A polymerization inhibitor composition, its use and method of evaluation

The polymerization inhibitor composition formed by compounding phenylenediamine and phenol compounds solves the problems of short polymerization inhibition time and high cost in the preparation of methyl methacrylate, achieves long-term polymerization inhibition effect and stable operation of the equipment, and provides a more accurate evaluation method.

CN122404147APending Publication Date: 2026-07-17KINGFA SCI & TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
KINGFA SCI & TECH CO LTD
Filing Date
2026-03-25
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing polymerization inhibitors have short polymerization inhibition times and high costs in the preparation of methyl methacrylate, and existing evaluation methods fail to fully consider the impact of actual working conditions, resulting in unsatisfactory polymerization inhibition effects.

Method used

A polymerization inhibitor composition is formed by combining p-phenylenediamine and phenolic compounds and adjusting the average viscosity with solvent. This composition is used in the preparation of methyl methacrylate to prevent the polymerization reaction.

Benefits of technology

It achieves long-term polymerization inhibition, avoids equipment blockage and shutdown, ensures stable operation of the reactor, and accurately evaluates the polymerization inhibition effect through an evaluation method that simulates the actual production process.

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Abstract

本发明公开了一种阻聚剂组合物及其应用和评价方法,所述阻聚剂组合物包括以下组分:对苯二胺类化合物、苯酚类化合物和溶剂;所述对苯二胺类化合物与所述苯酚类化合物的质量比为1:(0.005‑3);所述阻聚剂组合物在35℃下的平均粘度为10‑150cP。本发明采用对苯二胺类化合物和苯酚类化合物复配,两者能够共同作用,阻止甲基丙烯酸甲酯的聚合,并且通过溶剂将阻聚剂组合物调控至合适的平均粘度,能够确保实现良好的阻聚效果。本发明的阻聚剂组合物在用作甲基丙烯酸甲酯制备过程的阻聚剂中具有良好的应用效果,能够避免甲基丙烯酸甲酯制备过程中因原料、中间体或产物聚合而造成装置堵塞或停工等问题,保证反应装置稳定运行。
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