A benzotriazole polyurea microcapsule emulsion, a preparation method and applications thereof

By preparing benzotriazole-based polyurea microcapsule emulsions, the problems of easy migration and poor washability of benzotriazole-based UV absorbers in textile fabrics were solved, achieving high stability and long-lasting UV protection, and improving the washability and hand feel of the fabrics.

CN122399697APending Publication Date: 2026-07-17GUANGDONG HONGHAO CHEM CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
GUANGDONG HONGHAO CHEM CO LTD
Filing Date
2026-04-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Among existing UV-resistant finishing agents for textile fabrics, benzotriazole UV absorbers are prone to migration and have poor wash resistance, resulting in a rapid decline in UV resistance. Furthermore, existing microencapsulation technology has insufficient mechanical strength and poor density, making it impossible to achieve long-term protection.

Method used

Benzotriazole compounds were used as the core material, and isoflurane diisocyanate and ethylenediamine were used as the wall material. Benzotriazole polyurea microcapsule emulsions were prepared by interfacial polymerization. PEG-400 was used as a dispersant to control the particle size to 1~5μm, forming highly dense and mechanically stable microcapsules. Waterborne polyurethane adhesives were then used for textile finishing.

Benefits of technology

The stability and washability of the microcapsule emulsion are improved, ensuring long-lasting UV protection. The microcapsules are evenly attached to the fabric surface, enhancing the fabric's UV protection durability and softness, avoiding the defects of stiffness and poor breathability in existing technologies.

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Abstract

本发明公开了一种苯并三唑类聚脲微胶囊乳液、制备方法及其应用。本发明的苯并三唑类聚脲微胶囊乳液的制备方法,包括步骤:将苯并三唑类化合物、异氟尔酮二异氰酸酯于助溶剂中混合搅拌均匀形成油相;将PEG‑400、去离子水于反应容器中混合搅拌均匀形成水相;将油相缓慢滴入水相中搅拌分散形成水包油乳液;于水包油乳液中缓慢滴加乙二胺进行搅拌反应得苯并三唑类聚脲微胶囊乳液;其中,以质量份数计,包括10~20份异氟尔酮二异氰酸酯、4~8份乙二胺、2~8份苯并三唑类化合物、4~6份PEG‑400、14~18份助溶剂和80~120份去离子水。通过本发明制备方法制得的苯并三唑类聚脲微胶囊乳液具有优良的稳定性和致密性,且耐洗涤性能好,经多次洗涤后仍具有较好的抗紫外效果。
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