A coating for preparing high wear-resistant, super-hydrophilic transparent anti-reflective coating and a method for preparing anti-reflective coating by using the coating

CN122405073APending Publication Date: 2026-07-17SOUTHEAST UNIV
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Patent Information

Application Number
CN202610754426.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-28
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing photovoltaic transparent self-cleaning antireflective layers suffer from rapid degradation of their superhydrophilicity and self-cleaning properties due to friction and wear under complex service environments, limiting their large-scale application in photovoltaic modules.

Method used

An organic cross-linked network is formed by polyvinyl alcohol and epoxy acrylate resin, combined with porous silica, alumina and tin dioxide nanoparticles, and a highly wear-resistant, superhydrophilic hydrogen bond network coating is formed through hydrogen bonding and physical cross-linking. The coating is then applied to a glass substrate and cured at high temperature.

Benefits of technology

The resulting coating withstood over 7500 revolutions under a 500g load Taber abrasion test, still maintaining excellent superhydrophilic and antireflective properties, significantly improving the photoelectric conversion efficiency and long-term stability of photovoltaic modules.

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Abstract

本发明公开了一种用于制备高耐磨、超亲水透明减反涂层的涂料及采用上述涂料制备减反涂层的方法,所述涂料采用如下方法制备而成,具体步骤如下:(1)将聚乙烯醇加入到水中,于加热条件下搅拌,得到透明澄清无色溶液;往其中缓慢加入无水乙醇,继续搅拌,得到聚乙烯醇溶解液;往聚乙烯醇溶解液中加入环氧丙烯酸酯树脂和硅烷偶联剂,于加热条件下搅拌,得到有机交联浆料;(2)将多孔二氧化硅异丙醇分散液、多孔氧化铝水性分散液、二氧化锡分散液和表面活性剂加入到步骤(1)的有机交联浆料中,于加热条件下搅拌,得到透明的涂料。基于该涂料形成的减反涂层兼具优异的光学透过率、超亲水防雾自清洁性能与优异的机械耐磨性,能够保障减反涂层微观结构与化学组分在复杂摩擦环境下长期稳定。
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