Electrode assembly, and secondary battery, battery pack, and vehicle including the same

Abstract

The present specification relates to an electrode assembly in which a positive electrode, a negative electrode, and a separator provided between the positive electrode and the negative electrode are laminated and wound up, and a secondary battery, a battery pack, and a transportation means including the same.

Description

[Technical field]

[0001] This application claims the benefit of the filing date of Korean Patent Application No. 10-2022-0184812, filed with the Korean Intellectual Property Office on December 26, 2022, the entire contents of which are incorporated herein by reference.

[0002] The present specification relates to an electrode assembly in which a positive electrode, a negative electrode, and a separator provided between the positive electrode and the negative electrode are laminated and wound up, and a secondary battery, a battery pack, and a transportation means including the same. [Background technology]

[0003] In the case of cylindrical batteries, a jelly roll type electrode assembly is manufactured by winding a long electrode with a fixed width into a roll. A cylindrical battery manufactured by inserting such a jelly roll type electrode assembly into a battery case undergoes repeated electrode contraction / expansion during charging / discharging. In particular, when an in tab is located in the core of the jelly roll type electrode assembly or a silicon-based active material is added to the negative electrode, which increases the degree of contraction / expansion of the electrode assembly, the pressure acting on the winding core side of the electrode assembly increases significantly.

[0004] Recently, as low resistance / high capacity designs have increased, jelly roll type electrode assemblies have become more likely to include multiple tabs or to contain silicon-based active materials, which increases the possibility of deformation of the electrode assembly located on the winding core side due to contraction / expansion of the electrode assembly. In particular, if the separator located between the negative and positive electrodes is damaged, the negative and positive electrodes come into direct contact with each other, causing an internal short circuit, which can cause heat generation and fire.

[0005] In order to solve the problems of the separator breakage and internal short circuit caused by the deformation of the electrode assembly, there is currently a need to develop a technology that can protect the positive electrode and separator in the corresponding area and suppress the occurrence of internal short circuit. Summary of the Invention [Problem to be solved by the invention]

[0006] The present specification provides an electrode assembly in which a positive electrode, a negative electrode, and a separator provided between the positive electrode and the negative electrode are stacked and wound up, and a secondary battery, a battery pack, and a transportation means including the same. [Means for solving the problem]

[0007] One embodiment of the present specification provides an electrode assembly in which a positive electrode, a negative electrode, and a separator provided between the positive electrode and the negative electrode are laminated and wound up, the negative electrode including a negative electrode current collector and a negative electrode active material layer provided on at least one surface of the negative electrode current collector, the negative electrode including a negative electrode uncoated portion where the negative electrode active material layer is not provided at one end of the negative electrode current collector on the winding core side, and a negative electrode tab is provided on the negative electrode uncoated portion, the separator and the negative electrode extend longer than the longitudinal end of the positive electrode on the winding core side of the electrode assembly and are further wound up, the winding core of the electrode assembly is the center of the circle, and in any circle having a radius equal to the distance from the center of the circle to the longitudinal end of the positive electrode, a central angle of a minor arc formed from a contact point where a line extending from a winding start point of the negative electrode tab to an arbitrary point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle to the longitudinal end of the positive electrode is 90° or less. Specifically, the central angle of the minor arc formed from the contact point to the longitudinal end of the positive electrode may be 90° or less, 85° or less, 80° or less, 75° or less, 70° or less, 65° or less, 60° or less, 55° or less, 50° or less, 45° or less, 40° or less, 35° or less, 30° or less, 25° or less, 20° or less, 15° or less, 10° or less, or 5° or less, or may be 0° or more, more than 0°, 1° or more, 2° or more, 3° or more, or 4° or more.

[0008] In another embodiment of the present specification, the positive electrode may include a positive electrode current collector and a positive electrode active material layer provided on at least one surface of the positive electrode current collector, the positive electrode may include a positive electrode uncoated portion where the positive electrode active material layer is not provided, and a positive electrode tab may be provided on the positive electrode uncoated portion. In this case, in the arbitrary circle, a central angle of an arc formed from a contact point where a line extending from a winding start portion of the positive electrode tab to an arbitrary point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle to a longitudinal end of the positive electrode may be more than 90° and not more than 180°.

[0009] In another embodiment of the present specification, the positive electrode uncoated portion may be located between two positive electrode supporting portions on which the positive electrode active material layers are provided.

[0010] In another embodiment of the present specification, the negative electrode may further include an additional negative electrode uncoated portion at an end portion of an outer corner of the negative electrode current collector where the negative electrode active material layer is not provided, and an additional negative electrode tab may be provided on the additional negative electrode uncoated portion.

[0011] In another embodiment of the present specification, the positive electrode includes a positive electrode current collector and a positive electrode active material layer provided on both sides of the positive electrode current collector, and the positive electrode active material layers provided on both sides of the positive electrode current collector may have the same or different winding start portions, and preferably may have the same winding start portions.

[0012] In another embodiment of the present specification, the positive electrode includes a positive electrode active material layer provided on both sides of the positive electrode current collector, and the positive electrode active material layers provided on both sides of the positive electrode current collector may have the same or different winding end portions, and preferably may have the same end portions.

[0013] In another embodiment of the present specification, the length of the negative electrode tab may be 2 mm or more and 5 mm or less in the winding direction.

[0014] In another embodiment of the present specification, the separator may include a first separator and a second separator, and the electrode assembly may be formed by sequentially stacking the negative electrode, the first separator, the positive electrode, and the second separator and winding them up.

[0015] In other embodiments herein, the negative electrode may be wound so as to be positioned at the outermost corner.

[0016] Another embodiment of the present specification provides a secondary battery including the electrode assembly described above and a battery case for housing the electrode assembly. The electrode assembly may have a vertical cross section of a winding axis that is circular, and the battery case may be cylindrical.

[0017] Another embodiment herein provides a battery pack including two or more of the secondary batteries described above.

[0018] Another embodiment of the present specification provides a vehicle including the battery pack described above. The vehicle can be any vehicle that moves luggage, people, etc., or performs work while moving, and can be a bicycle, heavy machinery, agricultural equipment, a car, a bus, an airplane, etc. Effect of the Invention

[0019] In an electrode assembly according to one embodiment of the present specification, the negative electrode tab is disposed behind the positive electrode winding start portion in the winding direction of the positive electrode, thereby making it possible to suppress slippage of the positive electrode end portion during charging and discharging of the battery.

[0020] By providing an electrode assembly according to another embodiment of the present disclosure, damage to the separator due to deformation of the electrode assembly caused by contraction / expansion of the electrodes during charging / discharging of the battery can be prevented, and internal short circuits between the electrodes can be prevented, thereby improving battery stability and life characteristics.

[0021] In an electrode assembly according to another embodiment of the present specification, the negative electrode tab is disposed behind the positive electrode winding start portion in the positive electrode winding direction, so that the shape of the winding core can be well maintained during charging and discharging of the battery. [Brief description of the drawings]

[0022] [Figure 1] FIG. 2 is a perspective view of a wound electrode stack. [Diagram 2] 4 shows a winding process of an electrode stack. [Diagram 3] A plan view of the wound electrode laminate and an arbitrary circle having a radius equal to the distance from the center of the circle to the longitudinal end of the positive electrode based on the plan view are shown. [Figure 4] 4 is a vertical cross-sectional view of a secondary battery housed in a battery case that houses a wound electrode stack. FIG. [Diagram 5] 1 is a diagram illustrating a schematic configuration of a battery pack according to an embodiment of the present invention. [Figure 6] FIG. 6 is a diagram for explaining a vehicle including the battery pack of FIG. 5. [Figure 7] FIG. 11 is a diagram showing the positioning of a positive electrode winding start part in the embodiment. [Figure 8] 1 shows CT images of an example and a comparative example before and after battery operation. [Figure 9] This shows a method for confirming the degree of deformation of the negative electrode on the winding core side after battery operation in a CT image. [Explanation of symbols]

[0023] 1...electrode assembly 10. Winding core 1b: Outermost angle 1c...Internal 110...Negative electrode 111...Negative electrode current collector 112...first negative electrode active material layer 113...Second negative electrode active material layer 114 Negative electrode uncoated area 116 Negative electrode tab 120...Positive electrode 121...Positive electrode current collector 122...first positive electrode active material layer 123...Second positive electrode active material layer 131...1st separation membrane 132...Second separation membrane 20...Secondary battery 21 ···Can 22 Cap Assembly 200···Battery pack 201 ···Cylindrical battery cell 202 Pack Housing V ···Automotive DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0024] The present invention will be described in detail below with reference to the drawings. However, the drawings are for illustrating the present invention and the scope of the present invention is not limited by the drawings.

[0025] 1 is a perspective view of a wound electrode laminate. First, a positive electrode 120, a negative electrode 110, and separators 131 and 132 provided between the positive electrode 120 and the negative electrode 110 may be laminated. The separator may include two separators, and as shown in FIG. 1, a first separator 131 may be provided between the negative electrode 110 and the positive electrode 120, and an additional second separator 132 may be provided on the surface of the positive electrode 120 opposite to the surface of the positive electrode 120 contacting the first separator 131. Specifically, the second separator 132, the positive electrode 120, the first separator 131, and the negative electrode 110 may be sequentially laminated.

[0026] In the winding direction, the second separator 132, the positive electrode 120, the first separator 131, and the negative electrode 110 may be stacked in order and wound on the negative electrode 110 side. When wound in this manner, the separator may be exposed at the outermost corner 1b in the wound electrode assembly.

[0027] If necessary, the electrode assembly may be wound up toward the positive electrode 120 as shown in FIG. 2 in the opposite direction to the above winding direction. When wound up in this manner, the negative electrode 110 or both the negative electrode 110 and the separator (first separator 131, second separator 132) may be exposed at the outermost corner 1b in the wound electrode assembly. In this case, when the negative electrode is exposed at the outermost corner 1b, only the negative electrode uncoated portion (negative electrode uncoated portion 114) at the outer corner where no negative electrode active material layer is provided may be exposed, or the negative electrode uncoated portion at the outer corner and the negative electrode support portion at the outer corner may be exposed at the outermost corner 1b.

[0028] The inside 1c of the electrode assembly 1 wound up as shown in Fig. 1 refers to the part of the wound electrode assembly excluding the outermost corner 1b. In this case, if the wound electrode assembly is a pillar, the outermost corner 1b means the side exposed to the outside, and the inside 1c includes the entire inner region of the pillar excluding the side.

[0029] The laminated electrode assembly 1 as shown in FIG. 2 can be wound up to produce a wound roll having a plan view as shown in FIG.

[0030] The positive electrode 120 and the negative electrode 110 may each include a current collector and an active material layer provided on at least one surface of the current collector.

[0031] The positive electrode 120 may include a positive electrode current collector 121 and positive electrode active material layers 122, 123 provided on at least one surface of the positive electrode current collector 121. The positive electrode active material layers 122, 123 may be provided on both surfaces of the positive electrode current collector 121, or may include a first positive electrode active material layer 122 provided on one surface of the positive electrode current collector 121 and a second positive electrode active material layer 123 provided on the surface opposite to the surface on which the first positive electrode active material layer 122 is provided.

[0032] The positive electrode 120 includes one or more positive electrode tabs, and the positive electrode tabs are located in positive electrode uncoated portions where the positive electrode active material layers (first positive electrode active material layer 122 and second positive electrode active material layer 123) are not provided.

[0033] In one embodiment, the positive electrode 120 may include a positive electrode holder in which a positive electrode active material layer is provided on the positive electrode current collector 121, and a positive electrode uncoated portion in which no positive electrode active material layer is provided at one or both ends of the positive electrode current collector 121. In this case, the positive electrode tab may be located in the positive electrode uncoated portion located at one or both ends of the positive electrode current collector 121, preferably in the positive electrode uncoated portion at one end.

[0034] In another embodiment, the positive electrode 120 may include a positive electrode uncoated portion at an outer corner end of the positive electrode current collector 121 where a positive electrode active material layer is not provided, and a positive electrode tab may be formed on the positive electrode uncoated portion.

[0035] In another embodiment, the positive electrode 120 may include two or more positive electrode holding parts on the positive electrode current collector 121, spaced apart in the longitudinal direction and having a positive electrode active material layer thereon, and a positive electrode uncoated part between the two or more positive electrode holding parts where no positive electrode active material layer is provided. In this case, the positive electrode tab may be located in the positive electrode uncoated part between the two or more positive electrode holding parts, preferably in the positive electrode uncoated part between two positive electrode holding parts. In this case, both end parts of the positive electrode 120 may be formed as free edges without a positive electrode uncoated part.

[0036] The positive electrode 120 may include a positive electrode current collector 121 and positive electrode active material layers 122, 123 provided on both sides of the positive electrode current collector 121, and the first positive electrode active material layer 122 provided on one side of the positive electrode current collector 121 and the second positive electrode active material layer 123 provided on the other side may have the same or different lengths.

[0037] In another embodiment of the present specification, the positive electrode 120 includes a positive electrode current collector 121 and positive electrode active material layers (first positive electrode active material layer 122, second positive electrode active material layer 123) provided on both sides of the positive electrode current collector 121, and the positive electrode active material layers (first positive electrode active material layer 122, second positive electrode active material layer 123) provided on both sides of the positive electrode current collector 121 may have the same winding start portion.

[0038] In another embodiment of the present specification, the positive electrode 120 includes positive electrode active material layers (first positive electrode active material layer 122, second positive electrode active material layer 123) provided on both sides of the positive electrode current collector 121, and the positive electrode active material layers (first positive electrode active material layer 122, second positive electrode active material layer 123) provided on both sides of the positive electrode current collector 121 may have the same winding end portion.

[0039] The negative electrode 110 may include a negative electrode current collector 111 and negative electrode active material layers 112, 113 provided on at least one surface of the negative electrode current collector 111. The negative electrode active material layers 112, 113 may be provided on both surfaces of the negative electrode current collector 111, or may include a first negative electrode active material layer 112 provided on one surface of the negative electrode current collector 111 and a second negative electrode active material layer 113 provided on the surface opposite to the surface on which the first negative electrode active material layer 112 is provided.

[0040] The negative electrode 110 includes one or more negative electrode tabs 116, and the negative electrode tabs 116 are located in negative electrode uncoated portions where the negative electrode active material layers (first negative electrode active material layer 112, second negative electrode active material layer 113) are not provided.

[0041] In one embodiment, the negative electrode 110 may include a negative electrode holder in which a negative electrode active material layer is provided on the negative electrode current collector 111, and a negative electrode uncoated portion in which no negative electrode active material layer is provided at one or both ends of the negative electrode current collector 111. In this case, the negative electrode tab 116 may be located in the negative electrode uncoated portion located at one or both ends of the negative electrode current collector 111, and preferably, in the negative electrode uncoated portions at both ends.

[0042] In another embodiment, the negative electrode 110 may include a negative electrode uncoated portion at the end of the negative electrode current collector 111 on the winding core side where the active material layer is not provided, and a negative electrode tab 116 may be formed on the negative electrode uncoated portion.

[0043] The negative electrode 110 may include a negative electrode current collector 111 and negative electrode active material layers 112, 113 provided on both sides of the negative electrode current collector 111, and the first negative electrode active material layer 112 provided on one side of the negative electrode current collector 111 and the second negative electrode active material layer 113 provided on the other side may have the same or different lengths.

[0044] In still another embodiment, the positive electrode 120 may include two positive electrode holding portions spaced apart in the winding direction of the electrode assembly 1 and having the positive electrode active material layers (first positive electrode active material layer 122 and second positive electrode active material layer 123) provided on the positive electrode collector 121; and a positive electrode uncoated portion between the two holding portions where the positive electrode collector 121 does not have the positive electrode active material layer, and one positive electrode tab is formed on the positive electrode uncoated portion. The negative electrode 110 may include two negative electrode uncoated portions on both side ends of the negative electrode collector 111 where the negative electrode active material layers are not provided, and one negative electrode tab 116 is formed on each of the two negative electrode uncoated portions.

[0045] In one embodiment of the present specification, in an electrode assembly 1 in which a positive electrode 120, a negative electrode 110, and a separator (first separator 131, second separator 132) provided between the positive electrode 120 and the negative electrode 110 are laminated and wound, the negative electrode 110 includes a negative electrode current collector 111 and a negative electrode active material layer (first negative electrode active material layer 112, second negative electrode active material layer 113) provided on at least one surface of the negative electrode current collector 111, the negative electrode 110 includes a negative electrode uncoated portion where the negative electrode active material layer is not provided at one end of the negative electrode current collector 111 on the winding core side, a negative electrode tab 116 is provided on the negative electrode uncoated portion, and the separator (first separator 131, second separator 132) is provided on the winding core side of the electrode assembly 1. The electrode assembly is provided in which a separation film (a first separation film 131, a second separation film 132) and the negative electrode 110 extend longer than the longitudinal end of the winding core side of the positive electrode 120 and are further wound up, the winding core of the electrode assembly 1 is the center of a circle, and in any circle having a radius equal to the distance from the center of the circle to the longitudinal end of the positive electrode 120 on the winding core side, i.e., the winding start part of the positive electrode 120, a central angle a of a minor arc formed from a contact point where a line extending from the winding start part of the negative electrode tab 116 to an arbitrary point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle to the longitudinal end of the positive electrode 120 is 90° or less. Specifically, the central angle of the minor arc formed from the contact point to the longitudinal end of the positive electrode may be 90° or less, 85° or less, 80° or less, 75° or less, 70° or less, 65° or less, 60° or less, 55° or less, 50° or less, 45° or less, 40° or less, 35° or less, 30° or less, 25° or less, 20° or less, 15° or less, 10° or less, or 5° or less, or 0° or more, more than 0°, 1° or more, 2° or more, 3° or more, or 4° or more. In this case, the winding start portion of the positive electrode 120 may be the winding start portion of the positive electrode holder on which the positive electrode active material layer (first positive electrode active material layer 122, second positive electrode active material layer 123) is provided.

[0046] In this specification, the winding start portion can be expressed as a single point, namely, the winding start point.

[0047] In another embodiment of the present specification, the positive electrode 120 includes a positive electrode current collector 121 and a positive electrode active material layer (first positive electrode active material layer 122, second positive electrode active material layer 123) provided on at least one surface of the positive electrode current collector 121, and the positive electrode 120 may include a positive electrode uncoated portion where the positive electrode active material layer is not provided, and a positive electrode tab (not shown) may be provided on the positive electrode uncoated portion. In this case, in the arbitrary circle, a central angle b of an arc formed from a contact point where a line extending from a winding start portion of the positive electrode tab (not shown) to an arbitrary point around the arbitrary circle and a tangent to the arbitrary circle form a right angle with each other to an end of the longitudinal direction of the positive electrode 120 may be more than 90° and not more than 180°.

[0048] In this specification, the winding core 10, which is the winding device in Figure 2, is removed in Figure 3 after winding is completed, and the winding core 10 in Figure 3 may be a space that is retained after the winding device is removed, a winding reference line, or the center point of a circle in a vertical cross section cut perpendicular to the axis of the wound electrode assembly 1, and the "winding core side" means a region close to the winding core or a direction toward the winding core.

[0049] In another embodiment of the present specification, in an electrode assembly 1 in which a positive electrode 120, a negative electrode 110, and a separator (first separator 131, second separator 132) provided between the positive electrode 120 and the negative electrode 110 are laminated and wound, the negative electrode 110 includes a negative electrode current collector 111 and a negative electrode active material layer (first negative electrode active material layer 112, second negative electrode active material layer 113) provided on at least one surface of the negative electrode current collector 111, 0 indicates that a negative electrode tab 116 is provided at one end of the negative electrode current collector 111 on the winding core side, the separator (first separator 131, second separator 132) and the negative electrode 110 extend longer than the longitudinal end of the positive electrode 120 on the winding core side of the electrode assembly 1 and are further wound up, and in at least one cross section in the vertical direction of the winding core of the electrode assembly 1, a straight line L connecting the winding core to the longitudinal end of the positive electrode 120 on the winding core side is ce and a straight line L connecting the winding core to the winding start point of the negative electrode tab 116. at The angle θ1 between the straight line L and the axial line L may be 90° or less.ce From the line L at The angle in the counterclockwise direction from the line L at From the line L ce The angle in a clockwise direction to the line L ce From the line L at The angle in the winding direction is

[0050] In other words, the angle θ1 is the central angle a of a minor arc formed from a contact point between a line extending from the winding start part of the negative electrode tab 116 to an arbitrary point around the arbitrary circle and a tangent to the arbitrary circle, which forms a right angle, to the longitudinal end part on the winding core side of the positive electrode in Fig. 3. In the arbitrary circle, the contact point by the winding start part of the negative electrode tab 116 is within a range of 90° or less in the winding direction with respect to the longitudinal end part on the winding core side of the positive electrode.

[0051] Since the negative electrode 110 is wound around the core, the negative electrode tab 116 on the winding core side is wound first before the positive electrode winding start portion is wound, and then the positive electrode 120 is wound. As shown in FIG. 3, in the arbitrary circle, when the contact point by the winding start portion of the negative electrode tab 116 is in a range of 90° or less in the winding direction based on the longitudinal end portion of the winding core side of the positive electrode 120, the negative electrode tab 116 is disposed on the back side in the winding direction of the positive electrode 120 compared to the winding start portion of the positive electrode 120. In this case, the negative electrode tab 116, which is wound relatively before the positive electrode 120 and is relatively rigid, presses the end portion of the positive electrode 120 on the winding core side by centrifugal force, and the movement of the end portion of the positive electrode 120 on the winding core side, i.e., slippage, can be suppressed.

[0052] In another embodiment of the present specification, the length of the negative electrode tab 116 may be 2 mm or more and 5 mm or less in the winding direction. In this case, rigidity is imparted to the end of the positive electrode 120 on the winding core side by pressing the end to suppress the movement.

[0053] In another embodiment of the present specification, the negative electrode 110 may further include an additional negative electrode uncoated portion at one end of an outer corner of the negative electrode current collector 111 where the negative electrode active material layer is not provided, and an additional negative electrode tab may be provided on the additional negative electrode uncoated portion.

[0054] In another embodiment of the present specification, a straight line L connecting the winding core to the longitudinal end of the positive electrode 120 on the winding core side ce and a straight line L connecting the winding core to the winding start point of the positive electrode tab (not shown). ae The angle θ2 formed by the straight line L may be greater than 90° and less than 180°. ce From the line L ae The angle in the counterclockwise direction from the line L ae From the line L ce The angle in a clockwise direction to the line L ce From the line L ae The angle θ2 may be a central angle b of a minor arc formed from a contact point where a line extending from the winding start portion of the positive electrode tab (not shown) to an arbitrary point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle, to an end portion of the positive electrode 120 in the longitudinal direction on the winding core side.

[0055] If the positions within any circle are likened to a clock, as shown in FIG. 3, the longitudinal end (winding start portion) of the positive electrode 120 on the winding core side can be expressed as the 6 o'clock position, the winding start portion of the negative electrode tab 116 as the 4 o'clock position, and the winding start portion of the positive electrode tab (not shown) as the 12 o'clock position.

[0056] Another embodiment of the present specification provides a secondary battery including the electrode assembly described above and a battery case for housing the electrode assembly. The electrode assembly may have a vertical cross section of a winding axis that is circular, and the battery case may be cylindrical.

[0057] In one embodiment of the present specification, the secondary battery may be a battery with a form factor ratio (defined as the value obtained by dividing the diameter of a cylindrical battery by its height, i.e., the ratio of the diameter Φ to the height H) of about 0.4 or less. Here, the form factor means a value indicating the diameter and height of a cylindrical secondary battery. For example, it may be an 18650 cell, a 21700 cell, etc. In the case of an 18650 cell, the diameter is about 18 mm, the height is about 65 mm, and the form factor ratio is about 0.277. In the case of a 21700 cell, the diameter is about 21 mm, the height is about 70 mm, and the form factor ratio is about 0.300.

[0058] In one embodiment of the present specification, the secondary battery may be a cylindrical secondary battery having a form factor ratio of greater than 0.4.

[0059] A cylindrical secondary battery according to an embodiment of the present specification may be a 46110 cell, a 48750 cell, a 48110 cell, a 48800 cell, or a 46800 cell. In the number representing the form factor, the first two numbers represent the diameter of the cell, the next two numbers represent the height of the cell, and the last number 0 indicates that the cross section of the cell is circular.

[0060] The secondary battery according to one embodiment of the present specification may be a cylindrical secondary battery having a cylindrical cell with a diameter of 46 mm, a height of 110 mm, and a form factor ratio of 0.418.

[0061] The secondary battery according to one embodiment of the present specification may be a cylindrical secondary battery having a cylindrical cell with a diameter of 48 mm, a height of 75 mm, and a form factor ratio of 0.640.

[0062] The secondary battery according to one embodiment of the present specification may be a cylindrical secondary battery having a cylindrical cell with a diameter of 48 mm, a height of 110 mm, and a form factor ratio of 0.436.

[0063] The secondary battery according to one embodiment of the present specification may be a cylindrical secondary battery having a cylindrical cell with a diameter of 48 mm, a height of 80 mm, and a form factor ratio of 0.600.

[0064] The secondary battery according to one embodiment of the present specification may be a cylindrical secondary battery having a cylindrical cell with a diameter of 46 mm, a height of 80 mm, and a form factor ratio of 0.575.

[0065] Another embodiment of the present specification provides a secondary battery including the above-described electrode assembly 1 and a battery case for housing the electrode assembly 1.

[0066] 4 shows an example of a secondary battery 20 housed in a battery case housing a wound electrode assembly 1. The electrode assembly 1 may have a circular vertical cross section of a winding core axis, and the battery case may be cylindrical. The battery case may include a can 21 and a cap assembly 22.

[0067] The can 21 may have a columnar structure with a space formed therein. The can 21 may accommodate a battery assembly 1 including electrodes and a separator, and an electrolyte (not shown) in the space inside. One side of the can 21 may have an open structure, and the other side may have a sealed structure. Here, the one side and the other side of the can 21 refer to the ends located at the top and bottom along the direction of gravity or the central axis of the can 21.

[0068] Can 21 may be constructed of a lightweight, conductive metallic material such as aluminum or an aluminum alloy.

[0069] A cap assembly 22 may be coupled to the top of the can 21 and may include a top cap, a safety vent, and a current interrupt device.

[0070] The top cap may serve as an electrode terminal that protrudes from the top of the cap assembly 22 and is electrically connected to the outside. The safety vent may release high-pressure gas when gas is generated inside the battery above a certain level due to an increase in internal pressure, and the current interruption device may interrupt the current when the internal pressure of the battery increases.

[0071] The top cap may be coupled to the top of the can 21. That is, the top cap may be coupled to a crimping portion located at the top of the can 21.

[0072] The secondary battery 20 according to the present invention may include a gasket between the crimping portion and the top cap, which can increase the sealing force of the case.

[0073] The top cap may include a protrusion that protrudes upward in the direction of gravity, an edge that is coupled to the gasket, and a connecting portion that connects the protrusion and the edge.

[0074] The safety vent may be located under the top cap and coupled to an end of the top cap. The safety vent may contact an end of the top gap by a certain length, and a portion of the safety vent other than the contact length may be spaced a certain distance from the top cap.

[0075] The safety vent may be provided by being folded at least one time. For example, the safety vent may be provided with two notches in a portion that does not contact the top cap. That is, the safety vent may be folded by the notches, and the center of the safety vent may be recessed to form a concave central portion. The safety vent may be provided with a vent portion that connects the end that contacts the top cap and the concave central portion.

[0076] The current interrupt element may be positioned below the safety vent and in at least partial contact with the safety vent.

[0077] The current interrupting element may include a central portion protruding toward the safety vent and a CID filter portion located outside the central portion. Therefore, the cap assembly 22 may be in contact with the central portion of the current interrupting element and the recessed central portion of the safety vent.

[0078] The cap assembly 22 according to the present invention may be provided with a CID gasket at the end of the CID filter section, which can prevent the safety vent from contacting the current interrupting element at any portion other than the center.

[0079] Another embodiment of the present disclosure provides a battery pack including two or more of the secondary batteries described above. Figure 5 is a schematic diagram illustrating the configuration of a battery pack according to an embodiment of the present invention.

[0080] 5, a battery pack 200 according to an embodiment of the present invention includes an assembly of electrically connected secondary battery cells (cylindrical battery cells 201) and a pack housing 202 that accommodates the assembly. The cylindrical secondary battery cells (cylindrical battery cells 201) are the battery cells according to the above-described embodiment. For convenience of illustration, components such as bus bars for electrically connecting the cylindrical battery cells 201, a cooling unit, and external terminals are omitted in the drawings.

[0081] Another embodiment of the present specification provides a vehicle including the above-described battery pack 200. The vehicle may be any vehicle that moves luggage, people, etc., or performs work while moving, and may be a bicycle, heavy machinery, agricultural equipment, a car, a bus, an airplane, etc.

[0082] The battery pack 200 may be mounted on an automobile V. The automobile may be, for example, an electric automobile, a hybrid automobile, or a plug-in hybrid automobile. The automobile V includes a four-wheeled automobile or a two-wheeled automobile. FIG. 6 is a diagram for explaining an automobile V including the battery pack 200 of FIG. 5.

[0083] 6, an automobile V according to an embodiment of the present specification includes a battery pack 200 according to an embodiment of the present specification. The automobile V is operated by receiving power from the battery pack 200 according to an embodiment of the present invention. EXAMPLES

[0084] As described above, the present invention has been described using limited embodiments and drawings. However, the present invention is not limited thereto, and it goes without saying that various modifications and variations can be made by a person having ordinary knowledge in the technical field to which the present invention belongs within the technical spirit of the present invention and the equivalent scope of the claims described below.

[0085] [Example] As shown in Figure 2, the negative electrode, positive electrode, and two separators between them were stacked, and the electrode assembly was wound up in the same arrangement as in Figure 8b) before operation to produce a jelly roll (J / R) with a cross-sectional diameter of 20.5 mm. In this case, the thickness of the positive electrode current collector was about 0.015 mm, and the total thickness of the positive electrode holder in which the positive electrode active material layer was provided on both sides of the positive electrode current collector was about 0.150 mm. In addition, the thickness of the negative electrode current collector was about 0.008 mm, and the total thickness of the negative electrode holder in which the negative electrode active material layer was provided on both sides of the negative electrode current collector was about 0.180 mm.

[0086] "Before operation" in Figure 8 is a CT image showing the initial arrangement, in which the separation membrane is not visible, the relatively thick line is the positive electrode, and the thin line is the negative electrode. In this case, the negative electrode holder and the positive electrode holder are of the same or similar thickness, but the carbon-based active material of the negative electrode holder transmits light, so the negative electrode active material layer cannot be seen in the CT image, and only the negative electrode current collector is visible, making it appear relatively thin in the CT image.

[0087] The jelly roll assembly was inserted into a cylindrical can (cross-sectional diameter: 21 mm), and then a carbonate-based electrolyte was injected into the can and the can was sealed to complete the battery of the embodiment.

[0088] [Comparative Example] The same negative and positive electrodes as in the example were laminated with two separators between them, but the electrode assembly was wound up in the same arrangement as before operation in Fig. 8a) to produce a jelly roll (J / R) with a cross-sectional diameter of 20.5 mm. Then, it was placed in a case as in the example and electrolyte was injected to complete the battery.

[0089] In the jelly roll, the position of the positive electrode winding start was adjusted based on the laminate of the comparative example so that the arrangement was the same as that before operation in FIG. 8b), that is, the position of the positive electrode winding start was changed to be closer to the negative electrode tab. In this case, the changed position of the positive electrode winding start was determined in consideration of the size of the winding core 10, the target diameter of the wound jelly roll, and the diameter of the battery case. Specifically, as shown in FIG. 7, when the cumulative winding length from the winding start of the negative electrode tab on the winding core side to the winding start of the positive electrode is divided according to the number of windings and expressed as the number of turns, the winding start of the positive electrode was positioned at a position that is 3 / 4 or more and less than 4 / 4 of the winding length of n turns to which the positive electrode winding start belongs.

[0090] [Experimental Example] The batteries of the above examples and comparative examples were charged and discharged once under the following conditions, and then the presence or absence of deformation of the jelly roll was observed.

[0091] <Test Condition> Temperature: 25℃ Charge:4.25V 1C 50mA cut,rest 10min Discharge:1C 2.5V cut,rest 20min

[0092] To check the deformation of the battery after one charge and discharge, CT images were taken using XSCAN-8225 equipment at 225 kV and a frame rate of 3 fps, and the results are shown as "After operation" in Figure 8. Specifically, Figure 8a is a CT image of the comparative example, and Figure 8b is a CT image of the example.

[0093] As shown in FIG. 9, the degree of deformation of the negative electrode on the winding core side near the start of winding the positive electrode can be confirmed based on the deformation angle relative to the reference line, and the deformation degree was measured and is shown in Table 1 below.

[0094] [Table 1]

[0095] As can be seen from FIG. 8, in the battery of the comparative example, deformation occurs on the winding core side due to expansion of the electrodes during charging and discharging, but in the example in which the negative electrode tab is positioned on the back side in the winding direction of the positive electrode rather than the starting point of the positive electrode winding, it can be seen that movement is suppressed and deformation that can cause an internal short circuit is reduced by 53% ((33.9-15.9) x 100 / 33.9).

Claims

1. An electrode assembly in which a positive electrode, a negative electrode, and a separator provided between the positive electrode and the negative electrode are laminated and wound, the negative electrode includes a negative electrode current collector and a negative electrode active material layer provided on at least one surface of the negative electrode current collector, the negative electrode includes a negative electrode uncoated portion on which the negative electrode active material layer is not provided, at one end of the negative electrode current collector on a core portion side, and a negative electrode tab is provided on the negative electrode uncoated portion, On the winding core side of the electrode assembly, the separator and the negative electrode extend beyond the longitudinal end of the positive electrode and are further wound up, an electrode assembly, wherein the winding core of the electrode assembly is the center of a circle, and in any circle having a radius equal to the distance from the center of the circle to a longitudinal end of the positive electrode, a central angle of a minor arc formed from a contact point where a line extending from a winding start portion of the negative electrode tab to a point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle, to the longitudinal end of the positive electrode, is greater than 0° and less than 90°.

2. the positive electrode includes a positive electrode current collector and a positive electrode active material layer provided on at least one surface of the positive electrode current collector, the positive electrode includes a positive electrode uncoated portion on which the positive electrode active material layer is not provided, and a positive electrode tab is provided on the positive electrode uncoated portion; 2. The electrode assembly according to claim 1, wherein a central angle of an arc formed from a point where a line extending from a winding start portion of the positive electrode tab to an arbitrary point around the arbitrary circle forms a right angle with a tangent to the arbitrary circle, to an end portion in a longitudinal direction of the positive electrode, is greater than 90° and is not greater than 180°.

3. The electrode assembly according to claim 2 , wherein the positive electrode uncoated portion is located between two positive electrode holders on which the positive electrode active material layers are provided.

4. 2. The electrode assembly of claim 1, wherein the negative electrode further comprises an additional negative electrode uncoated portion at an end portion of an outer corner of the negative electrode current collector where the negative electrode active material layer is not provided, and an additional negative electrode tab is provided on the additional negative electrode uncoated portion.

5. the positive electrode includes a positive electrode current collector and a positive electrode active material layer provided on both sides of the positive electrode current collector, The electrode assembly according to claim 1 , wherein the positive electrode active material layers provided on both sides of the positive electrode current collector have the same winding start portion.

6. The positive electrode includes a positive electrode active material layer provided on both sides of the positive electrode current collector, The electrode assembly according to claim 3 , wherein the positive electrode active material layers provided on both sides of the positive electrode current collector have the same winding end portion.

7. The electrode assembly according to claim 1 , wherein the negative electrode tab has a length of 2 mm to 5 mm in the winding direction.

8. The separation membrane includes a first separation membrane and a second separation membrane, The electrode assembly of claim 1 , wherein the electrode assembly is formed by sequentially stacking the negative electrode, the first separator, the positive electrode, and the second separator and winding them up.

9. The electrode assembly according to claim 8 , wherein the negative electrode is wound so as to be disposed at the outermost corner.

10. A secondary battery comprising the electrode assembly according to any one of claims 1 to 9 and a battery case for housing the electrode assembly.

11. The secondary battery according to claim 10 , wherein the electrode assembly has a vertical cross section of a core axis that is circular, and the battery case is cylindrical.

12. A battery pack comprising two or more of the secondary batteries according to claim 10.

13. A vehicle comprising the battery pack of claim 12.

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