Ink composition and method for producing the same as well as inkjet ink set and inkjet printing system using ink composition

Abstract

To provide an ink composition having excellent storage stability, dischargeability and curability.SOLUTION: There is provided an ink composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound has one or a plurality of (meth)acrylates in the molecule and has an organic sulfonic acid content of 1 ppm or more and 50 ppm or less as measured by the water extraction method at 25°C, the water extraction method is a chromatographic method to measure the content of an organic sulfonic acid in a measuring liquid prepared by mixing the ink composition and water, and the water content is 0.01 mass% or more and 0.50 mass% or less based on the total mass of the ink composition as measured by the Karl Fischer method.SELECTED DRAWING: None

Description

Technical Field

[0001] The present invention relates to an ink composition used in an inkjet printer, a method for producing the same, an inkjet ink set using the ink composition, and an inkjet printing system.

Background Art

[0002] As inks applied to the inkjet method, aqueous inks mainly composed of water as a solvent and oily inks mainly composed of organic solvents have been used. However, in order to suppress bleeding of images, solventless active energy ray-curable inkjet inks that cure the ink by irradiation with active energy rays (for example, ultraviolet rays) have attracted attention.

[0003] Since this type of active energy ray-curable inkjet ink does not contain a solvent, it is not necessary to penetrate the solvent into the recording medium, and since the ink can be cured in an extremely short time, high printing quality with little bleeding can be obtained regardless of the type of recording medium.

[0004] On the other hand, in active energy ray-curable inkjet inks, deposits are likely to occur in the ink, and there is a problem that the inkjet head becomes clogged when the ink is ejected by an inkjet printer. This is because the polymerizable compound contained in the active energy ray-curable inkjet ink is produced using a catalyst such as organic sulfonic acid, so the catalyst usually remains in the polymerizable compound. When the ink is stored for a long time, the catalyst elutes into the ink and reacts with other components, and the reaction product deposits on the inkjet head to cause clogging.

[0005] In order to solve the above problems, it has been proposed to contain a certain amount of water in an ink containing a photopolymerizable compound containing an acid catalyst and a photoinitiator (Patent Document 1). According to Patent Document 1, it is said that this can prevent deposits from occurring in the ink.

Prior Art Documents

[0006] [Patent Document 1] Japanese Patent Publication No. 2011-213801 [Overview of the project] [Problems that the invention aims to solve]

[0007] However, when printing using ink containing water, there are problems with printability, such as blurring of the image. Therefore, the method proposed in Patent Document 1 ultimately requires the removal of water by some means, which necessitates equipment and other devices, making the printing system complex.

[0008] The present invention was made to solve the above problems and provides an ink composition that does not generate precipitates and has high ejection properties, a method for manufacturing the same, and an inkjet ink set and an inkjet printing system using the ink composition. [Means for solving the problem]

[0009] The present invention relates to an ink composition comprising a polymerizable compound and a photopolymerization initiator, characterized in that the content of organic sulfonic acid measured by water extraction at a temperature of 25°C is 50 ppm or less, and the water content measured by the Karl Fischer method is 0.50% by mass or less relative to the total mass of the ink composition.

[0010] Furthermore, the present invention provides a method for producing an ink composition, comprising the steps of: preparing an ink composition precursor containing a polymerizable compound and a photopolymerization initiator; adding an alkali metal salt to the ink composition precursor and stirring it at a temperature of 40°C to 70°C for 10 minutes to 120 minutes; aging the stirred ink composition precursor at a temperature of -20°C to 35°C; and filtering the aged ink composition precursor to produce an ink composition.

[0011] Furthermore, another method for producing the ink composition of the present invention comprises the steps of: preparing an ink composition precursor containing a polymerizable compound and a photopolymerization initiator; stirring the ink composition precursor at a temperature of 40°C to 70°C for 10 minutes to 120 minutes; aging the stirred ink composition precursor by holding it at a temperature of -20°C to 35°C; and filtering the aged ink composition precursor to produce an ink composition, characterized in that at least one of the polymerizable compound and the photopolymerization initiator contains an alkali metal ion.

[0012] The inkjet ink set of the present invention is characterized by comprising the above-described ink composition of the present invention.

[0013] The inkjet printing system of the present invention is an inkjet printing system using the above-described ink composition of the present invention and an inkjet recording device, wherein the inkjet recording device comprises an ink heating unit and an ink filter. [Effects of the Invention]

[0014] According to the present invention, it is possible to provide an ink composition that does not generate precipitates and has high ejection properties, a method for producing the same, and an inkjet ink set and inkjet printing system using the ink composition. [Modes for carrying out the invention]

[0015] (Embodiment 1) First, the ink composition of the present invention will be described. The ink composition of the present invention comprises a polymerizable compound and a photopolymerization initiator, and is characterized in that the content of organic sulfonic acid measured by water extraction at a temperature of 25°C is 50 ppm or less, and the water content measured by the Karl Fischer method is 0.50% by mass or less relative to the total mass of the ink composition.

[0016] The ink composition of the present invention has an organic sulfonic acid content of 50 ppm or less, as measured by water extraction at a temperature of 25°C, thus preventing the formation of precipitates and providing high discharge performance. Furthermore, the water content of the ink composition of the present invention, as measured by the Karl Fischer method, is 0.50% by mass or less relative to the total mass of the ink composition, thus reducing the reaction field between alkali metal ions in the material and organic sulfonic acid, and suppressing the generation of reaction products in the ink.

[0017] The ink composition of the present invention will be described in detail below.

[0018] <Organic sulfonic acid content> The organic sulfonic acid content in the ink composition of the present invention is a value measured by water extraction at a temperature of 25°C. The above organic sulfonic acid is contained in the polymerizable compound, which is an ink component, and is residual organic sulfonic acid used as a catalyst when synthesizing the polymerizable compound. In the ink composition of the present invention, the organic sulfonic acid content measured by water extraction at a temperature of 25°C is set to 50 ppm or less, more preferably 29 ppm or less, and even more preferably 7 ppm or less. Ideally, the lower limit of the organic sulfonic acid content is 0 ppm, but it is difficult to completely remove organic sulfonic acid, and the limit is about 1 ppm.

[0019] The above water extraction method measures the content of organic sulfonic acid in a measurement solution prepared by mixing the ink composition with water using chromatography. This is because it is difficult to directly measure the content of organic sulfonic acid in the ink composition. As the chromatography method, for example, liquid chromatography or ion chromatography can be used.

[0020] The organic sulfonic acid used as a catalyst in synthesizing the polymerizable compound is usually at least one selected from the group consisting of methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, dodecylbenzenesulfonic acid, toluenesulfonic acid, and naphthalenesulfonic acid.

[0021] <Water content> The water content in the ink composition of the present invention is a value measured by the Karl Fischer method. The above water is inevitably mixed in during the ink manufacturing process and is not intentionally added. In the ink composition of the present invention, the water content measured by the Karl Fischer method is 0.50% by mass or less based on the total mass of the above ink composition, preferably 0.20% by mass or less, and more preferably 0.03% by mass or less. The lower limit value of the above water content is ideally 0% by mass, but it is difficult to achieve 0% by mass under normal manufacturing environments, and about 0.01% by mass is the limit. If there is water exceeding 0.50% by mass based on the total mass of the ink composition of the present invention, the water serves as a reaction field for the reaction between the alkali metal ions in the material and the aforementioned organic sulfonic acid, and the reaction product is generated in the ink, which is not preferable.

[0022] <Polymerizable compound> As the above polymerizable compound, a monofunctional monomer or a polyfunctional monomer having one or more ethylenic double bonds in the molecule, which has the property of being cured by energy rays, can be used.

[0023] The above polymerizable compound preferably contains an amine-modified polymerizable compound. It is considered that the above amine-modified polymerizable compound can suppress polymerization inhibition by oxygen in the air, and can improve the curing rate during ultraviolet irradiation, particularly during low-energy ultraviolet irradiation using a light-emitting diode (LED).

[0024] The amine-modified polymerizable compound described above is preferably a polymerizable compound having at least one amino group (primary, secondary, or tertiary amine skeleton) in its molecule. Examples of such polymerizable compounds include amino(meth)acrylate, amine-modified polyether(meth)acrylate, amine-modified polyester(meth)acrylate, amine-modified epoxy(meth)acrylate, and amine-modified urethane(meth)acrylate. These can be used individually or in combination of two or more. The content of the amine-modified polymerizable compound described above is not particularly limited, but should be 1% by mass or more and 30% by mass or less, and more preferably 1% by mass or more and 11% by mass or less, relative to the total mass of the ink composition.

[0025] The above-mentioned amine-modified polymerizable compound preferably has a glass transition temperature of 25°C or lower, more preferably 10°C or lower, in its cured form, from the viewpoint of adhesion. The above glass transition temperature is measured by integrating a light intensity of 1,000 mJ / cm² with a mixture of the amine-modified polymerizable compound and 1-hydroxycyclohexylphenyl ketone (1,2-α-hydroxyalkylphenone-based initiator) as an initiator (mass ratio of polymerizable compound / initiator: 97 / 3). 2 This can be done by irradiating the polymer with ultraviolet light having a certain energy, forming a polymer, and then measuring this polymer using a differential thermal analyzer (product name "TG-DTA(2000S)" manufactured by Mac Science Co., Ltd.).

[0026] The mass-average molecular weight of the amine-modified polymerizable compound is preferably 100 or more, more preferably 500 or more, from the viewpoint of imparting flexibility to the cured ink. Furthermore, the mass-average molecular weight of the amine-modified polymerizable compound is preferably 2000 or less, more preferably 1500 or less, from the viewpoint of reducing the viscosity of the ink. Here, the mass-average molecular weight is the molecular weight on a polystyrene basis, measured by gel permeation chromatography (GPC) of the oligomer alone (solvent: tetrahydrofuran).

[0027] Examples of the amine-modified polymerizable compounds mentioned above include the trade names "EBECRYL80," "EBECRYL81," and "EBECRYL7100" from Daicel Ornex, the trade names "CN371," "CN550," and "CN551" from Sartomer, and the trade name "LaromerPO94F" from BASF.

[0028] In addition to the amine-modified polymerizable compounds mentioned above, the following polymerizable compounds can be used.

[0029] Specifically, examples of monofunctional monomers having one ethylenic double bond in the above molecule include amyl (meth)acrylate, isoamyl (meth)acrylate, octyl (meth)acrylate, isooctyl (meth)acrylate, decyl (meth)acrylate, isodecyl (meth)acrylate, lauryl (meth)acrylate, isomiristyl (meth)acrylate, stearyl (meth)acrylate, isostearyl (meth)acrylate, 2-ethylhexyl-diglycol (meth)acrylate, 2-(meth)acryloyloxyethylhexahydrophthalic acid, neopentyl glycol (meth)acrylate benzoate, butoxyethyl (meth)acrylate, ethoxy-diethylene glycol (meth)acrylate, methoxy-triethylene glycol (meth)acrylate, and methoxy-polyethylene glycol Examples include (meth)acrylate, methoxydipropylene glycol (meth)acrylate, phenoxyethyl (meth)acrylate, phenoxy-polyethylene glycol (meth)acrylate, nonylphenol ethylene oxide adduct (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, isobonyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, 2-hydroxy-3-phenoxypropyl (meth)acrylate, 2-(meth)acryloyloxyethyl succinic acid, 2-(meth)acryloyloxyethyl phthalic acid, 2-(meth)acryloyloxyethyl-2-hydroxyethyl phthalic acid, and (meth)acrylate monomers to which functional groups such as phosphorus or fluorine have been added. These may be used individually or in combination.

[0030] Specific examples of polyfunctional monomers having two ethylenic double bonds in the above molecule include, for example, neopentyl glycol di(meth)acrylate hydroxypivalate, polytetramethylene glycol di(meth)acrylate, trimethylolpropane(meth)acrylic acid benzoate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, polyethylene glycol (200) di(meth)acrylate, polyethylene glycol (400) di(meth)acrylate, polyethylene glycol (600) di(meth)acrylate, polyethylene glycol (1000) di(meth)acrylate, and dipropylene glycol di(meth)acrylate. Examples include acrylates, tripropylene glycol di(meth)acrylate, polypropylene glycol (400) di(meth)acrylate, polypropylene glycol (700) di(meth)acrylate, neopentyl glycol di(meth)acrylate, 1,3-butanediol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 1,9-nonanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, dimethylol-tricyclodecane di(meth)acrylate, bisphenol A ethylene oxide adduct di(meth)acrylate, bisphenol A propylene oxide adduct di(meth)acrylate, etc. These may be used individually or in combination.

[0031] Specific examples of polyfunctional monomers having three ethylenic double bonds in the above molecule include trimethylolpropane tri(meth)acrylate, pentaerythritol tri(meth)acrylate, tris(2-hydroxyethyl)isocyanurate tri(meth)acrylate, glyceryl tri(meth)acrylate, and their ethylene oxide modified, propylene oxide modified, and caprolactone modified derivatives. These may be used individually or in combination.

[0032] Specific examples of polyfunctional monomers having four ethylenic double bonds in the above molecule include ditrimethylolpropanetetra(meth)acrylate, pentaerythritoltetra(meth)acrylate, and their ethylene oxide modified, propylene oxide modified, and caprolactone modified forms. These may be used individually or in combination.

[0033] Specific examples of polyfunctional monomers having five ethylenic double bonds in the above molecule include, for example, dipentaerythritol hydroxypenta(meth)acrylate, and their ethylene oxide modified, propylene oxide modified, and caprolactone modified derivatives. These may be used individually or in combination.

[0034] Specific examples of polyfunctional monomers having six ethylenic double bonds in the above molecule include, for example, dipentaerythritol hexa(meth)acrylate, and their ethylene oxide modified, propylene oxide modified, and caprolactone modified derivatives. These may be used individually or in combination.

[0035] The above ink composition may further contain an oligomer or prepolymer as a polymerizable compound.

[0036] The content of the polymerizable compound in the above ink composition is not particularly limited, but is preferably 55 to 98% by mass relative to the total mass of the ink composition. If the content of the polymerizable compound is within this range, the curability and adhesion of the ink can be improved.

[0037] <Photopolymerization initiator> As the above-mentioned photopolymerization initiator, it is preferable to use a photopolymerization initiator that includes at least one compound selected from the group consisting of acylphosphine oxide compounds, α-aminoalkylphenone compounds, and thioxanthone compounds, which can initiate polymerization at low energy. In particular, an acylphosphine oxide compound, or a mixture of an α-aminoalkylphenone compound and a thioxanthone compound, is more preferable.

[0038] Examples of the above-mentioned acylphosphine oxide compounds include, specifically, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, 2,6-dimethoxybenzoyldiphenylphosphine oxide, 2,6-dichlorobenzoyldiphenylphosphine oxide, 2,3,5,6-tetramethylbenzoyldiphenylphosphine oxide, 2,6-dimethylbenzoyldiphenylphosphine oxide, 4-methylbenzoyldiphenylphosphine oxide, 4-ethylbenzoyldiphenylphosphine oxide, 4-isopropylbenzoyldiphenylphosphine oxide, 1-methylcyclohexanoylbenzoyldiphenylphosphine oxide, bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide, 2,4,6-trimethylbenzoylphenylphosphine methyl ester, 2,4,6-trimethylbenzoylphenylphosphine isopropyl ester, and bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentylphosphine oxide. These may be used individually or in combination. Examples of acylphosphine oxide compounds available on the market include "DAROCURE TPO" manufactured by Ciba Corporation.

[0039] Examples of the α-aminoalkylphenone compounds mentioned above include, for example, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1-(4-morpholinophenyl)butanone-1,2-methyl-1-[4-(methoxythio)-phenyl]-2-morpholinopropan-2-one, and the like. These may be used individually or in combination. Examples of α-aminoalkylphenone compounds available on the market include "IRGACURE 369" and "IRGACURE 907" manufactured by Ciba Corporation.

[0040] Examples of the thioxanthone compounds mentioned above include, for example, thioxanthone, 2-methylthioxanthone, 2-ethylthioxanthone, 2-isopropylthioxanthone, 4-isopropylthioxanthone, 2-chlorothioxanthone, 2,4-dimethylthioxanthone, 2,4-diethylthioxanthone, 2,4-dichlorothioxanthone, and 1-chloro-4-propoxythioxanthone. These may be used individually or in combination. Examples of thioxanthone compounds available on the market include "MKAYACURE DETX-S" manufactured by Nippon Kayaku Co., Ltd. and "ITX-S" manufactured by Double Bond Chemical Co., Ltd.

[0041] The amount of the photopolymerization initiator in the above ink composition depends on the amount of the polymerizable compound, but is preferably 2 to 15% by mass in total, relative to the total mass of the ink composition. If the amount of the photopolymerization initiator is 2% by mass or more, an ink with excellent curability and adhesion can be obtained even with low-energy irradiation. On the other hand, if the amount of the photopolymerization initiator is 15% by mass or less, the residue of unreacted components can be suppressed.

[0042] <Coloring agent> The ink composition of the present invention may further contain a coloring agent. However, if the ink composition of the present invention is a colorless, transparent clear ink composition, it does not contain a coloring agent.

[0043] The above-mentioned colorants are not particularly limited, but since the ink composition of the present invention is non-aqueous, pigments that disperse uniformly in a non-water-soluble medium and dyes that dissolve easily are preferred.

[0044] The above pigments can be either inorganic or organic. Examples of inorganic pigments include titanium dioxide, zinc oxide, zinc oxide, lithopone, iron oxide, aluminum oxide, silicon dioxide, kaolinite, montmorillonite, talc, barium sulfate, calcium carbonate, silica, alumina, cadmium red, red iron oxide, molybdenum red, chrome vermilion, molybdate orange, lead yellow, chrome yellow, cadmium yellow, yellow iron oxide, titanium yellow, chromium oxide, viridian, cobalt green, titanium cobalt green, cobalt chrome green, ultramarine blue, dark blue, cobalt blue, cerulean blue, manganese violet, cobalt violet, mica, and the like. Examples of organic pigments include azo, azomethine, polyazo, phthalocyanine, quinacridone, anthraquinone, indigo, thioindigo, quinophthalone, benzimidazolon, and isoindoline organic pigments. Carbon black consisting of acidic, neutral, or basic carbon may also be used. Furthermore, hollow particles of cross-linked acrylic resin may also be used as organic pigments.

[0045] The ink composition of the present invention typically uses black pigments, as well as the three primary colors of cyan, magenta, and yellow. However, pigments with other hues, metallic pigments such as gold and silver, and colorless or light-colored extender pigments can also be used depending on the purpose.

[0046] The above-mentioned colorants may be used individually or in combination of two or more. Furthermore, in this invention, two or more organic pigments or solid solutions of organic pigments may be used in combination. Also, different colorants may be used for each droplet and liquid to be applied, or the same colorant may be used for each.

[0047] For the dispersion of the above-mentioned colorants, dispersion devices such as bead mills, ball mills, sand mills, attritors, roll mills, jet mills, homogenizers, paint shakers, kneaders, agitators, Henschel mixers, colloid mills, ultrasonic homogenizers, pearl mills, and wet jet mills can be used, and mixers such as line mixers may also be used. Furthermore, after the dispersion of the above-mentioned colorants, classification treatment may be performed using centrifuges, filters, cross-flow filters, etc., in order to remove coarse particles of the colorants.

[0048] When dispersing the above-mentioned colorants, a dispersant may be added. There are no particular restrictions on the type of dispersant, but it is preferable to use a known polymeric dispersant.

[0049] The amount of the above-mentioned dispersant can be appropriately selected depending on the intended use, but for example, it can be set to 0.01 to 5% by mass relative to the total mass of the ink composition.

[0050] Furthermore, when adding the above-mentioned colorants, it is also possible to use a synergist appropriate for each colorant as a dispersion aid, if necessary.

[0051] The content of the above-mentioned coloring agent is appropriately selected depending on the color and intended use, but from the viewpoint of image density and storage stability, it is preferably 0.3 to 30% by mass, and more preferably 0.5 to 20% by mass, based on the total mass of the ink composition.

[0052] <Other ingredients> The ink composition of the present invention preferably contains a polymerization inhibitor, a gelation inhibitor, and a surface modifier. By adding the polymerization inhibitor and gelation inhibitor, the storage stability of the ink composition can be improved. Furthermore, by adding the surface modifier, the leveling properties of the printed surface can be improved.

[0053] Examples of polymerization inhibitors include hindered amine compounds, nitrosamine compounds, and quinone compounds. Examples of gelation inhibitors include hindered amine compounds. Examples of surface modifiers include polysiloxanes.

[0054] Furthermore, the ink composition of the present invention may contain additives such as defoaming agents, disinfectants, humectants, pH adjusters, preservatives, and rust inhibitors, as needed.

[0055] Next, a method for producing the ink composition of the present invention will be described.

[0056] A first method for producing the ink composition of the present invention is characterized by comprising the steps of: (A) preparing an ink composition precursor containing a polymerizable compound and a photopolymerization initiator; (B1) adding an alkali metal salt to the ink composition precursor and stirring it at a temperature of 40°C to 70°C for 10 minutes to 120 minutes; (C) aging the ink composition precursor after stirring at a temperature of -20°C to 35°C; and (D) filtering the ink composition precursor after aging to produce an ink composition.

[0057] Furthermore, a second method for producing the ink composition of the present invention comprises the steps of: (A) preparing an ink composition precursor containing a polymerizable compound and a photopolymerization initiator; (B2) stirring the ink composition precursor at a temperature of 40°C to 70°C for 10 minutes to 120 minutes; (C) aging the stirred ink composition precursor by holding it at a temperature of -20°C to 35°C; and (D) filtering the aged ink composition precursor to produce an ink composition, wherein at least one of the polymerizable compound and the photopolymerization initiator contains an alkali metal ion.

[0058] Furthermore, the first and second methods for producing the ink composition of the present invention may include a dehydration step (E).

[0059] In step (A) described above, the polymerizable compound and photopolymerization initiator, along with a colorant, polymerization inhibitor, gelation inhibitor, surface modifier, and other additives as needed, can be uniformly mixed using a stirrer to prepare an ink composition precursor. Examples of stirrers that can be used include a three-way motor, magnetic stirrer, dispensing machine, homogenizer, etc.

[0060] In step (B1) above, an alkali metal salt is added to the ink composition precursor to react the organic sulfonic acid contained in the polymerizable compound with the alkali metal ion. As the alkali metal salt, for example, alkali metal salts of organic acids such as sodium acetate, sodium tartrate, sodium citrate, sodium benzoate, and sodium acrylate; and alkali metal salts of inorganic acids such as sodium chloride, sodium carbonate, sodium bicarbonate, and sodium hydroxide can be used, but alkali metal salts that readily react with organic sulfonic acid according to the HSAB rule and readily dissolve in polymerizable compounds, such as sodium acrylate, are preferred.

[0061] The amount of alkali metal salt added is not particularly limited, but it should be between 0.001% by mass and 0.1% by mass relative to the total mass of the ink composition precursor. If the amount of alkali metal salt added is 0.001% by mass or more, the reaction with the organic sulfonic acid in the ink composition precursor will be sufficient, and the formation of precipitates during storage of the ink composition can be suppressed. On the other hand, if the amount of alkali metal salt added is 0.1% by mass or less, the formation of precipitates of the alkali metal salt itself during storage of the ink composition can also be suppressed.

[0062] In step (B1) described above, if an alkali metal salt that is poorly soluble in the ink composition precursor is used, a step of dissolving the alkali metal salt in water before adding it to the ink composition precursor may be used. In that case, it is preferable to include a dehydration step (E) in order to keep the water content at 0.50% by mass or less relative to the total mass of the ink composition.

[0063] In the first method of manufacturing the ink composition of the present invention, it is necessary to add an alkali metal salt to the ink composition precursor in step (B1). On the other hand, if the polymerizable compound, photopolymerization initiator, or other components of the ink composition contain alkali metal ions as impurities, for example, then it is not necessary to add an alkali metal salt to the ink composition precursor in step (B2) of the second method of manufacturing the ink composition of the present invention.

[0064] Whether or not the components of the above ink composition originally contain alkali metal ions can be confirmed by analysis using an ICP emission spectrometer, an ICP mass spectrometer, an atomic absorption spectrometer, etc.

[0065] The alkali metal ions mentioned above only need to be present in 5 to 200 ppm in at least one of the components of the ink composition, such as the polymerizable compound and the photopolymerization initiator. Typically, the alkali metal ions are present as impurities in the components of the polymerizable compound and the photopolymerization initiator, and the polymerizable compound and the photopolymerization initiator do not contain alkali metal ions as their basic components. Examples of alkali metal ions include sodium ions and potassium ions.

[0066] In step (B2) described above, the organic sulfonic acid contained in the polymerizable compound is reacted with alkali metal ions contained in the polymerizable compound, photopolymerization initiator, etc.

[0067] In step (C) above, the reaction product of the organic sulfonic acid and the alkali metal ion is analyzed. The aging temperature is set to -20°C to 35°C, and more preferably -20°C to 10°C, in order to induce a supersaturated precipitation phenomenon at low temperatures. The low-temperature aging period is set depending on the frequency of reaction product formation with respect to the organic sulfonic acid, but is preferably 60 minutes to 30 days. Furthermore, in order to promote the reaction, high-temperature aging at 40°C to 70°C can be incorporated as a pre-step before low-temperature aging. The high-temperature aging period is preferably 120 minutes to 20 days.

[0068] In step (D) above, the ink composition precursor is filtered using a filter or the like to remove precipitates and produce an ink composition with a reduced organic sulfonic acid content.

[0069] Step (E) described above can be carried out separately from steps (A) to (D), or it can be incorporated into steps (A) to (D). For example, when step (E) is incorporated into step (B1) or (B2), it can be carried out as a dehydration step by heating and stirring that utilizes the difference in evaporation rates between the polymerizable compound and water. When step (E) is incorporated into step (D), a water absorption step using a water-absorbing packing material such as molecular sieves, silica gel, activated alumina, or ion exchange resin can be placed before or after the filtration step.

[0070] By performing the above steps (A) to (D), the content of organic sulfonic acid in the ink composition of the present invention can be reduced to 50 ppm or less when measured by the aforementioned water extraction method.

[0071] Furthermore, since steps (A) to (E) above either do not include a step of adding water or include a step of dehydration, when the ink composition of the present invention is measured by the Karl Fischer method described above, the water content can be 0.50% by mass or less relative to the total mass of the ink composition.

[0072] (Embodiment 2) Next, the inkjet ink set of the present invention will be described. The inkjet ink set of the present invention is characterized by containing the ink composition of the present invention described above. Specifically, the inkjet ink set of the present invention comprises a plurality of inks made from the ink composition of the present invention. Examples of the above inks include pigment inks such as black ink containing black pigment, cyan ink containing cyan pigment, magenta ink containing magenta pigment, and yellow ink containing yellow pigment, and clear ink that does not contain pigment, etc.

[0073] (Embodiment 3) Next, the inkjet printing system of the present invention will be described. The inkjet printing system of the present invention is an inkjet printing system using the ink composition of the present invention and an inkjet recording device, wherein the inkjet recording device is characterized by comprising an ink heating unit and an ink filter. Specifically, the ink heating unit is provided to adjust the viscosity of the ink composition to the optimal discharge viscosity at the inkjet head, and the ink filter is used to remove dust and foreign matter from the ink composition and manufacturing processes such as cartridge filling, and to prevent clogging of the ink flow path and nozzle tip in the inkjet head.

[0074] In the inkjet printing system of the present invention, since an inkjet recording device equipped with an ink heating unit and an ink filter is used, if an ink composition with an organic sulfonic acid content exceeding 50 ppm and a water content exceeding 0.50% by mass is used, the formation of reactants is promoted by the ink heating state, and the large amount of precipitates generated clogs the entire surface of the ink filter, dividing the ink flow path, so the ink composition does not reach the nozzle tip. On the other hand, if an ink composition of the present invention with an organic sulfonic acid content of 50 ppm or less and a water content of 0.50% by mass or less is used, even if the ink is heated to lower the ink viscosity, the formation of reactants is suppressed, so the ink flow path in the inkjet head and the nozzle tip do not become clogged with precipitates.

[0075] The inkjet method used in the above-mentioned inkjet recording device is not particularly limited, but it can employ a charge control method that uses electrostatic attraction to eject ink, a drop-on-demand method (pressure pulse method) that uses the vibration pressure of a piezoelectric element, an acoustic inkjet method that uses radiation pressure to convert an electrical signal into an acoustic beam and irradiate the ink, or a thermal inkjet method that heats the ink to form bubbles and uses the resulting pressure.

[0076] In the inkjet printing system of the present invention, for example, an inkjet printer can be used to eject ink from an inkjet ink set containing the ink composition of the present invention, and then fix the ink by irradiating it with an energy beam. Examples of the energy beams that can be used include ultraviolet light in the range of 200 to 400 nm, far ultraviolet light, g-rays, h-rays, i-rays, KrF excimer laser light, ArF excimer laser light, electron beams, X-rays, molecular beams, LED light, etc. [Examples]

[0077] The present invention will be described below based on examples, but the present invention is not limited to these examples.

[0078] Table 1 shows the components used to prepare the ink in the following examples and comparative examples.

[0079] [Table 1]

[0080] Next, the organic sulfonic acid content of each of the above-mentioned polymerizable compounds, amine-modified polymerizable compounds, photopolymerization initiators, surface modifiers, gelation inhibitors, and polymerization inhibitors was measured by water extraction at a temperature of 25°C. Specifically, first, 3 parts by mass of each of the above-mentioned components were added to 25 parts by mass of deionized water, and after ultrasonic treatment for 5 minutes and mixing for 1 minute, the solution was filtered through a hydrophilic filter with a pore size of 0.2 μm to prepare the measurement solution. Next, the organic sulfonic acid content in the measurement solution was quantified using a liquid chromatography-time-of-flight mass spectrometer (LC / MS). The detection limit of the above spectrometer is 0.4 ppm or less. The results are shown in Table 2.

[0081] [Table 2]

[0082] (Examples 1-5) <Preparation of Pigment Ink> First, a primary dispersion of the coloring agent (pigment) was prepared as follows: The coloring agent, dispersant, and polymerizable compound were weighed into a plastic bottle in the proportions shown in Table 3 (unit: parts by mass). 100 parts by mass of zirconia beads with a diameter of 0.3 mm were added to this mixture, and the mixture was dispersed with paint conditioner for 1 hour.

[0083] Next, a pigment ink was prepared using the primary dispersion as follows: The remaining components, excluding the photopolymerization initiator, were added to the primary dispersion in the amounts (parts by mass) shown in Table 3, and the mixture was stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a pigment ink precursor.

[0084] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the pigment ink precursor in the amounts (parts by mass) shown in Table 3, and the mixture was stirred at 50°C for 30 minutes. After that, the pigment ink precursor was held at 25°C for 120 minutes, and then filtered through a glass filter (manufactured by Kiriyama Seisakusho) to prepare the pigment inks of Examples 1 to 5.

[0085] [Table 3]

[0086] (Examples 6-7) <Preparation of clear ink> The components, excluding the photopolymerization initiator, were weighed into a plastic bottle in the amounts shown in Table 4 (unit: parts by mass), and stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a clear ink precursor.

[0087] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the clear ink precursor in the amounts (parts by mass) shown in Table 4, and the mixture was stirred at 50°C for 30 minutes. After that, the clear ink precursor was held at 25°C for 120 minutes, and then filtered through a glass filter (manufactured by Kiriyama Seisakusho) to prepare the clear inks of Examples 6 and 7.

[0088] (Example 8) <Preparation of clear ink> The components, excluding the photopolymerization initiator, were weighed into a plastic bottle in the amounts shown in Table 4 (unit: parts by mass), and stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a clear ink precursor.

[0089] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the clear ink precursor in the amounts (parts by mass) shown in Table 4, and the mixture was stirred at 50°C for 30 minutes. After that, the clear ink precursor was held at 25°C for 120 minutes, and then dehydrated by passing it through a column packed with molecular sieves (Nacalai Tesque, trade name "4A"), followed by filtration through a glass filter (Kiriyama Seisakusho) to prepare the clear ink of Example 8.

[0090] (Example 9) <Preparation of clear ink> The mixture was measured into a plastic bottle in the proportions shown in Table 4 (unit: parts by mass) and stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a clear ink precursor.

[0091] Next, 0.02 parts by mass of sodium acrylate (alkali metal salt) was added to 100 parts by mass of the clear ink precursor, and the mixture was stirred at 60°C for 30 minutes. After that, the clear ink precursor was kept at -10°C for 24 hours, and then filtered through a glass filter (manufactured by Kiriyama Seisakusho) to prepare the clear ink of Example 9.

[0092] (Example 10) <Preparation of clear ink> The components, excluding the photopolymerization initiator, were weighed into a plastic bottle in the amounts shown in Table 4 (unit: parts by mass), and stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a clear ink precursor.

[0093] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the clear ink precursor in the amounts (parts by mass) shown in Table 4, and the mixture was stirred at 60°C for 60 minutes. After that, the clear ink precursor was held at 60°C for 7 days and then at -10°C for 7 days. The clear ink precursor was then passed through a column packed with molecular sieves (Nacalai Tesque, trade name "4A") to perform a dehydration process, and then filtered through a glass filter (Kiriyama Seisakusho) to prepare the clear ink of Example 10.

[0094] [Table 4]

[0095] (Comparative Examples 1-2) <Preparation of Pigment Ink> First, a primary dispersion of the coloring agent (pigment) was prepared as follows: The coloring agent, dispersant, and polymerizable compound were weighed into a plastic bottle in the proportions shown in Table 5 (unit: parts by mass). 100 parts by mass of zirconia beads with a diameter of 0.3 mm were added to this mixture, and the mixture was dispersed with paint conditioner for 1 hour.

[0096] Next, a pigment ink was prepared using the primary dispersion as follows: The remaining components, excluding the photopolymerization initiator, were added to the primary dispersion in the amounts (parts by mass) shown in Table 5, and the mixture was stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a pigment ink precursor.

[0097] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the pigment ink precursor in the amounts shown in Table 5, and the mixture was stirred at 50°C for 30 minutes. After that, the pigment ink precursor was held at 25°C for 120 minutes, and then filtered through a glass filter (manufactured by Kiriyama Seisakusho) to prepare the pigment inks of Comparative Examples 1 and 2.

[0098] (Comparative Examples 3-4) <Preparation of clear ink> The remaining components, excluding the photopolymerization initiator, were weighed into a plastic bottle in the proportions shown in Table 5 (unit: parts by mass), and stirred with a magnetic stirrer for 30 minutes. After stirring, the mixture was filtered by suction using a glass filter (manufactured by Kiriyama Seisakusho) to prepare a clear ink precursor.

[0099] Next, a photopolymerization initiator (a compound containing alkali metal ion impurities) was added to the clear ink precursor in the amounts shown in Table 5, and the mixture was stirred at 50°C for 30 minutes. After that, the clear ink precursor was held at 25°C for 120 minutes, and then filtered through a glass filter (manufactured by Kiriyama Seisakusho) to prepare the clear inks of Comparative Examples 3 and 4.

[0100] [Table 5]

[0101] Next, the organic sulfonic acid content and water content were measured using the pigment inks and clear inks of Examples 1-10 and Comparative Examples 1-4, which were prepared as described above, immediately after preparation. The results are shown in Table 6.

[0102] <Organic sulfonic acid content> Three parts by mass of each of the above inks were added to 25 parts by mass of deionized water, and after ultrasonic treatment for 5 minutes and mixing for 1 minute, the mixture was filtered through a hydrophilic filter with a pore size of 0.2 μm to prepare the measurement solution. Next, the content of organic sulfonic acid in the measurement solution was quantified using a liquid chromatography-time-of-flight mass spectrometer (LC / MS). The detection limit of the above spectrometer is 0.4 ppm or less. Furthermore, the content of organic sulfonic acid was calculated by taking three measurements using the same measurement solution and taking the arithmetic mean of the three measurement results.

[0103] <Water content> The water content of each of the above inks was measured using the Karl Fischer method. Specifically, the measurement was performed using a Karl Fischer moisture meter set manufactured by Kyoto Electronics Manufacturing Co., Ltd. (Karl Fischer moisture meter [volumetric titration method]: MKC-610, moisture vaporizer: ADP-351).

[0104] Next, the pigment inks and clear inks of Examples 1-10 and Comparative Examples 1-4, prepared as described above, were used to evaluate their ink properties as follows. The results are shown in Table 6.

[0105] <Storage stability> Each ink was filled into a glass bottle and subjected to a thermal test cycle using an environmental testing machine, consisting of storage at 60°C for 2 days and storage at -10°C for 2 days. Subsequently, the presence or absence of precipitates in the ink was checked by suction filtration using a SUS mesh (pore size 5 μm), and the state of the residue on the mesh was observed with an optical microscope. The storage stability of the ink was then evaluated according to the following criteria. Rating A: No residue, Rating B: Slight residue, Rating C: Residue present, Rating D: Large amount of residue

[0106] <Inkjet (IJ) ejection properties> For each ink, the inkjet ejection performance after storage stability testing was evaluated using an inkjet recording device equipped with a piezo-type inkjet nozzle. This inkjet recording device includes an ink tank, a supply pipe, a pre-chamber ink tank directly before the print head, and a piezo print head as its ink supply system. The pre-chamber ink tank directly before the print head and the piezo print head are equipped with filters (SUS mesh, pore size 5 μm) to remove ink debris. Furthermore, during ink ejection, the ink was heated by a temperature control system within the inkjet recording device so that the ink viscosity at the print head was optimally 8-13 mPa·s. The inkjet recording device was driven at a drive frequency of 10 kHz to achieve ink ejection with a droplet size of approximately 7 pl and a resolution of 600 × 600 dpi. The inkjet ejection performance of the ink was evaluated according to the following criteria. Rating A: No leakage, Rating B: Slight leakage, Rating C: Leakage present, Rating D: Numerous leakages

[0107] <Curability> Using each ink, a 3μm thick solid ink film was formed on a 188μm thick polyethylene terephthalate film (white PET film manufactured by Teijin DuPont Films, product name "U292W") using a bar coater. This printed film was then irradiated with an ultraviolet LED lamp (manufactured by Nichia Corporation, product name "NLBU21W01-E2", peak illuminance: 38.7mW / cm²). 2 Using ), the total irradiation light dose was 200 mJ / cm². 2 The solid print was cured by irradiating it with ultraviolet light. The curability of the ink was evaluated by touching this cured material with a finger according to the following criteria. Rating A: No ink adheres to the finger at all, Rating B: A small amount of ink adheres to the finger, Rating C: Ink adheres to the finger, Rating D: Ink has not hardened.

[0108] [Table 6]

[0109] Table 6 shows that the inks of Examples 1 to 10 yielded satisfactory results in terms of storage stability, inkjet ejection performance, and curability. On the other hand, Comparative Examples 1 and 3, which had an organic sulfonic acid content exceeding 50 ppm, and Comparative Examples 2 and 4, which had a water content exceeding 0.50% by mass, did not yield satisfactory results in terms of storage stability, inkjet ejection performance, and curability. [Industrial applicability]

[0110] According to the present invention, it is possible to provide an ink composition and an inkjet ink set using the same that are excellent in terms of storage stability, inkjet ejection properties, and curability.

[0111] Furthermore, the present invention relates to a method for manufacturing inks used in printed and molded products utilizing an inkjet method, and can also be applied to inkjet printing systems, such as not only conventional planar printing using an inkjet method, but also to printing that uses an inkjet method to build up ink to create a three-dimensional effect, or to three-dimensional molding methods using an inkjet method (such as inkjet stereolithography).

Claims

1. An ink composition comprising a polymerizable compound having an ethylenic double bond in the molecule, a photopolymerization initiator, and other components, the polymerizable compound includes an amine-modified polymerizable compound, the photopolymerization initiator contains an acylphosphine oxide compound, The other components do not include a colorant, The content of organic sulfonic acid measured by a water extraction method at a temperature of 25°C is 1 ppm or more and 50 ppm or less, The water extraction method involves measuring the content of organic sulfonic acid in a measurement solution prepared by mixing the ink composition with water by a chromatography method; An ink composition, wherein the water content measured by the Karl Fischer method is 0.01% by mass or more and 0.50% by mass or less, based on the total mass of the ink composition.

2. 2. The ink composition according to claim 1, wherein the organic sulfonic acid is at least one selected from the group consisting of methanesulfonic acid, ethanesulfonic acid, trifluoromethanesulfonic acid, benzenesulfonic acid, dodecylbenzenesulfonic acid, toluenesulfonic acid, and naphthalenesulfonic acid.

3. An inkjet ink set comprising the ink composition according to claim 1 or 2.

4. An inkjet printing system using the ink composition according to claim 1 or 2 and an inkjet recording device, The inkjet printing system is characterized in that the inkjet recording apparatus includes an ink heater and an ink filter.