Preparation of conductive polymer pedot dispersions based on supercritical dispersion technology

By combining supercritical dispersion technology with compound dopants and crosslinking agents, the problems of agglomeration and low conductivity of PEDOT dispersions have been solved, realizing the preparation of efficient and stable conductive polymer PEDOT dispersions, which are suitable for flexible electronics and transparent electrode fields.

CN122404679APending Publication Date: 2026-07-17BEILI TECH (CHONGQING) CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the preparation of PEDOT dispersions suffers from slow low-temperature polymerization rates, low production efficiency, high energy consumption, uneven particle size, poor stability, and traditional dispersion methods are prone to agglomeration and impurity introduction, resulting in low conductivity, which makes it difficult to meet the requirements of high-end flexible electronic and optoelectronic devices.

Method used

Supercritical dispersion technology, combined with compound dopants and UV crosslinking agents, is used to prepare conductive polymer PEDOT dispersions by polymerization under supercritical conditions. The synergistic effect of perfluorosulfonic acid resin and sulfonated polyether ether ketone forms a stable binding structure. Combined with UV curing process, the crosslinking network can be precisely controlled.

Benefits of technology

It significantly improves the conductivity and environmental adaptability of PEDOT dispersions, ensures dispersion stability and film uniformity, extends service life, and meets the long-term stability requirements of flexible electronics and transparent electrodes.

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Abstract

本申请涉及有机光电子材料技术领域,具体公开了基于超临界分散技术制备导电聚合物PEDOT分散体,所述导电聚合物PEDOT分散体的制备步骤为:(1)将导电单体、掺杂剂、紫外交联剂和分散剂分散在有机溶剂中,搅拌均匀,得前驱体混合液;(2)将前驱体混合液加入高压反应釜中,通入超临界介质,维持超临界状态,进行聚合反应3‑6h,反应结束后,经卸压、离心处理和高压均质处理,得导电聚合物PEDOT分散体。该产物体积电导率高,功函数达5.29‑5.35eV,均方根粗糙度低,可提高载流子浓度与迁移率,改善薄膜形貌及界面适配性,在柔性电子、光电器件领域具有优异的应用潜力。
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