High-flame-retardant oil-absorbing composite aerogel, and preparation method and application thereof

By employing a stepwise approach of adding V2C MXene and bentonite, along with vapor-phase hydrophobic modification, the contradiction between hydrophobic modification and flame retardancy in bacterial cellulose-based aerogels was resolved. This resulted in the preparation of a composite aerogel with ultra-high oil absorption capacity and high flame retardant properties, suitable for oil spill recovery and oily wastewater treatment under high-temperature and fire-risk conditions.

CN122399773APending Publication Date: 2026-07-17GUANGXI UNIV
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Patent Information

Application Number
CN202610640256.1
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-11
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing bacterial cellulose-based aerogels are prone to pore blockage during hydrophobic modification, and flame retardant components are difficult to disperse evenly, making it difficult to balance oil absorption capacity and flame retardancy, and thus failing to meet the comprehensive performance requirements of high-temperature working conditions and fire-risk areas.

Method used

By adopting a stepwise addition strategy of V2C MXene and bentonite, combined with vapor-phase hydrophobic modification, a highly flame-retardant oil-absorbing composite aerogel was prepared in an aqueous system to construct a three-dimensional interpenetrating network structure, avoiding the blockage of pores by nano-components and forming a dense protective layer at high temperature.

Benefits of technology

It achieves efficient hydrophobic modification, preservation of pore integrity, and uniform loading of flame-retardant components, and possesses ultra-high oil absorption capacity, excellent cycle stability, and high flame-retardant performance, meeting the safety requirements for use under high temperature and fire risk conditions.

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Abstract

本发明公开了一种高阻燃吸油复合气凝胶及其制备方法与应用,属于功能复合材料及油水分离技术领域。发明通过酸性预分散与硅烷化反应将甲基三甲氧基硅烷接枝于细菌纤维素骨架,分步引入V2C MXene与膨润土构建三维互穿网络,再经气相疏水改性在保留多级孔道的同时赋予超疏水特性。本发明解决了物理共混分散不均及液相浸渍堵塞孔道导致吸油容量下降的问题。所得气凝胶800℃残重率77.82%,极限氧指数42.2%,UL‑94达V‑0级,水接触角142.6°,原油吸附量24.8 g / g,循环5次后保持22.2 g / g。本发明工艺温和、重现性好,适用于高温工况下的溢油应急与含油废水处理。
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