is a combination of polyglyceryl-6 caprylate, polyglyceryl-4 caprate, polyglyceryl-3 cocoate and polyglyceryl-6 ricinoleate.

[0012] As a preferred embodiment of the present application, the poloxamer is poloxamer 184.

[0013] As a preferred embodiment of the present application, the moisturizing agent includes one or any combination of dipropylene glycol, 1,2-hexanediol and glycine.

[0014] As a preferred embodiment of the present application, the chelating agent is disodium EDTA.

[0015] As a preferred embodiment of the present application, the preservative is colloidal silver.

[0016] As a preferred embodiment of the present application, the mild makeup remover includes the following components by weight percentage: 0.1-1% of disodium cocamphodipropionate, 1-5% of poloxamer 184, 0.1-1% of polyglyceryl-6 caprylate, 0.1-1% of polyglyceryl-4 caprate, 0.1-1% of polyglyceryl-3 cocoate, 0.1-1% of polyglyceryl-6 ricinoleate, 0.01-0.5% of sodium lauroyl methyl amino acid, 0.1-1% of cocamidopropyl PG-dimethyl ammonium phosphate sodium, 1-8% of dipropylene glycol, 0-0.5% of 1,2-hexanediol, 0-0.1% of glycine, 0.02-0.5% of disodium EDTA, 0-0.005% of colloidal silver, water, the balance.

[0017] The second purpose of the present application is achieved by the following technical scheme:

[0018] A preparation method of a mild makeup remover, comprising the following steps:

[0019] Mix the formula amount of solvent, disodium cocamphodipropionate, poloxamer, polyglycerol ester compound, moisturizing agent and chelating agent, heat and stir until completely dissolved without particles, and wait for use;

[0020] Stir and cool down, then add the formula amount of sodium lauroyl methyl amino acid, cocamidopropyl PG-dimethyl ammonium phosphate sodium and preservative in turn, stir uniformly, and get it.

[0021] As a preferred scheme of the present application, the preparation method of the mild make-up remover water comprises the following steps:

[0022] Mix the formula amount of solvent, disodium cocoamphodiacetate, poloxamer, polyglycerol ester compound, humectant and chelating agent, stir and heat to 75-80°C until completely dissolved without particles, and wait for use;

[0023] Stir and cool to below 45°C, then add the formula amount of sodium lauroylmethyl amino acid, sodium cocamidopropyl PG-dimethyl ammonium phosphate and preservative in sequence, stir uniformly, and obtain.

[0024] Compared with the prior art, the present application has the beneficial effects that:

[0025] (1) The mild make-up remover water provided by the present application is more mild than conventional make-up remover liquid, and is a make-up remover liquid with mildness close to eye drops; at the same time, it has good make-up removing ability, can quickly dissolve makeup, foundation, BB cream and the like, can be applied to a no-wash make-up remover product, can quickly dissolve makeup, perfectly balances the make-up removing force and product mildness, and has a refreshing and moisturizing skin feel after use.

[0026] (2) The mild make-up remover water provided by the present application uses different surfactants for collocation, the micelles formed have oil-loving groups and can dissolve makeup; and the micelles have hydrophilic groups at the same time, so that the product is easy to rinse.

[0027] (3) The mild make-up remover water provided by the present application is convenient to produce and use, stable in performance, and easy to store. BRIEF DESCRIPTION OF DRAWINGS

[0028] Figure 1 is a comparison chart of the YSL lipstick make-up removing effect of Example 1 and Comparative Example 1 of the present application;

[0029] Figure 2 is a comparison chart of the Maybelline lip gloss make-up removing effect of Example 1 and Comparative Example 1 of the present application;

[0030] Figure 3 is a comparison chart of the Kate eyeliner pen make-up removing effect of Example 1 and Comparative Example 1 of the present application;

[0031] Figure 4 is a comparison chart of the BB cream make-up removing effect of Example 1 and Comparative Example 1 of the present application. DETAILED DESCRIPTION

[0032] The application will be further described below in conjunction with the accompanying drawings and specific embodiments. It should be noted that the following described embodiments or technical features can be combined in any manner to form new embodiments, without conflict. The raw materials and equipment used in the following embodiments can be obtained by purchase, unless otherwise specified.

[0033] Examples 1-3

[0034] A mild makeup remover, prepared from the following components in percentage by weight: disodium cocoamphodiacetate, poloxamer, polyglycerol ester compound, sodium lauroylmethyl amino acid, sodium cocamidopropyl PG-dimethyl ammonium phosphate, humectant, chelating agent, preservative and water. See Table 1 for details.

[0035] Table 1 Formulation of Examples 1-3

[0036]

[0037]

[0038] The mild makeup remover of Examples 1-3 is prepared as follows:

[0039] Mix the formulation amount of water, disodium cocoamphodiacetate, poloxamer 184, polyglyceryl-6 caprylate, polyglyceryl-4 caprate, polyglyceryl-3 cocoate, polyglyceryl-6 ricinoleate, humectant and chelating agent, and heat to 75-80°C with stirring until completely dissolved and no particles are present, and then let stand;

[0040] Stir to cool to below 45°C, then add the formulation amount of sodium lauroylmethyl amino acid, sodium cocamidopropyl PG-dimethyl ammonium phosphate and preservative in sequence, and stir until uniform.

[0041] Comparative Example 1

[0042] Comparative Example 1 differs from Example 1 in that the formulation omits sodium cocamidopropyl PG-dimethyl ammonium phosphate, and the amount of disodium cocoamphodiacetate is adjusted to 0.71%, with the rest being the same as Example 1.

[0043] Comparative Example 2

[0044] Comparative Example 2 differs from Example 1 in that the formulation omits disodium cocoamphodiacetate, and the amount of sodium cocamidopropyl PG-dimethyl ammonium phosphate is adjusted to 0.71%, with the rest being the same as Example 1.

[0045] Comparative Example 3

[0046] Comparative Example 3 differs from Example 1 in that polyglyceryl-6 caprylate and polyglyceryl-6 ricinoleate are omitted from the formulation, the amount of polyglyceryl-4 caprate is adjusted to 0.416%, and the amount of polyglyceryl-3 cocoate is adjusted to 0.384%. The remainder is the same as in Example 1.

[0047] Effect verification

[0048] I. Makeup removal effect

[0049] The sample of Comparative Example 1 is used as Sample 1, and the sample of Example 1 is used as Sample 2. YSL lipstick, Maybelline lip gloss, KATE eyeliner, and BB cream are used as test samples to compare the makeup removal ability of Comparative Example 1 and Example 1.

[0050] Experiment 1: (1) YSL lipstick is used to draw on the arm three times repeatedly, and allowed to dry for 2 hours; (2) cosmetic cottons with equal proportions of Sample 1 makeup remover and Sample 2 makeup remover are respectively applied to the makeup area for 3-5 seconds, and then gently wiped 1-2 times, which can be completely removed, as shown in Figure 1 . It can be seen that the makeup removal effect of the sample of Example 1 (Sample 2) on YSL lipstick is better than that of the sample of Comparative Example 1 (Sample 1).

[0051] Experiment 2: (1) Maybelline lip gloss is used to draw on the arm three times repeatedly, and allowed to dry for 2 hours; (2) cosmetic cottons with equal proportions of Sample 1 makeup remover and Sample 2 makeup remover are respectively applied to the makeup area for 10 seconds, and then gently wiped 3-5 times, as shown in Figure 2 . It can be seen that the makeup removal effect of the sample of Example 1 (Sample 2) on Maybelline lip gloss is better than that of the sample of Comparative Example 1 (Sample 1).

[0052] Experiment 3: (1) KATE eyeliner is used to draw on the arm three times repeatedly, and allowed to dry for 2 hours; (2) cosmetic cottons with equal proportions of Sample 1 makeup remover and Sample 2 makeup remover are respectively applied to the eyeliner area for 10 seconds, and then wiped on the arm once, as shown in Figure 3 . It can be seen that the makeup removal effect of the sample of Example 1 (Sample 2) on KATE eyeliner is better than that of the sample of Comparative Example 1 (Sample 1).

[0053] Experiment 4: (1) BB cream is used to draw on the arm three times repeatedly, and allowed to dry for 2 hours;

[0054] (2) cosmetic cottons with equal proportions of Sample 1 makeup remover and Sample 2 makeup remover are respectively applied to the area with BB cream for 10 seconds, and then wiped on the arm once, as shown in Figure 4The results are shown in the following table 3-4. Table 2 is a score index table.

[0055] II. Testers' trial

[0056] Thirty testers who often use make-up and make-up remover were selected, each of whom tried the make-up remover samples of examples 1-3 and comparative examples 1-3, and scored the use effect of the make-up remover samples after use, and the number of people was counted, and the results are shown in the following table 3-4. Table 2 is a score index table.

[0057] Table 2 Score index table

[0058]

[0059] Table 3 Make-up removal effect evaluation table

[0060]

[0061] From the records in table 3, it can be seen that most of the testers' evaluation of the samples of examples 1-3 is high, and the make-up removal effect of lip gloss, eye make-up and full face is good. The samples of comparative examples 1-3, due to the change of surfactant, the make-up removal effect is reduced, and the make-up removal ability is not as good as examples 1-3.

[0062] Table 4 Use effect evaluation table

[0063]

[0064] From the records in table 4, it can be seen that the samples of examples 1-3 are better than comparative examples in mildness, use skin feel, rinsing and moisturizing. The samples of comparative examples 1-3, due to the change of surfactant, the use effect evaluation is not as good as examples 1-3. This shows that the use of suitable surfactant combination in the examples of the present application not only makes the make-up removal effect excellent, but also ensures the mildness of the product, which is mild and non-irritating, does not cause skin sensitivity, is refreshing and not greasy, has good skin friendliness, is easy to rinse, does not leave dirt residues, has good moisturizing effect after rinsing, and the skin is moist and not tight.

[0065] The above embodiments are only preferred embodiments of the present application, and cannot be used to limit the scope of protection of the present application. Any non-essential changes and substitutions made by those skilled in the art on the basis of the present application are within the scope of the present application.

Claims

1. A mild cleansing water, characterized by, The composition comprises the following components by weight percentage: 0.1-1% of disodium cocoamphodiacetate, 1-5% of poloxamer, 0.35-3.5% of polyglycerin ester compound, 0.01-0.5% of sodium lauroylmethylamino acetate, 0.1-1% of sodium cocamidopropyl PG-dimethyl amido ammonium phosphate, 1-10% of humectant, 0.02-0.5% of chelating agent, 0-0.5% of preservative, water in remainder; the polyglycerin ester compound comprises one or any combination of polyglyceryl-6 caprylate, polyglyceryl-4 caprate, polyglyceryl-3 cocoate and polyglyceryl-6 ricinoleate.

2. The mild makeup removing water according to claim 1, wherein The polyglycerin ester compound is a combination of polyglyceryl-6 caprylate, polyglyceryl-4 caprate, polyglyceryl-3 cocoate and polyglyceryl-6 ricinoleate.

3. The mild makeup removing water according to claim 1, wherein The poloxamer is poloxamer 184.

4. The mild makeup removing water according to claim 1, wherein The humectant comprises one or any combination of dipropylene glycol, 1,2-hexanediol and glycine.

5. The mild makeup-removing water according to claim 1, wherein The chelating agent is disodium EDTA.

6. The mild makeup removing water according to claim 1, wherein The preservative is colloidal silver.

7. The mild makeup-removing water according to claim 1, wherein The composition comprises the following components by weight percentage: 0.1-1% of disodium cocoamphodiacetate, 1-5% of poloxamer 184, 0.1-1% of polyglyceryl-6 caprylate, 0.1-1% of polyglyceryl-4 caprate, 0.1-1% of polyglyceryl-3 cocoate, 0.1-1% of polyglyceryl-6 ricinoleate, 0.01-0.5% of sodium lauroylmethylamino acetate, 0.1-1% of sodium cocamidopropyl PG-dimethyl amido ammonium phosphate, 1-8% of dipropylene glycol, 0-0.5% of 1,2-hexanediol, 0-0.1% of glycine, 0.02-0.5% of disodium EDTA, 0-0.005% of colloidal silver, water in remainder.

8. The mild makeup removing water according to claim 1, wherein The composition comprises the following components by weight percentage: 0.35% of disodium cocoamphodiacetate, 2% of poloxamer 184, 0.216% of polyglyceryl-6 caprylate, 0.2% of polyglyceryl-4 caprate, 0.2% of polyglyceryl-3 cocoate, 0.184% of polyglyceryl-6 ricinoleate, 0.09% of sodium lauroylmethylamino acetate, 0.36% of sodium cocamidopropyl PG-dimethyl amido ammonium phosphate, 3.156% of dipropylene glycol, 0.08% of 1,2-hexanediol, 0.002475% of glycine, 0.1% of disodium EDTA, 0.000025% of colloidal silver, water in remainder.

9. A method for preparing the mild make-up removing water according to any one of claims 1 to 8, characterized by, The method comprises the following steps: Mix the formula amount of water, disodium cocoamphodiacetate, poloxamer, polyglycerin ester compound, humectant and chelating agent, and heat and stir until completely dissolved and no particles, and then cool down; Stir and cool down, and then add the formula amount of sodium lauroylmethylamino acetate, sodium cocamidopropyl PG-dimethyl amido ammonium phosphate and preservative in sequence, and stir until uniform, and then obtain.

10. The method for preparing the mild makeup-removing water according to claim 9, wherein the water-soluble polymer is added to the water-soluble polymer solution in an amount of 0.01 to 5% by weight. The method comprises the following steps: Mix the formula amount of water, disodium cocoamphodiacetate, poloxamer, polyglycerin ester compound, humectant and chelating agent, and heat and stir until completely dissolved and no particles, and then cool down; Stir and cool to 45℃ or below, then add the formula amount of sodium lauroyl amino acid, sodium cocamidopropyl PG-dimethyl ammonium phosphate and preservative in turn, stir until uniform, and then obtain.

Citation Information

Patent Citations

  • Three-in-one amino acid clear mousse and preparation method thereof

    CN113197790A

  • Mild double-layer cleansing lotion and preparation method thereof

    CN114306134A