Cosmetic composition containing a natural resin
Patent Information
- Authority / Receiving Office
- FR · FR
- Patent Type
- Patents
- Current Assignee / Owner
- LOREAL SA
- Filing Date
- 2022-07-05
- Publication Date
- 2026-04-17
AI Technical Summary
Cosmetic products face challenges in achieving a film deposit on keratin materials that is resistant to external aggressions, non-sticky, and maintains adhesion without using synthetic polymers or silicones, while ensuring good cosmetic properties and sensory qualities.
A cosmetic composition comprising a natural resin, a vinyl ester polymer, and a combination of volatile alcohol and volatile oil, which solubilizes the natural resin at room temperature, forming a film that is resistant to friction and non-sticky.
The composition provides a film with improved resistance to friction and adhesion to keratin materials, while being non-sticky and resistant to external aggressions such as sweat and oils, without the use of synthetic polymers or silicones.
Abstract
Description
Description Title of the invention: Cosmetic composition comprising a natural resin Technical field of the invention
[0001] — The present invention relates to a cosmetic composition, comprising at least a natural resin and a polymer (homopolymer or copolymer) of vinyl ester. The invention also relates to a cosmetic process implementing the application of such a cosmetic composition to keratin materials, including human such as skin, hair or eyelashes. Background to the invention
[0002] — Cosmetic products often require the use of film-forming polymer to obtain a deposit of the product on keratin materials presenting good cosmetic properties. It is necessary that the film-forming deposit has good held, that it does not transfer when in contact with fingers, clothing; as well as a good resistance to contact with water, especially rain or when showering: or although the deposit is insensitive to perspiration or sebum, as well as to fats in foods, including dietary fats such as oils.
[0003] — Dispersions of polymer particles, generally acrylic, in organic media such as hydrocarbon oils are commonly used as film-forming agents in makeup products such as mascaras, eyeliners, eyeshadows or lipsticks. Resins based on silicones are also used to improve cosmetic hold. These dis- persions are not always satisfactory in terms of resistance to fatty substances, in particular dietary fats or sebum, which can be a barrier to their use. lization in lip makeup for example.
[0004] — On the other hand, cosmetic formulation is undergoing a major transformation. Consumers have expectations of more naturalness, the need to be reassured about the ingredients of cosmetic formulas, in particular on their safety, their low environmental footprint- national, their origin, or even their renewable nature. In recent years, the replacement of synthetic polymers, and in particular silicones, in cosmetic formulas have become a major issue.
[0005] Although some natural resins, such as rosin resin, have already been explored as tackifying resins, it is necessarily in combination with a high proportion of silicone resins, for example to increase shine and the good hold of lip makeup (FR2918272). However, the document WO2013 / 147113 reports several problems encountered with such ingredients, for example: a loss of flexibility of the cosmetic film is often observed as the quantity of silicone resin increases; a sticky effect of the cosmetic film appears as the quantity of rosin resin increases. This results in a feeling of “loaded”, heavy, or lumpy makeup. Consumers are accustomed to certain sensory and textural properties, for example those characteristic of silicones and synthetic polymer fillers. This is why the formulator must meet the dual challenge: on the one hand, naturalness, in which silicone resins and synthetic polymers are gradually being replaced by more natural raw materials, or those of more natural origin; and on the other hand, performance and sensoriality, so that more natural formulas have an effectiveness and sensory properties at least equivalent to those of the less natural formulas they are intended to replace. Finally, successfully formulating solid natural resins, at room temperature (25°C), in a cosmetic product with a liquid fluid texture, always remains a technical challenge. Typically, natural resins are reported as being soluble in chlorinated solvents or in benzene compounds, or in large quantities of alcohols. Such solvents are not feasible for cosmetic use for skin care or makeup, particularly for the lips, where even ethanol, above a certain content, is likely to cause discomfort, dryness, irritation, or even a burning sensation of the skin. The present invention therefore also aims to make it possible and simple to prepare cosmetic compositions offering improved hold, based on the most natural ingredients possible, and in a cosmetically acceptable medium. In particular, the aim of the present invention is to provide a cosmetic composition whose residual film after application adheres well to keratin materials, is elastic with the least possible fragmentation, the least possible detachment from the substrate, non-sticky, exhibiting good resistance to external aggressions, such as friction, resistant to sweat, sebum, and not very sensitive to oils such as food oils. The inventors have notably shown that, surprisingly, a particular combination of volatile alcohol and volatile oil makes it possible to effectively solubilize at room temperature (25°C) a natural resin, including semi-solid or solid, which, combined with a vinyl ester polymer, makes it possible to obtain a cosmetic composition whose film obtained after application proves to be both particularly resistant to friction and non-sticky after drying. Summary of the invention The subject of the present invention is a cosmetic composition comprising, in a physiologically acceptable medium: - at least one natural resin, and - at least one vinyl ester polymer. Preferably, the composition according to the invention further comprises - at least one volatile oil, and / or - at least one volatile alcohol. Advantageously, the weight ratio of the total quantity of volatile oil(s) and volatile alcohol(s) to the quantity of natural resin(s) is greater than 1. Preferably, the subject of the present invention is a cosmetic composition comprising, in a physiologically acceptable medium: a- at least one volatile oil, b- at least one volatile alcohol, c- at least one natural resin, and d- at least one vinyl ester polymer, in which: - the weight ratio of the quantity of volatile oil(s) to the quantity of natural resin(s) is greater than 0.5; preferably greater than 1; and / or - the weight ratio of the quantity of volatile alcohol(s) to the quantity of natural resin(s) is greater than 0.5; preferably greater than 1. The present invention also relates to a cosmetic composition comprising, in a physiologically acceptable medium, at least one oily phase of composition as defined above. The oily phase of the invention is preferably continuous. The present invention also relates to a process for coating keratin materials, more particularly for making up and / or caring for keratin materials, such as the skin, characterized in that it comprises the application to the keratin materials of a composition as defined according to the invention. The present invention also relates to the use of a composition as defined according to the invention to improve the hold on the skin and / or the resistance to friction of a cosmetic film without increasing the sticky effect of said film obtained by application of said composition to keratin materials. Detailed description of the invention For the purposes of the present invention, and unless otherwise indicated: By “keratinous materials” we mean skin, mucous membranes and / or appendages. Preferably, the keratin materials are skin, in particular facial skin, mucous membranes such as the lips, and / or appendages such as the eyelashes. The compositions according to the invention may be cosmetic or dermatological compositions. Preferably, they are cosmetic compositions. The composition according to the invention contains a physiologically acceptable medium. In the present invention, the term "physiologically acceptable medium" means a non-toxic medium, compatible with keratin materials, in particular with the skin (including the inside of the eyelids), mucous membranes, hair or lips of human beings. A cosmetic composition is a product having a pleasant appearance, odor and feel, and intended for topical application. By "anhydrous composition" is meant a composition containing less than 5% by weight of water relative to the total weight of the composition, preferably less than 1% by weight of water, even more preferably less than 0.5% by weight of water relative to the total weight of the composition, and in particular free of water. By "volatile substance" is meant any substance capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. Said volatile substance is liquid at room temperature, in particular has a vapor pressure greater than or equal to 2.66 Pa, at room temperature (25°C) and atmospheric pressure, preferably in the range of 2.66 Pa to 40,000 Pa, preferably 2.66 Pa to 13,000 Pa, and preferably 2.66 Pa to 1300 Pa. Vapour pressure can be measured by the static method or by the isothermal thermogravimetric effusion method, depending on the vapour pressure of the oil (OECD 104 standard). By "soluble or solubilized compound" is meant a compound that can be dissolved in a liquid, or that is miscible, and forms only a single homogeneous phase when incorporated into the liquid. The expressions “between … and …” and “ranging from … to …” must be understood inclusively, unless otherwise specified. The expressions "at least one" and "one or more" are synonymous and can be used interchangeably. In the description and examples, unless otherwise indicated, the contents and percentages are percentages by weight. The percentages are therefore expressed by weight relative to the total weight of the composition. The ratios are also weight ratios. The temperature is expressed in degrees Celsius unless otherwise indicated, and the pressure is atmospheric pressure unless otherwise indicated. Composition A — Oily phase According to a first aspect, the present invention relates to a composition such that previously defined. The applicant has found, surprisingly, that the composition of the invention comprising natural resin(s), in particular solubilized, in a specific mixture of volatile oil(s) and volatile alcohol(s), as defined below, in association with a vinyl ester polymer, makes it possible to obtain a film with improved hold, resistant to friction and non-sticky, after the film has dried. Natural resins A resin is generally defined as a solid, highly viscous, or liquid substance of plant or synthetic origin. Resins have several unique characteristics, such as: - the ability to harden permanently, for example for synthetics under the influence of temperature and for natural ones under the influence of oxygen; - their insolubility in water and above all their good sticky and adhesive properties. ISO4618:2014(fr) defines a resin as a “generally amorphous macromolecular product, ranging in consistency from solid to liquid” Natural resins are almost exclusively of plant origin (fossil or harvested), and are secreted and then exuded from plants for defense, protection, and communication roles within their ecosystem. Shellack, of animal origin, secreted by the insect Coccus lacca, is an exception. By "natural resin", and in particular "plant resin", within the meaning of the invention, is meant any substance comprising a minimum content of terpene compounds, that is to say at least 30% by weight of terpene compounds on the total weight of the substance (or material) considered, as chemically defined below, said substance being derived directly or indirectly, from the secretion and exudation, mainly by plants (more rarely by animals), of a substance for roles of defense, protection and communication with their ecosystem. Advantageously, the natural resin according to the invention is not soluble in water at room temperature (unlike latex or gums for example). Natural resins are also considered natural glues that have the inherent ability to polymerize consistently and predictably on their own without synthetic chemistry. Preferably, the natural resin used in the composition according to the invention has a number average molecular weight of less than or equal to 10,000 g / mol. The resin preferably has a number average molecular weight of less than or equal to 10,000 g / mol, in particular ranging from 250 to 10,000 g / mol, preferably less than or equal to 5,000 g / mol, in particular ranging from 250 to 5,000 g / mol, better still, less than or equal to 2,000 g / mol, in particular ranging from 250 to 2,000 g / mol and even better still less than or equal to 1,000 g / mol. mol, in particular ranging from 250 to 1000 g / mol. Number-average molecular weights (Mn) are determined by gel permeation liquid chromatography (THF solvent, calibration curve established with linear polystyrene standards, refractometric detector). Thermal properties Advantageously, the resins according to the invention are characterized by the fact that they have a softening point, which designates the transition temperature from a pseudo-solid state to a plastic state upon heating. Preferably, the resins of the invention have a softening point (or temperature) in the range of 20°C to 150°C, more preferably 30°C to 100°C, even more preferably 40°C to 90°C. The softening point is the temperature at which a product reaches a certain degree of softening under standard conditions. It refers to the transition temperature from a pseudo-solid state to a plastic state upon heating. It can be measured by the ring and ball method (or TBA, ring and ball temperature) for resins according to ASTM E284; Depending on their class, some of the resins according to the invention may also have a melting temperature, preferably less than 360°C, preferably less than 190°C, and even more preferably less than 90°C. According to a preferred form of the invention, the resins do not have a melting temperature. The melting point (or melting temperature) of a substance at a given pressure corresponds to the temperature at which the liquid and solid states of this substance can coexist in equilibrium; Preferably, the resins of the invention have a glass transition temperature, this being preferably in the range from 0 to 200°C, more preferably from 10°C to 100°C, even more preferably from 20°C to 90°C and even more preferably from 30°C to 70°C. The glass transition temperature (Tg) of a material represents the temperature range across which the material changes from a rubbery state to a glassy, solid (rigid) state. The thermal properties, in particular the Tf and Tg of the resins, can be measured by DSC (Differential Scanning Calorimetry), for example using a Perkin Elmer DSC 8000 device, according to: - Protocol 1: Determination of melting temperatures Tf and crystallization Tc: Raw materials alone or solubilized / dispersed in solvents, stainless steel cups, scanning from 5 °C to 90 °C, scanning speed at 5 °C.min-1. - Protocol 2: Determination of the glass transition temperature Tg: measurement in 2nd heating. Aluminum cups (40 uL) are used containing the raw materials, a temperature scan between -100°C and 150°C (with isotherms) is carried out in order to observe the glass transition temperature. The temperature ramp applied is 10°C / min for the glass transition temperatures (2 cycles). Botanical definition of resins: Natural resins of plant or animal origin are classically defined by Ullmann's Encyclopedia of Industrial Chemistry, "Resins, Synthetic" 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, DOI: 10.1002 / 14356007.a23_089.pub2. Natural resins can be classified by their botanical aspects. Resins can be derived from gymnosperms (naked seeders) and angiosperms (covered seeders); the latter are subdivided into monocots (with one leaf embryo) and dicots (with two leaf embryos). They can also be chosen according to their physical and chemical properties. Natural resins include rosins (gum, wood, or tall oil rosins from tree and plant exudates; extracted woods; or by-products of papermaking), fossil resins such as amber; extracted resins such as asphaltite; shellacs such as those produced from insect secretions; and their principal derivatives. Preferably, the resins of the invention are of plant origin, in particular from plants or trees. Fossil resins are resins (hard and semi-hard) collected from the ground at the site of ancient forests that have now disappeared. Some of them are no longer even known with certainty. Some fossil resins have undergone considerable changes in their chemical structure through aging or ripening, which may have taken thousands of years. The transition from fossil to recent resins is variable. For example, they may include resins that are both found fossilized and collected from living plants. Semi-fossil varieties are collected at the foot of the trees that produced them (Ullmann's Encyclopedia of Industrial Chemistry, “Resins, Natural” 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, DOI: 10.1002 / 14356007.a23_073) (Techniques de l'Ingénieur, “Résines Naturelles”, 1982 Bernard Delmond). Harvested resins are recent (tender). They are harvested from plants that are all alive. Depending on their composition, they are subdivided into: - oleoresin: natural solution of resin in an essential oil; - balsam: resin characterized by a significant proportion of benzoic and cinnamic acids and their esters; - gum: resin composed essentially of polysaccharides; - gum resin: mixture of resins and hydrophilic gums; - latex: milky composition of organic materials dispersed in an aqueous medium (Engineering Techniques, “Natural Resins”, 1982 Bernard Delmond). Among the resins, in particular the recent resins, of the invention, resins soluble in oils and / or alcohols are preferred over water-soluble forms such as latexes or gums. According to a preferred embodiment of the invention, the resins of the invention are harvested resins; particularly interesting according to the invention from an ecological point of view because they are self-regenerating. Preferably, the resins of the invention are recent. Advantageously, the resins used according to the invention rely on resources which are not in competition with those intended for food applications. Advantageously, the resins used in the compositions of the invention find their origin in the recovery of co-products from the paper industry. Chemical definition of resins Chemically, natural resins are complex mixtures of several classes of compounds whose presence and content define the class of resin (oleoresin, balsam, gum, etc.): essential oils, neutral and acid constituents and polysaccharides (present exclusively in gums). The characteristic components of the resins are the terpene compounds they contain, preferably in a content of at least 30% by weight, based on the weight of the resin. By "terpene compounds" we mean terpenes, hydrocarbons formed from isoprene of general formula (CSHB)n, and their numerous derivatives (alcohols, aldehydes, ketones, acids, etc.) comprising a terpene structure (Montpellier Academy. Resins: https: / / tice.ac-montpellier.fr / ABCDORGA / Famille / Terpenes.html). Among the terpene hydrocarbons, we distinguish: monoterpenes with the empirical formula CIOH16 (n=2), sesquiterpenes with the empirical formula C15H24 (n=3), diterpenes (C20H32) (n=4), sesterterpenes (C25H40) (n=5), triterpenes (C30H48) (n=6), tetraterpenes (C40H64) (n=8) and other polyterpenes. Some have an acyclic structure; they have a number of double bonds corresponding to their empirical formula: 3 for C10H16; 5 for C20H32; 7 for C30H48. Others have one or more cycles, i.e. a smaller number of double bonds; for example, for C10H16, one cycle and two double bonds or two cycles and one double bond. Advantageously, the resins of the invention contain at least 30% of terpene compounds, preferably at least 40% by weight of terpene compounds, preferably at least 50% of terpene compounds, and even more preferably at least 60% of terpene compounds, or even greater than 70%, by weight of the total weight of resin or resinous substance used as raw material in the composition according to the invention. Monoterpene and sesquiterpene compounds are mostly volatile compounds, constituting, for example, essential oils. Polyterpene compounds derived from terpenes with n greater than or equal to 4 (such as derivatives of diterpenes and triterpenes) are resinous compounds of a rather solid nature. According to a preferred embodiment of the invention, the resins comprise at least 10%, preferably at least 20% by weight, preferably at least 30% by weight, preferably at least 35% by weight, of polyterpene compounds, i.e. derived from terpenes with n greater than or equal to 4, out of the total weight of the resin representing 100%. Thus, resins having a solid fraction, at room temperature (25°C), are preferred. Advantageously, said resins used according to the invention are not volatile. Advantageously, the polyterpene compounds of the resins or resinous substances used in the composition of the invention are predominantly (more than 50% by weight of the total weight of polyterpenes) derived from diterpenes and / or triterpenes. According to a preferred embodiment of the invention, the resins comprise less than 70% by weight of monoterpene or sesquiterpene compounds, i.e. derived from terpenes with n less than 4, on the total weight of the resin representing 100%, preferably said resins comprise less than 60% by weight, preferably less than 50% by weight, preferably less than 30% by weight, preferably less than 15% by weight, of monoterpene or sesquiterpene compounds, derived from terpenes with n less than 4, on the total weight of the resin representing 100%. It is thus preferred, for the compositions of the invention, to limit the use of the most volatile resins, because they are less effective in terms of cosmetic film strength. A non-exhaustive list of terpene compounds that may be contained in the natural resins of the invention has been established. It lists families of terpene compounds, subdivided according to the characteristic groups (alcohol function, ketone function, acid function, etc.) of each compound (Lists below). Examples of monoterpene compounds Advantageously, the monoterpene compound(s) of the resin are chosen from: alpha-pinene, B-pinene, 3-carene, Camphene, Dipentene,P-Cymene,B-Myrcene,a-Phellandrene, Sabinene,a-Thuyene, Limonene, Octyl Ethanoate, Neryl Ethanoate, Bornyl Ethanoate, Geranyl Ethanoate, a-Terpineol, Cineol, Linalool, Borneol, their derivatives, and their mixtures. Examples of sesquiterpene compounds Advantageously, the sesquiterpene compound(s) of the resin are chosen from: Alpha-copaene, B-caryophyllene, B-bisabolene, B-gurjunene, alpha-gurjunene, allo-Aromadendrene, 8 — Bourbonene, Delta-cadinene, Alpha-guaiene, œ — Elémène, B — Elémène, d - Elémène, & — Copaène, to — Selinene, B — Selinene, B — Bourbonene, Lindestrene, Furanoeudesma-1,3-diene, œ — Cubebene, Farnesol, a- Elémol, Viridiflorol, t- Cadinol, B- Elémol, Germacrone, Curzerenone, their derivatives, and their mixtures. Examples of diterpene compounds Advantageously, the diterpene compound(s) of the resin are chosen from: Abietic acid, Pimaric acid, Sandarcopimaric acid, Comunic acid, Levopimaric acid, Palustric acid, Isopimaric acid, Dehydroabietic acid, Neoabietic acid, Agathic acid, Cembrene A, Cembrene C, Isocembrene, Vercilla-4(20),7,11-triene, Incensole, Totarol, Sandaracopimarinol, Cembrenol, their derivatives, and their mixtures. Examples of triterpene compounds Advantageously, the triterpene compound(s) of the resin are chosen from: 3p6,20(S)-dihydroxydammar-24-ene, dammarenolic acid, dammardienone, hydroxydammarenone (I or II), Dammarenediol I (or II), Dammadienol, 11-keto-B-boswellic acid (KBA), 1 1-keto-B-boswellic acid acetate (AKBA), fB-boswellic acid, ursolic acid, mangiferonic acid, benthamic acid, ursolic aldehyde, a-amyrenone, a-amyrin, B-amyrin, Uvaol, oleanolic acid, oleanonic acid, moronic acid, oleanonic aldehyde, acetyl lupeolic acid, lupeolic acid, Lupeol Betulonal, Hydroxyhopanone, their derivatives, and their mixtures. According to a first embodiment of the invention, the resin(s) used according to the present invention contain at least one diterpene compound, preferably derived from abietic acid, natural or chemically modified. Preferably, the diterpene compound(s), in particular derived from abietic acid, are present in the resin in weight contents of at least 20%, preferably at least 30%, and even more preferably at least 40%, by weight of the total weight of the natural resin. Examples include rosin resins t) such as rosinates, containing such diterpene compounds. According to a second embodiment of the invention, alternative or complementary to the first, the resin(s) used according to the present invention contain at least one triterpene compound, preferably chosen from triterpene compounds following penic acids: alpha-amyrin, Beta-amyrin, alpha-amyrone, beta-amyrone, dammadienone, dammadienol, ursolic aldehyde, hydroxyhopanone, oleanonic aldehyde, ursolic acid, oleanonic acid, oleanolic acid, and mixtures thereof. The total content of triterpene compounds, in particular the content of those preferred above, in the resin used according to the invention is advantageously at least 10%, preferably at least 20%, even more preferably at least 30%, and preferably at least 35% by weight of the total weight of the natural resin. Mention may in particular be made of incense resins k) protium heptaphyllum or shorea robusta, containing such triterpene compounds. The chemical composition of a resin can be analyzed by conventional techniques known to those skilled in the art such as gas chromatographic analysis GC, chromatographic analysis with flame ionization detection called GC-FID, or GC / MS analysis which consists of the use of a mass spectrometer coupled to a gas chromatograph; preferably by GC-FID. The following article discusses these common methods “Methodological developments in TLC / MALDITOF MS and GC / MS for the analysis of terpenoid compounds present in plant resins”, https: / / tel.archives-ouvertes.fr / tel-01581308. Definition of resins by their origin: Advantageously, the natural resin(s) according to the invention are chosen from: a) acaroides resins, b) ambers, c) asphaltite and gilsonite, d) Peru balsam, e) Tolu balsam, f) Benzoin resins, g) Canada balsam, h) copal resins (in particular Kauri copal resins, Manila copal resins, West African copals such as Congo, Angola or Cameroon copals, East African copals such as Zanzibar or Madagascar copals, South American copals such as Brazilian or Colombian copals), i) damars, j) elemis, k) incenses, 1) Galbanums, m) labdanumns, n) mastics or mastics, 0) Myrrh, p) La Sandarac, q) Shellacs, r) Styrax (Storax), s) Venetian turpentine (Larch, Turpentine essence), t) Colophony, in particular Rosin and rosinate and Tall oils, v) Resins extracted from vegetable waxes; and mixtures of these resins. Preferably, the natural resin(s) used according to the invention are chosen from j), k), t), u) and v); it is understood that the resin(s) of the invention may be esterified, salified, form adducts, be modified by phenols, and / or dimerized and / or further hydrogenated. j) The elemis "Elemis" is the generic term for the group of recent natural resins derived from plants of the Burseraceae (Canarium indicum) family. Each type is described according to its country of origin. According to a particular embodiment of the invention, the elemi resin used comes from the Philippines, particularly Manila elemi. To extract it, the trees are injured and a pathological resin discharge appears, which solidifies over time. Elemi are yellowish to greenish in color, opaque, similar to an ointment, sticky, and solidify into brownish resins dotted with crystals. Elemis are soluble in aromatic solvents, alcohols, esters, and carbon disulfide; and less soluble in aliphatic solvents. Elemis have an acid number between 18 and 34, a saponification value between 25 and 60, and a softening point of approximately 80. Balms exuding from elemis contain up to 30% essential oils. According to a preferred embodiment of the invention, the resin(s) of the invention are chosen from elemi, in particular elemi from the Canarium Luzonicum family in its pure form or mixed with a latex, for example. Mention may be made of the elemi resin from Canarium Luzonicum marketed under the name ELEMI RESIN. According to a particular embodiment of the invention, the resin(s) are chosen from j) elemis. k) Incense (Oliban) Incense is found in the United Arab Emirates, Oman, Somalia, Ethiopia, and eastern India. Frankincense resins are recent and derived from the Boswellia carterii tree incense. Amazonian frankincense resins are also found. The bark is intentionally wounded to obtain a milky extract, which is recovered after drying. Preferably, the resin(s) of the invention are chosen from incense, particularly from the Amazon. Frankincense resins are pale yellow, forming irregular rounded or globular beads. They typically contain 20% to 40% by weight (approx. 33%) of boswellic acid (C32H5204). Frankincenses have an acid value of 30% to 50% (indirect) and are sparingly soluble in ethanol in alkaline media. According to a particular embodiment of the invention, the resin(s) of the invention are chosen from incense, in particular Amazonian incense resins marketed under the name Protium heptaphyllum resin, or PROTIUM RESIN, or WHITE BREU RESIN, and incense resins from the Sal tree, Shorea robusta. Advantageously, the resin(s) are in a mixture with one or more fatty substances as defined below according to the invention, preferably chosen from volatile or non-volatile oils. Examples that may be mentioned include Shorea robusta resin with sunflower seed oil (SHOREA ROBUSTA RESIN, HELIANTHUS ANNUUS (SUNFLOWER) SEED OIL, TOCOPHEROL: 50-75% by weight shorea robusta resin, 25-50% by weight sunflower seed oil) marketed under the name KAHLRESIN 6720, and Shorea robusta resin with octyldodecanol (SHOREA ROBUSTA RESIN and OCTYLDODECANOL 50-70% by weight shorea robusta resin, 30-50% by weight octyldodecanol) marketed by KAHLRESIN 6720. According to a particular embodiment of the invention, the resin(s) are chosen from k) incense. t) Rosins Preferably the natural resin(s) are chosen from rosin. Rosin are recent resins, from renewable resources, and can be modified (e.g. esterified, hydrogenated, substituted). Rosin gums are preferably purified, distilled, from the balsam of various pine essences (up to 80 different species). Their composition is determined by climate, soil composition, and other botanical and meteorological factors. For example, we can cite rosins from Pinus austriaca (black pine) Austria, Central America, caribaea (slash pine), United States, Caribbean, densiflora Japan, elliottii United States, halepensis (Aleppo pine) Greece, Portugal, Spain, langifolia India, maritima (seashore pine) France, Spain, Portugal, massoniana (Chinese red pine) China, mercusii Indonesia, Burma, Philippines, nigra (black pine) Austria, oocarpa Central America, Honduras, palustris (swamp pine), United States, (longleaf pine), pseudostrobus Central America, Mexico, sylvestris (Scots pine) Germany, Poland, tonkinensis China, yunnanensis China. The average composition is approx. 70-75% rosin and 20-25% turpentine. Wood rosin / 8050-09-7] Rosin comes from stumps in the USA that have remained in the ground for at least 10 years so that the resin-rich heartwood is available. Pine stumps contain between 10 and 30% by weight (approx. 19% rosin), between 1 and 10% by weight (preferably 4%) of turpentine oil, between 1 and 10% by weight (preferably 4%) of resins insoluble in petroleum ether, between 20 and 30% by weight (preferably 23%) of water and between 40 and 60% by weight (preferably 50%) of cellulose and lignin type. According to a particular embodiment of the invention, the resin(s) are chosen from rosins. u) Tall oils rosin (Rosin and rosinate) / 8052-70-67 Tall rosin oils often contain small amounts of higher fatty acids, particularly with a carbon number greater than or equal to 6 carbon atoms. In one embodiment, tall rosin oils are free of oxocarboxylic acid. They are particularly soluble in organic solvents. The rosin resins of the invention comprise in particular rosin acids belonging to the terpenes. The numbering of the carbon atoms in the rosin acid molecules is indicated using abietic acid as an example. Rosin acids have the molecular chemical formula Czo Hzp Oz and therefore belong to the diterpene family (four isoprene units). A large number of isomers exist of tricyclic rosin acids which differ in the position of the two double bonds. Advantageously, said resin according to the invention is chosen from: gum rosin obtained by incision on living trees, wood rosin which is extracted from pine stumps or wood, and tall oil rosin which is obtained from a by-product from paper production. Advantageously, said resin(s) comprise rosin acids; preferably mainly chosen from abietic and pimaric type acids; and in particular chosen from: levopimaric acid, neoabietic, abietic, dehydroabietic, tetrahydroabietic, dihydroabietic, dextropimaric, isodextropimaric acid; or palustric acid; and mixtures thereof. Rosin derivatives may be derived in particular from the polymerization, hydrogenation and / or esterification (for example with polyhydric alcohols such as ethylene glycol, glycerol, pentaerythritol) of rosin acids. Examples include rosin esters marketed under the references FORAL 85, PENTALYN H and STAYBELITE ESTER 10 by the company HERCULES; SYLVATAC 95 and ZONESTER 85 by the company ARIZONA CHEMICAL or UNIREZ 3013 by the company UNION CAMP. According to one embodiment of the invention, the resin(s) are chosen from rosinates (salts of alkaline agents of rosin acids, in particular salts of alkali metals such as sodium or potassium, alkaline earth metals such as calcium, or metals such as zinc or magnesium). According to another preferred embodiment of the invention, the resin(s) are chosen from rosin acid esters, in particular rosin acid esters as defined above and (C1-C6) alkanol, polyhydroxy(C1-C6)alkane polyols such as glycerol, pentaerythritol, and mixtures thereof, more preferably chosen from glyceryl rosinate sold under the name RESIESTER GUM A 35, glyceryl rosinate mixed with a hydrogenated vegetable oil and / or castor seed oil (GLYCERYL ROSINATE, RICINUS COMMUNIS SEED OIL, HYDROGENATED VEGETABLE OIL sold under the name EFP BIOTEK) pentaerythrityl rosinate sold under the name RESIESTER N 35 S and RESIESTER 80. According to another embodiment of the invention, the resin(s) are chosen from poly(carboxy)(C2-C6) alkane or poly(carboxy)(C2-C6) alkene adducts, in particular of maleic acids with rosin acids. According to another embodiment of the invention, the resin(s) are chosen from rosins modified by phenols. In particular those modified by (C1-C4) alkylene phenols or diphenols, optionally substituted by one or more (C1-C4) alkyl groups such as methyl or t-butyl, more particularly rosins modified by 4-tert-butylphenol and 4,4*-isopropylidenediphenol (bisphenol A). According to another embodiment of the invention, the resin(s) are chosen from dimerized rosins; in particular those in which the abietic acid is polymerized. Preferably, the rosins contain more than 50% of dimer acids and are thus called dimerized rosins. According to one embodiment, the rosins are polymerized and contain from 30% to 90% by weight of dimer acid (in particular at least 40%, 60 or 80% of dimer acids). According to a preferred embodiment of the invention, the resin(s) are chosen from hydrogenated rosins. The double bonds, in particular acids such as abietic acid, are subject to oxidation, which can be removed by hydrogenation. It is understood that the resin(s) of the invention can be esterified, salified, adducted, modified by phenols, and / or dimerized and further hydrogenated. In a preferred embodiment, the resin comprises at least one rosin acid ester selected from the group consisting of glyceryl rosinate, pentaerythrityl rosinate, silicone rosinate, diethylene glycol rosinate, hydrogenated dilinoleyl dimer rosinate, dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate, glyceryl dibehenate / hydrogenated rosinate, glyceryl diisostearate / hydrogenated rosinate, trihydrogenated glyceryl rosinate, glycol rosinate, hydrogenated methyl rosinate, methyl rosinate, hydrogenated pentaerythrityl rosinate, hydrogenated triethylene glycol rosinate; and mixtures thereof. According to a particular embodiment, the resin(s) of the invention are chosen from hydrogenated pentaerythrityl rosinate (PENTAERYTHRITYL HY-DROGENATED ROSINATE), hydrogenated methyl rosinate (METHYL HY-DROGENATED ROSINATE) marketed under the name SYMRISE BIO4326. In addition, the resin(s) of the invention may be mixed with fatty substances c) as defined below, in particular waxes or butters. Mention may be made of mixtures of glyceryl rosinate with one or more fatty substances c) chosen in particular from waxes or butters such as the mixture with shea butter or olive oil such as (GLYCERYL ROSINATE, RICINUS COMMUNIS SEED OIL, HY-DROGENATED VEGETABLE OIL), BUTYROSPERMUM PARKII (SHEA BUTTER) GLYCERYL ROSINATE, OLEA EUROPAEA (OLIVE) OIL UNSAPO- NIFIABLES GLYCERYL ROSINATE, OLEA EUROPAEA (OLIVE) OIL UNSAPO- NIFIABLES marketed by SHEA BUTTER & GLYCERYL ROSINATE & OILS: (v) resins extracted from vegetable waxes Natural plant waxes are not considered resins. Although they are among the substances secreted / excreted by plants and naturally contain a very low resin content, they contain less than 30% by weight of terpenes on the total weight of wax. For example, Camauba wax is naturally secreted by the leaves of a Copernica Cerifera palm to prevent the leaves from dehydrating. Candelilla wax is obtained from a shrub called Euphorbia Antisyphilitica native to northern Mexico. The wax protects the plant from its environment and prevents excessive evaporation. For example, candelilla wax consists primarily of hydrocarbons (about 50%, chains of 29 to 33 carbon atoms), higher molecular weight esters (20 to 29%), free acids (7 to 9%), and resins (12-14%, primarily triterpene esters). However, the definition of "natural resins" within the meaning of the present invention also includes resins derived from vegetable waxes, when they have been previously concentrated, isolated or extracted from these waxes, provided that the resinous or terpenic ingredient in question contains the minimum terpene content (30% by weight of the total weight of the ingredient) required by the present invention. Mention may in particular be made of Candelilla resin (100% pure resin extracted from the corresponding wax), with the INCI name: EUPHORBIA CERIFERA (CANDELLILA) WAX EXTRACT, marketed under the name CANDELILLA RESIN E-| by JAPAN NATURAL PRODUCTS.Document WO2013 / 147113 A1 also refers to Carnauba resin, a terpene resin extracted from Carnauba wax, and having physical properties similar to those of conventionally described natural resins, such as a softening temperature and not a melting temperature which differentiates the resin from the wax. Table 1 of the examples shows some characteristic differences between the waxes and resins according to the invention, concerning their thermal properties. Resins have a softening point and a glass transition temperature, but no melting temperature. The opposite is true for waxes that have a melting point. Preferably, the resin(s) are chosen from resin(s) j), k), t) and u) as defined above, and resin(s) v) extracted from waxes, in particular candelilla or carnauba; and mixtures thereof. Preferred resins according to the invention: According to a preferred embodiment of the invention, the resin(s) are chosen from the following references, indicated by their INCI name, used alone or in a mixture: - EUPHORBIA CERIFERA (CANDELILLA) WAX EXTRACT, such as CANDELILLA RESIN E-1 marketed by JAPAN NATURAL PRODUCTS, BOTANICAL RESIN marketed by CERA RICA NODA, TOWAX-1F12 marketed by TOA KASEI (type v resin); - PROTIUM HEPTAPHYLLUM RESIN, or PROTIUM RESIN, or WHITE BREU RESIN, which can be marketed for example by CITROLEO or Ephyla (type k resin) - Incense resins from the Sal tree, SHOREA ROBUSTA RESIN. The resin(s) may be found in a mixture with one or more fatty substances c) as defined below, preferably chosen from volatile or non-volatile oils. Examples include Shorea robusta resin with sunflower seed oil (SHOREA ROBUSTA RESIN, HELIANTHUS ANNUUS (SUNFLOWER) SEED OIL, TOCOPHEROLS: 50-75% by weight shorea robusta resin, 25-50% by weight sunflower seed oil) marketed under the name KAHLRESIN 6720, and Shorea robusta resin with octyldodecanol (SHOREA ROBUSTA RESIN and OCTYLDODECANOL 50-70% by weight shorea robusta resin, 30-50% by weight octyldodecanol) marketed by KAHLRESIN 6720 (k-type resin) - rosin acid esters (rosin) such as GLYCERYL ROSINATE marketed under the name RESIESTER GUM À 35, glyceryl rosinate mixed with a hydrogenated vegetable oil and / or castor seed oil (GLYCERYL ROSINATE, RICINUS COMMUNIS SEED OIL, HYDROGENATED VEGETABLE OIL marketed under the name EFP BIOTEK), pentaerythrityl rosinate marketed under the name RESIESTER N 35 S and RESIESTER 80 or hydrogenated rosinates such as hydrogenated pentaerythrityl rosinate (PENTAERYTHRITYL HYDROGENATED ROSINATE), hydrogenated methyl rosinate (METHYL HYDROGENATED ROSINATE) marketed under the name SYMRISE BIO4326 (t-type resin). According to a preferred embodiment of the invention, the resin(s) are chosen from EUPHORBIA CERIFERA (CANDELLILA) WAX EXTRACT. Advantageously, the resin(s) is(are) present in the composition of the invention in a content within the range of 0.1% to 40%, preferably 0.5% to 35%, preferably 1% to 30%, preferably 2% to 25%, preferably 3 to 22%, and more preferably 5% to 20%, by weight relative to the total weight of the composition representing 100%. Advantageously, the composition of the present invention comprises less than 10%, preferably less than 5%, preferably less than 1%, preferably less than 0.5%, preferably less than 0.1%, preferably free of synthetic resin. Advantageously, the composition of the present invention comprises less than 10%, preferably less than 5%, preferably less than 1%, preferably less than 0.5%, preferably less than 0.1%, preferably is free of silicone resin, i.e. synthetic resin in which the basic structure is a chain comprising siloxane groups (silicon-oxygen-silicon bonds). Oils The composition of the invention comprises an oily phase, advantageously continuous, comprising at least one volatile oil chosen from volatile hydrocarbon oils, volatile silicone oils and their mixtures. Said phase is liquid (in the absence of structuring agent) at room temperature (25°C) and atmospheric pressure 1.013.105 Pa). It is organic, namely comprising at least carbon and hydrogen atoms and immiscible in water. The oily phase comprises at least one volatile oil and optionally ingredients soluble or miscible in said phase. The total concentration in oily phase of the composition of the invention is advantageously within the range of 5 to 100%, preferably 10 to 98% by weight, preferably 15 to 90% by weight, preferably 20 to 80% by weight, preferably 25 to 70% by weight, preferably 30 to 60% by weight, relative to the total weight of the composition. By "oil" we mean a liquid compound at 25°C and atmospheric pressure (1.013.10° Pa), immiscible with water. By "immiscible" is meant that the mixture of the same quantity of water and oil, after stirring, does not lead to a stable solution comprising only one phase, under the aforementioned temperature and pressure conditions. Observation is made visually or using a phase contrast microscope if necessary, on 100g of mixture obtained after Rayneri stirring sufficient to cause a vortex to appear within the mixture (as an indication 200 to 1000 rpm); the resulting mixture is left to stand, in a closed bottle, for 24 hours at room temperature before observation. Volatile oils By "volatile oil" is meant an oil having a vapor pressure greater than or equal to 1.3 Pa, preferably greater than or equal to 2.66 Pa, at room temperature (25°C) and atmospheric pressure, preferably in the range of 2.66 Pa to 40,000 Pa, preferably 2.66 Pa to 13,000 Pa, and preferably 2.66 Pa to 1300 Pa. Conversely, by "non-volatile oil" we mean an oil whose vapor pressure at 25°C and atmospheric pressure is non-zero and less than 2.66 Pa, more particularly less than 0.13 Pa. For example, vapour pressure can be measured using the static method or the isothermal thermogravimetry effusion method, depending on the vapour pressure of the oil (OECD 104 standard). The volatile oil or oils are preferably present in a content ranging from 1 to 90% by weight, preferably from 2 to 70%, preferably from 3 to 50%, preferably from 5 to 45% by weight, preferably from 8 to 40% by weight, and even more preferably from 10 to 35% by weight relative to the total weight of the composition. The volatile oil or oils are advantageously chosen from volatile hydrocarbon oils, volatile silicone oils, and mixtures thereof; preferably chosen from volatile hydrocarbon oils. Volatile hydrocarbon oil The term "hydrocarbon oil" means an oil containing mainly hydrogen and carbon atoms and possibly one or more functions chosen from hydroxyl, ester, ether and carboxylic functions. A hydrocarbon oil therefore does not contain any silicon or fluorine atoms. By "non-polar hydrocarbon oil" is meant a hydrocarbon oil comprising only carbon and hydrogen atoms, preferably non-aromatic (also called hydrocarbon). By "polar hydrocarbon oil" we mean hydrocarbon oils comprising mainly hydrogen and carbon atoms and one or more functions chosen from hydroxyl, ester, ether, carboxylic functions, therefore oils with only C, H and O. As an example of volatile hydrocarbon oil that can be used in the invention, mention may be made of: - hydrocarbon oils having 8 to 16 carbon atoms, and in particular C8-C16 isoalkanes (also called isoparaffins) such as isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane, isohexadecane, and for example oils sold under the trade names Isopars® or Permethyls®, - linear alkanes, C6-C16, for example C11-C15, alone or in mixtures, for example such as hexane, decane, undecane, tridecane, isoparaffins such as, or n-dodecane (C12) and n-tetradecane (C14) sold by Sasol respectively under the references PARAFOL 12-97 and PARAFOL 14-97, the undecane-tridecane mixture, the mixtures of n-undecane (C11) and n-tridecane (C13) obtained to examples | and 2 of application WO 2008 / 155059 from Cognis Company, and their mixtures as well as the mixtures of n-undecane (C11) and n-tridecane (C13) Cetiol Ultimate® from BASF Company. - volatile C5-C12 cyclic, non-aromatic alkanes; - branched C8-C16 esters, isohexyl neopentanoate; - short-chain esters (having 3 to 8 carbon atoms in total) such as methyl acetate, ethyl acetate, methyl acetate, propyl acetate, n-butyl acetate or isobutyl acetate, for example sold by SOLVAY, DOW or OXEA; - volatile carbonate hydrocarbon oils of structure R°1-O-CO-OR"2 in which R°1 and R°2 independently denote a linear, branched or cyclic C4-C8 alkyl group, preferably a C4-C8 alkyl group. It may be preferable for R1 and R2 to be identical. Preferably R'1 and R°2 denote a linear butyl alkyl radical, a pentyl group. Advantageously, the ether oil is chosen from dibutyl carbonate or dipentyl carbonate; - volatile ether oils of formula RIOR2 in which R1 and R2 independently denote a linear, branched or cyclic C4-C8 alkyl group, preferably a C4-C8 alkyl group. It may be preferable for R1 and R2 to be identical. As a linear alkyl group, mention may be made of a butyl group, a pentyl group. As a branched alkyl group, mention may be made of a 1-methylpropyl group, a 2-methylpropyl group, a t-butyl group, a 1,1-dimethylpropyl group. Advantageously, the ether oil is chosen from dicaprylyl ether, dicaprylyl ether, especially dicaprylyl ether. Other volatile hydrocarbon oils such as petroleum distillates, in particular those sold under the name Shell Sol T by the company SHELL, can also be used; or volatile linear alkanes such as those described in the patent application of the company Cognis DE102008012457. The volatile hydrocarbon oils are preferably chosen from hydrocarbon-type hydrocarbon oils (therefore apolar hydrocarbon oils, consisting solely of carbon and hydrogen) having from 8 to 16 carbon atoms and their mixtures, and in particular: - branched C8-C16 alkanes such as isoalkanes (also called isoparaffins), isododecane, isodecane, isohexadecane, and for example oils sold under the trade names Isopars or Permetyls, alone or in mixtures, - linear alkanes, for example C11-C15, alone or in mixtures, and -their mixtures. The volatile hydrocarbon oil(s) are chosen in particular from C6-C16 alkanes and in particular alkanes such as dodecane, tetradecane, isohexadecane, mixtures of undecane and tridecane, and isoparaffins such as C13-16 Isoparaffin. According to a preferred embodiment of the invention, the volatile oil(s) are linear or branched hydrocarbon oils, which are volatile, notably chosen from undecane, decane, dodecane, isododecane, isohexadecane, tridecane, tetradecane and their mixture, preferably comprising isododecane and / or a mixture of undecane and tridecane. According to a particular embodiment of the invention, the volatile oil(s) of the invention are a mixture of C9-C12 alkanes, preferably of natural origin, the chains of which comprise from 9 to 12 carbon atoms, preferably linear or branched C9-C12 alkanes. This mixture is notably known under the INCI name C9-C12 ALKANE, CAS 68608-12-8, VEGELIGHT SILK® marketed by BioSynthls. According to a preferred embodiment, the volatile oil(s) are at least partially of plant origin. Volatile silicone oil By “silicone oil” is meant an oil comprising at least one silicon atom, and in particular at least one Si-O group, and more particularly an organopolysiloxane. The volatile silicone oils can be chosen from linear, branched or cyclic silicone oils such as polydimethylsiloxanes (PDMS) having from 3 to 7 silicon atoms. Examples of such oils include octyltrimethicone, hexyltrimethicone, methyl trimethicone, decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, decamethyltetrasiloxane, polydimethylsiloxanes such as those marketed under the reference DC 200 (1.5 cSt), DC 200 (3 cSt) by Dow Corning, or KF 96 A from Shin Etsu; alone or in mixtures. According to a particular form of the invention, a mixture of at least one volatile hydrocarbon oil and at least one volatile silicone oil will be used, and more particularly a mixture of isododecane and dodecamethylpentasiloxane. Advantageously, the composition according to the invention contains less than 30%, preferably less than 20%, preferably less than 10%, preferably less than 1%, preferably less than 0.5%, preferably less than 0.2%, preferably less than 0.1%, by weight of silicone oil relative to the total weight of the composition, and ideally the composition of the invention is free from any silicone oil. Preferably, in the composition according to the invention, the volatile oil or oils are chosen from volatile hydrocarbon oils. The composition of the present invention preferably comprises isododecane, linear or branched alkanes, C9-C12, and / or mixtures of n-undecane (C11) and n-tridecane (C13); preferably it comprises isododecane Preferably, the weight ratio of the amount of volatile oil(s) to the amount of natural resin(s) is in the range of 0.5 to 50, preferably 1 to 30, preferably 3 to 20; preferably 5 to 18, preferably 8 to 15. According to one embodiment of the invention, the composition may further comprise one or more non-volatile oils. Non-volatile oils By "non-volatile oil" is meant an oil whose vapour pressure at 25°C and atmospheric pressure is non-zero and less than 2.66 Pa, more particularly less than 0.13 Pa. For example, the vapour pressure can be measured using the static method or by the isothermal thermogravimetry effusion method, depending on the vapour pressure of the oil (OECD standard 104). The non-volatile oil(s) of the invention are of natural or synthetic origin, preferably natural. According to a particular embodiment of the invention, composition C1 or C'1 comprises one or more non-volatile oils. Non-volatile oils include: Non-volatile silicone oils The non-volatile silicone oil may in particular be chosen from non-volatile silicones with the following INCI names: dimethicone, dimethiconol, trimethyl pentaphenyl trisiloxane, tetramethyl tetraphenyl trisiloxane, diphenyl dimethicone, trimethylsiloxyphenyl dimethicone, phenyltrimethicone, diphenylsiloxy phenyl trimethicone; as well as mixtures thereof. These products are notably marketed under the names PH-1555 HRI Cosmetic Fluid (Trimethyl Pentaphenyl Trisiloxane), Dow Corning 556 Cosmetic Grade Fluid (Phenyltrimethicone) by Dow Corning; Diphenyl Dimethicone such as products KF-54, KF54HV, KF-50-300CS, KF-53 d, KF-50-100CS or Diphenylsiloxy Phenyl Trimethicone KF56 À marketed by Shin Etsu, marketed by Shin Etsu; products Belsil PDM 1000, Belsil PDM 20 marketed by Wacker Chemie (Trimethylsiloxy Phenyl Dimethicone), alone or in mixtures. Non-volatile fluorinated oils The term “fluorinated oil” means an oil comprising at least one fluorine atom. The fluorinated oil may in particular be chosen from fluorinated polyethers, as well as from fluorosilicone oils, fluorinated silicones as described in document EP-A-847752. Non-volatile non-polar hydrocarbon oils Non-volatile apolar hydrocarbon oils can be chosen from linear or branched compounds, of mineral or synthetic origin such as for example: - paraffin oil, - squalane, such as the NEOSSANCE SQUALANE reference marketed by AMYRIS, - isoeicosane, - linear, saturated hydrocarbons and their mixtures, more particularly C15-C28, such as mixtures whose INCI names are, for example, the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as, for example, the products Gemseal 40, Gemseal 60, Gemseal 120 marketed by Total, Emogreen L19, Emogreen L15 marketed by SEPPIC, - polybutenes, hydrogenated or not, such as for example products from the Indopol range marketed by the company INEOS Oligomers, products with the INCI name HYDROGENATED POLYISOBUTENE - polyisobutenes, hydrogenated or not, such as for example the non-volatile compounds of the Parléam® range marketed by the company NIPPON OIL FATS, - polydecenes, hydrogenated or not, such as, for example, non-volatile compounds from the PURESYN® range marketed by the company Exxonmobil), - decene / butene copolymers, butene / isobutene copolymers - and their mixtures. Polar non-volatile hydrocarbon oils They can be chosen from: - saturated, unsaturated, linear or branched fatty alcohols, C10-C26, preferably monoalcohols. Advantageously, the C10-C26 alcohols are fatty alcohols, preferably branched when they comprise at least 16 carbon atoms. Preferably, the fatty alcohol comprises from 10 to 24 carbon atoms, and more preferably from 12 to 22 carbon atoms, such as in particular lauryl alcohol, isostearyl alcohol, oleyl alcohol, 2-butyloctanol, 2-undecyl pentadecanol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol and mixtures thereof; - triglycerides consisting of fatty acid esters and glycerol, in particular the fatty acids of which may have chain lengths varying from C4 to C36, and in particular from C8 to C36, preferably from C18 to C36, these oils being able to be linear or branched, saturated or unsaturated. Examples that may be mentioned include heptanoic or octanoic triglycerides, caprylic / capric acid triglycerides; vegetable oils such as wheat germ, sunflower, grape seeds, sesame seeds, corn seeds, apricot seeds, castor oil seeds, shea seeds, avocado seeds, olive seeds, soybean seeds, sweet almond seeds, palm seeds, rapeseed seeds, cotton seeds, hazelnut seeds, macadamia seeds, jojoba seeds, alfalfa seeds, poppy seeds, pumpkin seeds, squash seeds, blackcurrant seeds, evening primrose seeds, millet seeds, barley seeds, quinoa seeds, rye seeds, safflower seeds, candlenut seeds, passionflower seeds, musk rose seeds; the liquid fraction of shea butter, and the liquid fraction of cocoa butter; as well as mixtures thereof; - linear aliphatic hydrocarbon esters of formula RCOOR” in which RCOO represents a carboxylic acid residue containing from 2 to 40 carbon atoms, and R° represents a hydrocarbon chain containing from 1 to 40 carbon atoms, aliphatic hydrocarbon esters of alkylene glycol, in particular ethylene glycol or propylene glycol; the total number of carbon atoms being advantageously at least 10. Examples of such esters include isoamyl laurate, cetostearyl octanoate, isopropyl myristate, isopropyl palmitate, isopropyl stearate or isostearate, ethyl palmitate, 2-ethylhexyl palmitate, isostearyl isostearate, octyl stearate, isostearyl heptanoate, coco caprylate / caprate, octanoates, decanoates or ricinoleates of alcohols or polyalcohols such as propylene glycol dioctanoate, cetyl octanoate, tridecyl octanoate, 2-ethylhexyl palmitate,alkyl benzoate, polyethylene glycol diheptanoate, propylene glycol diethyl 2-hexanoate and mixtures thereof, hexyl laurate, neopentanoic acid esters such as isodecyl neopentanoate, isotridecyl neopentanoate, isostearyl neopentanoate, octyl-2-docecyl neopentanoate, isononanoic acid esters such as isononyl isononanoate, isotridecyl isononanoate, octyl isononanoate, oleyl erucate; lauroyl isopropyl sarcosinate, diisopropyl sebacate, isocetyl stearate, isodecyl neopentanoate, isostearyl behenate, myristyl myristate; , - hydroxylated esters such as polyglycerol-2 triisostearate; - aromatic esters such as tridecyl trimellitate, C12-C15 alcohol benzoate, 2-phenyl ethyl ester of benzoic acid, butyl octyl salicylate; - linear fatty acid esters having a total carbon number ranging from 35 to 70 such as pentaerythrityl tetrapelargonate; - esters of fatty alcohol or branched C24-C28 fatty acids such as triisoarachidyl citrate, pentaerythrityl tetraisononanoate, glyceryl triisostearate, glyceryl tri-2-decyl tetradecanoate, pentaerythrityl tetraisostearate, polyglyceryl-2-tetraisostearate or pentaerythrityl-2-tetradecyl tetradecanoate; - polyesters obtained by condensation of dimer and / or trimer of unsaturated fatty acid and diol such as those with the INCI name dilinoleic acid / butanediol copolymer, dilinoleic acid / propanediol copolymer; polyesters obtained by condensation of dimer of fatty acid and dimer diol such as dimer dilinoleyl dimer dilinoleate; - synthetic ethers having 10 to 40 carbon atoms such as dicaprylyl ether; - di-alkyl carbonates, the 2 alkyl chains being able to be identical or different, such as dicaprylyl carbonate; - vinylpyrrolidone copolymers such as vinylpyrrolidone / 1-hexadecene copolymer (INCI name); - their mixtures. According to one embodiment, the non-volatile oil(s) are chosen from non-volatile silicone oils, non-volatile hydrocarbon oils, polar hydrocarbon oils as defined previously, and mixtures thereof, preferably chosen from non-volatile hydrocarbon oils, polar hydrocarbon oils as defined previously and mixtures thereof. According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil chosen from linear aliphatic hydrocarbon esters of formula RCOOR” in which RCOO represents a carboxylic acid residue comprising from 2 to 40 carbon atoms, and R° represents a hydrocarbon chain containing from 1 to 40 carbon atoms, aliphatic hydrocarbon esters of alkylene glycol, in particular ethylene glycol or propylene glycol as defined above, more preferably chosen from isoamyl laurate, isopropyl myristate, isodecyl neopentanoate, isostearyl neopentanoate, isononyl isononanoate, coco caprylate caprate and mixtures thereof and even better denotes isononyl isononanoate.; According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil chosen from saturated, unsaturated, linear or branched C10-C26 fatty alcohols, preferably monoalcohols, preferably branched when they comprise at least 16 carbon atoms as described above, in particular chosen from oleyl alcohol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol such as the reference EUTANOL G marketed by BASF and mixtures thereof. According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil chosen from triglycerides consisting of fatty acid esters and glycerol, in particular the fatty acids of which may have chain lengths varying from C4 to C36, and in particular from C18 C8 to C36, these oils being able to be linear or branched, saturated or unsaturated as described above, preferably chosen from heptanoic or octanoic triglycerides, caprylic / capric acid triglycerides and mixtures thereof and in addition preferentially caprylic / capric acid triglycerides such as the PALMESTER 3585 reference marketed by KLK OLEO. According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil chosen from non-volatile apolar hydrocarbon oils as described above, preferably chosen from mixtures of linear, saturated hydrocarbons, more particularly C15-C28, polybutenes, hydrogenated or not, and mixtures thereof. According to one embodiment, the non-volatile hydrocarbon oil(s) comprise or consist of at least one non-volatile oil chosen from non-volatile apolar hydrocarbon oils chosen from mixtures whose INCI names are, for example, the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as, for example, the products Gemseal 40, Gemseal 60, Gemseal 120 marketed by Total, Emogreen L19 marketed by SEPPIC, Emogreen L15 marketed by SEPPIC, the products with the INCI name HYDROGENATED POLYISOBUTENE, and mixtures thereof. According to a particular embodiment of the invention, the non-volatile hydrocarbon oil(s) c) comprise or consist of at least one non-volatile oil chosen from isoamyl laurate, isopropyl myristate, isodecyl neopentanoate, isostearyl neopentanoate, isononyl isononanoate, oleyl alcohol, 2-hexyldecyl alcohol, isocetyl alcohol, octyldodecanol, caprylic / capric acid triglycerides, mixtures whose INCI names are, for example, the following: C15-19 Alkane, C18-C21 Alkane, C21-C28 Alkane, such as, for example, the products Gemseal 40, Gemseal, products with the INCI name HY-DROGENATED POLYISOBUTENE, and mixtures thereof, more particularly chosen from products with INCI name HYDROGENATED POLYISOBUTENE, mixtures with INCI name C15-19 Alkane such as Emogreen LI5 marketed by SEPPIC, isononyl isononanoate. According to one embodiment, the non-volatile hydrocarbon oil(s) consist of one or more polar or apolar non-volatile hydrocarbon oils as defined above. According to one embodiment, the non-volatile oil(s) comprise at least one silicone oil as defined above, preferably chosen from dimethicones, such as the BELSIL DM 5 PLUS DIMETHICONE grade marketed by Wacker, the DOWSIL SH 200 C FLUID 10 CST reference marketed by DOW CHEMICAL or the XIAMETER PMX-200 SILICONE FLUID 1000 CST reference marketed by DOW CHEMICAL, or PHENYL TRIMETHICONE such as the DOWSIL SH 556 FLUID reference marketed by DOW CHEMICAL. Preferably when the non-volatile oil(s) are a mixture of at least one non-volatile hydrocarbon oil preferably chosen from hydro- non-volatile apolar hydrocarbon oils and polar non-volatile hydrocarbon oils with at least one volatile silicone oil, the amount of silicone oil is less than 30%, preferably less than 20%, preferably less than 10% by weight, relative to the total weight of the composition. According to a particular form of the invention, the optional non-volatile oil(s) are present in the composition in an amount of 0.1% to 50%, preferably 0.2% to 40%, preferably 0.5% to 35%, preferably 1 to 30%, more preferably between 2 and 20%, by weight, relative to the total weight of the composition. By weight ratio noted R, we mean the ratio of the sum of the masses of volatile oil(s) (HV) to the sum of the masses of non-volatile oil(s) HNV), defined by: R = [Sum of HV masses] / [Sum of HNV masses]. Preferably, R is such that 0 < R < 10,000, more particularly 0.01 < R < 1000; more particularly 0.05 < R < 500; preferably 0.1 < R < 100, or even 0.5 <R < 50. The addition of non-volatile oils tends to reduce the film's resistance to wear, so it is preferable to use them in low concentrations compared to volatile oils to maintain optimum resistance while having a comfortable skin sensation (soft, moisturizing, non-sticky sensations after applying a composition). Volatile alcohols The composition according to the invention comprises at least one volatile alcohol. By "alcohol" we mean any chemical compound containing at least one hydroxyl function in its structure. By "volatile substance" is meant any substance capable of evaporating on contact with the skin in less than one hour, at room temperature and atmospheric pressure. Said volatile substance is liquid at room temperature, in particular has a non-zero vapor pressure, at room temperature and atmospheric pressure, in particular having a vapor pressure ranging from 0.13 Pa to 40,000 Pa (10 -3 to 300 mm Hg), and preferably ranging from 1.3 Pa to 13,000 Pa (0.01 to 100 mm Hg), By "volatile alcohol" is meant any compound having at least one hydroxyl group and where more than 95% by weight of the compound is capable of evaporating in less than one hour at room temperature (25°C) and atmospheric pressure (760 mmHg) upon contact with a keratinous material such as skin or hair, in particular capable of evaporating upon contact with the skin in less than one hour, at room temperature and atmospheric pressure. Said volatile substance is liquid at room temperature, and preferably has a vapor pressure greater than or equal to 2.66 Pa, at room temperature (25°C) and atmospheric pressure, preferably in the range of 2.66 Pa to 40,000 Pa, preferably of 2.66 Pa to 13,000 Pa, and preferably from 2.66 Pa to 8000 Pa. Vapour pressure can be measured by the static method or by the isothermal thermogravimetric effusion method, depending on the vapour pressure of the oil (OECD 104 standard). The volatile alcohol(s) in accordance with the present invention are preferably chosen from lower C1-C4 monoalcohols, may be chosen from methanol, ethanol, propanol, isopropanol, n-butanol, isobutanol, t-butanol; preferably chosen from C1-C4 alcohols, preferably chosen from: ethanol, isopropanol, tert-butanol, n-butanol, and mixtures thereof, and more particularly ethanol. Their viscosity at 20°C, measured with a HAAKE Rheostress 600 device with a 60 mm diameter rotor, an angle of 2° at a shear rate of 200 s -1 is preferably 0.3 to 3 mPa.s. Advantageously, the volatile alcohol(s) are present in amounts ranging from 1 to 70% and more preferably from 5 to 50%, and more particularly from 5 to 30% by weight relative to the total weight of the composition. An advantage of the composition of the invention is that it can limit the level of volatile alcohol(s), which is often the cause of discomfort (dryness, tingling), without losing solubilizing power. Preferably, the weight ratio of the quantity of volatile alcohol(s) to the quantity of natural resin(s) is in the range of 0.5 to 50, preferably 1 to 30; preferably 1.2 to 20; preferably 1.5 to 15. Preferably, the weight ratio of the amount of volatile oil(s) to the amount of volatile alcohol(s) is within the range of preferably 0.01 to 100, preferably 0.1 to 10; preferably 0.5 to 5; preferably 1 to 4. Advantageously, in the composition according to the invention, the content by weight of volatile oil(s) is greater than the content by weight of volatile alcohol(s), itself greater than the content by weight of natural resin(s), over the total weight of the composition (oil > alcohol > resin). Thus, in the composition according to the invention, the sums (S) of the respective weight contents of volatile oil(s), volatile alcohol(s) and natural resin(s) preferably follow the rule: S (volatile oil(s)) > S (volatile alcohol(s)) > S (natural resin(s)). The undesirable properties of said volatile alcohols are counterbalanced by a judiciously chosen volatile oil content, while ensuring a sufficient volatile alcohol(s) content to allow solubilization of the natural resin. Liposoluble polymer The composition according to the invention comprises at least one ester (co)polymer vinyl, that is to say chosen from vinyl ester homopolymers and copolymers. Said polymer is advantageously liposoluble, that is to say soluble in an oily phase comprising organic oils or solvents. According to a first particularly advantageous embodiment, said vinyl ester (co)polymer is chosen from copolymers of: - (i) at least one vinyl ester monomer, in which the vinyl group is directly bonded to the oxygen atom of the ester group and the vinyl ester comprises a saturated, linear or branched hydrocarbon radical of 1 to 19 carbon atoms, preferably of 8 to 19 carbon atoms, and more preferably of 16 to 19 carbon atoms, bonded to the carbonyl of the ester group, and - (ii) at least one other monomer chosen from: a vinyl ester (different from the vinyl ester already present), an α-olefin (preferably having from 8 to 28 carbon atoms), an alkyl vinyl ether (the alkyl group of which preferably comprises from 2 to 18 carbon atoms), or an allylic or methallyl ester (preferably having a saturated, linear or branched hydrocarbon radical, from 1 to 19 carbon atoms, linked to the carbonyl of the ester group). The above copolymers are optionally crosslinked using crosslinking agents, in particular of the vinyl, allylic or methallyl type, such as tetraallyloxyethane, divinylbenzene, divinyl octanedioate, divinyl dodecanedioate, and divinyl octadecanedioate. Examples of such copolymers include vinyl acetate / allyl stearate, vinyl acetate / vinyl laurate, vinyl acetate / vinyl stearate, vinyl acetate / octadecene, vinyl acetate / octadecyl vinyl ether, vinyl propionate / allyl laurate, vinyl propionate / vinyl laurate, vinyl stearate / octadecene-1, vinyl acetate / dodecene-1, vinyl stearate / ethyl vinyl ether, vinyl propionate / cetyl vinyl ether, vinyl stearate / allyl acetate, 2,2-dimethyl vinyl octanoate / vinyl laurate, 2,2-dimethyl allyl pentanoate / vinyl laurate, dimethyl vinyl propionate / vinyl stearate, dimethyl vinyl ... allyl propionate / vinyl stearate, vinyl propionate / vinyl stearate, crosslinked with divinyl benzene, dimethyl vinyl propionate / vinyl laurate, crosslinked with divinyl benzene, vinyl acetate / octadecyl vinyl ether, crosslinked with tetraallyloxyethane, vinyl acetate / allyl stearate,crosslinked with divinyl benzene, vinyl acetate / octadecene-1 crosslinked with divinyl benzene and allyl propionate / allyl stearate crosslinked with divinyl benzene. , Advantageously, said at least one vinyl ester (co)polymer used in the composition according to the invention comprises, and preferably is, the vinyl acetate / allyl stearate copolymer (sold in particular under the trade name MEXOMERE PQ by Novéal). According to a second embodiment (alternative or complementary to the first), said vinyl ester (co)polymer is advantageously chosen from polyesters of polyvinyl alcohol and fatty acid. The polyvinyl alcohol used in polyvinyl alcohol fatty acid polyester is not particularly limited, and conventional polyvinyl alcohol can be used. Polyvinyl alcohol has a certain degree of polymerization. For example, polyvinyl alcohol with a degree of polymerization of 500 to 2000 can be used. The fatty acid used in the polyvinyl alcohol fatty acid polyester of the fat-soluble polymer is not particularly limited, and may include linear or branched, saturated or unsaturated C6-C30 fatty acids, optionally substituted with one or more hydroxyl groups. Preferably, linear and saturated C6 to C30, preferably C8 to C24, and more preferably C10 to C18 fatty acids are used. In the polyvinyl alcohol-fatty acid polyester of the fat-soluble polymer, the hydroxyl groups of the polyvinyl alcohol are esterified with the fatty acids. The hydroxyl groups of the polyvinyl alcohol may be fully esterified with the fatty acids, or the hydroxyl groups of the polyvinyl alcohol may be partially esterified with the fatty acids. As copolymers, one can also consider those resulting from copolymerization of vinyl esters having from 9 to 22 carbon atoms or of alkyl acrylates or methacrylates, the alkyl radicals having from 10 to 20 carbon atoms. Such (co)polymers may in particular be chosen from copolymers of vinyl polystearate, vinyl polystearate crosslinked using divinylbenzene, diallyl ether or diallyl phthalate, (co)polymers of stearyl poly(meth)acrylate, vinyl polylaurate, lauryl poly(meth)acrylate, these poly(meth)acrylates being able to be crosslinked using ethylene glycol dimethacrylate or tetraethylene glycol. Preferably, these copolymers have a weight average molecular weight ranging from 2,000 to 500,000 and preferably from 4,000 to 200,000. Advantageously, said at least one vinyl ester (co)polymer used in the composition according to the invention comprises, and preferably is, polyvinyl laurate (sold in particular under the trade name MEXOMERE PP by Novéal). Preferably, the vinyl ester polymer is present in the composition in a content of between 0.05% and 20% by weight, preferably between 0.1% and 15% by weight, more preferably between 0.2% and 12% by weight, better still between 0.5% and 10% by weight and / or the weight ratio between the total amount of resin(s) and the total amount of vinyl ester polymer(s) present in the composition ranges from 0.05 to 200, more preferably from 0.1 to 100, more preferably from 0.2 to 50, or even better from 0.5 to 20, preferably from 0.5 to 10. Advantageously, a composition according to the invention comprises between 1% and 20% by weight, and in particular between 2% and 10% by weight, for example from 2.5 to 5% by weight, of vinyl ester polymer(s) relative to the total weight of the composition. Other possible components of the oily phase The wax(es) According to a particular embodiment, the composition of the invention comprises one or more waxes. By "wax" is meant a lipophilic compound, solid at room temperature (25°C), with a reversible solid / liquid state change, having a melting point greater than or equal to 30°C and up to 200°C and in particular up to 120°C. In particular, the wax(es) suitable for the invention may have a melting point greater than or equal to 45°C, and in particular greater than or equal to 55°C. The composition according to the invention preferably comprises a wax content ranging from 0.5% to 30% by weight relative to the total weight of the composition, in particular from 1% to 20%, more particularly from 2% to 15%. According to a particular form of the invention, the composition of the invention is solid, in particular anhydrous. It can then be in the form of a stick. The pasty compound(s) According to a particular embodiment, the composition of the invention comprises one or more pasty compounds. For the purposes of the present invention, the term "pasty compound" means a lipophilic fatty compound with a reversible solid / liquid state change, having an anisotropic crystalline organization in the solid state, and comprising at a temperature of 23°C a liquid fraction and a solid fraction. According to a particular embodiment of the invention, the composition according to the invention comprises one or more volatile oils, one or more non-volatile oils, optionally water and optionally one or more organic solvents other than the oils a) and alcohols b) defined according to the invention. Advantageously, the total oily phase content is in the range of 5 to 100%, preferably 10 to 98% by weight, preferably 20 to 95% by weight, preferably 30 to 60% by weight, relative to the total weight of the composition. According to one embodiment of the invention, the composition comprises at least one continuous oily phase of composition defined above. According to a first embodiment, the composition of the invention is in the form of an oily composition, in particular anhydrous, such as an oily dispersion or an oily solution. According to a second embodiment of the invention, the composition further has an aqueous phase, Advantageously, the total content of oily phase is in the range of 5 to 100%, preferably 10 to 98% by weight, preferably 20 to 90% by weight, preferably 30 to 80% by weight, relative to the total weight of the composition. Aqueous phase The aqueous phase includes water and optionally water-soluble or water-miscible ingredients such as water-soluble solvents. A water suitable for the invention may be a floral water such as cornflower water and / or a mineral water such as VITTEL water, LUCAS water or LA ROCHE POSAY water and / or a thermal water. In the present invention, the term "water-soluble solvent" means a compound which is liquid at room temperature and miscible with water (miscibility in water greater than 50% by weight at 25°C and atmospheric pressure). The water-soluble solvents that can be used in the composition of the invention can also be volatile. Among the water-soluble solvents which may be used in the composition in accordance with the invention, mention may in particular be made of lower monoalcohols having from 1 to 5 carbon atoms such as ethanol and isopropanol, glycols having from 2 to 8 carbon atoms such as ethylene glycol, propylene glycol, 1,3-butylene glycol, propanediol, pentylene glycol, glycerin and dipropylene glycol, C 3-C 4 ketones and C z-C 4 aldehydes. The aqueous phase is preferably present in a concentration of 2 to 95% by weight, preferably 10 to 90% by weight, preferably in the range of 20 to 80% by weight, more particularly 30 to 60% by weight, relative to the total weight of said composition. Surfactants According to a particular embodiment of the invention, the composition further comprises one or more surfactants, preferably non-ionic, ionic or mixtures thereof. According to another particular embodiment of the invention, the composition does not comprise a surfactant. By "surfactant" we mean a compound that modifies the surface tension between two surfaces. The surfactant(s) are amphiphilic molecules, which have two parts of different polarity, one lipophilic (which retains fats) which is apolar, the other hydrophilic (miscible or soluble in water) is polar. The lipophilic part is generally a fatty chain, and the other water-miscible part is polar, and / or protic. By "ionic" we mean anionic, cationic, amphoteric, or zwitterionic. By “fatty chain” is meant a hydrocarbon chain comprising more than 6 atoms, preferably between 6 and 30 carbon atoms, preferably from 8 to 24 carbon atoms, linear or branched, saturated or unsaturated. Emulsifying surfactants are characterized by their HLB (Hydrophilic Lipophilic balance) value, HLB being the ratio of the hydrophilic part to the lipophilic part in the molecule. The term HLB is well known to those skilled in the art and is described, for example, in The HLB system. A time-saving guide to Emulsifier Selection (published by ICI Americas Inc; 1984). For emulsifying surfactants, the HLB generally ranges from 3 to 8 for the preparation of W / H emulsions. The HLB of the surfactant(s) used according to the invention can be determined by the GRIFFIN method or the DAVIES method. According to a first particular embodiment, the composition of the invention contains at least one non-ionic, silicone or non-silicone surfactant. Among the non-ionic surfactants according to the invention, mention may be made, alone or in mixtures, of fatty alcohols, alpha-diols, alkylphenols, these 3 types of compounds being polyethoxylated, polypropoxylated and / or polyglycerolated, and having a fatty chain comprising for example 8 to 22 carbon atoms, the number of ethylene oxide or propylene oxide groups being able to range in particular from 2 to 50 and the number of glycerol groups being able to range in particular from 2 to 30.Mention may also be made of copolymers of ethylene and propylene oxide, condensates of ethylene and propylene oxide on fatty alcohols; polyethoxylated fatty amides preferably having from 2 to 30 moles of ethylene oxide, polyglycerolated fatty amides comprising on average 1 to 5 glycerol groups and in particular 1.5 to 4; oxyethylenated sorbitan fatty acid esters having from 2 to 30 moles of ethylene oxide; sucrose fatty acid esters, polyethylene glycol fatty acid esters, alkylpolyglycosides, N-alkylglucamine derivatives, amine oxides such as (C,0-C14)alkylamine oxides or N-acylaminopropylmorpholine oxides. The surfactant(s) represent(s) in total particularly from 0.01% to 30% by weight relative to the total weight of the composition, preferably from 0.5% to 15% by weight and even more preferably from 1% to 10% by weight, better still between 1% and 5% by weight of the composition. Pigments According to a particular embodiment of the invention, the composition additionally comprises at least one pigment. Pigments are understood to mean white or colored particles, mineral or organic, insoluble in an aqueous medium, intended to color and / or opacify the composition. position and / or the resulting deposit. These pigments can be white or colored, mineral and / or organic. Preferably, the composition comprises at least 2% of pigments, preferably at least 5% by weight of pigment(s), more preferably from 5 to 40% by weight of pigment(s), in particular from 10 to 30% by weight and preferably from 9 to 20% by weight of pigment(s), relative to the total weight of said composition. According to a particular embodiment, the pigments used according to the invention are chosen from mineral pigments. Mineral pigment means any pigment that meets the definition of the Ullmann Encyclopedia in the inorganic pigment chapter. Among the mineral pigments useful in the present invention, mention may be made of zirconium or cerium oxides, as well as zinc, iron (black, yellow or red) or chromium oxides, manganese violet, ultramarine blue, chromium hydrate and ferric blue, titanium dioxide, metal powders such as aluminum powder and copper powder. The following mineral pigments may also be used: Ta:Os, Ti:Os, Ti 203, TiO, ZrO, in mixture with TiO,, ZrO, Nb:O;, CeO., ZnS. The size of the pigment useful in the context of the present invention is generally greater than 100 nm and can range up to 10 μm, preferably from 200 nm to 5 μm, and more preferably from 300 nm to 1 μm. According to a particular form of the invention, the pigments have a size characterized by a D
[50] greater than 100 nm and which can range up to 10 μm, preferably from 200 nm to 5 μm, and more preferably from 300 nm to 1 μm. The sizes are measured by static light scattering using a commercial particle size analyzer such as the Master Sizer 3000® from Malvern, which allows the particle size distribution of all particles to be determined over a wide range from 0.01 µm to 1000 µm. The data are processed based on the classical Mie scattering theory. This theory is most suitable for size distributions ranging from submicron to multimicron and allows the effective particle diameter to be determined. This theory is notably described in the work of Van de Hulst, HC, Light Scattering by Small Particles, Chapters 9 and 10, Wiley, New York, 1957. D
[50] represents the maximum size that 50% by volume of the particles has In the context of the present invention, the mineral pigments are more particularly iron oxide and / or titanium dioxide. By way of example, mention may be made more particularly of titanium dioxides and iron oxides, coated with aluminum stearoyl glutamate, for example marketed under the reference NAI® by the company MIYOSHI KASEIL. As mineral pigments which can be used in the invention, mention may also be made of: mother-of-pearl. By mother-of-pearl, we mean colored particles of any shape, iridescent or not, in particular, produced by certain molluscs in their shell or synthesized and which present a color effect by optical interference. The nacres may be chosen from pearlescent pigments, such as titanium mica coated with iron oxide, titanium mica coated with bismuth oxychloride, titanium mica coated with chromium oxide, titanium mica coated with an organic colorant, as well as pearlescent pigments based on bismuth oxychloride. They may also be mica particles on the surface of which are superimposed at least two successive layers of metal oxides and / or organic colorants. Examples of mother-of-pearl include natural mica coated with titanium oxide, iron oxide, natural pigment or bismuth oxychloride. Among the mother-of-pearls available on the market, we can cite the TIMICA®, FLAMENCO® and DUOCHROME® mother-of-pearls (mica-based) marketed by the company ENGELHARD, the TIMIRON® mother-of-pearls marketed by the company MERCK, the PRESTIGE® mica-based mother-of-pearls marketed by the company ECKART and the SUNSHINE® synthetic mica-based mother-of-pearls marketed by the company SUN CHEMICAL. Mother-of-pearl can more specifically have a yellow, pink, red, bronze, orange, brown, gold and / or coppery color or reflection. As an illustration of the mother-of-pearls that can be used in the context of the present invention, mention may be made, in particular, of gold-colored mother-of-pearls, in particular, marketed by the company ENGELHARD, under the name Brillant gold 212G® (Timica), Gold 222C® (Cloisonne), Sparkle Gold® (Timica), Gold 4504® (Chromalite) and Monarch Gold 233X® (Cloisonne); bronze mother-of-pearls, in particular, marketed by the company MERCK under the name Bronze fine® (17384) (Colorona) and Bronze® (17353) (Colorona) and by the company ENGELHARD under the name Super bronze (Cloisonne); orange mother-of-pearls, in particular, marketed by the company ENGELHARD under the name Orange 363C® (Cloisonne) and Orange MCR 101® (Cosmica) and by the company MERCK under the name Passion Orange® (Colorona) and Matte Orange (17449) ® (Microna);brown-tinted mother-of-pearl, in particular, marketed by the company ENGELHARD under the name Nu-Antique Copper 340XB® (Cloisonne) and Brown CL4509® (Chromalite); copper-reflecting mother-of-pearl, in particular, marketed by the company ENGELHARD under the name Copper 340A® (Timica); red-reflecting mother-of-pearl, in particular, marketed by the company MERCK under the name Sienna Fine® (17386) (Colorona); yellow-reflecting mother-of-pearl, in particular, marketed by the company; ENGELHARD under the name Yellow (4502) ® (Chromalite); red mother-of-pearl with a gold sheen, in particular, marketed by the company ENGELHARD under the name Sunstone G012® (Gemtone); pink mother-of-pearl, in particular, marketed by the company ENGELHARD under the name Tan Opale G005® (Gemtone); black mother-of-pearl with a gold sheen, in particular, marketed by the company ENGELHARD under the name Nu Antique Bronze 240 AB® (Timica), blue mother-of-pearl, in particular, marketed by the company MERCK under the name Matte Blue® (17433) (Microna), white mother-of-pearl with a silver sheen, in particular, marketed by the company MERCK under the name Xirona Silver® and orange-pinkish-green-gold mother-of-pearl, in particular, marketed by the company MERCEK under the name Indian Summer® (Xirona) and their blends. Among the pigments that can be used according to the invention, mention may also be made of those with an optical effect different from a simple conventional tint effect, that is to say unified and stabilized as produced by conventional coloring materials, such as, for example, monochromatic pigments. For the purposes of the invention, stabilized means devoid of the effect of variability of the color with the angle of observation or in response to a change in temperature. For example, this material may be chosen from metallic sheen particles, goniochromatic coloring agents, diffracting pigments, thermochromic agents, optical brightening agents, as well as fibers, in particular interference fibers. Of course, these different materials may be combined in such a way as to provide the simultaneous manifestation of two effects, or even a new effect in accordance with the invention. The particles with a metallic sheen that can be used in the invention are in particular chosen from: - particles of at least one metal and / or at least one metal derivative, - particles comprising an organic or mineral substrate, single-material or multi-material, covered at least partially by at least one layer with a metallic sheen comprising at least one metal and / or at least one metallic derivative, and - mixtures of said particles. Among the metals that may be present in said particles, there may be mentioned for example Ag, Au, Cu, Al, Ni, Sn, Mg, Cr, Mo, Ti, Zr, Pt, Va, Rb, W, Zn, Ge, Te, Se and their mixtures or alloys. Ag, Au, Cu, Al, Zn, Ni, Mo, Cr, and their mixtures or alloys (for example, bronzes and brasses) are preferred metals. Metal derivatives are compounds derived from metals, including oxides, fluorides, chlorides and sulfides. Examples of such particles include aluminum particles, such as those marketed under the names STARBRITE 1200 EAC® by the company SIBERLINE and METALURE® by the company ECKART. We can also cite metallic copper powders or mixtures of alloys, such as references 2844 marketed by the company RADIUM BRONZE, metallic pigments, such as aluminum or bronze, such as those marketed under the names ROTOSAFE 700® from the company ECKART, particles of aluminum coated with silica marketed under the name VISIONAIRE BRIGHT SILVER® from the company ECKART and particles of metallic alloy, such as bronze powders (copper and zinc alloy) coated with silica marketed under the name Visionaire Bright Natural Gold® from the company Eckart. These may also be particles comprising a glass substrate such as those marketed by the company NIPPON SHEET GLASS under the name MICROGLASS METASHINE®. The goniochromatic coloring agent may be selected, for example, from interference multilayer structures and liquid crystal coloring agents. Examples of symmetrical interference multilayer structures that can be used in compositions produced in accordance with the invention are, for example, the following structures: A / SiO / AI / SiO- / AI, pigments having this structure being marketed by the company DUPONT DE NEMOURS; Cr / MgF / A / MgF / Cr, pigments having this structure being marketed under the name CHROMAFLAIR® by the company FLEX; MoS / SiO / AV / SiO, / MoS; ; Fe,O / SiO / AI / SiO, / Fe:O;, and Fe,O; / SiO / Fe,0; / Si0, / Fe:0;, pigments having these structures being marketed under the name SICOPEARL® by the company BASF; MoS / SiO / mica-oxide / SiO, / MoS 2 ; Fe,0y / SiO0. / mica-oxide / SiO / Fe:0; ; TIO, / SIO, / TIO; and TIO / AI,O / TiO; ; SNO / TIO; / SIO / TIO / SnO; Fe,0 / Si0 / Fe20; ; SnO / mica / TiO / SIO / TIO / mica / SnO, pigments having these structures being marketed under the name XIRONA® by the company MERCK (Darmstadt).For example, these pigments may be the silica / titanium oxide / tin oxide structure pigments marketed under the name XIRONA MAGIC® by MERCK, the silica / brown iron oxide structure pigments marketed under the name XIRONA INDIAN SUMMER® by MERCK and the silica / titanium oxide / mica / tin oxide structure pigments marketed under the name XIRONA CARRIBEAN BLUEC® by MERCK. Mention may also be made of the INFINITE COLORS pigments from SHISEIDO. Depending on the thickness and nature of the different layers, different effects are obtained. Thus, with the Fe,0 / SiO / Al / SiO / Fe203 structure, the color changes from gold-green to gray-red for SiO layers; from 320 to 350 nm; from red to gold for SiO layers; from 380 to 400 nm; from violet to green for SiO layers, from 410 to 420 nm; from copper to . red for SiO layers, from 430 to 440 nm. Examples of pigments with a multi-layer polymer structure include those marketed by 3M under the name COLOR GLITTER®. Liquid crystal goniochromatic particles can be used, for example, those sold by the company CHENIX, as well as those marketed under the name HELICONE® HC by the company WACKER. Hydrophobic coated pigments According to a particular embodiment of the invention, the compositions according to the invention comprise at least one pigment coated with at least one lipophilic or hydrophobic compound and in particular as detailed below. This type of pigment is particularly advantageous in that it can be considered in large quantities in conjunction with a large quantity of water. Moreover, since they are treated with a hydrophobic compound, they show a predominant affinity for the oily gel phase which can then transport them. Of course, the compositions according to the invention can also contain uncoated pigments. The coating may also include at least one additional non-lipophilic compound. For the purposes of the invention, the coating of a pigment according to the invention generally designates the total or partial surface treatment of the pigment by a surface agent, absorbed, adsorbed or grafted onto said pigment. Surface-treated pigments may be prepared using chemical, electronic, chemical-mechanical or mechanical surface treatment techniques well known to those skilled in the art. Commercial products may also be used. The surfactant can be absorbed, adsorbed or grafted onto the pigments by solvent evaporation, chemical reaction and creation of a covalent bond. Alternatively, the surface treatment consists of coating the pigments. The coating may represent from 0.1% to 20% by weight, and in particular from 0.5% to 5% by weight, of the total weight of the coated pigment. The coating can be carried out for example by adsorption of a liquid surfactant on the surface of the solid particles by simple mixing with stirring of the particles and said surfactant, possibly hot, prior to the incorporation of the particles into the other ingredients of the makeup or care composition. Coating can be achieved, for example, by chemically reacting a surfactant with the surface of the solid pigment particles and creating a covalent bond between the surfactant and the particles. This method is described in particular in US patent 4,578,266. Chemical surface treatment may involve diluting the surfactant in a volatile solvent, dispersing the pigments in this mixture, and then slowly evaporating the volatile solvent so that the surfactant is deposited on the surface of the pigments. Lipophilic or hydrophobic treatment agent When the pigment comprises a lipophilic or hydrophobic coating, the latter is preferably present in the fatty phase of the composition according to the invention. According to a particular embodiment of the invention, the pigments may be coated according to the invention with at least one compound chosen from silicone surfactants; fluorinated surfactants; fluoro-silicone surfactants; metallic soaps; N-acylated amino acids or their salts; lecithin and its derivatives; isopropyl triisostearyl titanate; isostearyl sebacate; natural plant or animal waxes; polar synthetic waxes; fatty esters; phospholipids; and mixtures thereof. Silicone surfactant According to a particular embodiment, the pigments can be surface treated totally or partially with a silicone compound. The silicone surfactants can be chosen from organopolysiloxanes, silane derivatives, silicone-acrylate copolymers, silicone resins, and mixtures thereof. By organopolysiloxane compound is meant a compound having a structure comprising alternating silicon atoms and oxygen atoms and comprising organic radicals linked to the silicon atoms. Non-elastomeric organopolysiloxane Examples of non-elastomeric organopolysiloxanes that may be mentioned include polydimethylsiloxanes, polymethylhydrogensiloxanes and polyalkoxydimethylsiloxanes. The alkoxy group may be represented by the radical RO- such that R represents methyl, ethyl, propyl, butyl or octyl, 2-phenylethyl, 2-phenylpropyl or 3,3,3-trifluoropropyl radicals, aryl radicals such as phenyl, tolyl, xylyl, or substituted aryl radicals such as phenylethyl. One method for surface-treating pigments with polymethylhydrogensiloxane involves dispersing the pigments in an organic solvent and then adding the silicone compound. Heating the mixture creates covalent bonds between the silicone compound and the pigment surface. According to a preferred embodiment, the silicone surfactant may be a non-elastomeric organopolysiloxane, notably chosen from polydimethylsiloxanes. Alkylsilanes and alkoxysilanes Alkoxy-functional silanes are notably described by Witucki in A silane primer, Chemistry and applications of alkoxysilanes, Journal of Coatings Technology, 65, 822, pages 57-60, 1993, Alkoxysilanes such as alkyltriethoxysilanes and alkyltrimethoxysilanes marketed under the references Milquet A-137® (OSI Specialities) and Prosil 92202® (PCR) can be used for coating pigments. The use of alkylpolysiloxanes having a reactive terminal group such as alkoxy, hydroxy, halogen, amino or imino are described in the application JP H07-196946. They are also suitable for processing pigments. Silicone-acrylate polymers Grafted silicone-acrylic polymers having a silicone backbone as described in US patents 5,725,882, US 5,209,924, US 4,972,037, US 4,981,903, US 4,981,902, US 5,468,477, and in patents US 5,219,560 and EP 0 388 582, can be used. Other silicone-acrylate polymers may be silicone polymers having in their structure the following unit of formula (IT): [Chem.11] G, G j ÿ $, Mrs Fe O0 Ye (ee Sr 3rd me | See re f AS © f PT À (Ga-8 -6; G, (Ga S-6, (um in which the radicals G,, identical or different, represent hydrogen or a C,-Cp alkyl radical or a phenyl radical; the radicals G,, identical or different, represent a C,-C,0 alkylene group; G3 represents a polymeric residue resulting from the (homo)polymerization of at least one anionic monomer with ethylenic unsaturation; G, represents a polymeric residue resulting from the (homo)polymerization of at least one hydrophobic monomer with ethylenic unsaturation; m and n are equal to 0 or |; a is an integer ranging from 0 to 50; b is an integer which can be between 10 and 350, it is an integer ranging from 0 to 50, provided that one of the parameters a and c is different from 0. Preferably, the unit of formula (I) above has at least one, and even more preferably all, of the following characteristics: - the radicals G, denote an alkyl radical, preferably the methyl radical; -n is non-zero, and the Gz radicals represent a divalent C,-C3 radical, preferably a propylene radical; -Gz represents a polymeric radical resulting from the (homo)polymerization of at least one monomer of the carboxylic acid type with ethylenic unsaturation, preferably acrylic acid and / or methacrylic acid; - G4 represents a polymeric radical resulting from the (homo)polymerization of at least one monomer of the (C,-C;0)alkyl (meth)acrylate type, preferably of the isobutyl or methyl (meth)acrylate type. Examples of silicone polymers corresponding to formula (I) are in particular polydimethylsiloxanes (PDMS) onto which are grafted, via a thiopropylene type connecting link, mixed polymer units of the poly(meth)acrylic acid type and of the poly(methyl meth)acrylate type. Other examples of silicone polymers corresponding to formula (1) are in particular polydimethylsiloxanes (PDMS) onto which are grafted, via a thiopropylene type connecting link, polymer units of the isobutyl poly(meth)acrylate type. Silicone resins The silicone surfactant may be chosen from silicone resins such as those defined above. Fluorinated surfactant Pigments can be surface treated totally or partially with a fluorinated compound. The fluorinated surfactants may be chosen from perfluoroalkyl phosphates, perfluoropolyethers, polytetrafluoropolyethylenes (PTFE), perfluoroalkanes, perfluoroalkyl silazanes, hexafluoropropylene polyoxides, polyorganosiloxanes comprising perfluoroalkyl perfluoropolyether groups. A perfluoroalkyl radical is an alkyl radical in which all the hydrogen atoms have been replaced by fluorine atoms. Perfluoropolyethers are described in particular in patent application EP 0 486 135, and sold under the trade names FOMBLIN by the company MONTEFLUOS. Perfluoroalkyl phosphates are in particular described in JP application H05-86984. Perfluoroalkyl phosphate-diethanol amines marketed by Asahi Glass under the reference Asahi Guard AG530® can be used. Among the linear perfluoroalkanes, mention may be made of perfluorocycloalkanes, perfluoro(alkylcycloalkanes), perfluoropolycycloalkanes, aromatic perfluorohydrocarbons (perfluoroarenes) and organoperfluorinated hydrocarbon compounds comprising at least one heteroatom. Among the perfluoroalkanes, we can cite the series of linear alkanes such as per- fluorooctane, perfluorononane or perfluorodecane. Among the perfluorocycloalkanes and perfluoro(alkylcycloalkanes), we can cite perfluorodecalin sold under the name FLUTEC PPS GMP by the RHODIA Company, perfluoro(methyldecalin), perfluoro(C;-Cs)alkyl-cyclohexanes) such as perfluoro(butylcyclohexane). Among the perfluoropolycycloalkanes, mention may be made of bicyclo[3.3.1]nonane derivatives such as perfluorotrimethylbicyclo[3.3.1]nonane, adamantane derivatives such as perfluorodimethyladamantane and perfluorinated derivatives of hydrogenated phenanthrene such as tetracosafluoro-tetradecahydrophenanthrene. Perfluoroarenes include perfluorinated naphthalene derivatives such as perfluoronaphthalene and perfluoromethyl-1-naphthalene. Examples of commercial references of pigments treated with a fluorinated compound include: - yellow iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Yellow 601® by the company Daito Kasei; - red iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Red R 516L® by the company Daito Kasei; -black iron oxide / perfluoroalkyl phosphate sold under the reference PF 5 Black BL 100® by the company Daito Kasei; - titanium dioxide / perfluoroalkyl phosphate sold under the reference PF 5 TiO2 CR 50® by the company Daito Kasei; -yellow iron oxide / perfluoropolymethylisopropylether sold under the reference Iron Oxide Yellow BF-25-3® by the company Toshiki; - DC Red 7 / perfluoropolymethylisopropylether sold under the reference D&C Red 7 FHC® by Cardre Inc.; and - DC Red 6 / PTFE sold under the reference T 9506® by the company Warner-Jenkinson. Fluorosilicone surfactant The pigments can be surface treated totally or partially with a fluoro-silicon compound. The fluorosilicon compound may be selected from perfluoroalkyl dimethicones, perfluoroalkyl silanes and perfluoroalkyltrialkoxysilanes. Examples of perfluoroalkyl silanes include LP-IT® and LP-4T® products marketed by Shin-Etsu Silicone. As an example of commercial references of pigment treated with a fluoro-silicon compound, we can cite titanium dioxide / fluorosilicone sold under the reference Fluorosil Titanium Dioxide 100TA® by the company Advanced Dermaceuticals International Inc. Other lipophilic surfactants The hydrophobic treatment agent may also be selected from (i) metallic soaps such as aluminum dimyristate, and the aluminum salt of hydrogenated tallow glutamate; As metallic soaps, mention may in particular be made of metallic soaps of fatty acids having from 12 to 22 carbon atoms, and in particular those having from 12 to 18 carbon atoms. The metal in metallic soap can be zinc or magnesium, for example. As metallic soap, zinc laurate, magnesium stearate, magnesium myristate, zinc stearate, and their mixtures can be used. The hydrophobic treatment agent may also be chosen from ii) fatty acids such as lauric acid, myristic acid, stearic acid, palmitic acid. The hydrophobic treatment agent may also be chosen from iii) N-acylated amino acids or their salts which may comprise an acyl group having from 8 to 22 carbon atoms, such as for example a 2-ethyl hexanoyl, caproyl, lauroyl, myristoyl, palmitoyl, stearoyl, cocoyl group. The amino acid can be, for example, lysine, glutamic acid or alanine. The salts of these compounds can be aluminum, magnesium, calcium, zirconium, zinc, sodium, potassium salts. Thus, according to a particularly preferred embodiment, an N-acylated amino acid derivative may in particular be a glutamic acid derivative and / or one of its salts, and more particularly a stearoyl glutamate, such as for example aluminum stearoyl glutamate. The hydrophobic treatment agent may also be selected from iv) lecithin and its derivatives. The hydrophobic treatment agent may also be v) isopropyl triisostearyl titanate. Examples of pigments treated with isopropyl titanium triisostearate (ITT) include those sold under the commercial reference BWBO-I2® (Iron oxide CI77499 and isopropyl titanium triisostearate), BWYO-I2® (Iron oxide CI77492 and isopropyl titanium triisostearate), and BWRO-I2® (Iron oxide CI77491 and isopropyl titanium triisostearate) by the company KOBO. The hydrophobic treatment agent may also be vi) isostearyl sebacate The hydrophobic treatment agent may also be chosen from vii) natural vegetable or animal waxes or polar synthetic waxes; The hydrophobic treatment agent may also be chosen from viii) fatty esters, in particular jojoba esters; The hydrophobic treatment agent may also be chosen from ix) phos- pholipids. The waxes mentioned in the compounds cited above may be those generally used in the cosmetic field, as defined below. They can be hydrocarbon, silicone and / or fluorinated, possibly containing ester or hydroxyl functions. They can also be of natural or synthetic origin. Polar wax means a wax containing chemical compounds comprising at least one polar group. Polar groups are well known to those skilled in the art; they may be, for example, alcohol, ester or carboxylic acid groups. Polar waxes do not include polyethylene waxes, paraffin waxes, microcrystalline waxes, ozokerite or Fisher-Tropsch waxes. In particular, polar waxes have an average solubility parameter da of HANSEN at 25°C such that 6a > 0 (J / em°)"? and better ôa > 1 (J / em>)"2: 151 462 2, =49, where ôp and ôh are respectively the polar and interaction-type contributions specific to the Hansen solubility parameters. The definition of solvents in the three-dimensional solubility space according to HANSEN is described in the article by CM HANSEN, The three dimensional solubility parameters J. Paint Technol. 39, 105 (1967): - ôh characterizes the specific interaction forces (hydrogen bond type, acid / base, donor / acceptor, etc.); - Ôp characterizes the DEBYE interaction forces between permanent dipoles as well as the KEESOM interaction forces between induced dipoles and permanent dipoles. The parameters ôp and ôh are expressed in (J / em>)"2, A polar wax is made up of molecules containing, in addition to carbon and hydrogen atoms in their chemical structure, heteroatoms (such as O, N, P). By way of illustration and not limitation of these polar waxes, mention may in particular be made of natural polar waxes, such as beeswax, lanolin wax, orange wax, lemon wax, and Chinese insect waxes, rice bran wax, Carnauba wax, Candellila wax, Ouricury wax, cork fiber wax, sugar cane wax, Japanese wax and sumac wax, montan wax. According to a particular embodiment, the pigments can be coated with at least one compound chosen from silicone surfactants; fluorinated surfactants; N-acylated amino acids or their salts; isopropyl trisostearyl titanate; natural plant or animal waxes; fatty esters; and their mixtures. According to a particularly preferred embodiment, the pigments may be coated with an N-acylated amino acid and / or one of its salts, in particular with a glutamic acid derivative and / or one of its salts, or with a fatty ester, in particular with a jojoba ester. According to a more particularly preferred embodiment, the pigments may be coated with an N-acylated amino acid and / or one of its salts, in particular with a glutamic acid derivative and / or one of its salts, in particular a stearoyl glutamate, such as for example aluminum stearoyl glutamate. As examples of coated pigments according to the invention, mention may be made more particularly of titanium dioxides and iron oxides, coated with aluminum stearoyl glutamate, for example marketed under the reference NAI by MIYOSHI KASEI. Pigments not coated with a hydrophobic compound As stated previously, a composition may further contain pigments not coated with a lipophilic or hydrophobic compound. These other pigments can be coated with a hydrophilic compound or uncoated. These pigments may be mineral pigments, in particular as defined above. These pigments can also be organic pigments. Organic pigment means any pigment that meets the definition of the Ullmann Encyclopedia in the organic pigment chapter. The organic pigment may in particular be chosen from nitroso, nitro, azo, xanthene, quinoline, anthraquinone, phthalocyanine, metal complex type, isoindolinone, isoindoline, quinacridone, perinone, perylene, diketopyrrolopyrrole, thioindigo, dioxazine, triphenylmethane, quinophthalone compounds. The organic pigment(s) may be chosen, for example, from carmine, carbon black, aniline black, melanin, azo yellow, quinacridone, phthalocyanine blue, sorghum red, the blue pigments codified in the Color Index under the references CI 42090, 69800, 69825, 73000, 74100, 74160, the yellow pigments codified in the Color Index under the references CI 11680, 11710, 15985, 19140, 20040, 21100, 21108, 47000, 47005, the green pigments codified in the Color Index under the references CI 61565, 61570, 74260, the pigments oranges codified in the Color Index under the references CI 11725, 15510, 45370, 71105, the red pigments codified in the Color Index under the references CI 12085, 12120, 12370, 12420, 12490, 14700, 15525, 15580, 15620, 15630, 15800, 15850, 15865, 15880, 17200, 26100, 45380, 45410, 58000, 73360, 73915, 75470, and the pigments obtained by poly- oxidative merization of indolic and phenolic derivatives as described in patent FR 2 679 771. These pigments may also be in the form of composite pigments as described in patent EP1184426. These composite pigments may be composed in particular of particles comprising an inorganic core at least partially covered with an organic pigment and at least one binder ensuring the fixing of the organic pigments on the core. The pigment can also be a lake. Lake refers to insolubilized dyes adsorbed onto insoluble particles, the resulting mixture remaining insoluble during use. Inorganic substrates on which dyes are adsorbed include, for example, alumina, silica, calcium sodium borosilicate or calcium aluminum borosilicate, and aluminum. Organic colorants include cochineal carmine. Other products known under the following names include: D&C Red 21 (CI 45380), D&C Orange 5 (CI 45370), D&C Red 27 (CI 45410), D&C Orange 10 (CI 45425), D&C Red 3 (CI 45430), D&C Red 4 (CI 15510), D&C Red 33 (CI 17200), D&C Yellow 5 (CI 19140), D&C Yellow 6 (CI 15985), D&C Green (CI 61570), D&C Yellow 10 (CI 77002), D&C Green 3 (CI 42053), D&C Blue 1 (CI 42090). Examples of lakes include the product known as D&C Red 7 (CI 15850:1). Nature of the hydrophilic coating As stated previously, these other pigments can be coated with a hydrophilic compound. Said hydrophilic compound for treating a pigment on the surface to optimize its dispersion in the gelled aqueous phase is more particularly chosen from biological polymers, carbohydrates, polysaccharides, polyacrylates or polyethylene glycol derivatives. Examples of biological polymers include polymers based on carbohydrate monomers. More particularly, mention may be made of biosaccharide gum; chitosans and their derivatives, such as butoxychitosan, carboxymethyl chitosan, carboxybutyl chitosan, chitosan gluconate, chitosan adipate, chitosan glycolate, chitosan lactate, etc.; chitins and their derivatives, such as carboxymethyl chitin, chitin glycolate; cellulose and its derivatives such as cellulose acetate; microcrystalline cellulose; distarch phosphate; sodium hyaluronate; soluble proteoglycans; galacto-arabinans; glycosaminoglycans; glycogen; sclerotium gum; dextran; starch and its derivatives; and mixtures thereof. Examples of carbohydrates include polyhydroxyaldehydes or polyhydroxyketones, with the general formula: C,(H,0), in which x and y can range from 1 to 1,000,000. Carbohydrates can be monosaccharides, disaccharides or polysaccharides. Examples of carbohydrates that may be mentioned include amylodextrins, betaglucans, cyclodextrins, modified corn starch, glycogen, hyaluronic acid, hydroxypropylylodextrin, lactose, maltitol, guanosine, glyceryl starch, Triticum Vulgare starch, trehalose, sucrose and its derivatives, raffinose, sodium chondridine sulfate. C,-C» alkylene glycols or C,-C» alkylene glycol ethers, alone or in combination with tri-C,-C»g-alkylsilanes, may also be used as surface treatment agents. Examples include pigments surface-treated with PEG alkyl ether alkoxy silane, such as, for example, pigments treated with PEG-8-methyl ether triethoxysilane marketed by KOBO under the name SW pigments. Also suitable for the invention as a surface treatment agent are silicones such as dimethicones having hydrophilic groups, also known as dimethicone copolyols or alkyl dimethicone copolyols. In particular, such dimethicones may comprise, as repeating units, C1-C1, alkylene oxides, such as ethylenic or propylenic. An example is the pigment treated with PEG-12-Dimethicone, marketed by SENSIENT CORPORATION under the name LCW AQ® Pigment. The quantity of pigments coated by at least one hydrophilic compound and / or uncoated pigments is in particular conditioned by the destination of the cosmetic composition considered and its adjustment is of course within the competence of the formulator of the composition. According to a particular embodiment, the composition additionally comprises at least one pigment chosen from titanium dioxides and / or iron oxides, in particular coated with a hydrophobic surface treatment agent, in particular with an N-acylated amino acid and / or one of its salts, in particular with a glutamic acid derivative and / or one of its salts, in particular a stearoyl glutamate, such as for example aluminum stearoyl glutamate. Additives The compositions according to the invention may also comprise additives commonly used in care and / or makeup products such as organic UV filters other than those described above; inorganic UV filters; moisturizing agents such as polyols such as glycerin, propanediol, pentylene glycol; fillers; coloring materials; thickening or gelling agents; preservatives, chelating agents, perfumes and mixtures thereof. Fillers The compositions in accordance with the invention may also comprise at least one filler, of organic or mineral nature, making it possible, in particular, to give them additional properties of mattness, coverage, hold and / or improved stability. By filler, we mean colorless or white, solid particles of all shapes, which are insoluble and dispersed in the medium of the composition. Mineral or organic in nature, they allow to give body or rigidity to the composition and / or softness, and uniformity to the makeup. The fillers used in the compositions according to the present invention may be of lamellar, globular, spherical, fiber forms or any other intermediate form between these defined forms. The fillers according to the invention may or may not be surface coated, and, in particular, they may be surface treated with silicones, amino acids, fluorinated derivatives or any other substance promoting the dispersion and compatibility of the filler in the composition. Examples of mineral fillers include talc, mica, silica, hollow silica microspheres, kaolin, calcium carbonate, magnesium carbonate, hydroxyapatite, boron nitride, glass or ceramic microcapsules, silica and titanium dioxide composites, such as the TSG® series marketed by Nippon Sheet Glass, and hydrophobic silica aerogels. Examples of organic fillers include polyamide powders (Nylon® Orgasol from Atochem), polyethylene, polymethyl methacrylate, polytetrafluoroethylene powders (Teflon®), acrylic acid copolymers (Polytrap® from Dow Corning), lauroyl lysine, hollow polymeric microspheres such as those of polyvinylidene chloride / acrylonitrile such as Expancel® (Nobel Industrie), Hexamethylene Diisocyanate / Trimethylol Hexyllactone copolymer powder (Plastic Powder® from Toshiki), silicone resin microbeads (Tospearl® from Toshiba for example), synthetic or natural micronized waxes, metallic soaps derived from organic carboxylic acids having from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example, zinc, magnesium or lithium stearate, zinc laurate, zinc myristate magnesium, PolyporeÔ L 200 (Chemdal Corporation), powders crosslinked elastomeric organopolysiloxane coated with silicone resin, in particular silsesquioxane resin, as described for example in patent US5538793. It may also be cellulose powder such as that marketed by Daito in the Cellulobeads range. Silica particles According to a preferred form, the composition according to the invention comprises, in addition to the silica particles chosen from the hydrophobic silica aerogel particles, silica particles different from the previous ones, and mixtures thereof. Hydrophobic silica aerogels Hydrophobic silica aerogels are porous materials obtained by replacing (in particular by drying) the liquid component of a silica gel with air. They are generally synthesized by sol-gel process in a liquid medium and then dried usually by extraction of a supercritical fluid, the most commonly used being supercritical CO. This type of drying prevents contraction of the pores and the material. The sol-gel process and the different drying methods are described in detail in Brinker CT., and Scherer GW, Sol-Gel Science: New York: Academic Press, 1990. The hydrophobic silica aerogels used according to the present invention are preferably silylated silica aerogels (INCI name Silica Silylate). By hydrophobic silica is meant any silica whose surface is treated with silylating agents, for example with halogenated silanes such as alkylchlorosilanes, siloxanes, in particular dimethylsiloxanes such as hexamethyldisiloxane, or silazanes, so as to functionalize the OH groups with Si-R silyl groups, for example trimethylsilyl groups. Regarding the preparation of surface-modified hydrophobic silica aerogel particles by silylation, reference may be made to document US 7,470,725. In particular, hydrophobic silica aerogel particles modified on the surface by trimethylsilyl groups (trimethylsiloxylated silica) will be used. Hydrophobic aerogel particles are any aerogel-type particle with a water absorption capacity at WET POINT of less than 0.5 ml / g, i.e. less than 10 g of water per 100 g of particle. The absorption capacity measured at the Wet Point, and noted WP, corresponds to the quantity of a solvent (expressed in grams or milliliters) that must be added to 1 g of particles to obtain a homogeneous paste. It is measured according to the so-called Wet Point method or method for determining the uptake of solvent (water or oil) of powder described in standard NF T 30-022. It corresponds to the quantity of solvent adsorbed on the available surface of the powder and / or absorbed by the powder by measuring the Wet Point, described below: A glass plate (25 x 25 mm) is placed on a balance and a quantity m of | g of powder is weighed onto the glass plate, then a solvent (water or isononyl isononanoate for example) is added drop by drop. The solvent is gradually added to the powder, mixing the mixture regularly (every 3 to 4 drops) using the spatula. The addition of solvent is stopped when a homogeneous paste is obtained. This paste should spread on the glass plate without cracking or lumps forming. The mass of solvent required to obtain the Wet Point is noted. The average over 3 tests is taken. Knowing the density of the solvent, the volume Vs (expressed in ml) of solvent used is deduced. The solvent uptake corresponds to the ratio Vs / m. Preferably, the hydrophobic silica aerogel particles according to the invention preferably have an oil absorption capacity measured at the WET POINT ranging from 5 to 18 ml / g, preferably from 6 to 15 ml / g and better still from 8 to 12 ml / g. The hydrophobic silica aerogel particles used in the present invention preferably have a specific surface area per unit mass (SM) ranging from 200 to 1500 m? / g, preferably from 600 to 1200 m° / g and more preferably from 600 to 800 m2 / g, and a size expressed as volume average diameter (D [0.5]) of less than 1500 um and preferably ranging from 1 to 30 um, preferably from 5 to 25 um, more preferably from 5 to 20 um and even more preferably from 5 to 15 um. The specific surface area per unit mass can be determined by the nitrogen absorption method called the BET (BRUNAUER - EMMET - TELLER) method described in The Journal of the American Chemical Society, vol. 60, page 309, February 1938 and corresponding to the international standard ISO 5794 / 1 (Annex D). The BET specific surface area corresponds to the total specific surface area of the particles considered. The sizes of the aerogel particles according to the invention can be measured by static light scattering using a commercial particle size analyzer such as the Master Sizer 2000® from Malvern. The data are processed on the basis of Mie scattering theory. This theory, which is accurate for isotropic particles, makes it possible to determine an effective particle diameter in the case of non-spherical particles. This theory is described in particular in the work of Van de Hulst, HC, Light Scattering by Small Particles Chapters 9 and 10, Wiley, New York, 1957. The hydrophobic silica aerogel particles used in the present invention may advantageously have a packed density ranging from 0.02g / cm* to 0.10g / em*, preferably from 0.02g / cm* to 0.08g / cm°. In the context of the present invention, this density can be assessed according to the following protocol, known as the packed density: 40 g of powder are poured into a graduated cylinder; then the cylinder is placed on the STAV 2003® device from STAMPF VOLUMETER; the cylinder is then subjected to a series of 2500 tampings (this operation is repeated until the difference in volume between 2 consecutive tests is less than 2%); then the final volume Vf of tamped powder is measured directly on the test piece. The tamped density is determined by the ratio m / VË, in this case 40 / V£ (Vf being expressed in cm? and men g). According to one embodiment, the hydrophobic aerogel particles used in the present invention have a specific surface area per unit volume ranging from 5 to 60 m' / cm>, preferably from 10 to 50 m? / cm* and more preferably from 15 to 40 m? / cm*. The specific surface area per unit volume is given by the relation: Sy = Sy.p where p is the packed density expressed in g / cm° and Sy is the specific surface area per unit mass expressed in m' / g, as defined above. According to a particular embodiment, the aerogel particles used are inorganic and more particularly hydrophobic silica aerogel particles having the properties stated above. As hydrophobic silica aerogels which can be used in the invention, mention may be made, for example, of the aerogel marketed under the name VM-2260 (INCI name Silica Silylate), by the company Dow Corning, the particles of which have an average size of approximately 1000 microns and a specific surface area per unit mass ranging from 600 to 800 m? / g. We can also mention the aerogels marketed by the Cabot company under the references AEROGEL TLD 201®, AEROGEL OGD 201® and AEROGEL TLD 203®, ENOVA® AEROGEL MT 1100, ENOVA AEROGEL MT 1200®. In particular, the aerogel marketed under the name VM-2270® (INCI name Silica Silylate), by the company Dow Coming, will be used, the particles of which have an average size ranging from 5-15 microns and a specific surface area per unit mass ranging from 600 to 800 m° / g. The aerogel marketed under the name Enova® Aerogel MT 1100® (INCI name Silica Silylate) by the company CABOT will also be used, the particles of which have an average size ranging from 2-25 microns and a specific surface area per unit mass ranging from 600 to 800 m? / g. The hydrophobic aerogel particles represent from 0.05 to 10% by weight, preferably from 0.1 to 8% by weight, better still from 0.2 to 5% by weight, more preferably from 0.3 to 3% by weight relative to the total weight of the composition. Other silica particles Other usable silicas can be natural and untreated. Examples include silicas offered under the names SILLITIN N85®, SILLITIN N87®, SILLITIN N82®, SILLITIN V85® and SILLITIN V88® by the company HOFFMANN MINERAL. They can be pyrogenic. Fumed silicas can be obtained by high-temperature hydrolysis of a volatile silicon compound in an oxyhydrogen flame, producing a finely divided silica. This process makes it possible to obtain hydrophilic silicas which have a significant number of silanol groups on their surface. It is possible to chemically modify the surface of said silica, by chemical reaction generating a reduction in the number of silanol groups. In particular, silanol groups can be substituted by hydrophobic groups: a hydrophobic silica is then obtained. Hydrophobic groups can be: (a) trimethylsiloxyl groups, which are obtained in particular by treatment of fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are called Silica Silylate according to the CTFA (6th edition, 1995). ; (b) dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained in particular by treatment of fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are called Silica Dimethyl Silylate according to the CTFA (6th edition, 1995). As silica powders other than silica aerogels, we can more particularly cite: - porous silica microspheres sold under the name SILICA BEADS SB-700® by the company MYOSHI; SUNSPHERE® H51, SUNSPHERE® H33 by the company ASAHI GLASS; - amorphous silica microspheres coated with polydimethylsiloxane sold under the name SA SUNSPHERE® H 33®, SA SUNSPHERE® H53® by the company AGC SITECH; - precipitated silica microspheres, for example coated with mineral wax such as polyethylene and notably sold under the name ACEMATT OK 412® by the company EVONIK DEGUSSA. As silica powder, we will more particularly use porous silica microspheres such as those sold under the name SILICA BEADS SB-700® by the company MYOSHI; SUNSPHERE® H51, SUNSPHERE® H33 by the company AGC SITECH. The silica particles other than the hydrophobic silica aerogel particles are present in the composition according to the invention in a content ranging from 0.01 to 15% by weight, preferably ranging from 0.1 to 10% by weight, and most preferably ranging from 0.5 to 5% by weight, relative to the total weight of the composition. According to a preferred form, the composition according to the invention will comprise a mixture comprising at least hydrophobic silica aerogel particles such as those described above and other silica particles such as those described above, in particular porous silica microspheres. Additional coloring matters A composition according to the invention may further comprise at least one additional coloring material and preferably in an amount of at least 0.01% by weight relative to the total weight of the composition. For obvious reasons, this quantity is likely to vary significantly with regard to the intensity of the desired color effect and the color intensity provided by the coloring materials considered and its adjustment clearly falls within the skills of those skilled in the art. The additional coloring materials suitable for the invention may be water-soluble but also fat-soluble. For the purposes of the invention, the term "water-soluble coloring matter" means any generally organic, natural or synthetic compound, soluble in an aqueous phase or water-miscible solvents and capable of coloring. As water-soluble dyes suitable for the invention, mention may in particular be made of synthetic or natural water-soluble dyes such as, for example, FDC Red 4, DC Red 6, DC Red 22, DC Red 28, DC Red 30, DC Red 33, DC Orange 4, DC Yellow 5, DC Yellow 6, DC Yellow 8, FDC Green 3, DC Green 5, FDC Blue 1, betanin (beetroot), carmine, copper chlorophyllin, methylene blue, anthocyanins (enocyanin, black carrot, hibiscus, elderberry), caramel, riboflavin. Water-soluble colorants include, for example, beetroot juice and caramel. For the purposes of the invention, the term “liposoluble coloring matter” means any generally organic, natural or synthetic compound, soluble in an oily phase or solvents miscible with a fatty substance and capable of coloring. As liposoluble dyes suitable for the invention, mention may in particular be made of liposoluble dyes, synthetic or natural, such as, for example, DC Red 17, DC Red 21, DC Red 27, DC Green 6, DC Yellow 11, DC Violet 2, DC Orange 5, Sudan red, carotenes (B-carotene, lycopene), xanthophylls (capsanthin, capsorubin, lutein), palm oil, Sudan brown, quinoline yellow, annatto, curcumin. Form of the composition The composition of the invention may be in the form of an anhydrous composition, a water-in-oil emulsion or an oil-in-water emulsion. According to a first embodiment of the invention, the composition is monophasic oily. According to another advantageous embodiment of the invention, the composition comprises an aqueous phase, in which case it is preferably in the form of a water-in-oil emulsion, or optionally a composition with several separate phases (such as a two-phase). By “water-in-oil” emulsion or W / O or W / O for “water in oil”, we mean a composition comprising an immiscible oily phase and an aqueous phase; the aqueous phase being dispersed in the form of droplets in the oily phase (called continuous) so as to obtain a macroscopically homogeneous composition. Galenic forms with a continuous oily phase are preferred in the case of the composition of the invention where the performance driver of the hold is provided by the natural resin solubilized in the oily phase. These forms also promote the dispersion of the pigments, their homogeneity and thus optimize the coverage obtained for the film obtained after application of the composition according to the invention (as demonstrated in the examples). The composition of the present invention is particularly suitable for the manufacture of cosmetic products with fluid textures. Advantageously, the composition according to the invention is more particularly in the form of a viscoelastic liquid of fluid to viscous whose modulus G* (viscoelastic modulus) is between 0.1 and 20,000 Pa, more particularly between 1 and 5,000 Pa, or even between 10 and 1,000 Pa. The modulus G* is measured with an imposed stress rheometer and the values are taken on the viscoelastic plateau at 25°C. Applications According to one embodiment, a composition of the invention may advantageously be in the form of a composition for caring for the skin, body or face, in particular the face. According to another embodiment, a composition of the invention may advantageously be in the form of a makeup composition for keratin materials, in particular the skin of the body or face, in particular the face. Thus, according to a sub-mode of this embodiment, a composition of the invention can advantageously be presented in the form of a base composition for makeup. A composition of the invention may advantageously be in the form of a liquid product for lip makeup, in particular in the form of a liquid lipstick. According to another sub-mode of this embodiment, a composition of the invention may advantageously be in the form of a makeup composition for the skin and in particular for the face. It may thus be a foundation, an eyeshadow or a blush. It could also be a mascara, an eyeliner, a concealer or corrector, an eyebrow product, a skincare product, a sunscreen product, or a hygiene product, or even a hair styling product, hair coloring, or nail polish. Such compositions are in particular prepared according to the general knowledge of those skilled in the art. The invention is illustrated in more detail by the examples presented below. Unless otherwise indicated, the quantities indicated are expressed as a percentage by mass. The examples which follow allow a better understanding of the invention without, however, being limiting in nature. Examples Ingredients : [Tables 1] CANDELILL A Resin |wax A 66-71 GLYCERY |PROTIUM HEP- |CL TAPHYLLUM A ROSINATE |RESIN Resin Resin R c BA [Melting temperature (Tf) °C |- F | [Twisting point °C 45–52 nt°C 86 84-88 ition 43 40-45 42 40-45 51 48-55 Transition temperature 43 51 34 - glass (Tg) °C 40-45 48-55 [Tables2] [Business Name |Supplier CANDELILLA JAPAN NATURAL RESIN E-1 PRODUCTS [B- PROTIUM HEP- CITROBREU CITROLEO TAPHYLLUM RESIN Fe GLYCERYL |RESIESTER GUM A |RESIS Resin or|Name INCI [Commercial Name |Supplier Gellifier |A EUPHORBIA CANDELILLA JAPAN NATURAL CERIFERA RESIN E-1 PRODUCTS (CANDELILLA) WAX EXTRACT [B PROTIUM HEP- CITROBREU CITROLEO CITROLEO RESIESTER GUM A [LURESA RESINAS ROSINATE 35 SL; |p ALLYLSTEARATE / VA |MEXOMER PQ NOVEAL COPOLYMER Preparation of compositions Operating mode and hardware used for each test: Each resin (A, B, C) and gelling agent (D) were implemented in mixtures of ethanol and isododecane at room temperature, according to the weight proportions indicated in the following Tables, and according to the protocol described below. - Mix the resin with the solvents under magnetic stirring at 1200 rpm, for 24 hours at room temperature of 25°C - Add the gelling agent by raining it into the resin / solvent mixture - Leave stirring until the resin is completely dissolved and the polymer is deployed. - Weigh the whole thing (beaker + mixture), readjust the quantity of volatile solvents (if a slight loss of volatiles is observed) - The following colored raw materials are then added: the organic pigment RED 7 or the mineral pigments Iron oxides coated using a rotor-stator at room temperature (25°C). Evaluation protocol for dry and oil friction resistance Certain compositions are evaluated for their resistance to friction, by colorimetric measurements on dry film before and after abrasion, a test whose protocol is detailed below. Protocol for spreading compositions into a film: The spreading of the products is done on a spreading bench (Elcometer 4340 Applicator) allowing to adjust its speed as well as the distance over which it is done. The bench is equipped with a suction system connected to a pump so that the support where it is done the spreading, does not move. Contrast cards with a black background and an unvarnished white background are used (1 byko-chart, uncoated N2A, code 2831). The spreading thickness is adjustable thanks to the square spreader placed on the support so as to spread by leveling when the platform is switched on. Each slice of the spreader allows spreading with a different thickness ranging from 25um to 200yum. The chosen thickness is 25 μm in order to get closer to the thickness of the in vivo film. A weight of 960 g is added on top of the spreader during spreading. The spreading speed is set to lin / sec, or 2.54cm / s. The films are dried for 24 hours at 34°C and ambient RH on a hot plate. Friction resistance test protocol: The friction resistance test is performed by colorimetric measurements on dry film before and after abrasion. Abrasion is performed by attaching a strip of tissue (Chicopee® Veraclean® Polish Plus) to the spreader edge at 25um. The weight of 960g is added over the spreader during abrasion. The bench speed is set at 2.54cm / s. The color measurement before and after abrasion is done with the Konica Minolta CM-700d spectrophotometer. The contact measurement ensures the absence of light pollution. Selected settings: Aperture 8 mm; Uncertainty: 0.04; SCISCE measurement; Geometry d / 8°. The color measurements on the two backgrounds (black background FN and white background FB) make it possible to characterize the coverage of a foundation by calculating the "contrast ratio", (CR%), i.e. YFN / YFB x 100, where YFN and YFB are respectively the luminance values measured on a black background and the white background, the latter being higher as the foundation covers more. In order to evaluate the resistance to friction, the "Contrast Ratio" respectively before friction (CR Dry Deposition, %) and after abrasion (CR Rub Dry Deposition, %) are measured. The ratio [CR Rub Dry Deposition / CR Dry Deposition]*100, in percentage, indicates the resistance of the film to friction: the higher this ratio, the more resistant the film is to friction. Note: To obtain each Contrast Ratio value, at least two contrast maps are used for each composition, which are evaluated with three CR measurements on each map. Each CR value therefore represents an average of six measurements. The resistance to rubbing of the dry film was tested for two types of colored compositions 1) with organic pigments then 2) with iron oxides (foundation prototypes). The resistance of the film to olive oil was tested for compositions colored with organic pigments (lip prototypes). Homogeneity Assessment Using the aluminum stencil (the orifice is 20 mm long and 10 mm wide, the thickness is 100 um), the film is poured manually using a pipette onto an FP40 support (test piece 60 mm long and 10 mm wide, the FP40 substrate is made of butadiene-nitrile elastomer which contains a plasticizer (diethylhexyl-sebacate); from Supplier BRAMMER, Product reference JOINT DIVERS PLAQUE HPYF000504N4101, strip 60X1000x2 in FP40, Brand BUSAK-LU), then leveled to obtain a film 100 um thick. The test pieces are then left to dry for 24 hours at 35 ° C on a heating plate. Homogeneity is assessed visually and graded between 1 (uneven deposit) and 4 (homogeneous deposit). The assessment of the homogeneity of the deposit is associated with different scores explained below. (In the tables below, “-” means: “not measured”) [Tables 3] ads Score | 1 | Description Completely inhomogeneous deposit (numerous cracks on at least 50% of the surface) #e | Global deposit [homogeneous, homogeneous with |with the exception of |(100% of the surface of the deposit | some local inho- homogeneities are homogeneous) on less than 10% of the surface 7 8-R î : j [Tables 4] Homog eneity [Test Resin of [Allylstea|Ethanol |Isodo- |RED7 |[CR [CR ] Candelill [rate / VA |(%m) |decane |CI Frot Frot é a (A) copolym (%m) |15850 |Sec / CR |Olive (%em) er (D) (%em) |Sec] (%)|Oil / CR (em) Sec] (%) [jar jo je |s |s5 Jo [soox Fe |- 21 |25 [Thurs |s jp fes Jæas jo |o12+ 249+ 1 39 |39 3]ur io Jo Jo Jo Jo |so3x [sx Ja fs Pre 74e ee 1 ft | Jes Jus ju Ë me beep qe Jo Je qu "pire pe | 1 Eee ae 5 Hs F5 je Jess. Compositions outside the invention containing only Candelilla resin have a defect in their resistance to olive oil. Compositions outside the invention containing only Allylstearate / VA Copolymer have a defect in their homogeneity. The compositions of the invention, containing combinations of Candelilla resin and Allylstearate / VA Copolymer, exhibit both excellent resistance to dry rubbing, good resistance in the presence of olive oil and good homogeneity. Examples 9 to 11 - Results in the presence of Glyceryl Rosinate [Tables 5] [Test Glyceryl |Allylstearat |Ethanol |Isodo- |RED |[CR [CR Hom Rosinate |e / VA (Y%m) |decane |7 Frot |Frot _e (C) Copolymer (%m) |CI Sec / CR [Olive ité (%em) (D) (%m) 15850 |Sec] |Oil / CR (Fm)(%) |Sec] (%) [jar jo op Jus Jés |lo |soox |138x |- I [#1 jo 60 Jo |io [7524 |475* | 68 |22 [jar j js és Jes Jo |s60+|- - 60 js jar jo io jgo jo |ji0 |m19+ |s90+ |1 81 |84 [ojEx |s |s Jo Jo Ji Jroz4x[427+ 2 30 |83 [11 ex |10 |s [875 |75 Jio |o78x |- [- js j1o 50.0+ |13.8+ 21 |25 [go [io 75.24 |475+ 68 [22 'Tes jo |s60+ |- 6.0 Jo Jo |m19+ [s90+ 8.1 |sA Jo [10 103.4 + |42.7 + 3.0 |83 Jas [io [o78+ |- 4.1 The compositions of the invention, containing combinations of Glyceryl Rosinate and Allylstearate / VA Copolymer, exhibit both excellent resistance to dry rubbing, good resistance in the presence of olive oil and better homogeneity of the film obtained. Examples 12 to 13 - Results in the presence of Protium Heptaphyllum [Tables 6] | Essay Isodo-d |[RED7 |[CR Frot Homogén| ecane |CI15850 |Sec / CR jeité (%em) |(Yem) |Sec] (%) Protium |Allylstea [Ethanol heptaphyll|rate / VA |(%m) um (B) Copolym (%m) er (D) (7m) BTS [12 |Ex |s 5 40 [go jo 764x 3 [13 [Ex [10 [5 Js75 |75s io = - 37 The compositions of the invention, containing combinations of Protium Heptaphyllum and Allylstearate / VA Copolymer, exhibit excellent resistance to dry rubbing and good homogeneity of the film obtained. Example 14 - Results obtained in the presence of other solvents [Tables 7] |Candelill Essay | Allylstearate |[Ethano |Undecane |Pigm|[CR [CR Homo aResin | / VA 1 (and) ent |Frot Frot génit | (em) |Copolymer |(%m) |Tridecane |(%m |Sec / CR |Olive jé (D) (%m) (%m) ) Sec] JOi / CR (%) |Sec] (%) [isJex ke | I |5 Jos6+ [762+ |4 5.0 4.2
Claims
Claims
1. Cosmetic composition comprising in a physiologically acceptable: - at least one natural resin, and - at least one vinyl ester polymer.
2. Composition according to the preceding claim, further comprising - at least one volatile oil, and / or - at least one volatile alcohol.
3. Composition according to the preceding claim, in which the ratio weight of the total quantity of volatile oil(s) and volatile alcohol(s) on the quantity of natural resin(s) is greater than !; preferably: - the weight ratio of the quantity of volatile oil(s) to the quantity of natural resin(s) is greater than 0.5; preferably greater than 1; and / or - the weight ratio of the quantity of volatile alcohol(s) to the quantity of natural resin(s) is greater than 0.5; preferably greater than 1.
4. Composition according to any one of the preceding claims, ca- characterized in that the volatile oil is chosen from hydro- oils volatile carbonaceous oils, volatile silicone oils and their mixtures, preference chosen from volatile hydrocarbon oils, preferably chosen from C8-C16 isoalkanes, in particular the volatile hydrocarbon oil is chosen from isododecane, linear or branched alkanes, C9-C12, and / or mixtures of n- undecane (C1 1) and n-tridecane (C13); preferably it comprises isododecane; in particular the volatile hydrocarbon oil is isododecane.
5. A composition according to any preceding claim, ca- characterized in that the volatile oil(s) are at least partially of plant origin.
6. A composition according to any preceding claim, ca- characterized in that the weight ratio of the quantity of oil(s) volatile(s) on the quantity of natural resin(s) is included in the range from 0.5 to 50, preferably 1 to 30, preferably from 3 to 20; preferably 5 to 18, preferably 8 to 15.
7. A composition according to any preceding claim, ca- characterized in that the volatile alcohol is chosen from alcohols in C1-C4, preferably chosen from: ethanol, isopropanol, tert- butanol, n-butanol, and mixtures thereof; preferably ethanol.
8. A composition according to any preceding claim, ca- characterized in that the weight ratio of the quantity of alcohol(s) volatile(s) on the quantity of natural resin(s) is included in the range from 0.5 to 50, preferably 1 to 30; preferably from 1.2 to 20; preference from 1.5 to 15.
9. Cosmetic composition according to any one of the preceding claims- preceding, characterized in that the weight ratio of the quantity of volatile oil(s) on the quantity of volatile alcohol(s) is included in the range preferably from 0.01 to 100, preferably from 0.1 to 10; preferably from 0.5 to 5; preferably from 1 to 4.
10. | Composition according to any one of the preceding claims, in which the content by weight of volatile oil(s) is greater than the content by weight of volatile alcohol(s), itself greater than the content by weight of natural resin(s), on the total weight of the composition.
11. | Composition according to any one of the preceding claims, in which said at least one resin is chosen from: a) resins acaroids, b) ambers, c) asphaltite and gilsonite, d) balsam of Peru, e) Tolu balsam, f) Benzoin resins, g) balsam of the Canada, h) copal resins, 1) damars, j) elemis, k) incense, 1) galbanums, m) labdanums, n) mastics o) the Myrrh, p) Sandarac, q) Shellacs, r) Styrax, s) Tere- benzine, t) rosins, including rosin, rosinate and tall oils, (v) resins extracted from vegetable waxes, and mixtures of these resins; preferably the natural resin(s) are chosen from j), k), t), u) and v), and mixtures of these resins; said resins being able to be in particular esterified, salified, adducted, modified by phenols, di- merized and / or hydrogenated.
12. A composition according to any preceding claim, ca- characterized in that it contains at least one resin with an INCI name including at least one of the following terms: EUPHORBIA CERIFERA WAX EXTRACT, CANDELLILA WAX EXTRACT, PROTIUM HEPTAPHYILLUM RESIN, SHOREA ROBUSTA RESIN, or GLYCERYL ROSINATE; and mixtures thereof.
13. A composition according to any preceding claim, ca- characterized in that said resin contains at least 30% of compounds terpenic compounds, preferably at least 40% by weight of terpene compounds penic, preferably at least 50% terpenic compounds, and even more preferably at least 60%, or even better at least 70%, of terpene compounds, by weight relative to the total weight of resin.
14. | Composition according to any one of the preceding claims, ca- characterized in that said resin comprises at least 10%, preferably at least 20% by weight, preferably at least 30% by weight, of preferably at least 35% by weight of polyterpene compounds, on the total weight of the resin representing 100%.
15. A composition according to any preceding claim, ca- characterized in that said resin comprises less than 70% by weight of monoterpene or sesquiterpene compounds, on the total weight of the resin representing 100%, preferably less than 60% by weight, of preferably less than 50% by weight, preferably less than 30% by weight, preferably less than 15% by weight, of monoterpene compounds penic or sesquiterpenic, on the total weight of the resin re- showing 100%.
16. | Composition according to any one of the preceding claims, ca- characterized in that said resin contains at least one di- compound terpenic; preferably derived from abietic acid; especially natural or chemically modified; preferably chosen from resins of rosin, in particular said resins comprise co-acids lophanes, preferably mainly chosen from acids of the type abietic and pimaric type, their derivatives notably from the po- polymerization, hydrogenation and / or esterification of acids rosins, for example with polyhydric alcohols such as ethylene glycol, glycerol, pentaerythritol; and mixtures thereof; preferably said resin contains at least one rosin acid ester selected from the group consisting of glyceryl rosinate, rosinate pentaerythrityl, silicone rosinate, diethylene rosinate glycol, hydrogenated dilinoleyl dimer rosinate, dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate, glyceryl dibehenate / hydrogenated rosinate, diisostearate glyceryl / hydrogenated rosinate, trihydrogenated glyceryl rosinate, glycol rosinate, hydrogenated methyl rosinate, rosinate methyl, hydrogenated pentaerythrityl rosinate, rosinate of hydrogenated triethylene glycol; and mixtures thereof; more preferably chosen from glyceryl rosinate.
17. | Composition according to the preceding claim in which the content total diterpene compounds in the resin is at least 20%, preferably at least 30%, preferably at least 40%, by weight of diterpene compound(s) on the total weight of the natural resin.
18. Composition according to any one of the preceding claims, ca- characterized in that said at least one resin contains at least one triterpene compound; preferably chosen from: alpha-amyrin, beta-amyrin, alpha-amyrone, beta-amyrone, dammadienone, dam- madienol, ursolic aldehyde, hydroxyhopanone, oleanonic aldehyde, ursolic acid, oleanonic acid, oleanolic acid, and mixtures thereof ; and preferably the resin is chosen from incense resins, such as as protium heptaphyllum, shorea robusta. [Claim 19) Composition according to the preceding claim in which the content total triterpene compounds in the resin is at least 10%, preferably at least 20%, preferably at least 30%, and preferably at least 35% by weight of triterpene compound(s) on the total weight of the natural resin.
20. | Composition according to any one of the preceding claims, ca- characterized in that the resin has an average molecular weight of number less than or equal to 10,000 g / mol, in particular ranging from 250 to 10 000 g / mol, preferably less than or equal to 5,000 g / mol, in particular ranging from 250 to 5,000 g / mol, better, less than or equal to 2,000 g / mol in particular ranging from 250 to 2,000 g / mol and even better lower or equal to 1,000 g / mol, in particular ranging from 250 to 1,000 g / mol.
21. | Composition according to any one of the preceding claims, ca- characterized in that said resin(s) have a temperature of glass transition, this preferably being included in the range from 0°C to 200°C, more preferably from 10°C to 100°C, even more preferably from 20°C to 90°C and even more preferably from 30°C to 70°C.
22. A composition according to any preceding claim, ca- characterized in that the resin has a softening point of preferably in the range of 20°C to 150°C, more preferably- preferably from 30°C to 100°C, even more preferably from 40°C to 90°C.
23. A composition according to any preceding claim, ca- characterized in that the resin(s) is(are) present in said composition with a content in the range of 0.1% to 40%, preferably from 0.5% to 35%, preferably from 1% to 30%, of preferably from 2% to 25%, preferably from 3 to 22%, and more preferably- tively from 5% to 20%, by weight relative to the total weight of the com- position representing 100%.
24. A composition according to any preceding claim, in which the vinyl ester polymer is chosen from: - copolymers of (1) at least one vinyl ester monomer, in in which the vinyl group is directly bonded to the oxygen atom of the ester group and the vinyl ester includes a hydrocarbon radical saturated, linear or branched, from 1 to 19 carbon atoms, preferably from 8 to 19 carbon atoms, and more preferably from 16 to 19 carbon atoms, linked to the carbonyl of the ester group, and (ii) at least another monomer chosen from: a vinyl ester different from the ester vinyl already present, an α-olefin preferably having from 8 to 28 carbon atoms, an alkyl vinyl ether whose alkyl group contains preferably from 2 to 18 carbon atoms, or an allyl ester or me- thallylic having preferably a saturated, linear hydrocarbon radical or branched, from 1 to 19 carbon atoms, linked to the carbonyl of the group ester; - and / or among the polyesters of polyvinyl alcohol and fatty acid, in which fatty acids are preferably linear C6-C30 or branched.
25. Composition according to any one of the preceding claims, wherein the vinyl ester polymer is selected from: acetate of vinyl / allyl stearate, vinyl acetate / vinyl laurate, acetate vinyl / vinyl stearate, vinyl acetate / octadecene, acetate vinyl / octadecyl vinyl ether, vinyl propionate / allyl laurate, vinyl propionate / vinyl laurate, vinyl stearate / octadecene-1, vinyl acetate / dodecene-1, vinyl stearate / ethyl vinyl ether, vinyl propionate / cetyl vinyl ether, vinyl stearate / acetate allyl, 2,2-dimethyl vinyl octanoate / 2-dimethyl vinyl laurate, 2 allyl pentanoate / vinyl laurate, vinyl dimethyl propionate / vinyl stearate, allyl dimethyl propionate / vinyl stearate, vinyl propionate / vinyl stearate, crosslinked with divinyl benzene, vinyl dimethyl propionate / vinyl laurate, crosslinked with divinyl benzene, vinyl acetate / octadecyl vinyl ether, crosslinked with tetraallyloxyethane, vinyl acetate / allyl stearate, crosslinked with divinyl benzene, vinyl acetate / octadecene-1 crosslinked with divinyl benzene and allyl propionate / allyl stearate crosslinked with divinyl benzene; copolymers of polyvinyl stearate, poly- vinyl stearate crosslinked with divinylbenzene, diallyl ether or of diallyl phthalate, poly(meth)acrylate (co)polymers of stearyl, polyvinyl laurate, poly(meth)acrylate lauryl, these poly(meth)acrylates being optionally crosslinked using dime- ethylene glycol or tetraethylene glycol acrylate; preferably said at least one vinyl ester (co)polymer is chosen from co- vinyl acetate / allyl stearate polymer, polyvinyl laurate, and their mixtures.
26. A composition according to any preceding claim, in which the vinyl ester polymer is present in the com- position in a content of between 0.05% and 20% by weight, preferably primarily between 0.1% and 15% by weight, more preferably between 0.2 % to 12% by weight, better between 0.5% and 10% by weight and / or the weight ratio between the total quantity of resin(s) and the quantity total of vinyl ester polymer(s) present in the composition, ranges from 0.05 to 200, more preferably from 0.1 to 100, more preferably- typically from 0.2 to 50, or even better from 0.5 to 20, preferably from 0.5 to 10.
27. Cosmetic composition comprising, in a physiological medium- logically acceptable, at least one oily phase of composition according to any one of claims 1 to 25, said phase oily being a continuous oily phase.
28. A composition according to any preceding claim, ca- characterized in that it is in the form of an oily composition, in particular anhydrous, preferably anhydrous dispersion, preferably of anhydrous solution; or of a water-in-oil emulsion, or of a com- position with several separate phases such as a two-phase.
29. A composition according to any preceding claim, ca- characterized in that it also has an aqueous phase according to a total content by weight in the range of 2 to 95% by weight, of preferably from 10 to 90% by weight, preferably from 20 to 80% by weight, more particularly from 30 to 60% by weight, relative to the total weight of said composition.
30. Cosmetic composition according to any one of the preceding claims- preceding, characterized in that the total oily phase content is in the range of 5 to 100%, preferably 10 to 98% in weight, preferably 20 to 90% by weight, preferably 30 to 80% by weight, relative to the total weight of the composition.
31. Composition according to any one of the preceding claims, in which the volatile oil or oils are preferably present according to a content in the range of 1 to 90% by weight, of preferably 2 to 70%, preferably 3 to 50%, preferably 5 to 45% by weight, preferably from 8 to 40% by weight, and even more preferably- entially from 10 to 35% by weight, relative to the total weight of the com- position.
32. A composition according to any preceding claim, further comprising at least one pigment; preferably chosen from organic pigments and / or titanium dioxides and / or oxides of iron; in particular coated with a hy- surface treatment agent drophobe, in particular by an N-acylated amino acid and / or one of its salts, in particular by a glutamic acid derivative and / or one of its salts, including a stearoyl glutamate, such as stearoyl aluminum glutamate; preferably the composition comprising a pigment chosen from organic pigments and / or dioxides of titanium.
33. Composition according to the preceding claim, comprising at least 2% by weight of pigment(s), preferably at least 5% by weight of pigment(s), more preferably from 5 to 40% by weight of pigment(s), in particular from 10 to 30% by weight, and more particularly from 10 to 20 % by weight of pigment(s) relative to the total weight of said com- position.
34. A composition according to any preceding claim, presented in the form of a foundation, a lipstick, a mascara, eyeliner, concealer or corrector, a product for eyebrows, a skin care product, a sunscreen, a hygiene product, a hair styling product, a hair coloring product, or nail polish.
35. | Process for coating keratin materials, more particularly makeup and / or care of keratin materials, such as skin, characterized in that it comprises the application to keratin materials tinics of a composition as defined according to any one of the claims 1] to 33.
36. Use of a composition as defined in any one of of claims 1 to 33, to improve the hold and / or resistance to friction without increasing the sticky effect, of a film obtained by ap- application of said composition to keratin materials.