On-site rapid detection device and method for phenolic endocrine disruptors in baby bottle washing liquid

By using electrospinning technology with a polyacrylonitrile/multi-walled carbon nanotube coating on the surface of a stainless steel needle, combined with nanoliter extraction electrospray ionization and a small portable mass spectrometer, the problem of rapid on-site detection of phenolic endocrine disruptors in baby bottle washing liquid has been solved, achieving efficient and rapid detection results.

CN122409808APending Publication Date: 2026-07-17CHINESE ACAD OF INSPECTION & QUARANTINE
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
CHINESE ACAD OF INSPECTION & QUARANTINE
Filing Date
2026-06-02
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Current technologies cannot achieve rapid on-site detection of phenolic endocrine disruptors in baby bottle washing solutions. Traditional methods require complex sample pretreatment and laboratory equipment, which cannot meet the needs of rapid analysis.

Method used

A rapid on-site detection device and method for phenolic endocrine disruptors in baby bottle washing liquid was established by using electrospinning technology to modify the surface of stainless steel needles with a polyacrylonitrile/multi-walled carbon nanotube coating, combined with nanoliter extraction electrospray ionization and a small portable mass spectrometer.

Benefits of technology

This study achieved efficient extraction and enrichment of six phenolic endocrine disruptors in baby bottle washing solution. The detection time was completed within 5 minutes, with a detection limit of 10-20 ng/mL, a quantitation limit of 20-50 ng/mL, an average recovery rate of 87.8-106.9%, and a relative standard deviation of 4.4-11.2%. It is suitable for rapid on-site analysis.

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Abstract

本发明公开了一种奶瓶洗液中酚类内分泌干扰物的现场快速检测方法,包括如下步骤:(A)装置搭建:搭建自制固相微萃取探针结合小型便携式质谱现场快速分析装置,包括制备聚丙烯腈 / 多壁碳纳米管固相微萃取探针和目标物质的萃取及解吸附,并组装各部分结构;(B)质谱分析:实施电喷雾电压,目标物质从探针上解吸附并形成电喷雾,随即进入小型便携式质谱进行分析。本发明建立了奶瓶洗液中6种酚类内分泌干扰物的现场快速分析方法,为洗涤用品质量安全现场快速检测及监督执法提供了技术支撑。
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