Water-in-oil type water-containing eye shadow cream and preparation method thereof

Abstract

The invention relates to the technical field of cosmetics, and particularly discloses water-in-oil type water-containing eye shadow cream and a preparation method thereof. The water-in-oil type water-containing eye shadow cream comprises an emollient, a filler, a humectant, a VP / hexadecene copolymer, a film-forming agent I, toner, pearl powder, an emulsifier and water, the preparation method comprises the following steps: mixing the emollient and the VP / hexadecene copolymer to obtain a mixture; taking part of the mixture, mixing with the toner and the filler, grinding, adding into the rest mixture, and finally adding the emulsifier to obtain an oil phase; mixing water, a humectant and a film-forming agent I to obtain a water phase; adding the water phase into the oil phase, homogenizing and mixing, then adding pearl powder, stirring and mixing, and cooling to obtain the water-in-oil type water-containing eye shadow cream. The water-in-oil type water-containing eye shadow cream is high in stability, good in heat resistance and cold resistance, fresh and non-sticky after being smeared, and excellent in makeup holding effect and skin feeling.

Description

Technical Field

[0001] This application relates to the technical field of cosmetics, and more specifically, it relates to a water-in-oil type aqueous eyeshadow paste and a preparation method thereof. Background Art

[0002] Eyeshadow paste is an eye makeup product mainly in paste or cream texture, with high color rendering, smooth extensibility and luster, suitable for creating wet "metallic light" and "glass light" makeup effects.

[0003] Traditional eyeshadow paste is composed of an oil-wax system plus pigments. However, because the temperature sensitivity of oil wax is relatively high, in the high-temperature environment in summer, the eyeshadow paste is prone to softening and oiling, affecting the use experience of the eyeshadow paste. Summary of the Invention

[0004] In order to improve the stability of the eyeshadow paste in the high-temperature environment in summer, this application provides a water-in-oil type aqueous eyeshadow paste and a preparation method thereof.

[0005] In the first aspect, this application provides a water-in-oil type aqueous eyeshadow paste, adopting the following technical solution: A water-in-oil type aqueous eyeshadow paste, which is a water-in-oil emulsion system; The water-in-oil type aqueous eyeshadow paste is composed of the following components by weight percentage: Emollient 7.00 - 23.00% Filler 2.00 - 20.00%; Humectant 6.0 - 16.00%; Preservative 0.4 - 0.8%; Skin conditioner 0.1 - 0.5%; Volatile solvent 10.00 - 15.00%; Cetearyl alcohol 1 - 5%; Synthetic wax 10 - 15%; Synthetic beeswax 0.5 - 2%; Thickener I 0.5 - 3%; Thickener II 0.01 - 8%; VP / hexadecene copolymer 0 - 5%; Film-forming agent I 0 - 5%; Color powder 10.00 - 15.00%; Pearlescent powder 10.00 - 15.00%; Polyether-silicone copolymer emulsifier 1 - 5%; Polyether-siloxane copolymer emulsifier 0.5 - 3%; Polysorbate emulsifier 0.5 - 3%; Water is the balance; The thickener I is composed of a mixture of lithium dimethyldistearylammonium montmorillonite, propylene carbonate, and isododecane; The thickener II is composed of a mixture of polydimethylsiloxane and crosslinked polydimethylsiloxane polymer; The film-forming agent I is composed of a mixture of acrylate copolymer, water, ethanol, PPG-2-decylpolyether-30, sodium dehydroacetate, and sodium lauryl polyether sulfate; The hydrophilic-lipophilic balance value of the polyether-silicone copolymer emulsifier is 12-14; The hydrophilic-lipophilic balance value of the polyether-siloxane copolymer emulsifier is 5-7; The hydrophilic-lipophilic balance value of the polysorbate emulsifier is 14-16.

[0006] By adopting the above technical solutions, on the one hand, polyether-silicone copolymer emulsifiers and polyether-siloxane copolymer emulsifiers with similar structures can produce an obvious synergistic effect, which can stabilize silicone oil droplets and improve the stability of the water-in-oil system; then, the polysorbate emulsifier with a different conformation of its lipophilic group can produce a complementary effect, improving the compatibility of the water and oil phase components, which is beneficial to improving the stability of the water-in-oil system, making the water-in-oil type water-containing eyeshadow cream have excellent heat and cold resistance.

[0007] On the other hand, the thickener I composed of a mixture of lithium dimethyldistearylammonium montmorillonite, propylene carbonate, and isododecane has good thickening and suspending capabilities, which can increase the viscosity and suspension of the water-in-oil system, beneficial to improving the stability of the water-in-oil type water-containing eyeshadow cream, making it have excellent heat and cold resistance.

[0008] At the same time, using VP / hexadecene copolymer and / or film-forming agent I as the film-forming agent, the prepared water-in-oil type water-containing eyeshadow cream has good film-forming property and water resistance, is refreshing and non-greasy after application, and has excellent makeup retention effect and skin feel.

[0009] Preferably, the molecular weight of the polyether-silicone copolymer emulsifier is 1500-5000; the molecular weight of the polyether-siloxane copolymer emulsifier is 2000-6000; the molecular weight of the polysorbate emulsifier is 1200-1500.

[0010] Preferably, the polyether-silicone copolymer emulsifier is cetyl PEG / PPG-10 / 1 polydimethylsiloxane, and the polyether-siloxane copolymer emulsifier is lauryl PEG-10 tris(trimethylsiloxy)silylethyl polydimethylsiloxane.

[0011] Preferably, the polysorbate emulsifier is polysorbate-80.

[0012] By adopting the above technical solution, since cetyl PEG / PPG-10 / 1 dimethicone and lauryl PEG-10 tris(trimethylsiloxysilylethyl) dimethicone stabilize the emulsifier droplets through steric hindrance effect and electrostatic repulsion effect, and polysorbate-80 supplements the emulsified polar oil components to promote the compatibility of the oil-phase components, the stability of the water-in-oil system is improved.

[0013] Preferably, calculated by the weight percentage of the water-in-oil type aqueous eyeshadow paste, it includes 1-1.2% VP / hexadecene copolymer and 2-1.8% film-forming agent I.

[0014] By adopting the above technical solution, by adding VP / hexadecene copolymer and film-forming agent I simultaneously, the film-forming property and water resistance of the water-in-oil type aqueous eyeshadow paste can be increased, making it more compliant after application and having a better makeup-holding effect.

[0015] Preferably, the volatile solvent is isododecane.

[0016] By adopting the above technical solution, isododecane has a low viscosity and is easy to volatilize. After volatilization, it can form a film quickly, improving the skin feel and makeup-holding effect of the water-in-oil type aqueous eyeshadow paste.

[0017] Preferably, the skin conditioner is composed of a mixture of water, butylene glycol, Sophora flavescens root extract, Glycyrrhiza inflata root extract, and Scutellaria baicalensis root extract.

[0018] By adopting the above technical solution, adding the above skin conditioner can soothe sensitive skin, reduce irritation, and the antioxidant components contained in the skin conditioner can maintain the color stability of the eyeshadow paste, which is beneficial to improving the makeup-holding effect of the water-in-oil type aqueous eyeshadow paste.

[0019] In the second aspect, the present application provides a preparation method of a water-in-oil type aqueous eyeshadow paste, adopting the following technical solution: A preparation method of a water-in-oil type aqueous eyeshadow paste, including the following steps: S1: S11: After mixing cetearyl alcohol, synthetic wax, synthetic beeswax, emollient, and VP / hexadecene copolymer, stir and mix at 85-90 °C and 30-60 r / min for 8-10 min to obtain a mixture; S12: Take 15-20 wt% of the mixture and mix it with color powder, thickener I, thickener II, and filler, and grind it to a particle size of 10-30 μm to obtain the ground color powder; S13: Add the ground toner into the remaining mixture, and stir and mix at 85 - 90 °C and 30 - 60 r / min for 3 - 5 min to obtain the colored mixture; S14: Cool the colored mixture to 70 - 80 °C, then add polyether-silicone copolymer emulsifier, polyether-siloxane copolymer emulsifier, polysorbate emulsifier and volatile solvent, and stir and mix for 3 - 5 min to obtain the oil phase; S2: Stir and mix water, humectant and preservative at 70 - 80 °C and 30 - 60 r / min for 8 - 10 min, cool to 55 - 60 °C, then add skin conditioner and film-forming agent Ⅰ, and stir and mix for 3 - 5 min to obtain the water phase; S3: Add the water phase into the oil phase, and under the conditions of 55 - 60 °C, homogenization speed of 2500 - 3000 r / min and stirring speed of 30 - 45 r / min, homogenize and stir and mix for 8 - 10 min to obtain the emulsion; S4: Add pearlescent powder into the emulsion, and stir and mix at 40 - 45 °C and 30 - 45 r / min for 8 - 10 min, then cool to 25 - 35 °C to obtain the water-in-oil type aqueous eyeshadow paste.

[0020] By adopting the above technical solutions, first grind part of the mixture and toner without using a powder machine, which can greatly avoid the pollution caused by dust. Then mix the ground toner with the remaining mixture, and then add emulsifier, adjust the volatile solvent and match with grease, and carry out homogenization emulsification. The obtained water-in-oil type aqueous eyeshadow paste has high stability, film-forming property and water resistance, and excellent heat resistance, cold resistance and makeup holding effect. At the same time, in this application, the eyeshadow property is changed from the traditional powder to paste. Only by filling the liquid homogeneous emulsified paste can the production be completed. It is not only easier to realize automatic production line production, but also can improve the powder floating and powder flying of eyeshadow.

[0021] In summary, this application has the following beneficial effects: 1. Since this application uses cetyl PEG / PPG-10 / 1 polydimethylsiloxane and lauryl PEG-10 tris(trimethylsilyloxy)methylsilylethyl polydimethylsiloxane with similar structures to stabilize the silicone oil droplets and improve the stability of the water-in-oil system; polysorbate emulsifiers with different lipophilic group conformations can improve the compatibility of water and oil phase components, so the stability of the water-in-oil system is improved, making the water-in-oil type aqueous eyeshadow paste have excellent heat resistance and cold resistance; 2. In this application, VP / hexadecene copolymer and film-forming agent Ⅰ are added at the same time, which can increase the film-forming property and water resistance of the water-in-oil type aqueous eyeshadow paste, make it more fitting after application, and have a better makeup holding effect; 3. The method of the present application controls the process steps to add the aqueous phase to the oil phase, and the prepared water-in-oil type aqueous eyeshadow paste has high stability, is not easy to take off makeup, and is suitable for large-scale production. Detailed implementation manners

[0022] The present application will be further described in detail below in conjunction with embodiments.

[0023] Except for the special descriptions in the following table, the components used in the embodiments of the present application are all commercially available. Embodiments

[0024] Embodiment 1 A water-in-oil type aqueous eyeshadow paste, and its components and corresponding weights (kg) are shown in the following table.

[0025] The preparation method of the above water-in-oil type aqueous eyeshadow paste includes the following steps: S1: S11: Mix cetearyl alcohol, synthetic wax, synthetic beeswax, emollient and VP / hexadecene copolymer, and stir and mix at 85°C and 30 r / min for 10 min to obtain a mixture; S12: Take 20 wt% of the mixture and mix it with color powder, thickener I, thickener II, and filler, and grind it to a particle size of 10 μm to obtain the ground color powder; S13: Add the ground color powder to the remaining mixture, and stir and mix at 85°C and 30 r / min for 5 min to obtain a colored mixture; S14: Cool the colored mixture to 70°C, and then add polyether-silicone copolymer emulsifier, polyether-siloxane copolymer emulsifier, polysorbate emulsifier and volatile solvent, and stir and mix for 5 min to obtain an oil phase; S2: Mix water, humectant and preservative at 70°C and 30 r / min for 10 min, cool to 55°C, and then add skin conditioner and film-forming agent I, and stir and mix for 5 min to obtain an aqueous phase; S3: Add the aqueous phase to the oil phase, and under the conditions of 55°C, a homogenization speed of 2500 r / min, and a stirring speed of 30 r / min, homogenize and stir and mix for 10 min to obtain an emulsion; S4: Add pearlescent powder to the emulsion, stir and mix at 40°C and 30 r / min for 10 min, and cool to 25°C to obtain a water-in-oil type aqueous eyeshadow paste.

[0026] Embodiments 2-3 A water-in-oil type water-containing eye shadow paste, which is different from Example 1 in that the components and their corresponding weights (kg) are shown in the following table.

[0027] Examples 4 to 7 A water-in-oil type water-containing eye shadow paste, which is different from Example 1 in that the VP / hexadecene copolymer, film-forming agent I and their corresponding weights (kg) are shown in the following table.

[0028] Example 8 A water-in-oil type water-containing eye shadow paste, which is different from Example 1 in that the polyether-silicone copolymer emulsifier is PEG-12 polydimethylsiloxane, the polyether-siloxane copolymer emulsifier is bis-PEG-8 polydimethylsiloxane, and the polysorbate emulsifier is polysorbate 60.

[0029] Comparative Example Comparative Example 1 An eye shadow, which is a commercially available pressed eye shadow, and is composed of a mixture of mica, silica, synthetic fluorophlogopite, polyethylene, methyl methacrylate cross-linked polymer, hydrogenated polyisobutene, nylon-12, polydimethylsiloxane, butanediol dicaprylate / dicaprate, phenyltrimethylsiloxane, triethoxysilane octane, caprylic / capric triglyceride, phenoxyethanol, Cordyceps sinensis extract, Macadamia ternifolia seed oil, tocopheryl acetate, CI77491, pentaerythrityl tetra(bis-tert-butyl hydroxyhydrocinnamate), CI77492, CI77499, Ganoderma sinensis extract, Paeonia suffruticosa extract, Panax ginseng root extract, Saussurea involucrata extract.

[0030] Comparative Example 2 An eyeshadow, which is a commercially available baked eyeshadow, is composed of water, synthetic fluorophlogopite, silica, vinyl polydimethylsiloxane / polymethylsiloxane sesquisiloxane cross-linked polymer, bismuth oxyhydroxide, boron mononitride, cetyl alcohol ethylhexanoate, octyldodecyl stearoyloxystearate, diisostearyl malate, magnesium aluminum silicate, triethoxysilane octane, caprylic / capric triglyceride, octyldecanol, diethylhexyl syringylmalonate, phenoxyethanol, ethylhexylglycerin, sorbitan stearate, bis-diglycerol polyacyl adipate-2, CI77742, sodium hyaluronate, CI77007, CI15850, polyacrylamide, C13-14 isoparaffin, laureth-7 mixed composition.

[0031] Comparative Example 3 An eyeshadow, which is different from Example 1 in that an equal weight of polysorbate emulsifier is used to replace the polyether-silicone copolymer emulsifier.

[0032] Comparative Example 4 An eyeshadow, which is different from Example 1 in that an equal weight of polyether-silicone copolymer emulsifier is used to replace the polysorbate emulsifier.

[0033] Comparative Example 5 An eyeshadow, which is different from Example 1 in that the preparation method of the water-in-oil type water-containing eyeshadow paste includes the following steps: S1: S11: The same as Example 1 to obtain a mixture; S12: The same as Example 1 to obtain the ground color powder; S13: The same as Example 1 to obtain the colored mixture; S14: Cool the colored mixture to 90 °C, then add polyether-silicone copolymer emulsifier, polyether-siloxane copolymer emulsifier, polysorbate emulsifier and volatile solvent, stir and mix for 5 min to obtain an oil phase; S2: The same as Example 1 to obtain an aqueous phase; S3: Add the aqueous phase to the oil phase, and under the conditions of 50 °C, a homogenization speed of 2200 r / min, and a stirring speed of 30 r / min, homogenize and stir and mix for 10 min to obtain an emulsion; S4: Add pearlescent powder to the emulsion, stir and mix at 50 °C and 30 r / min for 10 min, and cool to 25 °C to obtain eyeshadow.

[0034] Performance testing Taking the water-in-oil type water-containing eyeshadow paste prepared in Examples 1-8 of the present application and the eyeshadows prepared in Comparative Examples 1-5 as samples, stability testing and makeup effect testing are carried out, and the testing methods are as follows: I. Stability testing Stability Test (at 50°C): The samples were left standing for 7 days, 30 days, and 90 days respectively in an environment with a temperature of 50 ± 2°C and a humidity of 50% RH. Visually check whether there are oil spots, melting, and powdering on the surface of the samples. If not, mark them as normal. Stability Test (at 45°C): The samples were left standing for 7 days, 30 days, and 90 days respectively in an environment with a temperature of 45 ± 2°C and a humidity of 50% RH. Visually check whether there are oil spots, melting, and powdering on the surface of the samples. If not, mark them as normal. Stability Test (at low temperature of -5 to 10°C): The samples were left standing for 7 days, 30 days, and 90 days respectively in an environment with a low temperature of -5 to 10°C. Visually check whether there are oil spots and white frost on the surface of the samples. If not, mark them as normal.

[0035] II. Makeup Effect Test 65 female volunteers were recruited. The age of each volunteer was between 22 and 25 years old, and the eye skin condition of each volunteer was good, without allergies, milia, etc. The 65 volunteers were randomly divided into 13 groups, with 5 people in each group.

[0036] The samples were distributed to 13 groups respectively, and one kind was applied around the eyes in each group. The eyeshadow cream was scored according to the makeup effect evaluation criteria in the following table, and the final result was the average value.

[0037] III. Performance Test Results (1) Stability Test Results By analyzing the data in the above table, it can be seen that the water-in-oil type water-containing eyeshadow creams prepared in Examples 1 - 8 of the present application were in normal properties after standing for 7 days, 30 days, and 90 days under the conditions of 50°C, 45°C, and low temperature of -5 to 10°C. For the water eyeshadow creams prepared in Comparative Examples 3 and 4, oil spots, melting, and powdering phenomena occurred in their properties after standing for 30 days and 90 days under the conditions of 50°C, 45°C, and low temperature of -5 to 10°C.

[0038] This shows that in the total raw materials for preparing the water-in-oil type water-containing eyeshadow cream of the present application, the compounding of polyether-silicone copolymer emulsifier, polyether-siloxane copolymer emulsifier, and polysorbate emulsifier can improve the stability of the water-in-oil type water-containing eyeshadow cream.

[0039] The water-based eyeshadow paste prepared in Comparative Example 5 showed oil spots, melting, and powdering phenomena after standing at 50 °C, 45 °C, and low temperature of -5 to 10 °C for 7 days. This indicates that in the preparation method of the water-in-oil type water-containing eyeshadow paste of the present application, by controlling the mixing temperature of the emulsifier in S14, the emulsification temperature and homogenization speed in S3, and the addition temperature of the pearlescent powder in S4, the stability of the water-in-oil type water-containing eyeshadow paste can be improved. The reason may be that if the mixing temperature of the emulsifier in S14 is too high, there is a risk of deactivation of the non-ionic emulsifier; if the emulsification temperature and homogenization speed in S3 are too low, there is a risk of demulsification; if the addition temperature of the pearlescent powder in S4 is too high, there is a risk of fading of the pearlescent powder.

[0040] (2) Makeup effect test results By analyzing the data in the above table, it can be seen that compared with Example 7, the scores of fineness, color rendering, adherence, and long-lastingness of Examples 1, 4-6 have all increased. This indicates that in the total raw materials for preparing the water-in-oil type water-containing eyeshadow paste of the present application, adding the water-based film-forming agent I or the oil-based film-forming agent VP / hexadecene copolymer will enhance the adherence and long-lastingness.

[0041] Compared with Examples 5 and 6, the scores of fineness, color rendering, adherence, and long-lastingness of Examples 1 and 4 have all increased. This indicates that in the total raw materials for preparing the water-in-oil type water-containing eyeshadow paste of the present application, adding both the water-based film-forming agent I and the oil-based film-forming agent VP / hexadecene copolymer will enhance the adherence and long-lastingness and increase the color rendering.

[0042] Compared with Example 4, Example 1 has higher scores for fineness, color rendering, adherence, and long-lastingness. This indicates that the combination ratio of the water-based film-forming agent I and the oil-based film-forming agent VP / hexadecene copolymer in Example 1 has a better effect.

[0043] Compared with Example 8, the scores of fineness, color rendering, adherence, and long-lastingness of Example 1 have all increased. This indicates that in the total raw materials for preparing the water-in-oil type water-containing eyeshadow paste of the present application, when the polyether-silicone copolymer emulsifier is cetyl PEG / PPG-10 / 1 polydimethylsiloxane, the polyether-siloxane copolymer emulsifier is lauryl PEG-10 tris(trimethylsiloxy)silylethyl polydimethylsiloxane, and the polysorbate emulsifier is polysorbate-80, the makeup effect of the water-in-oil type water-containing eyeshadow paste can be improved.

[0044] Compared with Comparative Examples 1 and 2, the scores of fineness, color rendering, adherence, and long-lastingness of Examples 1-8 have all increased. This indicates that the water-in-oil type water-containing eyeshadow paste of the present application has good effects in terms of powder fineness, color rendering, adherence, and long-lastingness compared with commercially available eyeshadows.

[0045] Compared with Comparative Examples 3 and 4, the scores of fineness, color rendering, conformability, and long-lasting makeup of Example 1 are all increased. This shows that in the total raw materials for preparing the water-in-oil type aqueous eyeshadow paste of the present application, the compounding of polyether-silicone copolymer emulsifiers, polyether-siloxane copolymer emulsifiers, and polysorbate emulsifiers can improve the makeup effect of the water-in-oil type aqueous eyeshadow paste.

[0046] Compared with Comparative Example 5, the scores of fineness, color rendering, conformability, and long-lasting makeup of Example 1 are all increased. This shows that in the preparation method of the water-in-oil type aqueous eyeshadow paste of the present application, by controlling the mixing temperature of the emulsifier in S14, the emulsification temperature and homogenization speed in S3, and the addition temperature of the pearlescent powder in S4, the makeup effect of the water-in-oil type aqueous eyeshadow paste can be improved.

[0047] This specific embodiment is only an explanation of the present application, and it is not a limitation of the present application. Those skilled in the art can make modifications to this embodiment without creative contributions according to needs after reading this specification, but as long as it is within the scope of the claims of the present application, it is protected by the patent law.

Claims

1. An oil-in-water type water-containing eye shadow cream, characterized in that, It is a water-in-oil emulsion system; The water-in-oil type water-containing eye shadow paste is composed of the following components by weight percentage: Emollient: 7.00 - 23.00% Filler: 2.00 - 20.00%; Humectant: 6.0 - 16.00%; Preservative: 0.4 - 0.8%; Skin conditioner: 0.1 - 0.5%; Volatile solvent: 10.00 - 15.00%; Cetearyl alcohol: 1 - 5%; Synthetic wax: 10 - 15%; Synthetic beeswax: 0.5 - 2%; Thickener I: 0.5 - 3%; Thickener II: 0.01 - 8%; VP / hexadecene copolymer: 0 - 5%; Film-forming agent I: 0 - 5%; Color powder: 10.00 - 15.00%; Pearlescent powder: 10.00 - 15.00%; Polyether-silicone copolymer emulsifier: 1 - 5%; Polyether-siloxane copolymer emulsifier: 0.5 - 3%; Polysorbate emulsifier: 0.5 - 3%; Water is the balance; The thickener I is composed of a mixture of lithium magnesium stearate montmorillonite, propylene carbonate, and isododecane; The thickener II is composed of a mixture of polydimethylsiloxane and cross-linked polydimethylsiloxane; The film-forming agent I is composed of a mixture of acrylate copolymer, water, ethanol, PPG-2-decyl polyether-30, sodium dehydroacetate, and sodium lauryl polyether sulfate; The hydrophilic-lipophilic balance value of the polyether-silicone copolymer emulsifier is 12 - 14; The hydrophilic-lipophilic balance value of the polyether-siloxane copolymer emulsifier is 5 - 7; The hydrophilic-lipophilic balance value of the polysorbate emulsifier is 14 - 16.

2. The water-in-oil type water-containing eye shadow paste according to claim 1, wherein The molecular weight of the polyether-silicone copolymer emulsifier is 1500 - 5000; the molecular weight of the polyether-siloxane copolymer emulsifier is 2000 - 6000; the molecular weight of the polysorbate emulsifier is 1200 - 1500.

3. The water-in-oil type water-containing eye shadow paste according to claim 2, wherein The polyether-silicone copolymer emulsifier is cetyl PEG / PPG-10 / 1 dimethicone, and the polyether-siloxane copolymer emulsifier is lauryl PEG-10 tris(trimethylsiloxy)silylethyl dimethicone.

4. The water-in-oil type water-containing eye shadow paste according to claim 2, characterized in that, The polysorbate emulsifier is polysorbate-80.

5. The water-in-oil type water-containing eye shadow paste according to claim 1, characterized in that, Calculated by the weight percentage of the water-in-oil type water-containing eye shadow paste, it includes 1 - 1.2% VP / hexadecene copolymer and 2 - 1.8% film-forming agent I.

6. The water-in-oil type water-containing eye shadow paste according to claim 1, characterized in that, The volatile solvent is isododecane.

7. The water-in-oil type aqueous eye shadow paste according to claim 1, characterized in that, The skin conditioner is composed of a mixture of water, butylene glycol, Sophora flavescens root extract, Glycyrrhiza inflata root extract, and Scutellaria baicalensis root extract.

8. The preparation method of the water-in-oil type water-containing eye shadow paste according to any one of claims 1 to 7, characterized in that, It includes the following steps: S1： S11: After stirring and mixing cetearyl alcohol, synthetic wax, synthetic beeswax, emollient, and VP / hexadecene copolymer, a mixture is obtained; S12: Take 15 - 20wt% of the mixture and stir and mix it with color powder, thickener I, thickener II, and filler, and then grind it to obtain the ground color powder; S13: Add the ground color powder to the remaining mixture, stir and mix to obtain the colored mixture; S14: Add polyether-silicone copolymer emulsifiers, polyether-siloxane copolymer emulsifiers, polysorbate emulsifiers and volatile solvents to the colored mixture at 70 - 80 °C, stir and mix to obtain the oil phase; S2: Stir and mix water, humectants and preservatives, then add skin conditioners and film-forming agent Ⅰ and stir and mix to obtain the aqueous phase; S3: Add the aqueous phase to the oil phase, and under the conditions of 55 - 60 °C and a homogenization speed of 2500 - 3000 r / min, homogenize, stir and mix to obtain the emulsion; S4: Add pearlescent powder to the emulsion, stir and mix at 40 - 45 °C, and then cool to 25 - 35 °C to obtain a water-in-oil type aqueous eyeshadow paste.

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