Composite double-coated positive electrode material, preparation method thereof and battery

By employing a composite coating technology of cerium oxide buffer layer and reduced graphene oxide coating layer on the surface of high-nickel ternary cathode material, the structural instability and interfacial side reactions of the material during deep charge and discharge processes are solved, thereby improving the thermal stability and electrochemical performance of the material.

CN122417845APending Publication Date: 2026-07-17JINGMEN GEM NEW MATERIAL CO LTD +1
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
JINGMEN GEM NEW MATERIAL CO LTD
Filing Date
2026-05-20
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing high-nickel ternary cathode materials exhibit structural instability, severe interfacial side reactions, and poor thermal stability during deep charge-discharge processes. Current modification techniques struggle to simultaneously address issues such as oxygen release, interfacial corrosion, and slow charge transport.

Method used

By employing a composite double-coating technology, a buffer layer is constructed using cerium oxide to actively stabilize lattice oxygen and suppress oxygen release, while a three-dimensional electronic superconducting network is constructed using reduced graphene oxide, thereby synergistically improving the stability and kinetic properties of the material.

Benefits of technology

It significantly improves the thermal stability and cycle life of the material, enhances electronic conductivity, and reduces charge transfer impedance, achieving a synergistic enhancement of the stability and kinetic performance of high-nickel cathode materials.

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Abstract

本发明提供了一种复合双包覆正极材料及其制备方法和电池,所述复合双包覆正极材料包括正极材料内核和依次包覆于所述正极材料内核表面的铈氧化物缓冲层和还原氧化石墨烯包覆层。本发明提供的复合双包覆正极材料,利用铈氧化物的氧空位缓冲能力构建缓冲层,主动锚定和稳定晶格氧,抑制氧释放及由此引发的系列副反应;同时利用还原氧化石墨烯构建三维电子超导网络,极大提升材料的电子电导率,二者协同作用可以实现正极材料的稳定性与动力学性能协同强化。
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