A high-nickel ternary positive electrode material, a preparation method and application thereof

By simultaneously modifying high-nickel ternary cathode materials through doping and coating, the problems of bulk structural instability and interfacial side reactions during cycling have been solved, resulting in a significant improvement in the structural stability and electrochemical performance of the materials, and promoting the commercial application of high-nickel ternary cathode materials.

CN122403522APending Publication Date: 2026-07-17江苏国轩新能源科技有限公司 +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
江苏国轩新能源科技有限公司
Filing Date
2026-04-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

High-nickel ternary cathode materials suffer from bulk structural instability and severe interfacial side reactions during cycling, affecting their cycle performance, rate performance, and safety performance. Single doping or coating modifications are insufficient to simultaneously solve these two core problems.

Method used

Two metal oxides with different properties are uniformly mixed with a high-nickel ternary precursor and sintered with lithium salt at high temperature to achieve simultaneous modification of doping and coating. Specifically, La2O3 and ZrO2 are selected as modifiers to form a stable inorganic layer coating material, which inhibits Li+/Ni2+ mixing and isolates the electrode from direct contact with the electrolyte.

Benefits of technology

It significantly improves the cycle stability and overall electrochemical performance of high-nickel ternary cathode materials, enhances the structural stability and electrochemical performance of the materials, and strengthens the rate performance and safety of the materials.

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Abstract

本申请涉及锂离子电池材料的技术领域,具体公开了一种高镍三元正极材料及其制备方法和应用。该材料的制备方法如下:将高镍三元前驱体、用于体相掺杂的第一类金属氧化物和用于表面包覆的第二类金属氧化物混合研磨并干燥,再与锂盐混合后进行分步高温烧结。第一类金属氧化物优选La2O3等镧系氧化物,第二类金属氧化物优选ZrO2、TiO2等。本申请通过一步烧结工艺,协同增强了材料体相结构稳定性和电极 / 电解液界面稳定性,显著抑制了循环过程中的容量衰减。所得材料在4.25V高电压下循环100圈后容量保持率可达93.4%以上,远高于单一改性或未改性材料,适用于高能量密度锂离子电池。
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Citation Information

Patent Citations

  • Doping modified ternary positive electrode material, preparation method thereof and battery

    CN120895640A

  • Preparation method of multi-element co-coated lithium ion ternary positive electrode material

    CN120914237A