Solid powder cosmetic

Abstract

To provide a solid powder cosmetic using a dry molding method with a simple production method, which is capable of improving use feeling such as moist use feeling and adhesion while suppressing caking.SOLUTION: A solid powder cosmetic contains the following components (A) to (C): (A) powder, (B) an oil agent solid at 25°C, and (C) an oil agent other than the component (B), wherein the total content of the component (B) and the component (C) is 0.5 to 10 mass% in the solid powder cosmetic, a cosmetic base agent containing the component (A), the component (B) and the component (C) is molded by a dry filling and molding method, and then the agent is heated into the solid powder cosmetic.SELECTED DRAWING: None

Description

[Technical Field]

[0001] The present invention relates to a solid powder cosmetic preparation. [Background technology]

[0002] Powder cosmetics, which are cosmetics blended with powder, are widely used as makeup cosmetics such as foundation, face powder, blush, eye shadow, eyebrow pencil, etc. Among these, many solid powder cosmetics that are molded into a solid form have been put on the market in terms of portability and texture.

[0003] Methods for molding solid powder cosmetics include the dry filling molding method, in which a powdered cosmetic base is filled into a container such as a metal plate and then pressurized, and the wet filling molding method, in which a solvent such as a volatile compound is added to the powdered cosmetic base to form a slurry, which is then filled into a container such as a metal plate and then molded by removing the solvent. The wet molding method is a commonly used molding method because it provides a moist feel when applied.

[0004] However, the wet filling method requires the addition of a solvent, which can pose environmental risks when using organic solvents, and when using water as a solvent, other ingredients may need to be blended to maintain bulk uniformity. For these reasons, the dry filling method is also widely used.

[0005] On the other hand, for solid powder cosmetics, suppressing caking during use (a phenomenon in which the surface of an applicator such as a cosmetic puff becomes hard and inaccessible after repeated use) is a very important quality item in terms of improving usability.

[0006] For example, in Patent Document 1, iron oxide, amorphous plate-like silica, and a kinematic viscosity of 10,000 mm 2 It is said that solid powder cosmetics containing hydrocarbon oils of 1 / s or more and oily ingredients that are paste-like at 25°C do not cause caking when used. [Prior art documents] [Patent documents]

[0007] [Patent Document 1] Japanese Patent Application Laid-Open No. 2016-124839 Summary of the Invention [Problem to be solved by the invention]

[0008] After applying a solid powder cosmetic to the skin, the powder adheres to the skin, forming a cosmetic film and achieving the cosmetic effect of the powder. Therefore, for a solid powder cosmetic, adhesion of the cosmetic to the skin (excellent adhesion) is extremely important for achieving the cosmetic effect. Furthermore, it is difficult to achieve a moist feel when using a solid powder cosmetic obtained by the dry filling molding method compared to solid powder cosmetics obtained by the wet filling molding method.

[0009] In order to improve the moist feel and adhesion of the product, it is conceivable to incorporate a high-viscosity oil agent with high skin adhesion in the dry filling molding method. However, if the amount of high-viscosity oil agent incorporated is too high, the bonding strength between the powder particles becomes too strong, making caking more likely to occur.

[0010] Therefore, an object of the present invention is to provide a solid powder cosmetic produced using a dry filling molding method that can suppress caking and improve the feel of use, such as a moist feel and adhesiveness. [Means for solving the problem]

[0011] In order to achieve the above object, the solid powder cosmetic of the present invention has the following constitution.

[0012] 1. The following ingredients (A) to (C): (A) Powder (B) Solid oil at 25°C (C) Oils other than component (B) A solid powder cosmetic comprising: the total content of the component (B) and the component (C) is 0.5 to 10% by mass in the solid powder cosmetic; A solid powder cosmetic is obtained by molding a cosmetic base containing the above-mentioned component (A), the above-mentioned component (B), and the above-mentioned component (C) by a dry filling molding method, and then heating the molded product.

[0013] 2. The solid powder cosmetic according to 1., wherein the heating temperature is equal to or lower than the melting point of component (B).

[0014] 3. The solid powder cosmetic preparation according to 1. or 2., wherein the mass ratio (B) / (C) of the content of component (B) to the content of component (C) is 0.1 to 10.

[0015] 4. The solid powder cosmetic preparation according to any one of 1. to 3., wherein the component (C) comprises component (C1) an oil agent that is pasty at 25°C.

[0016] 5. The solid powder cosmetic preparation according to any one of 1. to 4., wherein the component (A) includes component (A1) a metal soap.

[0017] 6. The solid powder cosmetic according to 5., wherein the content of the component (A1) is 0.01 to 10% by mass relative to the solid powder cosmetic.

[0018] 7. The cosmetic base is molded by a dry filling molding method and then heated; The cosmetic base is The following components (A) to (C): (A) Powder (B) Solid oil at 25°C (C) Oils other than component (B) and a total of 0.5 to 10 mass % of said component (B) and said component (C).

[0019] 8. The method for producing a solid powder cosmetic according to 7., wherein the heating temperature is equal to or lower than the melting point of component (B).

[0020] 9. The method for producing a solid powder cosmetic according to 7. or 8., wherein the mass ratio (B) / (C) of the content of component (B) to the content of component (C) is 0.1 to 10.

[0021] 10. The method for producing a solid powder cosmetic according to any one of 7. to 9., wherein the component (C) comprises component (C1) an oil agent that is pasty at 25°C.

[0022] 11. The method for producing a solid powder cosmetic according to any one of 7. to 10., wherein the component (A) includes component (A1) a metal soap. [Effects of the Invention]

[0023] The solid powder cosmetic of the present invention can suppress caking while improving the feel of use, such as a moist feel and high skin adhesion. DETAILED DESCRIPTION OF THE INVENTION

[0024] Hereinafter, embodiments of the present invention will be described. However, the present invention is not limited to the following embodiments. In this specification, the range "X to Y" includes X and Y and means "X or more and Y or less." Furthermore, unless otherwise specified, operations and measurements of physical properties, etc. are performed under conditions of room temperature (20 to 25°C) and relative humidity of 45 to 55% RH.

[0025] The detailed mechanism by which the solid powder cosmetic of the present invention exhibits the above-mentioned effects is unknown, but is thought to be as follows: Note that the following mechanism is not intended to limit the technical scope of the present invention in any way.

[0026] As described above, increasing the amount of oil in a solid powder cosmetic can achieve a moist feel and improved adhesion, but caking is more likely to occur. Focusing on this point, the inventors conducted research into improving the feel of use while suppressing caking by investigating a range of oil content that is low. As a result, they discovered that by combining a solid oil and a liquid / paste oil, using a cosmetic base with a low content of both, and heating after dry-filling molding, it is possible to suppress caking while improving the feel of use, such as a moist feel and adhesion. In dry-filling molding, the powder and oil are mixed in a dry state, which tends to result in uneven coverage of the oil on the powder surface, making it difficult for the oil to exert its effects. On the other hand, by heating the molded product after dry-filling molding, (part of) the solid oil dissolves and is uniformly coated on the powder surface, which is thought to result in a moist feel of use and improved skin adhesion. Furthermore, if the powder is heated before dry-fill molding, the moist feel and improvement in adhesion are not sufficient. Heating the powder in a state where the powder particles are in close contact with each other during the filling molding makes it easier for the oil agent to coat the powder uniformly, so it is thought that heating the molded product after dry-fill molding is necessary.

[0027] In this specification, the term "solid powder cosmetic" refers to a solid cosmetic whose main component is powder (powder). Here, the term "main component" refers to a cosmetic whose main component is powder (powder) at 50% by mass or more.

[0028] Hereinafter, each component contained in the solid powder cosmetic of the present invention will be described. Note that the solid powder cosmetic may also be simply referred to as the cosmetic.

[0029] (A: Powder) Powders are blended to impart cosmetic effects such as makeup effects.

[0030] The powder is not particularly limited in terms of shape (e.g., spherical, plate-like, spindle-like, needle-like, etc.), particle size (e.g., mist-like, fine particles, pigment-grade, etc.), particle structure (e.g., porous, non-porous, etc.), etc. Examples of powder include inorganic powders, organic powders, colored pigments, composite powders, polyethylene terephthalate-aluminum-epoxy laminated powder, polyethylene terephthalate-polymethyl methacrylate laminated powder, etc.

[0031] Examples of inorganic powders include carbon black, magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, aluminum silicate, aluminum hydroxide, magnesium silicate, magnesium aluminum silicate, titanium oxide, zinc oxide, aluminum oxide, cerium oxide, magnesium oxide, zirconium oxide, iron oxide, mica, synthetic phlogopite, sericite, synthetic sericite, talc, borosilicate (Ca / Al), borosilicate (Ca / Na), (fluoride / hydroxide / oxide) / (Mg / K silicon) (calcined talc-potassium silicofluoride), kaolin, silicon carbide, barium sulfate, boron nitride, silica, glass powder, and aluminum powder.

[0032] Examples of organic powders include metal soap, nylon, polymethylsilsesquioxane, crosslinked organopolysiloxane polymer, polystyrene, polyurethane, polyethylene, polypropylene, polyethylene terephthalate, polymethacrylate esters such as polymethyl methacrylate, and crosslinked polymethacrylate esters such as methyl methacrylate crosspolymer, complexes of polymethyl methacrylate and polyisoprene, polyacrylic esters, acrylonitrile-methacrylic acid copolymer powder, polytetrafluoroethylene, and (HDI / PPG / polycaprolactone) crosspolymer. Examples of crosslinked organopolysiloxane polymers include partially crosslinked methylpolysiloxanes such as dimethicone / vinyldimethicone crosspolymer, partially crosslinked methylphenylpolysiloxanes such as dimethicone / phenyldimethicone crosspolymer, partially crosslinked polyether-modified silicones such as dimethicone copolyol crosspolymer, partially crosslinked alkyl-modified silicones, and partially crosslinked alkyl-polyether-modified silicones such as lauryldimethicone-PEG crosspolymer. Examples of these crosslinked organopolysiloxane polymers include those with INCI names such as dimethicone / vinyldimethicone crosspolymer, dimethicone / phenylvinyldimethicone crosspolymer, dimethicone / vinyldiphenyldimethicone / methicone crosspolymer, dimethicone / lauryldimethicone crosspolymer, diphenyldimethicone / vinyldiphenyldimethicone / silsesquioxane crosspolymer, and vinyldimethicone / methicone silsesquioxane crosspolymer. Among these, an embodiment in which component (A) contains a crosslinked organopolysiloxane polymer is a preferred embodiment.

[0033] Examples of colored pigments include inorganic red pigments such as red iron oxide (red ochre), iron hydroxide, and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ochre; inorganic black pigments such as black iron oxide and carbon black; inorganic purple pigments such as manganese violet and cobalt violet; inorganic green pigments such as chromium hydroxide, chromium oxide, cobalt oxide, and cobalt titanate; inorganic blue pigments such as iron blue and ultramarine; lakes of tar-based pigments made with aluminum or the like; lakes of natural pigments; and synthetic resin powders made by combining these powders. Examples of tar-based dyes include Red No. 3, Red No. 104, Red No. 106, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, Red No. 227, Red No. 228, Red No. 230, Red No. 401, Red No. 505, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Yellow No. 204, Yellow No. 401, Blue No. 1, Blue No. 2, Blue 201, Blue No. 404, Green No. 3, Green 201, Green No. 204, Green No. 205, Orange No. 201, Orange No. 203, Orange No. 204, Orange No. 206, and Orange No. 207.

[0034] Examples of composite powders include titanium oxide-coated mica, titanium oxide-coated synthetic phlogopite, iron oxide-coated mica, iron oxide-coated titanium-mica, zinc oxide-coated titanium-mica, barium sulfate-coated titanium-mica, organic pigment-treated titanium-mica, silicon dioxide (silica)-titanium oxide-coated mica, titanium oxide-coated glass powder, iron oxide-titanium oxide-coated glass powder, titanium oxide-containing silicon dioxide, zinc oxide-containing silicon dioxide, titanium oxide-nylon composite powder, and titanium oxide-coated borosilicate (Ca / Al).

[0035] The powder may be surface-treated. Examples of surface treatments include fluorine compound treatment, silica treatment, alumina treatment, aluminum hydroxide treatment, silicone treatment (e.g., dimethicone treatment, hydrogen dimethicone treatment, etc.), silicone resin treatment (e.g., crosslinked product of dimethiconol and aminosilane, etc.), pendant treatment, silane coupling agent treatment, titanium coupling agent treatment, silane treatment, oil treatment, N-acylated amino acid treatment, polyacrylic acid treatment, metal soap treatment, acrylic resin treatment, metal oxide treatment, fatty acid treatment, phospholipid treatment, organic titanate treatment (e.g., isopropyl titanium triisostearate), etc. These surface treatments may be used alone or in combination of two or more.

[0036] The amount of the surface treatment agent to be used is preferably 0.1 to 30% by mass, more preferably 0.5 to 20% by mass, and even more preferably 1 to 10% by mass, based on the untreated powder.

[0037] The surface treatment can be carried out by a conventionally known method. For example, a surface treatment agent and powder particles to be treated are added to a solvent, stirred in a ball mill or the like, and then dried, washed with water, and filtered repeatedly as necessary to remove impurities, followed by drying and pulverization to obtain the desired surface-treated powder. Furthermore, several types of compounds that are surface treatment agents can be used simultaneously for surface treatment, or surface treatment can be carried out in advance with one compound and then with another compound.

[0038] The component (A) may be used alone or in combination of two or more types.

[0039] The content of component (A) may be 50% by mass or more, 60% by mass or more, 70% by mass or more, or 80% by mass or more relative to the cosmetic. The content of component (A) may be 99.5% by mass or less, 99% by mass or less, 98.5% by mass or less, or 98% by mass or less relative to the cosmetic.

[0040] In the case of surface-treated powders, the amount of the entire powder, including the surface treatment agent, is defined as the content of component (A). Even if the surface treatment agent corresponds to component (B) or component (C), the amount of the surface treatment agent is defined as the content of component (A), and the content of component (B) or component (C) does not include the amount of the surface treatment agent. In addition, when the powder contains the following component (A1), the content of component (A) refers to the content of the entire powder, including component (A1).

[0041] Furthermore, although not particularly limited, talc, mica, synthetic mica, and surface-treated powders thereof can be used as correction materials in solid powder cosmetics (materials other than functional materials that impart cosmetic effects, such as pigments).These correction materials may account for, for example, 20 to 99.5% by mass, or alternatively, 30 to 98% by mass, of the solid powder cosmetic.

[0042] (A1: Metal soap) In the present invention, it is preferable that component (A) contains component (A1) a metal soap. By further including a metal soap, the moist feeling during use is further improved, and the adhesion of the cosmetic to the skin is further improved.

[0043] Metal soaps are salts of fatty acids with metals other than sodium and potassium.

[0044] The fatty acids that make up metal soaps include those in which at least some of the hydrogen atoms in the side chains are substituted with substituents. Specific examples of such substituted fatty acids include hydroxy fatty acids in which at least one hydrogen atom in the side chain is substituted with a hydroxyl group.

[0045] Specific examples of fatty acids include saturated fatty acids such as butyric acid, valeric acid, caproic acid, enanthic acid, caprylic acid, pelargonic acid, capric acid, lauric acid, myristic acid, pentadecylic acid, palmitic acid, margaric acid, stearic acid, arachidic acid, behenic acid, lignoceric acid, cerotic acid, montanic acid, melissic acid, and isostearic acid; myristoleic acid, palmitoleic acid, oleic acid, elaidic acid, vaccenic acid, gadoleic acid, eicosenoic acid, and el Monounsaturated fatty acids such as capric acid and nervonic acid; diunsaturated fatty acids such as linoleic acid, eicosadienoic acid, and docosadienoic acid; and triunsaturated fatty acids such as linolenic acid, pinolenic acid, eleostearic acid, mead acid, and eicosatrienoic acid; 2-hydroxycaproic acid, 3-hydroxycaproic acid, 2-hydroxycaprylic acid, 3-hydroxycaprylic acid, 2-hydroxycapric acid, 3-hydroxycapric acid, 2-hydroxylauric acid, 3-hydroxylauric acid, 1 Hydroxy fatty acids such as 2-hydroxylauric acid, 12-hydroxystearic acid (ricinoleic acid), 2-hydroxymyristic acid, 3-hydroxymyristic acid, 14-hydroxymyristic acid, 2-hydroxypentadecanoic acid, 3-hydroxypentadecanoic acid, 15-hydroxypentadecanoic acid, 2-hydroxypalmitic acid, 16-hydroxypalmitic acid, 2-hydroxystearic acid, 3-hydroxystearic acid, 2-hydroxypalmitoleic acid, 3-hydroxypalmitoleic acid, 2-hydroxylinoleic acid, 3-hydroxylinoleic acid, 2-hydroxylinolenic acid, 3-hydroxylinolenic acid, 2-hydroxy-γ-linolenic acid, 3-hydroxyarachidonic acid, 2-hydroxy-4-methyldodecanoic acid, 18-hydroxy-3-methyloctadecanoic acid, 2-hydroxylignoceric acid, 2-hydroxyphytanic acid, and 18-hydroxy-4-ethyloleic acid are examples of hydroxy fatty acids. Among these, the fatty acid is preferably a saturated fatty acid having 8 to 24 carbon atoms, and more preferably a saturated fatty acid having 12 to 18 carbon atoms. Note that the term "saturated fatty acid having 8 to 24 carbon atoms" used here refers to the number of carbon atoms in each fatty acid when the metallic soap contains two or more fatty acids (for example, aluminum distearate) (for example, in aluminum distearate, stearic acid is the fatty acid and has 18 carbon atoms).

[0046] The metal constituting the metal salt is not particularly limited, but examples thereof include zinc, calcium, magnesium, lithium, barium, aluminum, etc. Among these, the metal constituting the metal salt is preferably zinc, calcium, magnesium, or aluminum, more preferably zinc or aluminum, and even more preferably zinc.

[0047] Among these, from the viewpoint of the effects of the present invention, the metal soap is more preferably a metal salt of a saturated fatty acid having 8 to 24 carbon atoms, even more preferably a metal salt of a saturated fatty acid having 12 to 18 carbon atoms, still more preferably at least one selected from the group consisting of metal salts of myristic acid, metal salts of stearic acid, metal salts of lauric acid, metal salts of palmitic acid, metal salts of isostearic acid, and metal salts of 12-hydroxystearic acid, even more preferably at least one selected from the group consisting of metal salts of myristic acid and metal salts of stearic acid, and even more preferably a metal salt of myristic acid.

[0048] More specifically, metal soaps such as zinc laurate, magnesium laurate, zinc myristate, magnesium myristate, zinc stearate, zinc isostearate, aluminum stearate (Al distearate), magnesium stearate, calcium stearate, calcium palmitate, and 12-hydroxyaluminum stearate are included. Among these, component (A1) preferably contains at least one selected from the group consisting of zinc myristate, zinc stearate, aluminum stearate (Al distearate), and zinc laurate, more preferably at least one selected from the group consisting of zinc myristate, zinc stearate, and aluminum stearate (Al distearate), and from the viewpoint of adhesion, it is even more preferable that component (A1) contains zinc myristate.

[0049] The metal soaps may be used alone or in combination of two or more.

[0050] The metal soap may be used only as a powder surface treatment agent, or may be a simple metal soap alone, or may be a combination of a powder surface treatment agent and a simple metal soap. In a preferred embodiment, at least component (A1) contains a simple metal soap (simple metal soap alone, or a combination of a powder surface treatment agent and a simple metal soap).

[0051] The content of component (A1) relative to the cosmetic is preferably 0.0005% by mass or more, or 0.001% by mass or more, from the viewpoint of drop strength; preferably 0.005% by mass or more, or 0.01% by mass or more, from the viewpoint of adhesion; and preferably 0.05% by mass or more, 0.1% by mass or more, 0.5% by mass or more, or 1% by mass or more, from the viewpoint of moist feel when used. The content of component (A1) relative to the cosmetic is preferably 15% by mass or less, 10% by mass or less, 7% by mass or less, 6% by mass or less, 5% by mass or less, or 4% by mass or less, from the viewpoint of suppressing caking, etc. The content of component (A1) relative to the cosmetic is preferably 0.0005 to 15% by mass, 0.001 to 10% by mass, 0.005 to 7% by mass, 0.01 to 6% by mass, 0.1 to 5% by mass, 0.5 to 4% by mass, or 1 to 4% by mass. Here, even when a metal soap is used as a surface treatment agent for the powder, the content of the component (A1) includes the amount of the surface treatment agent.

[0052] (B: solid oil at 25°C) Component (B) is an essential constituent element for providing a moist feel in use and improving adhesion.

[0053] Examples of oils that are solid at 25°C include waxes; higher alcohols such as behenyl alcohol, cetanol, and batyl alcohol; fatty acids such as stearic acid and behenic acid; cetyl palmitate, polyethylene glycol distearate, glyceryl tribehenate, cholesterol, phytosterol, stearyl-modified polysiloxane, palm oil, bisethylhexyloxyphenol methoxyphenyl triazine, diethylaminohydroxybenzoyl hexyl benzoate, and ethylhexyl triazone.

[0054] Specific examples of waxes include natural waxes such as beeswax (beeswax), carnauba wax (carnauba wax), candelilla wax, Japan wax, Japanese laurel wax, Chinese wax, shellac wax, and rice wax; mineral waxes such as ceresin wax, montan wax, and ozokerite wax; petroleum waxes such as paraffin wax, microcrystalline wax, and hydrogenated microcrystalline wax; synthetic hydrocarbon waxes such as polyethylene wax, polypropylene wax, (ethylene / propylene) copolymer, and Fischer-Tropsch wax; and synthetic waxes such as hydrogenated waxes such as hydrogenated castor oil. Waxes may be used alone or in combination of two or more.

[0055] From the viewpoint of the effects of the present invention, component (B) preferably contains a wax. From the viewpoint of adhesion, it is more preferable to contain a hydrocarbon wax such as a mineral wax, petroleum wax, or synthetic hydrocarbon wax. It is even more preferable to contain at least one selected from the group consisting of paraffin wax, microcrystalline wax, polyethylene wax, Fischer-Tropsch wax, polypropylene wax, and (ethylene / propylene) copolymer, and even more preferable to contain a Fischer-Tropsch wax. Furthermore, the wax preferably has a melting point of 50°C or higher, 60°C or higher, 80°C or higher, 100°C or higher, or 110°C or higher (each upper limit being, for example, 150°C or lower). Here, the melting point in this specification can refer to, for example, the melting point (Tm) defined as the peak top of the peak observed on the highest temperature side of the melting endothermic curve obtained using a differential scanning calorimeter (DSC) by holding a sample at -10°C for 5 minutes under a nitrogen atmosphere and then increasing the temperature at a rate of 10°C / min.

[0056] The content of component (B) in the cosmetic is preferably 0.1% by mass or more, 0.2% by mass or more, 0.5% by mass or more, or more than 1% by mass from the viewpoint of usability. The content of component (B) in the cosmetic is preferably 8% by mass or less, and may be 7% by mass or less, 6% by mass or less, or 5% by mass or less, from the viewpoint of inhibiting caking, etc. The content of component (B) is preferably 0.1 to 8% by mass, 0.2 to 7% by mass, 0.5 to 6% by mass, or more than 1% by mass and 5% by mass or less.

[0057] (Component (C): Oil other than component (B)) Component (C) functions as a binder, and in the absence of component (C), the powder cosmetic cannot be solidified.

[0058] Examples of oils other than component (B) include oils that are paste-like at 25°C (component (C1)) and oils that are liquid at 25°C. In the present invention, from the viewpoints of moist feel and adhesion, it is preferable that component (C) contains an oil that is paste-like at 25°C (component (C1)), and it is more preferable that component (C) is a combination of an oil that is liquid at 25°C and an oil that is paste-like at 25°C (component (C1)). The use of component (C1) makes it easier for the oil to coat the powder particles than when only a liquid oil is used, and heating after filling and molding can increase the fluidity of the oil between the powder particles, making it easier for the oil to coat the powder surfaces more uniformly, which is thought to improve the feel and other aspects of use.

[0059] Component (C1) is an oil agent that is pasty at 25°C. Here, "paste-like at 25°C" refers to an oil-based component that exhibits high viscosity at 25°C and has a melting point above 25°C (preferably a melting point of 30°C or higher but lower than 60°C, more preferably 35 to 50°C, and even more preferably 35°C or higher but lower than 50°C). "Paste-like at 25°C" refers to, for example, a state in which the viscosity at 25°C is greater than 30,000 mPa·s but not greater than 500,000 mPa·s. The viscosity can be measured using a single-cylinder rotational viscometer, Vismetron Model VS-A1 (manufactured by Shibaura Systems Co., Ltd.), after leaving a sample at 25°C for one day.

[0060] Component (C1) is not particularly limited, but examples thereof include hydrocarbon oils such as petrolatum; di(octyldodecyl / phytosteryl / behenyl) lauroyl glutamate, phytosteryl isostearate, phytosteryl oleate, phytosteryl hydroxystearate, di(phytosteryl / isostearyl / cetyl / stearyl / behenyl) dilinoleate, phytosteryl macadamiate, phytosteryl butyrate, phytosteryl nonanoate, cholesteryl stearate, cholesteryl isostearate, cholesteryl hydroxystearate, phytosteryl caprylate / caprate, phytosteryl ricinoleate, cholesteryl oleate, dihydrocholesteryl oleate, cholesteryl branched fatty acids (C12-31), phytosteryl canola glycerides, phytosteryl rapeseed glycerides, phytosteryl macadamiate, macadamia glycerides Examples of suitable fatty acids include sterol fatty acid esters such as cholesteryl, dihydrocholesteryl macadamia nut oil fatty acid, phytosteryl sunflower seed oil fatty acid, phytosteryl rice bran oil fatty acid, and cholesteryl lanolinate; dipentaerythrityl hexa(hydroxystearate / stearic acid / rosinate) dipentaerythrityl hexahydroxystearate, dipentaerythrityl rosinate, and dipentaerythrityl tri-polyhydroxystearate; dimer acid esters such as phytosteryl / isostearyl / cetyl / stearyl / behenyl dimer dilinoleate, dimer dilinoleyl bis(behenyl / isostearyl / phytosteryl) dimer dilinoleate, and di(isostearyl / phytosteryl) dimer dilinoleate; and hydrogenated castor oil fatty acid esters such as hydrogenated castor oil isostearate and hydrogenated castor oil monohydroxystearate. These components (C1) may be used alone or in combination of two or more.Among these, from the viewpoint of usability and the like, component (C1) is preferably petrolatum and / or ester oil, more preferably at least one selected from the group consisting of petrolatum, dipentaerythritol fatty acid esters, and sterol fatty acid esters, even more preferably at least one selected from the group consisting of dipentaerythritol fatty acid esters and di(octyldodecyl / phytosteryl / behenyl) lauroyl glutamate, even more preferably dipentaerythritol fatty acid esters, and particularly preferably dipentaerythritol hexa(hydroxystearate / stearic acid / rosinate).

[0061] The content of component (C1) in the cosmetic is preferably 0.01 to 8 mass%, more preferably 0.05 to 5 mass%. A content above the lower limit makes it easier to obtain the effects of component (C1), such as a moist feel in use and adhesion, while a content below the upper limit is advantageous in terms of suppressing caking, and is therefore preferred.

[0062] An oil agent that is liquid at 25°C (hereinafter also referred to simply as liquid oil) refers to an oil that is liquid (has fluidity) at 25°C. Specific examples of liquid oils include hydrocarbons such as isododecane, isohexadecane, light isoparaffin, liquid paraffin (mineral oil), squalane, squalene, α-olefin oligomer, polybutene, liquid isoparaffin, heavy liquid isoparaffin, polyisobutylene, and hydrogenated polyisobutene; rapeseed oil, avocado oil, almond oil, apricot kernel oil, perilla oil, orange oil, olive oil, kiwi seed oil, sesame oil, wheat germ oil, rice germ oil, rice bran oil, safflower oil, sage oil, soybean oil, chili oil; Animal and vegetable oils such as corn oil, rapeseed oil, evening primrose oil, camellia oil, persic oil, Job's tears oil, hazelnut oil, peanut oil, sunflower oil, grape seed oil, meadowfoam oil, rosemary oil, jojoba oil, macadamia nut oil, lavender oil, rosehip oil, camellia oil, and mink oil; glyceryl tri-2-ethylhexanoate (triethylhexanoin), isotridecyl isononanoate, isononyl isononanoate, cetyl 2-ethylhexanoate, isopropyl myristate, isopropyl palmitate Pyr, 2-ethylhexyl palmitate, octyldodecyl myristate, glyceryl trioctanoate, caprylic / capric triglyceride, glyceryl diisostearate, glyceryl triisostearate, decaglyceryl decaisostearate (polyglyceryl-10 decaisostearate), propylene glycol dicaprate, neopentyl glycol dicaprate, polyglyceryl triisostearate, diisostearyl malate, neopentyl glycol diethylhexanoate esters such as pentaerythritol tetraisostearate, pentaerythritol tetra-2-ethylhexanoate, dipentaerythritol pentaisostearate, dialkyl carbonate, bisethoxydiglycol cyclohexane-1,4-dicarboxylate, and dimer dilinoleyl hydrogenated rosin condensate; fatty acids such as oleic acid and isostearic acid; higher alcohols such as oleyl alcohol, 2-octyldodecanol, 2-decyltetradecanol, isostearyl alcohol, and 2-hexyldecanol;Examples of suitable oils include silicone oils such as dimethylpolysiloxane (dimethicone), methyltrimethicone, methylphenylpolysiloxane, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, tetramethyltetrahydrogencyclotetrasiloxane, tetramethyltetraphenylcyclotetrasiloxane, tetramethyltetratrifluoropropylcyclotetrasiloxane, pentamethylpentatrifluoropropylcyclopentasiloxane, polyether-modified methylpolysiloxane, oleyl-modified methylpolysiloxane, and polyvinylpyrrolidone-modified methylpolysiloxane; fluorine-based oils such as perfluoropolyether, perfluorodecane, and perfluorooctane; lanolin derivatives such as lanolin acetate, lanolin fatty acid isopropyl, and lanolin alcohol; and liquid ultraviolet absorbers such as 2-ethylhexyl paramethoxycinnamate, ethylhexyl salicylate, and polysilicone-15. These liquid oils may be used alone or in combination.

[0063] In terms of the effects of component (C), the content of component (C) in the cosmetic is preferably 0.01% by mass or more, 0.1% by mass or more, 0.2% by mass or more, 0.25% by mass or more, 0.5% by mass or more, or 1% by mass or more. In terms of suppressing caking, the content of component (C) is preferably 9.9% by mass or less, 9.8% by mass or less, 9.5% by mass or less, or 9% by mass or less. The content of component (C) is preferably 0.01 to 9.9% by mass, 0.1 to 9.8% by mass, 0.2 to 9.5% by mass, 0.25 to 9.5% by mass, 0.25 to 9% by mass, 0.5 to 9% by mass, or 1 to 9% by mass.

[0064] In the present invention, the total content of components (B) and (C) in the cosmetic is 10% by mass or less. If the total content of components (B) and (C) in the cosmetic exceeds 10% by mass, caking becomes significantly more likely to occur. The total content of components (B) and (C) in the cosmetic may be less than 10% by mass, or 9.5% by mass or less. Furthermore, the total content of components (B) and (C) in the cosmetic is 0.5% by mass or more. If the total content of components (B) and (C) in the cosmetic is less than 0.5% by mass, the moist feel and adhesion are significantly reduced. It is more preferable that the total content of components (B) and (C) in the cosmetic is 0.8% by mass or more, or 1% by mass or more. The total content of component (B) and component (C) in the cosmetic is preferably 0.5 to 10 mass %, 0.8 mass % or more but less than 10 mass %, or 1 to 9.5 mass % in the cosmetic.

[0065] In the present invention, the mass ratio (B) / (C) of the content of component (B) to the content of component (C) is preferably 0.1 to 10, more preferably 0.3 to 8, even more preferably 0.5 to 5, and even more preferably 0.7 to 4, from the viewpoint of the feel when used.

[0066] (Dry filling molding) In dry-fill molding, a cosmetic base containing components (A) to (C) is mixed in the absence of a volatile solvent, and then filled into a container under pressure to form the product. In contrast, in wet-fill molding, a cosmetic base in a fluid slurry state is filled into a container. The cosmetic base flows during filling, which tends to result in a structure in which the powder is oriented in the direction of the flow. On the other hand, solid powder cosmetics formed by dry methods are thought to have random powder orientation. Furthermore, the present invention requires the use of solid oil, which is incompatible with the solvent used in wet methods, making it difficult to achieve a caking-inhibiting effect. Therefore, the structure of the cosmetic product obtained varies depending on the manufacturing method, and the resulting physical properties also differ (see Example 2 and Comparative Examples 6 and 7, described below).

[0067] Before dry filling, component (A), component (B), component (C) and any optional components can be mixed to obtain a powdery cosmetic base.

[0068] The order of addition of components (A), (B), and (C) when preparing the cosmetic base is not particularly limited. Components (A), (B), and (C) may be mixed all at once, or components (A) and (B) may be mixed and then component (C) may be added, or components (A) and (C) may be mixed and then component (B) may be added. Adding component (C) after mixing components (A) and (B) is preferred, as this allows for uniform mixing of components (A) and (B). In this case, it is preferable to mix component (B) with component (A) without heating it, from the perspective of uniform mixing. Furthermore, when adding component (C), it is preferable to heat component (B) to a temperature at which it melts, from the perspective of uniform mixing.

[0069] When mixing the powder (component (A)) with the oily components (component (B), component (C), and other optional components), a high-speed agitator / mixer such as a Henschel mixer can be used. The resulting mixture can be pulverized using a pulverizer, atomizer, or other grinder.

[0070] The powdered cosmetic base is filled into any container. Examples of the container include dish-shaped containers such as metal dishes and resin dishes. The filling temperature is usually room temperature, and the temperature at which filling is possible is, for example, 10 to 35°C. After filling, the cosmetic base is pressed into a solid form using a press or the like. The pressing pressure during pressing can be appropriately set to obtain an appropriate hardness. The hardness in this case is, for example, 3 or more. The hardness can be measured using an automatic constant pressure load machine (GS-610, manufactured by TECROCK) / digital rubber hardness tester (GSD-706K, manufactured by TECROCK).

[0071] (heating) Heating is performed after the filling step. Heating before dry filling does not achieve the effects of the present invention. The heating temperature is preferably below the melting point of component (B) to suppress caking. By heating at a temperature below the melting point of component (B), components (B) and (C) do not completely melt, resulting in more uniform coating of the powder than when not heated. However, since the coating does not progress too far, it is thought that it is easier to achieve both a good feel when used and no caking. The heating temperature is, for example, preferably at least 5°C lower than the melting point of component (B), and may be at least 10°C lower. When multiple components (B) are used, the term "temperature lower than the melting point of component (B)" refers to a temperature lower than the melting point of the component (B) with the lowest melting point.

[0072] Specifically, the heating temperature is preferably 30 to 180° C., more preferably 40 to 150° C., and even more preferably 40 to 120° C., 45 to 100° C., 45 to 90° C., 45 to 80° C., 45 to 70° C., or 45 to 65° C. Heating within such a temperature range makes it easier to achieve both a pleasant feel in use and no caking.

[0073] The heating time is set appropriately taking into consideration the effects of the present invention, but is preferably 1 hour or more, and more preferably 3 to 24 hours. The heating means is preferably a means that heats the entire system, and is not particularly limited, but examples thereof include a thermostatic bath.

[0074] In addition to the above-mentioned components, the solid powder cosmetic of the present invention may contain optional components commonly used in cosmetics, such as emulsifiers, preservatives, antioxidants, cosmetic ingredients, antibacterial agents, fragrances, chelating agents (such as EDTA), ultraviolet absorbers, film-forming agents, and polyhydric alcohols, as appropriate, within the scope that does not impair the effects of the present invention.

[0075] In the solid powder cosmetic of the present invention, the water content is preferably 3% by mass or less, more preferably 1% by mass or less, and preferably substantially free of water. Here, "substantially free of water" means that the content of impurities is acceptable, for example, 0.1% by mass or less.

[0076] The solid powder cosmetic of the present invention can be used in makeup cosmetics such as foundation, face powder, face powder (white powder), concealer, eye color (eye shadow), eyeliner, eyebrow pencil, mascara, blush, lipstick, sunscreen cosmetics, and cosmetic base; skin care cosmetics such as body powder; and preferably, the cosmetic is a makeup cosmetic such as foundation, face powder, face powder, eye color, cosmetic base, sunscreen cosmetics, and blush, which are expected to exhibit the effects of the present invention more effectively, and more preferably, a foundation, face powder, or face powder, which have a large application area. The cosmetic can be used by applying it with the hands or fingers, or by impregnating a puff, sponge, or the like with the cosmetic. [Example]

[0077] The effects of the present invention will be explained using the following examples and comparative examples. In the examples, the terms "parts" and "%" may be used, but unless otherwise specified, they represent "parts by mass" or "% by mass." Furthermore, unless otherwise specified, each operation is carried out at room temperature (25°C). In the following examples, the "remaining amount" in the content (% by mass) means the amount that makes the total amount 100% by mass.

[0078] Examples 1 to 29 and Comparative Examples 1 to 7: Face powders were prepared according to the formulations shown in Tables 1 to 4 below.

[0079] (Manufacturing method) (1) Components (A), (A1) and (B) were mixed and stirred to obtain a mixture. (2) Components (C) and (C1) were heated and mixed, and then added to (1) and further mixed. (3) The mixture obtained in (2) was pulverized to obtain a powdered cosmetic base. (4) The powdered cosmetic base obtained in (3) is filled into a container (a resin dish (length 5 cm x width 4 cm x depth 1 cm)) in 10 g portions, and then compressed at 200 kg / cm by a dry filling molding method. 2 The molded product was press-molded at a pressure of 1000 kJ / cm. (5) The obtained pressed product was left to stand for 10 hours in a thermostatic oven set at the heating temperature shown in the table, and then removed from the thermostatic oven to obtain a solid powder cosmetic (face powder).

[0080] In Comparative Examples 6 and 7, face powders were produced by the wet filling molding method, in which 100 parts by mass of the cosmetic base obtained in (3) was mixed with the solvent (No. 20 purified water, No. 21 light liquid paraffin) in the amount shown in Table 4 to obtain a slurry composition, which was then filled into a mold and press-molded, followed by drying to remove the solvent, to obtain a solid powder cosmetic (face powder).

[0081] Evaluation method 1: Moist feeling when used Twenty cosmetic evaluation panel members were asked to use each face powder, and each panel member rated the "moisturizing feeling" using the following five-point scale, and the average score was calculated from the total scores of all panel members for each sample, and judged according to the following four-point scale. Moisturizing feeling was evaluated by applying each sample and assessing whether or not the skin felt moisturized. <5-point rating scale> [evaluation] Very good: 5 points Good: 4 points Average: 3 points Slightly poor: 2 points Defective: 1 point <4-level evaluation criteria> [Average score]:[Judgment] Over 4.5 points: A (Excellent) Over 4.0 points and under 4.5 points: B (Good) Over 3.0 points and under 4.0 points: C (passable) 3.0 points or less: D (not acceptable).

[0082] Evaluation method 2: Adhesion to the skin (adhesion) Twenty cosmetic evaluation panel members were asked to use each face powder, and each panel member rated and scored the "adhesion to the skin" using the absolute evaluation below on a 5-point scale. The average of the scores of all panelists for each sample was calculated and judged according to the 4-point rating scale below. Adhesion to the skin was evaluated by whether or not the powder did not fall off when each sample was applied to the skin and whether or not the cosmetic film felt to be adhering to the skin. <5-point rating scale> [evaluation] Very good: 5 points Good: 4 points Average: 3 points Slightly poor: 2 points Defective: 1 point <4-level evaluation criteria> [Average score]:[Judgment] Over 4.5 points: A (Excellent) Over 4.0 points and under 4.5 points: B (Good) Over 3.0 points and under 4.0 points: C (passable) 3.0 points or less: D (not acceptable).

[0083] Evaluation method 3: Absence of caking The surface of each sample was rubbed back and forth with a face powder puff 50 times in succession, and the surface condition of each sample was visually inspected. If caking (the surface of each sample solidified) occurred during the process, the puff was stopped and the number of times until caking occurred was recorded. The absence of caking was judged according to the following criteria. <Judgment criteria> (judgement) A: No caking even after 50 strokes B: Caking occurs after 46-50 round trips C: Caking occurs after 31-45 round trips D: Caking occurs after 16 to 30 round trips E: Caking occurs after 15 or fewer round trips.

[0084] Evaluation method 4: Drop test Each face powder was dropped once onto a plastic tile from a height of 40 cm, and the condition was observed. Five samples of each sample were subjected to the drop test. After the drop, the degree of disintegration was checked and evaluated according to the following evaluation criteria, and the average score of each of the five samples was judged according to the following evaluation criteria. <Evaluation criteria> (Score): (Evaluation result) 4: No change 3: Slight chips or gaps are observed 2: Chips and gaps are clearly visible 1: Dropping and cracking occur <Judgment criteria> (Judgment): (Average score) A: More than 3.5 points B: More than 3 points and less than 3.5 points C: More than 2 points but less than 3 points D: 2 points or less The results are shown in Tables 1 to 4.

[0085] [Table 1]

[0086] [Table 2]

[0087] [Table 3]

[0088] [Table 4]

[0089] *1: JS-1 (manufactured by Sanshin Mining Co., Ltd.) *2: KSP-100 (Shin-Etsu Chemical Co., Ltd.) *3: Tarox R-516P (manufactured by Titanium Industries Co., Ltd.) *4: TAROX IRON OXIDE YP1200P (manufactured by Titanium Industries Co., Ltd.) *5: Tarox Black BL-100P (manufactured by Titanium Kogyo Co., Ltd.) *6: Powder Base M (manufactured by NOF Corporation) *7: Nissan Ectrail (registered trademark) MZ-2 (manufactured by NOF Corporation) *8: Aluminum stearate 600 plant-based (manufactured by NOF Corporation) *9: PARACERA P (manufactured by Paramelt BV) *10:MULTIWAX W445 (manufactured by Sonneborn, LCC Inc.) *11: Sasolwax H1 (manufactured by Sasol Wax GmbH) *12:PERFORMA SW-100 Synthetic Wax (manufactured by NuCera Solutions LLC) *13: Refined Candelilla Wax SR-3 (manufactured by Nippon Natural Products Co., Ltd.) *14: TOWAX-1F6 (manufactured by Toa Kasei Co., Ltd.) *15: WHITE BEES WAX (Miki Chemical Industry Co., Ltd.) *16: Rice Wax SS-I (manufactured by Boso Oil Co., Ltd.) *17: Nikkor PDD (manufactured by Nikko Chemicals Co., Ltd.) *18: Cosmol 168ARN (manufactured by Nisshin Oillio Group Co., Ltd.) *19: SNOW WHITE SPECIAL (manufactured by Iwase Cosfa Co., Ltd.) *20: Eldew PS-306 (manufactured by Ajinomoto Healthy Supply Co., Ltd.) The face powders of the examples were confirmed to have a moist feel in use, good adhesion to the skin (adhesion), no caking, and good drop strength. On the other hand, Comparative Example 1, which did not contain component (B), exhibited significantly reduced moist feel in use and adhesion, and Comparative Example 2, which did not contain component (C), was unable to be filled and therefore could not be evaluated. Comparative Example 3, in which the total amount of components (B) and (C) exceeded 10% by mass, exhibited a significantly reduced caking-inhibiting effect. Comparative Example 4, in which the total amount of components (B) and (C) was less than 0.5% by mass, exhibited significantly reduced moist feel in use and adhesion, and also had insufficient drop strength. Comparative Example 5, in which no heating was performed after dry filling and molding, exhibited significantly reduced moist feel in use and good adhesion to the skin (adhesion). Comparative Example 6, in which water was used as the solvent for the wet filling and molding method, and Comparative Example 7, in which an organic solvent was used as the solvent for the wet filling and molding method, exhibited significantly reduced caking-inhibiting effect.

[0090] Example 30: Face powder (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Talc (ingredient A) (*21) 30.0% 3. Talc (ingredient A) (*22) 18.0% 4. Red iron oxide (ingredient A) (*3) 0.05% 5. Yellow iron oxide (ingredient A) (*4) 0.1% 6. Black iron oxide (ingredient A) (*5) 0.005% 7. Alumina / Stearic Acid Treated Titanium Dioxide / Nylon-12 (Component A) (*23) 2.0% 8. Zinc myristate (ingredient A1) (*6) 1.0% 9. Fischer-Tropsch wax (ingredient B) (*11) 4.0% 10. Propylene glycol dicaprate (ingredient C) (*17) 1.0% 11. Dimethicone (ingredient C) (*24) 1.0% 12. Mineral oil (ingredient C) (*25) 0.5% 13. Dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate (ingredient C1) (*18) 1.5% 14. Chlorphenesin (*26) 0.2% 15.Fragrance 0.15% 16. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.03% 17. Mixture of Hitori Shizuku extract, asparagus extract, artemia extract, guava extract, coffee extract, taiso extract, grape leaf extract, burnet extract, peppermint leaf extract, bifidobacterium culture lysate, cherry blossom flower extract, elderberry flower extract, tea leaf extract, cinnamon extract, jasmine flower extract, polyquaternium-51, multiflora rose fruit extract, rugosa rose flower extract, rosa izayoi extract, water-soluble collagen, royal jelly extract, angelica acutiloba root extract, rosa centifolia flower extract, damask rose flower water, rosemary leaf extract, acerola fruit extract, acetyl glutamic acid, theanine, glycine, hydrolyzed hyaluronic acid, iris root extract, sage leaf extract, tocopherol, honey, rosemary leaf extract, octyldodecanol, roasted bean gum, and sodium hyaluronate (mixture of beauty ingredients) 0.07% *21: Hi-Filler K-5 (Matsumura Sangyo Co., Ltd.) *22: Talc powder EX-15 (Yamaguchi Mica Co., Ltd.) *23: MTXO70-NL (manufactured by Hayate Material Co., Ltd.) *24: KF-96A-6CS (Shin-Etsu Chemical Co., Ltd.) *25:Krearol (manufactured by Sonneborn, LLC Inc.) *26:Elestab CPN Ultrapure (manufactured by BASF Japan Ltd.) (Manufacturing method) a: Components 1 to 9 and 14 were mixed uniformly. b: Components 10 to 13, 15, and 16 were heated and dissolved, then added to a, and component 17 was added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 65°C for 3 hours to obtain a solid powder cosmetic (face powder).

[0091] The face powder of Example 30 was confirmed to have a moist feel, good adhesion to the skin, no caking, and good drop strength. The total amount of component (A1) was 1.0%, the total amount of component (B) was 4.0%, the total amount of component (C) was 4.03%, and the total amount of component (C1) was 1.5%. Therefore, component (B) + (C) = 8.03%, and (B) / (C) = 0.99.

[0092] Example 31: Face Powder (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Dimethiconol-aminopropyltriethoxysilane-treated mica (ingredient A) (*27) 10.0% 3. Zinc laurate 6% treated mica (ingredient A, ingredient A1) 5.0% 4. Talc (ingredient A) (*21) 10.0% 5. Dimethiconol-aminopropyltriethoxysilane-treated talc (ingredient A) (*28) 5.0% 6. Titanium dioxide treated with 6% zinc laurate (ingredient A, ingredient A1) 5.0% 7. Red iron oxide (ingredient A) (*3) 0.025% 8. Yellow iron oxide (ingredient A) (*4) 0.05% 9. Black iron oxide (ingredient A) (*5) 0.002% 10. Dimethicone 2% treated red iron oxide (ingredient A) 0.025% 11. Dimethicone 2% treated yellow iron oxide (ingredient A) 0.05% 12. Dimethicone 2% treated black iron oxide (ingredient A) 0.03% 13. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (ingredient A) (*2) 5.0% 14. (Diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (ingredient A) (*29) 2.0% 15. Silica (ingredient A) (*30) 3.0% 16. Silica (ingredient A) (*31) 10.0% 17. Zinc Myristate (ingredient A1) (*6) 1.0% 18. Zinc stearate (ingredient A1) (*7) 0.3% 19. Microcrystalline wax (ingredient B) (*10) 0.5% 20. Fischer-Tropsch wax (ingredient B) (*11) 6.0% 21. Propylene glycol dicaprate (ingredient C) (*17) 1.0% 22. Diisostearyl Malate (ingredient C) (*32) 0.05% 23. Dimethicone (ingredient C) (*24) 0.05% 24. Dipentaerythrityl hexa(hydroxystearate / stearic acid / rosinate) (ingredient C1) (*18) 0.25% 25. Chlorphenesin (*26) 0.1% 26. Methyl parahydroxybenzoate (*33) 0.1% 27.Fragrance 0.15% 28. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.05% 29. Hydrolyzed conchiolin solution, gentian extract, hydrolyzed silk solution, hydrolyzed rice extract, seaweed extract, L-serine, Iwashobu leaf extract, Artemisia capillaris flower extract, Alpinia speciosa leaf extract, Saccharomyces cerevisiae extract, Pomegranate fruit extract, Pomegranate peel extract, Arisaema globulus fruit extract, Eggplant fruit extract, Harpagophytum root extract, Parsley extract, Royal jelly extract, Rosa alba flower extract, Avocado extract, Gynostemma pentaphyllum extract, Chamomilla recutita (matricaria) water, Barberry fruit extract, Apple extract, Lemongrass extract, Hitori Shizue extract Mixture of 0.05% of: Kiss, Asparagus Extract, Artemia Extract, Guava Extract, Coffee Extract, Dianthus Extract, Grape Leaf Extract, Burnt Extract, Artemisia Capillaris Extract, Rosa Rosa Extract, Oenothera Biennis Extract, Sambucus Nigra Flower Extract, Camellia Sinensis Leaf Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Leaf Extract, Acetyl Glutamic Acid, Theanine, Glycine, Hydrolyzed Hyaluronic Acid, and Sodium Hyaluronate (Mixture of Cosmetic Ingredients) *27: SE-MA-23 (manufactured by Miyoshi Kasei Co., Ltd.) *28: SE-TA-EX (manufactured by Miyoshi Kasei Co., Ltd.) *29: KSP-300 (Shin-Etsu Chemical Co., Ltd.) *30: Sunsphere NP-200 (AGC Si-Tech Co., Ltd.) *31: Silica Microbeads P-1505 (JGC Catalysts and Chemicals Co., Ltd.) *32: Cosmol 222 (manufactured by Nisshin Oillio Group Co., Ltd.) *33: Mekxance-M (manufactured by Ueno Pharmaceutical Co., Ltd.) (Manufacturing method) a: Components 1 to 20, 25, and 26 were mixed uniformly. b: Components 21 to 24, 27, and 28 were heated to dissolve and then added to a, and component 29 was then added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 65°C for 5 hours to obtain a solid powder cosmetic (face powder).

[0093] The face powder of Example 31 was confirmed to have a moist feel, good adhesion to the skin, no caking, and good drop strength. The total amount of component (A1) was 1.36%, the total amount of component (B) was 6.5%, the total amount of component (C) was 1.4%, and the total amount of component (C1) was 0.25%. Therefore, component (B) + (C) = 7.9, and (B) / (C) = 4.64.

[0094] Example 32: Face powder (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Dimethiconol-aminopropyltriethoxysilane-treated mica (ingredient A) (*27) 10.0% 3. Talc (ingredient A) (*21) 5.0% 4. Dimethicone-treated talc (ingredient A) (*34) 5.0% 5. Dimethiconol-aminopropyltriethoxysilane-treated talc (ingredient A) (*28) 10.0% 6. Talc (ingredient A) (*22) 0.025% 7.Synthetic phlogopite (component A) (*35) 10.0% 8. Red iron oxide (ingredient A) (*3) 0.05% 9. Yellow iron oxide (ingredient A) (*4) 0.1% 10. Black iron oxide (ingredient A) (*5) 0.005% 11. (Diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (ingredient A) (*29) 2.0% 12. Silica (ingredient A) (*31) 2.0% 13. Fine particle zinc oxide (ingredient A) (*36) 0.5% 14. Zinc Myristate (ingredient A1) (*6) 1.0% 15. Aluminum distearate (ingredient A1) (*8) 0.2% 16. Paraffin wax (ingredient B) (*9) 0.1% 17. Microcrystalline wax (ingredient B) (*10) 0.1% 18. Fischer-Tropsch wax (ingredient B) (*11) 2.5% 19. Candelilla wax (ingredient B) (*13) 0.1% 20. Beeswax (ingredient B) (*15) 0.1% 21. Rice wax (ingredient B) (*16) 0.1% 22. Triethylhexanoin (ingredient C) (*37) 0.05% 23. Isotridecyl isononanoate (ingredient C) (*38) 0.05% 24. Dimethicone (ingredient C) (*39) 0.05% 25. Dipentaerythrityl hexa(hydroxystearate / stearic acid / rosinate) (ingredient C1) (*18) 1.0% 26. Chlorphenesin (*26) 0.2% 27.Fragrance 0.15% 28. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.05% 29. Mixture of Hitorishige Extract, Asparagus Extract, Artemia Extract, Guava Extract, Coffee Extract, Dianthus Extract, Grape Leaf Extract, Burnt Leaves Extract, Peppermint Leaf Extract, Bifidobacterium Culture Lysate, Prunus Sativus Flower Extract, Sambucus Nigra Flower Extract, Camellia Sinensis Leaf Extract, Tencha Extract, Jasminum Sambac Flower Extract, Polyquaternium-51, Rosa Multiflora Fruit Extract, Rugosa Rose Flower Extract, Rosa Izayoi Extract, Water-Soluble Collagen, Royal Jelly Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Leaf Extract, Acerola Fruit Extract, Acetyl Glutamic Acid, Theanine, Glycine, Hydrolyzed Hyaluronic Acid, and Sodium Hyaluronate (Mixture of Cosmetic Ingredients) 0.05% *34: SA-Talc JA-13R (manufactured by Miyoshi Chemicals Co., Ltd.) *35: PDM-10S (manufactured by Topy Industries Ltd.) *36: MZ-500 (manufactured by Teika Co., Ltd.) *37: Myritol GTEH (manufactured by BASF Japan Ltd.) *38: Salakos 913 (manufactured by Nisshin Oillio Group Co., Ltd.) *39: KF-96A-10CS (Shin-Etsu Chemical Co., Ltd.) (Manufacturing method) a: Components 1 to 21 and 26 were mixed uniformly. b: Components 22 to 25, 27, and 28 were heated to dissolve and then added to a, and component 29 was then added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 50°C for 7 hours to obtain a solid powder cosmetic.

[0095] The face powder of Example 32 was confirmed to have a moist feel, good adhesion to the skin, no caking, and good drop strength. The total amount of component (A1) was 1.2%, the total amount of component (B) was 3.0%, the total amount of component (C) was 1.2%, and the total amount of component (C1) was 1.0%. Therefore, component (B) + (C) = 4.2%, and (B) / (C) = 2.5.

[0096] Example 33: Foundation (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Talc (ingredient A) (*21) 10.0% 3. Dimethiconol-aminopropyltriethoxysilane-treated talc (ingredient A) (*28) 20.0% 4. Titanium dioxide treated with 3% zinc laurate (ingredient A, ingredient A1) 3.0% 5. Lecithin 0.5% treated titanium dioxide (ingredient A) 12.0% 6. 2% Isopropyl Titanium Triisostearate Treated Titanium Oxide (Component A) 5.0% 7. Red iron oxide (ingredient A) (*3) 0.3% 8. Yellow iron oxide (ingredient A) (*4) 0.2% 9. Black iron oxide (ingredient A) (*5) 2.0% 10. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (ingredient A) (*2) 3.0% 11. Silica (ingredient A) (*31) 5.0% 12. Dimethicone / triethoxycaprylylsilane-treated fine zinc oxide (ingredient A) (*39) 3.0% 13. Boron nitride (ingredient A) (*41) 5.0% 14. Boron nitride (ingredient A) (*42) 5.0% 15. Zinc Myristate (ingredient A1) (*6) 0.5% 16. Fischer-Tropsch wax (ingredient B) (*11) 3.0% 17. Polyethylene wax (ingredient B) (*12) 0.1% 18. Carnauba wax (ingredient B) (*14) 0.1% 19. Propylene glycol dicaprate (ingredient C) (*17) 0.1% 20. Ethylhexyl methoxycinnamate (ingredient C) (*43) 2.0% 21. Polysilicone-15 (ingredient C) (*44) 2.0% 22. Dimethicone (ingredient C) (*24) 0.5% 23. Dimethicone (ingredient C) (*45) 0.1% 24. Dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate (ingredient C1) (*18) 0.5% 25. Vaseline (ingredient C1) (*19) 0.5% 26. Chlorphenesin (*26) 0.2% 27.Fragrance 0.15% 28. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.05% 29. Hydrolyzed conchiolin solution, gentian extract, hydrolyzed silk solution, hydrolyzed rice extract, seaweed extract, L-serine, Iwashobu leaf extract, Artemisia capillaris flower extract, Alpinia speciosa leaf extract, Saccharomyces cerevisiae extract, Pomegranate fruit extract, Pomegranate peel extract, Arisaema globulus fruit extract, Eggplant fruit extract, Harpagophytum root extract, Parsley extract, Royal jelly extract, Rosa alba flower extract, Avocado extract, Gynostemma pentaphyllum extract, Chamomilla recutita (matricaria) water, Barberry fruit extract, Apple extract, Lemongrass extract, Hitori Shizue extract Mixture of 0.05% of: Kiss, Asparagus Extract, Artemia Extract, Guava Extract, Coffee Extract, Dianthus Extract, Grape Leaf Extract, Burnt Extract, Artemisia Capillaris Extract, Rosa Rosa Extract, Oenothera Biennis Extract, Sambucus Nigra Flower Extract, Camellia Sinensis Leaf Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Leaf Extract, Acetyl Glutamic Acid, Theanine, Glycine, Hydrolyzed Hyaluronic Acid, and Sodium Hyaluronate (Mixture of Cosmetic Ingredients) *40: SALT-MZ-500 (manufactured by Miyoshi Kasei Co., Ltd.) *41: SHP-3 (manufactured by Mizushima Ferroalloy Co., Ltd.) *42: SHP-6 (manufactured by Mizushima Ferroalloy Co., Ltd.) *43:Uvinal MC80 (manufactured by BASF Japan Ltd.) *44: Parsol SLX (manufactured by DSM Co., Ltd.) *45: KF-96A-100CS (Shin-Etsu Chemical Co., Ltd.) (Manufacturing method) a: Components 1 to 18 and 26 were mixed uniformly. b: Components 19 to 25, 27, and 28 were heated to dissolve and then added to a, and component 29 was then added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 40°C for 10 hours to obtain a solid powder cosmetic.

[0097] The foundation of Example 33 was confirmed to have a moist feel when used, good adhesion to the skin (adhesion), no caking, and good drop strength. The total amount of component (A1) was 0.59%, the total amount of component (B) was 3.2%, the total amount of component (C) was 5.75%, and the total amount of component (C1) was 1.0%. Therefore, component (B) + (C) = 8.95%, and (B) / (C) = 0.56.

[0098] Example 34: Eyeshadow (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Dimethiconol-aminopropyltriethoxysilane-treated mica (ingredient A) (*27) 5.0% 3. 0.5% lecithin-treated titanium dioxide (ingredient A) 0.5% 4. Red iron oxide (ingredient A) (*3) 3.0% 5. Yellow iron oxide (ingredient A) (*4) 0.1% 6. Black iron oxide (ingredient A) (*5) 0.1% 7. Red No. 226 (ingredient A) 5.0% 8. Yellow No. 4 (Component A) 1.0% 9. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (ingredient A) (*2) 12.0% 10. (Diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane) crosspolymer (ingredient A) (*29) 8.0% 11. Silica (ingredient A) (*30) 5.0% 12. Boron nitride (ingredient A) (*42) 10.0% 13. Titanium Mica (Component A) (*46) 0.5% 14. Dimethicone 2% treated titanium dioxide coated mica (ingredient A) 1.5% 15. Titanium dioxide-coated borosilicate (Ca / Al) (ingredient A) (*47) 4.0% 16. Polyglyceryl-2 tetraisostearate 2% treated titanium dioxide coated borosilicate (Ca / Al) (ingredient A) 0.5% 17. Titanium oxide-coated synthetic phlogopite (ingredient A) (*48) 2.0% 18. Titanium oxide-coated synthetic phlogopite (ingredient A) (*49) 1.0% 19. Silica / Titanium Oxide Coated Mica (Component A) (*50) 3.0% 20. Zinc Myristate (ingredient A1) (*6) 2.0% 21. Fischer-Tropsch wax (ingredient B) (*11) 3.0% 22. Propylene glycol dicaprate (ingredient C) (*17) 2.0% 23. Dimethicone (ingredient C) (*24) 0.5% 24. Dimethicone (ingredient C) (*39) 0.5% 25. Dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate (ingredient C1) (*18) 2.9% 26. Vaseline (ingredient C1) (*19) 0.1% 27. Chlorphenesin (*26) 0.2% 28. 1,3-Butylene glycol 0.1% 29.Fragrance 0.1% 30. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.05% 31. Mixture of Hitorishige Extract, Asparagus Extract, Artemia Extract, Guava Extract, Coffee Extract, Dianthus Extract, Grape Leaf Extract, Burnt Leaves Extract, Peppermint Leaf Extract, Bifidobacterium Culture Lysate, Cherry Blossom Flower Extract, Sambucus Nigra Flower Extract, Tea Leaf Extract, Tea Extract, Jasminum Sambac Flower Extract, Polyquaternium-51, Rosa Multiflora Fruit Extract, Rugosa Rose Flower Extract, Rosa Izayoi Extract, Water-Soluble Collagen, Royal Jelly Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Leaf Extract, Acerola Fruit Extract, Acetyl Glutamic Acid, Theanine, Glycine, Hydrolyzed Hyaluronic Acid, and Sodium Hyaluronate (Mixture of Cosmetic Ingredients) 0.05% *46: Flamenco Gold 220C (BASF Ltd.) *47: Microglass Metashine MT1080RR (manufactured by Nippon Sheet Glass Co., Ltd.) *48: Helios R100S (manufactured by Topy Industries Ltd.) *49: HELIOS R10R (manufactured by Topy Industries Ltd.) *50: TIMIRON SPLENDID RED (Merck) (Manufacturing method) a: Components 1 to 21 and 27 were mixed uniformly. b: Components 22 to 26 and 28 to 30 were heated to dissolve and then added to a, and component 31 was then added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 60°C for 15 hours to obtain a solid powder cosmetic.

[0099] The eye shadow of Example 34 was confirmed to have a moist feel when used, good adhesion to the skin (adhesion), no caking, and good drop strength. The total amount of component (A1) was 2.0%, the total amount of component (B) was 3.0%, the total amount of component (C) was 6.05%, and the total amount of component (C1) was 3.0%. Therefore, component (B) + (C) = 9.05, and (B) / (C) = 0.50.

[0100] Example 35: Eyebrows (Component) (mass%) 1. Mica (ingredient A) (*1) remaining amount 2. Talc (ingredient A) (*21) 10.0% 3. Red iron oxide (ingredient A) (*3) 5.0% 4. Yellow iron oxide (ingredient A) (*4) 5.0% 5. Black iron oxide (ingredient A) (*5) 40.0% 6. Fine particle zinc oxide (ingredient A) (*36) 2.0% 7. Boron nitride (ingredient A) (*37) 2.0% 8. Black iron oxide coated mica titanium (ingredient A) (*51) 5.0% 9. Titanium dioxide-coated mica (ingredient A) (*46) 3.0% 10. Zinc myristate (ingredient A1) (*6) 0.1% 11. Fischer-Tropsch wax (ingredient B) (*11) 3.0% 12. Polyethylene wax (ingredient B) (*12) 0.5% 13. Beeswax (ingredient B) (*15) 0.5% 14. Mineral oil (ingredient C) (*25) 2.0% 15. Hydrogenated polyisobutene (component C) (*52) 1.0% 16. Dipentaerythrityl hexahydroxystearate / hexastearate / hexarosinate (ingredient C1) (*18) 0.1% 17. Vaseline (ingredient C1) (*19) 0.9% 18. Chlorphenesin (*26) 0.1% 19.Fragrance 0.3% 20. Mixture of lavender oil, almond oil, macadamia nut oil, camellia oil, refined jojoba oil, apricot kernel oil, corn oil, grape seed oil, sunflower oil, hazelnut oil, and rosehip oil (mixture of beauty ingredients) (ingredient C) 0.05% 21. Mixture of Hitorishige Extract, Asparagus Extract, Artemia Extract, Guava Extract, Coffee Extract, Dianthus Extract, Grape Leaf Extract, Burnt Leaves Extract, Peppermint Leaf Extract, Bifidobacterium Culture Lysate, Prunus Sinensis Flower Extract, Sambucus Nigra Flower Extract, Camellia Sinensis Leaf Extract, Tencha Extract, Jasminum Sambac Flower Extract, Polyquaternium-51, Rosa Multiflora Fruit Extract, Rugosa Rose Flower Extract, Rosa Izayoi Extract, Water-Soluble Collagen, Royal Jelly Extract, Angelica Root Extract, Rosa Centifolia Flower Extract, Rosa Damascena Flower Water, Rosemary Leaf Extract, Acerola Fruit Extract, Acetyl Glutamic Acid, Theanine, Glycine, Hydrolyzed Hyaluronic Acid, and Sodium Hyaluronate (Mixture of Cosmetic Ingredients) 0.05% *51:COLORONA MICA BLACK (Merck Co., Ltd.) *52: Pearleem 18 (manufactured by NOF Corporation) (Manufacturing method) a: Components 1 to 13 and 18 were mixed uniformly. b: Components 14 to 17, 19, and 20 were heated to dissolve and then added to a, and component 21 was added in the same manner and mixed uniformly. c: The mixture obtained in b was pulverized to obtain a powdered cosmetic base. d: The powder bulk obtained in c was filled into a container and press molded using the dry filling molding method. e: The pressed product obtained in d was heated at 55°C for 18 hours to obtain a solid powder cosmetic.

[0101] The eyebrow cream of Example 35 was confirmed to have a moist feel, good adhesion to the skin, no caking, and good drop strength. The total amount of component (A1) was 0.1%, the total amount of component (B) was 4.0%, the total amount of component (C) was 4.05%, and the total amount of component (C1) was 1.0%. Therefore, component (B) + (C) = 8.05, and (B) / (C) = 0.99.

Claims

1. The following components (A) to (C): (A) Powder (B) Oil solution that is solid at 25°C (C) Oil other than component (B) A solid powder cosmetic comprising: the total content of the component (B) and the component (C) is 0.5 to 10% by mass in the solid powder cosmetic; A solid powder cosmetic is prepared by molding a cosmetic base containing the components (A), (B), and (C) by a dry filling molding method, and then heating the molded product.

2. 2. The solid powder cosmetic according to claim 1, wherein the heating temperature is equal to or lower than the melting point of said component (B).

3. 3. The solid powder cosmetic preparation according to claim 1, wherein the mass ratio (B) / (C) of the content of said component (B) to the content of said component (C) is 0.1 to 10.

4. 3. The solid powder cosmetic according to claim 1, wherein the component (C) comprises a component (C1) an oil agent that is pasty at 25°C.

5. 3. The solid powder cosmetic preparation according to claim 1, wherein the component (A) comprises a component (A1) metal soap.

6. 6. The solid powder cosmetic according to claim 5, wherein the content of said component (A1) is 0.01 to 10% by mass based on the mass of the solid powder cosmetic.

7. The method comprises molding a cosmetic base by a dry filling molding method and then heating the molded product; The cosmetic base is The following components (A) to (C): (A) Powder (B) Oil solution that is solid at 25°C (C) Oil other than component (B) and wherein the component (B) and the component (C) are contained in a total amount of 0.5 to 10 mass %.

8. 8. The method for producing a solid powder cosmetic according to claim 7, wherein the heating temperature is equal to or lower than the melting point of said component (B).

9. 9. The method for producing a solid powder cosmetic according to claim 7, wherein the mass ratio (B) / (C) of the content of said component (B) to the content of said component (C) is 0.1 to 10.

10. The method for producing a solid powder cosmetic according to claim 7 or 8, wherein the component (C) comprises a component (C1) an oil agent that is pasty at 25°C.

11. The method for producing a solid powder cosmetic according to claim 7 or 8, wherein the component (A) comprises a component (A1) metal soap.

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