Fluorine-free water-based extinguishing agent, preparation method thereof and application thereof in thermal runaway of lithium battery

By utilizing the physical isolation and chemical passivation mechanisms of fluorine-free water-based fire extinguishing agents, the problem of efficient cooling and prevention of reignition in lithium battery thermal runaway is solved, achieving an environmentally friendly fire extinguishing effect suitable for new energy vehicles and energy storage power stations.

CN122399306APending Publication Date: 2026-07-17JIERUN TECH (GUANGZHOU) CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JIERUN TECH (GUANGZHOU) CO LTD
Filing Date
2026-05-14
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium battery fire extinguishing technologies suffer from weak cooling capacity, insufficient anti-reignition performance, or lack of environmental friendliness. Traditional dry powder and gaseous fire extinguishing agents cannot simultaneously meet the requirements of efficient cooling, deep suppression of reignition, and green environmental protection. Water-based fire extinguishing agents have cooling advantages but low fire extinguishing efficiency and poor anti-reignition ability. Fluorine-containing products are contrary to the trend of fluorine-free environmental protection and are also costly.

Method used

Using a fluorine-free water-based fire extinguishing agent, a combination of low-temperature hot-melt polymer powder and cationic natural polymer derivatives is used to cut off the triggering source of thermal runaway reignition through a dual path of physical isolation and chemical passivation. An anti-reignition combination agent is added to react and cross-link at high temperature to construct a micro-dense carbonized isolation layer, blocking oxygen diffusion and thermal feedback.

Benefits of technology

It achieves efficient heat absorption and cooling, rapid extinguishing of open flames, and suppression of micro-short circuits and thermal runaway re-ignition inside the battery. It is environmentally friendly, non-toxic, and non-corrosive, and is suitable for lithium battery-intensive applications such as new energy vehicles and energy storage power stations.

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Abstract

本申请涉及灭火剂领域,特别是涉及一种无氟水系灭火剂及其制备方法和在锂电池热失控中的应用。一种无氟水系灭火剂,以质量份计,其至少包括阻隔降温料10~20份,复合抑制剂2.5~5份,抗复燃组合剂0.6~2份以及去离子水90~95份。本申请所制得无氟水系灭火剂兼具高效吸热冷却与快速灭火能力、能有效抑制电池内短路及热失控复发,且完全不含氟、无毒低腐蚀、环境相容性优良的水系灭火剂,以满足锂电池密集应用场景的消防保护需求。
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