A herbicidal composition

Abstract

The present application relates to a kind of herbicidal composition, it includes glufosinate and / or precision glufosinate, and foliage fertilizer;The foliage fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, urea.The good synergies between the components of the present application, can be effectively used in low temperature conditions perennial tolerance plant, large age weed, new germination weed etc., effectively improve the control range of glufosinate and / or precision glufosinate, significantly prolong the effective period.Meanwhile the preparation method of the composition is simple and easy to operate, processing equipment is easy to get, cost is low, has obvious market promotion value and economic benefits.

Description

Technical Field

[0001] This invention belongs to the field of agricultural chemical applications, and specifically relates to a herbicidal composition. Background Technology

[0002] The chemical formula of glufosinate is C5H. 12 NO4P, with a molecular weight of 198.1574, is chemically named 2-amino-4-[hydroxy(methyl)phosphono]butanoic acid ammonium; (RS)-2-amino-4-(hydroxymethoxyphosphono)butanoic acid ammonium. It is readily soluble in water but sparingly soluble in organic solvents, photostable, and has a melting point of 210℃. It is a highly effective, low-toxicity, non-selective contact phosphate herbicide. Glufosinate-ammonium is an L-type glufosinate-ammonium, and its herbicidal activity is twice that of racemic DL-type glufosinate-ammonium mixtures. Glufosinate-ammonium and / or granulated glufosinate-ammonium inhibit glutamine synthase, leading to nitrogen metabolism disorders in plants, ammonium ion accumulation and poisoning, which in turn affects chloroplast synthesis, hinders photosynthesis, and ultimately causes plant death. Glufosinate and / or glufosinate-ammonium have low toxicity and are relatively safe. They are easily degraded in soil, safe for crops, have a broad spectrum of weed control, high activity, and rapid weed killing. They can control or quickly kill more than 100 kinds of annual or perennial weeds. Glufosinate and / or glufosinate-ammonium primarily act as contact herbicides and do not migrate elsewhere, making them safe for subsequent crops. Glufosinate and / or glufosinate-ammonium have excellent water solubility, stable structure, and are easy to process and mix for use.

[0003] However, due to the characteristics and mechanism of action of glufosinate and / or glufosinate, they are suitable for use at temperatures above 20°C. However, their efficacy deteriorates when used at low temperatures below 15°C. There are few studies and reports on how to improve the efficacy of glufosinate and / or glufosinate at low temperatures. Summary of the Invention

[0004] The purpose of this invention is to provide a herbicidal composition that can improve the efficacy of glufosinate and / or succinate at low temperatures.

[0005] To achieve the above objectives, the technical solution adopted by the present invention is as follows:

[0006] The first aspect of the present invention provides a herbicidal composition comprising glufosinate and / or succinate, and a foliar fertilizer; said foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea.

[0007] Foliar fertilizer is a fertilizer applied directly to the leaves of crops for absorption. Plant leaves have two layers of epidermis, composed of epidermal cells. The outer layer of these cells has a cuticle and a waxy layer, which protect the mesophyll cells beneath the epidermis from adverse external conditions, allowing them to perform photosynthesis and respiration. The leaf surface also has many tiny stomata, which facilitate gas exchange. Research shows that the cuticle is composed of a long-chain fatty acid polymer with hydroxyl and carboxyl groups. The intermolecular gaps and the hydrophilic hydroxyl and carboxyl groups on the polymer allow aqueous solutions to penetrate into the leaf. Of course, the stomata on the leaf surface provide an even more convenient channel for foliar fertilizer to enter the leaf.

[0008] The inventors have unexpectedly discovered that the combined use of glufosinate and / or granulated glufosinate with specific foliar fertilizers can have a synergistic effect, significantly improving the efficacy of glufosinate and / or granulated glufosinate under low-temperature conditions. The specific mechanism may be that foliar fertilizers are a type of fertilizer where nutrients are applied to the surface of crop leaves and absorbed through the leaves. With foliar fertilization, various nutrients can be quickly absorbed by the crop leaves, entering the plant directly from the leaves and participating in the crop's metabolism. Because nutrients enter the plant directly from the leaves, the absorption rate is rapid, greatly increasing the amount of nutrients in the plant within a short period. This leads to an increase in the accumulation of ammonium ions in the plant under low-temperature conditions, thereby improving the efficacy of glufosinate and / or granulated glufosinate at low temperatures.

[0009] According to some specific embodiments, the foliar fertilizer includes at least boron, for example, the foliar fertilizer is boron, or boron and potassium hydrogen phthalate, or boron and ammonium sulfate, or boron and urea, or boron, potassium hydrogen phthalate and ammonium sulfate, or boron, potassium hydrogen phthalate and urea, or boron, ammonium sulfate and urea, or potassium hydrogen phthalate, boron, ammonium sulfate and urea, or potassium hydrogen phthalate, boron, ammonium sulfate and urea.

[0010] According to some specific implementation methods, the foliar fertilizer is two or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea.

[0011] Furthermore, the foliar fertilizer includes at least one of boron and urea.

[0012] Furthermore, the foliar fertilizer includes boron and urea.

[0013] According to some specific and preferred embodiments, the foliar fertilizer includes potassium hydrogen phthalate, boron, and urea.

[0014] Further, the mass ratio of the potassium hydrogen phthalate, the boron and the urea is 25-35:1:25-35, preferably 27-33:1:27-33, more preferably 28-32:1:28-32, and even more preferably 29-31:1:29-31.

[0015] According to some specific embodiments, the mass ratio of glufosinate and / or granulated glufosinate to the foliar fertilizer is 1 to 400:1; for example, 1:1, 5:1, 10:1, 15:1, 20:1, 25:1, 30:1, 35:1, 40:1, 45:1, 50:1, 55:1, 60:1, 65:1, 70:1, 75:1, 80:1, 85:1, 90:1, 95:1, 100:1, 105:1, 110:1, 115:1, 120:1, 125:1, 130:1, 135:1, 140:1, etc. 145:1, 150:1, 155:1, 160:1, 165:1, 170:1, 175:1, 180:1, 185:1, 190:1, 200:1, 210:1, 220:1, 230:1, 240:1, 250:1, 260:1, 270:1, 280:1, 290:1, 300:1, 310:1, 320:1, 330:1, 340:1, 350:1, 360:1, 370:1, 380:1, 390:1, or 400:1, etc.; preferably 1 to 200:1.

[0016] According to some specific embodiments, the mass ratio of glufosinate to foliar fertilizer is 2-400:1, preferably 3-200:1.

[0017] According to some specific embodiments, the mass ratio of glufosinate to foliar fertilizer is 1-200:1, preferably 1-100:1.

[0018] According to some specific embodiments, the foliar fertilizer includes boron, and the mass ratio of glufosinate and / or succinate to boron is 50–400:1, for example, 50:1, 55:1, 60:1, 65:1, 70:1, 75:1, 80:1, 85:1, 90:1, 95:1, 100:1, 105:1, 110:1, 115:1, 120:1, 125:1, 130:1, 135:1, 140:1, 145:1, 150:1, 155:1, 16 0:1, 165:1, 170:1, 175:1, 180:1, 185:1, 190:1, 200:1, 210:1, 220:1, 230:1, 240:1, 250:1, 260:1, 270:1, 280:1, 290:1, 300:1, 310:1, 320:1, 330:1, 340:1, 350:1, 360:1, 370:1, 380:1, 390:1, or 400:1, etc.; preferably 80 to 250:1.

[0019] According to some specific embodiments, the foliar fertilizer includes boron, and the mass ratio of glufosinate to boron is 100-400:1, preferably 150-250:1.

[0020] According to some specific embodiments, the foliar fertilizer includes boron, and the mass ratio of glufosinate to boron is 50-200:1, preferably 80-150:1.

[0021] According to some specific embodiments, the herbicidal composition also includes pesticide-acceptable adjuvants.

[0022] Further, by mass percentage, the glufosinate and / or granulated glufosinate comprise 0.1% to 80%, and the foliar fertilizer comprises 0.001% to 50%.

[0023] Furthermore, the herbicidal composition is in the form of an oil suspension, a soluble liquid, or soluble granules.

[0024] Furthermore, the pesticide-acceptable adjuvants include one or more of surfactants, binders, thickeners, fillers, and solvents.

[0025] The surfactant is selected from one or more combinations of alkyl glycoside auxiliaries, tallow amine auxiliaries, sodium dodecylbenzene sulfonate, calcium dodecylbenzene sulfonate, sodium dodecyl sulfate, sodium dodecylbenzene sulfate, lignin sulfonate, polyoxyethylene ether sulfonate, alkylnaphthalene sulfonate formaldehyde condensate, polycarboxylate, alkylphenol polyoxyethylene ether, fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, fatty alcohol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene ether sulfate, phenethylphenol polyoxyethylene ether, alkylphenol polyoxyethylene ether phosphate, and phenethylphenol polyoxyethylene ether phosphate.

[0026] The binder is selected from one or more combinations of soluble starch, dextrin, glucose, carboxymethyl cellulose, and lignin sulfonate.

[0027] The thickener is selected from one or more combinations of xanthan gum, magnesium aluminum silicate, silica, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, and bentonite.

[0028] The filler is selected from one or more combinations of lactose, glucose, sodium pyrophosphate, trisodium phosphate, urea, corn starch, bentonite, diatomaceous earth, kaolin, silica, perlite, and light calcium carbonate.

[0029] The solvent is selected from one or more combinations of methyl oleate, vegetable oil, soybean oil, corn oil, rapeseed oil, castor oil, mineral oil, cottonseed oil, palm oil, and water.

[0030] According to some specific embodiments, when the herbicidal composition is an oil suspension, it comprises the following components by mass percentage: 10% to 30% glufosinate and / or succinate glufosinate, 0.001% to 30% foliar fertilizer, 2% to 20% surfactant, 0.1% to 2% thickener, and solvent to make up to 100%.

[0031] Furthermore, when the herbicidal composition is an oil suspension, it comprises, by mass percentage: 10%–30% glufosinate and / or succinate, 0.05%–20% foliar fertilizer, 10%–20% surfactant, 0.1%–2% thickener, and solvent to 100%.

[0032] Furthermore, when the herbicidal composition is an oil suspension, it comprises, by weight percentage: 10%–30% glufosinate and / or succinate, 0.1%–15% foliar fertilizer, 15%–20% surfactant, 1%–2% thickener, and solvent to make up to 100%.

[0033] According to these embodiments, the surfactant is a fatty alcohol polyoxyethylene ether and an alkylbenzene sulfonate in a mass ratio of 2 to 5:1.

[0034] According to these embodiments, the thickener is bentonite.

[0035] According to these embodiments, the solvent is methyl oleate.

[0036] According to these embodiments, for solid foliar fertilizers, the preparation method of the oil suspension is as follows: glufosinate and / or refined glufosinate, thickener, surfactant and foliar fertilizer are added to a solvent, stirred evenly at a speed of 150-200 rpm, and then ground by a sand mill to obtain the oil suspension.

[0037] For foliar fertilizers containing both solid and liquid components, the preparation method of the oil suspension is as follows: glufosinate and / or refined glufosinate, thickener and part of surfactant, and solid foliar fertilizer are added to part of the solvent, stirred evenly at a speed of 150-200 rpm, and then ground by a sand mill. Then, liquid foliar fertilizer, the remaining surfactant and the remaining solvent are dissolved evenly and then mixed evenly with the ground system to obtain the oil suspension.

[0038] According to some specific embodiments, when the herbicidal composition is a soluble liquid, it comprises the following components by mass percentage: 0.1% to 60% glufosinate and / or succinate glufosinate, 0.001% to 50% foliar fertilizer, 2% to 20% surfactant, and solvent to make up to 100%.

[0039] Furthermore, when the herbicidal composition is a soluble liquid, it comprises, by mass percentage: 10%–30% glufosinate and / or succinate, 0.01%–30% foliar fertilizer, 2%–20% surfactant, and solvent to 100%.

[0040] Furthermore, when the herbicidal composition is a soluble liquid, it comprises, by mass percentage: 10%–30% glufosinate and / or succinate, 0.05%–20% foliar fertilizer, 10%–20% surfactant, and solvent to 100%.

[0041] Furthermore, when the herbicidal composition is a soluble liquid, it comprises, by mass percentage: 10%–30% glufosinate and / or succinate, 0.05%–15% foliar fertilizer, 15%–20% surfactant, and solvent to 100%.

[0042] According to these embodiments, the surfactant is a C12-14 alkyl glycoside and fatty alcohol polyoxyethylene ether sulfate in a mass ratio of 2 to 5:1.

[0043] According to these embodiments, the solvent is water.

[0044] According to these embodiments, the method for preparing the soluble liquid is as follows:

[0045] Add glufosinate and / or refined glufosinate, foliar fertilizer, and surfactant to a solvent, and stir at 150-200 rpm to dissolve evenly to obtain the soluble liquid preparation.

[0046] According to some specific embodiments, when the herbicidal composition is a soluble granule, it comprises the following components by mass percentage: 10% to 80% glufosinate and / or succinate glufosinate, 0.001% to 50% foliar fertilizer, 2% to 20% surfactant, 2% to 10% binder, and filler to make up to 100%.

[0047] Furthermore, when the herbicidal composition is a soluble granule, it comprises, by weight percentage, the following components: 25%–80% glufosinate and / or granulated glufosinate, 0.01%–30% foliar fertilizer, 2%–20% surfactant, 2%–10% binder, and filler to make up to 100%.

[0048] Furthermore, when the herbicidal composition is a soluble granule, it comprises, by weight percentage: 25%–60% glufosinate and / or succinate glufosinate, 0.05%–15% foliar fertilizer, 15%–20% surfactant, 2%–8% binder, and filler to 100%.

[0049] According to these embodiments, the surfactant is a sodium sulfonate and a polycarboxylate in a mass ratio of 2 to 5:1.

[0050] According to these embodiments, the binder is soluble starch.

[0051] According to these embodiments, the filler is diatomaceous earth.

[0052] According to these embodiments, the method for preparing the soluble granules is as follows:

[0053] The soluble granules are prepared by mixing glufosinate and / or refined glufosinate, foliar fertilizer, binder and surfactant evenly, ultra-finely pulverizing them through an air jet mill, stirring evenly at a speed of 100-150 rpm, adding water to knead and granulate, and drying at 50℃-70℃.

[0054] A second aspect of the present invention provides a herbicidal composition, which is an oil suspension and, by weight percentage, comprises 10% to 30% glufosinate and / or succinate, 0.001% to 30% foliar fertilizer, and the balance being a pesticide-acceptable adjuvant, wherein the foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea.

[0055] The further limitations of the foliar fertilizer in the herbicidal composition are the same as those in the herbicidal composition provided in the first aspect above, and will not be repeated here.

[0056] According to some specific embodiments, the pesticide-acceptable adjuvant includes 2% to 20% surfactant, 0.1% to 2% thickener, and the balance being solvent.

[0057] Furthermore, the surfactant is a fatty alcohol polyoxyethylene ether and an alkylbenzene sulfonate, the thickener is bentonite, and the solvent is methyl oleate.

[0058] A third aspect of the present invention provides a herbicidal composition, which is a water-soluble formulation comprising, by weight percentage, 0.1% to 80% glufosinate and / or succinate, 0.001% to 50% foliar fertilizer, and the balance being a pesticide-acceptable adjuvant, wherein the foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea.

[0059] The further limitations of the foliar fertilizer in the herbicidal composition are the same as those in the herbicidal composition provided in the first aspect above, and will not be repeated here.

[0060] According to some specific embodiments, the water-soluble formulation is a soluble liquid, and the pesticide-acceptable adjuvant includes 2% to 20% surfactant and the balance solvent.

[0061] Furthermore, the surfactant is an alkyl glycoside and a fatty alcohol polyoxyethylene ether sulfate, and the solvent is water.

[0062] According to some specific embodiments, the water-soluble formulation is a soluble granule, and the pesticide-acceptable adjuvants include 2% to 20% surfactant, 2% to 10% binder, and the balance being filler.

[0063] Furthermore, the surfactant is a naphthalene sulfonate formaldehyde condensate and a polycarboxylate, the binder is soluble starch, and the filler is diatomaceous earth.

[0064] According to some implementation methods, when using glufosinate as the active ingredient, the amount of glufosinate added in each formulation is 1.5 to 3 times that of glufosinate, preferably about 2 times, compared to using granulated glufosinate as the active ingredient.

[0065] The glufosinate mentioned above refers to glufosinate technical grade, while succinate refers to succinate technical grade.

[0066] The composition of glufosinate and / or glufosinate-ammonium with foliar fertilizer of the present invention can greatly improve the efficacy of glufosinate and / or glufosinate-ammonium under low-temperature conditions. The present invention uses a mixture of glufosinate and / or glufosinate-ammonium with foliar fertilizer within a certain range. With the synergistic effect of other components in the formulation, the active ingredients are fully utilized to enhance the herbicidal effect, resulting in significantly better efficacy than glufosinate and / or glufosinate-ammonium used alone. Furthermore, this composition of glufosinate and / or glufosinate-ammonium with foliar fertilizer is simple to implement, produces stable product quality, has significant market value, and is suitable for large-scale promotion and application.

[0067] The composition of glufosinate and / or granulated glufosinate with foliar fertilizer of the present invention is used to control unwanted vegetation growth, including weed control in non-arable fields, weeding in forests, weeding in orchards, weeding between crop rows in arable fields, and stubble removal in the field before sowing or transplanting.

[0068] When using glufosinate and / or granulated glufosinate in combination with foliar fertilizer, the effective ingredient dosage is 225–1800 g / ha, where the effective ingredient dosage is calculated based on the amount of glufosinate and / or granulated glufosinate used.

[0069] Due to the application of the above technical solution, the present invention has the following advantages compared with the prior art:

[0070] The components of this invention exhibit excellent synergistic effects, effectively controlling perennial tolerant plants, mature weeds, and newly sprouting weeds under low-temperature conditions. This significantly enhances the control range of glufosinate and / or succinate, and substantially prolongs the duration of effectiveness. Furthermore, the preparation method of this composition is simple and easy, the processing equipment is readily available, and the cost is low, demonstrating significant market potential and economic benefits. Detailed Implementation

[0071] All features disclosed in this invention, or all steps in the disclosed methods or processes, may be combined in any way except for mutually exclusive features or steps.

[0072] The technical solution of the present invention will be further described below with reference to specific embodiments. However, the present invention should not be limited to these embodiments. Unless specifically stated otherwise, all features can be replaced by other equivalent or similar alternative features. Unless specifically stated otherwise, each feature is only one example of a series of equivalent or similar features. All contents mentioned below are mass contents, and "%" means mass percentage.

[0073] Glufosinate and / or methyl glufosinate TC were purchased from Zhejiang Yongnong Chemical Co., Ltd.; potassium hydrogen phthalate was purchased from Wuhan Kemike Biomedical Technology Co., Ltd.; boron was purchased from Henan Aimuwoer Agricultural Technology Co., Ltd. (liquid boron); ammonium sulfate was purchased from Changzhou Lanya New Material Technology Co., Ltd.; urea was purchased from Suzhou Quanding Chemical Technology Co., Ltd.; fatty alcohol polyoxyethylene ether (AEO-9), C12-14 alkyl glycoside (APG), and fatty alcohol polyoxyethylene ether sulfate (AES) were purchased from Jiangsu Haian Petrochemical Plant; alkylbenzene sulfonate (500#) was purchased from Jiangsu Haian Petrochemical Plant; polycarboxylate (SD-816) was purchased from Shanghai Shida Polymer Materials Co., Ltd.; sodium sulfonate (SD-661) was purchased from Shanghai Shida Polymer Materials Co., Ltd.; diatomaceous earth was purchased from Shanghai Yansheng Industrial Co., Ltd.; bentonite was purchased from Guangxi Runxing New Material Co., Ltd.; and soluble starch was purchased from Wen'an Changhong Cellulose Factory.

[0074] Example 1

[0075] The raw material formula for preparing 20% ​​glufosinate + 9% potassium hydrogen phthalate oil suspension is shown in Table 1.

[0076] Table 1

[0077] Components Proportion glufosinate 20% off 100 Potassium hydrogen phthalate 9％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0078] Glufosinate, potassium hydrogen phthalate, bentonite, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredients were moistened. The mixture was then sand-milled. Once the sand-milling was qualified, a 20% glufosinate + 9% potassium hydrogen phthalate oil suspension was obtained.

[0079] Example 2

[0080] The raw material formula for preparing 20% ​​glufosinate + 0.05% boron oil suspension is shown in Table 2.

[0081] Table 2

[0082] Components Proportion glufosinate 20% off 100 boron 0.05％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0083] Glufosinate, bentonite, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 0.05% boron oil suspension.

[0084] Example 3

[0085] The raw material formula for preparing a 20% glufosinate + 0.1% boron oil suspension is shown in Table 3.

[0086] Table 3

[0087] Components Proportion glufosinate 20% off 100 boron 0.1％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0088] Glufosinate, bentonite, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 0.1% boron oil suspension.

[0089] Example 4

[0090] The raw material formula for preparing a 20% glufosinate + 0.2% boron oil suspension is shown in Table 4.

[0091] Table 4

[0092] Components Proportion glufosinate 20% off 100 boron 0.2％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0093] Glufosinate, bentonite, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 0.2% boron oil suspension.

[0094] Example 5

[0095] The raw material formula for preparing 20% ​​glufosinate + 9% ammonium sulfate oil suspension is shown in Table 5.

[0096] Table 5

[0097] Components Proportion glufosinate 20% off 100 ammonium sulfate 9％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0098] Glufosinate, ammonium sulfate, bentonite, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled. Once the sand-milling was qualified, a 20% glufosinate + 9% ammonium sulfate oil suspension was obtained.

[0099] Example 6

[0100] The raw material formula for preparing a 20% glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron oil suspension is shown in Table 6.

[0101] Table 6

[0102] Components Proportion glufosinate 20% off 100 Potassium hydrogen phthalate 4.5％ boron 0.1％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0103] Glufosinate, potassium hydrogen phthalate, bentonite, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron oil suspension.

[0104] Example 7

[0105] The raw material formula for preparing a 20% glufosinate + 4.5% ammonium sulfate + 0.1% boron oil suspension is shown in Table 7.

[0106] Table 7

[0107] Components Proportion glufosinate 20% off 100 ammonium sulfate 4.5％ boron 0.1％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0108] Glufosinate, bentonite, ammonium sulfate, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 4.5% ammonium sulfate + 0.1% boron oil suspension.

[0109] Example 8

[0110] The raw material formula for preparing a 20% glufosinate + 4.5% urea + 0.1% boron oil suspension is shown in Table 8.

[0111] Table 8

[0112]

[0113]

[0114] Glufosinate, bentonite, urea, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 4.5% urea + 0.1% boron oil suspension.

[0115] Example 9

[0116] A 20% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate oil suspension was prepared, and its raw material formula is shown in Table 9.

[0117] Table 9

[0118] Components Proportion glufosinate 20% off 100 Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0119] Glufosinate, bentonite, urea, potassium hydrogen phthalate, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate oil suspension.

[0120] Example 10

[0121] A 20% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate oil suspension was prepared, and its raw material formula is shown in Table 10.

[0122] Table 10

[0123] Components Proportion glufosinate 20% off 100 ammonium sulfate 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0124] Glufosinate, bentonite, ammonium sulfate, potassium hydrogen phthalate, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 20% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate oil suspension.

[0125] Example 11

[0126] The raw material formula for preparing 10% glufosinate + 0.1% boron oil suspension is shown in Table 11.

[0127] Table 11

[0128] Components Proportion glufosinate 10% discount boron 0.1％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0129] Add glufosinate, bentonite, and 500# to a portion of methyl oleate and stir at 180 rpm until the active ingredient is moistened. Then, mill the mixture in a sand mill until it passes the milling test to obtain glufosinate oil suspension. Dissolve boron, AEO-9, and the remaining methyl oleate evenly and add them to the glufosinate oil suspension. Stir evenly to obtain a 10% glufosinate + 0.1% boron oil suspension.

[0130] Example 12

[0131] A 10% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate oil suspension was prepared, and its raw material formula is shown in Table 12.

[0132] Table 12

[0133] Components Proportion glufosinate 10% discount Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0134] Glufosinate, bentonite, urea, potassium hydrogen phthalate, and 500# were added to a portion of methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled to obtain a glufosinate oil suspension. Boron, AEO-9, and the remaining methyl oleate were dissolved evenly and added to the glufosinate oil suspension. The mixture was stirred evenly to obtain a 10% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate oil suspension.

[0135] Comparative Example 1

[0136] The raw material formula for preparing a 20% glufosinate + 2% amino acid oil suspension is shown in Table 13.

[0137] Table 13

[0138]

[0139]

[0140] Glufosinate, bentonite, amino acids, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled. Once the sand-milling was qualified, a 20% glufosinate + 2% amino acid oil suspension was obtained.

[0141] Comparative Example 2

[0142] The raw material formula for preparing 20% ​​glufosinate + 1.5% superphosphate oil suspension is shown in Table 14.

[0143] Table 14

[0144] Components Proportion glufosinate 20% off 100 Superphosphate 1.5% discount Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0145] Glufosinate, bentonite, superphosphate, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredients were moistened. The mixture was then sand-milled. Once the sand-milling was qualified, a 20% glufosinate + 1.5% superphosphate oil suspension was obtained.

[0146] Comparative Example 3

[0147] The raw material formulation for preparing a 20% glufosinate + 2% nucleotide oil suspension is shown in Table 15.

[0148] Table 15

[0149] Components Proportion glufosinate 20% off 100 Nucleotides 2% discount Surfactant fatty alcohol polyoxyethylene ether (AEO-9) 15％ Surfactant alkylbenzene sulfonate (500#) 5％ Bentonite 2％ Methyl oleate Replenish to 100%

[0150] Glufosinate, bentonite, nucleotides, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredient was wetted. The mixture was then sand-milled until it passed the sand-milling test, thus obtaining a 20% glufosinate + 2% nucleotide oil suspension.

[0151] Comparative Example 4

[0152] The raw material formula for preparing 20% ​​glufosinate-ammonium oil suspension is shown in Table 16.

[0153] Table 16

[0154]

[0155]

[0156] Glufosinate, bentonite, 500# and AEO-9 were added to methyl oleate and stirred at 180 rpm until the active ingredient was moistened. The mixture was then sand-milled. Once the sand-milling was qualified, a 20% glufosinate oil suspension was obtained.

[0157] Example 13

[0158] Efficacy tests of oil suspensions for controlling field weeds in vineyards in Examples 1 to 12 and Comparative Examples 1 to 4

[0159] Application method: Dilute with 30 liters of water per acre and spray evenly in each plot.

[0160] Application time: When weeds are in the early or middle stage of the field, spray the stems and leaves once.

[0161] Survey methods and efficacy calculations:

[0162] The study investigated annual and perennial grass and broadleaf weeds, focusing on their control efficacy against weeds 14 and 30 days after application.

[0163] The purpose of this experiment was to confirm the actual control efficacy of glufosinate and / or succinate combined with foliar fertilizer against inter-row weeds in vineyards, and to comprehensively evaluate the combination of glufosinate and / or succinate with foliar fertilizer, providing a theoretical basis for future applications. The experiment was conducted in accordance with GB / T 17980-2000, the guidelines for field efficacy trials of pesticides.

[0164] 1. Materials and Methods

[0165] 1.1 Test reagents

[0166] Control agents: compound formulations of glufosinate and / or granulated glufosinate with foliar fertilizers, etc., as detailed in Examples 1-12 and Comparative Examples 1-4.

[0167] 1.2 Test subjects

[0168] The main weeds between the rows of grapevines were barnyard grass, foxtail grass, crabgrass, and purslane, with fleabane being the dominant perennial weed. At the time of herbicide application, the weed coverage in each treatment plot was 80%, with plant height ranging from 15 to 30 cm.

[0169] 1.3 Experimental Design

[0170] The experiment included 16 treatments, each with a control (CK). Each plot was 66 square meters, with three replicates, for a total of 51 plots. The plots for each treatment were arranged in a completely randomized block design. The treatment design is shown in Table 17.

[0171] Table 17

[0172]

[0173]

[0174] 1.4 Test Environment Conditions

[0175] The experiment was conducted in Daxin Town, Zhangjiagang City, Jiangsu Province, using a 5-year-old vineyard as the experimental site. The experimental field was flat and had sandy loam soil.

[0176] Test weather: On the day of application, the weather was cloudy with a high of 14°C and a low of 4°C, and no wind. There was no rainfall for 3 days after application.

[0177] 1.5 Test Methods

[0178] The experiment was conducted on the afternoon of March 17, 2022. A backpack electric sprayer was used for spraying, with a protective cover installed. The spraying was directed at the weeds between the grape rows, and efforts were made to avoid spraying the pesticide onto the grapes. Each treatment used 30L of water per acre.

[0179] 2. Survey methods and efficacy evaluation methods

[0180] The control effects of each treatment were investigated 14 and 30 days after application. A three-point sampling method was used, with 0.5 square meters selected at each point, and the types and number of weeds were recorded. The impact on grapevines was also visually assessed.

[0181]

[0182] The survey results are shown in Table 18 below.

[0183] Table 18

[0184]

[0185]

[0186] As shown in Table 18, compared with the comparative and control agents, the combination of glufosinate / ammonium glufosinate and foliar fertilizer in the examples significantly improved the control efficacy against both annual and perennial weeds under low temperature conditions.

[0187] As can be seen from the comparison of Examples 2-4, different amounts of boron have different synergistic effects on glufosinate, and the synergistic effect will decrease after exceeding a certain amount.

[0188] Examples 9 and 12 show that the combination of glufosinate / glufosinate with boron, urea, and potassium hydrogen phthalate resulted in the most significant synergistic effect.

[0189] Comparative Examples 1-3 are combinations of glufosinate with other foliar fertilizers, but their synergistic effect on glufosinate is not obvious, and they even have a certain inhibitory effect on the efficacy of glufosinate.

[0190] The grapes in all the above treatment groups grew normally, indicating that the agents in the examples and comparative examples are safe for grapes.

[0191] Example 14

[0192] A soluble liquid formulation of 20% glufosinate + 9% potassium hydrogen phthalate was prepared, and its raw material formula is shown in Table 19.

[0193] Table 19

[0194] Components Proportion glufosinate 20% off 100 Potassium hydrogen phthalate 9％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0195] Glufosinate, potassium hydrogen phthalate, and a surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 9% potassium hydrogen phthalate soluble liquid.

[0196] Example 15

[0197] The raw material formula for preparing a 20% glufosinate + 0.05% boron soluble liquid is shown in Table 20.

[0198] Table 20

[0199]

[0200]

[0201] Glufosinate, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 0.05% boron soluble liquid.

[0202] Example 16

[0203] The raw material formula for preparing a 20% glufosinate + 0.1% boron soluble liquid is shown in Table 21.

[0204] Table 21

[0205] Components Proportion glufosinate 20% off 100 boron 0.1％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0206] Glufosinate, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 0.1% boron soluble liquid.

[0207] Example 17

[0208] The raw material formula for preparing a 20% glufosinate + 0.2% boron soluble liquid is shown in Table 22.

[0209] Table 22

[0210] Components Proportion glufosinate 20% off 100 boron 0.2％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0211] Glufosinate, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 0.2% boron soluble liquid.

[0212] Example 18

[0213] The raw material formula for preparing a soluble liquid formulation of 20% glufosinate + 9% ammonium sulfate is shown in Table 23.

[0214] Table 23

[0215] Components Proportion glufosinate 20% off 100 ammonium sulfate 9％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0216] Glufosinate, ammonium sulfate, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 9% ammonium sulfate soluble liquid.

[0217] Example 19

[0218] A soluble liquid containing 20% ​​glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron was prepared, and its raw material formula is shown in Table 24.

[0219] Table 24

[0220] Components Proportion glufosinate 20% off 100 Potassium hydrogen phthalate 4.5％ boron 0.1％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0221] Glufosinate, potassium hydrogen phthalate, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron soluble liquid.

[0222] Example 20

[0223] A soluble liquid containing 20% ​​glufosinate, 4.5% ammonium sulfate, and 0.1% boron was prepared, and the raw material formula is shown in Table 25.

[0224] Table 25

[0225] Components Proportion glufosinate 20% off 100 ammonium sulfate 4.5％ boron 0.1％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0226] Glufosinate, ammonium sulfate, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 4.5% ammonium sulfate + 0.1% boron soluble liquid.

[0227] Example 21

[0228] A soluble liquid containing 20% ​​glufosinate + 4.5% urea + 0.1% boron was prepared, and the raw material formula is shown in Table 26.

[0229] Table 26

[0230] Components Proportion glufosinate 20% off 100 Urea 4.5％ boron 0.1％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0231] Glufosinate, urea, boron, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until uniformly dissolved to prepare a 20% glufosinate + 4.5% urea + 0.1% boron soluble liquid.

[0232] Example 22

[0233] A soluble liquid containing 20% ​​glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate was prepared, and its raw material formula is shown in Table 27.

[0234] Table 27

[0235] Components Proportion glufosinate 20% off 100 Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0236] Glufosinate, urea, boron, potassium hydrogen phthalate and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until dissolved to obtain a soluble liquid of 20% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate.

[0237] Example 23

[0238] A soluble liquid formulation of 20% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate was prepared, and the raw material formula is shown in Table 28.

[0239] Table 28

[0240] Components Proportion glufosinate 20% off 100 ammonium sulfate 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0241] Glufosinate, ammonium sulfate, boron, potassium hydrogen phthalate and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until dissolved to obtain a soluble liquid of 20% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate.

[0242] Example 24

[0243] The raw material formula for preparing 10% glufosinate + 0.1% boron soluble liquid is shown in Table 29.

[0244] Table 29

[0245] Components Proportion glufosinate 10% discount boron 0.1％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0246] Add glufosinate, boron, and surfactant to water, heat to 50°C, and stir at 180 rpm until dissolved to obtain a 10% glufosinate + 0.1% boron soluble liquid.

[0247] Example 25

[0248] A soluble liquid formulation of 10% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate was prepared, and its raw material formula is shown in Table 30.

[0249] Table 30

[0250] Components Proportion glufosinate 10% discount Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0251] Add glufosinate, urea, boron, potassium hydrogen phthalate and surfactant to water, heat to 50°C, and stir at 180 rpm until dissolved to obtain a soluble liquid of 10% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate.

[0252] Comparative Example 5

[0253] A soluble liquid formulation of 20% glufosinate + 2% amino acids was prepared, and its raw material formula is shown in Table 31.

[0254] Table 31

[0255] Components Proportion glufosinate 20% off 100 amino acids 2% discount Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0256] Add glufosinate, amino acids, and surfactants to water, heat to 50°C, and stir at 180 rpm until dissolved and homogeneous to obtain a 20% glufosinate + 2% amino acid soluble liquid.

[0257] Comparative Example 6

[0258] A soluble liquid formulation of 20% glufosinate + 1.5% superphosphate was prepared, and its raw material formula is shown in Table 32.

[0259] Table 32

[0260] Components Proportion glufosinate 20% off 100 Superphosphate 1.5% discount Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0261] Add glufosinate, superphosphate, and surfactant to water, heat to 50°C, and stir at 180 rpm until dissolved and homogeneous to obtain a 20% glufosinate + 1.5% superphosphate soluble liquid.

[0262] Comparative Example 7

[0263] The raw material formula for preparing a 20% glufosinate + 2% nucleotide soluble liquid is shown in Table 33.

[0264] Table 33

[0265] Components Proportion glufosinate 20% off 100 Nucleotides 2% discount Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0266] Glufosinate, superphosphate, and surfactant were added to water, heated to 50°C, and stirred at 180 rpm until dissolved and homogeneous to obtain a 20% glufosinate + 2% nucleotide soluble liquid.

[0267] Comparative Example 8

[0268] The raw material formula for preparing 20% ​​glufosinate-ammonium soluble liquid is shown in Table 34.

[0269] Table 34

[0270] Components Proportion glufosinate 20% off 100 Surfactant C12-14 alkyl glycoside (APG) 15％ Surfactant fatty alcohol polyoxyethylene ether sulfate (AES) 5％ water Replenish to 100%

[0271] Add glufosinate and surfactant to water, heat to 50°C, and stir at 180 rpm until dissolved and homogeneous to obtain a 20% glufosinate-soluble liquid.

[0272] Example 26

[0273] The method of application for the efficacy test of soluble liquid agent for controlling field weeds in vineyards in Examples 14 to 25 and Comparative Examples 4 to 7 was as follows: Dilute with 30 liters of water per acre and spray evenly in each plot.

[0274] Application time: When weeds are in the early or middle stage of the field, spray the stems and leaves once.

[0275] Survey methods and efficacy calculations:

[0276] The study investigated annual and perennial grass and broadleaf weeds, focusing on their control efficacy against weeds 14 and 30 days after application.

[0277] The purpose of this experiment was to confirm the actual control efficacy of glufosinate and / or succinate combined with foliar fertilizer against inter-row weeds in vineyards, and to comprehensively evaluate the combination of glufosinate and / or succinate with foliar fertilizer, providing a theoretical basis for future applications. The experiment was conducted in accordance with GB / T 17980-2000, the guidelines for field efficacy trials of pesticides.

[0278] 1. Materials and Methods

[0279] 1.1 Test reagents

[0280] Control agents: compound formulations of glufosinate and / or granulated glufosinate with foliar fertilizers, etc., as detailed in Examples 14-25 and Comparative Examples 5-8.

[0281] 1.2 Test subjects

[0282] The main weeds between the rows of grapevines were barnyard grass, foxtail grass, crabgrass, and purslane, with fleabane being the dominant perennial weed. At the time of herbicide application, the weed coverage in each treatment plot was 80%, with plant height ranging from 15 to 30 cm.

[0283] 1.3 Experimental Design

[0284] The experiment included 16 treatments, each with a control (CK). Each plot was 66 square meters, with three replicates, for a total of 39 plots. The plots for each treatment were arranged in a completely randomized block design. The treatment design is shown in Table 35.

[0285] Table 35

[0286] Processing Number Treatment agents Dosage of active ingredient (g / mu) A Example 14 25 B Example 15 25 C Example 16 25 D Example 17 25 E Example 18 25 F Example 19 25 G Example 20 25 H Example 21 25 I Example 22 25 J Example 23 25 K Example 24 12.5 L Example 25 12.5 M Comparative Example 5 25 N Comparative Example 6 25 O Comparative Example 7 25 P Comparative Example 8 25 Q Blank (CK) /

[0287] 1.4 Test Environment Conditions

[0288] The experiment was conducted in Daxin Town, Zhangjiagang City, Jiangsu Province, using a 5-year-old vineyard as the experimental site. The experimental field was flat and had sandy loam soil.

[0289] Test weather: On the day of application, the weather was cloudy with a high of 13°C and a low of 5°C, and no wind. There was no rainfall for 3 days after application.

[0290] 1.5 Test Methods

[0291] The experiment was conducted on the afternoon of March 18, 2022. A backpack electric sprayer was used for spraying, with a protective cover installed. The spraying was directed at the weeds between the grape rows, and efforts were made to avoid spraying the pesticide onto the grapes. Each treatment used 30L of water per acre.

[0292] 2. Survey methods and efficacy evaluation methods

[0293] The control effects of each treatment were investigated 14 and 30 days after application. A three-point sampling method was used, with 0.5 square meters selected at each point, and the types and number of weeds were recorded. The impact on grapevines was also visually assessed.

[0294]

[0295] The survey results are shown in Table 36 below.

[0296] Table 36

[0297]

[0298] As shown in Table 36, compared with the comparative example, under low temperature conditions, the glufosinate and / or glufosinate-ammonium compound formulations with foliar fertilizers in the examples showed significantly improved control efficacy against both annual and perennial weeds.

[0299] As can be seen from Comparative Examples 15-17, different amounts of boron have varying synergistic effects on glufosinate, and the synergistic effect will decrease after exceeding a certain amount.

[0300] Examples 22 and 25 show that the combination of glufosinate / glufosinate with boron, urea and potassium hydrogen phthalate resulted in the most significant synergistic effect.

[0301] Further comparison shows that the efficacy of soluble liquid formulations is slightly weaker than that of oil suspensions, but soluble liquid formulations are more economical than oil suspensions.

[0302] The grapes in all the above treatment groups grew normally, indicating that the above-mentioned agents are safe for grapes.

[0303] Example 27

[0304] The raw material formula for preparing 50% glufosinate + 9% potassium hydrogen phthalate soluble granules is shown in Table 37.

[0305] Table 37

[0306] Components Proportion glufosinate 50% off 100 Potassium hydrogen phthalate 9％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0307] Glufosinate, potassium hydrogen phthalate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 9% potassium hydrogen phthalate soluble granules.

[0308] Example 28

[0309] The raw material formula for preparing 50% glufosinate + 0.05% boron soluble granules is shown in Table 38.

[0310] Table 38

[0311] Components Proportion glufosinate 50% off 100 boron 0.05％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0312] Glufosinate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 0.05% boron soluble granules.

[0313] Example 29

[0314] The raw material formula for preparing 50% glufosinate + 0.1% boron soluble granules is shown in Table 39.

[0315] Table 39

[0316] Components Proportion glufosinate 50% off 100 boron 0.1％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0317] Glufosinate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 0.1% boron soluble granules.

[0318] Example 30

[0319] The raw material formula for preparing 50% glufosinate + 0.2% boron soluble granules is shown in Table 40.

[0320] Table 40

[0321] Components Proportion glufosinate 50% off 100 boron 0.2％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0322] Glufosinate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 0.2% boron soluble granules.

[0323] Example 31

[0324] The raw material formula for preparing 50% glufosinate + 9% ammonium sulfate soluble granules is shown in Table 41.

[0325] Table 41

[0326] Components Proportion glufosinate 50% off 100 ammonium sulfate 9％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0327] Glufosinate, ammonium sulfate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 9% ammonium sulfate soluble granules.

[0328] Example 32

[0329] A 50% glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron soluble granule was prepared, and its raw material formula is shown in Table 42.

[0330] Table 42

[0331]

[0332]

[0333] Glufosinate, potassium hydrogen phthalate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 4.5% potassium hydrogen phthalate + 0.1% boron soluble granules.

[0334] Example 33

[0335] The raw material formula for preparing 50% glufosinate + 4.5% ammonium sulfate + 0.1% boron soluble granules is shown in Table 43.

[0336] Table 43

[0337] Components Proportion glufosinate 50% off 100 ammonium sulfate 4.5％ boron 0.1％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0338] Glufosinate, ammonium sulfate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 4.5% ammonium sulfate + 0.1% boron soluble granules.

[0339] Example 34

[0340] The raw material formula for preparing 50% glufosinate + 4.5% urea + 0.1% boron soluble granules is shown in Table 44.

[0341] Table 44

[0342] Components Proportion glufosinate 50% off 100 Urea 4.5％ boron 0.1％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0343] Glufosinate, urea, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 4.5% urea + 0.1% boron soluble granules.

[0344] Example 35

[0345] A soluble granule formulation of 50% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate was prepared, and its raw material formula is shown in Table 45.

[0346] Table 45

[0347] Components Proportion glufosinate 50% off 100 Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0348] Glufosinate, urea, boron, potassium hydrogen phthalate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 3% urea + 3% boron + 3% potassium hydrogen phthalate soluble granules.

[0349] Example 36

[0350] A soluble granule formulation of 50% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate was prepared, and its raw material formula is shown in Table 46.

[0351] Table 46

[0352] Components Proportion glufosinate 50% off 100 ammonium sulfate 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0353] Glufosinate, ammonium sulfate, boron, potassium hydrogen phthalate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 3% ammonium sulfate + 0.1% boron + 3% potassium hydrogen phthalate soluble granules.

[0354] Example 37

[0355] The raw material formula for preparing 25% glufosinate + 0.1% boron soluble granules is shown in Table 47.

[0356] Table 47

[0357]

[0358]

[0359] The glufosinate, boron, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 25% glufosinate + 0.1% boron soluble granules.

[0360] Example 38

[0361] The raw material formula for preparing soluble granules of 25% glufosinate + 3% urea + 0.1% boron + 3% potassium hydrogen phthalate is shown in Table 48.

[0362] Table 48

[0363] Components Proportion glufosinate 25% off 100 Urea 3％ boron 0.1％ Potassium hydrogen phthalate 3％ Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0364] The glufosinate, urea, boron, potassium hydrogen phthalate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain soluble granules of 25% glufosinate + 3% urea + 3% boron + 3% potassium hydrogen phthalate.

[0365] Comparative Example 9

[0366] The raw material formula for preparing 50% glufosinate + 2% amino acid soluble granules is shown in Table 49.

[0367] Table 49

[0368] Components Proportion glufosinate 50% off 100 amino acids 2% discount Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0369] Glufosinate, amino acids, soluble starch, surfactants and diatomaceous earth are mixed evenly and then ultra-finely pulverized using an air jet mill. Water is added and the mixture is kneaded in a kneader. The mixture is then extruded into granules using an extrusion granulator and dried to obtain 50% glufosinate + 2% amino acid soluble granules.

[0370] Comparative Example 10

[0371] The raw material formula for preparing 50% glufosinate + 1.5% superphosphate soluble granules is shown in Table 50.

[0372] Table 50

[0373] Components Proportion glufosinate 50% off 100 Superphosphate 1.5% discount Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0374] Glufosinate, superphosphate, soluble starch, surfactant and diatomaceous earth are mixed evenly and then ultra-finely pulverized by an air jet mill. Water is added and the mixture is kneaded in a kneader. Then it is extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate + 1.5% superphosphate soluble granules.

[0375] Comparative Example 11

[0376] The raw material formula for preparing 50% glufosinate + 2% nucleotide soluble granules is shown in Table 51.

[0377] Table 51

[0378] Components Proportion glufosinate 20% off 100 Nucleotides 2% discount Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0379] Glufosinate, nucleotides, soluble starch, surfactants and diatomaceous earth are mixed evenly and then ultra-finely pulverized using an air jet mill. Water is added and the mixture is kneaded in a kneader. The mixture is then extruded into granules using an extrusion granulator and dried to obtain 50% glufosinate + 2% nucleotide soluble granules.

[0380] Comparative Example 12

[0381] The raw material formula for preparing 50% glufosinate-ammonium soluble granules is shown in Table 52.

[0382] Table 52

[0383] Components Proportion glufosinate 20% off 100 Surfactant sodium sulfonate (SD-661) 15％ Surfactant polycarboxylate (SD-816) 5％ Soluble starch 5％ diatomite Replenish to 100%

[0384] Glufosinate, soluble starch, surfactant and diatomaceous earth are mixed evenly, then ultra-finely pulverized by an air jet mill, water is added and kneaded in a kneader, then extruded into granules by an extrusion granulator and dried to obtain 50% glufosinate soluble granules.

[0385] Example 27

[0386] Efficacy tests of soluble granules for controlling field weeds in vineyards in Examples 27 to 38 and Comparative Examples 9 to 12.

[0387] Application method: Dilute with 30 liters of water per acre and spray evenly in each plot.

[0388] Application time: When weeds are in the early or middle stage of the field, spray the stems and leaves once.

[0389] Survey methods and efficacy calculations:

[0390] The study investigated annual and perennial grass and broadleaf weeds, focusing on their control efficacy against weeds 14 and 30 days after application.

[0391] The purpose of this experiment was to confirm the actual control efficacy of glufosinate and / or succinate combined with foliar fertilizer against inter-row weeds in vineyards, and to comprehensively evaluate the combination of glufosinate and / or succinate with foliar fertilizer, providing a theoretical basis for future applications. The experiment was conducted in accordance with GB / T 17980-2000, the guidelines for field efficacy trials of pesticides.

[0392] 1. Materials and Methods

[0393] 1.1 Test reagents

[0394] Control agents: compound formulations of glufosinate and / or granulated glufosinate with foliar fertilizers, etc., as detailed in Examples 27-38 and Comparative Examples 9-12.

[0395] 1.2 Test subjects

[0396] The main weeds between the rows of grapevines were barnyard grass, foxtail grass, crabgrass, and purslane, with fleabane being the dominant perennial weed. At the time of herbicide application, the weed coverage in each treatment plot was 80%, with plant height ranging from 15 to 30 cm.

[0397] 1.3 Experimental Design

[0398] The experiment included 16 treatments, each with a control (CK). Each plot was 66 square meters, with three replicates, for a total of 39 plots. The plots for each treatment were arranged in a completely randomized block design. The treatment design is shown in Table 53.

[0399] Table 53

[0400]

[0401]

[0402] 1.4 Test Environment Conditions

[0403] The experiment was conducted in Daxin Town, Zhangjiagang City, Jiangsu Province, using a 5-year-old vineyard as the experimental site. The experimental field was flat and had sandy loam soil.

[0404] Test weather: On the day of application, the weather was cloudy with a high of 12°C and a low of 6°C, and no wind. There was no rainfall for 3 days after application.

[0405] 1.5 Test Methods

[0406] The experiment was conducted on the afternoon of March 19, 2022. A backpack electric sprayer was used for spraying, with a protective cover installed. The spraying was directed at the weeds between the grape rows, and efforts were made to avoid spraying the pesticide onto the grapes. Each treatment used 30L of water per acre.

[0407] 2. Survey methods and efficacy evaluation methods

[0408] The control effects of each treatment were investigated 14 and 30 days after application. A three-point sampling method was used, with 0.5 square meters selected at each point, and the types and number of weeds were recorded. The impact on grapevines was also visually assessed.

[0409]

[0410] The survey results are shown in Table 54 below.

[0411] Table 54

[0412]

[0413]

[0414] As shown in Table 54, compared with the comparative and control agents, under low temperature conditions, the glufosinate and / or glufosinate compounded with foliar fertilizer in different embodiments of the examples showed significantly improved control efficacy against annual and perennial weeds.

[0415] As can be seen from Comparative Examples 28-30, different amounts of boron have varying synergistic effects on glufosinate, and the synergistic effect will decrease after exceeding a certain amount.

[0416] Examples 35 and 38 show that the combination of glufosinate / glufosinate with boron, urea and potassium hydrogen phthalate has the most significant synergistic effect.

[0417] Further comparison shows that the efficacy of soluble granules is not much different from that of soluble liquids, but soluble liquids are more economical than soluble granules.

[0418] The grapes in all the above treatment groups grew normally, indicating that the above-mentioned soluble granules are safe for grapes.

[0419] The above embodiments are only for illustrating the technical concept and features of the present invention, and are intended to enable those skilled in the art to understand the content of the present invention and implement it accordingly. They should not be construed as limiting the scope of protection of the present invention. All equivalent changes or modifications made in accordance with the spirit and essence of the present invention should be covered within the scope of protection of the present invention.

Claims

1. A herbicidal composition, characterized in that: It includes glufosinate and / or granulated glufosinate, as well as foliar fertilizer; the foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea; and the foliar fertilizer includes at least boron, and the mass ratio of glufosinate and / or granulated glufosinate to boron is 50~400:

1.

2. The herbicidal composition according to claim 1, characterized in that: The foliar fertilizer is two or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea.

3. The herbicidal composition according to claim 1, characterized in that: The foliar fertilizer includes boron and urea.

4. The herbicidal composition according to claim 1, characterized in that: The foliar fertilizer includes potassium hydrogen phthalate, boron, and urea.

5. The herbicidal composition according to claim 1, characterized in that: The mass ratio of glufosinate and / or granulated glufosinate to the foliar fertilizer is 1~400:

1.

6. The herbicidal composition according to claim 5, characterized in that: The mass ratio of glufosinate and / or granulated glufosinate to the foliar fertilizer is 1~200:

1.

7. The herbicidal composition according to claim 5, characterized in that: The mass ratio of glufosinate to foliar fertilizer is 2-400:1; the mass ratio of refined glufosinate to foliar fertilizer is 1-200:

1.

8. The herbicidal composition according to claim 1, characterized in that: The mass ratio of glufosinate and / or succinate to boron is 80~250:

1.

9. The herbicidal composition according to claim 1, characterized in that: The mass ratio of glufosinate to boron is 100-400:1; the mass ratio of glufosinate to boron is 50-200:

1.

10. The herbicidal composition according to any one of claims 1 to 9, characterized in that: The herbicidal composition also includes pesticide-acceptable adjuvants.

11. The herbicidal composition according to claim 10, characterized in that: The glufosinate and / or succinate-ammonium, by weight percentage, comprise 0.1% to 80%, and the foliar fertilizer comprises 0.001% to 50%.

12. The herbicidal composition according to claim 10, characterized in that: The herbicidal composition is formulated as an oil suspension, a soluble liquid, or soluble granules.

13. The herbicidal composition according to claim 10, characterized in that: The pesticide-acceptable adjuvants include one or more of surfactants, binders, thickeners, fillers, and solvents.

14. The herbicidal composition according to claim 13, characterized in that: The surfactant is selected from one or more combinations of alkyl glycoside auxiliaries, tallow amine auxiliaries, sodium dodecylbenzene sulfonate, calcium dodecylbenzene sulfonate, sodium dodecyl sulfate, sodium dodecylbenzene sulfate, lignin sulfonate, polyoxyethylene ether sulfonate, alkylnaphthalene sulfonate formaldehyde condensate, polycarboxylates, alkylphenol polyoxyethylene ethers, fatty alcohol polyoxyethylene ethers, castor oil polyoxyethylene ethers, fatty alcohol polyoxyethylene ether sulfates, alkylphenol polyoxyethylene ether sulfates, phenethylphenol polyoxyethylene ethers, alkylphenol polyoxyethylene ether phosphates, and phenethylphenol polyoxyethylene ether phosphates; and / or, The binder is selected from one or more combinations of soluble starch, dextrin, glucose, carboxymethyl cellulose, and lignin sulfonate; and / or, The thickener is selected from one or more combinations of xanthan gum, magnesium aluminum silicate, silica, hydroxymethyl cellulose, hydroxyethyl cellulose, polyvinyl alcohol, and bentonite; and / or, The filler is selected from one or more combinations of lactose, glucose, sodium pyrophosphate, trisodium phosphate, urea, corn starch, bentonite, diatomaceous earth, kaolin, silica, perlite, and light calcium carbonate; and / or, The solvent is selected from one or more combinations of methyl oleate, vegetable oil, soybean oil, corn oil, rapeseed oil, castor oil, mineral oil, cottonseed oil, palm oil, and water.

15. The herbicidal composition according to claim 12, characterized in that: The herbicidal composition is an oil suspension, comprising, by weight percentage: 10%–30% glufosinate and / or methyl glufosinate, 0.001%–30% foliar fertilizer, 2%–20% surfactant, 0.1%–2% thickener, and solvent to 100%; or, The herbicidal composition is a soluble liquid formulation, comprising, by mass percentage: 0.1%–60% glufosinate and / or methyl glufosinate, 0.001%–50% foliar fertilizer, 2%–20% surfactant, and solvent to 100%; or, The herbicidal composition is a soluble granule, which, by mass percentage, comprises the following components: 10%–80% glufosinate and / or granulated glufosinate, 0.001%–50% foliar fertilizer, 2%–20% surfactant, 2%–10% binder, and filler to make up to 100%.

16. A herbicidal composition, characterized in that: The herbicidal composition is an oil suspension, comprising, by mass percentage, 10% to 30% glufosinate and / or succinate, 0.001% to 30% foliar fertilizer, and the balance being a pesticide-acceptable adjuvant. The foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea; and the foliar fertilizer includes at least boron, with the mass ratio of glufosinate and / or succinate to boron being 50 to 400:

1.

17. The herbicidal composition according to claim 16, characterized in that: The pesticide-acceptable adjuvants include 2% to 20% surfactant, 0.1% to 2% thickener, and the balance being solvent.

18. The herbicidal composition according to claim 17, characterized in that: The surfactant is fatty alcohol polyoxyethylene ether and alkylbenzene sulfonate, the thickener is bentonite, and the solvent is methyl oleate.

19. A herbicidal composition, characterized in that: The herbicidal composition is a water-soluble formulation, comprising, by mass percentage, 0.1% to 80% glufosinate and / or succinate, 0.001% to 50% foliar fertilizer, and the balance being a pesticide-acceptable adjuvant. The foliar fertilizer is one or more of potassium hydrogen phthalate, boron, ammonium sulfate, and urea; and the foliar fertilizer includes at least boron, with the mass ratio of glufosinate and / or succinate to boron being 50 to 400:

1.

20. The herbicidal composition according to claim 19, characterized in that: The water-soluble formulation is a soluble liquid, and the pesticide-acceptable adjuvants include 2% to 20% surfactant and the balance being solvent.

21. The herbicidal composition according to claim 20, characterized in that: The surfactant is an alkyl glycoside and a fatty alcohol polyoxyethylene ether sulfate, and the solvent is water.

22. The herbicidal composition according to claim 19, characterized in that: The water-soluble formulation is a soluble granule, and the pesticide-acceptable adjuvants include 2% to 20% surfactant, 2% to 10% binder, and the balance being filler.

23. The herbicidal composition according to claim 22, characterized in that: The surfactant is a naphthalene sulfonate formaldehyde condensate and a polycarboxylate, the binder is soluble starch, and the filler is diatomaceous earth.

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