Preparation method and application of hierarchical structure magnesium-based prussian white hybrid flame-retardant and smoke-suppressing agent

By constructing a polyphenol functional transition layer on the surface of magnesium-based Prussian white and loading ultrafine Prussian blue nanoparticles, a hierarchical hybrid flame retardant and smoke suppressant is formed, which solves the problems of flammability and toxic smoke release of soft PVC and achieves a synergistic effect of flame retardancy, smoke suppression and toxicity reduction.

CN122404802APending Publication Date: 2026-07-17UNIV OF SCI & TECH OF CHINA

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
UNIV OF SCI & TECH OF CHINA
Filing Date
2026-06-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing flexible PVC materials are flammable and release toxic fumes. Traditional flame retardants suffer from resource scarcity, performance degradation, and poor interfacial compatibility, making it difficult to achieve the synergistic integration of multiple flame retardant mechanisms.

Method used

By constructing a polyphenol functional transition layer on the surface of sheet-like magnesium-based Prussian white and loading ultrafine Prussian blue analog nanoparticles in situ, a hierarchical magnesium-based Prussian white hybrid flame retardant and smoke suppressant is formed, achieving the synergistic effect of physical barrier, catalytic char formation and catalytic oxidation.

Benefits of technology

Only 3 to 7 parts of the additive can significantly improve the flame retardant, smoke suppression and toxicity reduction properties of flexible PVC. The flame retardant effect is improved by 19.0%, the heat release rate is reduced by 37.4%, the carbon monoxide release is reduced by 21.5%, and the release of toxic gases is significantly reduced.

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Abstract

本发明公开了一种分级结构镁基普鲁士白杂化阻燃抑烟剂的制备方法及其应用,属于阻燃高分子复合材料技术领域。本发明分级结构镁基普鲁士白杂化阻燃抑烟剂具有“片状镁基普鲁士白‑多酚功能过渡层‑超细普鲁士蓝类似物纳米颗粒”的三级复合结构,其中多酚功能过渡层具有双重络合锚定作用,实现了超细普鲁士蓝类似物纳米颗粒在片状镁基普鲁士白表面的原位、均匀且牢固负载,有效克服了纳米颗粒的团聚难题;此外,片状Mg‑PW提供物理屏障并促进成炭,外层超细PBA催化氧化有毒气体、降低烟气,二者协同增效,赋予高分子复合材料优异的阻燃、抑烟及减毒性能。
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