Lithium ion battery cathode material, preparation method and application thereof

By designing a core-shell structure with a manganese-rich surface and an iron-rich bulk in lithium manganese iron phosphate materials, and by using a spray method to precisely control the component distribution and combining doping and carbon coating, the contradiction between high voltage and long cycle stability of lithium manganese iron phosphate materials has been resolved, achieving a synergistic improvement in high energy density and excellent cycle performance.

CN122417840APending Publication Date: 2026-07-17XIAOGAN CORNEX NEW ENERGY INNOVATION TECHNOLOGY CO LTD
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
XIAOGAN CORNEX NEW ENERGY INNOVATION TECHNOLOGY CO LTD
Filing Date
2026-05-12
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing lithium manganese iron phosphate cathode materials present a contradiction in terms of improving operating voltage and cycle stability. Existing improvement schemes have failed to effectively coordinate and harmonize the electrochemical properties of manganese and iron, resulting in insufficient release of high voltage potential or insufficient cycle life.

Method used

A core-shell structured lithium manganese iron phosphate material is designed, with a higher manganese-to-iron ratio on the surface region than in the bulk phase. A manganese-rich surface layer and an iron-rich bulk phase are formed by precisely controlling a spray method. Combined with metal ion doping and carbon coating, the high-manganese region dominates the high voltage in the electrochemical reaction, while the iron-rich bulk phase provides structural stability.

Benefits of technology

It significantly improves the operating voltage and cycle stability of the material, achieving a balance between high energy density and long cycle life, and optimizes electrochemical performance.

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Abstract

本发明的技术领域涉及锂离子电池技术,具体涉及一种锂离子电池正极材料及其制备方法和应用。该正极材料为具有核壳梯度结构的磷酸锰铁锂,其体相具有第一锰铁比,表面区域具有第二锰铁比,且第二锰铁比高于第一锰铁比。该设计使得材料在充放电过程中能够通过表层富锰区域提供高工作电压,同时通过体相富铁区域保证结构稳定性,从而协同提升材料的能量密度与循环寿命。其制备方法关键在于采用分段进料喷雾法,通过控制前驱体溶液中锰、铁离子浓度比例随时间变化,精确构建上述梯度结构。本发明有效解决了现有磷酸锰铁锂材料难以兼顾高电压与长循环稳定性的问题,制备工艺可控,适于规模化生产。
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