Lithium secondary battery positive electrode active material and lithium secondary battery comprising the same

By using a bimodal lithium transition metal oxide combination in lithium secondary batteries, the problems of insufficient density and output characteristics of lithium-rich layered cathode materials were solved, thereby improving electrode energy density and battery life.

CN122423005APending Publication Date: 2026-07-17POSCO HLDG INC +1

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
POSCO HLDG INC
Filing Date
2024-12-17
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Lithium-rich layered cathode active materials have a high lithium content and a relatively low proportion of transition metals in their structure, resulting in low tap density and electrode density. Furthermore, the redox reaction easily generates oxygen, leading to insufficient electrode energy density and output characteristics.

Method used

The positive electrode active material for lithium secondary batteries with a bimodal structure includes a first lithium transition metal oxide and a second lithium transition metal oxide. By adjusting its particle size and weight ratio, the particle strength and electrode compaction density are improved, oxygen generation is suppressed, and the battery output characteristics are enhanced.

Benefits of technology

It significantly improves electrode energy density and battery output characteristics, extends battery life, and solves the problem of insufficient density and output characteristics of lithium-rich layered cathode materials in practical applications.

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Abstract

本发明涉及一种锂二次电池正极活性材料,其包含第一锂过渡金属氧化物及第二锂过渡金属氧化物,所述第一锂过渡金属氧化物及所述第二锂过渡金属氧化物各自独立地满足锂相对于过渡金属的摩尔比(Li / Me)大于1,所述第一锂过渡金属氧化物的平均粒径(D50)大于所述第二锂过渡金属氧化物的平均粒径(D50),所述第一锂过渡金属氧化物与所述第二锂过渡金属氧化物的重量含量比为60:40至80:20(第一锂过渡金属氧化物:第二锂过渡金属氧化物),所述第一锂过渡金属氧化物及所述第二锂过渡金属氧化物各自独立地满足BET比表面积为1.0至3.5m2 / g。
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