Yellowing-resistant SBS polymer and preparation method thereof

By purifying styrene and butadiene monomers twice and precisely controlling polymerization reaction conditions, and using alkylaluminum and alkyllithium compounds as impurity breakers, the yellowing problem of SBS polymers was solved, achieving highly efficient yellowing resistance.

CN121609855APending Publication Date: 2026-03-06CHINA PETROLEUM & CHEMICAL CORP +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-12-19
Publication Date
2026-03-06

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Abstract

The invention discloses an anti-yellowing SBS polymer and a preparation method thereof, and relates to the technical field of high-molecular copolymers. According to the preparation method of the yellowing-resistant SBS polymer, firstly, lithium alkyl or aluminum alkyl compound is used as an impurity breaking agent at a low temperature to react with unavoidable impurities in styrene and butadiene monomers and auto-polymers to form inert substances, then the inert substances are removed through a molecular sieve bed or distillation, and the yellowing-resistant SBS polymer is obtained. The anti-yellowing SBS polymer provided by the invention has the advantages that impurities in styrene and butadiene monomers are fully removed, the situation that a block copolymer SBS cannot be formed in the polymerization process is avoided, the anti-yellowing problem of the SBS polymer is radically solved, and on the basis, the anti-yellowing SBS polymer provided by the invention can be kept not yellowing for more than 2 hours under external thermal stimulation of 180 DEG C, and the anti-yellowing SBS polymer has good anti-yellowing performance. And under the double stimulation of 50 DEG C thermal stimulation and light and heat of a 500 W xenon lamp, the product can be kept without yellowing for more than 360 hours.
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