Concentrated washing agent composition with improved properties

Abstract

Detergent preparation containing, based on its total weight, a) 0.5 to 4 wt% of a polyalkoxylated amine with a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting ammonia or primary alkyl or hydroxyalkyl amines having a molecular weight below 200 g / mol with alkylene oxides; b) 0.5 to 4 wt% of an alcohol polyalkoxylate with a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting di- or triols with primary and / or secondary OH groups having a molecular weight Mw in the range of 60 g / mol to 200 g / mol with alkylene oxides and a process for textile cleaning using the free-flowing detergent composition.

Description

[0001] The present invention relates to a highly concentrated detergent preparation based on a combination of specific polyalkoxylated amines and alcohol polyalkoxylates. The application further relates to detergent portion units comprising this detergent preparation and to a method for washing textiles using the detergent preparation or the detergent portion unit.

[0002] The packaging and presentation of detergents and cleaning agents are subject to constantly changing requirements. For some time now, a major focus has been on convenient dosing by the consumer and simplifying the steps required for washing or cleaning. Pre-portioned detergents and cleaning agents, such as foil pouches with one or more compartments for solid or liquid detergents or cleaning agents, offer a technical solution.

[0003] A relevant trend in the production of these foil bags is their miniaturization. This development is driven not only by increased consumer acceptance due to simplified handling, but also by sustainability considerations, such as reduced transport volumes and costs, and the amount of packaging material used.

[0004] The increased concentration of modern detergents, especially modern liquid detergents, generally affects their optical and rheological properties, has an impact on the storage stability of these products, and can affect their cleaning performance, particularly if the high concentration of active ingredients leads to incompatibilities.

[0005] The European patent EP 3 122 849 B1 describes cleaning compositions which, in addition to other components, also contain polyalkoxylated amines.

[0006] International application WO 2017 / 151257 A1 describes alkoxylated diols and detergent compositions based on these alkoxylated diols.

[0007] Washing and cleaning agents are also known from WO 92 / 06153, JP 2007 / 161805, WO 97 / 26319, DE 102019216681, EP 3974507, WO 2022 / 063466 and US 4597898.

[0008] The application was based on the task of providing visually appealing, concentrated, free-flowing detergent preparations that are easy and efficient to produce, have good storage properties, and are characterized in particular by good cleaning results. Specifically, the detergent preparation should be packaged in water-soluble portion packs.

[0009] The first subject matter of the application is a detergent preparation containing, based on its total weight, a) 0.5 to 4 wt% of a polyalkoxylated amine with a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting ammonia or primary alkyl or hydroxyalkylamines having a molecular weight below 200 g / mol with alkylene oxides; b) 0.5 to 4 wt% of an alcohol polyalkoxylate with a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting di- or triols with primary and / or secondary OH groups having a molecular weight Mw in the range of 60 g / mol to 200 g / mol with alkylene oxides, wherein the alcohol polyalkoxylate is selected from the group of polypropylene glycols; and c) 0.1 to 3 wt.% of an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer, wherein the copolymer comprises a first EO block, a second EO block and a PO block, wherein the first EO block and the second EO block are connected to the PO block.

[0010] The detergent preparation is preferably liquid under standard conditions (20°C, 1013 mbar).

[0011] A key component of the detergent formulation is a specific polyalkoxylated amine with a weight fraction of 0.5 to 4 wt.%. Preferred detergent formulations contain, based on their total weight, 1 to 3 wt.%, preferably 1 to 2.5 wt.%, of polyalkoxylated amine. These weight fractions have proven advantageous for cleaning performance.

[0012] Preferred polyalkoxylated amines have a weight-average molecular weight Mw in the range of 1300 g / mol to 6000 g / mol, particularly from 1400 g / mol to 4500 g / mol. (The mean molecular weights given here and subsequently, if applicable, for other polymers, are weight-average molecular weights Mw, which can generally be determined by gel permeation chromatography using an RI detector, the measurement being expediently carried out against an external standard.)) For their preparation, one can start in a known manner from ammonia, a monoalkylamine, a monoalkyl monoalkanolamine or a monoalkyl dialkanolamine or a mono-, di- or trialanolamine, for example triethanolamine, methyl-, ethyl-, propyl- and isopropyl-diethanolamine, methyl-, ethyl-, propyl- and isopropyl-diisopropanolamine, tripropanolamine, triisopropanolamine, N,N-di-(2-hydroxyethyl)cyclohexylamine, N,N-di-(2-hydroxypropyl)cyclohexylamine, n-butylamine, n-hexylamine, n-octylamine, isopropylamine, sec-butylamine, tert-butylamine, cyclohexylamine, 2-ethylhexylamine, 2-phenylethylamine and mixtures thereof, which is combined with an alkylene oxide, in particular selected from the group consisting of ethylene oxide, propylene oxide, Butylene oxide and mixtures thereof, is reacted, in particular with a mixture containing propylene oxide and preferably ethylene oxide, especially preferably with propylene oxide.The polyalkoxylated amines obtained in this way can have block or random structures. A polyalkoxylated amine obtainable by propoxylation of triethanolamine is particularly preferred, preferably with each of its three side arms having a length of 15 propylene oxide units. A polyalkoxylated amine obtainable by propoxylation of triisopropanolamine is also preferred, preferably with each of its three side arms having a length of 15 propylene oxide units. Polyalkoxylated monoalkylamines with a linear, branched, or cyclic alkyl group are also suitable, wherein alkoxylation is performed with an alkylene oxide selected from the group consisting of ethylene oxide, propylene oxide, butylene oxide, and mixtures thereof, preferably with a mixture containing propylene oxide, and particularly preferably with propylene oxide.A polyalkoxylated amine obtainable by propoxylation of tert-butylamine is also preferred, preferably with a length of the two side arms of 12 propylene oxide units each.

[0013] Preferred polyalkoxylated amines satisfy the general formula (I), in which R represents a linear, optionally branched or optionally cyclic alkyl group with 1 to 12 C atoms or a group -(CH 2 CHR'O) n" -(CH 2 CHR"O) m" -H, R' and R" independently represent H, CH 3 or CH 2 CH 3, n, n' and n" independently represent numbers from 0 to 30, preferably from 0 to 10 and in particular from 0 to 5, and m, m' and m" independently represent numbers from 0 to 30, preferably from 5 to 20 and in particular from 12 to 16, with the proviso that the sum n + n' + n" + m + m' + m" is at least 14, preferably in the range of 18 to 100 and in particular in the range of 20 to 70. Preferably, in the compounds of formula I, at least one of the residues R' and R" is a CH 3 group.

[0014] Particularly preferred polyalkoxylated amines are obtained by ethoxylation and subsequent propoxylation of triethanolamine.

[0015] A second essential component is the alcohol polyalkoxylate, comprising 0.5 to 4 wt.% of the total weight of the detergent preparation. Particularly preferred detergent preparations, due to their washing properties, contain 1 to 3 wt.%, preferably 1 to 2.5 wt.%, of alcohol polyalkoxylate based on their total weight, wherein the alcohol polyalkoxylate is selected from the group of polypropylene glycols.

[0016] Preferred alcohol polyalkoxylates have a weight-average molecular weight Mw in the range of 1300 g / mol to 6000 g / mol, particularly from 1400 g / mol to 4500 g / mol. Alcohol polyalkoxylates satisfy the general formula (I). in which R represents a linear, optionally branched or optionally cyclic alkyl group with 1 to 12 C atoms or a group -(CH 2 CHR'O) n" -(CH 2 CHR"O) m" -H, R' and R" independently represent H, CH 3 or CH 2 CH 3, n, n' and n" independently represent numbers from 0 to 30, preferably from 0 to 10 and in particular from 0 to 5, and m, m' and m" independently represent numbers from 0 to 30, preferably from 5 to 20 and in particular from 12 to 16, with the proviso that the sum n + n' + n" + m + m' + m" is at least 14, preferably in the range of 18 to 100 and in particular in the range of 20 to 70.

[0017] For the cleaning performance of the detergent preparation, it has proven advantageous if the polyalkoxylated amine and the alcohol polyalkoxylate are present in a weight ratio of 5:1 to 1:5, preferably 3:1 to 1:3 and particularly 3:2 to 2:3.

[0018] A third essential component of the detergent preparation is 0.1 to 3 wt% of an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer, wherein the copolymer comprises a first EO block, a second EO block and a PO block, the first EO block and the second EO block being linked to the PO block.

[0019] The ethylene oxide-propylene oxide-ethylene oxide (EO / PO / EO) triblock copolymer preferably has an average propylene oxide chain length between 15 and 70, more preferably between 20 and 60, more preferably between 25 and 50, even more preferably between 25 and 40, most preferably between 25 and 35 propylene oxide units.

[0020] The average molecular weight of the ethylene oxide-propylene oxide-ethylene oxide (EO / PO / EO) triblock copolymer is preferably between 1000 and 10,000, preferably between 1500 and 5000, more preferably between 2000 and 4500, even more preferably between 2500 and 4000, most preferably between 2500 and 3000.

[0021] Each ethylene oxide chain of the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer preferably has an average chain length between 2 and 90, preferably between 3 and 50, more preferably between 4 and 20, even more preferably between 5 and 15, most preferably between 10 and 15 ethylene oxide units independently.

[0022] The ethylene oxide-propylene oxide-ethylene oxide triblock copolymer comprises, on average, between 10 wt.% and 90 wt.%, preferably between 20 wt.% and 70 wt.%, most preferably between 30 wt.% and 50 wt.% of the copolymer the combined ethylene oxide blocks, wherein, more preferably, the total ethylene oxide content is distributed over the two ethylene oxide blocks such that each ethylene oxide block comprises, on average, between 40% and 60%, preferably between 45% and 55%, even more preferably between 48% and 52%, most preferably 50% of the total number of ethylene oxide units, wherein the percentage of both ethylene oxide blocks together constitutes 100% of the ethylene oxide units present.

[0023] Preferred detergent preparations contain an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer with an average molecular weight between 2500 and 3000, an average propylene oxide content between 25 and 35 propylene oxide units, and an average ethylene oxide content between 10 and 15 ethylene oxide units per ethylene oxide block.

[0024] The polyalkoxylated amine and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in preferred detergent preparations in a weight ratio of 5:1 to 1:5.

[0025] Appropriate weight ratios have proven advantageous for the cleaning effect of the detergent preparation.

[0026] For the same reasons, detergent preparations are preferred in which the alcohol polyalkoxylate and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in a weight ratio of 5:1 to 1:5.

[0027] Preferred detergent preparations contain, based on their total weight, 35 to 55 wt.%, preferably 40 to 50 wt.% surfactant.

[0028] The group of surfactants includes nonionic, anionic, cationic, and amphoteric surfactants. The compositions according to the invention can comprise one or more of these surfactants. Particularly preferred compositions contain surfactants from the group of anionic and nonionic surfactants.

[0029] The anionic surfactant is preferably selected from the group comprising C9-C13 alkylbenzenesulfonates, olefin sulfonates, C12-C18 alkanesulfonates, ester sulfonates, alk(en)yl sulfates, fatty alcohol ether sulfates, and mixtures thereof. Compositions comprising C9-C13 alkylbenzenesulfonates and fatty alcohol ether sulfates as the anionic surfactant exhibit particularly good dispersing properties. Suitable sulfonate-type surfactants include preferably C9-C13 alkylbenzenesulfonates, olefin sulfonates (i.e., mixtures of alkene and hydroxyalkanesulfonates), and disulfonates, such as those obtained, for example, from C12-C18 monoolefins with terminal or internal double bonds by sulfonation with gaseous sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products.Also suitable are C 12 -C 18 -alkanesulfonates and the esters of α-sulfofaticial acids (estersulfonates), for example the α-sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.

[0030] Preferred detergent preparations contain, based on their total weight, 12 to 30 wt.%, preferably 15 to 28 wt.% and in particular 18 to 26 wt.% anionic surfactant.

[0031] It is particularly preferred if the composition contains at least one anionic surfactant of formula (I), in which R' and R" are independent H or alkyl and together contain 8 to 18, preferably 9 to 15 and in particular 9 to 13 C atoms and Y +< denote a monovalent cation or the nth part of an n-valent cation (in particular monoethanolamine).

[0032] The group of alkyl ether sulfates includes fatty alcohol ether sulfates, for example, the sulfuric acid monoesters of straight-chain or branched C7-C21 alcohols ethoxylated with 1 to 6 mol of ethylene oxide, such as 2-methyl-branched C9-C11 alcohols with an average of 3.5 mol of ethylene oxide (EO) or C12-C18 fatty alcohols with 1 to 4 EO. Alkyl ether sulfates with the formula (II) R1< -O-(AO)n-SO3-< X+< (II) are preferred.

[0033] In this formula (II), R<1> represents a linear or branched, substituted or unsubstituted alkyl group, preferably a linear, unsubstituted alkyl group, and particularly preferably a fatty alcohol group. Preferred R<1> groups of formula (II) are selected from decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, heptadecyl, octadecyl, nonadecyl, and eicosyl groups and mixtures thereof, with those having an even number of carbon atoms being preferred. Particularly preferred R<1> groups of formula (II) are derived from fatty alcohols with 12 to 18 carbon atoms, for example, coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl, or stearyl alcohol, or from oxo alcohols with 10 to 20 carbon atoms.

[0034] In formula (II), AO represents an ethylene oxide (EO) or propylene oxide (PO) group, preferably an ethylene oxide group. The index n in formula (I) is an integer from 1 to 50, preferably from 1 to 20, and particularly from 2 to 10. n 2, 3, 4, 5, 6, 7, or 8 is most preferred. X is a monovalent cation or the nth part of an n-valent cation, preferably the alkali metal ions, including Na⁺ or K⁺, with Na⁺ being most preferred. Further cations X⁺ can be selected from NH₄⁺, ½ Zn²⁺, ½ Mg²⁺, ½ Ca²⁺, ½ Mn²⁺, and mixtures thereof, as well as primary and secondary amines, particularly monoethanolamine.

[0035] Particularly preferred compositions contain an alkyl ether sulfate selected from fatty alcohol ether sulfates of formula (III) with k = 11 to 19, n = 2, 3, 4, 5, 6, 7, or 8. Particularly preferred representatives are Na fatty alcohol ether sulfates with 12 to 18 carbon atoms and 2 EOs (k = 11 to 13, n = 2 in Formula III). The stated degree of ethoxylation represents a statistical average, which may be a whole number or a fraction for a specific product. The stated degrees of alkoxylation represent statistical averages, which may be a whole number or a fraction for a specific product. Preferred alkoxylates / ethoxylates exhibit a narrow range of homologs (narrow range ethoxylates, NRE).

[0036] In summary, preferred detergent preparations contain, based on their total weight, 12 to 30 wt.%, preferably 15 to 28 wt.% and in particular 18 to 26 wt.% anionic surfactant from the group of C 8-18 alkylbenzenesulfonates and alkyl ether sulfates, preferably from the group of C 8-18 alkylbenzenesulfonates.

[0037] The use of fatty acids has proven advantageous for stability and cleaning performance. Preferred detergent preparations therefore contain 4 to 12 wt%, preferably 6 to 10 wt%, of fatty acids based on their total weight. Particularly preferred fatty acids are selected from the group consisting of caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof. For the purposes of this application, the fatty acids are not classified as anionic surfactants.

[0038] The detergent preparations contain a nonionic surfactant as a further preferred optional component. Its weight fraction in the total weight of the detergent preparation is preferably 12 to 30 wt.%, preferably 15 to 28 wt.%, and particularly 18 to 26 wt.%.

[0039] The use of a non-ionic surfactant from the group of alkyl ethoxylates is particularly preferred, wherein preferred alkyl ethoxylates are selected from the group of ethoxylated primary C 8-18 alcohols, preferably the ethoxylated primary C 8-18 alcohols with a degree of alkoxylation ≥ 4, particularly preferably the C 12-14 alcohols with 4 EO or 7 EO, the C 9-11 alcohols with 7 EO, the C 13-15 alcohols with 5 EO, 7 EO or 8 EO, the C 13-15 oxo alcohols with 7 EO, the C 12-18 alcohols with 5 EO or 7 EO, in particular the C 12-18 fatty alcohols with 7 EO or the C 13-15 oxo alcohols with 7 EO.

[0040] In summary, preferred detergent preparations contain, based on their total weight, 12 to 30 wt.%, preferably 15 to 28 wt.%, and particularly 18 to 26 wt.%, non-ionic surfactant from the group of ethoxylated primary C 8-18 alcohols, preferably ethoxylated primary C 8-18 alcohols with a degree of alkoxylation ≥ 4, particularly preferably C 12-14 alcohols with 4 EO or 7 EO, C 9-11 alcohols with 7 EO, C 13-15 alcohols with 5 EO, 7 EO or 8 EO, C 13-15 oxo alcohols with 7 EO, C 12-18 alcohols with 5 EO or 7 EO, in particular C 12-18 fatty alcohols with 7 EO or the C 13-15 -Oxo alcohols with 7 EO.

[0041] With regard to the rheological properties of the detergent preparation, its processability and cleaning effect, it has proven advantageous to use non-ionic surfactant and anionic surfactant in a weight ratio of 3:1 to 1:3, preferably 2:1 to 1:2 and particularly 3:2 to 2:3.

[0042] Preferred detergent preparations contain, based on their total weight, 2 to 15 wt.%, preferably 4 to 12 wt.% water.

[0043] In addition to water, at least one organic solvent is preferably used as a further solvent. The use of aqueous-organic solvent systems has proven particularly advantageous for manufacturability and shelf life and is therefore preferred.

[0044] In a preferred embodiment, the detergent preparation contains, based on its total weight, 8 to 30 wt.%, preferably 12 to 25 wt.% organic solvent.

[0045] Preferred organic solvents are selected from the group consisting of ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycyl, propyldiglycol, butyldiglycyl, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol tert-butyl ether, di-n-octyl ether, and the organic amines, in particular Monoethanolamine, and mixtures thereof, preferably from the group consisting of propanediol, glycerin, ethanol, monoethanolamine and mixtures thereof.

[0046] The detergent preparation contains a phosphonate as a preferred optional ingredient.

[0047] The weight fraction of the phosphonate in the total weight of the detergent preparation is preferably 0.1 to 3 wt.% and particularly 0.2 to 1 wt.%.

[0048] The phosphonate compound is preferably selected from the group of hydroxyalkane and / or aminoalkane phosphonates, preferably from the group of aminoalkane phosphonates and in particular from the group of ethylenediaminetetramethylenephosphonate (EDTMP) and diethylenetriaminepentamethylenephosphonate (DTPMP).

[0049] Due to their improved cleaning effect, detergent preparations are preferred which contain, as a further optional component, 0.2 to 7 wt.%, preferably 0.5 to 5 wt.% enzyme preparation.

[0050] An enzyme preparation comprises, in addition to the actual enzyme protein, other components such as enzyme stabilizers, carrier materials, or fillers. The enzyme protein typically constitutes only a fraction of the total weight of the enzyme preparation. Preferably, enzyme preparations contain between 0.1 and 40 wt.%, preferably between 0.2 and 30 wt.%, more preferably between 0.4 and 20 wt.%, and most preferably between 0.8 and 10 wt.% of the enzyme protein. In such compositions, an enzyme stabilizer may be present in an amount of 0.05 to 35 wt.%, preferably between 0.05 and 10 wt.%, based on the total weight in the enzyme composition.

[0051] Protein concentration can be determined using established methods, such as the BCA method (bicinchoninic acid; 2,2'-bicinolyl-4,4'-dicarboxylic acid) or the biuret method. The determination of the active protein concentration is carried out by titrating the active sites using a suitable irreversible inhibitor (for proteases, for example, phenylmethylsulfonylfluoride (PMSF)) and determining the residual activity.

[0052] It is preferred if the detergent preparation contains at least one enzyme preparation, preferably at least three enzyme preparations of enzymes from the group amylase, protease, cellulase and mannanase.

[0053] According to the invention, it is preferred if the detergent preparation contains at least one lipase preparation. Preferred lipases according to the invention are selected from at least one enzyme of the group consisting of triacylglycerol lipase (EC 3.1.1.3), lipoprotein lipase (EC 3.1.1.34), and monoglyceride lipase (EC 3.1.1.23).

[0054] Preferred lipase preparations according to the invention are the commercial products marketed by Amano Pharmaceuticals under the names Lipase M-AP10®, Lipase LE®, and Lipase F® (also Lipase JV®). Lipase F® is, for example, naturally present in Rhizopus oryzae. Lipase M-AP10® is, for example, naturally present in Mucor javanicus.

[0055] A highly preferred lipase is commercially available under the trade name Lipex® from Novozymes (Denmark) and can be advantageously used in the detergent preparations according to the invention. Lipex® 100 L is particularly preferred.

[0056] Preferred detergent preparations are characterized in that they contain 0.01 to 1 wt.%, in particular 0.05 to 0.3 wt.%, of lipase preparation based on their total weight.

[0057] The detergent preparations preferably contain at least one amylase, in particular an α-amylase. α-Amylases (EC 3.2.1.1) act as enzymes to hydrolyze internal α-1,4-glycosidic bonds of starch and starch-like polymers. Examples include α-amylases from Bacillus licheniformis, B. amyloliquefaciens, and B. stearothermophilus, as well as their improved formulations for use in detergents or cleaning agents. The enzyme from B. licheniformis is available from Novozymes under the trade name Termamyl® and from Genencor under the trade name Purastar® ST. Further developmental products of these α-amylases are available from Novozymes under the trade names Duramyl® and Termamyl® ultra, from Genencor under the name Purastar® OxAm, and from Daiwa Seiko Inc., Tokyo, Japan, as Keistase®. The α-amylase of B.Amyloliquefaciens is marketed by Novozymes under the name BAN®<, and derivatives of the α-amylase from B. stearothermophilus are marketed under the names BSG®< and Novamyl®<, also by Novozymes. Examples of α-amylases from other organisms include the further developments of α-amylase from Aspergillus niger and A. oryzae, available from Novozymes under the trade names Fungamyl®<.

[0058] The weight fraction of the amylase preparation, in particular the amylase preparation, in the total weight of the detergent preparation is preferably 0.1 to 2 wt.%, in particular 0.2 to 1 wt.%.

[0059] According to the invention, it is preferred if the detergent preparation contains at least one protease as an enzyme. A protease is an enzyme that cleaves peptide bonds by hydrolysis. According to the invention, each of the enzymes from class EC 3.4 falls under this category (comprising each of the thirteen subclasses included therein). "Protease activity" is present according to the invention if the enzyme possesses proteolytic activity (EC 3.4). Various types of protease activity are known: The three main types are: trypsin-like, wherein cleavage of the amide substrate occurs along the amino acids Arg or Lys at P1; chymotrypsin-like, wherein cleavage occurs along one of the hydrophobic amino acids at P1; and elastase-like, wherein cleavage of the amide substrate occurs along the Ala at P1.

[0060] Surprisingly, it was found that a protease of the alkaline protease type from Bacillus lentus DSM 5483, or a sufficiently similar protease (with respect to sequence identity) exhibiting several of these modifications in combination, is particularly suitable for use in the detergent preparations according to the invention and is advantageously stabilized therein. The advantages of using this protease thus arise particularly with regard to washing performance and / or stability.

[0061] Particularly preferably, the detergent preparation according to the invention contains a protease of the alkaline protease type from Bacillus lentus DSM 5483 or a sufficiently similar protease (with respect to sequence identity) which has several of these modifications in combination,

[0062] The weight fraction of the protease preparation in the total weight of the detergent preparation is preferably 0.2 to 5 wt.%, preferably 0.4 to 4 wt.%.

[0063] Preferred detergent preparations contain, as an optional component, based on their total weight, 0.05 to 2 wt.%, preferably 0.1 to 0.4 wt.%, of a preparation of a pectinolytic enzyme.

[0064] Within the scope of the present invention, the pectinolytic enzymes include enzymes designated as pectinase, pectate lyase, pectin esterase, pectin demethoxylase, pectin methoxylase, pectin methyl esterase, pectase, pectin methyl esterase, pectin pectyl hydrolase, pectin depolymerase, endopolygalacturonase, pectolase, pectin hydrolase, pectin polygalacturonase, endo-polygalacturonase, poly-α-1,4-galacturonide glycanohydrolase, endogalacturonase, endo-D-galacturonase, galacturan 1,4-α-galacturonidase, exopolygalacturonase, poly(galacturonate) hydrolase, exo-D-galacturonanase, and exo-D-galacturonanase. Exopoly-D-galacturonase, exopoly-α-galacturonosidase, exopolygalacturonosidase, or 25-exopolygalacturanosidase. The use of pectate lyases is particularly preferred.

[0065] Within the EC classification of enzymes, the numerical classification system for enzymes, pectinolytic enzymes belong specifically to the enzyme classes (Enzyme Commission numbers) EC 3.1.1.11, EC 3.2.1.15, EC 3.2.1.67, and EC 3.2.1.82. Consequently, they are part of the third of the six main enzyme classes, the 10 hydrolases (EC 3.1.1.1), specifically the glycosylases (EC 3.2.1.1.1), and within these, the glycosidases (EC 3.2.1.1.1), i.e., enzymes that hydrolyze O- and / or S-glycosyl compounds. Pectinolytic enzymes are therefore particularly effective against residues on dishes containing pectic acid and / or other galacturonans, and catalyze their hydrolysis.

[0066] Pectate lyases within the meaning of the invention are enzymes that catalyze the non-hydrolytic cleavage of pectate via an endo-mechanism.

[0067] Examples of suitable pectinolytic enzymes are the enzymes and enzyme preparations available under the trade names Gamanase®, Pectinex AR®, X-Pect® or Pectaway® from Novozymes, under the trade names Rohapect UF®, Rohapect TPL®, Rohapect PTE100®, Rohapect MPE®, Rohapect MA plus HC, Rohapect DA12L®, Rohapect 10L®, Rohapect B1L® from AB Enzymes and under the trade name Pyrolase® from Diversa Corp., San Diego, CA, USA.

[0068] The detergent preparation preferably contains 0.01 to 1 wt.%, preferably 0.02 to 0.3 wt.% of a mannanase preparation.

[0069] A mannanase catalyzes the hydrolysis of 1,4-beta-D-mannosidic bonds in mannans, galactomannans, glucomannan, and galactoglucomannan. These mannanases are classified as EC 3.2.1.78 according to enzyme nomenclature.

[0070] As a further preferred optional component, the detergent preparations contain a cellulase preparation. Synonymous terms can be used for cellulases, in particular endoglucanase, endo-1,4-beta-glucanase, carboxymethylcellulase, endo-1,4-beta-D-glucanase, beta-1,4-glucanase, beta-1,4-endoglucan hydrolase, celludextrinase, or avicelase. The decisive factor in determining whether an enzyme is a cellulase within the meaning of the invention is its ability to hydrolyze 1,4-β-D-glucosidic bonds in cellulose.

[0071] Suitable cellulases (endoglucanases, EG) according to the invention include, for example, fungal endoglucanase (EG)-rich compositions offered by Novozymes under the trade name Celluzyme®. The products Endolase® and Carezyme®, also available from Novozymes, are based on the 50 kDa EG and 43 kDa EG from Humicola insolens DSM 1800, respectively. Other usable trade products from this company are Cellusoft®, Renozyme®, and Celluclean®. Also suitable are, for example, cellulases available from AB Enzymes, Finland, under the trade names Ecostone® and Biotouch®, which are at least partially based on the 20 kDa EG from Melanocarpus. Other cellulases from AB Enzymes are Econase® and Ecopulp®. Other suitable cellulases are from Bacillus sp. CBS 670.93 and CBS 669.93, with the one from Bacillus sp. CBS 670 being the most suitable.93 is available from Danisco / Genencor under the trade name Puradax®. Other usable commercial products from Danisco / Genencor are "Genencor detergent cellulase L" and IndiAge® Neutra.

[0072] The weight fraction of the cellulase preparation in the total weight of the detergent preparation is preferably 0.01 to 1 wt.%, preferably 0.05 to 0.3 wt.%.

[0073] As an additional preferred component, the detergent preparation contains a polyalkoxylated polyalkylenemine, which is obtainable by reacting polyalkylenemines with alkylene oxides. Particularly preferred detergent preparations, based on their cleaning performance, contain 0.5 to 10 wt%, preferably 0.5 to 6 wt%, of polyalkoxylated polyalkylenemine, based on their total weight.

[0074] The polyalkoxylated polyalkylenemine is a polymer with a polyalkylenemine backbone bearing polyalkoxy groups at the nitrogen atoms. It preferably has a weight-average molecular weight (Mw) in the range of 5000 g / mol to 60000 g / mol, particularly from 10000 g / mol to 22500 g / mol. The polyalkylenemine has primary amino groups at its ends and preferably both secondary and tertiary amino groups in its interior; optionally, it may also have only secondary amino groups in its interior, resulting in a linear rather than a branched-chain polyalkylenemine. The ratio of primary to secondary amino groups in the polyalkylenemine is preferably in the range of 1:0.5 to 1:1.5, particularly in the range of 1:0.7 to 1:1. The ratio of primary to tertiary amino groups in the polyalkylenemine is preferably in the range of 1:0.2 to 1:1, particularly in the range of 1:0.5 to 1:0.8.Preferably, the polyalkylenemine has a weight-average molecular weight in the range of 500 g / mol to 50,000 g / mol, particularly from 550 g / mol to 2,000 g / mol. The nitrogen atoms in the polyalkylenemine are preferably separated from one another by alkylene groups with 2 to 12 carbon atoms, particularly 2 to 6 carbon atoms, whereby not all alkylene groups need to have the same number of carbon atoms. Ethylene groups, 1,2-propylene groups, 1,3-propylene groups, and mixtures thereof are particularly preferred. The primary amino groups in the polyalkylenemine can bear 1 or 2 polyalkoxy groups, and the secondary amino groups can bear 1 polyalkoxy group, whereby not every amino group needs to be alkoxy substituted. The average number of alkoxy groups per primary and secondary amino function in the polyalkoxylated polyalkyenimine is preferably 5 to 100, particularly 10 to 50.The alkoxy groups in the polyalkoxylated polyalkylenemine are preferably ethoxy, propoxy, or butoxy groups, or mixtures thereof. Polyethoxylated polyethyleneimines are particularly preferred. The polyalkoxylated polyalkylenemines are accessible by reacting the polyalkylenemines with the alkoxy groups of corresponding epoxides. Optionally, the terminal OH function of at least some of the polyalkoxy substituents can be replaced by an alkyl ether function with 1 to 10, and in particular 1 to 3, carbon atoms.

[0075] A preferred detergent preparation optionally comprises 0.2 to 4 wt.%, preferably 0.5 to 3 wt.% fragrance preparation.

[0076] In addition to the actual fragrance ingredients, the fragrance preparation includes, for example, solvents, solid carrier materials or stabilizers.

[0077] A fragrance is a chemical substance that stimulates the sense of smell. To stimulate the sense of smell, the chemical substance should be at least partially dispersible in the air, meaning the fragrance should be at least slightly volatile at 25°C. If the fragrance is highly volatile, the odor intensity dissipates quickly. With lower volatility, however, the odor impression is more lasting, meaning it does not disappear as quickly. In one embodiment, the fragrance therefore has a melting point in the range of -100°C to 100°C, preferably from -80°C to 80°C, even more preferably from -20°C to 50°C, and particularly from -30°C to 20°C. In another embodiment, the fragrance has a boiling point in the range of 25°C to 400°C, preferably 50°C to 380°C, more preferably 75°C to 350°C, and in particular 100°C to 330°C.

[0078] In general, a chemical substance should not exceed a certain molecular mass to function as a fragrance, as the required volatility cannot be guaranteed if the molecular mass is too high. In one embodiment, the fragrance has a molecular mass of 40 to 700 g / mol, or more preferably, 60 to 400 g / mol.

[0079] The scent of a fragrance is perceived as pleasant by most people and often corresponds to the smell of, for example, flowers, fruits, spices, bark, resin, leaves, grasses, mosses, and roots. Fragrances can therefore be used to mask unpleasant odors or to imbue an odorless substance with a desired scent. Individual odorant compounds, such as synthetic products like esters, ethers, aldehydes, ketones, alcohols, and hydrocarbons, can be used as fragrances.

[0080] Preferably, mixtures of different fragrances are used, which together create an appealing scent. Such a mixture of fragrances can also be called perfume or perfume oil. These perfume oils can also contain natural fragrance mixtures, such as those available from plant sources.

[0081] To prolong the fragrance effect, encapsulating the fragrance has proven advantageous. In a corresponding embodiment, at least a portion of the fragrance is used in encapsulated form (fragrance capsules), particularly in microcapsules. However, the entire fragrance can also be used in encapsulated form. The microcapsules can be water-soluble and / or water-insoluble. For example, melamine-urea-formaldehyde microcapsules, melamine-formaldehyde microcapsules, urea-formaldehyde microcapsules, or starch microcapsules can be used. "Fragrance precursor" refers to compounds that release the actual fragrance only after chemical conversion / decomposition, typically through exposure to light or other environmental conditions such as pH, temperature, etc. Such compounds are also frequently referred to as fragrance precursors or "pro-fragrances."

[0082] The composition of some preferably liquid (20°C, 1013 mbar) detergent preparations can be found in the following tables (values ​​in wt.% based on the total weight of the preparation unless otherwise specified). Formulas 1-4, 9-12, 17-20, 25-28, 33-36, 41-44 are not according to the invention. The detergent preparations are particularly preferably packaged as detergent portion units in which the detergent preparation is completely enclosed by a water-soluble film. formula 1 Formula 2 Formula 3 Formula 4 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 Misc ad 100 ad 100 ad 100 ad 100 Formula 5 Formula 6 Formula 7 Formula 8 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 Misc ad 100 ad 100 ad 100 ad 100 Formula 9 Formula 10 Formula 11 Formula 12 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Misc ad 100 ad 100 ad 100 ad 100 Formula 13 Formula 14 Formula 15 Formula 16 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Misc ad 100 ad 100 ad 100 ad 100 Formula 17 Formula 18 Formula 19 Formula 20 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 fatty acid 4 to 12 4 to 12 4 to 12 6 to 10 Misc ad 100 ad 100 ad 100 ad 100 Formula 21 Formula 22 Formula 23 Formula 24 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 fatty acid 4 to 12 4 to 12 4 to 12 6 to 10 Misc ad 100 ad 100 ad 100 ad 100 Formula 25 Formula 26 Formula 27 Formula 28 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Phosphonate 0.1 to 3 0.1 to 3 0.1 to 3 0.2 to 1 Misc ad 100 ad 100 ad 100 ad 100 Formula 29 Formula 30 Formula 31 Formula 32 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Phosphonate 0.1 to 3 0.1 to 3 0.1 to 3 0.2 to 1 Misc ad 100 ad 100 ad 100 ad 100 Formula 33 Formula 34 Formula 35 Formula 36 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Enzyme preparation 0.2 to 7 0.2 to 7 0.2 to 7 0.5 to 5 Misc ad 100 ad 100 ad 100 ad 100 Formula 37 Formula 38 Formula 39 Formula 40 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 Enzyme preparation 0.2 to 7 0.2 to 7 0.2 to 7 0.5 to 5 Misc ad 100 ad 100 ad 100 ad 100 Formula 41 Formula 42 Formula 43 Formula 44 polyalkoxylated amine 1)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 2)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 fatty acid 4 to 12 4 to 12 4 to 12 6 to 10 Phosphonate 0.1 to 3 0.1 to 3 0.1 to 3 0.2 to 1 Enzyme preparation 0.2 to 7 0.2 to 7 0.2 to 7 0.5 to 5 Misc ad 100 ad 100 ad 100 ad 100 Formula 45 Formula 46 Formula 47 Formula 48 polyalkoxylated amine 3)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 Alcohol polyalkoxylate 4)< 0.5 to 4 1 to 3 1 to 3 1 to 2.5 (EO / PO / EO)-Triblock copolymer 0.1 to 3 0.1 to 3 0.2 to 2.5 0.2 to 2.5 surfactant 35 via 55 35 to 50 40 to 50 40 to 50 fatty acid 4 to 12 4 to 12 4 to 12 6 to 10 Phosphonate 0.1 to 3 0.1 to 3 0.1 to 3 0.2 to 1 Enzyme preparation 0.2 to 7 0.2 to 7 0.2 to 7 0.5 to 5 Misc ad 100 ad 100 ad 100 ad 100 1) < Polyalkoxylated amine with a weight-average molecular weight Mw in the range of 600 g / mol to 10,000 g / mol, obtainable by reacting ammonia or primary alkyl or hydroxyalkylamines having a molecular weight below 200 g / mol with alkylene oxides. 2) < Alcohol polyalkoxylate with a weight-average molecular weight Mw in the range of 600 g / mol to 10,000 g / mol, obtainable by reacting di- or triols with primary and / or secondary OH groups having a molecular weight Mw in the range of 60 g / mol to 200 g / mol with alkylene oxides. 3) < Polyalkoxylated amine obtainable by ethoxylation and subsequent propoxylation of triethanolamine. 4) < Alcohol polyalkoxylate selected from the group of polypropylene glycols.

[0083] The material systems described above are not only suitable for ensuring ease of manufacture, good shelf life, and cleaning performance, but also enable the realization of a product appearance that is attractive to consumers. For example, detergent preparations that are transparent and consequently exhibit low turbidity are perceived as visually appealing. Preferred detergent preparations therefore have a turbidity (HACH Turbidimeter 2100Q, 20°C, 10 ml cuvette) below 100 NTU, preferably below 50 NTU, and particularly below 20 NTU. At an NTU value (at 20°C) of 60 or more, molded bodies exhibit a perceptible turbidity, visible to the naked eye, in accordance with the invention.

[0084] The visual advantages of concentrated detergent preparations are particularly evident in packaging materials that are transparent and allow a direct view of the detergent composition. Therefore, in addition to transparent plastic bottles, transparent pouches, especially water-soluble transparent pouches, are preferred for packaging and assembly.

[0085] Another preferred subject matter of this application is therefore a detergent portion unit comprising i) a detergent preparation according to the invention ii) a water-soluble film which completely encloses the detergent preparation.

[0086] The water-soluble film in which the detergent preparation is packaged can comprise one or more structurally different water-soluble polymers. Particularly suitable water-soluble polymers include polymers from the group of (optionally acetalized) polyvinyl alcohols (PVALs) and their copolymers.

[0087] Water-soluble films are preferably based on a polyvinyl alcohol or a polyvinyl alcohol copolymer whose molecular weight is in the range of 10,000 to 1,000,000 gmol -1< , preferably from 20,000 to 500,000 gmol -1< , particularly preferably from 30,000 to 100,000 gmol -1< and particularly from 40,000 to 80,000 gmol -1< .

[0088] The production of polyvinyl alcohols and polyvinyl alcohol copolymers generally involves the hydrolysis of intermediate polyvinyl acetates. Preferred polyvinyl alcohols and polyvinyl alcohol copolymers have a degree of hydrolysis of 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol%, and especially 82 to 88 mol%.

[0089] Preferred polyvinyl alcohol copolymers comprise, in addition to vinyl alcohol, an ethylene-unsaturated carboxylic acid, its salt, or its ester. Particularly preferred are such polyvinyl alcohol copolymers containing, besides vinyl alcohol, sulfonic acids such as 2-acrylamido-2-methyl-1-propanesulfonic acid (AMPS), acrylic acid, methacrylic acid, acrylic acid esters, methacrylic acid esters, or mixtures thereof; among the esters, C1-4 alkyl esters or hydroxyalkyl esters are preferred. Further monomers include ethylene-unsaturated dicarboxylic acids, for example, itaconic acid, maleic acid, fumaric acid, and mixtures thereof.

[0090] Suitable water-soluble films for use are distributed by companies such as MonoSol LLC, for example under the designations M8630, M8720, M8310, C8400, or M8900. Films such as Solublon®< PT, Solublon®< GA, Solublon®< KC, or Solublon®< KL from Aicello Chemical Europe GmbH, or the VF-HP films from Kuraray, are also suitable.

[0091] The water-soluble films may contain additional active ingredients or fillers, as well as plasticizers and / or solvents, especially water.

[0092] Other active ingredients include, for example, materials that protect the ingredients of the preparation, enclosed by the film material, from degradation or deactivation by light exposure. Antioxidants, UV absorbers, and fluorescent dyes have proven particularly suitable for this purpose.

[0093] Examples of plasticizers that can be used include glycerin, ethylene glycol, diethylene glycol, propanediol, 2-methyl-1,3-propanediol, sorbitol or mixtures thereof.

[0094] To reduce its coefficient of friction, the surface of the water-soluble film of the detergent portion unit can optionally be dusted with fine powder. Sodium aluminosilicate, silicon dioxide, talc, and amylose are examples of suitable powders.

[0095] Preferred water-soluble films are suitable for processing in a thermoforming apparatus.

[0096] The volume of the detergent portion unit is preferably from 12 to 22 ml, in particular from 12 to 20 ml.

[0097] Preferred detergent portion units have one to four receiving chambers, preferably three or four. In detergent portion units with two or more receiving chambers, preferably at least one, and preferably the majority, of the receiving chambers is transparent.

[0098] Another subject matter of the application is a method for textile cleaning in which a previously described detergent preparation or detergent portion unit is introduced into the washing liquor of a textile washing machine. The textile cleaning method is preferably used for cleaning cotton fabrics or polyester.

[0099] In preferred process variants, the detergent preparation or the detergent portion unit is dosed directly into the drum or into the detergent dispenser drawer of the textile washing machine.

[0100] The machine washing process preferably takes place at temperatures of 15 to 35°C, preferably from 15 to 25°C.

[0101] This registration will provide, among other things, the following items: 1. Detergent preparation containing, based on its total weight, a) 0.5 to 4 wt% of a polyalkoxylated amine having a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting ammonia or primary alkyl or hydroxyalkyl amines having a molecular weight below 200 g / mol with alkylene oxides; b) 0.5 to 4 wt% alcohol polyalkoxylate with a weight-average molecular weight Mw in the range of 600 g / mol to 10000 g / mol, obtainable by reacting di- or triols with primary and / or secondary OH groups having a molecular weight Mw in the range of 60 g / mol to 200 g / mol with alkylene oxides, wherein the alcohol polyalkoxylate is selected from the group of polypropylene glycols; and c) 0.1 to 3 wt%-% of an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer, wherein the copolymer comprises a first EO block, a second EO block, and a PO block, the first EO block and the second EO block being linked to the PO block. 2. Detergent preparation according to point 1, wherein the detergent preparation contains, based on its total weight, 1 to 3 wt.%, preferably 1 to 2.5 wt.%, polyalkoxylated amine. 3. Detergent preparation according to any of the preceding points, wherein the polyalkoxylated amine has a weight-average molecular weight Mw in the range of 1300 g / mol to 6000 g / mol, in particular from 1400 g / mol to 4500 g / mol. 4. Detergent preparation according to any of the preceding points, wherein the polyalkoxylated amine conforms to general formula (I). in which R represents a linear, optionally branched or optionally cyclic alkyl group with 1 to 12 C atoms or a group -(CH 2 CHR'O) n" -(CH 2 CHR"O) m" -H, R' and R" independently represent H, CH 3 or CH 2 CH 3, n, n' and n" independently represent numbers from 0 to 30, preferably from 0 to 10 and in particular from 0 to 5, and m, m' and m" independently represent numbers from 0 to 30, preferably from 5 to 20 and in particular from 12 to 16, with the proviso that the sum n + n' + n" + m + m' + m" is at least 14, preferably in the range of 18 to 100 and in particular in the range of 20 to 70. Preferably, in the compounds of formula I, at least one of the R' and R" residues is a CH3 group. 5. Detergent preparation according to one of the preceding steps, wherein the polyalkoxylated amine is obtained by ethoxylation and subsequent propoxylation of triethanolamine. 6.7. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 1 to 3 wt%, preferably 1 to 2.5 wt%, of alcohol polyalkoxylate. 8. Detergent preparation according to any one of the preceding clauses, wherein the alcohol polyalkoxylate has a weight-average molecular weight Mw in the range of 1300 g / mol to 6000 g / mol, in particular from 1400 g / mol to 4500 g / mol. 9. Detergent preparation according to any one of the preceding clauses, wherein the polyalkoxylated amine and the alcohol polyalkoxylate are present in a weight ratio of 5:1 to 1:5, preferably from 3:1 to 1:3, and in particular from 3:2 to 2:3.Detergent preparation according to any one of the preceding points, wherein the ethylene oxide-propylene oxide-ethylene oxide (EO / PO / EO) triblock copolymer has an average propylene oxide chain length between 15 and 70, preferably between 20 and 60, more preferably between 25 and 50, even more preferably between 25 and 40, most preferably between 25 and 35 propylene oxide units. 10. Detergent preparation according to any one of the preceding points, wherein the ethylene oxide-propylene oxide-ethylene oxide (EO / PO / EO) triblock copolymer has an average molecular weight between 1000 and 10,000, preferably between 1500 and 5000, more preferably between 2000 and 4500, even more preferably between 2500 and 4000, most preferably between 2500 and 3000. 11.A detergent preparation according to any one of the preceding clauses, wherein each ethylene oxide chain of the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer independently has an average chain length between 2 and 90, preferably between 3 and 50, more preferably between 4 and 20, even more preferably between 5 and 15, and most preferably between 10 and 15 ethylene oxide units. A detergent preparation according to any one of the preceding clauses, wherein the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer contains on average between 10 wt.% and 90 wt.%, preferably between 20 wt.% and 70 wt.%, and most preferably between 30 wt.% and 50 wt.%.-% of the copolymer comprises the combined ethylene oxide blocks, wherein more preferably the total ethylene oxide content is distributed over the two ethylene oxide blocks such that each ethylene oxide block comprises on average between 40% and 60%, preferably between 45% and 55%, more preferably between 48% and 52%, and most preferably 50% of the total number of ethylene oxide units, wherein the percentage of both ethylene oxide blocks together constitutes 100% of the ethylene oxide units present. 13. Detergent preparation according to any of the preceding points, wherein the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer has an average molecular weight between 2500 and 3000, an average propylene oxide content between 25 and 35 propylene oxide units, and an average ethylene oxide content between 10 and 15 ethylene oxide units per ethylene oxide block. 14.15. Detergent preparation according to any one of the preceding clauses, wherein the polyalkoxylated amine and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in a weight ratio of 5:1 to 1:5. 16. Detergent preparation according to any one of the preceding clauses, wherein the alcohol polyalkoxylate and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in a weight ratio of 5:1 to 1:5. 17. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 35 to 55 wt.%, preferably 40 to 50 wt.% surfactant. 18. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 12 to 30 wt.%, preferably 15 to 28 wt.%, and particularly 18 to 26 wt.% anionic surfactant. 18. Preparation of detergent according to one of the preceding points, wherein the detergent preparation, based on its total weight, is 12 to 30 wt.-%, preferably 15 to 28 wt.% and particularly 18 to 26 wt.% anionic surfactant from the group of C 8-18 alkylbenzenesulfonates and alkyl ether sulfates, preferably from the group of C 8-18 alkylbenzenesulfonates. 19. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 12 to 30 wt.%, preferably 15 to 28 wt.% and particularly 18 to 26 wt.% nonionic surfactant. 20. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 12 to 30 wt.%, preferably 15 to 28 wt.%-% and in particular 18 to 26 non-ionic surfactant from the group of ethoxylated primary C 8-18 alcohols, preferably the ethoxylated primary C 8-18 alcohols with a degree of alkoxylation ≥ 4, particularly preferably the C 12-14 alcohols with 4 EO or 7 EO, the C 9-11 alcohols with 7 EO, the C 13-15 alcohols with 5 EO, 7 EO or 8 EO, the C 13-15 oxo alcohols with 7 EO, the C 12-18 alcohols with 5 EO or 7 EO, in particular the C 12-18 fatty alcohols with 7 EO or the C 13-15 oxo alcohols with 7 EO. 21. A detergent preparation according to any of the preceding clauses, wherein the detergent preparation contains non-ionic surfactant and anionic surfactant in a weight ratio of 3:1 to 1:3, preferably 2:1 to 1:2, and particularly 3:2 to 2:3. 22. A detergent preparation according to any of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 4 to 12 wt.%, preferably 6 to 10 wt.% fatty acid. 23.Detergent preparation according to point 22, wherein the fatty acid is selected from the group consisting of caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, and mixtures thereof. 24. Detergent preparation according to any of the preceding points, wherein the detergent preparation contains, based on its total weight, 2 to 15 wt.%, preferably 4 to 12 wt.% water. 25. Detergent preparation according to any of the preceding points, wherein the detergent preparation contains, based on its total weight, 8 to 30 wt.%, preferably 12 to 25 wt.% organic solvent. 26.Detergent preparation according to point 25, wherein the organic solvent is selected from the group consisting of ethanol, n-propanol, i-propanol, butanols, glycol, propanediol, butanediol, methylpropanediol, glycerol, diglycylene, propyldiglycol, butyldiglycylene, hexylene glycol, ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol propyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, methoxytriglycol, ethoxytriglycol, butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, and propylene glycol-t-butyl ether. Di-n-octyl ether, organic amines, in particular monoethanolamine, and mixtures thereof, preferably from the group consisting of propanediol, glycerol, ethanol, monoethanolamine and mixtures thereof. 27.28. Detergent preparation according to any of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 0.1 to 3 wt.%, preferably 0.2 to 1 wt.% phosphonate. 29. Detergent preparation according to any of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 0.2 to 7 wt.%, preferably 0.5 to 5 wt.% enzyme preparation. 21. Detergent preparation according to any of the preceding clauses, wherein the detergent preparation further contains at least one enzyme preparation, preferably at least three enzyme preparations of enzymes from the group consisting of amylase, protease, cellulase, and mannanase. 30. Detergent preparation according to clause 28 or 29, wherein the enzyme preparations have, based on their total weight, a weight fraction of active protein of 0.1 and 40 wt.%, preferably 0.2 and 30 wt.%. 31.32. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains phosphonate and the phosphonate is selected from the group of hydroxyalkane and / or aminoalkane phosphonates, preferably from the group of aminoalkane phosphonates and in particular from the group of ethylenediaminetetramethylenephosphonate (EDTMP) and diethylenetriaminepentamethylenephosphonate (DTPMP). 33. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains 0.5 to 6 wt.% polyethoxylated polyethyleneimine. 34. Detergent preparation according to any one of the preceding clauses, wherein the detergent preparation contains, based on its total weight, 0.2 to 4 wt.%, preferably 0.5 to 3 wt.% fragrance preparation. 35. Detergent portion unit comprising i) a detergent preparation according to any one of clauses 1 to 33 ii) a water-soluble film completely enclosing the detergent preparation. 35.36. Detergent portion unit according to point 34, wherein the detergent portion unit has a volume of 12 to 22 ml, preferably 12 to 20 ml. 37. Detergent portion unit according to point 34 or 35, wherein the detergent portion unit has one to four receiving chambers, preferably three or four receiving chambers. 38. Method for textile cleaning, in which a detergent preparation according to point 1 to 33 or a detergent portion unit according to point 34 to 36 is introduced into the washing liquor of a textile washing machine. 39. Method according to point 37 for cleaning cotton fabric or polyester. 31. Method according to point 37 or 38, wherein the washing liquor has a temperature in the range of 15 to 35°C, preferably 15 to 25°C. Examples

[0102] Liquid detergents of the following composition were produced, wherein E2 is according to the invention and V1, V2, V3 and E1 are not according to the invention: Table 1: Detergent compositions (wt%) V1 V2 V3 E1 E2 polyalkoxylated amine 1)< 4,4 -- -- 2,2 1,4 Alcohol polyalkoxylate 2)< -- 4,4 -- 2,2 1,4 EO-PO-EO triblock copolymer 3)< -- -- 4,4 -- 1,4 Propanediol-1,2 5,2 5,2 5,2 5,2 5,2 Glycerin 9,8 9,8 9,8 9,8 9,8 Monoethanolamine 6,0 6,0 6,0 6,0 6,0 C12-18 fatty alcohol ethoxylate, 7 EO 22 22 22 22 22 C10-13 alkylbenzenesulfonic acid 22 22 22 22 22 C12-18 fatty acid 7,0 7,0 7,0 7,0 7,0 polyethoxylated polyethyleneimine 4,7 4,7 4,7 4,7 4,7 DTPMP (40% in water) 0,5 0,5 0,5 0,5 0,5 Optical brightener 0,5 0,5 0,5 0,5 0,5 Protease 2,5 2,5 2,5 2,5 2,5 Mannanase 0,1 0,1 0,1 0,1 0,1 Amylase 0,4 0,4 0,4 0,4 0,4 Cellulase 0,1 0,1 0,1 0,1 0,1 Water, Misc ad 100 ad 100 ad 100 ad 100

[0103] Textile fabrics were soiled with standardized materials and subsequently washed at 20°C in liquors containing 17 g of a detergent of class V1 to V3, E1, or E2 (washing time 119 minutes with 17 L of liquor). After washing, the textiles were dried. The brightness values ​​of the cleaned textiles were determined. The values ​​given are averages from five washing trials.

[0104] The measurement results are shown in the following tables (higher numbers indicate a higher degree of whiteness): Table 2: Test results Whiteness (Y-value) Textile Soiling V1 V2 E1 Cotton red wine 74,4 73,9 74,7 Cotton Beef fat (colored) 50,4 53,8 56,0 polyester Collar dirt 63,2 64,0 65,5 polyester Mascara 71,4 71,6 72,1 polyester potting soil 82,2 82,2 82,6 Table 3: Test results Whiteness (Y-value) Textile Soiling V1 V2 V3 E2 Cotton red wine 74,4 73,9 73,9 74,5 Cotton Beef fat (colored) 50,4 53,8 53,8 55,5 polyester Collar dirt 63,2 64,0 61,7 65,5

Claims

1. Detergent preparation containing, based on its total weight, a) 0.5 to 4 wt% of a polyalkoxylated amine with a weight-average molecular weight Mw in the range from 600 g / mol to 10,000 g / mol, which is obtainable by reacting ammonia or primary alkyl or hydroxyalkylamines having a molecular weight below 200 g / mol with alkylene oxides; b) 0.5 to 4 wt% of alcohol polyalkoxylate with a weight-average molecular weight Mw in the range from 600 g / mol to 10,000 g / mol, which can be obtained by reacting di- or triols with primary and / or secondary OH groups, which have a molecular weight Mw in the range from 60 g / mol to 200 g / mol, with alkylene oxides, wherein the alcohol polyalkoxylate is selected from the group consisting of polypropylene glycols; and c) 0.1 to 3 wt% of an ethylene oxide-propylene oxide-ethylene oxide triblock copolymer, wherein the copolymer comprises a first EO block, a second EO block, and a PO block, wherein the first EO block and the second EO block are connected to the PO block.

2. Detergent preparation according to claim 1, wherein the detergent preparation contains 1 to 3 wt.%, preferably 1 to 2.5 wt.%, of polyalkoxylated amine, based on its total weight.

3. Detergent preparation according to one of the preceding claims, wherein the polyalkoxylated amine is obtainable by ethoxylation and subsequent propoxylation of triethanolamine.

4. Detergent preparation according to one of the preceding claims, wherein the detergent preparation contains 1 to 3 wt.%, preferably 1 to 2.5 wt.%, of alcohol polyalkoxylate, based on its total weight.

5. Detergent preparation according to one of the preceding claims, wherein the polyalkoxylated amine and the alcohol polyalkoxylate are present in a weight ratio of 5:1 to 1:5, preferably 3:1 to 1:3 and, in particular, 3:2 to 2:3.

6. Detergent preparation according to one of the previous claims, wherein the polyalkoxylated amine and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in a weight ratio of 5:1 to 1:5.

7. Detergent preparation according to one of the preceding claims, wherein the alcohol polyalkoxylate and the ethylene oxide-propylene oxide-ethylene oxide triblock copolymer are present in a weight ratio of 5:1 to 1:5.

8. Detergent preparation according to one of the previous claims, wherein the detergent preparation contains 35 to 55 wt.%, preferably 40 to 50 wt.%, surfactant based on its total weight.

9. Detergent preparation according to one of the preceding claims, wherein the detergent preparation contains 4 to 12 wt.%, preferably 6 to 10 wt.%, of fatty acid, based on its total weight.

10. Detergent preparation according to one of the preceding claims, wherein the detergent preparation contains 2 to 15 wt.%, preferably 4 to 12 wt.%, water, based on its total weight.

11. Detergent preparation according to one of the preceding claims, wherein the detergent preparation contains 8 to 30 wt.%, preferably 12 to 25 wt.%, of organic solvent, based on its total weight.

12. Detergent portion unit comprising i) a detergent preparation according to one of claims 1 to 11 ii) a water-soluble film which completely encloses the detergent preparation.

13. Method for cleaning textiles, in which a detergent preparation according to one of claims 1 to 11 or a detergent portion unit according to claim 12 is introduced into the washing liquor of a textile washing machine.

Images