Preparation method and process of medical magnesium alloy micro-arc oxidation sealing coating

By forming a high-thickness, low-porosity ceramic coating on the surface of magnesium alloy and performing calcium-phosphorus sealing treatment, the problems of degradation rate and uniformity of magnesium alloy materials are solved, corrosion resistance and biocompatibility are improved, and the stability and safety of implantable devices are ensured.

CN122406334APending Publication Date: 2026-07-17TIANJIN KANGER MEDICAL DEVICE

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
TIANJIN KANGER MEDICAL DEVICE
Filing Date
2026-04-27
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing medical magnesium alloy materials suffer from problems such as excessively rapid degradation rate, uneven degradation, poor corrosion resistance, and insufficient biocompatibility during the degradation process, leading to surgical failure and health risks.

Method used

A ceramic coating is grown in situ on the surface of a magnesium alloy using a micro-arc oxidation process. By optimizing the electrolyte composition and process parameters, a high-thickness, low-porosity coating is formed. Combined with a calcium-phosphorus sealing process, a dense double-layer protective structure is formed.

Benefits of technology

It significantly reduces the corrosion rate of magnesium alloys in physiological environments, improves biocompatibility and corrosion resistance, ensures the stability and safety of implanted devices at fracture sites, and reduces surgical pain and medical costs.

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Abstract

一种医用镁合金微弧氧化封孔涂层的制备方法及工艺,通过以下两个步骤得以实现:第一步骤:S1,将经机加工并完成清洗烘干后的镁合金样品作为阳极,不锈钢为阴极,在电解液中进行微弧氧化涂层制备;S2,所述的电解液组成包括:可溶性钙盐0.019mol / L,六偏磷酸钠5.0g / L,可溶性硅酸盐0.042mol / L,氢氧化钠0.036mol / L,氟化氢铵4.5g / L,甘油16.5mL / L;本发明从根本上解决了现有医用镁合金降解速率过快、降解均匀性差、微弧氧化涂层无法兼具高膜层厚度与表面低孔隙率的行业痛点。该制备方法工艺可控、操作简便,所制得的涂层与镁合金基体结合紧密,兼具优异的耐腐蚀性、生物相容性、力学稳定性与体内降解匹配性,在骨科植入器械等医用镁合金制品领域具有极高的应用价值。
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