Hydrophilic composition for IPM characterized by modification due to acid or base
A hydrophilic composition modified by an acid or a base addresses the inefficiencies of chemical pesticides by enhancing adhesion to hydrophobic pests, ensuring effective pest control with reduced environmental and health impacts, aligning with IPM principles.
Patent Information
- Application Number
- JP2025117674
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- Filing Date
- 2025-07-13
- Publication Date
- 2025-09-19
AI Technical Summary
Chemical pesticides lead to drug-resistant pests, environmental contamination, and health risks, and existing control methods are inefficient against pests with hydrophobic cuticles, such as scale insects, causing economic losses and environmental harm.
A hydrophilic composition modified by an acid or a base that enhances wettability and adhesion to hydrophobic surfaces, denaturing the cuticle layer to improve pesticide efficacy while minimizing environmental impact.
The composition effectively controls pests with hydrophobic cuticles, reduces drug resistance, and minimizes environmental and health risks, enabling safe and efficient pest management suitable for IPM practices.
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Figure 2025137630000001_ABST
Abstract
Description
[Technical Field]
[0001] The present invention relates to hydrophilic and modified compositions for IPM. [Background technology]
[0002] When carrying out pest control and weed management, the Agricultural Chemicals Control Act must be observed. This law stipulates the standards for pesticides and the regulations for their manufacture, sale, and use. Unless pesticides are registered, they cannot be manufactured, processed or imported. The Ministry of the Environment will carry out the inspection by the Food and Agricultural Materials Inspection Center, an independent administrative institution, and the Minister of the Environment will carry out the inspection by the Ministry of the Environment. There are standards for pesticide residue concentrations (registration withholding standards) to determine whether or not to register. The Minister of Fisheries and the Minister of the Environment have set the application standards for pesticides to clear the registration suspension standards. Product name, applicable diseases, dilution factor, amount of liquid used, timing of use, number of annual uses, method of use, method of spraying, and The Act also stipulates the total number of times each pesticide can be used per year for each substance contained in each type of pesticide. (Currently, baking soda, vinegar, natural enemies collected around the area where they are used, etc.) These are designated as specified pesticides (hereinafter referred to as specified pesticides), and prohibition regulations are not applied to them. The Ministry of the Environment has a provisional manual for pest and weed management for parks, roadside trees, etc. other than agricultural land. In parks, roadside trees, etc., there will be no health damage to residents and children caused by the scattering of pesticides. When spraying pesticides, inform the surrounding residents in advance of the purpose of the pesticide, the date and time of spraying, and the method of use. Regarding pesticides, the following points should be taken into consideration and efforts should be made to fully inform the public. Even when pesticides are used by trunk injection (for example), efforts will be made to publicize the use of pesticides as necessary. It is well known.
[0003] In general, pesticides (hereinafter referred to as pest control compositions) are applied to plants in water ( Groundwater, well water, reservoir water, river water, tap water, etc.) diluted with water as a base material (hereinafter referred to as water as a base material) A pest and weed control composition (described below) is used.
[0004] Generally, plant pest control and weed management compositions contain a weed spreader (hereinafter referred to as the weed spreader) depending on the purpose. (hereinafter referred to as "") will be added as appropriate.
[0005] Generally, pests have natural predators or pathogens (hereinafter referred to as natural enemies) in nature. Natural enemies are species that cause the death of a particular organism.
[0006] In general, chemical control compositions are used for pest and weed control. (Below, referred to as chemical control).
[0007] Pesticides are used to kill (eliminate) pests (animals including insects) that are harmful to humans and crops. In a broad sense, it also includes acaricides, nematicides, etc. (hereinafter referred to as insecticides) (Write it down).
[0008] A fungicide is a pest control composition that kills pathogenic or harmful microorganisms (hereafter (hereinafter referred to as fungicide).
[0009] Herbicides are used to kill (suppress) plants (weeds) and are used for weed control. The composition is referred to as a herbicide hereinafter.
[0010] Pest control is the process of controlling pests and diseases by appropriately selecting the cultivation method, variety, or environmental conditions of the field. This is a method of control that creates conditions that make it difficult for the pest to occur, suppressing its occurrence and reducing damage. This is a technology that effectively utilizes the inherent ability to suppress the occurrence of pests (hereinafter referred to as the cultivator's (hereinafter referred to as prevention).
[0011] Physical control is a method or material that kills pathogens or pests by creating conditions that are unsuitable for their survival. Covering crops to block direct contact with pests or controlling their behavior using color and light This is a method of controlling diseases and pests that generally uses machines or tools, such as rolling. (Below, referred to as physical control).
[0012] Biological control is the use of microorganisms, insects, and sex pheromones that are natural enemies of pathogens and pests to control diseases. It is a method of controlling pests. In addition to indigenous natural enemies, many materials (natural enemies) registered as pesticides are used. There are control methods that use biological control (hereinafter referred to as biological control).
[0013] Pests include Lepidoptera, Coleoptera, Thripida, Diptera, Hemiptera, and Mites. It can be obtained.
[0014] Sap-sucking pests are insects that suck water and nutrients from plants by inserting thin tubes into them. Aphids, mites, grasshoppers, and psyllids (hereinafter referred to as sap-sucking pests) be.
[0015] Sucking insects excrete unnecessary substances that contain a lot of sugar, and this excrement contains the substance that induces sooty mold. Sooty mold causes black stains on the surface of plants (leaves, fruits, etc.) and inhibits photosynthesis. This can cause the plant to weaken or even die.
[0016] Sap-sucking insects have symbiotic bacteria in their bodies, and they cannot provide the nutrients essential for survival by sucking sap alone. It coexists with symbiotic bacteria as a source of food.
[0017] Sap-sucking pests often carry pathogenic bacteria and viruses harmful to plants within their bodies. These sap-sucking pests transmit pathogenic bacteria and pathogenic viral diseases by sucking the sap from the plants they move to.
[0018] The cuticle is a tough membrane secreted from the outer surface of the cells that make up the epidermis. The outer surface of the epidermis is made up of non-hydrophilic waxes (hydrocarbon waxes, polyesters called cutin, etc.). The transparent layer, known as the cuticle, is formed by secretions of substances such as cellulose, polysaccharides, and cuticles. Insects also have a layer called the cuticle on the outside of their cuticle (polymerized hydrocarbon wax, chitin). A transparent layer formed by secretions of substances such as the body, proteins, calcium salts, and polysaccharides called chitin. The cuticle layer is formed on the surface of mammalian hair. also exists.
[0019] Sucking insects form a water-repellent, hydrophobic covering on the outer surface of their cuticle. Body coverings are made of hydrocarbons and wax to absorb excess sugars that have been taken into the bodies of sap-sucking pests. The insect converts the substance into waxy (paraffin, lipid) secretions such as cellulose and resin acids, which then adhere to the surface of the insect. Insects with particularly thick body coats are secreted from the There are scale insects, and these scale insects can be broadly divided into two types: ruby scale insects and In the case of rice grain beetles, Yanon scale and plum scale, etc., once they have passed the larval stage, they will die. The type that settles and adheres to the surface of an object (hereinafter referred to as the adhesive type) and the Fujikonakai type The types that move around throughout their lives, such as gulls and mealybugs (hereinafter referred to as "moving types") The optimum time for controlling scale insects is said to be about 5 days after emergence. The emergence of all the insects in the early spring is synchronized, but thereafter the emergence periods gradually become irregular, with eggs, larvae and adults emerging. There is a mixture of individuals at various stages of development.
[0020] Methods for controlling scale insects include the use of brushes and water pressure to remove them from the plant body. In addition, in the control method of spraying a water-based control composition, Water-based machine oil emulsion and lime sulfur mixture are used, and from spring to autumn, water containing insecticides is used. Spraying control compositions based on cereals, machine oil emulsions, etc. The active ingredient in the composition is polyglycerin fatty acid ester, which suffocates and kills insects by blocking their spiracles. Fumon (Nippon Kayaku Co., Ltd.), Patent Document 1, organic solvent-based scale insect aerosol (Sumitomo Chemical Gardening Co., Ltd.), and the sex attractant which is a mating disruptant for scale insects described in Patent Documents 2 to 4. Substance (pheromone), cutinase-like substance that removes the insect body covering of scale insects, as described in Patent Document 5 There are methods involving enzymes. [Prior art documents] [Patent documents]
[0021] [Patent Document 1] Patent 6602710 [Patent Document 2] Patent 6659440 [Patent Document 3] Patent 6659439 [Patent Document 4] Patent 5857369 [Patent Document 5] Patent Publication No. 2020-063199 Summary of the Invention [Problem to be solved by the invention]
[0022] By using chemical control compositions, which are pesticides approved under the Agricultural Chemicals Control Law, to control pests and diseases, As a result, drug-resistant individuals (pests, weeds) have appeared due to the accumulation of resistance factors through selection. For example, if the same insecticide is used repeatedly on aphids, the number of aphids will decrease. Only individuals in the colony that are resistant to the insecticide will survive, and the insecticide will not kill them. This phenomenon is caused by the removal of natural enemies and competing species through the use of chemical control compositions. The phenomenon of re-increase of target pests is called resurgence (hereafter referred to as resurgence). In addition, chemical control compositions can cause contamination of the environment, humans, animals, etc., and remain on agricultural crops for a long time. This poses a major challenge to the continued existence of agriculture.
[0023] Against this background, there is a demand for agricultural practices that emphasize environmental conservation, and the government is Based on the law, we will carefully consider all available pest control techniques and economic feasibility. -Appropriate measures will be taken comprehensively to suppress the increase in weeds, and through this, Reduce or minimize the risks to human health and the burden on the environment, and By minimizing disturbance to the ecosystem surrounding the industry as much as possible, we aim to prevent pests and diseases that are present in the ecosystem. Utilizing weed suppression functions as much as possible will contribute to the stable production of safe, consumer-reliable agricultural products. IPM is also a comprehensive approach to pest and weed management. It is also called biological control and is used for disinfection and pest control in building management. IPM is a method of combining cultural, physical, biological and chemical pest control methods to minimize economic damage. To reduce pest populations below harmful levels and maintain those low levels It is a system for managing pest populations, and it not only reduces damage caused by pests but also provides added value. The concept is to provide products, reduce drug resistance problems, and protect the agricultural environment for farmers and consumers. In implementing IPM, there are several steps to managing pest populations. It is necessary to manage weeds (trees, etc.) around agricultural land, etc.
[0024] The control composition is used as a water-based control agent, so it has a water-repellent, hydrophobic cuticle layer and The insect's body coating repels water-based pesticides. High contact angle, super water-repellent Plants with hydrophobic properties (lotus, onion, grasses, etc.), insects with waxy coverings For insects (scale insects, aphids, grasshoppers, psyllids, mites, etc.), The control composition based on this compound exhibits hydrophilicity, penetration, adhesion, spreading, extensibility and permeability. Also, scale insects with thick, sticky coverings are prone to damage. After the second instar larvae, they are covered with a waxy, water-repellent membrane that gradually thickens as they grow. It goes on.
[0025] The body surfaces of the pests, pathogens, and weeds that are the target of control are covered with fine hairs, wax, and chitin. The cuticle layer is covered with a chemical solution, which has poor wettability and adhesiveness, and can easily become uneven. In order to improve these and make it easier for the spray to adhere to the target, and to prevent insufficient effectiveness and dripping, A liquid of the main agent (hereinafter referred to as the main agent), which is a pesticide containing an active ingredient used to control pests and weeds. The agent added later to improve the physical properties of the ingredients is called a spreading agent. Adding an adhesive improves the wettability, emulsification, dispersion, penetration, adhesion, and The physicochemical properties such as suspension and defoaming properties are improved, and the pest control effect is enhanced. (1) Plant wettability, adhesion, spreading, and suspension (stability of wettable powder particles in water) (2) A spreading agent (spreader) that strengthens the properties of the chemical solution and allows it to adhere evenly. It is a functional spreading agent (adjuvant) that enhances the penetration and penetration of the drug solution and makes it easier for the drug solution to penetrate into the plant. (3) Strengthening the adhesiveness and fixation of the chemicals, and fixing the chemical solution to the plant body to improve rain resistance The active ingredient and properties of the spreading agent are to reduce the surface tension. (4) Nonionic surfactants have strong emulsifying power and are effective in wetting water. (5) Anionic surfactants are mixed with powders to improve adhesion to plants and pests that are difficult to remove. (6) Cationic surfactants have the ability to adsorb to fibers. It has excellent properties, and improves the penetration of chemicals to improve the effectiveness of pest control and weed control.(4)~(6 In addition to this, (7) silicone surfactants have the same effect as the nonionic surfactants mentioned above, In particular, it can improve the wettability of the agent, allowing it to spread evenly on the surface of the plant. (8) Paraffin Wax-based sprays create a film on the outside of the pesticide to prevent it from washing away due to rain, etc. In addition to the same effect as the main paraffin-based agent, polyoxyethylene resin acid ester has the effect of These are divided into (4) to (8) with the characteristics of increasing the effectiveness of preventing the drug from flowing out. can be. Since wetting agents are pesticides, they must be used within the concentration range specified by pesticide use standards. If the adhesive concentration is too high, the spreader will spread it thinly, which will actually reduce the amount of adhesive that adheres to the base. If the main agent is an emulsion, Since the emulsion itself has the property of dissolving wax, when two or more emulsions are mixed together, In the case of a curative agent, the functional spreading agent of a cationic surfactant is more effective than the main agent. It increases the yield but is also prone to damage from the pesticides.
[0026] Immediately after spraying, machine oil emulsion physically suffocates the insects with a film of oil. Since oil emulsions also inhibit the respiration of plants, the effects may vary depending on the time of application, the crop to which they are applied, the concentration, and the temperature. It causes damage to the plant that inhibits growth, such as leaf fall, fruit fall, flower fall, leaf scorch, and withering of new shoots (hereinafter referred to as "phytotoxicity"). Therefore, even if a pesticide is registered, it can cause damage to any plant at any time. It cannot be used on weakened plants, new shoots, flowering, fruiting before harvest, during high temperatures, and Do not use on plants that are weak or weak (thin leaves, susceptible to chemical damage, etc.). In addition, immediately after the lime sulfur mixture was applied, the lime and sulfur caused oxygen deficiency. It physically suffocates pests. This lime sulfur mixture causes phytotoxicity to leaves, flower buds, and fruits, so it is It can only be used in winter before the buds sprout. Machine oil emulsion contains mineral oil and is toxic to fish and other water sources. Because it affects the flora and fauna, environmental considerations are required, and the spraying period is determined based on the time of citrus fruit. The spraying period and concentration are limited because it has effects such as delaying coloring and reducing the number of flower buds the following year. Lime sulfur mixtures contain calcium pentasulfide as their main ingredient, and have a foul odor and can be harmful to the skin. If it comes into contact with the skin, it will cause irritation to the eyes and other mucous membranes. Be considerate of the surrounding environment, people, plants, animals (pets, free-roaming animals, etc.), cars, laundry, etc. It is generally not used indoors or outdoors. It is used in public facilities, parks, roadside trees, etc. When using the above pesticides, they must be used more carefully than on farmland.
[0027] When scale insect aerosol was sprayed in one place repeatedly, cold damage occurred to leaves and flowers. For example, scale insect aerosol (Sumitomo Chemical) is used to control scale insects on citrus fruits. We compared two formulations, Engei Co., Ltd. and Mospilan Water-soluble (Nihon Nohyaku Co., Ltd., Nippon Soda Co., Ltd.). In this case, when spraying Mospilan water-soluble solution with a powered sprayer (hereinafter referred to as powered spraying), ) requires about 200 to 700 liters per 10 ares, and scale insect aerosol (1 can) At a volume of 480 mL per 10A, approximately 42 to 146 bottles are required. Since it is a spray type, it can be easily applied using a power sprayer, just like Mospilan water-soluble. Furthermore, it was not possible to spray large quantities of the compound over a wide area mechanically.
[0028] As a method of farming to control scale insects, methods such as using a brush or water pressure to remove them from the leaves the back of the fruit, gaps between the fruit and the trunk, tape wrapped around the plant, strings, the inside of fruit bags, etc. Because they were in a small location, it took time and effort to completely remove them. Not all of the dropped individuals die; those with eggs hatch and new eggs appear. Furthermore, there were some difficulties in removing the substance, such as it getting into the eyes.
[0029] The sooty mold fungus, which is induced by sap-sucking insects, causes black stains. To prevent this, fungicides are sprayed, but the black stains remain attached to the plant body and become the source of the disease. If the sap-sucking insects that are present in the soil are not eradicated, the sooty mold will recur. However, there has been no effective composition for removing scale insects that have adhered to plants. Black stains caused by sooty mold on fruit and leaves, and attached scale insects, do not fall off naturally. Therefore, it is not easy to remove them without damaging the fruit or leaves, so they must be removed by scratching with a brush or fingernails. This can damage the surface of the fruit, causing mold, discoloration (browning of the surface of the fruit), and reducing the freshness retention rate. Fruits and plants that have been infected with sooty mold or scale insects are discarded or processed or sold as non-standard products. This resulted in products that could not be sold or were sold at a low price, which was a factor in lowering profitability.
[0030] It is predicted that killing the symbiotic bacteria of sap-sucking pests will allow the pests to be killed, There have been no reports of a control composition that can be applied to pests that have symbiotic fungi (for example, sap-sucking pests).
[0031] In the method using a cutinase-like enzyme of Patent Document 5, the tangerine leopard The killing activity of gall insects is only 80%, and the killing activity of scale insects such as the sessile type ruby beetle is There have been no reported cases of its use on mosquitoes. [Means for solving the problem]
[0032] As a result of extensive research aimed at solving the above problems, it has been found that the composition and method of the present invention can be suitably used in IPM. For example, as a plant (agricultural and horticultural) composition, it can be used as an insecticide, acaricide, nematode repellent, Pesticides, fungicides, plant growth regulators, weed control agents (herbicides and weed suppressants), cleaning agents, deodorizers, spreaders and freshness preservatives, as well as parasitic fungi that infect humans, pet animals such as dogs and cats, and livestock such as cows and sheep. It has excellent effects as at least one agent selected from pest control agents, cleaning agents, and deodorizers. By using the composition of the present invention, risks to human health and environmental burdens can be reduced, and safety can be improved. This will contribute to the stable production of agricultural products that are trusted by consumers.
[0033] Without being bound by any particular theory, it is believed that the composition of the present invention is excellent as an IPM composition. The effect can be explained by A to C, for example. A. Hydrophilicity, which has a property selected from wettability, penetration, adhesion, spreading, extensibility and permeability. At least one property is exhibited. B. Deterioration (emulsification, saponification, solidification, powdering, evaporation, dissolution, melting and disintegration) due to denaturation of acid or base (at least one property selected from the group consisting of breaking). C. By modification with an acid or base, insecticides, acaricides, nematode repellents, fungicides, plant growth regulators agents, weed control agents (herbicides and herbicide inhibitors), cleaning agents, deodorizers, spreading agents and freshness preservatives. It has the effect of at least one drug. The acid or base of the present invention refers to an acid (acidic) or base (alkaline) in an aqueous solution. A base is called a basic (alkaline) aqueous solution. The Arrhenius definition is that an acid is a substance that dissolves in water. A substance that dissociates in water to produce hydrogen ions H+, and a base is a substance that dissociates in water to produce hydroxide ions OH-. However, acidity and basicity cannot be defined for solutions other than water, and substances containing OH- This does not necessarily explain why an aqueous solution of ammonia or the like that is not dissolved in water becomes basic. Since the composition is not limited to a solution and can contain ammonia, etc., the acid is a proton. A substance that can transfer protons H+ to other substances (hereafter referred to as an acid), and a base is a substance that can transfer protons H + from other substances (hereafter referred to as bases) The composition of the present invention is a more general concept, The Lewis definition of acidity allows us to define acids and bases even for reactions that do not involve the exchange of H+. It is also possible to use the definition that an electron acceptor is an electron pair acceptor and a base is an electron pair donor.
[0034] That is, the present invention relates to the following [1] to [9]. [1] A composition for IPM, which is hydrophilic and characterized by being denatured by an acid or a base. [2] The IPM according to [1] above, characterized by basicity due to being an electron pair donor. Composition for use. [3] The basicity is a carbonate, bicarbonate, hydrogen carbonate, phosphate, chloride, sulfate, and The above [1] or [2] contains at least one or more selected from the group consisting of ammonia and urea. The composition for IPM described in [Illegible]. [4] The composition further comprising at least one agent selected from an insecticide, an acaricide, and a nematicide. The composition for IPM according to any one of [1] to [3]. [5] The composition for IPM according to any one of [1] to [4] above, further comprising a fungicide. . [6] Furthermore, (a), (b), (c), (d), (e), (f), (g), (h), ( i), (j), (k) and (l), containing at least one or more selected from the group consisting of: The composition for IPM according to any one of [1] to [5]. (a): Porous material; (b): Viscosity modifier; (c):Enzyme; (d): Microbial materials (e): insect pheromones; (f): Plant growth regulators; (g): herbicidal activator; (h): synergist; (i): Safeners; (j): repellents; (k): Molluscicidal component; (l):oil; [7] The IP according to any one of [1] to [6], wherein the carbonate is a sesquicarbonate. Composition for M. [8] An application method suitable for IPM using the composition according to any one of [1] to [7]. Law. [9] A product using the IPM composition according to any one of [1] to [8]. [Effects of the Invention]
[0035] According to the present invention, the composition, method and method of the present invention, which are hydrophilic and characterized by modification with an acid or a base, By using this method, you can obtain the effects (products) that are suitable for IPM. It is important to combine physical, biological and chemical control methods to prevent economic damage. Pest population reduction to below a certain level and to sustain that low level. - A system for managing weeds and other pests can be realized. Providing value-added products, reducing drug resistance issues, and preserving the agricultural environment are some of the goals that farmers and consumers should strive for. can be brought to.
[0036] The composition of the present invention is useful as an insecticide, acaricide, nematode repellent, fungicide, plant repellent, etc. for plants (for agricultural and horticultural use). Plant growth regulators, weed control agents (herbicides and herbicide inhibitors), cleaning agents, deodorizers, spreading agents and freshness preserving agents, In addition, it is used as a pest control agent for pests that parasitize humans, pets such as dogs and cats, and livestock such as cows and sheep. It has the effect of at least one agent selected from a cleaning agent and a deodorant. It can be suitably used as a composition for M.
[0037] The composition of the present invention is particularly effective against thick, adherent pests that are difficult to control with conventional insecticides. It has a dramatic effect as an insecticide for controlling adult scale insects that have insect body coverings. This composition has good wettability against pests and weeds that have poor wettability, which could not be achieved with other control agents. , penetration, adhesion, spreading, extensibility and permeability As a result, excellent pest and weed control can be achieved. Effective against not only scale larvae and eggs but also sessile scale adult insects with thick coverings. It is effective, can be used all year round, and is safer than conventional agents in terms of its effects on the environment, people, and animals. Therefore, it can be used anywhere (farmland, public facilities, parks, roadside trees, indoors, etc.) and can be used in areas with harvests. Since it can be used in this state, it is possible to obtain products that are highly safe as food. . [Brief explanation of the drawings]
[0038] [Figure 1] 1 shows a conceptual diagram of the effect of the composition of the present invention. [Figure 2] The photographs show observations of mandarin orange leaves immediately after spraying the composition of the present invention (the same leaf, the left is the top of the leaf, the right is the bottom of the leaf) (Example 1). [Figure 3] 1 shows a photograph of ruby wax scale insects observed after spraying the composition of the present invention (Example 3). [Figure 4] Photographs of holly leaf aphids before (left) and after (right) application of the composition of the present invention are shown (Example 13). DETAILED DESCRIPTION OF THE INVENTION
[0039] The composition and method of the present invention can be suitably used in IPM, and can be used in agriculture, forestry, horticulture, and indoor It can be used to prevent or eliminate harmful organisms in livestock and hygiene situations. For example, for plants (For agricultural and horticultural use) Insecticides, mites, nematodes, fungicides, plant growth regulators, weed control agents (Weed killer / weed suppressant), cleaning agent, deodorizer, spreading agent and freshness preserving agent, and also for humans, dogs and cats Selected from pesticides for pets or livestock such as cows and sheep, cleaning agents and deodorizers. It is possible to obtain a product that has the effect of at least one agent and is suitable for IPM. Specific use situations, target pests, use methods, etc. are shown, but the contents of the present invention are not limited to these. It is not something that can be done.
[0040] [1] A composition for IPM (hereinafter referred to as this composition) characterized by being hydrophilic and denatured by an acid or a base. (hereinafter referred to as composition Q). The hydrophilic and acidic composition Q used in the present invention may be, for example, a polyvalent cation compound. As substances, calcium, magnesium, and barium salts with a water solubility of 1% or less at 20°C and alkaline earth metal salts of copper, iron, manganese, zinc, and aluminum. Carriers containing cationic compounds with a water solubility of 1% or less at °C include barium carbonate, sulfur Barium sulfate, calcium carbonate, calcium sulfite, calcium hydroxide, anhydrous calcium sulfate Calcium sulfate dihydrate, magnesium carbonate, magnesium hydroxide, magnesium sulfate , zinc carbonate, magnesium oxide, zinc oxide, iron oxide, aluminum oxide, stearic acid Calcium, Zinc Stearate, Calcium Bentonite, Magnesium Bentonite, Calcium montmorillonite, magnesium montmorillonite, talc, zeolite, di Examples include quartzite, kaolin minerals, sericite, and activated clay. Lilonite is a type of hydrated aluminum silicate that adsorbs calcium ions. Talc is mainly composed of magnesium silicate, and kaolin is a mineral that is Minerals including rhynite, halloysite, metahalloysite, dickite, nacrilite, etc. These polyvalent cation compounds are formulated as a mixture of one or more types, The amount of the compound to be added is usually about 0.01 to 95% by weight, preferably about 1 to 60% by weight, of the composition of the present invention. When the amount of these polyvalent cation compounds is within the above range, It can be used effectively for the control of pests and weeds, targeting the deficiency of nutrients in plants. By appropriately selecting the above composition, it is not only suitable for IPM but also as a fertilizer. It is expected to have a beneficial effect on the environment and promote good growth. It can also produce plants with high nutritional value, and has excellent effects as a composition suitable for IPM. It is possible.
[0041] The hydrophilic and acidic composition Q used in the present invention may contain, for example, the following acidic compounds: Citric acid, malic acid, fumaric acid, succinic acid, tartaric acid, formic acid, etc., whose pH in a 1% aqueous solution is 7 or less. Acetic acid, propanoic acid, butyric acid, valeric acid, oxalic acid, malonic acid, glutaric acid, adipic acid, Cholic acid, aspartic acid, pimelic acid, maleic acid, phthalic acid, isophthalic acid, terephthalic acid Taric acid, glutamic acid, lactic acid, hydroxyacrylic acid, α-hydroxybutyric acid, glyceric acid , tartronic acid, salicylic acid, gallic acid, mandelic acid, tropic acid, ascorbic acid, glutamic acid Conic acid, cinnamic acid, benzoic acid, phenylacetic acid, nicotinic acid, kainic acid, sorbic acid, Lolidonecarboxylic acid, trimellitic acid, benzenesulfonic acid, toluenesulfonic acid, phosphoric acid Potassium dihydrogen, sodium bisulfite, sodium dihydrogen phosphate, potassium bisulfite , Sodium pyrosulfite, Sodium acid hexametaphosphate, Sodium acid pyrophosphate ammonium, potassium acid pyrophosphate, sulfamic acid, O-phosphate, pyrophosphate, phosphoric acid, etc. These divalent or higher cation compounds are preferably citric acid. One or more kinds may be blended together, and the blending amount thereof is usually 0.001 to 0.001 in the composition of the present invention. It is desirable to use about 50% by weight, preferably about 0.1 to 20% by weight. For example, The pH of the solution is preferably 0 to 7, more preferably 1.5 to 4.0. The acidity of the soil in which plants live ranges from about pH 4 to alkaline pH 9. Therefore, in the natural environment, plants and insects are unlikely to encounter a pH below 4.0. When used at pH 1.5 to 4.0 for plants, insects, and animals, The composition of the present invention can be used in various ways depending on the intended agent. The concentration of use may be varied, for example, insecticides, acaricides, nematode repellents, disinfectants, cleaning agents In the case of deodorants and freshness-preserving agents, the amount may be about 0.01 to 20% by weight in the composition of the present invention. As a spreading agent and / or plant growth regulator, it is effective even at very low concentrations. The amount of the compound may be about 0.0001 to 20% by weight in the composition of the present invention. The higher the concentration of the agent, the more stable the effect. When the amount of these acidic compounds is within the above range, the composition is suitable for IPM. As a composition, excellent effects can be obtained.
[0042] The present composition Q of the hydrophilic and basic compound used in the present invention includes, for example, carbonate Salts, sesquicarbonates, bicarbonates, hydrogen carbonates, phosphates, chlorides, sulfates and ammonia, Examples include urea, other basic compounds, organic bases (organic bases used as bases), etc. These bases may be used singly or in combination of two or more. The amount of the compound to be added is usually 0.001 to 50% by weight, preferably 0.001 to 50% by weight, based on the composition of the present invention. It is desirable to use about 1 to 20% by weight. For example, the pH of a 1% aqueous solution is between 7 and 11. It is more preferable to set the pH to 9.0 or higher and 11.0 or lower. The natural environment is characterized by a pH range from about 4, which is acidic, to about 9, which is alkaline. Under these conditions, plants and insects are unlikely to encounter a pH above 9.0. When used in animals at pH levels between 9.0 and 11.0, it produces effects that cannot be obtained under natural conditions. It can be demonstrated. Depending on how the composition of the present invention is used, it can be used as, for example, an insecticide, acaricide, nematodeicide, For disinfectants, detergents, deodorizers and freshness-preserving agents, the amount is about 0.01 to 20% by weight of the composition of the present invention. It can be used as a spreading agent and plant growth regulator and is effective even at very small concentrations. Therefore, it may be contained in an amount of about 0.0001 to 20% by weight in the composition of the present invention, and it is also effective as a weed control agent (except As a weed suppressant, the higher the concentration, the more stable the effect. The amount of the base may be about 5 to 100% by weight. As an IPM composition that is gentle on the environment and people while exerting its effect on the target, Excellent effects can be obtained.
[0043] Due to the above-mentioned constitution, the composition Q can obtain, for example, the following effects (A) to (E): Figure 1). [Explanation of symbols]
[0044] 1. This composition 2. Scale insects 3 Black stains (sooty mold, etc.) 4. Cuticle layer (plants, etc.) 5 Insect body covering (insect)
[0045] (A) At least one selected from wettability, penetration, adhesion, spreadability, extensibility, and permeability exhibits excellent properties. Due to its hydrophilicity (wettability), this material adheres to waxy (paraffin) insect body coatings and plant body surfaces. When the composition Q1 reaches the surface, it forms a water-repellent or hydrophobic cuticle layer (the epidermis of plants, insects, etc.), insect body coat, etc. It is hydrophilic (easily wetted) and is not repelled by the covering material, so it wets, adheres, spreads and penetrates. (at least one property selected from penetration, spreading, extensibility, and permeability) It is possible. (B) Deterioration (at least one selected from emulsification, saponification, solidification, powdering, vaporization, dissolution, and melting) The denaturation with acid or base causes the formation of multiple molecules of organic compounds, which are biopolymers. A compound formed by polymerizing (combining to form a network or network) monomers. The secondary structure of substances such as waxes (hydrocarbon compounds), polysaccharides, nucleic acids and proteins is destroyed. By destroying the tertiary structure of the food, changes (emulsification, saponification, solidification, powdering, evaporation, disintegration, dissolution, melting, etc.) ) can be made. For example, 1) the cuticle (the covering of the insect's body) and waxy substances change in quality. 2) The cells of the pathogenic fungus causing sooty mold are altered. 3) Cells of symbiotic bacteria of sap-sucking pests (such as scale insects) are altered. (C) Kill pests and diseases (symbiotic fungi, etc.). It blocks the spiracles of pests (scale insects, etc.) or produces carbon dioxide, causing them to die due to lack of oxygen. In addition, the cells of symbiotic fungi (such as sap-sucking pests), pathogens, bacteria, etc. Physicochemical effects such as disrupting ion balance and metabolic functions through the denaturing effect of acids or bases The bacteria can be killed by at least one of the following properties: (D) Can be neutralized, cleaned, deodorized, etc. 1) By denaturation, acids denature (neutralize, convert) alkaline substances (calcium, iron, zinc, etc.) The base reacts with acidic substances, waxes (higher fatty acids and higher alkyl ions), etc. Monovalent esters consisting of alcohols), hydrocarbon compounds, resin acids (carboxylic acids and their esters), It denatures (neutralizes, decomposes, etc.) polysaccharides, nucleic acids, proteins, etc. 2) When an acid neutralizes calcium, etc., and a base neutralizes wax, etc., they become a kind of soap-like substance. The cleaning effect allows scale insects and black stains caused by sooty mold to fall off naturally. 3) Acids and bases react with aldehydes, etc., and acids produce ammonia, amines, etc., while bases produce acetic acid. It neutralizes esters, hydrogen sulfide, isovaleric acid, etc., providing a deodorizing effect. (E) It has the function of regulating plant growth. Denaturation alters the plant's biological balance (plant growth regulation, plant hormones, etc.) By doing so, it is possible to affect metabolism and give plants growth regulation functions. Thickening and hardening of leaves, increasing sugar and acid content, increasing polyphenol content, and resistance to pests and diseases secrete an anti-inflammatory agent, or . Due to the effects of (A) to (E) above, the composition Q is suitable for the following IPM compositions (F) and (G). It is explained that it is a composition. (F) This composition Q prevents the re-increase of target pests due to the elimination of natural enemies and competing species caused by the use of pesticides. It prevents resurgence, which is a major problem, and maintains natural enemies of pests. It is safe for dyes, crops, people and animals. (G) By using this composition Q, it is possible to make a product that is compatible with IPM. An example in which the substance Q can be used is given in Example 1 below. [Example 1] By using this composition Q, farmers can prevent diseases and pests that are inherent to crops and the environment. By effectively utilizing the suppressive effect, conditions are created that are less susceptible to the occurrence of pests, suppressing their occurrence and reducing damage. For example, by using the composition Q, it is possible to physically prevent the growth of pathogens and pests. Various materials that are used to kill or impregnate (spray, attach, etc.) the organisms in question under conditions that are inappropriate for their existence. (Fruit bags, nets, etc.) can be used to cover crops and block pests, and the pest control effect can be utilized. In addition, by using machines and tools, diseases and pests can be controlled. , and can also control weeds. Biologically, by using this composition Q, it is possible to control pests while releasing sex pheromones and indigenous In addition to natural enemies, many materials (natural enemies) that are registered as pesticides can be utilized. Chemically, by using this composition Q, it is possible to control pests and weeds (trees, etc.). Furthermore, in plants, it acts as a growth regulator (plant hormone) and regulates the balance of plant hormones. The plant's resistance (diseases, pests, dryness, humidity, heat, cold, sunlight) is improved by denaturing it with acid or base. For example, it makes the leaves thicker, harder, increases sugar and acid, It causes changes such as increasing the amount of phenol and secreting substances that combat pests and diseases. In addition, by using this composition Q, advantageous growth regulation (increasing fruit sugar content) can be achieved in agricultural and horticultural crops. Increases fruit coloring, accelerates fruit coloring, evens out fruit coloring, provides moisture stress, improves fruit coloring suppresses fruit respiration, aids in physiological fruit drop, prevents peeling, and firm the peel At least one of these excellent properties is selected. From the results of this study, it is believed that the use of this composition Q will contribute to the realization of the concept of IPM, which is to reduce the level of pesticides that cause economic damage. pest population management to reduce pest populations below 100m and sustain those low levels; The effects of Composition Q and the agents that can be used are as follows: and provide examples.
[0046] The effects of this composition Q make it suitable for use as an insecticide, acaricide, nematode repellent, fungicide, and plant growth regulator. agents, weed control agents (herbicides and herbicide inhibitors), cleaning agents, deodorizers, spreading agents and freshness preserving agents, and also for humans, Pesticides, cleaning agents, and disinfectants for pests that infest pets such as dogs and cats, and livestock such as cows and sheep. It has an excellent effect of at least one agent selected from deodorants.
[0047] This composition Q is a plant control composition (agricultural and horticultural drug) that is gentle on the environment, humans, and animals. It can be used as an insecticide, acaricide, nematodeicide or fungicide. At least one insecticide with excellent efficacy selected from pests that parasitize pets or livestock such as cows and sheep. It has fruit.
[0048] This composition Q can be used as a safe cleaning agent and deodorizer, and can also be used on food, fruits and vegetables. Sooty mold that occurs on plants due to sap-sucking insects, which cannot be washed away with water alone, can be used. It can clean (peel off, decompose) dirt and scale insects, and deodorize. It has the effect of cleaning and deodorizing pests and stains on pets such as dogs and cats, and livestock such as cows and sheep. Has.
[0049] The composition Q can be used as a plant growth regulator (plant hormone), for example, , and has the effect of promoting and inhibiting vegetative growth, flowering, flowering, fruiting, coloring, and enlargement, etc., and specifically, Accelerates ripening, promotes fruit thinning, flower thinning, and leaf fall, increases fruit sugar content, and increases useful components such as polyphenols. Promotes fruit coloring, promotes flowering, prevents fruit peeling, promotes fruit abscission layer formation (for harvesting by picking) , suppression of internode elongation, reduction of lodging due to growth promotion effect, promotion of germination, promotion of rooting, root (rhizome) It has excellent effects on thickening, growth inhibition (germination, rooting, leaf development) and root (rhizome) thickening promotion. It can be used to impart various stress tolerance, such as pests, dryness, humidity, heat, cold, lack of sunlight, etc. It is also effective in preventing nutrient (fertilizer, etc.) deficiencies. It also regulates the opening and closing of plant stomata and ion balance. These hormones can act on plant growth regulators and cells. Plant growth regulators such as auxin, gibberellin, cytokinin, and jasmonic acid are known to regulate plant growth. It also has the effect of synergistically enhancing or suppressing the growth-promoting effect. It can also be used to improve the taste of fruits, and to control the sugar content, functional components, and useful components (polyphenols). phenol, etc.) can be increased.
[0050] The composition Q can be used as a herbicide (weed suppressor), for example, to suppress necrosis (necrosis). It is a term that means to induce the death of parts of the living body (organs, tissues, cells) and to kill and suppress weeds. It has the effect of inhibiting grass growth (germination and root growth).
[0051] This composition Q can be used as a spreading agent and has hydrophobic, water-repellent, and other properties that make it difficult to get wet. Plants, insects, and mammals with cuticles, or materials (paper, cloth, nonwoven fabric, glass, etc.) For example, it can be used for waxy, rough, filamentous materials and plant bodies with structures (ne Weeds (soybean, grasses, etc.) and pests, In addition, by applying it to agricultural and horticultural materials, packaging materials, preservation materials, etc., it improves wettability, penetration, and adhesion. It has excellent effect on at least one property selected from the group consisting of adhesiveness, spreadability, extensibility and permeability. do.
[0052] The composition Q can be used as a freshness-preserving agent (post-harvest agent), for example, Improves fruit shelf life, maintains freshness, prevents wilting, aging, discoloration, stem withering, and decay, improves coloring, and sugar content Rise, taste, functional components (β-cryptoxanthin, carotenoids, polyphenols, etc.) It has the effect of improving and increasing plant metabolism by suppressing plant respiration. In addition, it has been shown to inhibit the action of ethylene, a plant hormone that promotes fruit ripening and aging. Has.
[0053] In addition, the present composition Q can be used as a packaging material (cardboard) for post-harvest (pre-harvest) packaging of fruits and vegetables, etc. By using it in food products (bags, tapes, etc.), it is possible to suppress the occurrence of pests and prevent their attachment, for example, to maintain freshness. It has the effect of a retention composition or post-harvest agent. By using this composition Q in the above, it is possible to improve shelf life, maintain freshness, prevent pests, and improve coloring. It has the effect of removing (killing) attached scale insects. The composition Q is suitable for use as an insecticide, Mites, nematodes, fungicides, plant growth regulators, weed control agents (herbicides and herbicides), cleaning Deodorants, spreading agents and freshness preserving agents, as well as for humans, pet animals such as dogs and cats, cows and sheep, etc. The period when the composition Q is used as a pesticide for pests that parasitize livestock, a cleaning agent and a deodorizer , location (leaves, roots, flowers, fruits, etc.), concentration, method (spraying, immersion, adhesion, application, etc.), number of times, amount, etc. By appropriately combining these, the present composition contains, as at least one agent selected from the above, IP It is an IPM composition that protects the agricultural land environment and prevents the occurrence of pests and diseases, which is the concept of M. It can be suitably used as such.
[0054] [2] The composition for IPM according to [1], characterized by basicity due to being an electron pair donor. Composition (hereinafter referred to as composition Q1). The basic composition Q1 used in the present invention as an electron pair donor is generally water-soluble. An inorganic or organic compound that becomes alkaline in a liquid and acts as an electron donor. The composition Q1 is, for example, a 1% aqueous solution. Carbonates, sesquicarbonates, bicarbonates, hydrogen carbonates, phosphates, and chlorides with a pH between 7 and 11 compounds, sulfates and ammonia, urea, other basic compounds, organic bases (used as bases) The base contains at least one or more selected from the group consisting of organic bases such as sesquicarbonate and methylcellulose, and is preferably methylcellulose. It is desirable to include an acid salt of these bases. These bases are blended in one kind or in a mixture of two or more kinds, and The amount of the compound to be added is usually 0.001 to 50% by weight, preferably 0.1 to 20% by weight, of the composition of the present invention. For example, a 1% aqueous solution preferably has a pH of 7 to 11. Preferably, the pH is 9.6 or higher and 10.5 or lower. Depending on how the composition of the present invention is used, it can be used as, for example, an insecticide, acaricide, nematodeicide, For disinfectants, detergents, deodorizers and freshness-preserving agents, the amount is about 0.01 to 20% by weight of the composition of the present invention. It can also be used as a spreading agent and / or plant growth regulator, and is effective even at very low concentrations. Therefore, it may be added in an amount of about 0.0001 to 20% by weight in the composition of the present invention, and is effective for weed control. As a herbicide / herbicide, the higher the concentration, the more stable the effect. The amount of the present composition Q1 may be about 5 to 100% by weight in the total amount. When the amount is less than 100%, the agent can be at a preferable concentration, and an excellent effect can be obtained as an IPM composition. This can be done.
[0055] Specific examples of the composition Q1 include sesquicarbonate, potassium carbonate, sodium carbonate, carbonate Specific examples of water-soluble bicarbonates include potassium bicarbonate and sodium bicarbonate. ammonium bicarbonate, etc., and specific examples of water-soluble chlorides include potassium chloride, sodium chloride, etc. sodium chloride, calcium chloride, magnesium chloride, etc., and water-soluble phosphates include hydrogen phosphate. Disodium, Sodium Dihydrogen Phosphate, Dipotassium Hydrogen Phosphate, Potassium Dihydrogen Phosphate The water-soluble sulfate is copper sulfate, and the compound is selected from ammonia, urea, etc. It is desirable to contain at least one or more types, and preferably to contain sesquicarbonate. These bases are used alone or in combination of two or more, and the amount of bases used is usually in the composition of the present invention. It is desirable to use it in an amount of 0.001 to 50% by weight, preferably 0.1 to 20% by weight. When the blending amount of the present composition Q1 is within the above range, it is possible to obtain excellent effects as a cosmetic composition. This can be done. These basic substances are highly lipophilic and have the properties of emulsifying oils and fats and breaking down proteins. Therefore, by using this composition Q1, it is possible to improve the wettability and penetration of plant pests and materials. , excellent in at least one effect selected from adhesion, spreadability, extensibility and permeability, and further Due to its denaturing effect, it can be suitably used as an IPM composition for pest and weed control. This composition Q1 can be used to treat, for example, water-repellent or hydrophobic insect body coatings. It wets the cuticle layer on the surface of the plant body due to its hydrophilic effect and acts as an electron pair donor. The basicity of this emulsion emulsifies and disperses waxy substances (lipids, waxes, etc.), denaturing them to form glycerides. It breaks down into phosphorus and fatty acid salts, which are then converted into surfactants (a type of soap) that help control pests and weeds. Furthermore, the composition Q1 can denature proteins, nucleic acids, etc. The composition Q1 is effective as a plant (agricultural and horticultural) control composition, and is also effective as an insecticide, Mites, nematodes, fungicides, plant growth regulators, weed control agents (herbicides and herbicides), cleaning Deodorants, spreading agents and freshness preserving agents, as well as for humans, pet animals such as dogs and cats, cows and sheep, etc. and at least one agent selected from the group consisting of pesticides for pests parasitic on livestock, cleaning agents, and deodorizers. It has a significant effect.
[0056] A specific example using the composition Q1 is given in Example 2 below.
[0057] [Example 2] By using the present composition Q1, for example, from the viewpoint of cultivation, it acts as a plant growth regulator. This changes the biological balance of plants and suppresses the occurrence of pests that are inherent to crops and the environment. By enhancing the effect of this, conditions are created that make it difficult for pests to occur, and it is possible to suppress their occurrence and reduce damage. Physically, the conditions are unsuitable for the survival of pathogens and pests, and the waxy covering of the pests' bodies is removed. It turns the insect into a surfactant (a kind of soap), takes away its defense mechanism, blocks the spiracles, and kills it. In addition, the denaturation of the insect's body covering generates carbon dioxide, which reduces oxygen deficiency. Chemically, the cuticle layer of plants and pests, The present composition can reach the pest or plant without being repelled by insect body coverings, etc., and has excellent The spreading function (a minimum of wetting, penetration, adhesion, spreading, extensibility and penetration) The effect of this plant is to kill pests and diseases due to its excellent properties. It is possible to preserve microorganisms and insects that are natural enemies of pathogens and sap-sucking pests, and also to release insect sex pheromones. It can be used in combination with many materials (natural enemies) that are registered as indigenous natural enemy pesticides. Its spreading agent function and cuticle modification effect make it excellent in wetting properties and effective as a plant growth regulator. It alters the hormone balance in weeds, killing cells (suppressing activity and disrupting the balance). By making the plant grow, it can be used for weed control (weed suppression, etc.). By killing certain symbiotic bacteria (bacteria that provide essential nutrients and are essential for survival), pests can be prevented. Another effect is that the cuticle layer (insect body covering) By denaturing into a surfactant (a type of soap), it can prevent sooty mildew and scale insects from staining the plant body. It can cleanse fruits, leaves, and animal skins. It dissolves, cleans, and prevents pest pheromones, and also eliminates mold, decay, and fermentation odors. Plant growth regulation (promotion or inhibition of growth, germination, flowering and fruiting, coloring, etc., sugar content) It can be used as a freshness preserving agent (post-harvest agent) and to increase the amount of active ingredients. It has the effect of controlling pests (suppressing their occurrence, etc.), preserving the freshness of fruits and vegetables, and preventing wilting, aging, and discoloration. , preventing stem wilting and decay, and also coloring, sugar content, taste and functional components (β-cryptoxan at least one selected from the group consisting of improving or increasing vitamin D, vitamin B6, vitamin B12, vitamin B12, vitamin B6, vitamin B12, vitamin B ... Due to its properties, it has excellent effects. The composition Q1 is an insecticide having at least one property and effect selected from the above examples. , mites, nematodes, fungicides, plant growth regulators, weed control agents (herbicides and herbicides), washing agents Cleaning agents, deodorizers, spreading agents and freshness preserving agents, as well as for humans, pet animals such as dogs and cats, or cows and sheep The composition Q1 is used as a pesticide for pests that parasitize livestock, such as Time, location (leaves, roots, flowers, fruits, etc.), concentration, method (spraying, immersion, adhesion, application, etc.), number of times, By appropriately combining the amounts, etc., the present composition contains at least one agent selected from the above, It can be suitably used in IPM.
[0058] The most preferred method of using the composition Q1 is, for example, spraying it as a water-based agent. It can be sprayed, impregnated, applied, pasted, wrapped around, or hung on materials such as paper, cloth, tape, and string. By using it for hanging, covering, laying and soil application, it can prevent contact, adhesion, spreading, penetration and damage to pests. By extending the product, etc., it exerts a control effect while blocking direct contact and controlling behavior. The composition is preferably used by a machine (power sprayer, sprayer, etc.) or a tool ( Examples include the use of brushes and sprays.
[0059] [3] The basicity is a carbonate, bicarbonate, hydrogen carbonate, phosphate, chloride, sulfate, and [1] or [2], which contains at least one or more selected from ammonia and urea The composition for IPM described above (hereinafter referred to as composition Q2). The basic composition Q2 used in the present invention is, for example, a carbonate such as sesquioxane. Carbonate, potassium carbonate, sodium carbonate, ammonium carbonate, etc. are water-soluble bicarbonates. Potassium bicarbonate, sodium bicarbonate, ammonium bicarbonate, etc. are water-soluble chlorides. As a result, potassium chloride, sodium chloride, calcium chloride, magnesium chloride, etc. are water-soluble. Phosphate salts include disodium hydrogen phosphate, sodium dihydrogen phosphate, and dipotassium hydrogen phosphate. Umium, potassium dihydrogen phosphate, etc. are water-soluble sulfates, copper sulfate, water-soluble compounds At least one or two selected from ammonia, urea, and other basic compounds It is desirable that the compound contains at least one species, and preferably contains sesquicarbonate.
[0060] Composition Q2 contains one or more of these bases in a mixture, and the amounts are as follows: Generally, the amount is about 0.001 to 50% by weight, preferably about 0.01 to 50% by weight, in the composition of the present invention. It is desirable to do so. Depending on how the composition of the present invention is used, it can be used as, for example, an insecticide, acaricide, nematodeicide, For disinfectants, detergents, deodorizers and freshness-preserving agents, the amount is about 0.01 to 20% by weight of the composition of the present invention. It can be used as a spreading agent and / or plant growth regulator, and is effective even at very low concentrations. Therefore, it may be added in an amount of about 0.0001 to 20% by weight in the composition of the present invention, and is effective for weed control. As a herbicide / herbicide, the higher the concentration, the more stable the effect. The amount of the present composition Q2 may be about 5 to 100% by weight in the total amount. If it is present, excellent effects can be obtained as an IPM composition.
[0061] The pH of the composition Q2 is preferably in the range of 7 to 11. More preferably, it is 9.6 The pH range of the present composition Q2 is preferably within 10.5. It is possible to obtain excellent effects as an IPM composition while minimizing the impact on humans and animals. can.
[0062] Due to the effects of this composition Q2, it can be used as a plant (agricultural and horticultural) pest control composition as an insecticide, anti-mite agent, Pesticides, nematode control agents, fungicides, plant growth regulators, weed control agents (herbicides and herbicide inhibitors), cleaning agents, Odors, spreading agents and freshness preservatives, as well as for humans, pets such as dogs and cats, and livestock such as cows and sheep and at least one agent selected from the group consisting of a pesticide for insects and diseases that parasitize insects, a cleaning agent, and a deodorizer. It has fruit.
[0063] [4] The composition further comprising at least one agent selected from an insecticide, an acaricide, and a nematicide. A composition for IPM according to any one of [1] to [3] (hereinafter referred to as composition X). Composition X is added to compositions Q, Q1 and Q2 to contain the insecticide, acaricide and nematicide ( By including this ingredient X1), it can be used as a plant (agricultural and horticultural) control composition as an insecticide, acaricide, Pesticides, nematode control agents, fungicides, plant growth regulators, weed control agents (herbicides and herbicide inhibitors), cleaning agents, Deodorizers, spreading agents and freshness preserving agents, and also for people, pet animals such as dogs and cats, and household items such as cows and sheep. The effect of at least one agent selected from pesticides for pests that parasitize livestock, cleaning agents, and deodorizers is In particular, the spreading function (wettability, penetration, adhesion, spreading, elongation) At least one property selected from the group consisting of spreadability and penetration) has been significantly improved, and it has a higher level of efficacy than conventional insecticides alone. Compared with the composition used in 2. above, the killing activity against pests is dramatically improved, and the effectiveness can be improved. As a combination of the insecticide X1 and any of the present compositions Q, Q1 and Q2, for example, neonicotinoids Cotinoids, organophosphates, thiadiazines, quinazolines, pyriproxyfen, IG R series (JH agent), chloronicotinyl series, BT agent (Kurstaki bacteria), BT agent (Aizawai fungi), pyrethroids, spinosyns, carbamates, phenylpyrazoles, macro They are classified into benzodiazepine, pyridinediazomethine, and macrolide respiratory inhibitors. , BHC, BPMC, CVMP, CVP, CYAP, DMTP, EPN, MEP, MIP C, MPMC, MPP, NAC, PAP, PHC, PMP, XMC, allethrin, isoki Sathion, Isofenphos, Imidacloprid, Ethiofencarb, Ethion, Ethyl Thiometon, etofenprox, ethoprophos, carbosulfan, clothianidin , chlorpyrifos, chlorpyrifos-methyl, chlorfluazuron, salithion, cyclopropanol Lothrin, cyhalothrin, cyfluthrin, diflubenzuron, cypermethrin, dimethyl Vinphos, tolfenpyrad diazinon, thiodicarb, thiometon, tebufenozide , tefluthrin, teflubenzuron, tralomethrin, parathion, bifenthrin, Laclofos, pyridaphenthion, pirimiphos-methyl, phenisobromorate, phenoxazole Sicarb, fenvalerate, fenpropathrin, sulfuryl fluoride, flucitrine fluvalinate, fluacrypyrim, prothiofos, propafos, profenofos, Permethrin, Bensultap, Benzoepin, Bendiocarb, Benfuracarb, Ho Salon, Marathon, Mecarbam, Methyl Parathion, Resmethrin, Machine Oil, BT and Insects A combination of at least one or more pesticides selected from microbial pesticides such as pathogenic viruses Preferably, the hydrophilic and denaturing effects of the compositions of the present invention are prevented. It is advisable not to combine the above ingredients.
[0064] As a combination of the acaricidal component X1 and any of the compositions Q, Q1 and Q2 of the present invention, for example, For example, BPPS, alanycarb, clofentezine, chlorbenzilate, Kelthane, Nochlor, tetradifon, tebufenpyrad, fenothiocarb, fenpyroximate , flufenoxuron, hexythiazox, benzomate, fenbutatin oxide, DPC , binapacryl, pyridaben, etc. Preferably, the hydrophilic and denaturing effects of the composition of the present invention are not hindered. It is desirable to combine the above ingredients.
[0065] As a combination of the nematicidal component X1 and any of the compositions Q, Q1 and Q2 of the present invention, for example For example, aluminum phosphide, benclothiaz, cadusafos, ethoprophos, fluensulf fosthiazate, furfural, imidiyafos, levamisole hydrochloride, mesulfenfo s, carbam, methyl isocyanate (morantel tartrate, oxamyl, thioxazafen At least one or a combination of two or more selected from the group consisting of benzophenone, ... The above-mentioned components are combined so as not to interfere with the hydrophilic and denaturing effects of the composition of the present invention. It is desirable to do so.
[0066] The present components, insecticide, acaricide, nematicide X1 and the composition of the present invention, Specific examples of combinations with either Q1 or Q2 include abamectin, acephate, cephate, acequinocyl, acetamiprid, acetopro acetoprole, acrinathrin, acinonapyr, af afidopyropen, afoxolaner, alanycarb rb), aldicarb, allethrin, alphacypermethrin pha-cypermethrin, alpha-endosulfan, aluminum phosphide Aluminum phosphide, amitraz, azadirachtin , azamethiphos, azinphos-ethyl, azinphosmethi Azocyclotin, Celastrus angulatus bark of Celastrus angulatus, bendiocarb, benfluthrin hrin, benfuracarb, bensultap, benzoxime benzoximate, benzpyrimoxan, beta-cyfluthrin fluthrin, beta-cypermethrin, bifenazate , bifenthrin, bilobalide, bioallet hrin), bioresmethrin, bistrifluron, Borax, boric acid, broflanilide, bromopropyl bromopropylate, buprofezin, butocarboxim , butoxycarboxim, cadusafos, calcium phosphide calcium phosphide, carbaryl, carbofuran, carbo Sulfan (carbosulfan), cartap hydrochloride (cartap hydrochloride), cartap (ca rtap), cevadine, chinomethionate, chlorantranil Chlorantraniliprole, chlordane, chlorethoxyphos hoxyfos, chlorfenapyr, chlorfenvinphos ), chlorfluazuron, chlormephos, chlorpic chloropicrin, chlorpyrifos, chlorpyrifos-methyl rifos-methyl, chromafenozide, clofentezine ), clothianidin, concanamycin A, coumaphos (coumaphos), cryolite, cyanophos, cyantranilp cyantraniliprole, cyclaniliprole, cyclobutriflu cyclobutrifluram, cycloprothrin, cycloxapride oxaprid, cyenopyrafen, cyetpyrafen, cyflumetofen metofen, cyfluthrin, cyhalodiamide, cyhalotri cyhalothrin, cyhexatin, cypermethrin, cyf Cyphenothrin, cyromazine, dazomet, delta deltamethrin, demeton-S-methyl, diafenthion Diafenthiuron, diazinon, dichlorvos, dichlor dicloromezotiaz, dicofol, dicrotophos, DiflovidaZin, di?ubenZuron, dime?thrin dimefluthrin, dimethoate, dimethylvinphos, d Impropyridaz, dinotefuran, disodium octaborate ate), disulfoton, DNOC (2-methyl-4,6-dinitrophenol), doramectin doramectin, dried leaves of Dryopteris filix-mas, Emamectin benzoate, empenthrin, endothel Endosulfan, EPN(O-ethyl O-(4-nitrophenyl) phenylphosphonothioate), Epsilon metofluthrin, Epsilon metofluthrin silon-momfluorothrin, esfenvalerate, ethiofencarb (ethiofencarb), ethion, ethiprole, ethoprophos rophos, etofenprox, etoxazole, nigayo Mogi extract (extract of Artemisia absinthium), Cassia nigricans extract (extract of Cassia nigricans, extract of clitoria ternatea ), Symphytum officinale extract, Symphytum officinale extract cts or simulated blend of Chenopodium ambrosioides), tansy extract Tanacetum vulgare, nettle extract (extract of Urtica dioica), mistletoe Extract of Viscum album, famphur, fenamiphos , fenazaquin, fenbutatin oxide, fenitrothion Fenitrothion, fenobucarb, fenoxycarb , fenpropathrin, fenpyroximate, fenthion, fenvalerate, fipronil, flometoquin, flonicamid, fluacrypyrim yrim), fluazaindolizine, fluazuron, flu Flubendiamide, flucycloxuron, flucitrine Flucythrinate, fluensulfone, flufenprox oprox), flufenoxuron, flufiprole, flu Flumethrin, flupentiofenox, flupyradiflo Flupyradifurone, flupyrimin, fluralaner, flu Valinate, fluxametamide, formetanate tanate, fosthiazate, furamethrin, furathiocal furathiocarb, gamma-cyhalothrin, ginkgolide A Ginkgolide A, ginkgolide B, ginkgolide C, ginkgolide Ginkgolide J, Ginkgolide M, GS-Omega / Kappa HXTX-Hv1a peptide GS-omega / kappa HXTX-Hv1a peptide), Halfenprox, Halo Fenozide (halofenozide), heptafluthrin, heptenophos ophos, hexaflumuron, hexythiazox, hops Potassium salt of hop beta acid, hydrame thylnon, hydroprene, imicyafos, imidacloprid (imidacloprid), imidaclothiz, imiprothrin, i Indoxacarb, isocycloseram, isofenphos ofenphos, isoprocarb, isopropyl O-(methoxyaminothiophos) Isopropyl-O-(methoxyaminothiophosphoryl) salicylate, isopropyl-O-(methoxyaminothiophosphoryl) salicylate Isoxathion, Ivermectin, Kadethrin, kappa-tefluthrin, kappa-bifenthrin, Kinoprene, lambda-cyhalothrin, lenolemycin noremycin, lepimectin, lime sulfur, lotilaner otilaner, lufenuron, machine oil, malathion on), mecarbam, meperfluthrin, metaflumizone taflumizone, metham, methamidophos, methidathion athion, methiocarb, methomyl, methoprene , methoxychlor, methoxyfenozide, methyl bromide methyl bromide, metofluthrin, metolcarb, Toxadiazone, mevinphos, milbemectin in), milbemycin oxime, momfluorothrin in), monocrotophos, moxidectin, naled d) neem oil, nicotine, nicotine sulfate, Nitenpyram, novaluron, noviflumuron , Chenopodium anthelminticum seed oil (oil of the seeds of Chenopodium anthelminticum), Methoate, oxamyl, oxazosulfyl, Oxydemeton-methyl, parathion, parathion methyl parathion-methyl, permethrin, phenothrin, phenthoate, phorate, phosalone, phosmet phosmet, phosphamidon, phosphine, phoxi m), pirimicarb, pirimiphos-methyl, praletri prallethrin, profenofos, profluthrin, propargite, propetamphos, propoxur , propylene glycol alginate, prothiofos (pr othiofos, pyflubumide, pymetrozine, pyraclofos (pyraclofos), pyrethrins, pyridaben, pyrid alyl, pyridaphenthion, pyrifluquinazone , pyrimidifen, pyriminostrobin, pyripro pyriproxyfen, quinalphos, Resmethrin, rotenone, ryanodine, sarolaner (sarolaner), Sabadilla seed extract (seed extract of Schoenocaulon spp.), Sera Mectin (selamectin), sigma-cypermethrin, silafluofen Silafluofen, sodium borate, sodium metaborate metaborate, spinetoram, spinosad, spirodiclofe spirodiclofen, spiromesifen, spiropidione , spirotetramat, sulfluramid, sulfotep ( sulfotep, sulfoxaflor, sulfur, sulfuryl fluoride uryl fluoride, tartar emetic, tau-fluvalinate, Tebufenozide, tebufenpyrad, tebupirimfos ebupirimfos, teflubenzuron, tefluthrin, teme Temephos, terbufos, terpene components extracted from the plant ne constituents of the extract of chenopodium ambrosioides near ambrosioidesBran d name: Terpenoid blend QRD 460), tetrachlorantraniliprole aniliprole, tetrachlorvinphos, tetradifon , tetramethrin, tetramethylfluthrin, Tetraniliprole, theta-cypermethrin, Thiacloprid, thiamethoxam, thiocyclam clam), thiodicarb dicarb, thiofanox, thiometon, thiosultap Disodium thiosultap, monosodium thiosultap sodium), tioxazafen, tolfenpyrad, tralo Tralomethrin, transfluthrin, triazamate zamate, triazophos, trichlorfon, triflumezo Pyrim (triflumezopyrim), triflumuron, trimethacarb arb), tyclopyrazoflor, vamidothion, berat Lysine (veratridine), wood extract of Quassia amara , XMC (3,5-dimethylphenyl N-methylcarbamate), xylylcarb, Ze Zeta-cypermethrin, zinc phosphide, N-[3-chloro-1 -(pyridin-3-yl)-1H-pyrazol-4-yl]-N-ethyl-3-(3,3,3-trifluoropropanesulfinyl)propa namide (1477923-37-7), 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4,5-dihydr o-1,2-oxazol-3-yl]-2-methyl-N-(1-oxothietan-3-yl)benzamide (1241050-20-3), 3-me thoxy-N-(5-{5-(trifluoromethyl)-5-[3-(trifluoromethyl)phenyl]-4,5-dihydro-1,2-ox azol-3-yl}indan-1-yl)propanamide (1118626-57-5), 4-chloro-5-[2,2-difluoro-2-(3, 4,5-trifluorophenyl)ethoxy]-2-methylphenyl 2,2,2-trifluoroethyl sulfoxide (16322 18-00-8), 4-fluoro-5-[2,2-difluoro-2-(3,4,5-trifluorophenyl)ethoxy]-2-methylphe nyl 2,2,2-trifluoroethyl sulfoxide (1632217-98-1) ,2-({2-fluoro-4-methyl-5-[(2, 2,2-trifluoroethyl)sulfinyl]phenyl}imino)-3-(2,2,2-trifluoroethyl)-1,3-thiazolid in-4-one (1445683-71-5), (3R)-3-(2-chlorothiazol-5-yl)-8-methyl-7-oxo-6-phenyl- 2,3-dihydrothiazolo[3,2-a]pyrimidin-4-ium-5-olate (2249718-27-0), etc. At least one or a combination of two or more of the above may be used. It is desirable to combine the above ingredients in a way that does not interfere with the hydrophilic and denaturing effects.
[0067] [5] Any of [1] to [4], wherein the compositions Q, Q1, and Q2 further contain a fungicide. The composition for IPM described above (hereinafter referred to as composition Y). Composition Y contains fungicide Y1 (hereinafter referred to as Y1) in compositions Q, Q1, and Q2. By using this product, it can be used as an insecticide, acaricide, nematode repellent, fungicide, plant growth regulator, weed control agent (except Weed and weed suppressants), cleaning agents, deodorizers, spreading agents and freshness preserving agents, and also for people, dogs, cats and other pets. The agent is selected from pesticides for insects and diseases that parasitize animals or livestock such as cows and sheep, cleaning agents, and deodorizers. It can synergistically enhance the effect of at least one agent. In particular, the spreading agent function (wetting, penetration) At least one property selected from the group consisting of adhesiveness, adhesion, spreadability, extensibility and permeability has been significantly improved. Furthermore, the killing activity of pathogens is dramatically improved compared to the conventional composition using only fungicides, and the effectiveness is It can also be used to prevent sap-sucking pests (scale insects, aphids, mites, and bruises). It kills the symbiotic bacteria necessary for the survival of insects such as scale insects, lice, and scale insects. It can provide an insecticidal effect.
[0068] The present composition Y is a combination of the fungicide Y1 and any of the present compositions Q, Q1 and Q2, e.g. For example, mitotic inhibitors, respiratory inhibitors, SH inhibitors, cell division and cytoskeleton inhibitors, respiratory inhibitors, Amino acid synthesis inhibitors, protein synthesis inhibitors, lipid synthesis and membrane synthesis inhibitors, signal transduction inhibitors , inhibition of glucose metabolism, inhibition of nucleic acid biosynthesis, inhibition of cell membrane function, inhibition of phospholipid synthesis, ergosterol Inhibitor of EBI, cell wall synthesis, melanin synthesis, plant defense inducer, non-fungicidal These include pesticide ingredients and other fungicidal active ingredients. The above ingredients can be used alone. Alternatively, two or more types may be mixed and used as required.
[0069] A specific example that can be combined with the composition Y is acibenzolar-S-methyl (acibenzolar-S- methyl), aldimorph, ametoctradin, aminopyri Aminopyrifen, Amisulbrom, Anilazine, Aza Conazole (azaconazole), azoxystrobin (azoxystrobin), basic copper sulfate (basic copper sulfate), benalaxyl, benalaxyl-M, Benoda benodanil, benomyl, benthiavalicarb, benthiavalicarb Benthiavalicarb-isopropyl, Benzovindiflupyr zovindiflupyr, binapacryl, biphenyl, bitertanol Bitertanol, bixafen, blasticidin-S, bol Bordeaux mixture, boscalid, bromothalonil , bromuconazole, bupirimate, captafol ptafol, captan, carbendazim, carboxin in), carpropamid, chinomethionate, chitin itin), chloroneb, chlorothalonil, chlozolinate ( chlorzolinate, colletochlorin B, copper(II) acetate ate), copper(II) hydroxide, basic copper chloride, Copper(II) sulfate, coumoxystrobin, cyazof cyazofamid, cyflufenamid, cymoxanil, Cyproconazole, cyprodinil, diclofenac Dichlofluanid, diclocymet, t), diclomezine, dicloran, diethofencarb ofencarb), difenoconazole, diflumetorim, Dimethachlone, dimethirimol, dimethomorph omorph, dimoxystrobin, diniconazole, di Niconazol-M (diniconazole-M), dinocap, dipotassium hydrogen phosphite (dip otassium hydrogenphosphite, dipymetitrone, dithianon on), dodecylbenzenesulfonic acid bisethylenediamine copper(II) complex salt (dodecylbenzenesu bisethylenediamine copper(II) salt), dodemorph, Dodine, edifenphos, enoxastrobin, Epoxiconazole, etaconazole, ethaboxam thaboxam, ethirimol, etridiazole, tea tree -extract from Melaleuca alternifolia, extract from Melaleuca alternifolia Reynoutria sachalinensis, extract from the cotyledons of lupin seedlings Cotyledons of lupine plantlets (BLAD), garlic extract (extract of Allium sativum) ivum), horsetail extract (extract of Equisetum arvense), nasturtium extract (extrac) t of Tropaeolum majus, famoxadone, fenamidone , fenaminstrobin, fenarimol, fenbuconazole Fenbuconazole, fenfuram, fenhexamid, Fenoxanil, fenpiclonil, fenpicoxamid enpicoxamid, fenpropidin, fenpropimorph , fenpyrazamine, triphenyltin acetate, triphenyltin chloride Triphenyltin (fentin chloride), triphenyltin hydroxide (fentin hydroxide), ferrocene Ferbam, ferimzone, florylpicoxamid , fluazinam, flubeneteram, fludioxonil ioxonil, flufenoxystrobin, fluindapy r), flumorph, fluopicolide, fluopyram m), fluopimomide, fluoroimide, fluoxapip Fluoxapiprolin, fluoxastrobin, fluquinconazole Fluquinconazole, flusilazole, flusulfamide e), flutianil, flutolanil, flutriafol iafol, fluxapyroxad, folpet, fosetyl l), fosetyl-aluminium, fuberidazole, Furalaxyl, furametpyr, guazatine, hex Hexaconazole, hymexazole, imazalil , imibenconazole, iminoctadine, iminoctadine Iminoctadine triacetate, inpyrfluxam, iodine Iodocarb, ipconazole, ipfentrifluconazole trifluconazole, ipflufenoquin, iprobenfos , iprodione, iprovalicarb, isofetamide fetamid, isoflucypram, isoprothiolane, Isopyrazam, isotianil, kasugamycin , kresoxim-methyl, laminarin, oak leaf and Quercus leaves and bark, mancozeb, mandestrobin strobin, mandipropamid, maneb, mefentriflu Conazole (mefentrifluconazole), mepanipyrim, mepronil l), meptyldinocap, metalaxyl, metalaxyl M (metalaxyl-M), metconazole, methasulfocarb , metiram, metominostrobin, metrafenone fenone, methyltetraprole, mineral oils, Myclobutanil, Naftifine, Nuarimol, Octilinone, ofurace, orysastrobin, Oxadixyl, oxathiapiprolin, oxine-copper , oxolinic acid, oxpoconazole, oxpo Conazole fumarate (oxpoconazole fumarate), oxycarboxin, Oxytetracycline, pefurazoate, pencona penconazole, pencycuron, penflufen, Penthiopyrad, phenamacril, phosphorous acid), phthalide, picarbutrazox, picoxyst Picoxystrobin, piperalin, polyoxins, carbonated water Potassium hydrogencarbonate, potassium dihydrogen phosphite rogenphosphite, probenazole, prochloraz, pro Procymidone, propamidine, propamocarb , propiconazole, propineb, proquinazide zid, prothiocarb, prothioconazole, pyzine Flumetofen (pydiflumetofen), pyraclostrobin (pyraclostrobin), pyramethos pyrametostrobin, pyraoxystrobin, pyrapropioi pyrapropoyne, pyraziflumid, pyrazophos, pyri Bencarb (pyribencarb), pyributicarb, pyridaclomethyl chlometyl, pyrifenox, pyrimethanil, pirimol pyrimorph, pyriophenone, pyrisoxazole, Pyroquilon, Quillaja extract, Quinconazole (quinconazole), quinofumelin, quinoxyfen, kin Quintozene, Saponins of Chenopodium quinoa, Sedaxa Sedaxane, silthiofam, simeconazole, carbonate Sodium hydrogencarbonate, spiroxamine, streptavidin Streptomycin, sulfur, tebuconazole, tebu Tebufloquin, Teclofthalam, Tecnazene, Terbinafine, tetraconazole, thiabendazole (thiabendazole), thifluzamide, thiophanate, Thiophanate-methyl, thiuram, thymol, Tiadinil, tolclofos-methyl, tolfenpyrad olfenpyrad, tolprocarb, tolylfluanid, triflurane Azimefon, triadimenol, triazoxide ide), triclopyricarb, tricyclazole, tridemorph, trifloxystrobin, triflumizo triflumizole, triforine, triticonazole, Validamycin, valifenalate, vinclozolin nclozolin), mustard powder (yellow mustard powder), zinc thiazole, zineb ( zineb, ziram, zoxamide, 3-(difluoromethyl)-N-methoxy-1-m ethyl-N-[(1R)-1-methyl-2-(2,4,6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-48-7) 、3-(difluoromethyl)-N-methoxy-1-methyl-N-[(1S)-1-methyl-2-(2,4, 6-trichlorophenyl)ethyl]-1H-pyrazole-4-carboxamide (1639015-49-8) 、3-(difluorom ethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carb oxamide (141573-94-6) 、3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3- dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide (1513466-73-3) 、N'-[4 -({3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl}oxy)-2,5-dimethylphenyl]-N-e thyl-N-methylmethanimidamide (1202781-91-6) 、N'-{4-[(4,5-dichlorothiazol-2-yl)o xy]-2,5-dimethylphenyl}-N-ethyl-N-methylmethanimidamide (929908-57-6) 、N'-(2,5- dimethyl-4-phenoxyphenyl)-N-ethyl-N-methylmethanimidamide (1052688-31-9) 、N'-[5 -choro-4-(2-fluorophenoxy)-2-methylphenyl)-N-ethyl-N-methylmethanimidamide (2055 589-28-9) 、N'-[2-choro-4-(2-fluorophenoxy)-5-methylphenyl)-N-ethyl-N-methylmeth animidamide (2055756-21-1) 、N'-[4-(1-hydroxy-1-phenyl-2,2,2-trifluoroethyl)-2-m ethyl-5-methoxyphenyl)-N-isopropyl-N-methylmethanimidamide (2101814-55-3) 、N'-[ 5-bromo-6-(1-methyl-2-propoxyethoxy)-2-methylpyridin-3-yl)-N-ethyl-N-methylmetha nimidamide (1817828-69-5) 、4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluoropheny l)-1,3-dimethyl-1H-pyrazol-5-amine (1362477-26-6) 、2-[6-(3-fluoro-4-methoxyphen yl)-5-methylpyridin-2-yl]quinazoline (1257056-97-5) 、5-fluoro-4-imino-3-methyl- 1-tosyl-3,4-dihydropyrimidin-2(1H)-one (1616664-98-2) 、ethyl (2Z)-3-amino-2-cya no-3-phenylacrylate (39491- 78-6) 、N-[(2-chlorothiazol-5-yl)methyl]-N-ethyl-6-methoxy-3-nitropyridin-2-amin e (1446247-98-8) 、α-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-ox azol-4-yl]-3-pyridinemethanol (1229605-96-2) 、(αS)-[3-(4-chloro-2-fluorophenyl )-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyridinemethanol (1229606-46-5) 、( αR)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl]-3-pyri dinemethanol (1229606-02-3) 、5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H -1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-11-4) 、(1R2S5S)-5-(4-chloro benzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-o l (1801930-06-2) 、(1S2R5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1 ,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-07-3) 、(1R,2R,5R)-5-(4-chloro benzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-o l (1801919-53-8) 、(1S,2S,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H -1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-54-9) 、(1R,2R,5S)-5-(4-chlo robenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1 -ol (1801919-55-0) 、(1S,2S,5R)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-( 1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-56-1) 、(1R,2S,5R)-5-(4-ch lorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan -1-ol (1801919-57-2) 、(1S,2R,5S)-5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1 -(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801919-58-3) 、methyl 3-[(4-chl orophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane -1-carboxylate (1791398-02-1) 、methyl (1R,2S,3S)-3-[(4-chlorophenyl)methyl]-2-h ydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (20807 43-90-2) 、methyl (1S,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H -1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-91-3) 、methyl (1R ,2R,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylme thyl)cyclopentane-1-carboxylate (2080743-92-4) 、methyl (1S,2S,3S)-3-[(4-chlorop henyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-c arboxylate (2080743-93-5) 、methyl (1R,2R,3S)-3-[(4-chlorophenyl)methyl]-2-hydro xy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-9 4-6) 、methyl (1S,2S,3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2 ,4-triazol-1-ylmethyl)cyclopentane-1-carboxylate (2080743-95-7) 、methyl (1R,2S, 3R)-3-[(4-chlorophenyl)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl )cyclopentane-1-carboxylate (2081061-22-3) 、methyl (1S,2R,3S)-3-[(4-chloropheny l)methyl]-2-hydroxy-1-methyl-2-(1H-1,2,4-triazol-1-ylmethyl)cyclopentane-1-carbo xylate (2081061-23-4) 、,2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2, 4-triazol-1-ylmethyl)cyclopentan-1-ol (1394057-13-6) 、(1R,2S,5S)-2-(chloromethy l)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol ( 1801930-08-4) 、(1S,2R,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1, 2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1801930-09-5) 、(1R,2R,3R)-2-(chloromet hyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-08-4) 、(1S,2S,3S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H- 1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-10-8) 、(1R,2R,3S)-2-(chlorom ethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1- ol (1638898-13-1) 、(1S,2S,5R)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1 H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-16-4) 、(1R,2S,5R)-2-(chlor omethyl)-5-(4-fluorobenzyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentan- 1-ol (1638898-20-0) 、(1S,2R,5S)-2-(chloromethyl)-5-(4-fluorobenzyl)-2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl)cyclopentan-1-ol (1638898-24-4) 、1-(2,4-difluoroph enyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4-bromo-2,6-difluorophenoxy)cyclopropyl]et hanol (2019215-86-0) 、1-(2,4-difluorophenyl)-2-(1H-1,2,4-triazol-1-yl)-1-[1-(4- chloro-2,6-difluorophenoxy)cyclopropyl]ethanol (2019215-84-8) 、1-[2-(1-chlorocy clopropyl)-3-(2-fluorophenyl)-2-hydroxypropyl]-1H-imidazole-5-carbonitrile (2018 316-13-5) 、1-[2-(1-chlorocyclopropyl)-3-(2,3-difluorophenyl)-2-hydroxypropyl]-1 H-imidazole-5-carbonitrile (2018317-25-2) 、4-({6-[2-(2,4-difluorophenyl)-1,1-di fluoro-2-hydroxy-3-(1H-1,2,4-triazol-1-yl)propyl]pyridin-3-yl}oxy)benzonitrile ( 2046300-61-0) 、2-[6-(4-bromophenoxy)-2-(trifluoromethyl)pyridin-3-yl]-1-(1H-1,2 ,4-triazol-1-yl)propan-2-ol (2082661-43-4) 、2-[6-(4-chlorophenoxy)-2-(trifluoro methyl)pyridin-3-yl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol (2082660-27-1) 、methy l ({2-methyl-5-[1-(4-methoxy-2-methylphenyl)-1H-pyrazol-3-yl]phenyl}methyl)carba mate (1605879-98-8) 、2-(difluoromethyl)-N-[1,1,3-trimethyl-2,3-dihydro-1H-inden -4-yl]pyridine-3-carboxamide (1616239-21-4) 、2-(difluoromethyl)-N-[(3R)-1,1,3-t rimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1616239-33-8) 、2-(di fluoromethyl)-N-[3-ethyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carbo xamide (1847460-02-9) 、2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-2,3-dihy dro-1H-inden-4-yl]pyridine-3-carboxamide (1952305-97-3) 、2-(difluoromethyl)-N-[ 3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl]pyridine-3-carboxamide (1847460- 05-2) 、2-(difluoromethyl)-N-[(3R)-3-propyl-1,1-dimethyl-2,3-dihydro-1H-inden-4- yl]pyridine-3-carboxamide (1952306-00-1) 、(2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyr azol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide (1445331-27-0) 、(2E, 3Z)-5-{[1-(2,4-dichlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethy lpent-3-enamide (1445331-54-3) 、5-chloro-4-({2-[6-(4-chlorophenoxy)pyridin-3-yl ]ethyl}amino)-6-methylpyrimidine (1605340-92-8) 、N-(1-benzyl-1,3-dimethylbutyl) -8-fluoroquinoline-3-carboxamide (2132414-04-9), N-[(1S)-1-benzyl-1,3-dimethylb utyl]-8-fluoroquinoline-3-carboxamide, N-[(1R)-1-benzyl-1,3-dimethylbutyl]-8-fl uoroquinoline-3-carboxamide (2132414-06-1), N-(1-benzyl-3,3,3-trifluoro-1-methy lpropyl)-8-fluoroquinoline-3-carboxamide (2132414-00-5), N-[(1S)-1-benzyl-3,3,3 -trifluoro-1-methylpropyl]-8-fluoroquinoline-3-carboxamide (2132414-01-6), N-[( 1R)-1-benzyl-3,3,3-trifluoro-1-methylpropyl]-8-fluoroquinoline-3-carboxamide, 4 ,4-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}methyl)isoxaz olidin-3-one (2098918-25-1), 5,5-dimethyl-2-({4-[5-(trifluoromethyl)-1,2,4-oxad at least one selected from the group consisting of iazol-3-yl]phenyl}methyl)isoxazolidin-3-one (2098918-26-2) and the like; One or more of these may be used in combination. Preferably, the hydrophilicity of the composition of the present invention is improved. It is desirable to combine the above ingredients in a manner that does not interfere with the effects characterized by denaturation.
[0070] Furthermore, the present compositions Q, Q1, and Q2 contain the present component X1 and the present component Y1, [1] to [ 4) a composition for IPM integrated pest and weed management (hereinafter referred to as Component Z) (Note below). The present composition Z is added to the present compositions Q, Q1 and Q2 by the insecticidal component of the present component X1 and further by the component Y1. By containing fungicides, it can be used as an insecticide, acaricide, nematode repellent, fungicide, plant growth regulator, weed repellent, etc. Management agents (weed killers and weed suppressants), cleaning agents, deodorizers, spreading agents and freshness preserving agents, as well as for humans, dogs and cats pesticides for pets such as hamsters, or livestock such as cows and sheep, as well as cleaning agents and deodorizers. In particular, the insecticidal active ingredient is and fungicidal active ingredient, both of which can bring about synergistic insecticidal activity. As an effect, for example, the insecticidal effect and the bactericidal effect, for example, effective control (death) by synergistic effect, etc. It also complements other pest control effects and increases the absorption rate of ingredients. These include killing symbiotic bacteria and inhibiting metabolism. As a combination of a miticide and a nematicide with the fungicide of the present component Y1, for example, A combination of one or more insecticides, acaricides and nematicides of X1 and fungicides of Y1. They can be used in combination or in conjunction.
[0071] The mixed or combined use of component Z means the use of component X1 and component Y1 simultaneously, separately, or This means that the components Q, Q1, and Q2 are used at intervals of 20 seconds. When components Q, Q1 and Q2 and components X1 and Y1 are used simultaneously, They may be contained in separate preparations or may be contained in a single preparation.
[0072] [6] Furthermore, (a), (b), (c), (d), (e), (f), (g), (h), ( i), (j), (k) and (l), containing at least one or more selected from the group consisting of: The composition for IPM according to any one of [1] to [5]. (a): Porous material; (b): Viscosity modifier; (c):Enzyme; (d): Microbial materials (e): insect pheromones; (f): Plant growth regulators; (g): herbicidal activator; (h): synergist; (i): Safeners; (j): repellents; (k): Molluscicidal component; (l):oil; The compositions Q, Q1, Q2, X, Y and Z are each added with one or more of the components (a) to (l). (a) to (l) can be used in combination with the ingredient (hereinafter referred to as ingredient W1). The species can be used alone or in a mixture of two or more species as required. By containing the above (a) to (l), it is possible to use an insecticide, acaricide, nematode repellent, fungicide, plant growth inhibitor, Growth regulators, weed control agents (herbicides and weed suppressants), cleaning agents, deodorizers, spreading agents and freshness preservatives, , pesticides for humans, pets such as dogs and cats, and livestock such as cows and sheep, cleaning agents At least one agent selected from the group consisting of a deodorant and a deodorant can be expected to have an excellent effect.
[0073] The above-mentioned mixture or combination of the present component W1 means the mixture or combination of the present compositions Q, Q1, Q2, X, Y and Z with the present component W1. This means that the composition Q and W1 are used simultaneously, separately, or at intervals. When Q1, Q2, X, Y, and Z are used simultaneously with the present component W1, the present composition Q, Q1, Q 2. X, Y and Z and the present ingredient W1 may be contained in separate preparations, or may be contained in one preparation. It may be contained in the agent.
[0074] The ingredients described below are all known ingredients and are either obtained from commercially available preparations or from known methods. If the component is a microorganism, it can be obtained from a bacterial depository institution. The numbers in parentheses represent the CAS RN (registered trademark).
[0075] [(a): Porous material] A device capable of combining the porous material (a) with the present compositions Q, Q1, Q2, X, Y and Z. Examples include activated carbon, zeolite, silica gel, lava rock, porous ceramics, artificial pumice, Porous plastic, charcoal, bone fragments, sponges, filters (plastic, plant, animal) Examples include porous materials (made of plastic, plant-based, or animal-based materials), membranes, and fabrics. The structural material has a large specific surface area, which allows for an increased amount of the composition to be supported or incorporated. By adjusting the pore size, the amount of active ingredient released can be controlled, making it suitable as a sustained release carrier. It's nice.
[0076] The composition of the activated carbon is a highly adsorbent carbon that has been chemically or physically treated (activated, activated). The surface area of 1g is 500~2500m2. Porous materials can be used alone or in combination of two or more types as required. The composition according to any one of the above items [1] to [5] can be mixed with a porous material (activated carbon, porous sand, etc.) ) can, for example, maintain a suitable humidity level, absorb heat, retain heat, adsorb, and penetrate into gaps. This action can enhance the effectiveness of killing pests. At least one of the following is selected from the group consisting of peeling, falling, disintegration, dissolution, decomposition, and absorption of insect coverings. This can promote the properties of
[0077] [(b): Viscosity modifier] (b) A device for combining the viscosity modifier with the present compositions Q, Q1, Q2, X, Y and Z Examples include the viscosity of natto (polyglutamic acid), the viscosity of seaweed (seaweed glue, kakumata, ginkgo grass, and fu). glue, etc.), plant glue (cellulose, etc.), chemical substances (polyacrylic acid, polyethylene glycol The composition according to any one of [1] to [5] above is added with a viscosity of (b). The regulator, for example, increases adhesion to pests or plants and extends the time they can be applied, thereby (b) The viscosity modifier can be used alone to enhance the effectiveness of the composition and increase the killing activity. Alternatively, two or more types may be mixed and used as needed.
[0078] [(c):Enzyme] Specific examples of combinations of the enzyme (c) with compositions Q, Q1, Q2, X, Y, and Z include: Proteases (pepsin, trypsin, papain, bromelain, thrombin), Lipid-degrading enzymes (lipase, lipopolysaccharide lipase), oxygenase (monooxygenase) , peroxidase), enzymes related to energy metabolism, DNA polymerase, RNA polymerase Enzymes, nucleases, aminoacyl-tRNA synthetases, kinases ), dephosphorylating enzymes (phosphatases), glycosyltransferases, DNA methylases The cutinase-like enzyme produced by a microorganism is added to the culture medium of the microorganism. It may be used in the form of a culture filtrate, or it may be isolated and purified therefrom. The microorganisms that produce the enzyme-like enzyme are not particularly limited, but include, for example, pseudomonas aeruginosa, Pseudozyma and Moesziomyces , Paraphoma genus, Cryptococcus s), Mucor, Humicola, Thermomyces ( Thermomyces, Talaromyces, Chaetomium (Chaetomium), Torula, Sporo trichum), Malbranchea, and Alternaria lternaria, Cladosporium, Penicillium Genus Penicillium, genus Paecilomyces, Pseudomonas, Bacteroides Examples of cutinase-like enzymes include those from the genus Acidovorax and the genus Acidovorax. As the enzyme, for example, Pseudozyma antarctica (Pseudoz Paraforma spp., esterase (PaE) produced by Paraforma antarctica Periphyton cutinase-like enzyme (PCLE) and Cryptococcus magnus (Crypto Cutinase-like enzyme 1 (C) produced by Coccus magnus or its related fungi For example, the pH of a 1% aqueous solution is 5 or less, 0 or more, 7 or more, 11 or less, etc. It is desirable to use an enzyme derived from at least one microorganism that is highly active under these conditions. Enzymes can be used singly or in combination of two or more types as required. By including the enzyme (c) in the composition according to any one of [1] to [5], For example, it decomposes the cuticle layer (the covering of the insect body), denatures the skeleton and cells of pests, and disrupts internal functions. It can enhance killing activity by affecting metabolism, internal balance, and depriving necessary elements.
[0079] [(d): Microbial materials] (d) Microbial materials, for example, those having a pest control effect (e.g., insecticidal activity, (e.g., miticidal, nematicidal, fungicidal, herbicidal, etc.) or plant growth regulators such as rhizobia and mycorrhizal fungi A group of microbial materials (including proteins produced by microorganisms) that have regulating effects can be cited. .
[0080] (d) A device capable of combining the microbial material with the present compositions Q, Q1, Q2, X, Y and Z. Examples include Abreviata caucasica, Acua spp. ria spp.), Agamermis decaudata, Agrobacterium Agrobacterium radiobacter strain K1026 Agrobacterium radiobacter strain K84, Agrobacterium Agrobacterium vitis strain VAR03-1, Allantonema spp. tonema spp., Alternaria destruens strain 59, Alternaria destruens, Ampelomyces quiscalis A Q10 strain (Ampelomyces quisqualis strain AQ10), Amphimermis spp. .), Arthrobotrys dactyloides, Arthrobotrys Arthrobotrys superba, Ashersonia alba eyrodes, Aspergillus flavus strain AF36, Aspergillus Aspergillus flavus strain NRRL21882, Aureo Aureobasidium pullulans strain DSM14940, Aureobasidium pullulans strain DSM14941, Azopirillum, Azorhizobium kaurinodans ZB-SK-5 strain uma caulinodans strain ZB-SK-5), Azotobacter crococcum strain H23 chroococcum strain H23, Azotobacter chroocuccum , Azotobacter cyst, Azotobacter vinelandii ATCC12837 Azotobacter vinelandii strain ATCC12837, Azotobacter, wasp Bacillus acidocaldarius, Bacillus acidocaldarius (Bacillus acidoterrestris), Bacillus Albolactis, Bacillus alcalophilus, Bacillus alvei alvei), Bacillus aminoglucosidicus, Bacillus Bacillus aminovorans, Bacillus amyloliquefaciens (Aveo ( Trademark) EZ Nematicide)(Bacillus amyloliquefaciens (Aveo (trademark) EZ Nematicide)), Bacillus amyloliquefaciens strain AT332 , Bacillus amyloliquefaciens strain B3, Bacillus amyloliquefaciens strain D747 , Bacillus amyloliquefaciens strain DB10 1), Bacillus amyloliquefaciens strain DB102 (Bacillus amyloliquefaciens strain D B102), Bacillus amyloliquefaciens FZB24 strain (Bacillus amyloliquefaciens strain n FZB24), Bacillus amyloliquefaciens strain FZB42 (Bacillus amyloliquefaciens st rain FZB42), Bacillus amyloliquefaciens strain GB03 strain GB03), Bacillus amyloliquefaciens strain IN937a ns strain IN937a), Bacillus amyloliquefaciens strain MBI600 (Bacillus amylolique faciens strain MBI600, Bacillus amyloliquefaciens strain QST713 liquefaciens strain QST713), Bacillus amyloliquefaciens isolate B246 (Bacil Bacillus amyloliquefaciens isolate strain B246, Bacillus amyloliquefaciens F72 7 strains (Bacillus amyloliquefaciens strain F727), Bacillus amyloliquefaciens Bacillus amyloliquefaciens subsp. Plantarum strain D747 , Bacillus amylolyticus , Bacillus aneurysmal Bacillus aneurinolyticus, Bacillus agri, Bacillus Bacillus atrophaeus, Bacillus azotoformans otoformans), Bacillus badius, Bacillus cereus strain BP01 (B Bacillus cereus strain BP01, Bacillus cereus CNCM I-1562 strain CM strain I-1562), Bacillus chitinosporus strain AQ746 (Bacillus chitinosporus strain n AQ746), Bacillus chitinosporus strain CM-1, Bacillus circulans, Bacillus coagulans TQ33 strain (Ba Bacillus coagulans strain TQ33, Bacillus fastidiosus sus), Bacillus firmus strain GB-126, Bacillus Bacillus firmus strain I-1582, Bacillus lacticola lus lacticola), Bacillus lactimorbus, Bacillus lactimorbus Bacillus lactis, Bacillus lautus, Bacillus lentis Bacillus Lentimorbus, Bacillus lentus, Bacillus Bacillus licheniformis strain FMCH001, Bacillus Bacillus licheniformis strain HB-2, Bacillus licheniformis Bacillus licheniformis strain SB3086, Bacillus maloccanus cillus maroccanus, Bacillus medusa, Bacillus megateriu Bacillus megaterium strain YFM3.25, Bacillus methylotrophicus BA Bacillus methylotrophicus strain BAC-9912, Bacillus metiens lus metiens, Bacillus mojavensis strain SR11 , Bacillus mycoides strain AQ726, Bacillus mycoides Bacillus mycoides isolate J, Bacillus nematocida atocida), Bacillus nigrificans, Bacillus nigrum (Bacillus nigrum), Bacillus popilliae, Bacillus cyclo Bacillus psychrosaccharolyticus, Bacillus pumilus AQ717 strain (Ba Bacillus pumilus strain AQ717, Bacillus pumilus strain BUF-33 n BUF-33), Bacillus pumilus strain GB34, Bacillus Bacillus pumilus strain QST2808, Bacillus thiamensis Bacillus siamensis, Bacillus simplex strain CGF2856 F2856), Bacillus smithii, Bacillus sp. AQ175 strain (Bacillus sp. strain AQ175), Bacillus sp. strain AQ177, Bacillus sp. AQ Bacillus sp. strain AQ178, Bacillus sphaericus strain 2362 Bacillus sphaericus strain 2362, Bacillus sphaericus strain ABTS1743 in ABTS1743), Bacillus sphaericus serotype H5a5b strain (Bacillus sphaericus Serotype e strain H5a5b), Bacillus subtilis strain AQ153, Bacillus subtilis strain AQ743, Bacillus subtilis Bacillus subtilis strain C-3102, Bacillus subtilis strain D747 s subtilis strain D747, Bacillus subtilis strain DB101 B101), Bacillus subtilis strain FMCH002, Bacillus Bacillus subtilis strain FZB24, Bacillus subtilis GB03 Bacillus subtilis strain GB03, Bacillus subtilis strain HAI0404 lis strain HAI0404), Bacillus subtilis strain IAB / BS03 (Bacillus subtilis strain IA B / BS03), Bacillus subtilis strain MBI600, Bacillus Bacillus subtilis strain QST30002 / AQ30002, Bacillus subtilis strain QST30004 / AQ30004 , Bacillus subtilis strain QST713, Bacillus subtilis Bacillus subtilis strain QST714, Bacillus subtilis var amylo Bacillus subtilis var. Amyloliquefaciens strain FZB24 , Bacillus subtilis strain Y1336, Bacillus subtilis Bacillus subtillis subsp. natto, Bacillus tecuilensis NII -0943 strain (Bacillus tequilensis strain NII-0943), Bacillus thuringiensis AQ52 strain (Bacillus thuringiensis strain AQ52), Bacillus thuringiensis strain BD#32 (Bac Bacillus thuringiensis strain BD#32, Bacillus thuringiensis strain CR-371 s thuringiensis strain CR-371), Bacillus thuringiensis strain EX297512 (Bacillus thuringiensis strain EX297512), Bacillus thuringiensis Aizawai subspecies AB TS-1857 strain (Bacillus thuringiensis subsp. Aizawai strain ABTS-1857), Bacillus thuringiensis Bacillus thuringiensis subsp. Aizawai strain GC-91 rain GC-91), Bacillus thuringiensis Aizawai subspecies Serotype H-7 (Bacillus thuringiensis subsp. Aizawai Serotype H-7), Bacillus thuringiensis Bacillus thuringiensis subsp. Kurstaki strain ABTS351, Bacillus thuringiensis subsp. chrystachii strain BMP123 bsp. Kurstaki strain BMP123), Bacillus thuringiensis kurstaki subsp. EG2 34 strain (Bacillus thuringiensis subsp. Kurstaki strain EG234), Bacillus thuringiensis Bacillus thuringiensis subsp. Kurstaki strain EG7841 EG7841), Bacillus thuringiensis chrystachii subspecies EVB113-19 strain (Bacillus th uringiensis subsp. Kurstaki strain EVB113-19), Bacillus thuringiensis k Bacillus thuringiensis subsp. Kurstaki strain F810, Bacillus thuringiensis subsp. K urstaki strain HD-1), Bacillus thuringiensis chrystaki subsp. strain PB54 (Baci Bacillus thuringiensis subsp. Kurstaki strain PB54), Bacillus thuringiensis Bacillus thuringiensis subsp. Kurstaki strain SA-11, Bacillus thuringiensis subsp. chrystachii SA-12 strain sp. Kurstaki strain SA-12), Bacillus thuringiensis subsp. Morrisonii (Bacillus thuringiensis subsp. morrisoni), Bacillus thuringiensis tenebrionis Bacillus thuringiensis subsp. Tenebriosis strain NB 176, Bacillus Bacillus thuringiensis subsp. thuringiensis MPPL002 strain sp. Thuringiensis strain MPPL002), Bacillus thuringiensis var. columelli (B acillus thuringiensis subsp. var. colmeri), Bacillus thuringiensis da mustadiensis var. 24-91 strain (Bacillus thuringiensis subsp. var. darmstadiensis strain 24-91), Bacillus thuringiensis var. dendrolimus (Bacillus thuringiensis giensis subsp. var. dendrolimus), Bacillus thuringiensis var. galleria (Ba cillus thuringiensis subsp. var. galleriae), Bacillus thuringiensis is Bacillus thuringiensis subsp. israelensis strain BMP144 ), Bacillus thuringiensis israelensis subspecies AM65-52 strain (Bacillus thuringiensis giensis subsp. israelensis strain AM65-52), Bacillus thuringiensis Bacillus thuringiensis subsp. var. japonensis strain buibui ui), Bacillus thuringiensis Bacillus thuringiensis subsp. var. aegypti, Bacillus Bacillus thuringiensis var. 7216, Bacillus thuringiensis Bacillus thuringiensis var. sandiego strain M-7 M-7), Bacillus thuringiensis var. T36, BT BT crop protein Cry1Ab, BT crop protein Cry1Ac rop protein Cry1Ac), BT crop protein Cry1Fa (BT crop protein Cry1Fa), BT crop BT crop protein Cry1A.105, BT crop protein Cry2Ab crop protein Cry2Ab), BT crop protein Vip3A (BT crop protein Vip3A), BT crop Protein mCry3A (BT crop protein Cry3A), protein Cry3Ab (BT crop protein Cry3Ab), BT crop protein Cry3Bb (BT crop protein Cry3Bb), BT crop protein Cry3Bb Bacillus unicellularis (BT) crop protein Cry34Ab1 / Cry35Ab1 Bacillus uniflagellate, Bacillus uniflagellatus flagellatus), Bacillus velezensis, Bacillus spp.(bac teria spp.), bacteriophage of Clavobacter michiganesis ibacter michiganesis), Bacteriophage active against Xanthomonas campestris pv. vesicatoria and Pseudomonas syringae pv. tomato , Bacteriophage active against C lavibacter michiganensis subsp. michiganensis, Beauveria bassiana strain ANT-03 (B Beauveria bassiana strain ANT-03, Beauveria bassiana strain ATCC74040 (Beauveria b assiana strain ATCC74040), Beauveria bassiana GHA strain (Beauveria bassiana strain n GHA), Beauveria bassiana strain PPRI 5339 , Beauveria bassiana strain IMI1389521, Beauveria brongniartii, Bedd ingia siridicola, Bovienema spp., Brevibacillus brevis 290 4 strain (Brevibacillus brevis strain 2904), Brevibacillus brevis strain SS86-3 (Breviba Brevibacillus brevis strain SS86-3, Brevibacillus brevis strain SS86-4 evis strain SS86-4, Brevibacillus brevis strain SS86-5 in SS86-5), Brevibacillus laterosporus ATCC64 strain (Brevibacillus laterosporus s train ATCC64), Brevibacillus laterosporus BPM3 strain strain BPM3), Brevibacillus laterosporus strain G4 (Brevibacillus laterosporus str ain G4), Brevibacillus laterosporus NCIMB 41419 strain NCIMB 41419, Brevibacillus laterosporus strain NRS1111 (Brevibacillus lat Brevibacillus laterosporus strain NRS1111, Brevibacillus laterosporus strain NRS1645 s laterosporus strain NRS1645), Burkholderia cepacia Wisconsin type J82 strain (Burkholderia cepacia type Wisconsin strain J82), Burkholderia cepacia Burkholderia cepacia type Wisconsin strain M54, Burkholderia cepacia Burkholderia cepacia, Burkholderia gladii strain BA-7 ( Burkholderia gladii strain BA-7, Burkholderia linogensis strain A396 lderia rinojensis strain A396), Cameronia spp., Dianthus Canadian thistle fungus, Candida oleophila strain O phila strain O), Candida saitoana, Candida spp. spp.), Chaetomium cupreum, Chitowoodiella obophii lamenta (Chitwoodiella ovofilamenta), Chromobacterium subtsugae PRAA4-1T strain ( Chromobacterium subtsugae strain PRAA4-1T), Cladosporium cladosporioi Cladosporium cladosporioides strain H39, Clonostachys rosea ostachys rosea), Conidiobolus obscurus, Conidiobolus Coniothyrium minitans strain CGMCC8325, Coniothyrium Coniothyrium minitans strain CON / M / 91-08, Contortylenchus spp., Cryptococcus albidus (cr yptococcus albidus, Culicimermis spp., Dactylella ellips Dactyllela ellipsospora, Decylaria thaumasi a) Delftia acidovorans strain RAY209, Dilophosphora alopecuri, Diplotriaena spp. iaena spp.), Empidomermis spp., Entomophthora virulence Entomophthora virulenta, Erwinia carotovora subsp. carotovora CGE234M4 03 strain (Erwinia carotovora subsp. carotovora strain CGE234M403), Philippi shrimpel Miss Leipsandra (Filipjevimermis leipsandra), Fusarium oxysporum Fo4 7 strain (Fusarium oxysporum strain Fo47), Fusarium oxysporum strain RS-21 (Fusarium oxysporum strain RS-21, Fusarium oxysporum strain RS-25 strain RS-25), Fusarium proliferatum, Gastrome Gastromermis spp., Gliocladium catenulatum strain J1446 ium catenulatum strain J1446), Gluconacetobacter diazotrophicus (gluco nacetobacter diazotrophicus, Gongylonema spp., Gynopoecili Gynopoecilia pseudovipara, Harpin protein n), Heterorhabditis bacteriophora, He Heterorhabditis baujardi, Heterorhabditis Heterorhabditis heliothidis, Heterorhabditis inde Heterorhabditis indica, Heterorhabditis malleratus marelatus), Heterorhabditis megidis, Heterorhabditis Heterorhabditis zealandica, Hexamermis spp. Hexamermis spp., Hirsutella minnesotensis, Hirsutella Hirsutella rsiliensis, Hirsutell thompsonii a thompsonii), Hydromermis spp., Isaria fumosorosea ( Isaria fumosorosea, Isomermis spp., Lactobacillus acidophilus Lactobacillus acidophilus, Lactobacillus brevis vis), Lactobacillus plantarum, Lactobacillus spp .(Lactobacillus spp.), Lagenidium giganteum, Reca Lecanicillium lecanii KV01 strain (Lecanicillium lecanii KV01), Lecanicillium lecanii DAO Conidia of strain M198499 (Lecanicillium lecanii conidia of strain DAOM198499) Conidia of strain DAOM216596 (Lecanicillium lecanii conidia of strain DAOM2 16596), Lecanicillium muscarium strain Ve6 (Lecanicillium muscarium (formerly Vertic illium lecanii strain Ve6), Limnomermis spp., Lysobacter Lysobacter antibioticus strain 13-1, Lysobacter Lysobacter enzymogenes strain C3, Maupasina weissii upasina weissi), Mermis nigrescens, Mesomermis sp. p.(Mesomermis spp.), Metarhizium anisopliae F52 strain(Metarhizium anisopliae s train F52), Metarhizium anisopliae acridum var. var. acridum), Metarhizium anisopriae anisopriae var. BIPESCO 5 / F52 strain (Metarhizium anisopliae var. anisopliae BIPESCO 5 / F52), Metarhizium flavobi Metarhizium flavoviride, Metschnikowia dimer um), Metschnikowia fructicola strain NR RRLY-30752 (Metschnikowia fructicola strain NR RLY-30752), Microsphaeropsis ochracea, Mo Monacrosporium phymatopagum, Mucor hiema Squirrel (Mucor hiemalis), Muscodor albus strain 620, Muscodor albus strain QST 20799 Muscodor albus strain SA13, Muscodor roseus strain A3-5 oseus strain A3-5), Myrothecium verrucaria strain AARC-0255 (Myrothecium verrucaria strain AARC-0255), Neomesomermis spp., Neoparasitylene Neoparasitylenchus rugulosi, Nomuraea lily CG128 strain rileyi strain CG128), Nomuraea rileyi strain GU87401 (Nomuraea rileyi strain GU874 01), Nomuraea rileyi strain SA86101, Nomuraea Nomuraea rileyi strain SR86151, Nomuraea rileyi strain VA9101 uraea rileyi strain VA9101, Nosema locustae, Octomaio Octomyomermis spp., Ophiostoma pyriferum D97 strain (Ophiostoma piliferum strain D97), P. fumosoroseus Apopka 97 strain (currently Isaria Paecilomyces fumosoroseus Apopka 97 (also known as Paecilomyces fumosoroseus Apopka 97) train 97NowIsaria fumosorosea Apopka strain 97), Pekylomyces lilacinus 251 strain (Paecilomyces lilacinus strain 251), Paecilomyces tenuipes strain T1 (Paecilomy ces tenuipes strain T1), Paecilomyces variotii strain Q-09 (Paecilomyces variotii ii strain Q-09), Paenibacillus alvei strain 2771 ), Paenibacillus alvei strain 46C3, Paenibacillus alvei Paenibacillus alvei strain III2E Paenibacillus alvei strain III3DT-1A, Paenibacillus alvei T3 6 strain (Paenibacillus alvei strain T36), Paenibacillus macerans (Paenibacillus macerans, Paenibacillus polymyxa strain AC-1 ), Paenibacillus polymyxa strain BS-0105 , Paenibacillus popilliae, Pandora delphaci ndora delphacis, Pantoea agglomerans strain E325 325), Pantoea vagans strain C9-1, Paracytaphe Parasitaphelenchus spp., Parasitor habditis spp.), Parasitylenchus spp., Pasteuria Pasteuria nishizawae strain Pn1, Pasteuria penetrans (Pa steuria penetrans), Pasteuria ramose, Pasteuria usu Pasteuria usgae, Pectobacterium carotovorum rum), Penicillium bilaiae strain ATCC22348 , Penicillium citrinum strain VFI-51, Penicillium Penicillium vermiculatum, Pertilimermis cucumis Perutilimermis culicis, Pasteuria thoynei, Phasmarhabditis hermaphrodita, Ferret Biopsis gigantea Phlebiopsis gigantea strain VRA1992, Physaloptera spp. ra spp.), Phytophthora palmivora, Pichia anomala WR Pichia anomala strain WRL-076, Pichia guillermonde Z1 strain iermondii strain Z1), Pichia guilliermondii strain Z8 8), Pochonia chlamydosporia isolate strain PC10 (Pochonia chlamydosporia isolate strain in PC10), Pochonia chlamydosporia, Protrelatus s pp. (Protrellatus spp.), Pseudomonas aeruginosa strain PN1 (Pseudomonas aeruginos a strain PN1), Pseudomonas aeruginosa strain WS-1 WS-1), Pseudomonas aureofaciens strain TX-1 (Pseudomonas aureofaciens str ain TX-1), Pseudomonas cepacia Wisconsin type J82 strain sconsin strain J82, Pseudomonas cepacia Wisconsin type M54 strain ia type Wisconsin strain M54), Pseudomonas chlororaphis strain 63-28 (Pseudomona s chlororaphis strain 63-28), Pseudomonas chlororaphis strain AFS009 (Pseudomona s chlororaphis strain AFS009), Pseudomonas chlororaphis strain MA342 (Pseudomona chlororaphis strain MA342, Pseudomonas fluorescens strain 1629RS Pseudomonas fluorescens strain 1629RS, Pseudomonas fluorescens strain A506 Pseudomonas fluorescens strain A506, Pseudomonas fluorescens strain CL145A Pseudomonas fluorescens strain CL145A, Pseudomonas fluorescens strain G7090 Pseudomonas fluorescens strain G7090), Pseudomonas fluorescens biover B strain XJ3 ( Pseudomonas fluorescens biover B strain XJ3) Pseudomonas fluorescens biover B strain XS18, Pseudomonas Pseudomonas fluorescens biover A strain LRS12 , Pseudomonas proradix , Pseudomonas putida ( Pseudomonas putida, Pseudomonas reactans, Pseudomonas resinovorans, Pseudomonas rhodesiae HA I-0804 strain (Pseudomonas rhodesiae strain HAI-0804), Pseudomonas sp. CAB-02 strain (Pseudomonas sp. Pseudomonas sp. strain CAB-02, Pseudomonas syringae strain 742RS gae strain 742RS, Pseudomonas syringae strain MA-4 MA-4), Pseudozyma flocculosa strain PF-A22UL (Pseudozyma flocculosa strain P F-A22UL), Pterygodermatites spp., Puccinia sera Puccinia thlaspeos strain woad, Purpureoscillium lilacinum ( Purpureocillium lilacinum), Pythium oligandrum DV74 strain (Pythium oligandrum s train DV74), Pythium oligandrum strain M1, Rhodo Rhodococcus globerulus strain AQ719, Romanomer Romanomermis spp., Saccharomyces cerevisiae LASO2 strain cerevisiae strain LASO2), Saccharomyces cerevisiae strain DDSF623 (saccharomyces c erevisiae strain DDSF623, Sclerotinia minor strain IMI34414 strain IMI34414), Serratia entomophila, Serratia Serratia marcescens strain 35, Serratia marcescens SRM strain (Se rratia marcescens strain SRM), Seuratum cadarachense ,,Sphaerulariopsis spp., Spirula gayanensis ( Spirura guianensis, Sporothrix insectorum, Steinernema bibionis, Steinernema carpocapsae Steinernema carpocapsae, Steinernema feltiae, Steinernema glaseri, Steinernema classii ernema kraussei), Steinernema riobrave, Steiner Steinernema scapterisci, Steinernema scarabaei inernema scarabaei), Steinernema siamkayai, Steinernema spp., Strelkovim ptersenii ermis peterseni), Streptomyces acidiscaviae strain RL-110T (Streptomyces ac idiscabies strain RL-110T), Streptomyces candidus strain Y21007-2 Streptomyces candidus strain Y21007-2, Streptomyces columbiensis es colombiensis), Streptomyces galbus strain QST6047 (Streptomyces galbus str ain QST6047), Streptomyces goshikiensis, Streptomyces griseoviridis strain K61 , Streptomyces lavendulae, Streptomyces Streptomyces lydicus strain WYCD108US, Streptomyces Streptomyces lydicus strain WYEC108, Streptomyces Streptomyces prasinus, Streptomyces rimosus rimosus, Streptomyces saraceticus, Streptomyces Streptomyces sp. strain NRRL No. B-30145, Streptomyces sp. strain WYE20, Streptomyces Streptomyces sp. strain WYE 324, Streptomyces venezuelae (S treptomyces venezuelae), Subulura spp., Salpletilencus Sulphuretylenchus elongatus, Talaromyces flavus SAY-Y-94-0 1 strain (Talaromyces flavus strain SAY-Y-94-01), Talaromyces flavus V117b strain (Tal aromyces flavus strain V117b), Tetrameres spp., Telochania spp. Thelohania solenopsis, Thiobacillus spp., and birds Trichoderma album, Trichoderma aspereroides JM41R strain (Tr Trichoderma asperelloides strain JM41R, Trichoderma asperellum strain ICC012 (Trich oderma asperellum strain ICC012), Trichoderma asperellum strain T25 (Trichoderma a sperellum T25), Trichoderma asperellum strain T34 (Trichoderma asperellum strain T 34), Trichoderma asperellum strain SKT-1, Trichoderma asperellum strain TV1, Trichoderma Trichoderma atroviride strain CNCM 1-1237, Trichoderma atroviride Trichoderma atroviride strain LC52, Trichoderma Trichoderma atroviride strain IMI 206040, Trichoderma Trichoderma atroviride strain SC1, Trichoderma atroviride Trichoderma atroviride strain SKT-1, Trichoderma atroviride Trichoderma atroviride strain T11, Trichoderma gammii strain ICC080 hoderma gamsii strain ICC080), Trichoderma harzianum strain 21 (Trichoderma harzi anum strain 21), Trichoderma harzianum DB 104 strain (Trichoderma harzianum strain n DB 104), Trichoderma harzianum strain DSM 14944 SM 14944), Trichoderma harzianum strain ESALQ-1303 ESALQ-1303), Trichoderma harzianum strain ESALQ-1306 (Trichoderma harzianum strain n ESALQ-1306), Trichoderma harzianum IIHR-Th-2 strain (Trichoderma harzianum stra in IIHR-Th-2), Trichoderma harzianum strain ITEM908 ITEM908), Trichoderma harzianum strain kd, Trichoderma harzianum strain MO1, Trichoderma Trichoderma harzianum strain SF, Trichoderma harzianum T2 2 strain (Trichoderma harzianum strain T22), Trichoderma harzianum strain T39 (Trichoderma rma harzianum strain T39, Trichoderma harzianum strain T78 m strain T78), Trichoderma harzianum strain TH35 35), Trichoderma harzianum rifai, Trichoderma Trichoderma koningii, Trichoderma lignorum gnorum), Trichoderma polysporum strain IMI206039 I206039), Trichoderma spp., Trichoderma stromaticum choderma stromaticum, Trichoderma virens strain G-41 -41), Trichoderma virens strain GL-21 (formaly Glio cladium virens GL-21), Trichoderma viride, Tsukamurella Paulometabola (Tsukamurella paurometabola), Typhula phacorizae strain 94671 (Typhula la phacorrhiza strain 94671), Ulocladium oudemansii strain HRU3 (Ulocladium oudemansii udemansii strain HRU3), Vairimorpha spp. strain Q-09 , Variovorax paradoxus strain GF4526, Verticillium alboatrum strain WCS850, Verticillium chlamydosporium, Verticillium Verticillium dahliae, Verticillium lecanii strain NCIM1312 illium lecani strain NCIM1312), Birgibacillus pantothenicus strain ATCC14576 (Vi Birgibacillus pantothenticus strain ATCC14576), Birgibacillus pantothenticus D Virgibacillus pantothenticus strain DSM491, Xanthomonas campestris Xanthomonas campestris pv poae, Xanthomonas campestris (X anthomonas campestris, Xenorhabdus luminescens , Xenorhabdus nematophila , Zooftora radicans (Zoophtora radicans), Adoxophyes orana granulosis virus BV-0001 strain (Adoxophyes es orana granulosis virus strain BV-0001), Agrotis segeetum nuclear polyhedrosis virus Rus (Agrotis segetum nuclear polyhedrosis virus (NPV)), Anagraoha falcifera nuclear polyhedrosis Anagraoha falcifera NPV, Anticarcia gemataris nucleopolyhedrovirus Anticarsia gemmatalis mNPV, Autographa californica nuclear polyhedrosis virus Autographa californica mNPV, Biston suppressoria nuclear polyhedrosis virus (Biston suppressaria NPV), Bombyx mori nuclear polyhedrosis virus (Bombyx mori NPV) ), Cryptophlebia leucotreta granulosis virus (Cryptophlebia leucotreta GV), Cydia pomonella granulosis virus strain V15 (Cydia pomonella GV strain V15) Monera granulosis virus V22 strain (Cydia pomonella GV strain V22), Dendrolimus pneumoniae Dendrolimus punctatus cypovirus, Helicoverpa a Helicoverpa armigera NPV strain BV-0003, Helicoverpa zea nuclear polyhedrosis virus (Helicoverpa zea NPV), Leucoma salicys Leucoma salicis NPV, Rhymantria dispar NPV Lymantria dispar NPV, Mamestra brassicae nuclear polyhedrosis virus brassicae NPV), Mamestra Mamestra configurata nuclear polyhedrosis virus (NPV), Neodiprion Neodiprion abietis NPV), Neodiprion Neodiprion lecontei nuclear polyhedrosis virus (Neodiprion lecontei NPV), Neodiprion cells Neodiprion nuclear polyhedrosis virus (NPV), Orgyia pseudotuberculosis Orgyia pseudotsugata NPV, Pepino mosaic virus C Pepino mosaic virus strain CH2 isolate 1906, Putolimaea operculata Phthorimaea operculella granulosis virus (GV), Pieris rapae granulosis Virus (Pieris rapae GV), Plodia interpunctella granulosis virus (Plodia i interpunctella GV), Plutella xylostella granulosis virus (Plutella xylostella GV) ), Plutella xylostella GV, Spodoptera albula nucleopolysaccharide Spodoptera albula mNPV) and Spodoptera exempta nuclear polyhedrosis virus Spodoptera exempta mNPV, Spodoptera exempta nucleopolyhedrovirus BV-00 04 strain (Spodoptera exigua mNPV strain BV-0004), Spodoptera frugiperta nucleopolyhedron Spodoptera frugiperda mNPV, Spodoptera littoralis nucleopolyhedrovirus virus (Spodoptera littoralis mNPV), Spodoptera littoralis nuclear polyhedrosis virus (Spod optera litura NPV), Tobacco mild green tobamovirus U2 strain (Tobacco mild tobamovirus strain U2), Zucchini yellow mosaic virus weak strain (Zucchini Yellow Mosaik Virus weak strain), Acaulospora spp., Ambispora Ambispora spp., Archaeospora spp., Claroideogro Mus species (Claroideoglomus spp. formerly Glomus spp.), Claroideoglomus etuni Glomus etunicatum (formerly Claroideoglomus etunicatum) Claroideoglomus claroideum (formerly Glomus claroideum), diver Diversispora spp., Entrophospora spp., Fanneliformis spp. (formerly Glomus spp.), Fanneliformis Mosseae (Funneliformis mosseae, formerly Glomus mosseae), Geosiphon species on spp.), Gigaspora spp., Gigaspora margarita argarita), Gigaspora rosea, Glomus spp., Glomus spp. Glomus aggregatum, Glomus desert icola, Glomus monosporum, Pacispora sp. p.), Paraglomus spp., Paraglomus brasilianum s brasillianum (formerly Glomus brasillianum), Racocetra spp., Rai Rhizophagus spp. (formerly Glomus spp.), Rhizophagus claus ( Rhizophagus clarus (formerly Glomus clarum), Rhizophagus intraradicis (Rhiz Rhizophagus intraradices (formerly Glomus intraradices), Rhizophagus intraradices RTI-801 strain, Rhizophagus irregularis (formerly Glom us intraradices), Rhizophagus irregularis strain DAOM 197198 (Rhizophagus irregularis ularis strain DAOM 197198), Scutellospora spp., Azorhizobi Azorhizobium spp., Azorhizobium caulinodans odans), Azospirillum amazonense, Azospirillum Azospirillum brasilense, Azospirillum brasilense XOH strain (Azo spirillum brasilense strain XOH), Azospirillum brasilense strain Ab-V5 (Azospiri Azospirillum brasilense strain Ab-V5) and Azospirillum brasilense strain Ab-V6 m brasilense strain Ab-V6), Azospirillum caulinodans dans), Azospirillum halopraeferens, Azo Azospirillum irakense, Azospirillum lipoferrum spirillum lipoferum, Bradyrhizobium spp., Bradyrhizobium Bradyrhizobium elkanii, Bradyrhizobium elkanii SEMIA Bradyrhizobium elkanii strain SEMIA 587, Bradyrhizobium elkanii SE Bradyrhizobium elkanii strain SEMIA 5019, Bradyrhizobium japonica Bradyrhizobium japonicum, Bradyrhizobium japonicum strain TA-11 (Br Bradyrhizobium japonicum strain TA-11), Bradyrhizobium japonicum USDA 110 Bradyrhizobium japonicum strain USDA 110, Bradyrhizobium liaoninge Bradyrhizobium liaoningense, Bradyrhizobium lupini pini), Bradyrhizobium sp. (Arachis), Bradyrhizobium sp. (Arachis) Bradyrhizobium sp. (Vigna), Delftia acidovora Delftia acidovorans, Delftia acidovorans strain RAY209 rans strain RAY209), Methylobacterium spp., Mesorhizobium Mesorhizobium ciceri, Mesorhizobium huak ii) Mesorhizobium loti, Mesorhizobium spp.), Rhizobium etli, Rhizobium gale gae), Rhizobium leguminosarum bv. phaseoli (Rhizobium leguminosarum bv. Phas eoli), Rhizobium leguminosarum bv. Trifo lii), Rhizobium leguminosarum bv. Viciae ), Rhizobium trifolii, Rhizobium tropisi opici), Sinorhizobium fredii, Sinorhizobium melilo Others, additive bacteria (food, industry, agriculture, horticulture, etc.), food (natto bacteria, fermentation, etc.), cleaning (detergent At least one or two or more kinds of bacteria selected from bacteria used in the production, etc. The above can be combined. Preferably, the hydrophilic and modified nature of the composition of the present invention is characterized by It is desirable to combine the above ingredients in a way that does not interfere with the effects of the above ingredients.
[0081] The component selected from the microbial materials of (d) is usually prepared by a culture method known in the art. For example, when the component selected from the microbial materials in (d) is a bacterium or a fungus, The composition is prepared using a culture medium and a fermentation method known in the art. The preparation contains 1×10 4 to 1×10 13 CFU (colony forming units) per gram, preferably contains 1 x 108 to 1 x 1012 CFU of the component. If the component is a virus, The substance has 1×104 to 1×1013 occlurion bodies (Obs) per gram. Preferably, 1×10 8 to 1×10 12 occlurion bodies (referred to as Obs) are used. If the ingredient is a nematode, the preparation contains 1 The amount of the component is 1×10 to 1×10, preferably 1×10 to 1×10. By including the microbial material (d) in the composition according to any one of [1] to [5], for example, It decomposes the trichomes (insect coverings) and denatures the skeletons and cells of pests, affecting their internal functions, metabolism, and body functions. It can enhance the killing activity by depriving the plant of necessary elements and maintaining the internal balance. By disrupting the balance with living bacteria, the activity of symbiotic bacteria can be abnormally reduced or increased. At least one selected property can kill sap-sucking pests. It can also be decomposed by microorganisms.
[0082] [(e): insect pheromone] (e) The insect pheromone can be combined with the present compositions Q, Q1, Q2, X, Y and Z. A specific example is the pear scale insect (7-methyl-3-methylene-7-octenyl Propionate, (Z)-3,7-dimethyl-2,7-octadienyl propionate and (E)-3,7-dimethyl-2,7-octadienyl propionate; Fuji mealybug (2-isopropylidene-5-methyl-4-hexen-1-yl butyrate) ); Mulberry scale ((R,Z)-(+)-3,9-dimethyl-6-isopropenyl- 3,9-decadienyl propionate); Sable mealybug (2,2-dimethyl-3-(propan-2-ylidene)cyclobutyl)methyl 3-methylbut-2-enoate ((2,2-dimethyl-3-(propan-2-ylidene)cyclobutyl)methy l 3-methylbut-2-enoate); Two-striped mealybug (2,2-dimethyl-3-(propan-2-ylidene)cyclobutyl)methyl 3-methylbut-2-enoate ((2,2-dimethyl-3-(propan-2-ylidene)cyclobutyl)methy l 3-methylbut-2-enoate;) Matsumoto mealybug (3-methyl-3-butenyl 5-methylhexanoate); (E)-2-hexenal , (E)-2-octadecenal , (E)-4-tridecen-1-yl acetate , (E)-5-decen-1- yl acetate, (E)-5-decen-1-ol, (E)-3,3-dimethylcyclohexylideneacetaldehyde, (E )-7-dodecen-1-yl acetate, (E)-8-dodecen-1-yl acetate, (E)-9-dodecen-1-yl aceta te, (E)-10-hexadecenal, (E)-11-hexadecen-1-yl acetate, (E)-11-tetradecen-1-yl acetate, (E)-11-tetradecen-1-ol, (E)-4-tridecen-1-yl acetate, (E)-6-methylhe pt-2-en-4-ol 、(Z)-2-(3,3-dimethylcyclohexylidene)ethanol 、(Z)-4-decene-1-yl ace tate 、(Z)-4-tridecene-1-yl acetate 、(Z)-5-decene-1-yl acetate 、(Z)-5-decene-1-ol 、(Z)-7-tetradecenal 、(Z)-7-dodecene-1-yl acetate 、(Z)-8-dodecene-1-yl acetate 、(Z)-9-dodecene-1-yl acetate 、(Z)-8-dodecene-1-ol 、(Z)-9-hexadecenal 、(Z)-10-h exadecen-1-yl acetate 、(Z)-11-hexadecen-1-ol 、(Z)-11-hexadecenal 、(Z)-11-hexa decene-1-yl acetate 、(Z)-11-octadecenal 、(Z)-13-octadecenal 、(Z)-hexadec-13-ene -11-yn-1-yl acetate 、(Z)-13-octadecenal 、(Z)-icos-13-en-10-one 、(Z)-7-tetrade cenal 、(Z)-tetradec-9-en-1-ol 、(Z)-9-tetradecen-1-yl acetate 、(Z)-11-tetradec en-1-yl acetate 、(Z)-13-icosen-10-one 、(Z,E)-7,11-hexadecadiene-1-yl acetate 、 (Z,E)-9,12-tetradecadien-1-yl acetate 、(E,Z)-4,10-tetradecadien-1-yl acetate 、 (E,E)-8,10-dodecadiene-1-ol 、(E,E)-10,12-hexadecadienal 、(E,E)-9,11-tetradecadienal en-1-yl acetate 、(E,Z)-2,13-octadecadien-1-ol 、(E,Z)-3,13-octadecadien-1-ol 、 (E,Z)-2,13-octadecadien-1-yl acetate 、(E,Z)-3,13-octadecadien-1-yl acetate 、(E ,Z)-7,9-dodecadien-1-yl acetate 、(E,E)-7,9-dodecadien-1-yl acetate 、(Z,E)-9,12 -tetradecadien-1-yl acetate 、(Z,E)-9,11-tetradecadien-1-yl acetate 、(Z,E)-7,11 -hexadecadien-1-yl acetate 、(Z,Z)-3,13-octadecadien-1-ol 、(Z,Z)-4,7-decadien-1 -yl acetate 、(Z,Z)-3,13-octadecadien-1-yl acetate 、(Z,Z)-7,11-hexadecadien-1-y l acetate 、(Z,Z,E)-7,11,13-hexadecatrienal 、(5R)-5-[(1Z)-1-decen-1-yl]dihydro- 2(3H)-furanone 、(2R,5R)-ethyl-1,6-dioxaspiro[4,4]nonane 、(2R,5S)-ethyl-1,6-dio xaspiro[4,4]nonane 、(4R,8R)-4,8-dimethyldecanal 、(4R,8S)-4,8-dimethyldecanal 、2,4-dimethyl-5-ethyl-6,8-dioxabicyclo[3,2,1]octane 、(-)-4-methyl-3-heptanol 、1,7-dioxaspiro[5,5]undecane 、3-carene 、3-methylcyclohex-2-en-1-one 、14-meth yloctadec-1-ene 、4-methylnonan-5-ol 、4-methylnonan-5-one 、4-(3-oxobutyl)pheny l acetate 、dodecyl acetate 、dodeca-8,10-dien-1-yl acetate 、ethyl (2E,4Z)-deca dienoate 、ethyl 4-methyloctanoate 、methyl 2,6,10-trimethyldodecanoate 、tetrad ecan-1-ol 、tetradec-11-en-1-ol 、tetradec-11-en-1-yl acetate 、tridec-4-en-1-yl acetate 、(3S,6R)-3-methyl-6-isopropenyl-9-decen-1-yl acetate 、(3S,6S)-3-methy l-6-isopropenyl-9-decen-1-yl acetate 、alpha-multistriatin 、alpha-pinene 、endo -brevicomin 、exo-brevicomin 、camphene 、codlelure 、codlemone 、cuelure 、disp arlure 、dominicalure 、eugenol 、farnesol 、ferrolure 、frontalin 、gossyplure 、grandlure 、grandlure I 、grandlure II 、grandlure III 、grandlure IV 、hexalu re 、ipsdienol 、ipsenol 、japonilure 、lineatin 、litlue 、looplure 、medlure 、megatomoic acid 、methyl eugenol 、muscalure 、nerolidol 、orfralure 、oryctal ure, ostramone, rhyncolure, siglure, sordidin, sulcatol, trimedlure, trim edlure A, trimedlure B1, trimedlure B2, trimedlure C, trunc-call, (E)-verbe At least one member selected from the group consisting of (Z)-verbenol, trans-verbenol, (S)-verbenone, etc. Or two or more kinds can be combined. Preferably, the hydrophilic and modifiable composition of the present invention It is desirable to combine the above ingredients in a way that does not interfere with the effects characteristic of the drug. By adding the insect pheromone (e) to the composition according to any one of [1] to [5] above, For example, male pests are attracted to pheromone-like substances from female pests and then killed using tools and materials. (physical) to capture and kill them, (biological) to disrupt mating and reduce the population, and (fungi) to attract them. It is possible to increase the number of males by killing them with chemical pest control agents (chemical).
[0083] [(f): Plant growth regulator] (f) Plant growth regulators include, for example, plant growth regulators: ethylene agents, auxin agents , cytokinins, gibberellins, auxin antagonists, gibberellin biosynthesis inhibitors, etc. Classified as ancymidol, inabenfide, uniconazole, ethychlozate , paclobutrazol, flurprimidol, forchlorfenuron, mefluidide, etc. Examples include:
[0084] (f) The plant growth regulator can be combined with the present compositions Q, Q1, Q2, X, Y and Z. Specific examples include 1-methylcyclopropene, 1,3-diphenylurea, and 2,3,5-triiodobenzoic acid. acid, IAA ((1H-indol-3-yl)acetic acid), IBA (4-(1H-indol-3-yl)butyric acid) , MCPA (2-(4-chloro-2-methylphenoxy)acetic acid), MCPB (4-(4-chloro-2-methylphe (oxy)butyric acid), 4-CPA (4-chlorophenoxyacetic acid), 5-aminolevulinic acid hydrochloride, 6-benzylaminopurine, abscisic acid, AVG (aminoethoxyvinylglyci ne), ancymidol, butralin, calcium carbonate calcium carbonate, calcium chloride, calcium formate ), calcium peroxide, calcium polysulfide, calcium sulfate calcium sulfate, chlormequat chloride, chlor Chlorpropham, choline chloride, cloprop ), cyanamide, cyclanilide, cyprosulfamide sulfamide, daminozide, decan-1-ol, dichloro Dichlorprop, dikegulac, dimethipin, dichlorprop Diquat, ethephon, ethychlozate, chamomile Extract of Matricaria chamomilla, Flumetralin, Flurprimidol, forchlorfenuron, hormone Nonetin, Gibberellin A, Gibberellin A3 n A3), inabenfide, kinetin, lipoproteins ide MOR116, lipochitooligosaccharide SP104, maleic hydrazide ide), mefluidide, mepiquat chloride, methyl α-D-mannopyranoside (methyl-α-D-mannopyranoside), oxidized glutathione (oxidized ized glutathione, paclobutrazol, pendimethalin thalin), prohexandione-calcium, prohydrojasmo prohydrojasmon, pyraflufen-ethyl, sintophen fen), sodium 1-naphthaleneacetate, sodium cyanate sodium cyanate, streptomycin, thidiazuron ron), triapenthenol, tribufos, trinexapa Trinexapac-ethyl, Uniconazole-P, 2-(naphthalene 2-(naphthalen-1-yl)acetamide, [4-oxo-4-(2 -phenylethyl)amino]butyric acid, 5-(trifluoromethyl)benzo[b]thiophene -2-carboxylic acid methyl ester, 3-[(6-chloro-4-phenylquinazolin-2-yl)a [amino]propan-1-ol, strigolactone, (1E) )-1-[[1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-5-oxo-2H-pyrrol-2-yl]oxymethyl ene]-3,3a,4,8b-tetrahydroindeno[2,1-b]pyrrol-2-one, as described in WO 2018 / 145979 (2R)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-dihydro- 3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one, International Publication No. 2018 / 14597 (2S)-1-[3,5-bis(trifluoromethyl)phenyl]-4-methyl-2-[(E)-(2-oxo-4,8b-d a small amount selected from the group consisting of ihydro-3aH-indeno[2,1-b]furan-1-ylidene)methoxy]-2H-pyrrol-5-one, etc. At least one or a combination of two or more of the above may be used. It is desirable to combine the above ingredients in a way that does not interfere with the hydrophilic and denaturing effects. By adding the plant growth regulator (f) to the composition according to any one of [1] to [5] above, For example, to improve plant growth and increase resistance to pests (biological, chemical, physical), etc. It can accelerate ripening, thin fruit, flowers, and leaves, increase fruit sugar content, and has the effect of producing polyphenols. Increases beneficial ingredients, promotes fruit coloring, promotes flowering, promotes fruit abscission layer formation (for harvesting by plucking), Inhibits internode elongation, reduces lodging due to growth promotion effect, promotes germination, promotes root growth, and fertilizes roots (rhizomes). It has the effect of inhibiting growth (germination, rooting, leaf development) and root (rhizome) growth. It also has effects on germination, vegetative growth, flowering, flowering, fruiting, enlargement and coloring. The factors include pests, dryness, humidity, heat, cold, lack of sunlight, and nutrient deficiency. They can also act on plant cells, such as opening and closing stomata. Plant growth regulating hormones found in auxin, gibberellin, cytokinin, jasmonic acid, etc. For example, it has the effect of synergistically enhancing or suppressing growth-promoting effects. At least one of the properties selected from the above exhibits a synergistically excellent effect. do.
[0085] [(g): Herbicidal activator] (g) Herbicidal active agents include, for example, oxazinones, phenoxy acids, diphenyl ethers, ethers, carbamates, acid amides, ureas, sulfonyl ureas, triazines, Rasil, Diazine, Pirazole, Bipyridylium, Dinitroaniline, Fat They are classified into acid-based, organophosphorus-based, and amino acid-based compounds, and include 2,4-PA, CAT, CNP, and D BN, DCBN, DCMU, DCPA, DNBP, IPC, MCP, MCPB, MCPP , PAC, SAP, TCTP, ioxynil, atrazine, ametryn, alachlor , Isouron, Isoxaben, Imazosulfuron, Esprocarb, Oxadiazon, Quizalofop-ethyl, Orthobencarb, Carbutilate, Quizalofop-ethyl, Chlomethol Cinyl, Cyanazine, Dichlorprop, Dithiopyr, Siduron, Diphenamide, Zime Tametryn, Simetryn, Dimepiperate, Cinmethylin, Tarbacil, Dimron, De Smetrin, thenylchlor, triclopyr, trifluralin, naproanilide, naproxen Pamide, nitralin, vernolate, picloram, bifenox, piperophos, pyrazo Sulfuron ethyl, pyrazolate, pyridate, fenoxaprop ethyl, fenothione ol, phenmedipham, butachlor, butamifos, flazasulfuron, fluazifos butyl, fluthiacet methyl, pretilachlor, prodiamine, propazine, Propyzamide, Bromacil, Prometryne, Bromobutide, Hexylthiocarbamate, Bess Rosin, bensulfuron methyl, benzofenap, bentazone, benthiocarb, pen Dimethalin, Benfuresate, Methyldimethalon, Metolachlor, Mefenacet, Examples include molinate, linuron, and lenacil.
[0086] (g) A device capable of combining the herbicidal active agent with the present compositions Q, Q1, Q2, X, Y and Z Examples include 2,3,6-TBA (2,3,6-trichlorobenzoic acid), 2,3,6-TBA dimethylammonium 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2, 3,6-TBA potassium salt (2,3,6-TBA-potassium), 2,3,6-TBA sodium salt (2,3,6-TBA-sodium) , 2,4-D , 2,4-D choline salt , 2,4-D biproamine e), 2,4-D-doboxyl, 2,4-D 2-ethylhexyl yl), 2,4-D 3-butoxypropyl, 2,4-D ammonium D-ammonium, 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-di Ethylammonium (2,4-D-diethylammonium), 2,4-D dimethylammonium (2,4-D-dime thylammonium), 2,4-D diolamine salt (2,4-D-diolamine), 2,4-D dodecyl ammonium 2,4-D-dodecylammonium, 2,4-D-ethyl, 2,4-D-heptylammonium (2,4-D-heptylammonium), 2,4-D-isobutyl, 2,4-D-isooctyl -D-isooctyl), 2,4-D-isopropyl, 2,4-D-isopropylammonium 2,4-D-isopropylammonium, 2,4-D-lithium, 2,4-D-meptyl -D-mepty, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl 2,4-D-pentyl, 2,4-D-propyl, 2,4-D-sodium , 2,4-D-tefuryl, 2,4-D-tetradecylammonium ammonium), 2,4-D triethylammonium (2,4-D-triethylammonium), 2,4-D tris(2 -hydroxypropyl)ammonium (2,4-D-tris(2-hydroxypropyl)ammonium), 2,4-D tris(2-hydroxypropyl)ammonium 2,4-D-trolamine, 2,4-DB, 2,4-DB choline salt, 2,4-DB-biproamine, 2,4-DB-butyl, 2,4-DB-dimethyl 2,4-DB-dimethylammonium, 2,4-DB-isoctyl , 2,4-DB potassium salt (2,4-DB-potassium), 2,4-DB sodium salt (2,4-DB-sodium), acetonitrile Acetochlor, acifluorfen, acifluorfenna Acifluorfen-sodium, aclonifen, ACN (2-amino-3-chloro ronaphthalene-1,4-dione), alachlor, alloxydim, Metryn, amicarbazone, amidosulfuron n), aminocyclopyrachlor, aminocyclopyrachlor me Aminocyclopyrachlor-methyl, Aminocyclopyrachlor potassium salt pyrachlor-potassium, aminopyralid, aminopyralid choline salt aminopyralid choline salt, aminopyralid potassium salt, aminopyralid-tripromine, amiprophosmethyl hos-methyl), amitrole, anilofos, asulam , atrazine, azafenidin, azimsulfuron uron), beflubutamid, benazolin-ethyl, ben Bencarbazone, benfluralin, benfuresate ate), bensulfuron, bensulfuron-methyl, bensulide, bentazon, benthiocarb, benthiocarb benzfendizone, benzobicyclon, benzophena benzofenap, benzthiazuron, bialaphos s), bicyclopyrone, bifenox, bispyribac Spyribac, Bispyribac-sodium, Bixlozone ne), bromacil, bromobutide, bromofenoxime ofenoxim, bromoxynil, bromoxynil octanoate -octanoate), butachlor, butafenacil, butamifos (butamifos), butroxydim, butyrate, cafenstro Cafenstrole, carbetamide, carfentrazone ), carfentrazone-ethyl, chlormethoxyfen xyfen, chloramben, chloridazon, chlorimuron chlorimuron, chlorimuron-ethyl, chlorbromuron ron), chlorotoluron, chloroxuron, chlorpro Chlorpropham, chlorsulfuron, chlorthal dimethyl (ch lorthal-dimethyl), chlorthiamid, cinidon, cinidon Cinidon-ethyl, cinmethylin, cinosulfuron , clethodim, clodinafop, clodinafop propargy clodinafop-propargyl, clomazone, clomeprop, Clopyralid, clopyralid choline salt, clopyralid Clopyralid-methyl, clopyralid-olamin salt e), clopyralid potassium salt, clopyralid tris(2-hydro) Clopyralid-tris(2-hydroxypropyl)ammonium, chlorane Cloransulam, cloransulam-methyl, cumyluron luron, cyanazine, cycloate, cyclopyranyl ranil, cyclopyrimorate, cyclosulfamuron ron), cycloxydim, cyhalofop, cyhalofop butyl (cyhalofop-butyl), dalapon, dazomet, desmedipham medipham, desmetryn, di-allate, dicamba , dicamba choline salt, dicamba biproamine ne), dicambatrolamine salt (dicamba-trolamine), dicambadiglycolamine salt (dicamba-diglycolamine), dicamba dimethylammonium m), dicambadiolamine salt (dicamba-diolamine), dicambaisopropylammonium um (dicamba-isopropylammonium), dicamba methyl, dicamba o dicamba-olamine, dicamba-potassium, dicamba Dicloprop choline salt (dicamba-sodium), dichlobenil, dicloprop choline salt ( dichlorprop choline salt, dichlorprop-biproamine , dichlorprop-2-ethylhexyl, dichlorprop- Dichlorprop-butotyl, dichlorprop-dimethylammonium ethylammonium), dichlorprop-ethylammonium, Dichlorprop-isoctyl, dichlorprop-methyl -methyl), dichlorprop P (dichlorprop-P), dichlorprop P choline salt (dichlorpro pP choline salt), dichlorprop-P-biproamine, di Dichlorprop-P-etexyl, Dichlorprop-P-dimethylammon Dichlorprop-P-dimethylammonium, Dichlorprop potassium salt tassium, dichlorprop-sodium, diclofop p), diclofop-methyl, diclosulam, difenox Difenoxuron, difenzoquat, difenzoquat methylsulfonate Difenzoquat metilsulfate, diflufenican, diflufenican Diflufenzopyr, diflufenzopyr sodium , dimefuron, dimesulfazet, dimepiperate piperate), dimethachlor, dimethametryn, dimeth Dimethenamid, dimethenamid-P, dinitramine ne), dinoseb, dinoterb, diphenamid, dic Diquat-dibromide, DSMA (disodium methylarsonate), dithiopyr (dithiopyr), diuron, DNOC (2-methyl-4,6-dinitrophenol), esproca Esprocarb, ethalfluralin, ethametsulfuron lfuron), ethametsulfuron-methyl, ethidimuron muron), ethofumesate, ethoxyfen-ethyl, Ethoxysulfuron, etobenzanid, fenoxap Fenoxaprop, fenoxaprop-ethyl, fenoxaprop Fenoxaprop-P, fenoxaprop-P-ethyl, fenoxaprop-P-ethyl Fenoxasulfone, fenquinotrione, fenthrazami Fentrazamide, fenuron, flamprop-M, flaza Sulfuron (flazasulfuron), florasulam (florasulam), florpilauxiphen (fl orpyrauxifen), florpyrauxifen-benzyl, fluazi Hops (fluazifop), fluazifop-butyl, fluazifop P (flu azifop-P, fluazifop-P-butyl, fluazolat e), flucarbazone, flucarbazone sodium salt um), flucetosulfuron, flufenacet, flu Flufenpyr, flufenpyr-ethyl, flumetsulam flumetsulam, flumetsulam, flumiclorac, flumi Flumiclorac-pentyl, Flumioxazin, Fluo Meturon, fluoroglycofen-ethyl, flu Flupoxam, flupropanate, flupyrsulfuron sulfuron), flupyrsulfuron-methyl-sodium, Flurenol, fluridone, flurochloridone , fluroxypyr, fluroxypyr-butometyl , fluroxypyr-meptyl, flurtamone, fluthi Fluthiacet, fluthiacet-methyl, fomesafen mesafen, fomesafen sodium, foramsulfuron uron), fosamine, glufosinate, glufosinate ammo ammonium salt (glufosinate-ammonium), glufosinate P (glufosinate-P), glufosinate Glufosinate-P-ammonium salt, glufosinate-P sodium salt inate-P-sodium), glyphosate, glyphosate choline salt line salt), glyphosate-isopropylammonium , glyphosate-biproamine, glyphosate ammonium salt (g lyphosate-ammonium), glyphosate diammonium salt (glyphosate-diammonium), gly Glyphosate potassium salt (glyphosate-potassium), glyphosate sodium salt (glyphosate-sodium) odium), glyphosate-trimesium, halauxifen xifen, halauxifen-methyl, halosaphen, Halosulfuron, Halo Sulfuronmethyl, haloxyfop, haloxyfop Haloxyfop-etotyl, haloxyfop-methyl, haloxyfop Hop P (haloxyfop-P), haloxyfop-P-etotyl, haloxyfop Haloxyfop-P-methyl, hexazinone, imazamethabenz (imazamethabenz), imazamethabenz-methyl, imazamoc imazamox, imazamox-ammonium, imazapic azapic, imazapic ammonium, imazapyr , imazapyr-isopropylammonium salt, imazaquin ( imazaquin, imazaquin-ammonium, imazethapyr apyr, imazethapyr ammonium salt, imazosulfuron osulfuron, indanofan, indaziflam, iodosulfuron CFCs (iodosulfuron), iodosulfuron methyl sodium (iodosulfuron-methyl-sodium um), iofensulfuron, iofensulfuron sodium sulfuron-sodium), ioxynil, ioxynil octanoate l-octanoate, ipfencarbazone, isoproturon ), isouron, isoxaben, isoxachlorthor ortole, isoxaflutole, lactofen, lenacil enacil, linuron, maleic hydrazide, MCPA MCPA choline salt, MCPA biproamine, MCPA etexil (M CPA-etexyl, MCPA-butotyl, MCPA-butyl, MCPA-dimethyl Ammonium (MCPA-dimethylammonium), MCPA diolamine salt (MCPA-diolamine), MCP MCPA-ethyl, MCPA-isobutyl, MCPA-isooctyl tyl), MCPA isopropyl, MCPA methyl, MCPA allyl MCPA-olamine, MCPA sodium salt, MCPA trolamine salt -trolamine), MCPB (4-(4-chloro-2-methylphenoxy)butanoic acid), MCPB choline salt (MC MCPB choline salt, MCPB-biproamine, MCPB-ethyl, MCPB methyl (MCPB-methyl), MCPB sodium salt (MCPB-sodium), mecoprop choline salt (m ecoprop choline salt, mecoprop-biproamine, mecoprop Mecoprop-2-ethylhexyl, Mecoprop dimethylammonium (mecoprop-dimethylammonium), mecoprop-diolamine salt (mecoprop-diolamine) , mecoprop-ethadyl, mecoprop-isoctyl yl), mecoprop-methyl, mecoprop potassium salt ssium), mecoprop sodium salt (mecoprop-sodium), mecoprop trolamine Salt (mecoprop-trolamine), Mecoprop P (mecoprop-P), Mecoprop P choline salt (mec mecoprop-P choline salt, mecoprop-P 2-ethylhexyl yl), mecoprop-P-dimethylammonium, mecoprop Mecoprop-P-isobutyl, Mecoprop-P potassium salt ssium), mefenacet, mesosulfuron, mesosulfuron mesotrione, metham, metham Metamifop, Metamitron, Metazachlor, Metazosulfuron, methabenzthiazuron, Methiozolin, methyldymron, metobromuron bromuron, metolachlor, metosulam, metoxuron etoxuron, metribuzin, metsulfuron, metsulf metsulfuron-methyl, molinate, monolinuron n), naproanilide, napropamide, napropamide M(n apropamide-M), naptalam, neburon, nicosulfuron lfuron, norflurazon, oleic acid, orbencarb orbencarb, orthosulfamuron, oryzalin, okki Oxadiargyl, oxadiazon, oxasulfuron ron), oxaziclomefone, oxyfluorfen, Paraquat, paraquat-dichloride, pebulate bulate), pelargonic acid, pendimethalin, peno penoxsulam, pentanochlor, pentoxazone zone), pethoxamid, phenisopham, phenmedif Phenmedipham, picloram, picolinafen, Picolinafen, pinoxaden, piperophos , pretilachlor , primisulfuron , primisulfuron Primisulfuron-methyl, prodiamine, profluazole (profl diazimine (thidiazimin), thiencarbazone (thiencarbazone), thiencarba Thiencarbazone-methyl, thifensulfuron, thifen Thifensulfuron-methyl, thiafenacil, thiocaine Tiocarbazil, tolpyralate, topramezone , tralkoxydim, triafamone, tri- allate, triasulfuron, triaziflam, tribenu tribenuron, tribenuron-methyl, triclopyr r), triclopyr-butotyl, triclopyr-ethyl l), triclopyr-triethylammonium, Trizipha tridiphane, trietazine, trifloxysulfuron ron), trifloxysulfuron sodium salt, trifloxysulfuron-sodium Moxadine (trifludimoxazin), trifluralin, triflusulfuron riflusulfuron, triflusulfuron-methyl, tritosulf Tritosulfuron, vernolate, Ethyl [(3-{2-chloro-4-fluoro-5- [3-methyl-4-(trifluoromethyl)-2,6-dioxo-1,2,3,6-tetrahydropyrimidin-1-yl]phenoxy }pyridin-2-yl)oxy]acetate (353292-31-6), and the like. Preferably, the hydrophilic and modified nature of the composition of the present invention can be combined. It is desirable to combine the above ingredients in a way that does not interfere with the effects of the ingredients. By adding the herbicidal active agent (g) to the composition according to any one of [1] to [5], For example, it decomposes the cuticle layer (insect body covering), denatures the skeleton and cells of pests, and disrupts internal functions and metabolism. It can enhance the killing activity by absorbing necessary elements, balancing the body, and so on. It enhances the effects of inhibiting plant synthesis, disrupting plant hormones, and inhibiting the biosynthesis of amino acids specific to plants. At least one of the properties selected from the above can provide a synergistically excellent effect. Demonstrate.
[0087] [(h): Synergist] (h) Examples of synergists that can be combined with compositions Q, Q1, Q2, X, Y, and Z 1-dodecyl-1H-imidazole, N-(2-ethyl) Hexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide(N- (2-ethylhexyl)-8,9,10-trinorborn-5-ene-2,3-dicarboximide), bucarporate rpolate), N,N-dibutyl-4-chlorobenzenesulfonamide benzobenzenesulfonamide, dietholate, diethyl maleate leate, piperonyl butoxide, piperonyl cyclonene yl cyclonene, piprotal, propyl isome, safloxacin Safroxan, sesamex, sesamolin, sulfoxide oxide), Verbutin, DMC (1,1-bis(4-chlorophenyl)ethanol) phenyl)eth anol), FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethanol), ETN (1,2-epoxy- 1,2,3,4-tetrahydronaphthalene), ETP (1,1,1-trichloro-2,3-expoxypropane), PSCP (phenylsaligenin cyclic phosphate), TBPT (S,S,S-tributyl phosphorotrithioate) , TPP (triphenyl phosphate). FDMC (1,1-bis(4-chlorophenyl)-2,2,2-trifluoroethane ol), ETN (1,2-epoxy-1,2,3,4-tetrahydronaphthalene), ETP (1,1,1-trichloro-2,3- expoxypropane), PSCP (phenylsaligenin cyclic phosphate), TBPT (S,S,S-tributyl At least one selected from the group consisting of methyl phosphate (TPP), ... Preferably, the hydrophilic and modified hydroxybenzoates of the composition of the present invention are It is desirable to combine the above ingredients in a manner that does not interfere with the effects characterized by the above. By adding the synergist (h) to the composition according to any one of [1] to [5], for example, , insecticides, mites, nematodes, fungicides, plant growth regulators, weed control agents (weed killers and weed suppressants) agents), cleaning agents, deodorizers, spreading agents and freshness preserving agents, and also for humans, pet animals such as dogs and cats, or At least one selected from pesticides for pests that parasitize livestock such as cows and sheep, cleaning agents, and deodorizers It can dramatically increase the effectiveness of one drug.
[0088] [(i): Safener] (i) A device for combining the safener with the present compositions Q, Q1, Q2, X, Y and Z Examples include allidochlor, benoxacor, and cloquinto. Cloquintocet, cloquintocet-mexyl, symmetry Cyometrinil, cyprosulfamide, dichlormid ), dicyclonone, dimepiperate, disulfotone lfoton, dymron, fenchlorazole, fenchlora Fenchlorazole-ethyl, fenclorim, flurazole razole, furilazole, fluxofenim, hexim im), isoxadifen, isoxadifen-ethyl, Mecoprop, mefenpyr, mefenpyr-ethyl hyl), mefenpyr-diethyl, mephenate, methocal Metcamifen, oxabetrinil, 1,8-naphthalic anhydride ( 1,8-naphthalic anhydride, octane-1,8-diamine, AD -67 (4-(dichloroacetyl)-1-oxa-4-azaspiro [4.5] decane), CL-304415 (4-carboxy-3, 4-dihydro-2H-1-benzopyran-4-acetic acid), CSB (1-bromo-4-[(chloromethyl)sulfony l]benzene), DKA-24 (2,2-dichloro-N-[2-oxo-2-(2-propenylamino)ethyl]-N-(2-propene yl)acetamide), MG191 (2-(dichloromethyl)-2-methyl-1,3-dioxolane), MG-838 (2-pr openyl 1-oxa-4-azaspiro[4.5]decane-4-carbodithioate), PPG-1292 (2,2-dichloro-N- (1,3-dioxan-2-ylmethyl)-N-(2-propenyl)acetamide), R-28725 (3-(dichloroacetyl)-2 ,2-dimethyl-1,3-oxazolidine) , R-29148 (3-(dichloroacetyl)-2,2,5-trimethyl-1,3-o at least one selected from the group consisting of TI-35 (1-(dichloroacetyl)azepane), TI-36 (1-(dichloroacetyl)azepane), and the like; Two or more of them can be combined. Preferably, the hydrophilic and modified compositions of the present invention are It is desirable to combine the above ingredients in a way that does not interfere with the characteristic effects. By including the phytotoxicity safener (i) in the composition according to any one of [1] to [5], For example, as a plant (agricultural and horticultural) control composition, an insecticide, a mite control agent, a nematode control agent, a fungicide, , plant growth regulators, weed control agents (herbicides and herbicide inhibitors), cleaning agents, deodorizers, spreading agents and freshness preservation agents and pest control for humans, pets such as dogs and cats, and livestock such as cows and sheep. The chemical damage caused by at least one agent selected from the group consisting of a cleaning agent, a detergent, and a deodorant can be reduced.
[0089] [(j): Repellent] Specific examples of combinations of (j) repellents with compositions Q, Q1, Q2, X, Y, and Z As anthraquinone, chloralose, acrep rep), butopyronoxyl, camphor, d-camphor camphor, carboxide, dibutyl phthalate, di Deet, dimethyl carbate, dimethyl phthalate thalate), dibutyl succinate, dibutyl adipate ate), ethohexadiol, hexamide, icaridin idin, methoquin-butyl, methylneodecanamide mide), 2-(octylthio)ethanol, butoxypolypropanol Pyrene glycol (butoxypolypropylene glycol), oxamate, quwenzhi , Quyingding , Zengxiaon , Rebemide , Copper naphthenate and zinc naphthenate. Preferably, the hydrophilic and denaturing properties of the composition of the present invention are It is desirable to combine the above ingredients in a way that does not interfere with the fruit. By including the repellent (j) in the composition according to any one of [1] to [5], for example, This can dramatically improve the effects of the composition of the present invention.
[0090] [(k): Molluscicidal ingredient] (k) The molluscicidal component can be combined with the present compositions Q, Q1, Q2, X, Y and Z. Specific examples include bis(tributyltin) oxide, alicyclic allicin, bromoacetamide, cloethocarb , copper sulfate, fentin, ferric phosphate , metaldehyde, niclosamide, pentachlorophen pentachlorophenol, sodium pentachlorophenoxide henoxide, tazimcarb, tralopyril, triphenmol At least one or a combination of two or more selected from the group consisting of trifenmorph, Preferably, the above-mentioned components do not interfere with the hydrophilic and denaturing effects of the composition of the present invention. It is desirable to combine By adding the molluscicidal component (k) to the composition according to any one of [1] to [5] above, For example, the effect of the composition of the present invention can be dramatically improved.
[0091] [(l):Oil content] Specific examples of the oil (l) that can be combined with compositions Q, Q1, Q2, X, Y, and Z include: Vegetable oils (soybean oil, cottonseed oil, camellia oil, tung oil, perilla oil, rapeseed oil, etc.), animal oils (whale oil, fish oil, etc.) At least one or a combination of two or more selected from the group consisting of oils, mineral oils, etc. Preferably, the composition contains cottonseed oil, tung oil, perilla oil, rapeseed oil, and whale oil. It is desirable to combine the above ingredients so as not to interfere with the hydrophilic and denaturing effects of . By adding the oil component (l) to the composition according to any one of [1] to [5], By containing ingredients, it can be used as an insecticide, acaricide, nematode repellent, fungicide, plant growth regulator, weed control agent, etc. Chemicals (weed killers and weed suppressants), cleaning agents, deodorizers, spreading agents and freshness preserving agents, as well as for humans, dogs and cats. From pesticides for pets and livestock such as cattle and sheep, to cleaning agents and deodorizers It can dramatically increase the effectiveness of at least one selected agent. It also improves the waterproofing effect. This can improve adhesion, fixation, etc., and can improve residual effects.
[0092] [7] The IP according to any one of [1] to [6], wherein the carbonate is a sesquicarbonate. Composition for M (hereinafter referred to as this composition Q3). The sesquicarbonate of composition Q3 is weakly alkaline, and is therefore generally used in household cleaning products. It is widely used in dishwashing detergents, bath additives, etc., and is considered to be harmful in terms of oral ingestion, skin contact, and food residue. Therefore, it is a highly safe substance for the environment, animals, and humans (infants, children, etc.). It is highly safe and can therefore be used in public facilities, parks, indoors, etc. From the above, it can be said that it is desirable to use sesquicarbonate in the composition of the present invention. Conventional pesticides that can be used to control scale insects include machine oil emulsions and lime sulfur mixtures. , environmental impact (dirt, odor, pollution, etc.), health hazards to nearby residents and children (infants, etc.) Sesquicarbonate is a substance that requires special care, but it is not suitable for use in areas with small children or pets. It can be used very safely even when kept as a pet. When the present composition Q3 is used for the present compositions Q, Q1, Q2, X, Y and Z, the sesquicarbon The acid salts can be used alone or, if necessary, can be mixed or used in combination. Ingredient Q3 is an insecticide, acaricide, nematode repellent, fungicide, plant growth regulator, weed control agent (except Weed and weed suppressants), cleaning agents, deodorizers, spreading agents and freshness preserving agents, and also for people, dogs, cats and other pets. The agent is selected from pesticides for insects and diseases that parasitize animals or livestock such as cows and sheep, cleaning agents, and deodorizers. A synergistic effect of at least one agent can be expected. The above-mentioned mixture or combination of the present composition Q3 means the mixture or combination of the present compositions Q, Q1, Q2, X, Y and Z with the present composition Q3. This means that the composition Q and the composition W1 are used simultaneously, separately, or at intervals. When Q1, Q2, X, Y, and Z are used together with the present component W1, the present composition Q, Q1, Q2, X, Y and Z and the present ingredient W1 may each be contained in a separate preparation, or may be contained in a single preparation. It may be included in the formulation. The pH of the sesquicarbonate salt of Composition Q3 in a 1% aqueous solution is approximately 9.6 to 10.5. For example, soil in which plants live is acidic, ranging from about pH 4 to about pH 5. Alkaline salts have a pH range of about 9, while sesquicarbonates have a pH range of about 9.6 to 10. 5, which is unsuitable for the survival of normal plants. Plants and insects do not normally encounter a pH of acid salts, and both plants and insects are sesquicarbonates. By using salt, it is possible to achieve an effect that cannot be achieved under natural conditions (breaking through the defense mechanisms of pests and diseases). Also, if the pH changes by 1 degree, the concentration of H+ (hydrogen ions) will change by 10 times. Therefore, compared to the neutral pH of 7, the pH of sesquicarbonate is about 2.6 to 3.5. When sesquicarbonate is sprayed as an aqueous solution, the alkalinity is about 26 to 35 times higher. The part that denatures (neutralizes, decomposes, etc.) immediately after reaching plants, insects, animals, materials, etc., and the part that denatures (neutralizes, decomposes, etc.) The remaining portion is the portion that has not been decomposed (neutralized, decomposed, etc.), and the remaining portion that has had the effect of denaturation (neutralization, decomposition, etc.) is It is reactivated by moisture (rain, humidity, moisture excreted by plants and insects, etc.) and denatures (neutralizes, decomposes, etc.). It will remain in effect until the effect of the solution (e.g., solution) is lost. The amount of sesquicarbonate to be added is usually 0.001 to 50% by weight, preferably 0.001 to 50% by weight, based on the composition of the present invention. It is desirable to use about 0.01 to 0.5% by weight, and more preferably 0.5 to 0.15% by weight. % is preferable. Depending on how the composition of the present invention is used, it can be used as, for example, an insecticide, acaricide, nematodeicide, Disinfectants, cleaning agents, deodorizers and freshness preservatives are effective in preventing damage to plants while also mitigating pests. In order to achieve the above effect, the amount of the spreading agent in the composition of the present invention may be about 0.01 to 20% by weight. and plant growth regulators, even in very small amounts, they function as a spreading agent and a plant growth regulator. Therefore, the amount of the compound may be about 0.0001 to 20% by weight in the composition of the present invention. As a herbicide / weed suppressant, the higher the concentration, the more effective it is in inhibiting plant growth (killing plants). The components remaining in the plant, soil, or attached sheet continue to exert their effects. Therefore, the content of the composition of the present invention may be about 5 to 100% by weight. When the blending amount is within the above range, excellent effects can be obtained as an IPM composition.
[0093] Composition Q3 is preferably used as in Example 3 below. [Example 3] From the viewpoint of farmers, by using this composition Q3, the surface of the plant body is hydrophilic and modified. By applying stress such as penetration, dissolution, and affecting the opening and closing of stomata, It acts on growth regulators (plant hormones) in the body, making leaves thicker (harder) and roots more expansive. By reducing the amount of pesticides present, it is possible to impart the antidote effect that crops naturally have to suppress the occurrence of pests. Enhances the physiological activity of plants in response to weather conditions (heat, cold, lack of water, etc.) and prevents the occurrence of pests and diseases. This will create conditions that make it less likely for this to occur, preventing its occurrence and reducing damage. For example, when using this composition Q3 on sticky scale insects, etc., use a brush If you spray or apply it before or at the same time as rubbing it off, it will loosen the adhesion and thin the wax, making it easier to remove. It can kill scale insects and at the same time, it can also increase the effect of removing the insect bodies themselves. For example, spraying or applying the fungus to plants that have developed sooty mold can cause them to peel off and fall off. It has at least one effect selected from cleaning, deodorizing, and the like.
[0094] By using the present composition Q3, for example, it is possible to physically kill scale insects that adhere to the surface. It destroys the insect's body covering, closes the spiracles, and produces carbon dioxide, causing suffocation. The drug denatures the enzyme, and induces at least one of metabolic disorders caused by high sodium levels, dorsal vascular abnormalities, etc. It has two effects, which make it highly effective in killing pathogens and harmful insects. It kills live bacteria (bacteria that supply essential nutrients, etc.) by altering the ion balance. Biologically, ladybugs, which are natural enemies of aphids, are more resistant to insects than aphids. It has a much larger skeleton, a hard exoskeleton, and no symbiotic bacteria, so the effects of this composition After spraying this composition, ladybugs can survive and are less susceptible to the effects of the weak exoskeleton. The insects die. The surviving ladybugs fly to new plants and feed on the migrated oil beetles. They prey on insects and can kill or reduce aphids on plants. The target is the effect of pest control agents against pests (insects, sap-sucking pests), pathogenic fungi (filamentous fungi; blue Mold, blast, scab, rust, gray mold, red star, powdery mildew, wilt, black spot It has the effect of killing, suppressing and preventing diseases such as black spot and black spot. In addition, due to its action as a plant growth regulator, it is possible to promote the coloring of fruits before harvest, It has the effect of making it easier to pick citrus fruits, increasing sugar content, and improving the active ingredients. At least one of the effects selected from the above provides an excellent pest control composition for IPM. It can be said that:
[0095] By using this composition Q3, for example, it can be used to control and suppress weeds (trees, etc.), It can be used to kill plants and weeds (trees, etc.), suppress weeds, and inhibit germination. In the case of cuts, excisions, cuts, abrasions, etc., the composition of the present invention is preferably about 5 to 100% by weight. A sufficient amount of a composition containing 5 to 20% by weight is applied (by spraying, soil spraying, painting, etc.). By applying a cloth or similar to the above, it can be used to suppress withering, growth, and germination. Therefore, by applying (spraying, soil scattering, coating, etc.) a sufficient amount of a composition containing 15 to 100% by weight, It can be used to inhibit withering, growth, and germination.
[0096] Post-harvest (referring to the general techniques related to the preservation of agricultural products after harvest. Agricultural chemicals or additives used on agricultural products are called post-harvest agents. Composition Q3 is sprayed, applied, or immersed in, for example, plants or materials (coverings, packaging, wrapping, tape, etc.). By using it in the above places, it can suppress the occurrence of pests and preserve freshness. It also kills (suppresses) pests such as scale insects and sooty mold, and has cleaning, deodorizing, and freshness-preserving effects. The effects of the present invention include improved shelf life, improved functional ingredients, increased sugar content, and improved coloring. The composition can also be applied to materials during plant growth and / or after harvest.
[0097] From the above Example 3, it can be seen that the composition Q3 is a composition according to any one of the above [1] to [6]. By using sulfur carbonate, it can be used as a composition that is safe for the environment, humans, and animals (natural enemies). As mentioned above, this is an excellent IPM composition. It has a very high killing effect when used as a water-based insecticide to control scale insects that adhere to the surface. Since there is no growth inhibition due to chemical damage, it can be used all year round and at the same time, it can wash away stains caused by sooty mildew. It has promising effects as a safe pest control agent for agricultural and horticultural crops with its cleansing properties. By using this composition, conventional winter control and prediction of occurrence are possible, with only 5 days from egg to larval stage. It is a simple and labor-free method of pest control that can be sprayed outside of the optimal spraying period, and is profitable. This is a composition that dramatically improves the performance.
[0098] The composition of the present invention exhibits excellent fungal control effects, and is therefore effective against symbiotic fungi of pest insects. Mutual aid fungi and other organisms are used for the survival (growth, growth, development, metamorphosis, etc.) of insects. The method has at least one effect selected from the effects of killing (suppressing) fungi and the like that cause pests. It also demonstrates this.
[0099] The present compound refers to a compound described in any one of compositions Q, Q1, Q2, and Q3 (hereinafter, the present compound). The weight ratio of the application amount of compositions Q, Q1, Q2, and Q3 to the application amount of this component The types of plants to be protected and the types of harmful arthropods to be controlled are not particularly limited. harmful nematodes, harmful mollusks, plant pathogenic microorganisms, parasitic pests (pets, or cattle and sheep) livestock, etc.) or type and frequency of weeds, formulation, application time, application method, application location, weather The weight ratio can be adjusted appropriately depending on the conditions. When used on plants (especially stems, leaves, seeds, vegetative reproductive organs) or on cultivation carriers for cultivating plants (especially When used in soil, the following weight ratios can be used. The weight of the component refers to the weight of the preparation. For example, a weight ratio of 1:500 means ( d) The amount of application of the preparation of one or more components selected from the microorganisms of the present invention is It means that the amount is 500 parts by weight.
[0100] Weight ratio [(this compound):(this component)] = 1:10^15 to 10^15:1, specifically For example, 1:10^15, 1:10^14, 1:10^13, 1:10^12, 1:1 0^11, 1:10^10, 1:10^9, 1:10^8, 1:10^7, 1:10^6 , 1:10^5, 1:10000, 1:9000, 1:8000, 1:7000, 1:6 000, 1:5000, 1:4000, 1:3000, 1:2000, 1:1000, 1 :900, 1:800, 1:700, 1:600, 1:500, 1:400, 1:350 , 1:300, 1:250, 1:200, 1:150, 1:100, 1:90, 1:80 , 1:70, 1:60, 1:50, 1:40, 1:30, 1:20, 1:19, 1:18 , 1:17, 1:16, 1:15, 1:14, 1:13, 1:12, 1:11, 1:10 , 1:9, 1:8, 1:7, 1:6, 1:5, 2:9, 1:4, 2:7, 1:3, 3:8 , 2:5, 3:7, 4:9, 1:2, 5:9, 4:7, 3:5, 2:3, 5:7, 3:4 , 7:9, 4:5, 5:6, 6:7, 7:8, 8:9, 1:1, 9:8, 8:7, 7:6 , 6:5, 5:4, 9:7, 4:3, 7:5, 3:2, 5:3, 7:4, 9:5, 2:1 , 9:4, 7:3, 5:2, 8:3, 3:1, 7:2, 4:1, 9:2, 5:1, 6:1 , 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15 :1, 16:1, 17:1, 18:1, 19:1, 20:1, 30:1, 40:1, 50 :1, 60:1, 70:1, 80:1, 90:1, 100:1, 150:1, 200:1 , 250:1, 300:1, 400:1, 500:1, 600:1, 700:1, 800 :1, 900:1, 1000:1, 2000:1, 3000:1, 4000:1, 500 0:1, 6000:1, 7000:1, 8000:1, 9000:1, 10000:1, 10^5:1, 10^6:1, 10^7:1, 10^8:1, 10^9:1, 10^10 :1, 10^11:1, 10^12:1, 10^13:1, 10^14:1, 10^15 :1. Here, the caret symbol "^" is the operator that represents exponentiation, for example, "10^5 " means "105" (i.e., 10 to the power of 5).
[0101] A cultivation carrier for cultivating plants is a support for plants and can be made of any material that allows plants to grow. Examples of suitable materials include soil, seedling mats, and water. Examples include sand, pumice, vermiculite, diatomaceous earth, gel-like substances, polymeric substances, rock Examples include wool, glass wool, wood chips, and bark.
[0102] When Composition A is used as a plant disease control composition, the following may be used, but is not limited to: Usually, it is preferable to use the composition as a composition further containing an inert carrier (hereinafter referred to as composition B). (Write it down.) Usually, composition A and this component are mixed separately with any solid or liquid carrier, and then mixed as needed. If necessary, surfactants and other formulation adjuvants are added to formulate the present compound formulation and the present compound formulation. The compound is a mixture of the component formulations, or the compound is a mixture of the component formulations and the component formulations, and the compound is a mixture of the component formulations and the component formulations. Mixing the carrier or liquid carrier, adding surfactants and other formulation auxiliaries as needed, It is formulated into a single preparation. The dosage form of the preparation can be emulsion, oil, powder, liquid, Granules, fine granules, bait, tablets, wettable powders, water-soluble powders, underwater suspensions, underwater emulsions, and other flowables formulations, flowable formulations, dry flowable formulations, capsules, microcapsules, sprays, Azole agents, fumigants, poison baits, resin preparations, paste preparations, foams, carbon dioxide preparations, tablets In these preparations, the present compound and the present ingredient are usually contained in a total amount of 0.001 to 5 0% by weight. Preferably, the present compound and the present component are contained in an amount of usually 0.10 to 20% by weight, as can be seen from the examples. It is preferable to use 100% by weight of the composition. For example, 100% by weight of the product is applied to the plant body or soil as granules, powder or solid form, and then water (empty) is added. It can also be dissolved by moisture in the air, mist, rain, watering, etc.
[0103] Examples of solid carriers used in formulation include clays (kaolin clay, diatomaceous earth, Montmorillonite, bentonite, fubasami clay, acid clay, etc.), synthetic hydrous silicon oxide, Stone, ceramics, and other inorganic minerals (sericite, feldspar, quartz, alumina, sulfur, activated charcoal, calcium carbonate, hydrated silica, etc.), chemical fertilizers (ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, ammonium chloride, etc.), etc. Fine powders and granules of synthetic resins (polypropylene, polyacrylonitrile, poly Polyester resins such as methyl methacrylate and polyethylene terephthalate, nylon-6 Nylon resins such as nylon-11 and nylon-66, polyamide resins, polyvinyl chloride , polyvinylidene chloride, vinyl chloride-propylene copolymer, etc.), sawdust, nitrocellulose , starch, gum arabic, etc.
[0104] Examples of liquid carriers include water, alcohols (methanol, ethanol, isopropyl Alcohol, butanol, hexanol, benzyl alcohol, ethylene glycol, propylene glycol, phenoxyethanol, etc.), ketones (acetone, methyl ethyl ketone, toluene, xylene, ethylbenzene, etc.), aromatic hydrocarbons (toluene, xylene, ethylbenzene, etc.) , dodecylbenzene, phenylxylylethane, methylnaphthalene, etc.), aliphatic hydrocarbons (hexane, cyclohexane, kerosene, diesel, etc.), esters (ethyl acetate, butyl acetate, etc. , Isopropyl myristate, Ethyl oleate, Diisopropyl adipate, Adipic acid diisobutyl acetate, propylene glycol monomethyl ether acetate, etc.), nitriles (acetonitrile, isobutyronitrile, etc.), ethers (diisopropyl ether, 1 ,4-Dioxane, Ethylene glycol dimethyl ether, Diethylene glycol dimethyl Diethylene glycol monomethyl ether, propylene glycol monomethyl ether Dipropylene glycol monomethyl ether, 3-methoxy-3-methyl- 1-butanol, etc.), acid amides (N,N-dimethylformamide, N,N-dimethyla cetoamide, etc.), halogenated hydrocarbons (dichloromethane, trichloroethane, carbon tetrachloride, etc.) esters, etc.), sulfoxides (dimethyl sulfoxide, etc.), propylene carbonate and vegetable oils (soybean oil, cottonseed oil, camellia oil, tung oil, perilla oil, rapeseed oil, etc.), animal oil (whale oil, fish oil, etc.), mineral oil, etc. Examples include:
[0105] Gaseous carriers include, for example, fluorocarbons, butane gas, and LPG (liquefied petroleum gas). , dimethyl ether and carbon dioxide gas.
[0106] Examples of surfactants include sodium higher alcohol sulfate and stearyl trimethyl Ammonium chloride, polyoxyethylene alkyl ether, lauryl betaine, poly Oxyethylene alkyl aryl ether, polyethylene glycol fatty acid ester nonionic surfactants such as alkyl sulfonates, alkyl benzene sulfonates, Anionic surfactants such as alkyl sulfates, cationic surfactants, amphoteric surfactants, etc. Examples include:
[0107] Spreading agent; Wetting agent such as dialkyl sulfosuccinate; Carboxymethyl cellulose, poly Fixing agents such as vinyl alcohol; sodium lignosulfonate, sodium lauryl sulfate Of course, the composition A and the composition B of the present invention may be used alone or in combination. Two or more of these can be combined and formulated as active ingredients. The content of the composition of the present invention as a percentage is, for example, 0.01 to 99.5% by mass, and is preferably Or, it is selected from the range of 0.5 to 90 mass %, and it depends on various conditions such as the formulation form and application method. For example, in the case of a powder, the amount is about 0.5 to 20% by mass, preferably 1 to 10% by mass, for wettable powders, about 1 to 90% by mass, preferably 10 to 80% by mass, The emulsion contains about 1 to 90% by mass, preferably 10 to 40% by mass, of the active ingredient. It can be manufactured like this.
[0108] Other formulation adjuvants include adhesives, dispersants, colorants, and stabilizers, etc. For example, casein, gelatin, sugars (starch, gum arabic, cellulose derivatives, algin Acids, etc.), lignin derivatives, bentonite, synthetic water-soluble polymers (polyvinyl alcohol, poly Vinylpyrrolidone, polyacrylic acids, etc.), PAP (isopropyl acid phosphate), BH T (2,6-di-tert-butyl-4-methylphenol), BHA (2-tert- Butyl-4-methoxyphenol and 3-tert-butyl-4-methoxyphenol The coloring agent may be a red pigment, a blue pigment, a green pigment, a yellow pigment, or the like. Specifically, monazol red, cyanine green, Prussian blue, In particular, in the case of granules and microgranules, It is preferable to add a coloring agent so that the granules and fine granules can be easily identified later. When treating seeds or vegetative reproductive organs, coloring agents are used because it is easy to confirm that the treatment has been carried out. The addition of is preferred.
[0109] Specifically, mineral oil, vegetable oil, and other oils that can be mixed together, as surfactants Nimbus®, Assist®, Aureo®, I harol®, Silwet L-77®, BreakThru® Registered trademark), Sundance II (registered trademark), Induce (registered trademark), Pene Trator®, AgriDex®, Lutensol A8 NP-7 (registered trademark), Triton (registered trademark), Nufilm (registered trademark) ), Emulgator NP7 (registered trademark), Emulad (registered trademark), TRITO NX 45 (registered trademark), AGRAL 90 (registered trademark), AGROTIN (registered trademark) ), ARPON (registered trademark), EnSpray N (registered trademark), BANOLE (registered trademark) Examples include:
[0110] Composition A and Composition B may be mixed with or without a fertilizer, soil conditioner, or fertilizer. They can also be used simultaneously without any modification.
[0111] The seeds used in the present invention are plant seeds to which an effective amount of Composition B has been attached. The vegetative reproductive organ of the invention is a vegetative reproductive organ of a plant to which an effective amount of composition B is attached. For example, the microencapsulated composition B may be attached to seeds or vegetative reproductive organs. In addition, in the attachment of composition B to the seeds or vegetative reproductive organs of a plant, composition B is It may completely or partially cover the reproductive organs or may be scattered over their surface; and / or may be present inside it.
[0112] When Composition B is used to control plant diseases, the application amount depends on the type of plant used and the target of control. The type and frequency of a certain plant disease, formulation type, application time, application location, application method, weather conditions, etc. The application rate of one active ingredient is usually 10,000 m 2, 1 to 10,000 g, preferably 5 to 5,000 g, more preferably 50 to 200 0 g (specifically, for example, 100 g, 200 g, 500 g). When formulated as an emulsifiable concentrate, wettable powder, flowable, etc., the concentration of one active ingredient is usually 0.01 to 10,000 ppm, preferably 0.1 to 5,000 ppm, more preferably 1 ~1000 ppm (specifically, for example, 10 ppm, 100 ppm, 500 ppm) When Composition B is formulated as granules, powder, etc., it is usually diluted with water. It is usually used as is.
[0113] These formulations or their aqueous dilutions can be applied directly to the plants to be protected from plant diseases. It may also be applied to cultivated soil to control plant diseases that occur in the soil. .
[0114] For example, sheets, strings, tapes, resin, mesh-like resin, paper, waterproof paper, cloth, rubber, The composition B is contained in a carrier such as glass, a plate, a net, etc. by immersion, impregnation, coating, kneading, etc. The formulation is wrapped around plants, bagged on fruits (vegetables), stretched around the plant, or applied to the base of the plant. It can be used by spreading it on the soil or covering the plant cultivation area. Examples of how it can be used for materials (outer boxes, inner boxes, insoles, underlays, top linings, packaging bags, cushioning materials) include can be done.
[0115] In the present invention, the term "plant" includes the whole plant and specific parts of the plant. The parts include the stems, leaves, flowers, spikes, fruits, trunks, branches, crowns, seeds, vegetative reproductive organs and seedlings. It can be enjoyed.
[0116] Vegetative reproductive organs are the roots, stems, leaves, etc. of plants that are separated from the main body and planted in the soil. Vegetative reproductive organs include, for example, , tuberous root, creeping root, bulb, corm or so lid bulb, tuber, rhizome, stolon, rhizophore ), cane cuttings, propagules, and vine cuttings. In addition, stolon is also called runner, and bulbil is also called bulbil. They are called broad buds and bulbils. It refers to the shoots (a collective term for leaves and stems) of yam, etc. Bulbs, corms, tubers, rhizomes, The stem fragment, rhizophore or tuberous root is collectively called a bulb. It starts by planting, and the tubers used are generally called seed potatoes. Includes edlings and saplings.
[0117] In the control method of the present invention, the present compound and the present component are applied to the plant or plants grown separately at the same time. The present compounds and ingredients may be applied to the soil where the plant disease occurs or to the site of the plant disease. Even if they are applied separately at different times to plants, the soil in which the plants are grown, or the area where plant diseases occur, good.
[0118] In the present invention, the locations where plant diseases occur include paddy fields, farmlands, tea fields, orchards, non-agricultural land, Examples include seedling trays, seedling boxes, seedling soil and seedling mats, and hydroponic solutions in hydroponic farms. .
[0119] When applying Composition B to plants or areas where plants are grown, it may be applied once or multiple times. The cultivation area of the plant may be one in which plant diseases have already occurred, or may be one in which plant diseases have not yet occurred.
[0120] Examples of control methods using Composition A and Composition B include spraying with a sprayer (hand spraying, speech sprayers, drones, etc.), granular sprayers, soil drench and aerosol sprayers, brushes, paintbrushes, Among these, the above-mentioned hydration method is also applicable. It is preferable to spray the composition of the agent or the like as a concentrate.
[0121] The application method of Composition B may be, for example, foliage application, soil application, root application, or shower application. These include smoke treatment, water surface treatment, seed treatment and hydroponic solution treatment.
[0122] For foliage treatment, for example, Composition B is applied to foliage, trunks, fruits, flowers (before flowering, during flowering, and after flowering). Examples of methods for treating the roots include treating the ears (including the rear) or the surface of the entire plant. For example, a method of immersing the roots in a chemical solution containing composition B, and a solid preparation containing composition B Examples of soil treatment include soil spraying, soil application, and soil treatment. The soil treatment can be carried out in the following places: , planting hole, row, near planting hole, near row, entire cultivated area, plant ground edge, between plants, under tree trunk, main trunk ridge Examples of the treatment time include before sowing. , at the time of sowing, after sowing, during the seedling raising period, before planting, at the time of planting, and during the growing period after planting. In the above soil treatment, composition B may be simultaneously applied to the plant, and a composition containing composition B may be Solid fertilizers such as paste fertilizers may be applied to the soil. They may also be mixed with irrigation liquid. For example, injection into irrigation equipment (irrigation tubes, irrigation pipes, sprinklers, etc.), inter-row watering liquid In addition, the active ingredient may be mixed with the irrigation solution in advance, For example, the treatment is carried out using the above-mentioned irrigation method or other appropriate irrigation methods such as sprinkling water or flooding. As a shower treatment, for example, a diluted solution of Composition B is sprayed onto the harvested fruit. For example, a diluted solution of composition B is sprayed in the form of a mist. The method involves scattering the fungus in the air and allowing it to adhere to the stems, leaves, and fruits of plants. For example, a liquid containing composition B or a solid containing composition B is applied to a flooded rice paddy. For seed treatment, for example, spraying a formulation onto seeds or vegetative reproductive organs is used. In particular, for example, a suspension of composition B is sprayed onto the surface of the seeds. spraying treatment by spraying composition B onto the surface of the seed or vegetative reproductive organ; Smear treatment, in which seeds are applied, soaking treatment, in which seeds are immersed in a solution of composition B for a certain period of time, and soaking treatment, in which seeds are immersed in a solution of composition B for a certain period of time. A method of coating seeds or vegetative reproductive organs with a carrier that The vegetative reproductive organs mentioned above include seed potatoes. When applying A to seeds or vegetative reproductive organs, composition A is applied to the seeds or vegetative reproductive organs as a single formulation. Composition A can be applied to the reproductive organs or in multiple doses in different formulations. Composition A can also be applied to offspring or vegetative reproductive organs. As an example of the method of treating the compound separately, a preparation containing only the present compound as an active ingredient is treated. and a method of treating the seeds or vegetative reproductive organs with a formulation containing the present ingredient after air-drying the seeds or vegetative reproductive organs; The seeds or vegetative reproductive organs are treated with a formulation containing the present compound or the present ingredient as an active ingredient, and then air-dried. and then treating the treated plant with a formulation containing ingredients other than the present ingredient. For example, a chemical solution containing composition B or a solid formulation containing composition B is added to a hydroponic solution. Examples of methods include mixing or incorporating the agent into the solution (hydroponic solution mixing treatment, hydroponic solution mixing treatment, etc.).
[0123] When applying Composition B to seeds or vegetative reproductive organs, manganese, copper, zinc, etc. may be applied at the same time. The seeds or vegetative reproductive organs treated with Composition B may be sown or treated in a field in the usual manner. It is planted.
[0124] When applying Composition B to seeds or vegetative reproductive organs, the application rate of Composition B is The amount is usually 0.001 to 100 g, preferably 0.02 to 50 g, per 1 kg of reproductive organs. The application rate of each active ingredient contained in Composition B is per 1 kg of seeds or vegetative reproductive organs. , usually 0.001 to 100 g, preferably 0.01 to 50 g, more preferably 0.1 to Specifically, the processing amount is as follows: 0.05g of active ingredient per 1kg of seeds or vegetative reproductive organs; 0.5g of active ingredient per 1kg of seeds or vegetative reproductive organs; 5g of active ingredient per 1kg of seeds or vegetative reproductive organs.
[0125] When applying Composition B to seeds or vegetative reproductive organs, it is necessary to add azithromycin to Composition B as needed. A soluble fiber may be mixed with the soluble fiber.
[0126] When composition B is used for controlling harmful arthropods, this compound and this ingredient are applied to different places. Specifically, for example, seeds or seeds treated with either the present compound or the present component may be used. Before or after planting the vegetative reproductive organ in a cultivation carrier (for example, soil, etc.), the other is applied to the cultivation carrier. It may also be used.
[0127] In the present invention, the seeds or vegetative reproductive organs carrying the present compound or composition A are seeds or a state in which the present compound or composition A is attached to the surface of the vegetative reproductive organ. The seeds or vegetative reproductive organs carrying the above composition A are then transferred to the seeds or vegetative reproductive organs. Before or after the application of this compound or composition A, materials other than this compound or composition A are applied. It's fine. In addition, when composition A is attached to the surface of a seed or a vegetative reproductive organ as a layer, the layer , consists of one layer or multiple layers. In addition, when it consists of multiple layers, each layer has one or more A layer containing an active ingredient, or a layer containing one or more active ingredients and an active ingredient The seed or vegetative reproductive organ carrying composition A is, for example, Composition B containing composition A is applied to seeds or vegetative reproductive organs by the seed treatment method described above. It can be obtained by
[0128] More specifically, the soil treatment method of Composition B is, for example, planting hole treatment (planting hole spraying, planting hole treatment) soil incorporation), plant base treatment (plant base spray, plant base soil incorporation, plant base irrigation, plant base treatment in the latter half of the seedling raising period), Furrow treatment (planting furrow spraying, planting furrow soil mixing), crop row treatment (crop row spraying, crop row soil mixing, growing season crop row spraying) cloth), row treatment at sowing (row spray at sowing, soil incorporation at sowing), overall treatment (overall soil spray Fabric, full soil mixing), side stripe application, water surface application (water surface application, water surface application after flooding), other soil applications Fabric application (granular foliar application during the growing season, application under the crown or around the main trunk, soil surface application, soil surface incorporation, Hole spraying, furrow surface spraying, interplant spraying), other irrigation treatments (soil irrigation, seedling irrigation, chemical solution Injection treatment, ground level irrigation, chemical drip irrigation, chemigation), seedling box treatment ( Seedling tray spraying, seedling tray irrigation, seedling tray flooding), seedling tray treatment (seedling tray spraying, seedling tray Seedling irrigation, seedling tray flooding with chemical solution), seedling bed treatment (seedling bed spraying, seedling bed irrigation, water seedling bed spraying, seedling Soaking), bed soil mixing treatment (bed soil mixing, bed soil mixing before sowing, spraying before covering with soil when sowing, spraying after covering with soil when sowing Cloth, covering soil mixing), other treatments (mixing soil, plowing, mixing topsoil, mixing soil in areas that have fallen rain, planting position This is sometimes called "place treatment," "granular inflorescence spraying," or "paste fertilizer mixing."
[0129] Examples of plants for which Composition A and Composition B can be used include the following [Plant Examples]: do. [Plant example] Crops: Corn (horse-tooth, hard-grain, soft-grain, explosive, glutinous, sweet), Rice (long grain, short grain, medium grain, japonica, tropical japonica, indica, Wanika seeds, paddy rice, upland rice, floating rice, direct sowing, transplanting, glutinous rice), Wheat (bread wheat (hard, soft, medium, red, white), durum wheat, Spanish (rut wheat, club wheat, and their respective autumn and spring varieties), Barley (two-rowed barley (= beer barley), six-rowed barley, naked barley, glutinous barley, Autumn sowing type, spring sowing type), Rye (autumn sowing type, spring sowing type), Triticale (autumn and spring varieties), Oats (autumn sowing type, spring sowing type), Oats, sorghum, Cotton (Upland and Pima varieties), Soybean (determinate, determinate, semi-determinate), Peanuts, kidney beans, lima beans, adzuki beans, cowpeas, Mung beans, vermicelli, scarlet beans, bamboo azuki beans, moss beans, tepary beans, Broad beans, peas, chickpeas, lentils, lupins, pigeon peas, alfalfa, sugar beet, rapeseed, canola (autumn and spring), sunflower, sugarcane, tobacco Ko et al. Vegetables; Nightshade vegetables (eggplant, tomato, bell pepper, chili pepper, pepper, bell pepper, potatoes, etc.), Cucurbitaceae vegetables (cucumber, pumpkin, zucchini, watermelon, melon, melon, squash) Yu et al.), Cruciferous vegetables (radish, turnip, horseradish, kohlrabi, sugar beet, Chinese cabbage, cabbage) Vegetables such as beets, mustard greens, broccoli, cauliflower, and komatsuna. Asteraceae vegetables (burdock, garland chrysanthemum, artichoke, lettuce, etc.), Liliaceae vegetables (leeks, onions, garlic, asparagus, etc.), Umbelliferous vegetables (carrots, parsley, celery, parsley, etc.), Chenopodiaceae vegetables (spinach, Swiss chard, etc.), Lamiaceae vegetables (perilla, mint, basil, lavender, rosemary, thyme, etc.), strawberries, Sweet potato, yam, taro, okra, lotus root, pepper, hops, etc. Fruit trees: pome fruits (apples, European pears, Japanese pears, Chinese quince, quince, etc.), Stone fruits (peaches, plums, nectarines, plums, cherries, apricots, prunes, etc.), Citrus fruits (Satsuma mandarins, oranges, lemons, limes, grapefruits, Sanshi) Zhou et al.), Nuts (chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, macadamia) Annatto, etc.), Berries (blueberries, cranberries, blackberries, raspberries, etc.), grapes, persimmons , olives, loquats, bananas, coffee, dates, coconuts, ginger, etc.), Others: Tea, mulberry, cotton, hemp, olive, rubber, coffee, flowering trees, roadside trees (weeping willow) , Korean willow, Chinese walnut, mulberry, paper mulberry, privet, Japanese bush clover, sweet osmanthus, and silver ginseng Osmanthus, oaks, Mallotus japonicus, China tree, flowering peach, ash, birch, dogwood , eucalyptus, ginkgo, lilac, maple, oak, poplar, redbud, liquidamum, prata eggplant, zelkova, arborvitae, fir, hemlock, juniper, pine, spruce, yew), Flowers (roses, periwinkles), kudzu, Japanese lacquer tree, cycads, Amur cork, bitter orange, and starwort Trees, broom, currants, purple holly, Japanese holly, ornamental plants, lawn grasses, pasture plants, Forest trees (Todomatsu, Ezomatsu, pine, hiba, beech, cedar, cypress, Chinese parasol, paulownia, etc.), mushrooms (shiitake mushrooms, mushrooms, etc.), Pasture and forage crops (timothy, clover, alfalfa, corn, sorghum) , orchard grass, grasses, legumes, etc.) Grass (Korean grass, bentgrass, etc.), Ornamental plants (herbs and flowers such as chrysanthemums, roses, carnations, orchids, cherry blossoms, bluebells, etc.) Garden trees, etc.
[0130] The above-mentioned plants are not limited as long as they are varieties that are commonly cultivated. It can also be used.
[0131] The above-mentioned plants include plants that can be produced by natural crossbreeding, plants that can be generated by mutation, and F1 hybrids. They may be hybrid plants or transgenic plants (also called genetically modified plants). These plants generally have the following characteristics: resistance to herbicides, accumulation of toxic substances to pests (harmful to pests), Insect resistance, disease susceptibility (also called disease resistance), yield potential Increased resistance to biotic and abiotic stress factors, altered product quality (e.g. For example, an increase or decrease in the content of a specific ingredient, a change in composition, or an improvement in shelf life or processability. do.
[0132] F1 hybrid plants are first-generation hybrids obtained by crossbreeding two varieties of different lineages. It is a plant that generally has hybrid vigor characteristics that are superior to either of its parents. Transgenic plants are plants that have been cultivated by introducing foreign genes from other organisms such as microorganisms. Therefore, it is easily obtained by cross-breeding, mutagenesis, or natural recombination in the natural environment. It is a plant that has been given characteristics that make it impossible to do so.
[0133] Techniques for producing the above plants include, for example, conventional breeding techniques; Recombinant technology; genomic breeding technology; new breeding techniques; genome editing technology Conventional breeding techniques are the techniques for improving plants by using mutations and crossbreeding to create desirable traits. Genetic engineering is the technology to obtain plants that have the By extracting the desired gene (DNA) from the target organism and introducing it into the genome of another target organism, techniques to give the organism new properties, or to silence other genes present in the plant. Antisense or RNA interference techniques that confer new or improved properties by Genomic breeding technology is a technique for improving the efficiency of breeding by using genomic information. DNA markers (also called genome markers or gene markers), breeding techniques and genomics For example, DNA marker breeding involves the selection of specific genes for useful traits on the genome. Using DNA markers, which are DNA sequences that mark the location of the target gene, we can identify the target gene from a large number of progeny. This is a method for selecting offspring that have genes for desired traits. By using this method for analysis, it has the advantage of being able to effectively shorten the time required for breeding. Genomic selection involves creating a prediction formula based on previously obtained phenotype and genome information. This is a method for predicting characteristics without evaluating phenotypes using prediction formulas and genome information. New breeding techniques are technologies that can contribute to the efficiency of molecular breeding. It is a general term for breeding techniques that combine biological methods. For example, cisgenesis / Intragenesis, oligonucleotide-directed mutagenesis, RNA-dependent DNA methylation , genome editing, grafting onto GM rootstocks or scions, reverse breeding, agroinfiltration, seeds There are technologies such as Seed Production Technology (SPT). Genome editing technology and is a technology that converts genetic information in a sequence-specific manner, resulting in deletion of base sequences and substitution of amino acid sequences. For example, sequence-specific DNA cleavage is possible. Zinc finger nucleases (ZFNs) that can TALEN, CRISPR / Cas9, CRISPR-CPF1 (CRISPER / Cpf1) and Meganuclease. Sequence-specific genome modification techniques such as CAS9 nickase and Target-AID, which are created by modifying the gene There is a technique.
[0134] As the above-mentioned plants, for example, INTERNATINAL SERVICE for Agri-Biotechnology The Acquisition of Agri-Biotech Applications (ISAAA) electronic information site (http: The GM Approval Database at www.isaaa.org / More specifically, for example, herbicide-resistant plants, pest-resistant plants, etc. Plants, disease-resistant plants, altered product quality (e.g., increase or decrease in the content of ingredients, changes in composition, storage plants with improved fertility or processability, fertility-modified plants, abiotic stress-tolerant plants, or There are plants with modified traits related to yield and productivity.
[0135] Examples of plants that have been made tolerant to herbicides include: Mechanisms of resistance to herbicides include, for example, reduced affinity between the herbicide and its target; Rapid metabolism (decomposition, modification, etc.) of herbicides due to the expression of enzymes that inactivate herbicides; herbicides and inhibition of herbicide translocation within the plant.
[0136] Plants that have been given herbicide resistance through genetic engineering are, for example, those that are resistant to flumioxazin. Protoporphyrinogen oxidase (PPO) herbicide: Isoxaflut 4-hydroxyphenylpyruvate dioxygenase (hereinafter HPPD) (abbreviated as "inhibitors"); imidazolinone herbicides such as imazethapyr, thifensulfuron methyl acetolactate synthase (hereafter abbreviated as ALS) inhibitors, such as sulfonylurea herbicides; 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS) ) inhibitors; glutamine synthetase inhibitors such as glufosinate; 2,4-D, dicamba, etc. Plants that have been given resistance to oxynil-type herbicides such as bromoxynil Preferred herbicide-tolerant transgenic plants are wheat, barley, rye, and oats. wheat, canola, sorghum, soybeans, corn, cotton, rice, rapeseed, beets, sugarcane, grapes, lentils, sunflowers, alfalfa, pome fruits, stone fruits , coffee, tea, strawberry, shiba, tomato, potato, cucumber, lettuce and other vegetables more preferably wheat, barley, rye, oats, and other grains; soybean; These are loco, rice, grapes, tomatoes, potatoes and pome fruits. Specific herbicide-tolerant plants are shown below. Glyphosate herbicide-resistant plants: Agrobacterium tomefaciens strain CP4 (Agrobac Glyphosate-tolerant EPSPS gene (CP4 epsps) derived from Tertium tumefaciens strain CP4 Glyphosate N-acetylacetone derived from Bacillus licheniformis The glyphosate N-acetyltransferase gene was modified to gene (gat4601 or gat4621), Ochrobacterium anthropi LBAA strain (Ochrobacterum an glyphosate oxidase gene (goxv247) derived from L. thropi strain LBAA, or The EPSPS gene (mepsps or 2me) with glyphosate-tolerant mutations from sorghum (Zea mays) The main plants are, for example, Alpha Luffa (Medicago sativa), Argentine canola (Brassica napus), cotton (Gossypi um hirsutum L.), creeping bentgrass (Agrostis stolonifera), corn (Zea mays L.), Polish canola (Brassica rapa), potato (Solanum tuberosum L. ), soybean (Glycine max L.), sugar beet (Beta vulgaris) and wheat (Triticum aestivum L.) Several glyphosate-tolerant plants are commercially available, such as CP4 Transgenic plants incorporating epsps are marketed under the trade name "Roundup Ready (registered trademark)" and are Transgenic plants into which t4601 or gat4621 has been introduced are called "Optimum GAT (trademark)" and "Optimum ( Transgenic plants into which mepsps or 2mepsps has been introduced under the trademark name "Gly canola" or other products. It is sold under the trade name "GlyTol™." For example, corn may be labeled as "Roundup Ready (trademark) Maize" or "Roundup Ready ( Trademark) 2 Maize", "Agrisure (Trademark) GT", "Agrisure (Trademark) GT / CB / LL", "Agrisu re (trademark) GT / RW", "Agrisure (trademark) 3000GT", "YieldGard (trademark) VT (trademark) Root worm™ RR2 and YieldGard™ VT Triple; "Soybean" and "Optimum GAT"; "Roundup Ready Cotton" "Roundup Ready (trademark) Flex Cotton" and "GlyTol (trademark)"; canola is "Roundup Ready™ Canola and Optimum® Gly canola; alfalfa "Roundup Ready™ Alfalfa"; rice is "Roundup Ready Rice"; sugarcane is "R Roundup Ready™ sugarbeet and InVigor™ sugarbeet; cum aestivum) is sold under the brand name "Roundup Ready™ wheat." Glyphosinate herbicide-resistant plants: Streptomyces hygroscopicus (Streptomyces Phosphinothricin N-acetyltransferase (Phos) from Escherichia coli hygroscopicus phinothricin N-acetyltransferase (PAT) gene (bar), strepto The PAT gene (p at), or Streptomyces viridochromogenes Tu494 strain (Streptomyces viridoch One or more of the synthetic PAT genes (pat syn) derived from the genus PAT (Pat syn) strain Tu494 was introduced. The main plants are Argentine canola (Brassica napus), chicory (Cichorium intybus), cotton (Gossypium hirsutum L.), corn (Zea mays L.), Polish canola (Brassica rapa), rice (Oryza sativa L.), Some groups include sugar beet (Glycine max L.) and sugar beet (Beta vulgaris). Fosinate-resistant plants are commercially available, for example, transgenic plants incorporating bar or pat. is a trademark of "LibertyLink(TM)", "InVigor(TM)", or "WideStrike(TM)". More specific glyphosinate-tolerant plants are sold under the name " Roundup Ready(TM) 2", "Liberty Link(TM)", "Herculex(TM) I", "He rculex RW”, “Herculex XTRA(TM)”, “Agrisure(TM) GT / CB / LL”, “Agrisure (trademark) CB / LL / RW" and "Bt10"; cotton is "FiberMax(trademark) Liberty Link(trademark)" Rice is "Liberty Link (trademark) Rice"; canola is "inVigor (trademark) Canola"; "Liberty Link™ Soybean"; "Liberty Link™ sugarbeet" It is sold under the trademark " Oxynil herbicide (e.g., bromoxynil)-resistant plants: Klebsiella pneumoniae The nitrilase gene (bxn) from Klebsiella pneumoniae subsp. Ozaenae ) can be obtained by introducing the main plants, such as Argentine canola (Br assica napus), cotton (Gossypium hirsutum L.) and tobacco (Nicotiana tabacum L.) Some oxynil-type herbicide-tolerant plants are commercially available. It is sold under the trade names "vigator™" or "BXN™". Examples of plants resistant to oxynil herbicides include cotton, which is resistant to oxynil herbicides, and Alze Cotton canola is sold under the trade name "Navigator™ Cotton." ALS herbicide-resistant plants: ALS herbicide derived from tobacco (Nicotiana tabacum) as a selection marker Carnation (Dianthus caryophyllus) into which the drug-resistant ALS gene (surB) has been introduced has been For example, "Moondust(TM)", "Moonshadow(TM)", "Moonshade(TM)", "Moonlite(TM)" Trademark)", "Moonaqua (Trademark)", "Moonvista (Trademark)", "Moonique (Trademark)", "Moonp Sold under the trade names "earl™," "Moonberry™," or "Moonvelvet™." The ALS gene (als) for herbicide resistance derived from Arabidopsis thaliana ) has been introduced into flax (Linum usitatissumum L.), for example, under the trademark "CDC Triffid Flax." It is sold under the name of ALS, which is a plant that has been introduced with the ALS herbicide resistance gene (zm-hra) derived from corn. Corn (Zea mays) tolerant to sulfonylurea and imidazolinone herbicides Arabidopsis thaliana L.) is sold, for example, under the trade name "Optimum GAT (trademark)". A strain of ALS-derived herbicide-resistant ALS gene (csr1-2) was introduced to produce imidazolinone-herbicide-resistant mutants. Soybeans having the above structure are sold, for example, under the trade name "Cultivance". Soybean into which the ALS herbicide-resistant gene (gm-hra) derived from the ALS gene (Gm-hra) has been introduced has been used for example in the "Tre Sold under the trade names "us (trademark)", "Plenish (trademark)" and "Optimum GAT (trademark)". In addition, the ALS gene, which confers resistance to ALS herbicides, derived from tobacco (Nicotiana tabacum cv. Xanthi) There is cotton that has been introduced with (S4-HrA). HPPD herbicide-resistant plants: HPPD gene (avhppd-03) derived from oat (Avena sativa) was introduced. For example, the above genes can be introduced into Streptomyces viridis at the same time. The PAT gene (pat) derived from Streptomyces viridochromogenes was introduced. Soybeans are listed as "Herbicide-tolerant" soybeans that are resistant to mesotrione and glufosinate. It is sold under the trademark "Ferrant Soybean line." 2,4-D-resistant plants or ACCase herbicide-resistant plants: Sphingobium herbicidvorans (S Aryloxyalkanoate dioxygenase (aryl) from Phingobium herbicidovorans Aad-1 (oxyalkanoate dioxygenase) gene was introduced into the plant, which is resistant to 2,4-D or ACCase herbicides. Corn containing the enzyme is sold, for example, under the trade name "Enlist™ Maize." Allyloxyalkanoate diesters derived from Delftia acidovorans Soybean with 2,4-D or ACCase herbicide tolerance introduced with the oxygenase gene (aad-12) and cotton are known and are sold, for example, under the trade name "Enlist™ Soybean". do. Dicamba herbicide-resistant plants: Stenotrophomonas maltophilia strain DI-6 Dicamba monooxygenase from Onas maltophilia strain DI-6 The soybean and It is known that the above genes were also expressed in cotton by Agrobacterium tomefaciens CP The glyphosate-resistant EPSPS gene from Agrobacterium tumefaciens strain CP4 ( Soybean (Glycine max L.) into which CP4 epsps has been introduced is available, for example, under the trademark "Genuity (registered trademark) Root It is sold under the trade name "dup Ready™ 2 Xtend™." Further plants with engineered tolerance to herbicides are well known, e.g., glyphosate. Alfalfa, apple, barley, eucalyptus, flax, and grapes are resistant to nitrate. , lentil, rapeseed, pea, potato, rice, sugar beet, sunflower, tobacco, Tomato, turfgrass and wheat (e.g., US 5188642, US 4940835, US 5633435, US 5804425, See US5627061); beans, cotton, soybeans, and peas tolerant to dicamba , potatoes, sunflowers, tomatoes, tobacco, corn, sorghum and sugarcane (e.g. See, for example, WO2008 / 051633, US7105724 and US5670454; soybeans, sugar beets, potatoes, tomatoes and tobacco (e.g., US6376754, US56460 24, see US5561236); cotton, peppers, apples, and tomatoes tolerant to 2,4-D , sunflower, tobacco, potato, corn, cucumber, wheat, soybean, sorghum and millet (e.g., US6153401, US6100446, WO2005 / 107437, US5608147 and US5670454 ALS-inhibiting herbicides (e.g., sulfonylurea herbicides or imidazolinone herbicides) Canola, corn, millet, barley, wheat, and other crops that are resistant to herbicides mustard, lettuce, lentils, melon, millet, oats, natto, potatoes, Rice, rye, sorghum, soybean, sugar beet, sunflower, tobacco, tomato and wheat (e.g. For example, US5013659, WO2006 / 060634, US4761373, US5304732, US6211438, US6211439 and See US6222100), and rice plants that are resistant to imidazolinone herbicides in particular are known. Certain mutations in the acetohydroxyacid synthase gene (e.g., S653 Rice having N, S654K, A122T, S653(At)N, S654(At)K, A122(At)T (e.g., US2003 / 021 7381, see WO2005 / 020673); HPPD inhibitor herbicides (e.g., isoxaflutole, etc.) Sasol herbicides; triketone herbicides such as sulcotrione and mesotrione; and pyrazoline herbicides. Diketonitriles, decomposition products of pyrazole herbicides such as linate or isoxaflutole Barley, sugarcane, rice, corn, tobacco, soybean, wheat, etc. that are resistant to rice, rapeseed, sugar beet, wheat and potato (e.g., WO2004 / 055191, WO1996 / 38567 see WO1997 / 049816 and US6791014); and co-cultivation of resistant PPO-inhibiting herbicides. Wheat, soybeans, cotton, sugar beets, rapeseed, rice, corn, sorghum, sugarcane, and and sugar beet (e.g., US2002 / 0073443, US2008 / 0052798, Pest Management Science, 61, 2005, 277-285).
[0137] Plants that have been given herbicide resistance through conventional breeding techniques or genomic breeding techniques include: For example, it is resistant to imidazolinone ALS-inhibiting herbicides such as imazethapyr and imazamox. Clearfield® Rice, a rice variety with a genotype, and Clearfield® Whey, a wheat variety with a genotype eat', sunflower 'Clearfield (registered trademark) Sunflower', lentil 'Clearfield (registered trademark) lentils and Clearfield® canola (BASF); Dyes that are resistant to sulfonylurea ALS-inhibiting herbicides such as thifensulfuron methyl "STS soybean"; Trione oxime herbicide, aryloxyphenoxypropion SR co-produced maize that is resistant to acetyl-CoA carboxylase inhibitors such as acid herbicides rn" (also known as "Poast Protected corn"); tribenuron, etc. Sunflower "ExpressSun (registered trademark)" that is resistant to sulfonylurea herbicides; Provisia (trademark) rice, which is resistant to acetyl-CoA carboxylase inhibitors such as thrombin, ) Rice; and Triazine Tolerant Canola "; and "Igrowth™", a sorghum that is tolerant to imidazolinone herbicides.
[0138] Rapid breeding technology (Rapid Variety Development Technology) has been developed to develop plants that are herbicide-resistant using genome editing technology. d Sulfonylurea herbicide tolerance using the Trait Development System (RTDS®) SU Canola (registered trademark) is a canola with RTDS (registered trademark). This corresponds to the oligonucleotide-directed mutagenesis of genome editing technology, Gene Repair Oligon DNA and RNA chimeric oligonucleotides (GRON) are used to express D in plants. This is a technique that allows for the introduction of mutations without cleaving the NA. Deletion of the endogenous IPK1 gene using link finger nucleases conferred herbicide resistance and and corn with reduced phytic acid content (see, for example, Nature 459, 437-441 2009). ); rice plants conferred herbicide resistance using CRISPR-Cas9 (e.g., Rice, 7, 5 (see 2014).
[0139] Plants that have been given herbicide resistance through new breeding techniques include grafted varieties. Examples include soybeans in which the scion has been given the properties of a GM rootstock through improved technology. The glyphosate-tolerant Roundup Ready® soybean was used as the rootstock. , soybean in which glyphosate tolerance was conferred to non-transgenic soybean scions (Weed Technology ogy 2013, 27, 412.
[0140] Examples of plants that have been given pest resistance include:
[0141] Examples of plants that have been given resistance to lepidopteran pests through genetic engineering include: It is an insecticidal protein derived from the soil bacterium Bacillus thuringiensis (hereafter referred to as Bt bacteria). Maize transgenic with a gene encoding a delta-endotoxin Zea mays L., soybean (Glycine max L.), cotton (Gossypium hirsutum L.), rice (Oryza sativa L.), poplar (Populus sp.), tomato (Lycopersicon esculentum), Eggplant (Solanum melongena) and sugarcane (Saccharum sp.) are examples of lepidopteran pests. Examples of delta-endotoxins that confer resistance to Cry1A, Cry1Ab, modified Cry1Ab, etc. Modified Cry1Ab (Cry1Ab with a truncated portion), Cry1Ac, Cry1Ab-Ac (Cry1Ab and Cry1Ac fused) modified hybrid protein), Cry1C, Cry1F, Cry1Fa2 (modified cry1F), moCry1 F (modified Cry1F), Cry1A.105 (a hybrid of Cry1Ab, Cry1Ac, and Cry1F) Proteins), Cry2Ab2, Cry2Ae, Cry9C, Vip3A, and Vip3Aa20. Examples of plants that have been given resistance to coleopteran pests through genetic engineering include: , which encodes delta-endotoxin, an insecticidal protein derived from the soil bacterium Bt. Examples include corn and potatoes with genes that have been introduced to enhance resistance to coleopteran pests. Examples of delta-endotoxins that confer cytotoxicity include Cry3A and mCry3A (modified Cry3A). ), Cry3Bb1, Cry34Ab1, Cry35Ab1, Cry6A, Cry6Aa and mCry6Aa (modified Cry6Aa) Examples include: Examples of plants that have been given resistance to dipteran pests through genetic engineering include: eCry3.1Ab, a hybrid protein that combines Cry3A and Cry1Ab from the soil bacterium Bt. Maize (Zea mays L.) and cowpea (Vigna ungulata) were transfected with a synthetic gene encoding Cotton (Gossypium uiculata) was transformed with the gene encoding the trypsin inhibitor CpTI. hirsutum L.) Furthermore, protea derived from arrowhead (Sagittaria sagi.jpgolia) Examples include poplar trees that have been transfected with a gene encoding API, an enzyme inhibitor protein A, and It shows resistance to pests. The insecticidal protein that confers pest resistance to plants is a hybrid of the above insecticidal proteins. This also includes proteins with partial deletions and modified proteins. The rDNA protein is a recombinant protein that combines different domains of multiple insecticidal proteins. These are produced by combining the following two genes, and Cry1Ab-Ac and Cry1A.105 are known. Known examples of such proteins include Cry1Ab, which lacks a portion of its amino acid sequence. The modified protein contains one or more of the amino acids of the naturally occurring delta-endotoxin. Modified proteins include Cry1Fa2, moCry1F, and mCry3A. A modified protein is a toxin in which a non-naturally occurring protease recognition sequence has been inserted. For example, Cry3A05, in which a cathepsin G-recognition sequence is inserted into the Cry3A toxin. 5 (see WO2003 / 018810). Using genetic engineering, a modified BT protein, Cry51Aa2 (Cry51Aa2.834_16), was introduced. The cotton plant (event MON88702) was developed by Monsanto and is effective against Lygus lineolaris and other insects. Resistant to Hemiptera such as Lygus species and aphids, and thrips such as Frankliniella species Indicates gender. In addition, it is used as an insecticidal protein to confer pest resistance to plants through genetic engineering technology. , for example, Bacillus cereus or Bacillus popiliae popilliae; plant insecticidal proteins Vip1, Vip2, and Vip3 (subclone Known examples of Vip3Aa to Vip3Aj, Vip3Ba, Vip3B, and Vip3Ca are: For example, Vip3Aa20 and Vip3Aa61 are known) and Vip4; Photorhabdus luminescence Photorhabdus spp. such as Photorhabdus luminescens or Xenorhabdus Xenorhabdus nematophilus and other species of the genus Xenorhabdus Insecticidal proteins derived from bacteria that are symbiotic with nematodes (that colonize nematodes), such as Pseudomonas spp. Produced by animals, including insect-specific neurotoxins such as scorpion toxins, spider toxins, and bee toxins toxins produced by fungi, such as Streptomyces toxins; Plant lectins such as pea lectin, barley lectin, and snowdrop lectin; Rutinine; trypsin inhibitor, serine protease inhibitor, patatin, cystatin, papain Protease inhibitors such as lysine inhibitors; ricin, maize-RIP, abrin, rufin Ribosome-inactivating proteins (RIPs) such as saporin and bryodin; Ecdysteroid oxidase, ecdysteroid-UDP-glucosyltransferase steroid metabolic enzymes such as esterase and cholesterol oxidase; ecdysone inhibitors; HMG-C oA-reductase; ion channel inhibitors such as sodium channel blockers and calcium channel blockers Channel inhibitors; juvenile hormone esterase; diuretic hormone receptor; stilbene synthase bibenzyl synthase; chitinase; and glucanase.
[0142] In addition, the introduction of one or more insecticidal protein genes can confer pest resistance. Plants that have been cultivated are already known, and some plants are commercially available. An example of cotton that has been given insect resistance is cotton that expresses the insecticidal protein Cry1Ac derived from Bt bacteria. "Bollgard™ cotton," "BXN™ Plus Bollgard™ Cotton," and "BXN™ (Trademark) Plus Bollgard (Trademark) Cotton", "JK 1", "Roundup Ready (Trademark) Bollgard (trademark) Cotton" and "Ingard (trademark)"; insecticidal protein modified Cry1F (Cry1 "Herculex™ I" and "Herculex™ CB" expressing Fa2; insecticides derived from Bt bacteria "VIPCOT (trademark) Cotton" expressing the insecticidal protein Vip3A; "Bollgard II™ cotton" and "Roundup Ready™ Bol lgard II (trademark) Cotton", "Roundup Ready (trademark) Flex (trademark) Bollgard II (trademark) Cotton" and "Fivermax (trademark) Liberty Link (trademark) Bollgard II (trademark)" ; Bollgard III (Registered Trademark) expressing insecticidal proteins Cry1Ac, Cry2Ab, and Vip3A derived from Bt bacteria. "Bollgard® III x Roundup Ready™ Flex™" and "Bollgard® III x Roundup Ready™ Flex™"; Bt VIPCOT (trademark) Roundup Ready F expresses the fungal insecticidal proteins Vip3A and Cry1Ab. lex (trademark) Cotton"; "VIPCOT" expressing the insecticidal proteins Vip3A and Cry1Ac derived from Bt bacteria; (registered trademark) Cotton"; "WideS" expressing insecticidal proteins Cry1Ac and Cry1F derived from Bt bacteria; trike (trademark) Cotton," "WideStrike (trademark) Roundup Ready (trademark) Cotton" and Widestrike™ Roundup Ready Flex™ Cotton; insecticidal protein derived from Bt bacteria "TwinLink™ Cotton" and "Glytol™ x Twin" expressing Cry1Ab and Cry2Ae link (trademark)"; Wides trike (registered trademark) 3" and "Widestrike (trademark) x Roundup Ready Flex (trademark) x VIPCOT (trademark) Cotton"; "G" expressing insecticidal proteins Cry1Ab, Cry2Ae, and Vip3A derived from Bt bacteria; lytol (trademark) x Twinlink (trademark) x VIPCOT (trademark) Cotton, which are commercially available. It is being done. An example of corn that has been conferred pest resistance is the insecticidal protein Cry3Bb derived from Bt bacteria. "YieldGard® Rootworm RW", "YieldGard™ RW + RR", which express 1; "YieldGard(TM) VT(TM) Rootworm(TM) RR2" and "MaxGard(TM)"; YieldGard® VT Triple expressing the original insecticidal proteins Cry3Bb1 and Cry1Ab " and "YieldGard™ Plus with RR" expressing the insecticidal protein Cry1Ac derived from Bt bacteria "Bt Xtra™ Maize" expresses the insecticidal proteins Cry1Ab and Cry3Bb1 derived from Bt bacteria. "YieldGard Plus (registered trademark)" expressing the insecticidal protein Cry1Ab derived from Bt bacteria; Bt10”, “Liberty Link (trademark) Yieldgard (trademark) Maize”, “Agrisure (trademark) GT / CB / LL" and "YieldGard™ CB + RR": insecticidal protein Cry1A.105 derived from Bt bacteria and YieldGard™ VT Pro™ and Genuity™ VT expressing Cry2Ab2 Double Pro (trademark)"; Agrisure (registered trademark) expressing the insecticidal protein mCry3A derived from Bt bacteria; "Agrisure (trademark) RW" and "Agrisure (trademark) GT / RW": expressing the insecticidal protein Cry9C derived from Bt bacteria. "Starlink™ Maize" expressing the insecticidal protein Cry1Ab derived from Bt bacteria; rd (trademark)", "MaizeGard (trademark)", "NaturGard KnockOut (trademark)", "Maximizer ( Trademark)", "Roundup Ready (Trademark) YieldGard (Trademark) maize", "Agrisure (Trademark) CB / L "Mavera™ YieldGard™ Maize" and "Mavera™ YieldGard™ Maize"; insecticidal protein Cry1A derived from Bt bacteria b) "Agrisure (registered trademark) 3122" expressing Cry1F, modified Cry3A, Cyr34Ab1, and Cyr35Ab1 "Agrisure (registered trademark) Viptera" expressing the insecticidal protein Vip3Aa20 derived from Bt bacteria; B Agrisure (registered trademark) Vipte expressing the insecticidal proteins Vip3Aa20 and Cry1Ab derived from the fungus Agrisure® Viptera® 2100 and Agrisure® Viptera® 3110; insecticides derived from Bt bacteria Agrisure (registered trademark) Vipte expressing the virulence proteins Vip3Aa20, Cry1Ab, and modified Cry3A. Agrisure (registered trademark) Viptera (registered trademark) 3100, Agrisure (registered trademark) Viptera (registered trademark) 3111 and Agrisure (registered trademark) Viptera™ 4: a compound containing the insecticidal proteins Vip3Aa20, Cry1Ab and modified Cr derived from Bt bacteria Agrisure® Viptera™ 3220 expressing y1F, an insecticidal protein derived from Bt bacteria. Agrisure (registered trademark) expressing the protein Cry3.1Ab (a chimeric protein of Cry3A-Cry1Ab) Duracade (trademark)"; insecticidal protein eCry3.1Ab derived from Bt bacteria (a chimeric protein of Cry3A-Cry1Ab) Agrisure (registered trademark) Duracade expressing modified Cry3A, Cry1Ab, and modified Cry1F (trademark) 5122"; insecticidal protein eCry3.1Ab derived from Bt bacteria (Cry3A-Cry1Ab chimeric protein) Agrisure® Duracad® strain expressing modified Cry3A, modified Cry1Ab, and Vip3A variants "Hercules e (trademark) 5222" expressing the insecticidal proteins Cyr34Ab1 and Cyr35Ab1 derived from Bt bacteria; lex (trademark) RW" expressing the insecticidal proteins Cyr34Ab1, Cyr35Ab1, and Cry1F derived from Bt bacteria "Herculex XTRA (trademark)": insecticidal proteins Cry1A.105, Cry2Ab2 and Cry3B derived from Bt bacteria Genuity® VT Triple Pro™ expresses b1, an insecticidal protein derived from Bt bacteria. Genuity β-lactamase expressing the proteins Cry1F, Cry2Ab, Cyr34Ab1, Cyr35Ab1, Cry3Bb1, and Cry1A.105 (registered trademark) SmartStax (trademark)"; insecticidal proteins derived from Bt bacteria, modified Cry1F, Cry2Ab and Cr "Power Core™" expressing y1A.105; modified Cry1F, an insecticidal protein derived from Bt bacteria; "Herculex XTRA (trademark) RR" expressing r34Ab1 and Cyr35Ab1; insecticidal proteins derived from Bt bacteria "Optimum (registered trademark)" expressing modified Cry1F, Cyr34Ab1, Cyr35Ab1, Cry1Ab, and modified Cry3A Intrasect Xtreme™: insecticidal proteins derived from Bt bacteria, modified Cry1F, Cyr34Ab1, and Cyr35Ab Optimum® Intrasect XTRA expressing Cry1Ab and Cry1Ab; an insecticidal protein derived from Bt bacteria and "Optimum (registered trademark) TRIsect" expressing modified Cry1F and modified Cyr3A proteins. These are commercially available. Another example of a plant that has been given resistance to pests is the insecticidal protein Cry3A derived from Bt bacteria. The potatoes expressing the compound "Atlantic NewLeaf (trademark) potato" and "NewLeaf (trademark) Russet Burbank potato", "Lugovskoi plus", "Elizaveta plus", "Hi-Lite NewLeaf (commercial Superior NewLeaf (trademark) Y potato, Superior NewLeaf (trademark) potato" and "Shepody NewLeaf (trademark) Y pot ato"; rice "hanyou 63" expressing insecticidal proteins Cry1Ab and Cry1Ac derived from Bt bacteria; "Huahui-1": Intacta® soybean expressing the insecticidal protein Cry1Ac derived from Bt bacteria Boundup Ready™ 2 Pro; BAR, an eggplant expressing the insecticidal protein Cry1Ac derived from Bt bacteria; Examples include Bt Begun-1, -2, -3 and -4, which are commercially available. In addition, we have developed a corn variety called YieldGard corn rootworm resistant. tworm," "YieldGard VT," "Herculex RW," "Herculex Rootworm," and "Agrisure" "CRW"; "YieldGard corn borer" corn with resistance to corn borers , “YieldGard plus”, “YieldGard VT Pro”, “Agrisure CB / LL”, “Agrisure 3000G T”, “Hercules I”, “Hercules II”, “KnockOut”, “NatureGard” and “StarLink Western bean cutworm, corn borer, black cutworm and four Lureworm-resistant corn varieties "Herculex I" and "Herculex Xtr" a", "NewLeaf", "NewLeaf Y" and "NewLeaf Plus"; Corn Borer and Corn Leaf 'YieldGard Plus' Corn with Resistance to Cornworm; Cotton "Bollgard I" and "Bollgard II" with resistance to the Japanese dung moth; Box moth, cotton boll worm, fall armyworm, beet armyworm, cabbage "Bollga" cotton, which is resistant to looper, soybean looper and pink bollworm rd II, WideStrike™, and VipCot; potato varieties with tobacco hornworm resistance Potatoes "NewLeaf", "NewLeaf Y" and "NewLeaf Plus"; eggplant borer, fruit borer and cotton bollworm-resistant eggplants "Bt brinjal" and "Dumaguete Long "Purple" and "Mara" (see, for example, US Pat. No. 5,128,130) are known. Further plants with pest resistance are commonly known, for example, stem borer resistance. resistant rice (see, for example, Molecular Breeding, Vol. 18 (2006), No. 1), Lepidoptera-resistant lettuce (see, e.g., US5349124), Lepidoptera (e.g., rice stem borer, skipper, rice armyworm) , rice leafroller, rice caseworm, and rice armyworm) For example, rice (see, for example, WO2001 / 021821) can be used. These methods are generally known to those skilled in the art and are described, for example, in the publications mentioned above.
[0143] Plants that have been given pest resistance through RNA interference technology include those that are resistant to lepidopteran pests (e.g., corn). Borers, corn earworms, black cutworms and other cutworms, and four Corn resistant to lureworms and coleopteran pests (corn rootworms) The firmness is "SmartStax (registered trademark)", "SmartStax (registered trademark) Pro" or "Genuity (registered trademark)". These products are commercially available or under development under the trademark "SmartStax Pro."
[0144] Plants that have been given pest resistance through conventional breeding techniques or genomic breeding techniques For example, the aphid resistance gene Rag1 (Resistance to Aphis glycines 1) " gene or "Rag2 (Resistance to Aphis glycines 2)" gene Soybean resistant to the Aphis glycines (J. Econ. Entomol., 2015, 108, 326. Soybean (Phytopa gracilis) resistant to the soybean cyst nematode (Heterodera glycines) ethology, 2016, 106, 1444. (See also) Resistance to root-knot nematodes (Meloidogyne incognita) Cotton showing resistance to the brown planthopper (J. Nematol., 2009, 41, 140); Rice showing resistance to the brown planthopper " Kanto BPH1; and Fukuminori, a soybean variety that is resistant to the common cutworm.
[0145] These pest-resistant plants can be used to protect against any harmful insects (especially lepidopteran insects, coleopteran insects, etc.). Resistance to insects (Diptera, Coleoptera, and Arachnids), harmful spiders, and harmful nematodes The plant to which pest resistance has been imparted is preferably a barley or oat (e.g., wheat, barley, rye, oats), corn, canola, sorghum, soybeans, rice, rapeseed Seeds, sugar beets, sugarcane, grapes, lentils, sunflowers, alfalfa, pome fruits, Stone fruits, peanuts, coffee, tea, strawberries, grass, vegetables (e.g., tomatoes, potatoes) , Cucurbitaceae and lettuce), more preferably soybean, corn, tomato and rice and cereals (e.g., wheat, barley, rye, and oats), Most preferably, soybeans, rice, corn, and wheat (e.g., wheat, barley, rye) are used. and oats).
[0146] Examples of plants that have been given disease resistance include:
[0147] Plants that have been given disease resistance through genetic engineering techniques, for example, have so-called "pathogenicity-related Proteins linked to phosphodiesterases (PRPs, see e.g. EP 0 392 225) or so-called "antifungal proteins" (AFPs, See, for example, US 6,864,068. Various antifungal proteins have been isolated from specific plant species and are now well known. Examples of pathogenic substances and plants capable of synthesizing such antipathogenic substances are e.g., EP 0392225, WO1993 / 05153, WO1995 / 33818, and EP0353191. Plants that are resistant to ungicidal pathogens, viral pathogens, and bacterial pathogens Resistance genes are created by introducing disease resistance genes. Many resistance genes have been identified. These resistance genes have been isolated and used to improve disease resistance. For example, tobacco mosaic virus (TMV)-infected tobacco plants can be used to generate TMV-resistant tobacco plants. N gene introduced into susceptible tobacco lines (see, e.g., US 5571706), enhanced pathogen resistance Prf genes introduced into plants to obtain resistance (see, for example, WO1998 / 02545), and sh Resistance to bacterial pathogens such as Pseudomonas syringae The Rps2 gene ( See, for example, WO1995 / 028423. Plants that exhibit a systemic acquired resistance response include those that express the N gene. (See, e.g., US 66306 18) Further examples of known resistance genes include the the Xa21 gene (see, e.g., US5952485, US5977434, WO1999 / 009151, WO1996 / 022375), The Rcg1 gene for Colletotrichum resistance (e.g., US2006 / 225152) See, e.g., US5859332, WO2008 / 017706), prp1 gene (see, e.g., US5859332, WO2008 / 017706), plum pox virus ppv-cp gene (see, for example, US PP15,154Ps), P1 gene (see, for example, See, for example, US Pat. No. 5,968,828), Phytophthora infestation in potatoes s) to introduce resistance to genes such as Blb1, Blb2, Blb3, RB2, and Rpi-vnt1 (e.g. See, e.g., US7148397), LRPKml gene (see, e.g., WO1999 / 064600), potato the P1 gene for virus Y resistance (see, e.g., US5968828), the HA5-1 gene (see, e.g., US58 77403 and US6046384), potato virus X (PVX), potato virus Y (PVY), PI to induce broad-spectrum resistance to viruses such as Potato Leaf Curl Virus (PLRV) P genes (see, for example, EP0707069), as well as Arabidopsis (A rabidopsis) (e.g., US670695 2 and EP1018553). Also, bean golden mosaic virus Beans that are resistant to Bean golden mosaic virus (BGMV) are developed using RNA interference. The plant is resistant to the virus through the use of a technology that encodes the double-stranded RNA gene (sense and d antisense ac1 gene) was introduced, which inhibited the synthesis of BGMV replication proteins, resulting in the BG The method for producing such a plant is generally known to those skilled in the art, and can be, for example, as described in the publications mentioned above. Antipathogenic substances that can be expressed by such plants include, for example, ion channels. Blockers (sodium channel blockers, calcium channel blockers, etc.); viral KP1, KP4 and KP6 toxin; stilbene synthase; bibenzyl synthase; chitinase; glucanase proteins; so-called "pathogenesis-related proteins" (PRPs; see, for example, EP 0 392 225); proteins produced by microorganisms Antipathogenic substances (e.g., peptide antibiotics, heterocyclic antibiotics (e.g., WO199 5 / 033818) and protein or polypeptide factors involved in plant pathogen defense. Examples include the so-called "plant disease resistance genes" described in WO2003 / 000906. Antipathogenic substances produced by plants are effective against various pathogens such as fungi, viruses, and bacteria. The present invention provides a method for protecting plants from microorganisms. The cereals that are used include wheat, barley, rye, and oats, soybeans, corn, and rye. Rapeseed, rapeseed, pome fruits, stone fruits, peanuts, coffee, tea, strawberries, grasses; vines and wild plants Vegetables (e.g., tomatoes, potatoes), cucurbits, papayas, melons, lentils s) and lettuce, more preferably soybean, tomato, rice and cereals (e.g., wheat, onion, etc.). barley, rye and oats), most preferably soybean, rice and wheat (e.g. For example, wheat, barley, rye and oats. Plants that are resistant to fungal pathogens include, for example, soybeans. Resistant to rust fungi (Phakopsora pachyrhizi and Phakopsora meibomiae) soybean (see, for example, WO2008 / 017706); potato blight (Phytophthora infestans); Solanaceous plants such as cotton, tomato, and potato that are resistant to 7148397, see EP1334979); Colletotrichum graminico Colletotrichum resistant corn (e.g., U la) S2006 / 225152); Resistant to apple scab (Venturia inaequalis) Apples (see, e.g., WO1999 / 064600); Fusarium species (e.g., Fusarium graminearum , fusarium sporotrichioides, fusarium lateritium, fusarium pseudograminearum , fusarium sambucinum, fusarium culmorum, fusarium poae, fusarium acuminatum , Fusarium equiseti) in plants (e.g., rice, wheat, barley) , rye, corn, oats, potatoes, melons, soybeans, and sorghum) (e.g. See, for example, US 6,646,184, EP 1,477,557; broad-spectrum fungicide-resistant corn, soybeans, and wheat, barley, rye and oats), rice, tobacco, sorghum, Plants such as cane and potato (e.g., US5859332, US5689046, US6706952, EP1018553 and US6020129). Plants that are resistant to bacterial pathogens include, for example, Xylella fastida. rice with resistance to xylella fastidiosa (see, e.g., US 6,232,528); Rice, cotton, soybean, potato, sorghum, and tomato that are resistant to bacterial blight Plants such as corn, wheat, barley, sugarcane, tomato, and pepper (e.g., W see US 5952485, US 5977434, WO1999 / 09151, WO1996 / 22375); Pseudomonas Tomatoes with resistance to pseudomonas syringae (e.g., Can. J. Plant Path., 1983, 5:251-255). Plants that are resistant to viral pathogens include, for example, plum pox virus. Stone fruits (e.g., plums, almonds, apricots, cherries, peaches, nectarines) (see, for example, US PP15154Ps, EP0626449); Potatoes resistant to potato virus Y (e.g., US See 5968828; Resistant to tomato spotted wilt virus potatoes, tomatoes, cucumbers and legumes (e.g., EP0626449, US597 3135); resistance to maize streak virus maize (see, e.g., US 6,040,496); papaya ring spot virus (papaya ring spot virus papaya with resistance to ot virus (see, e.g., S5877403, U.S. Pat. No. 6,046,384); Cucurbitaceae plants (e.g., cucumber mosaic virus) resistant to cucumber mosaic virus cucumbers, melons, watermelons and pumpkins) and nightshades (e.g. potatoes) , tobacco, tomatoes, eggplants, paprika, chillies and peppers) (see, e.g., US6849780 Watermelon mosaic virus 2 and zucchini yellow mosaic virus Cucurbitaceae plants (e.g., cucurbitaceae plants) that are resistant to Zucchini yellow mosaic virus cucumbers, melons, watermelons and pumpkins) (see, e.g., U.S. Pat. No. 6,015,942); potato cigars Potatoes resistant to viruses (potato leafroll virus) (e.g., US55762 potato virus X, potato virus Y Y), and broad resistance to viruses such as potato leafroll virus Potatoes with resistance (see, for example, EP 0707069); Bean Golden Mosaic Bean golden mosaic virus resistant common beans (e.g., Mol Pl ant Microbe Interact. 2007 Jun;20(6):717-26. Plants resistant to antibiotics (e.g., kanamycin, neomycin, and ampicillin) The naturally occurring bacterial nptII gene is involved in the production of the antibiotics kanamycin and neomycin. The ampicillin resistance gene ampR (also known as blaTEM1) is expressed in the bladder. Salmonella paratyphi (which is a bacterium) is derived from the bacterium Salmonella paratyphi and is a It is used as a marker gene in the transformation of plants. It is involved in the synthesis of beta-lactamase, an enzyme that neutralizes antibiotics of the penicillin group. Plants that are resistant to antibiotics include, for example, potatoes, tomatoes, flax, and canola. , rapeseed, canola seeds, and corn (see, e.g., Plant Cell Reports, 2 0, 2001, 610-615, Trends in Plant Science, 11, 2006, 317-319, Plant Molecula r Biology, 37, 1998, 287-296, Mol Gen Genet., 257, 1998, 606-13. Plant Cell Reports, 6, 1987, 333-336, Federal Register (USA), Vol. 60, No. 113, 1995, 311 39 pages. Federal Register (USA), Vol. 67, No. 226, 2002, pp. 70392, Federal Register (U SA), Vol. 63, No. 88, 1998, pp. 25194, Federal Register (USA), Vol. 60, No. 141, 199 5, 37870 pages, Canadian Food Inspection Agency, FD / OFB-095-264-A, October 1999, FD / (See OFB-099-127-A, October 1999). Preferably, the plant is soybean, tomato, and selected from the cereals (e.g., wheat, barley, rye and oats), most preferably It is selected from soybeans and cereals (such as wheat, barley, rye and oats). Plants that have been made resistant to plant viruses are available, such as papaya, Rainbow papaya, which has been given resistance to Papaya ringspot virus ow", "SunUp" and "Huanong No. 1"; against potato late blight (Phytophthora infestans) Potatoes that are resistant to the disease, such as "Innate(R) Hibernate" and "Innate(R) Glaciate" and "Innate® Acclimate"; Potato virus Y and / or Potatoes that are resistant to potato leaf curl virus (PLRV) include the "Newleaf (trademark)" variety. It can be obtained.
[0148] Plants that have been given disease resistance through conventional breeding techniques or genomic breeding techniques include: Rice that has been given resistance to rice blast; Rice with resistance to leaf rust; Wheat with resistance to stripe rust; stem rust Wheat with resistance to powdery mildew Wheat with resistance to leaf blotch; Wheat with resistance to leaf blotch Wheat with glume blotch resistance; tan spot resistance Wheat with resistance to powdery mildew Wheat; Barley with resistance to dwarf leaf rust; Net blotch Barley with resistance to blotch; barley with resistance to scald Barley with resistance to Ramularia leaf spot disease Barley with resistance to anthracnose; Corn with resistance to anthracnose ; Maize with resistance to gray leaf spot Koshi; Maize with resistance to Goss's wilt; Fusari Maize with resistance to Fusarium stalk rot; Asia Soybean with resistance to Asian soybean rust; Phytophthora stem rot Soybean with resistance to sudden death syndrome (SDS) Soybean with resistance to Phytophthora rot syndrome; Peppers with resistance; powdery mildew resistant lettuce Tomatoes with resistance to bacterial wilt; Geminivirus Tomatoes resistant to ni virus; Resistance to downy mildew Lettuce; rapeseed, cabbage, and sprouts resistant to clubroot Brassica vegetables such as cabbage, cauliflower, collard greens (Borekale), and broccoli Rapeseed, cabbage, Brussels sprouts, etc., which have been given resistance to black leg disease. Brassica plants such as cauliflower, collard greens (Borekale), and broccoli; Fusari Resistance to Fusarium wilt of melon caused by Um oxysporum f.sp. melonis Examples include melons that have been given resistance (see, for example, WO2009 / 000736).
[0149] Plants that have been conferred disease resistance through genome editing include talen and CRISPR. Using Cas9, we identified the powdery mildew resistance gene (MILDEW RESISTANCE LOCUS O, hereafter referred to as MLO). By deleting the .GAMMA. gene, the Panko strain is resistant to powdery mildew. Wheat (see, for example, Nat. Biotech., 32, 947-951 2014); using CRISPR-Cas9 In this study, the SlMLO1 gene, one of the MLO genes, was deleted to suppress powdery mildew. dew) (e.g., Scie.jpgic Reports 7, Article n umber: 482 2017 ); by editing the OsSWEET14 gene in rice using talen, Xanthomonas oryzae, which causes bacterial leaf blight oryzae pv. Oryzae) (see Nat. Biotechnol. 30, 390-392 2012) By using CRISPR-Cas9 to modify the OsERF922 gene in rice, Resistant to Magnaporthe oryzae, which causes blast disease rice (PLoS ONE 11:e0154027. doi: 10.1371 / journal.pone.0154027 2016 reference); Disruption of the recessive eIF4E (eukaryotic translation initiation factor 4E) gene using RISPER-Cas9 Due to cucumber vein yellow ingvirus(CVYV), zucchini yellow mosaic virus(ZYMV) , cucumber resistant to papaya ringspot virus-type W (PRSV-W) (Mol. PlantPathol. 17, 7 1140-1153 2016); CRISPR-Cas9 was used to identify RXLR effector genes. Disruption of the Avr4 / 6 gene inhibits stem disease caused by Phytophthora sojae. Soybean resistant to phytophthora stem and root rot (Mol Plant Pathol 17(1) 127-139 (see 2016).
[0150] Vent Rvi6 (previously known as Rvi6) is resistant to apple scab caused by Uria inaequalis. Apples resistant to apple blight (e.g., Plant Biotech.J., 12, 2-9, 2014); GM, a breeding technique that uses grafting An example of a virus that gives the scion the characteristics of a tree is the Prunus necrotic ringspot virus. Transgenic rootstocks that are resistant to ringspot virus infection were used to cultivate non-transgenic The sweet cherry whose characteristics were transferred to the scion (Plant Biotech. J., 12, 1319-1328) (See 2014).
[0151] Examples of plants with altered product qualities include: The quality modification of a product means the synthesis or formation of an altered component compared to the corresponding wild-type plant. The alteration of the quality of the product is referred to as an increase or decrease in the amount of vitamin A synthesis. Modifications that increase or decrease the content of carbohydrates, amino acids, proteins and starches, and various oils Plants, as well as modified plants with reduced nicotine content.
[0152] Plants whose product quality has been modified by genetic engineering are, for example, those related to lignin production. S-Adenosyl-L-methionine:trans-Caffeoyl CoA from Alfalfa The gene for 3-methyltransferase (ccomt) that produces double-stranded RNA was introduced into the RNA Alfalfa with reduced lignin content due to interference; By introducing the 12:0 ACP thioesterase gene from Umbellularia californica, Canola "Laurical" has an increased content of triacylglycerols containing lauric acid due to the addition of "Canola" trademark; a portion of the omega-6 desaturase from soybean, a fatty acid desaturase enzyme By introducing the gene (gm-fad2-1), the expression of this gene was suppressed, and the oleic acid content was reduced. Increased soybean "Plenish™" and "Treus™"; soy-derived acyl-acyl Generating double-stranded RNA from the carrier protein thioesterase gene (fatb1-A) The gene and the soybean delta-12 desaturase gene (fad2-1A) produce double-stranded RNA. Vistive Gold™ soybeans with reduced saturated fatty acid content due to gene introduction "; the delta-6 desaturase gene from Primrose (Pj.D6D) and the delta-6 desaturase gene from Neurospora crassa By introducing the -12 desaturase gene (Nc.Fad3), one of the ω3 fatty acids Genetically modified soybean producing stearidonic acid; Thermococcus for starch degradation By introducing the thermostable alpha-amylase gene (amy797E) from the fungus Thermococcales sp. Enogen (registered trademark) is a corn that enhances bioethanol production by Corynebacterium glutamate for the production of the amino acid lysine By introducing the dihydrodipicolinate synthase gene (cordapA) derived from Cordaporus icum, "Mavera™ Maize" and "Mavera™ Yie" corn varieties with increased lysine production ldGard™ Maize; granule-bound starch synthase derived from potato; By introducing the antisense gene gbss of GBSS, the amino acid sequence of starch granules was "Amflora(TM)" potatoes with reduced sucrose and increased amylopectin content "Starch Potato": PhL, a transcription factor gene that promotes starch degradation from potato, and By introducing the genes pPhL and pR1 that generate double-stranded RNA of R1, starch degradation was suppressed and asparagus By introducing the gene asn1, which produces double-stranded RNA of the gene Asn1 involved in paragine synthesis, Inhibition of asparagine synthesis (aspartic acid involved in the production of acrylamide, a carcinogenic substance, by heating) (The purpose is to suppress the accumulation of paragine and reducing sugars) and potato-derived polyphenol oxidase The introduction of the gene ppo5, which produces double-stranded RNA of the enzyme Ppo5, suppressed black spot formation. Potato "Innate(R) Cultivate", "Innate(R) Generate", "In Innate® Accelerate, Innate® Invigorate, Innate® "Innate® Glaciate," "Innate® Acclimate," and "Innate® Hibe" rnate"; quinolinic acid phosphoribosyltransferase derived from tobacco (Nicotiana tabacum) By introducing an antisense gene (NtQPT1) of the enzyme QpTase, nicotine-containing Reduced-dose tobacco: phytoe from daffodil (Narcissus pseudonarcissus) Carotenoid synthase gene (psy) and carotenoid-synthesizing soil bacterium (Erwinia uredovora) By introducing the carotene desaturase gene (crt1) from rice and expressing it specifically in the endosperm, Golden rice, which produces β-carotene in its milk tissue and produces rice rich in vitamin A, Other examples include rice with improved amylopectin content. Modified potatoes and corn (e.g., US6784338, US2007 / 0261136, WO1997 / 044 71); oil-modified canola, corn, cotton, grapes, cattails (see il), cowpea (catalpa), rice, soybean, rapeseed, wheat, sunflower, bitter melon, red cucumber Safflower and plants of the genus Vernonia (e.g., US7294759, US7157621 , US5850026, US6441278, US5723761, US6380462, US6365802, US6974898, WO2001 / 07949 9, US 2006 / 0075515 and US 7294759); sunflower with increased fatty acid content (see, e.g., US 6,084,164); soybeans with reduced allergen content (see, e.g., U.S. Pat. No. 6,864,362); Reduced tin tobacco (e.g., US 2006 / 0185684, WO 2005 / 000352 and WO 2007 / 06463 6); canola and soybeans with increased lysine content (e.g., Bio / Technology 13,199 5, 577-582); modified composition of methionine, leucine, isoleucine, and / or valine Modified corn and soybeans (see, e.g., US6946589, US6905877); sulfur amino acids soybeans with increased levels of lactic acid bacteria (see, for example, EP 0929685, WO 1997 / 041239); 3'-Phosphoadenosine-5'-phosphosulfate reductase (3'-Phosphoadenosine-5 By expressing α-phosphosulfate reductase specifically in the leaf surface, the methionine content increases. corn (see PNAS, 2017, 114(43), 11386); free amino acids (e.g., aspartame) Lactic acid, aspartic acid, serine, threonine, alanine, histidine and glutamic acid ) content (see, e.g., US6727411); Tomatoes with increased amino acid content potato (see, for example, WO05 / 077117); potato with modified starch content; rice and corn (see, for example, WO 1997 / 044471 and US 7,317,146); Modified tomatoes, corn, grapes, alfalfa, apples, beans, and peas Beans (see, e.g., WO00 / 04175); corn modified for phenolic compound content , rice, sorghum, cotton, and soybean (see, e.g., US2008 / 0235829); Vitamin A content Tomato and canola with increased vitamin E (see, e.g., US6797498, US7348167); Increased content in tomatoes, canola, soybeans, wheat, sunflowers, rice, corn, Barley and rye (see, e.g., US 7,348,167, WO 2004 / 058934); Nutritionally modified alfalfa, apples, beans, corn, grapes, tomatoes, and and pea (see, for example, WO 00 / 04175). Methods for producing such plants are generally known to those skilled in the art and are described, for example, in the publications mentioned above. Plants include soybeans, canola, tomatoes, rice, and cereals (e.g., wheat, barley, rye). wheat and oats), most preferably soybean, canola, rice, wheat and and barley.
[0153] Plants whose product quality has been modified by conventional breeding techniques or genomic breeding techniques Nexera® Canola, a rapeseed that produces unsaturated omega-9 fatty acids; "Yumeminori" soybean with reduced content; rice with improved taste, e.g., Amino Rice varieties with reduced sucrose content, such as "Yumepirika," are available on the market. The characteristics of the fruit (e.g., fruit weight, aroma, juiciness, and sugar content) can be improved by selection. Strange citrus fruits are known (see Scie.jpgic Reports 7, 4721 2017).
[0154] Plants with altered nutrient utilization include, for example, plants with altered nitrogen or phosphorus assimilation or metabolism. Plants with enhanced nitrogen assimilation and nitrogen utilization capabilities through genetic engineering are also included. Potential plants include, for example, canola, corn, wheat, sunflower, rice, tobacco, Coconut, soybeans, cotton, alfalfa, tomatoes, wheat, potatoes, sugar beets, sugarcane and rapeseed (e.g., WO1995 / 009911, WO1997 / 030163, US6084153, US595 (See US Pat. No. 5651 and US Pat. No. 6,864,405). Plants with improved phosphorus uptake through genetic engineering include Examples include alfalfa, barley, canola, corn, cotton, tomatoes, and Seeds, rice, soybeans, sugar beets, sugarcane, sunflowers, wheat and potatoes are examples. (See, e.g., US7417181, US2005 / 0137386). Methods for producing such plants are known. These methods are generally known to those skilled in the art and are described, for example, in the publications mentioned above. The crops are selected from soybeans, tomatoes and cereals (e.g., wheat, barley, rye and oats). and most preferably selected from soybean, rice, corn and wheat.
[0155] Plants whose fertility traits have been modified using genetic engineering techniques are subject to male sterility and fertility restoration. For example, plants that have been given traits such as Bacillus subtilis ( Expressing the ribonuclease gene (barnase) derived from Bacillus amyloliquefaciens Maize and chicory conferred male sterility by the addition of DNA from Escherichia coli. Tow plants conferred male sterility by introducing the nin methyltransferase gene (dam) Sorghum; the alpha-amylase gene (zm-aa) from maize confers male sterility. 1) and by introducing the ms45 protein gene (ms45) from maize, which confers fertility restoration traits. Maize fertility traits controlled by Bacillus subtilis in the tapetum cells of anthers Fertility was induced by expressing the ribonuclease inhibitor protein gene (barstar) derived from Refunctionalized canola: A Bacillus-derived ribonuclease that confers male sterility. A gene (barnase) and a ribonuclease inhibitor protein from Bacillus that confers fertility-restoring traits. One example is canola in which fertility traits are controlled by expressing the white gene (barstar). Other plants that have been given fertility traits through genetic engineering include tomatoes, rice, Mustard, wheat, soybean, and sunflower (e.g., US6720481, US6281348, US56591 24, US6399856, US7345222, US7230168, US6072102, EP1135982, WO2001 / 092544 and WO19 Methods for producing such plants are generally known to those skilled in the art, e.g. For example, the plant is described in the above publications. Preferably, the plant is corn, canola, Selected from soybean, rice, tomatoes and cereals (e.g., wheat), most preferably The grain is selected from corn, canola, soybean, rice, and wheat.
[0156] Plants that are endowed with abiotic stress tolerance are able to tolerate drought, high salinity, high light intensity, and high U. V irradiation, chemical contamination (e.g., high heavy metal concentrations), low or high temperatures, and nutrient (i.e., nitrogen, phosphorus) Plants that exhibit increased tolerance to abiotic stress conditions such as limited supply and population stress (See, for example, WO 2000 / 004173, WO2007 / 131699, CA2521729 and US2008 / 0229448) (see).
[0157] Examples of plants that have been given abiotic stress tolerance through genetic engineering include drought stress. Drought-tolerant rice, corn, soybeans, sugarcane, alfalfa, wheat, Tomato, potato, barley, rapeseed, beans, oats, sorghum and cotton (e.g. see WO 2005 / 048693, WO 2008 / 002480 and WO 2007 / 030001); low temperature resistant tow sorghum, soybean, wheat, cotton, rice, rapeseed and alfalfa (e.g., US 4,731,499 and WO2007 / 112122); high-salinity tolerant rice, cotton, potato, soybean, Wheat, barley, rye, sorghum, alfalfa, grapes, tomatoes, sunflowers and Tobacco (see, for example, US Pat. No. 7,256,326, US Pat. No. 7,034,139, WO / 2001 / 030990). The cold shock protein gene cspB of Bacillus subtilis The corn variety introduced is "DroughtGard®" (a Monsanto product).
[0158] Plants that have been given abiotic stress tolerance through conventional breeding techniques or genomic breeding techniques For example, corn, which has drought tolerance, is a plant that has been Isure Artesian® and Optimum® AQUAmax® products It is developed under the name
[0159] Other trait-imparted plants include plants with modified maturation characteristics. Modifications include, for example, delayed ripening, delayed softening, and early ripening. Examples of plants whose maturation characteristics have been modified by engineering include those related to the production of the plant hormone ethylene. The S-adenosylmethionine hydrolase gene (sam) from Escherichia coli bacteriophage T3 -K) for improved shelf life in melons and tomatoes; A gene that lacks a part of the ACC synthase gene from tomato, which is involved in ethylene synthesis. ACC derivatization from Pseudomonas chlororaphis, which degrades the precursor ACC polygalacturonase gene from tomato, which breaks down pectin in the cell wall The gene that produces double-stranded RNA from the tomato plant, or the ACC oxidase enzyme involved in ethylene production Tomatoes with improved shelf life due to the introduction of one or more of the parent genes; By introducing the gene pg, which generates double-stranded RNA of the original polygalacturonase gene, One example is the FLAVR SAVR (trademark) tomato, which has improved shelf life due to the use of genetically modified Plants whose maturation characteristics have been modified by recombinant techniques include, for example, delayed-ripening tomatoes, melon, raspberry, strawberry, cantaloupe, pepper, and papaya (e.g. For example, US 5767376, US7084321, US6107548, US5981831, WO1995 / 035387, US 5952546, US 5 512466, WO1997 / 001952, WO1992 / 008798 and Plant Cell. 1989, 53-63. Plant Molecular (See Biology, 50, 2002). Methods for producing such plants are generally known to those skilled in the art. and are described, for example, in the publications mentioned above. Preferably, the plant is a fruit-bearing plant (e.g. , tomatoes, vines, melons, papayas, bananas, peppers, raspberries and strawberries); Stone fruits (e.g., cherries, apricots, and peaches); pome fruits (e.g., apples and rapeseed) and citrus fruits (e.g., citron, lime, orange, pomelo, grapefruit) and mandarin), more preferably tomato, melon, papaya, vine Plants selected from apples, bananas, oranges and strawberries, most preferably tomatoes, melons Hmm, it's papaya.
[0160] Plants that have been given other quality modifications through genetic engineering include, for example, The 3-phytase gene from Aspergillus niger, a phytic acid decomposing enzyme, Canola "Phytas" was developed by introducing the gene (phyA) to enhance the degradation of endogenous phytic acid. eed® Canola: an enzyme that produces the blue pigment delphinidin and its derivatives A dihydroflavonol-4-reductase gene from petunia (Petunia hybrida) Genes, petunias, pansies (Viola wittrockiana), and salvia (Salvia splendens) or a flavonoid-3',5'-hydroxylase gene derived from carnation By introducing the blue-colored carnation "Moondust (trademark)" and "Mo onshadow(trademark)", "Moonshade(trademark)", "Moonlite(trademark)", "Moonaqua(trademark)" "Moonvista(trademark)" "Moonique(trademark)" "Moonpearl(trademark)" "Moonvista(trademark)" "Moonique(trademark)" "Moonpearl(trademark)" Moonberry™ and Moonvelvet™; the blue pigment delphinidin and its derivatives Anthocyanin-5-acylate from Torenia sp., an enzyme that produces the thiol transferase gene and flavonoid-3,5'-hydroxylase from pansy Roses with blue flower color controlled by introducing genes; modified cedar pollen antigen By introducing a protein gene (7crp), it has an immune tolerance effect and is effective in alleviating hay fever. Rice: Endogenous phytase was induced by introducing the 3-hydroxybenzoate (phyA) gene from Aspergillus niger. Corn with enhanced phosphoric acid decomposition; fiber micronization, increased fiber strength, uniform length Cotton that produces high-quality fibers with improved fertility and color (e.g., WO1996 / 26639, US7329 802, US6472588 and WO2001 / 17333).
[0161] Examples of plants whose traits related to plant growth and yield have been modified include plants with enhanced growth ability. Plants that have been modified with genetic engineering techniques to alter their growth and yield characteristics. Plants, for example, have genes encoding transcription factors that control the day period ( bbx32) to enhance plant growth and result in high yields in soybeans; A member of the homeodomain-leucine 14 zipper (HD-Zip) family from Arabidopsis Introduction of a transcription factor gene (athb17) belonging to the ras II HD-Zip II gene increased ear weight. As a result, corn varieties that are expected to produce high yields have been developed.
[0162] Zinc finger nucleases are used to modify the quality of plants using genome editing technology. The enzyme inositol-1,3,4,5,6-pentakisphosphate 2-kinase, which is involved in phytic acid biosynthesis, was used to Maize with reduced phytic acid content by deleting the IPK1 gene encoding e "ZFN-12 maize"; polyphenol oxidase (PO) was detected using CRISPR-Cas9. Browning resistance was conferred by deleting the gene encoding lyphenol oxidase. Mushrooms (see, for example, Nature., Vol. 532, 21 April 2016) are examples.
[0163] Examples of plants whose quality has been modified using new breeding techniques include cisgenesis. The low polyphenol oxidase (enzyme that causes browning) gene sequence GEN- isolated from apple By introducing 03 into new apple varieties, the expression level of polyphenol oxidase was reduced, and browning was prevented. "Arctic (registered trademark)" apple; GM rootstock, a breeding technology using grafting, has As an example of imparting traits to scions, non-transgenic tomato plants were cultivated using salt-tolerant tomato rootstocks. Tomatoes with salt tolerance conferred to scion tomatoes (Physiol Plantarum, 124, 465-475 2005) ) are listed.
[0164] In rice, many genes that confer resistance to diseases, pests, and abiotic stresses are known. The development of resistant varieties using these resistant strains is currently underway. Genes that show resistance to biotic stress include, for example, BPH1, BPH2, BPH3, BPH4, BPH5, BPH6, BPH7, BPH8, BPH9, BPH10, BPH11, BPH12, BPH13, BPH14, BPH15, BPH17, B PH18, BPH19, BPH20, BPH21, BPH22, BPH23, BPH24, BPH25, BPH26, BPH27, BPH28, BPH2 9, BPH32, qBPH-12, qBPHR-1, qBPHR-3, qBPHR-8, qBPHR-5-1qBPHR-5-2qBPHR-11-1 , qBPHR-11-2 and other brown planthopper resistance genes; WBPH1, WBPH2, WBPH3, WBPH4, WBPH5, White-backed planthopper resistance genes such as WBPH6, OVC, qOVA-5-2, qOVA1-3, and qOVA5-1; Qsbph2b, Qsb ph3, Qsbph3b, Qsbph3c, Qsbph3d, Qsbph4, Qsbph8, Qsbph11, Qsbph11d, Qsbph11e, Qsb Small brown planthopper resistance genes such as ph11f, Qsbph11g, and Qsbph12a; GLH, GLH1, GLH3, GLH4, GLH5, GLH6, GLH7, GLH8, GLH9, GLH10, GLH11, GLH12, GLH13, GRH1, GRH2, GRH3, GRH4 GRH5, Zlh1, Zlh2, Zlh3, qGRH-4, qGRH-2, qGRH-5, qGRH-6, qGRH-11, qGRH-3 The cylindrical scaffold of SB;Pii, PI65, PIZT, and PI2 4. PI29, PI25, Pi-jnw1, PB1, PIQ6, PID3, PI67, PITQ5, PITP, PITQ6, PLM2, PISE3. IPI、PISE1、PI157、PIQ4、PI21、PIA、PIB、PIK、PIKUR1、PIKUR2、PI3、PIF、PIZH、PI R4、PIR7、PI30、PI、PIGD2、PIG、PIGD3、PIGD1、PIZ、PI(、PI18、PIM、PI17、PI20、P I1、PI19、PI5、FISH、PI10、PI9、PI21、PI22、PI44、PI22、PI13、PII、PIB1、PIQ1、P IQ2、PIQ3、PIIS1、PII2、PI62、PI12、IPI3、PI14、PI15、PI16、PIT、PI11、PI6、PI23 PI14, PI11, PIIS2, PIB2, PI12, PI39, PI40, PITA, PIR2-3, PIR9-2, PIR12-2, PIRF 2-1, qRBR-2, qRBR-3, PI27, PI28, PI26, PIGM, PI47, PI48, PI7, PI56, PI49, PI34 PIKG, PI38, PI32, PI31, PI46, PIX, PIXY, Pita3, PI41, PI42, PI2, PI36, PI37, PIK H、PIKM、PIKP、PI35、PIZ5、PIB2、PI43、PI50、PI51、PID1、PIY1、PIY2、PI55-2、PIC O39, PI55-1, PIBH8, PIR7A, PIR7B, PID2, PI33, qBFR4-1, qBFR4-2, qRBR-2, qRBR -3, qRBR-8, qRBR-1-1, qRBR-1-3, qRBR-7-1, qRBR-7-2, qRBR-9-1, qRBR-9-2 Rice blast resistance genes such as qRBR-9-3, qRBR-1-2, and qRBR-1-4; STVA, STVB, and Stvb-i Stripe resistance genes: XA21D, XA, XA40, XA NM, XA8, XA33, XA34, XA35, XA36, XA3 7, XA7, XA3, XA25, XA28, XA29, XA30, XA31, XA32, XA38, XA39, XA11, XA16, A18, XA19, XA20, XA14, XA2, XA12, XA1, XA K, XA A, XA H, XA10, XA23, XA22, XA24 , XA21, SERRT13, XA4, XA5, XA13, and other bacterial leaf blight resistance genes; qSB-2, qSB-3, qSB-7, and qS Resistance genes for sheath blight such as B-11 and qSB-9-1; resistance genes for southern leaf blight such as CE; yellow spot such as YDV Dwarf disease resistance genes; black-streaked dwarf disease resistance genes such as BSV; Amy1A, Amy1C, Amy3A, Amy3B, etc. high temperature ripening tolerance genes; low amylose genes such as dul3, qAC9.3, rsr1, Wx and Wx1-1; A Lodging resistance genes such as P01, SCM2, and Sd1; pre-harvest sprouting resistance genes such as Sdr4; CTB1, CTB2, and qLTG3-1 low-temperature tolerance genes such as Dro1; drought tolerance genes such as DEP1, Cn1a, GPS, SPIKE, PTB1, TAWAWA1 , WFP, IPA1, GS3, GS5, GS6, GL3.1, GW2, GW8, qGL3, qSS7, qSW5, etc. Genes related to offspring shape: Hd1, Ghd8, DTH8, etc.; genes that regulate photoperiod responsiveness: FLO4, PDIL1, etc. endosperm floury genes; lipoxygenase deficiency genes such as LOX3 (which reduce the stale rice flavor); Genes related to amylopectin chain length, such as k, are known. Rice varieties incorporating these genes or multiple genes simultaneously are being developed or commercially available.
[0165] The plants mentioned above are cultivated using genetic engineering technology, conventional breeding technology, genome breeding technology, and new breeding technology. Using seed technology or genome editing technology, etc., we aim to develop abiotic stress tolerance and disease resistance as mentioned above. Sex, herbicide tolerance, pest resistance, growth and yield traits, nutrient utilization modification, product quality modification, fertility Lines that have been given two or more sexual traits, etc., and lines that have been crossed with plants that have similar or different properties Also included are plants that have been given two or more characteristics of the parent lines by crossing them.
[0166] Commercially available plants that have been made tolerant to two or more herbicides include, for example, glyphosate. GlyTol (trademark) LibertyLink (trademark) cotton resistant to methicillin and glufosinate "GlyTol™ LibertyLink™"; glyphosate- and glufosinate-tolerant Roundup Ready™ LibertyLink™ Maize corn; glufosine Glyphosate-tolerant and 2,4-D-tolerant soybean "Enlist™ Soybean"; Glyphosate-tolerant and Dicamba-tolerant soybean "Genuity® Roundup Ready™ 2 Xtend" Optimum glyphosate- and ALS-inhibitor-tolerant corn and soybean GAT™: a genetically modified strain that is resistant to three herbicides: glyphosate, glufosinate, and 2,4-D. Genetically modified soybeans "Enlist E3 (trademark)" and "Enlist (trademark) Roundup Ready 2 Yield (registered)" Trademark); glyphosate, 2,4-D and allyloxyphenoxypropionic acids (FOPs) herbicides Enlist™ Roundup Ready™ Corn 2, a corn variety that is resistant to the fungicide; Tolerant to lyphosate, 2,4-D, and allyloxyphenoxypropionic acid (FOP) herbicides Enlist™ Roundup Ready® Corn 2; dicamba, Lyphosate and glufosinate resistant cotton "Bologrd II (registered trademark) XtendFlex ( Cotton, which is resistant to three herbicides: glyphosate, glufosinate, and 2,4-D. Cotton "Enlist™ Cotton"; glyphosate, glufosinate, and HPPD herbicides (e.g., Liberty Link® G soybean, which is resistant to three herbicides (i.e., cyclohexyl benzoate, cyclohexyl benzoate, and isoxaflutole), T27 (trademark) is one of the other varieties that are resistant to both glufosinate and 2,4-D. Cotton resistant to both glufosinate and dicamba; cotton resistant to glyphosate and 2,4-D Corn resistant to both glyphosate and HPPD herbicides; Glyphosate, glufosinate, 2,4-D, allyloxyphenoxypropionic acid (F Corn that is resistant to OPs and cyclohexadiones (DIMs) herbicides is also It is being developed. Commercially available plants that have been given herbicide tolerance and pest resistance include, for example, glyphosate. YieldGard Roundup Reactor Corn with Tolerance to Corn Borer and Corn Borer ady™ and YieldGard Roundup Ready 2™; glufosinate tolerance and Agrisure CB / LL™ corn with borer resistance; glyphosate tolerance Yield Gard VT Rootworm / RR2 corn with corn rootworm resistance and (trademark)"; glyphosate tolerance and resistance to corn rootworm and corn borer Yield Gard VT Triple™ corn with glufosinate tolerance and lepidoptera Resistance to insect pests (Cry1F) (e.g., western bean cutworm, corn borer, black borer) Corn "H" with resistance to corn cutworm and fall armyworm erculex I™; a corn variety with glyphosate tolerance and corn rootworm resistance Locosi 'YieldGard Corn Rootworm / Roundup Ready 2'; glufosinate-resistant and Coleoptera resistance in corn (Cry3A) (e.g., Western corn rootworm, No. Resistance to Mexican corn rootworm and Mexican corn rootworm Agrisure GT / RW corn; glufosinate tolerance and coleopteran resistance (Cry 34 / 35Ab1) (e.g., Western corn rootworm, Northern corn rootworm, and Herculex RW (commercially available) corn with resistance to the Xanthomonas corn rootworm "Yield Corn with Glyphosate Tolerance and Corn Rootworm Resistance" Gard VT Rootworm / RR2™; Dicamba Tolerant, Glyphosate Tolerant, Glyphosinate Resistance and lepidopteran resistance in cotton (e.g. bollworms and tobacco budworm, Bollgard® 3 XtendFlex cotton (resistant to insects such as cereals and pests) (registered trademark).
[0167] Commercially available plants that have been conferred disease and pest resistance include those that have been conferred resistance to potato virus. Potato "Hi-Lite NewLeaf" with resistance to Potato virus Y and pests (Trademark) Y Potato, "NewLeaf (Trademark) Y Russet Burbank Potato, and "Shepody NewL eaf™ Y Potato; Potato leafroll virus resistance and harm NewLeaf™ Plus Russet Burbank Potato, a potato variety with insect resistance, Examples include:
[0168] Commercially available plants that have been endowed with herbicide tolerance and product quality modifications include, for example, "InVigor™ Canola" canola with rufosinate tolerance and fertility traits; InVigor™ Maize corn with foscinate tolerance and fertility traits; Examples include Vistive Gold™ soybeans that have been conferred phosate tolerance and modified for oil content. do.
[0169] Examples of commercially available plants with three or more traits are glyphosate tolerance, glyphosate tolerance, and Fosinate-resistant and lepidopteran-resistant (Cry1F) (i.e., Western bean cutworm, Resistance to corn borers, black cutworms and fall armyworms Herculex I / Roundup Ready 2™ corn; glyphosate-tolerant, YieldGard Plus Corn with Rootworm and Corn Borer Resistance / Roundup Ready 2™; glyphosate-resistant, glufosinate-resistant and corn borer-resistant -resistant corn "Agrisure GT / CB / LL (trademark)"; glufosinate-resistant, Lepidoptera resistant (Cry1F) and Coleoptera resistant (Cry34 / 35Ab1) (i.e., Western bee Cutworms, corn borers, black cutworms and fall army worms Which lepidopteran pests and western corn rootworm, northern corn rootworm, "Her" corn, which has resistance to coleopteran pests such as the Sikan corn rootworm culex Xtra™; glufosinate resistant, corn borer resistant (Cry1Ab) and coleoptera Pest resistance (Cry3A) (i.e., Western corn rootworm, Northern corn rootworm) Agrisure corn with resistance to corn rootworm and Mexican corn rootworm CB / LL / RW™; glyphosate tolerant, corn borer resistant (Cry1Ab) and coleopteran pests Resistance (Cry3A) (i.e., Western corn rootworm, Northern corn rootworm, and Agrisure (trademark) corn with resistance to Mexican corn rootworm and Mexican corn rootworm )3000GT"; glyphosate resistant, corn rootworm and European corn borer "Mavera high-value corn" with resistance to lepidoptera and high lysine traits; European corn borer, Southwestern corn borer, corn earworm, Fall army worms, black cutworms and / or western bean worms Optimum (registered trademark) corn, which is resistant to pests that attack the above-ground parts of plants. Leptra™; glyphosate resistant, glufosinate resistant, soybean leaf spot (frogeye) Leaf spot resistance, sudden death syndrome resistance, stem canker (s outhern stem canker) resistance, phytophthora stem and root rot resistance, Resistant to southern root-knot nematode, stem rot ) Resistance, Brown Stem Rot Resistance, Soybean Cyst Nematode Resistance It has resistance to iron deficiency chlorosis, and is effective against chloride deficiency. Credenz® soybean, a soybean with modified chloride sensitivity 'Stoneville (registered trademark) Cotton' ( In order to respond to the occurrence of weeds and pests in the fields in each region, 48GLT, ST4949GLT, ST5020GLT, ST5115GLT, ST6182GLT, ST4747GLB2, ST4946GLB2, ST644 There are nine varieties of 8GLB2.
[0170] The plants that are commercially available or under development are listed below (A1 to A556). Event Name, Event Code, Tradename, etc. NA stands for "information" Many of these plants are listed in the International Agricultural Biotechnology Association. INTERNATINAL SERVICE for the ACQUISITION of AGRI-BIOTECH APPLICATIONS, The registration database (GM APPROV) on the ISAAA electronic information site (http: / / www.isaaa.org / ) It is included in the AL DATABASE. A1: [Alfalfa, J101, MON-00101-8, Roundup Ready® Alfalfa], A2: [Alfalfa Alfalfa, J101 x J163, MON-00101-8 x MON-00163-7, Roundup Ready™ Alfalfa , A3: [Alfalfa, J163, MON-00163-7, Roundup Ready (trademark) Alfalfa], A4: [Alfalfa Alfalfa, KK179, MON-00179-5, HarvXtra®)], A5: [Alfalfa, KK179 x J101, MON-00179-5 x MON-00101-8 ], A6: [Apple, GD743, OKA-NB001-8, Arcti c(trademark) "Golden Delicious" Apple], A7: [Apple, GS784, OKA-NB002-9, Arctic(trademark) )], A8: [Apple, NF872, OKA-NB003-1, Arctic Fuji Apple], A9: [Arzen Chin Canola, 23-18-17 (Event 18), CGN-89111-8, Laurical™ Canola, A10 : [Argentine Canola, 23-198 (Event 23), CGN-89465-2, Laurical™ Canola ola], A11: [Argentine canola, 61061, DP-061061-7], A12: [Argentine Canola, 73496, DP-073496-4, Optimum® Gly canola], A13: [Argentina Canola, 73496 x RF3, DP-073496-4 x ACS-BN003-6, NA], A14: [Argentina Roundup Ready Canola, GT200 (RT200), MON-89249-2, Roundup Ready Canola], A15: [ Argentine Canola, GT73 (RT73), MON-00073-7, Roundup Ready™ Canola] , A16: [Argentine Canola, HCN10 (Topas 19 / 2), NA, Liberty Link™ In dependence(trademark)], A17: [Argentine canola, HCN28 (T45), ACS-BN008-2, In Vigor™ Canola], A18: [Argentine Canola, HCN28 x MON88302, ACS-BN 008-2 x MON-88302-9, InVigor(TM) x TruFlex(TM) Roundup Ready(TM) ) Canola], A19: [Argentine Canola, HCN92 (Topas 19 / 2), ACS-BN007-1, Libe rty Link™ Innovator™), A20: [Argentine Canola, HCN92 x MO N88302, ACS-BN007-1 x MON-88302-9, Liberty Link(TM) Innovator(TM) x TruFlex™ Roundup Ready™ Canola], A21: [Argentine Canola, M ON88302, MON-88302-9, TruFlex™ Roundup Ready™ Canola], A22: [A Lugentine Canola, MON88302 x MS8 x RF3, MON-88302-9 x ACS-BN005-8 x ACS-BN003-6, InVigor(TM) x TruFlex(TM) Roundup Ready(TM) Canola] , A23: [Argentine canola, MON88302 x RF3, MON-88302-9 x ACS-BN003-6, NA], A24: [Argentine Canola, MPS961, NA, Phytaseed® Canola], A25: [Argentine Canola, MPS962, NA, Phytaseed® Canola], A26: [Argentine China Canola, MPS963, NA, Phytaseed® Canola], A27: [Argentina Canola Canola, MPS964, NA, Phytaseed® Canola], A28: [Argentine Canola, MPS9 65, NA, Phytaseed™ Canola], A29: [Argentine Canola, MS1 (B91-4), A CS-BN004-7, InVigor™ Canola], A30: [Argentine Canola, MS1 x MON8 8302, ACS-BN004-7 x MON-88302-9, InVigor(TM) x TruFlex(TM) Roundup Ready™ Canola], A31: [Argentine canola, MS1 x RF1 (PGS1), ACS-BN 004-7 x ACS-BN001-4, InVigor™ Canola], A32: [Argentine Canola, M S1 x RF1 (PGS2), ACS-BN004-7 x ACS-BN002-5, InVigor(TM) Canola], A33: [ Argentine Canola, MS1 x RF3, ACS-BN004-7 x ACS-BN003-6, InVigor ) Canola], A34: [Argentine Canola, MS8, ACS-BN005-8, InVigor™ Canola ola], A35:[Argentine canola, MS8 x MON88302, ACS-BN005-8 x MON-88302- 9, InVigor(TM) x TruFlex(TM) Roundup Ready(TM) Canola], A36:[A Lugentin Canola, MS8 x RF3, ACS-BN005-8 x ACS-BN003-6, InVigor™ Canola], A37: [Argentine Canola, MS8 x RF3 x GT73 (RT73), ACS-BN005-8 x ACS-BN003-6 x MON-00073-7, NA], A38 :[Argentine Canola, OXY-235, A CS-BN011-5, Navigator™ Canola], A39: [Argentine Canola, PHY14, NA , NA], A40: [Argentine canola, PHY23, NA, NA], A41: [Argentine canola La, PHY35, NA, NA], A42: [Argentine canola, PHY36, NA, NA], A43: [Arze Canola, RF1 (B93-101), ACS-BN001-4, InVigor™ Canola], A44: [A Lucent Canola, RF1 x MON88302, CS-BN001-4 x MON-88302-9, InVigor TruFlex™ Roundup Ready™ Canola, A45: Argentina Nola, RF2 (B94-2), ACS-BN002-5, InVigor™ Canola], A46: [Argentina Canola, RF2 x MON88302, ACS-BN002-5 x MON-88302-9, InVigor(TM) x Tru Flex™ Roundup Ready™ Canola], A47: [Argentine Canola, RF3, ACS-BN003-6, InVigor™ Canola], A48: [Bean, EMBRAPA5.1, EMB-PV051-1, NA], A49: [Carnation, 11 (7442), FLO-07442-4, Moondust (trademark)], A50: [Carnation ion, 11363 (1363A), FLO-11363-1, Moonshadow (trademark)], A51: [Carnation, 1226 A(11226), FLO-11226-8, Moonshade (trademark)], A52: [Carnation, 123.2.2 (40619) , FLO-40619-7, Moonshade (trademark)], A53: [Carnation, 123.2.38 (40644), FLO-40 644-4, Moonlite(TM)], A54:[Carnation, 123.8.12, FLO-40689-6, Moonaqua (trademark)], A55: [Carnation, 123.8.8 (40685), FLO-40685-1, Moonvista (trademark)] , A56: [Carnation, 1351A (11351), FLO-11351-7, Moonshade (trademark)], A57: [Carnation, 1351A (11351), FLO-11351-7, Moonshade (trademark)] Carnation, 1400A (11400), FLO-11400-2, Moonshade (trademark)], A58: [Carnation A59: [Carnation, 16, FLO-00016-3, M Moondust (trademark)], A60: [Carnation, 19907, IFD-19907-9, Moonique (trademark)], A 61: [Carnation, 25947, IFD-25947-1, Moonpearl (trademark)], A62: [Carnation 25958, IFD-25958-3, Moonberry (trademark)], A63: [Carnation, 26407, IFD-264 07-2, Moonvelvet (trademark)], A64: [Carnation, 4, FLO-00004-9, Moondust (trademark) )], A65: [Carnation, 66, FLO-00066-8, NA] A66: [Carnation, 959A (11959) , FLO-11959-3, Moonshade (trademark)], A67: [Carnation, 988A (11988), FLO-11988- 7, Moonshade (trademark)], A68: [Chicory, RM3-3, NA, SeedLink (trademark)], A69: [Chicory, RM3-4, NA, SeedLink®)], A70: [Chicory, RM3-6, NA, SeedLink®)], A71: [Wa 19-51a, DD-01951A-7, NA], A72: [Cotton, 281-24-236, DAS-24236-5, NA], A73: [Cotton TA, 281-24-236 x 3006-210-23 (MX B-13), DAS-24236-5 x DAS-21023-5, WideStrike (commercial Cotton], A74: [Cotton, 281-24-236 x 3006-210-23 x COT102 x 81910, DAS-24236-5 x DAS-21023-5 x SYN-IR102-7 x DAS-81910-7, NA], A75:[Wata, 3006-210-23, DAS-210 23-5, NA], A76:[Wata, 3006-210-23 x 281-24-236 x MON1445, DAS-21023-5 x DAS-242 36-5 x MON-01445-2, WideStrike(TM) RoundupReady(TM) Cotton], A77:[Cotton, 300 6-210-23 x 281-24-236 x MON88913, DAS-21023-5 x DAS-24236-5 x NAMON-88913-8, Wid estrike® RoundupReadyFlex® Cotton], A78: [Cotton, 3006-210-23 x 281-24-2 36 x MON88913 x COT102, DAS-21023-5 x DAS-24236-5 x MON-88913-8 x SYN-IR102-7, W idestrike(TM) RoundupReadyFlex(TM) Cotton], A79:[Cotton, 31707, NA, BXN(TM) ) Plus Bollgard® Cotton], A80: [Cotton, 31803, NA, BXN® Plus Bollgard® ) Cotton], A81: [Cotton, 31807 x 31808, NA, NA], A82: [Cotton, 31807, NA, BXN (trademark) PlusBollgard™ Cotton], A83: [Cotton, 31808, NA, BXN™ PlusBollgard™ Cotton], A84: [Cotton, 42317, NA, BXN™ Plus Bollgard™ Cotton], A85: [Cotton , 81910, DAS-81910-7, NA], A86: [Cotton, BNLA-601, NA, NA], A87: [Cotton, BXN10211(1 0211), BXN-10211-9, NA], A88: [Cotton, BXN10215 (10215), BXN-10215-4NA, BXN (trademark) C Cotton], A89: [Cotton, BXN102 Cotton 22 (10222), BXN-10222-2, BXN (trademark) Cotton], A90: [ Cotton, BXN10224 (10224), BXN-10224-4NA, BXN (trademark) Cotton], A91: [Cotton, COT102 (IR10 2), SYN-IR102-7, VIPCOT (trademark) Cotton], A92: [Cotton, COT102 x COT67B, SYN-IR102-7N A x NASYN-IR67B-1, VIPCOT(R) Cotton], A93:[Cotton, COT102 x COT67B x MON88913 , SYN-IR102-7NA x NASYN-IR67B-1NA x NAMON-88913-8, VIPCOT(TM) RoundupReadyFle x (trademark) Cotton], A94: [Cotton, COT102 x MON15985, SYN-IR102-7NA x NAMON-15985-7, Bollgard® III], A95: [Cotton, COT102 x MON15985 x MON88913, SYN-IR102-7NA x NAMON-15985-7NA x NAMON-88913-8, Bollgard® III x RoundupReady™ Fle x (trademark)], A96: [Cotton, COT102 x MON15985 x MON88913 x MON88701, SYN-IR102-7 NA x NAMON-15985-7NA x NAMON-88913-8NA x NAMONNA88701-3, NA], A97:[Wata, COT67B (IR67B), SYN-IR67B-1, NA], A98:[Cotton, Event1, NA, JK1], A99:[Cotton, GFMCry1A, G TL-GFM311-7, NA], A100: [Cotton, GHB119, BCS-GH005-8, NA], A101: [Cotton, GHB614, BC S-GH002-5, GlyTol™)], A102: [Cotton, GHB614 x LLCotton25, BCS-GH002-5NA x NAA CS-GH001-3, GlyTol™ LibertyLink™)], A103: [Cotton, GHB614 x LLCotton25 x MON15985, BCS-GH002-5NA x NAACS-GH001-3NA x NAMON-15985-7, NA], A104:[Wata, GH B614 x MON15985, BCS-GH002-5NA x NAMON-15985, NA], A105:[Cotton, GHB614 x T304-40 x GHB119, BCS-GH002-5NA x NABCS-GH004-7NA x NABCS-GH005-8, Glytol(TM) x Twinl ink (trademark)], A106: [cotton, GHB614 x T304-40 x GHB119 x COT102, BCS-GH002-5NA x NA BCS-GH004-7NA x NABCS-GH005-8NA x NASYN-IR102-7, Glytol(trademark) x Twinlink(trademark) x VIPCOT (trademark) Cotton], A107: [Cotton, GK12, NA, NA], A108: [Cotton, LLCCotton25, AC S-GH001-3NA, Fiberma x (trademark) LibertyLink (trademark)], A109: [Cotton, LLCotton25 x MON 15985, ACS-GH001-3NA x NAMON-15985-7, Fiberma x(TM) LibertyLink(TM) Bollgar dII (trademark)], A110: [Cotton, MLS9124, NA, NA], A111: [Cotton, MON1076, MON-89924-2, B ollgard™ Cotton], A112: [Cotton, MON1445, MON-01445-2, RoundupReady™ Cotton ton], A113: [Cotton, MON15985, MON-15985-7, Bollgard II (trademark) Cotton], A114: [Cotton , MON15985 x MON1445, MON-15985-7NA x NAMON-01445-2, RoundupReady(TM) Bollgard II™ Cotton], A115: [Cotton, MON1698, MON-89383-1, RoundupReady™ Cotton] , A116: [Cotton, MON531, MON-00531-6, Bollgard® Cotton, Ingard®], A117: [Cotton, MON531 x MON1445, MON-0531-6NA x NAMON-01445-2, RoundupReady™ Bollga rd (trademark) Cotton], A118: [cotton, MON757, MON-00757-7, Bollgard (trademark) Cotton], A119 :[Cotton, MON88701, MONNA88701-3, NA], A120:[Cotton, MON88701 x MON88913, MONNA887 01-3NA x NAMON-88913-8, NA], A121:[Wata, MON88701 x MON88913 x MON15985, MONNA8 8701-3NA x NAMON-88913-8NA x NAMON-15985-7, Bollgard II® XtendFlex™ Cotton], A122: [Cotton, MON88913, MON-88913-8, RoundupReady™ Flex™ Cotto n], A123:[Wata, MON88913 x MON15985, MON-88913-8NA x NAMON-15985-7, RoundupRead y(trademark) Flex(trademark) Bollgard II(trademark) Cotton], A124: [Cotton, NgweChi6Bt, NA, NgweCh i6Bt], A125: [Cotton, SGK321, NA, NA], A126: [Cotton, T303-3, BCS-GH003-6, NA], A127 :[Cotton, T304-40, BCS-GH004-7, NA], A128:[Cotton, T304-40 x GHB119, BCS-GH004-7NA x NABCS-GH005-8, TwinLink™ Cotton], A129: [Creeping bentgrass, ASR36 8, SMG-36800-2, NA], A130: [Eggplant, BtBrinjalEventEE1, BtBrinjalEventEE1, BARIBtBe gun-1,-2,-3and-4], A131:[Eucalyptus, H421, H421, GMEucalyptus], A132:[Flax, FP96 7(CDCTriffid), CDC-FL001-2, CDCTriffidFla x], A133:[Lentil, RH44, RH44, Cl earfield(R) lentil], A134: [corn, 32138, DP-32138-132138, 2138SPTmaintainer], A135: [Maize, 3272, SYN-E3272-5, Enogen®], A136: [Maize, 3272 x Bt 11, SYN-E3272-5 x SYN-BT011-1, NA], A137: [Maize, 3272 x Bt11 x GA21, SYN -E3272-5 x SYN-BT011-1 x MON-00021-9, NA], A138:[Maize, 3272 x Bt11 x MI R604, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5, NA], A139:[Corn, 3272 x BT11 x MIR604 x GA21, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5 x MON-00021-9, NA] , A140: [Maize, 3272 x Bt11 x MIR604 x TC1507 x 5307 x GA21, SYN-E3272-5 x SYN-BT011-1 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A141 :[Corn, 3272 x GA21, SYN-E3272-5 x MON-00021-9, NA], A142:[Corn Shi, 3272 x MIR604, SYN-E3272-5 x SYN-IR604-5, NA], A143: [Corn, 3272 x M IR604 x GA21, SYN-E3272-5 x SYN-IR604-5 x MON-00021-9, NA], A144: corn; 33121, DP-033121-3, NA], A145: [Corn, 4114, DP-004114-3, NA], A146: [Tomato Corn, 5307, SYN-05307-1, Agrisure® Duracade®], A147: [Tow sorghum, 5307 x GA21, SYN-05307-1 x MON-00021-9, NA], A148:[maize, 5307 x MIR604 x Bt11 x TC1507 x GA21, SYN-05307-1 x SYN-IR604-5 x SYN-BT011-1 x DAS- 01507-1 x MON-00021-9, Agrisure® Duracade® 5122], A149: [Tomorrow Koshi, 5307 x MIR604 x Bt11 x TC1507 x GA21 x MIR162, SYN-05307-1 x SYN-IR604-5 x SYN-BT011-1 x DAS-01507-1 x MON-00021-9 x SYN-IR162-4, Agrisure® Durac ade™ 5222], A150: [corn, 59122, DAS-59122-7, Hercule x™ RW], A151: [Corn, 59122 x DAS40278, DAS-59122-7 x DAS-40278-9, NA], A152: [Tomato Corn, 59122 x GA21, DAS-59122-7 x MON-00021-9, NA], A153:[Corn, 5 9122 x MIR604, DAS-59122-7 x SYN-IR604-5, NA], A154:[Maize, 59122 x MIR6 04 x GA21, DAS-59122-7 x SYN-IR604-5 x MON-00021-9, NA], A155:[Corn, 59 122 x MIR604 x TC1507, DAS-59122-7 x SYN-IR604-5 x DAS-01507-1, NA], A156:[Tow Sorghum, 59122 x MIR604 x TC1507 x GA21, DAS-59122-7 x SYN-IR604-5 x DAS-01507- 1 x MON-00021-9, NA], A157:[Corn, 59122 x MON810, DAS-59122-7 x MON-008 10-6, NA], A158:[Maize, 59122 x MON810 x MIR604, DAS-59122-7 x MON-00810 -6 x SYN-IR604-5, NA], A159:[Maize, 59122 x MON810 x NK603, DAS-59122-7 x MON-00810-6 x MON-00603-6, NA], A160:[Corn, 59122 x MON810 x NK603 x MIR604, DAS-59122-7 x MON-00810-6 x MON-00603-6 x SYN-IR604-5, NA], A161:[Tow sorghum, 59122 x MON88017, DAS-59122-7 x MON-88017-3, NA], A162:[maize , 59122 x MON88017 x DAS40278, DAS-59122-7 x MON-88017-3 x DAS-40278-9, NA], A16 3: [Corn, 59122 x NK603, DAS-59122-7 x MON-00603-6, Herculex® RWRou ndupReady™ 2], A164: [corn, 59122 x NK603 x MIR604, DAS-59122-7 x M ON-00603-6 x SYN-IR604-5, NA], A165:[Corn, 59122 x TC1507 x GA21, DAS-5 9122-7 x DAS-01507-1 x MON-00021-9, NA], A166:[Corn, 676, PH-000676-7, NA], A167: [Corn, 678, PH-000678-9, NA], A168: [Corn, 680, PH-00 0680-2, NA], A169: [Corn, 98140, DP-098140-6, Optimum GAT®], A170 :[Corn, 98140 x 59122, DP-098140-6 x DAS-59122-7, NA], A171:[Corn Koshi, 98140 x TC1507, DP-098140-6 x DAS-01507-1, NA], A172: [Maize, 98140 x TC1507 x 59122, DP-098140-6 x DAS-01507-1 x DAS-59122-7, NA], A173: [Tomorrow Koshi, Bt10, NA, Bt10], A174: [Maize, Bt11 ( X 4334CBR, X 4734CBR), SYN-BT0 11-1, Agrisure™ CB / LL], A175: [corn, Bt11 x 5307, SYN-BT011-1 x SYN -05307-1, NA], A176:[Maize, Bt11 x 5307 x GA21, SYN-BT011-1 x SYN-05307- 1 x MON-00021-9, NA], A177:[Maize, Bt11 x 59122, SYN-BT011-1 x DAS-59122 -7, NA], A178:[Maize, Bt11 x 59122 x GA21, SYN-BT011-1 x DAS-59122-7 x M ON-00021-9, NA], A179:[Maize, Bt11 x 59122 x MIR604, SYN-BT011-1 x DAS-5 9122-7 x SYN-IR604-5, NA], A180:[Maize, Bt11 x 59122 x MIR604 x GA21, SY N-BT011-1 x DAS-59122-7 x SYN-IR604-5 x MON-00021-9, NA], A181: [Corn, B t11 x 59122 x MIR604 x TC1507, SYN-BT011-1 x DAS-59122-7 x SYN-IR604-5 x DAS-015 07-1, NA], A182:[Maize, BT11 x 59122 x MIR604 x TC1507 x GA21, SYN-BT011 -1 x DAS-59122-7 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, Agrisure® 3 122], A183:[Maize, Bt11 x 59122 x TC1507, SYN-BT011-1 x DAS-59122-7 x DA S-01507-1, NA], A184: [Maize, Bt11 x 59122 x TC1507 x GA21, SYN-BT011-1 x DAS-59122-7 x DAS-01507-1 x MON-00021-9, NA], A185: [Maize, Bt11 x GA21 , SYN-BT011-1 x MON-00021-9, Agrisure™ GT / CB / LL], A186: [Corn, Bt11 x MIR162, SYN-BT011-1 x SYN-IR162-4, Agrisure® Viptera™ 2100], A1 87: [Maize, Bt11 x MIR162 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-05307-1 , NA], A188: [Maize, Bt11 x MIR162 x 5307 x GA21, SYN-BT011-1 x SYN-IR162 -4 x SYN-05307-1 x MON-00021-9, NA], A189:[Maize, Bt11 x MIR162 x GA21, SYN-BT011-1 x SYN-IR162-4 x MON-00021-9, Agrisure® Viptera™ 3110 , A190: [Maize, BT11 x MIR162 x MIR604, SYN-BT011-1 x SYN-IR162-4 x SYN-I R604-5, Agrisure® Viptera™ 3100], A191: [Corn, BT11 x MIR1 62 x MIR604 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1, NA], A192: [Maize, Bt11 x MIR162 x MIR604 x 5307 x GA21, SYN-BT011-1 x SYN-IR1 62-4 x SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A193:[Maize, Bt11 x MIR162 x MIR604 x GA21, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x MON-00021-9, Agrisure® Viptera® 3111, Agrisure® Viptera® 4, A194 :[Maize, Bt11 x MIR162 x MIR604 x MON89034 x 5307 x GA21, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x MON-89034-3 x SYN-05307-1 x MON-00021-9, NA], A195: [Maize, BT11 x MIR162 x MIR604 x TC1507, SYN-BT011-1 x SYN-IR162-4 x SYN- IR604-5 x DAS-01507-1, NA], A196:[Maize, BT11 x MIR162 x MIR604 x TC1507 x 5307, SYN-BT011-1 x SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA ], A197:[Maize, Bt11 x MIR162 x MIR604 x TC1507 x GA21, SYN-BT011-1 x SY N-IR162-4 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A198: [Corn, B t11 x MIR162 x MON89034, SYN-BT011-1 x SYN-IR162-4 x MON-89034-3, NA], A199:[To Corn, Bt11 x MIR162 x MON89034 x GA21, SYN-BT011-1 x SYN-IR162-4 x MON-890 34-3 x MON-00021-9, NA], A200:[Maize, Bt11 x MIR162 x TC1507, SYN-BT011- 1 x SYN-IR162-4 x DAS-01507-1, NA], A201:[Maize, Bt11 x MIR162 x TC1507 x 5307, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1 x SYN-05307-1, NA], A202:[Tow Sorghum, Bt11 x MIR162 x TC1507 x 5307 x GA21, SYN-BT011-1 x SYN-IR162-4 x DAS- 01507-1 x SYN-05307-1 x MON-00021-9, NA], A203:[Maize, Bt11 x MIR162 x T C1507 x GA21, SYN-BT011-1 x SYN-IR162-4 x DAS-01507-1 x MON-00021-9, Agrisure (commercial) Mark) Viptera 3220], A204: [Maize, Bt11 x MIR604, SYN-BT011-1 x SYN-IR604-5 , Agrisure™ CB / LL / RW], A205: [Maize, Bt11 x MIR604 x 5307, SYN-BT011 -1 x SYN-IR604-5 x SYN-05307-1, NA], A206:[Maize, Bt11 x MIR604 x 5307 x GA21, SYN-BT011-1 x SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A207: [Tomo Rokosi, BT11 x MIR604 x GA21, SYN-BT011-1 x SYN-IR604-5 x MON-00021-9, Agrisure( Trademark) 3000GT], A208: [Corn, Bt11 x MIR604 x TC1507, SYN-BT011-1 x SYN-IR 604-5 x DAS-01507-1, NA], A209: [Maize, Bt11 x MIR604 x TC1507 x 5307, SY N-BT011-1 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A210: [Corn, B t11 x MIR604 x TC1507 x GA21, SYN-BT011-1 x SYN-IR604-5 x DAS-01507-1 x MON-0002 1-9, NA], A211: [Maize, Bt11 x MON89034, SYN-BT011-1 x MON-89034-3, NA], A212: [Maize, Bt11 x MON89034 x GA21, SYN-BT011-1 x MON-89034-3 x MON-000 21-9, NA], A213: [Maize, Bt11 x TC1507, SYN-BT011-1 x DAS-01507-1, NA], A 214: [Maize, Bt11 x TC1507 x 5307, SYN-BT011-1 x DAS-01507-1 x SYN-05307- 1, NA], A215:[Maize, Bt11 x TC1507 x 5307 x GA21, SYN-BT011-1 x DAS-0150 7-1 x SYN-05307-1 x MON-00021-9, NA], A216:[Maize, Bt11 x TC1507 x GA21 , SYN-BT011-1 x DAS-01507-1 x MON-00021-9, NA], A217: [Maize, Bt176(176) , SYN-EV176-9, NaturGardKnockOut (trademark), Maximizer (trademark)], A218: [corn , BVLA430101, NA, NA], A219: [Corn, CBH-351, ACS-ZM004-3, Starlink (trademark ) Maize], A220: [Corn, DAS40278, DAS-40278-9, Enlist™ Maize], A221 :[Corn, DAS40278 x NK603, DAS-40278-9 x MON-00603-6, NA], A222:[Corn locosi, DBT418, DKB-89614-9, Bt Xtra™ Maize], A223: [corn, DLL25 (B 16), DKB-89790-5, NA], A224: [Corn, GA21, MON-00021-9, RoundupReady (trademark ) Maize, Agrisure™ GT], A225: [Corn, GA21 x MON810, MON-00021-9 x MO N-00810-6, RoundupReady™ YieldGard™ maize], A226: [corn, GA21 x T25, MON-00021-9 x ACS-ZM003-2, NA], A227: [Corn, HCEM485, HCEM485, NA ], A228: [Corn, LY038, REN-00038-3, Mavera® Maize], A229: [Corn Koshi, LY038 x MON810, REN-00038-3 x MON-00810-6, Mavera(TM) YieldGard(TM) Ma ize], A230: [corn, MIR162, SYN-IR162-4, Agrisure™ Viptera], A231: [ Corn, MIR162 x 5307, SYN-IR162-4 x SYN-05307-1, NA], A232:[Corn , MIR162 x 5307 x GA21, SYN-IR162-4 x SYN-05307-1 x MON-00021-9, NA], A233:[To maize, MIR162 x GA21, SYN-IR162-4 x MON-00021-9, NA], A234:[maize; MIR162 x MIR604, SYN-IR162-4 x SYN-IR604-5, NA], A235:[Maize, MIR162 x M IR604 x 5307, SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1, NA], A236:[Corn , MIR162 x MIR604 x 5307 x GA21, SYN-IR162-4 x SYN-IR604-5 x SYN-05307-1 x MON-0 0021-9, NA], A237:[Maize, MIR162 x MIR604 x GA21, SYN-IR162-4 x SYN-IR60 4-5 x MON-00021-9, NA], A238:[Corn, MIR162 x MIR604 x TC1507 x 5307, SY N-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1, NA], A239: [Maize, M IR162 x MIR604 x TC1507 x 5307 x GA21, SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A240:[Corn, MIR162 x MIR604 x TC1507 x GA21, SYN-IR162-4 x SYN-IR604-5 x DAS-01507-1 x MON-00021-9, NA], A241: [Tomo Rokosi, MIR162 x MON89034, SYN-IR162-4 x MON-89034-3, NA], A242: [Maize; MIR162 x MON89034 x GA21, SYN-IR162-4 x MON-89034-3 x MON-00021-9, NA], A243:[ Maize, MIR162 x NK603, SYN-IR162-4 x MON-00603-6, NA], A244:[Maize SYN-IR162 x TC1507, SYN-IR162-4 x DAS-01507-1, NA], A245: [Maize, MIR162 x TC1507 x 5307, SYN-IR162-4 x DAS-01507-1 x SYN-05307-1, NA], A246:[Tomorrow Koshi, MIR162 x TC1507 x5 307 x GA21, SYN-IR162-4 x DAS-01507-1 x SYN-05307-1 x MON-00021-9, NA], A247:[ Corn, MIR162 x TC1507 x GA21, SYN-IR162-4 x DAS-01507-1 x MON-00021-9, N A], A248: [Corn, MIR604, SYN-IR604-5, Agrisure® RW], A249: [Corn Rokoshi, MIR604 x 5307, SYN-IR604-5 x SYN-05307-1, NA], A250:[Maize, MIR6 04 x 5307 x GA21, SYN-IR604-5 x SYN-05307-1 x MON-00021-9, NA], A251:[Tomorrow Koshi, MIR604 x GA21, SYN-IR604-5 x MON-00021-9, Agrisure (trademark) GT / RW], A252: [To Corn, MIR604 x NK603, SYN-IR604-5 x MON-00603-6, NA], A253:[Corn , MIR604 x TC1507, SYN-IR604-5 x DAS-01507-1, Optimum® TRisect®)], A 254:[Corn, MIR604 x TC1507 x 5307, SYN-IR604-5 x DAS-01507-1 x SYN-0530 7-1, NA], A255:[Maize, MIR604 x TC1507 x 5307 x GA21, SYN-IR604-5 x TC15 07 x SYN-05307-1 x MON-00021-9, NA], A256:[Corn, MIR604 x TC1507 x GA21 , SYN-IR604-5 x TC1507 x MON-00021-9, NA], A257: [Corn, MON801 (MON80100) , MON801, NA], A258: [corn, MON802, MON-80200-7, NA], A259: [corn , MON809, PH-MON-809-2, NA], A260: [Corn, MON810, MON-00810-6, YieldGa rd(trademark), MaizeGard(trademark)], A261:[Corn, MON810 x MIR162, MON-00810-6 x SYN-IR162-4, NA], A262:[Maize, MON810 x MIR162 x NK603, MON-00810-6 x S YN-IR162-4 x MON-00603-6, NA], A263:[Maize, MON810 x MIR604, MON-00810-6 x SYN-IR604-5, NA], A264:[Corn, MON810 x MON88017, MON-00810-6 x MON-8 8017-3, YieldGard™ VTTriple], A265: [Corn, MON810 x NK603 x MIR604 , MON-00810-6 x MON-00603-6 x SYN-IR604-5, NA], A266:[Corn, MON832, NA , RoundupReady™ Maize], A267: [Corn, MON863, MON-00863-5, YieldGard (Trademark) Rootworm RW, MaxGard(Trademark)], A268:[Corn, MON863 x MON810, MON-0 0863-5 x MON-00810-6, YieldGard™ Plus], A269: [Corn, MON863 x MON81 0 x NK603, MON-00603-6 x MON-00810-6 x MON-00863-5, YieldGard(TM) PluswithRR] , A270: [Corn, MON863 x NK603, MON-00863-5 x MON-00603-6, YieldGard (trademark )RW+RR], A271:[Maize, MON87403, MON87403-1, NA], A272:[Maize, M ON87411, MON-87411-9, NA], A273: [corn, MON87419, MON87419-8, NA], A274 :[Corn, MON87427, MON-87427-7, RoundupReady™ Maize], A275:[Corn Rokoshi, MON87427 x 59122, MON-87427-7 x DAS-59122-7, NA], A276: [Maize, M ON87427 x MON88017, MON-87427-7 x MON-88017-3, NA], A277:[corn, MON8742 7 x MON88017 x 59122, MON-87427-7 x MON-88017-3 x DAS-59122-7, NA], A278:[Tow sorghum, MON87427 x MON89034, MON-87427-...
Claims
1. The control agent contains sesquicarbonate as an active ingredient and has a control effect on at least one species selected from scale insects, leafhoppers, psyllids, aphids, thrips, flies, spittlebugs and longhorn beetles.
2. A pesticide containing sesquicarbonate as an active ingredient (excluding those containing gum arabic or a water-soluble polymeric substance primarily composed of gum arabic mixed with aluminum chloride and water-insoluble fine powder), which has a control effect against at least one selected from harmful nematodes and sap-sucking pests.
3. The fungicide contains sesquicarbonate as an active ingredient and has a preventive effect against at least one disease selected from sooty mildew, sooty mold, powdery mildew, soft rot, damping-off, bacterial damping-off, blight, rust, and black spot.
4. A plant growth regulator containing sesquicarbonate as an active ingredient (excluding those containing light-burned magnesia or magnesium hydroxide, and citric acid and / or humic acid).
5. A spreading agent containing sesquicarbonate as the active ingredient (excluding guazatine sesquicarbonate).
6. The agent according to any one of claims 1 to 5, further comprising at least one agent selected from the group consisting of insecticides, acaricides, nematicides, parasiticides and fungicides.
7. The agent according to any one of claims 1 to 6, further comprising at least one or more selected from (a), (b), (c) and (d). (a): Porous material; (b): viscosity modifier; (c): Enzyme; (d): surfactant;
Citation Information
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