Compact write and read heads for ultra-high speed data recording in ceramic materials.

The combination of a DMD and picosecond or femtosecond lasers enables rapid and efficient data recording in ceramic materials by forming well-defined recesses, addressing the inefficiencies of existing methods and achieving high data density and speed.

JP2025528725APending Publication Date: 2025-09-02CERAMIC DATA SOLUTIONS GMBH
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Patent Information

Application Number
JP2025503376
Authority / Receiving Office
JP · JP
Patent Type
Applications
Current Assignee / Owner
Filing Date
2022-08-17
Publication Date
2025-09-02

AI Technical Summary

Technical Problem

Existing methods for recording data in ceramic materials are tedious, time-consuming, and inefficient, particularly when aiming for high data density and fast recording speeds, as they rely on slow rotating disk technologies and uncontrolled ablation processes that result in unfavorable hole shapes.

Method used

Utilizing a digital micromirror device (DMD) in conjunction with a scanning device and picosecond or femtosecond lasers to selectively ablate ceramic materials, forming well-defined recesses by configuring laser beam parameters and irradiation time, enabling rapid data recording through controlled ablation.

Benefits of technology

Achieves extremely fast data writing speeds, allowing for data recording rates of at least 10 MB/s to 10 GB/s, with the potential for millions of pixels to be encoded in a few hundred femtoseconds, and significantly increases data density by creating highly defined, reproducible recesses.

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Abstract

The present invention relates to compact write and read heads for ultra-high speed data recording in ceramic materials.
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Description

[Technical Field]

[0001] The present invention relates to a method for recording data in a layer of ceramic material and to a device for recording data in a layer of ceramic material. [Background technology]

[0002] The applicant of the present invention has developed a method for long-term storage of information and a storage medium therefor (see WO 2021 / 028035 and WO 2022 / 002418). According to one aspect of the method for long-term storage of information, information is encoded on a writable plate comprising a ceramic material by using a laser beam to manipulate local areas of the writable plate. In principle, this method can be performed using a laser beam with a fixed focus by mounting the writable plate on an XY positioning system and moving these local areas of the writable plate to the laser focus where the encoding should be performed, but this method is tedious and time-consuming.

[0003] Also, U.S. Patent Nos. 4,069,487 and 4,556,893 disclose laser-recordable recording media that utilize recording layer materials such as metal oxides and metal carbides. However, recording in both cases is based on rotating disk technology, which is disadvantageous due to the slow recording process caused by the need to form pits one after the other along the recording spiral.

[0004] It is therefore an object of the present invention to provide an improved method for recording data in a layer of ceramic material that is suitable for recording large amounts of data in a relatively short amount of time. It is a further object of the present invention to provide an improved device for recording data in a layer of ceramic material that has a compact write head. Summary of the Invention

[0005] This object is achieved by a method according to claim 1 and a device according to claim 31. Preferred embodiments of the invention are set out in the dependent claims.

[0006] The present invention therefore relates to a method for recording data in a layer of ceramic material, according to which a layer of ceramic material is provided, and a plurality of regions of the layer of ceramic material are selectively irradiated with a laser beam using a digital micromirror device (DMD) and at least one scanning device, wherein parameters of the laser beam and irradiation time for each selected region are configured to ablate each of the selected regions to record data in the layer of ceramic material by forming recesses in the layer of ceramic material.

[0007] The combination of a DMD and at least one scanning device allows for extremely fast data writing, as the ablation pattern formed by the DMD can be shifted over the surface of the substrate at extreme speeds.

[0008] The laser beam is preferably generated from a picosecond or femtosecond laser. Using a picosecond or femtosecond laser is highly suitable for creating well-defined recesses. The ablation technique disclosed in U.S. Pat. No. 4,556,893 utilizes a focused, modulated laser diode beam that forms pits or bubbles depending on the laser power. Because the recording layer material is light-absorbing, the layer is locally heated, thereby melting and / or vaporizing. However, these processes are rather uncontrolled and typically result in unfavorable hole shapes. For example, as shown in FIG. 4 of U.S. Pat. No. 4,556,893, a ring of melted and subsequently solidified material can form around the edge of the hole. This is unacceptable when creating extremely small recesses to increase data density, as these recesses must be reproducibly formed to enable reproducible readout techniques.

[0009] The inventors of the present invention conducted multiple experiments using different ablation techniques for ceramic materials. They found that utilizing picosecond or femtosecond lasers allows for the creation of highly defined holes with circular cross-sections and very sharp edges. This is believed to be due to the ablation process initiated by the picosecond or femtosecond laser. The picosecond or femtosecond laser pulse does not heat the ceramic material, but rather interacts with the electrons of the material. It is hypothesized that the picosecond or femtosecond laser pulse interacts with the outer valence electrons responsible for chemical bonds, thus separating them from the atoms, leaving them positively charged. Given the mutual repulsion between atoms whose chemical bonds are broken, the material "explodes" into a small plasma cloud of energetic ions at a speed faster than that seen with thermal release. This phenomenon, known as a Coulomb explosion, is distinct from conventional laser ablation, for example with nanosecond lasers, which heats, melts, and vaporizes the material on the surface, leaving molten material at the edge of the impact area. Coulomb explosion is a physical process that is clearly limited to the area of ​​the laser impact, whereas thermally induced ablation suffers from undefined heat flow within the material. Therefore, Coulomb explosion is ideal for generating a vast number of small recesses, allowing for a dramatic increase in data density compared to known techniques. While good results can be achieved with picosecond lasers, the use of femtosecond lasers is preferred in this regard. Therefore, the laser preferably has a pulse duration of less than 10 ps, ​​more preferably less than 1 ps.

[0010] The fluence of each of the multiple laser beams emitted by the DMD is 100 mJ / cm 2 greater than 250 mJ / cm 2 more preferably 500 mJ / cm 2 Preferably, the fluence of each of the multiple laser beams emitted by the DMD is greater than 5 J / cm. 2 less than 3 J / cm 2 less than 1 J / cm2 It is preferable that it is smaller than

[0011] Preferably, the laser beam passes through a prism or semi-transparent mirror, strikes a digital micromirror device, and then passes through the prism or semi-transparent mirror again before selectively irradiating multiple regions of the ceramic material layer. Using such a prism or semi-transparent mirror is particularly advantageous in that it allows for compact arrangement of various components of the device used for recording. The laser beam preferably passes through a λ / 4 plate positioned between the prism or semi-transparent mirror and the digital micromirror device two more times. Changing the polarization of the laser beam with such a λ / 4 plate allows the laser beam from the laser to be directed through the prism or semi-transparent mirror to the digital micromirror device, and then through the prism or semi-transparent mirror again to selectively irradiate multiple regions of the ceramic material layer.

[0012] In the context of the present invention, the term "recess" relates to a hole, groove or depression in a ceramic material. In other words, a recess forms a volume without the presence of any ceramic material. Said volume is in fluid communication with the atmosphere. In other words, each recess is open to the atmosphere and is not covered or closed.

[0013] Open recesses are preferred for the techniques described in U.S. Patent No. 4,069,487, which utilize a protective layer covering the information recording portion, because the open recesses allow for clean and complete ablation of the material that was in the recess prior to ablation. This is particularly important when forming very small recesses to increase data density, as these recesses must be formed reproducibly to allow for reproducible readout techniques.

[0014] A DMD contains an array or matrix of micromirrors, which allows for selective illumination of predetermined pixels on a ceramic material by adjusting each micromirror in the array or matrix. Thus, a vast number of pixels on a ceramic material can be illuminated simultaneously in a well-controlled manner, which can be easily automated. Depending on the number of micromirrors present in the DMD, millions of selected regions (i.e., pixels) of a layer of ceramic material can be simultaneously manipulated for a period of time sufficient to ablate one selected region to record data. Such digital micromirror devices are readily available and can be easily implemented into recording devices.

[0015] Alternatively, the present invention may utilize a ferroelectric spatial light modulator (SLM) or liquid crystal SLM with a repetition rate of at least 200 Hz, preferably at least 500 Hz, instead of a DMD. A ferroelectric SLM allows for on-off switching at frequencies up to 5 kHz and may therefore replace the DMD of the present invention. Therefore, in all methods and devices described herein, the term "DMD" may be replaced with the term "ferroelectric SLM" or the term "liquid crystal SLM with a repetition rate of at least 200 Hz, preferably at least 500 Hz."

[0016] Preferably, the pixels on the ceramic material, i.e., the predetermined positions where recesses can be formed, are arranged in a regular matrix or array, i.e., a repeating two-dimensional pattern having a lattice or grid-like structure. Particularly preferred matrices or arrays include, for example, square or hexagonal patterns. Such matrices or arrays allow for optimized data densities substantially greater than those of, for example, CDs, DVDs, or Blu-ray discs, because individual pixels or bits are not separated by a track pitch (e.g., 320 nm for Blu-ray discs) that is no more than twice the size of the individual pixels in the bit dimension (e.g., 150 nm for Blu-ray discs). Conventional disc-shaped recording media are also limited in terms of the maximum rotational speed that can be safely achieved during recording or reading. Therefore, the write / read speed achievable by such matrices or arrays is much greater than that possible with spirally arranged pits.

[0017] Preferably, the recesses have a circular cross section. The recesses may extend only partially into the ceramic layer, or may form through-holes within the ceramic layer. In the former case, recesses or holes of different depths may be formed, each corresponding to a predetermined bit of information, as described in WO 2022 / 002418. To this end, the layer of ceramic material may be irradiated with two or more laser pulses, and the micromirrors of the DMD are adjusted between subsequent pulses to achieve areas of the layer of ceramic material that are (i) not irradiated at all, (ii) irradiated once with a single laser pulse, (iii) irradiated twice with two laser pulses, etc.

[0018] Previous experiments by the applicant have shown that a layer of CrN having a thickness of 5 μm can be visually and reliably manipulated by a single femtosecond laser pulse (see WO 2022 / 002418). Therefore, the method of the present invention makes it possible to encode at least thousands to millions of pixels within a few hundred femtoseconds. Therefore, the recording speed of the method of the present invention is limited only by the number of micromirrors of the DMD and the time required to adjust the micromirrors.

[0019] Preferably, the layer of ceramic material is moved laterally or translated during recording, for example by an XY positioning system (with the z axis being perpendicular to the surface of the layer), such as a scanning stage, so that once an array or matrix of pixels has been recorded, an adjacent array or matrix of pixels can be recorded by simply moving the layer of ceramic material to an adjacent area.

[0020] Therefore, the method of the present invention preferably includes the steps of selectively irradiating a laser beam onto a plurality of regions within a first area of ​​a layer of ceramic material using a DMD, where the first area can be covered by the DMD; translating the layer of ceramic material so that a second area different from the first area can be covered by the DMD; and selectively irradiating a plurality of regions within the second area of ​​the layer of ceramic material using the DMD.

[0021] If both the DMD and the XY positioning system are properly controlled, data recording rates of at least 10 MB / s, preferably at least 100 MB / s, preferably at least 1 GB / s, and more preferably at least 10 GB / s can be achieved.

[0022] Preferably, the laser beam (i.e., multiple laser beams emitted from the DMD) is focused onto the layer of ceramic material by a lens (or more complex optical system) with a high numerical aperture, preferably at least 0.5, more preferably at least 0.8. Preferably, immersion optics are used to further increase the numerical aperture. If immersion optics are used, the numerical aperture can be at least 1.0, preferably at least 1.2.

[0023] It is further preferable to utilize a beam shaping device to form a specific beam shape suitable for data recording. For example, a matrix of laser zone plates can be transmitted by the multiple laser beams generated from the DMD. These laser zone plates can be adapted to form, for example, a needle-shaped Bessel beam for each of the multiple laser beams.

[0024] Bessel beams have the advantage of substantially increased depth of focus. While the focal length of a regular Gaussian beam is on the order of the wavelength of the focused light, the focal length achievable with a Bessel beam is at least four times the wavelength of the focused light. At the same time, the width of the focal spot is approximately half that achievable with a Gaussian beam.

[0025] In general, the feature sizes achievable by the method of the present invention (e.g., the diameter of recesses in ceramic materials) vary between 2 / 3λ (air) and 1 / 2λ (immersion) for Gaussian beams and between 1 / 3λ (air) and 1 / 4λ (immersion) for Bessel beams, where λ is the wavelength of the laser light. Therefore, Bessel beam geometries are advantageous in that they can achieve smaller process features and, therefore, greater recording data density. Furthermore, increasing the focal length of a Bessel beam is advantageous in that, for example, deeper recesses can be created. This is particularly relevant when features of different depths are to be created, for example, to encode information by recess depth. Because the focus of a Gaussian beam is conical, increasing the recess depth implies increasing the diameter of the recess at the surface. In contrast, the more cylindrical focus of a Bessel beam allows for the creation of much deeper recesses with a nearly constant diameter.

[0026] Such Bessel beams can also be generated by other beam shaping devices, one particularly preferred example of which is a spatial light modulator, which is particularly versatile as it can be used to shape Bessel beams, enable optical proximity control, and provide phase shift masks.

[0027] Preferably, the layer of ceramic material comprises metal nitrides such as CrN, CrAlN, TiN, TiCN, TiAlN, ZrN, AlN, VN, Si3N4, ThN, HfN, BN, and / or metal carbides such as TiC, CrC, Al4C3, VC, ZrC, HfC, ThC, B4C, SiC, and / or metal oxides such as Al2O3, TiO2, SiO2, ZrO2, ThO2, MgO, Cr2O3, Zr2O3, V2O3, and / or metal borides such as TiB2, ZrB2, CrB2, VB2, SiB6, ThB2, HfB2, WB2, WB4, and / or metal silicides such as TiSi2, ZrSi2, MoSi2, WSi2, PtSi, Mg2Si. Particularly preferred materials are B4C, HfC, Cr2O3, ZrB2, CrB2, SiB6, Si3N4, ThN, CrN, and CrAlN, which provide sufficient hardness and resistance to environmental degradation for long-term preservation of recorded data.

[0028] Instead of utilizing ceramic materials, the present invention can also be practiced using metals. Particularly preferred metals are those with melting points above 1,000°C, such as B, Cr, Co, Cu, Fe, Hf, Ir, Nb, Ni, Mn, Mg, Mo, Os, Pt, Pd, Rh, Si, Ta, Th, Ti, V, W, and Zr. Even more preferred metals are Al, Au, and Ag. Therefore, in all methods and devices described herein, the term "ceramic material" can be replaced with one or a combination of the above metals.

[0029] Preferably, providing the layer of ceramic material includes providing a substrate and coating the substrate with a layer of ceramic material different from the material of the ceramic substrate. Thus, less of the potentially more expensive coating material is required, while structural integrity is achieved using a robust and potentially less expensive substrate. The layer of ceramic material preferably has a thickness of 10 μm or less, more preferably 5 μm or less, more preferably 2 μm or less, more preferably 1 μm or less, even more preferably 100 nm or less, and most preferably 10 nm or less.

[0030] Preferably, the substrate has a thickness of less than 1 mm, preferably less than 250 μm, more preferably less than 200 μm, and most preferably less than 150 μm.

[0031] Furthermore, the use of a substrate can create optical contrast between the substrate (where holes are created in the coating) and the surrounding coating material. Thus, selectively irradiating multiple regions of the layer of ceramic material with a laser beam using a digital micromirror device preferably includes ablating enough material in each of the regions so that recesses extend toward the substrate. Preferably, manipulating the selected areas makes these areas distinguishable from the surrounding material. In some applications, this may involve achieving optical distinction. However, in other instances (especially when the encoded structures are too small), these areas can only be distinguished from the surrounding material by, for example, scanning electron microscopy or by measuring changes in another physical parameter, such as magnetic, dielectric, or conductive properties.

[0032] Preferably, the ceramic substrate comprises an oxide ceramic. More preferably, the ceramic substrate comprises at least 90% by weight, and most preferably at least 95% by weight, of one or a combination of Al2O3, TiO2, SiO2, ZrO2, ThO2, MgO, Cr2O3, Zr2O3, and VO3. These materials are known to be particularly durable under various conditions and / or resistant to environmental degradation. Therefore, these materials are particularly suitable for long-term storage under different conditions. It is particularly preferred that the ceramic substrate comprises one or a combination of sapphire (Al2O3), silica (SiO2), zirconium silicate (Zr(SiO4)), zirconium oxide (ZrO2), boron monoxide (BO), boron trioxide (BO3), sodium oxide (Na2O), potassium oxide (KO), lithium oxide (Li2O), zinc oxide (ZnO), and magnesium oxide (MgO).

[0033] Preferably, the ceramic substrate comprises a non-oxide ceramic, and more preferably, the ceramic substrate comprises at least 90% by weight, and most preferably at least 95% by weight, of one or a combination of metal nitrides such as CrN, CrAlN, TiN, TiCN, TiAlN, ZrN, AlN, VN, Si3N4, ThN, HfN, and BN; metal carbides such as TiC, CrC, Al4C3, VC, ZrC, HfC, ThC, B4C, and SiC; metal borides such as TiB2, ZrB2, CrB2, VB2, SiB6, ThB2, HfB2, WB2, and WB4; and metal silicides such as TiSi2, ZrSi2, MoSi2, WSi2, PtSi, and Mg2Si. These materials are known to be particularly durable under various conditions and / or resistant to environmental degradation. Therefore, these materials are particularly suitable for long-term storage under different conditions. It is particularly preferred that the ceramic substrate comprises one or a combination of BN, CrSi2, SiC, and SiB6.

[0034] Preferably, the ceramic substrate comprises one or a combination of Ni, Cr, Co, Fe, W, Mo, or other metals with a melting point above 1,400°C. Preferably, the ceramic material and metal form a metal matrix composite in which the ceramic material is dispersed in the metal or metal alloy. Preferably, the metal comprises 5-30 wt. % of the ceramic substrate, i.e., the metal matrix composite, preferably 10-20 wt. %. Particularly preferred metal matrix composites are WC / Co-Ni-Mo, BN / Co-Ni-Mo, TiN / Co-Ni-Mo, and / or SiC / Co-Ni-Mo.

[0035] The ceramic material layer is preferably coated directly onto the ceramic substrate, i.e., without any intermediate layer, to achieve a strong bond between the ceramic substrate and the ceramic material layer. The coated ceramic substrate is preferably tempered before and / or after recording to achieve such a strong bond. Tempering can create a sintered interface between the ceramic substrate and the ceramic material layer. The sintered interface can contain at least one element from both the substrate material and the ceramic material, as one or more elements from one of the two adjacent layers can diffuse into the other of the two adjacent layers. The presence of the sintered interface can further strengthen the bond between the ceramic substrate and the ceramic material layer.

[0036] Preferably, tempering the coated ceramic substrate comprises heating the coated ceramic substrate to a temperature in the range of 200°C to 4,000°C, more preferably in the range of 1,000°C to 2,000°C. The tempering process may comprise a heating phase with a temperature increase of at least 10 K / hr, a plateau phase at the peak temperature for at least 1 minute, and a final cooling phase with a temperature decrease of at least 10 K / hr. The tempering process may help harden the ceramic substrate and / or permanently bond the ceramic material to the ceramic substrate.

[0037] Laser ablation of selected areas of the layer of ceramic material exposes the underlying ceramic substrate, which can result in an (optically) distinguishable contrast of the engineered areas relative to the remainder of the layer of ceramic material.

[0038] According to a particularly preferred embodiment of the present invention, the substrate is transparent to the wavelength of the laser beam. Preferably, the substrate has a transmittance of at least 95%, more preferably at least 97%, and most preferably at least 99% for light having the wavelength of the laser beam. The substrate may comprise, for example, a glassy transparent ceramic material or a crystalline ceramic material, such as sapphire (AlO), silica (SiO), zirconium silicate (Zr(SiO)), zirconium oxide (ZrO), boron monoxide (BO), boron trioxide (BO), sodium oxide (NaO), potassium oxide (KO), lithium oxide (LiO), zinc oxide (ZnO), or magnesium oxide (MgO).

[0039] Particularly suitable crystalline ceramic materials are sapphire (Al2O3), silica (SiO2), zirconium silicate (Zr(SiO4)), zirconium oxide (ZrO2), and magnesium oxide (MgO).

[0040] Such transparent materials are particularly suitable because they allow selective illumination of multiple regions of a layer of ceramic material (coated on a substrate) through the transparent substrate. Therefore, debris generated during recording occurs on the surface of the coated substrate opposite the recording optics. This surface can therefore be easily cleaned and / or cooled without affecting the recording optics.

[0041] Due to the high transmittance of the transparent substrate material, the laser light does not interact with the substrate but simply passes through it, e.g. to ablate only the coating. In particular, the substrate material is not substantially heated by the laser beam.

[0042] Preferably, the laser beam (ie, each of the multiple laser beams emitted from the DMD) has a minimum focal diameter of 400 nm or less, more preferably 300 nm or less, even more preferably 200 nm or less, and most preferably 100 nm or less.

[0043] Preferably, the wavelength of the laser beam is less than 700 nm, preferably less than 650 nm, more preferably less than 600 nm, even more preferably less than 500 nm, and most preferably less than 400 nm. Smaller wavelengths allow for the formation of smaller structures, thus enabling greater data density. Furthermore, the energy per photon (action quantum) increases with smaller wavelengths.

[0044] The method preferably includes the steps of selectively irradiating a laser beam onto a plurality of regions of the layer of ceramic material using a DMD, where the plurality of regions are limited within a first area of ​​the layer of ceramic material; shifting the focal point by a first scanning device to a second area of ​​the layer of ceramic material adjacent to the first area of ​​the layer of ceramic material; and selectively irradiating the laser beam onto a plurality of regions of the layer of ceramic material using a digital micromirror device, where the plurality of regions are limited within the second area of ​​the layer of ceramic material.

[0045] Preferably, the steps of shifting the focal point by the first scanning device to a second area of ​​the layer of ceramic material adjacent to the first area of ​​the layer of ceramic material and selectively irradiating a plurality of regions of the layer of ceramic material with the laser beam using the DMD are repeated for further adjacent areas of the layer of ceramic material, which areas are preferably linearly arranged along the first axis.

[0046] Preferably, the method further includes the steps of shifting the focal point by a second scanning device to a third area of ​​the layer of ceramic material adjacent to the line of areas including the first area and the second area of ​​the layer of ceramic material, and selectively irradiating a laser beam onto a plurality of areas of the layer of ceramic material using a digital micromirror device, wherein the plurality of areas are limited within the third area of ​​the layer of ceramic material.

[0047] Again, the steps of shifting the focus by the second scanning device to a third area of ​​the ceramic material layer adjacent to the line of areas including the first and second areas of the ceramic material layer, and selectively irradiating multiple regions of the ceramic material layer with the laser beam using the DMD, can be repeated for further adjacent areas of the ceramic material layer, these areas preferably being linearly arranged along a second axis perpendicular to the first axis.

[0048] Preferably, the method further comprises the step of shifting the layer of ceramic material along a second axis perpendicular to the first axis by a conveying mechanism, the shifting step preferably being performed by an XY stage or continuously by a conveying belt.

[0049] Preferably, the first scanning device is a polygon scanner or an acousto-optical deflector. Preferably, the second scanning device is a galvo scanner.

[0050] The present invention further relates to a device for recording data in a layer of ceramic material, the device comprising: a laser source, a digital micromirror device (DMD) adapted to emit a plurality of laser beams, a prism or semi-transparent mirror disposed between the laser source and the DMD, a substrate holder for mounting a substrate, focusing optics adapted to focus each of the plurality of laser beams emitted by the DMD onto a substrate mounted on the substrate holder, and one or more scanning devices for steering the pattern of the plurality of laser beams emitted by the digital micromirror device onto the substrate.

[0051] The device preferably further comprises collimating optics for collimating the laser light emitted by the laser source onto the DMD.

[0052] Preferably, the device further comprises a λ / 4 plate disposed between the prism or semi-transparent mirror and the DMD.

[0053] The prism or semi-transparent mirror is preferably positioned between the laser source and the DMD such that light emitted from the laser source passes, in order, through the prism or semi-transparent mirror, optionally through the λ / 4 plate, and optionally through the λ / 4 plate and the prism or semi-transparent mirror again before hitting the DMD and selectively irradiating multiple regions of the substrate.

[0054] The fluence of each of the multiple laser beams emitted by the DMD is preferably 100 mJ / cm 2 greater than 400 mJ / cm 2 more preferably 800 mJ / cm 2 greater than 1 J / cm 2 is greater than.

[0055] The laser source preferably comprises a picosecond or femtosecond laser, and preferably has a pulse duration of less than 10 ps, ​​more preferably less than 1 ps.

[0056] All preferred features mentioned above in the context of the method of the invention may be used in the device of the invention as well, and vice versa.

[0057] The fluence of the laser beam is preferably adapted to manipulate the layer of ceramic material sufficiently to record data on or in the layer of ceramic material, and preferably the fluence of the laser beam makes it possible to ablate said ceramic material.

[0058] The focusing optics preferably includes a lens (or more complex optics) with a high numerical aperture, preferably at least 0.5, more preferably at least 0.8. If immersion optics are used, the numerical aperture may be at least 1.0, more preferably at least 1.2.

[0059] The device further comprises a beam shaping device, preferably a matrix of laser zone plates or a spatial light modulator, for example to form the above-mentioned multiple Bessel beams. Such a beam shaping device is preferably arranged before the focusing optics. In this case, preferably a plurality of lenses, preferably Fresnel lenses, are located directly behind the beam shaping device, for example to focus the Bessel beams. The device preferably further comprises a flat-top beam shaper, preferably located in the optical path before the prism or semi-transparent mirror.

[0060] At the substrate, each of the plurality of laser beams is preferably a Bessel beam, and at the substrate, each of the plurality of laser beams preferably has a minimum focal diameter of 400 nm or less, more preferably 300 nm or less, even more preferably 200 nm or less, and most preferably 100 nm or less.

[0061] The substrate holder is preferably mounted on an XY positioning system, such as a scanning stage. The device preferably includes a processor configured to control the DMD and the XY positioning system to sequentially illuminate adjacent areas or pixel arrays of a substrate mounted on the substrate holder.

[0062] This processor (or additional processing unit) is preferably adapted and configured to receive a set of data to be recorded (i.e. analog or digital data such as text, numbers, an array of pixels, a QR code, etc.) and to control the components of the device (in particular the DMD and the XY positioning system, and optionally the beam shaping device) to perform the method of the present invention so as to record the received set of data on or within the layer of ceramic material.

[0063] Preferably, the wavelength of the laser source is less than 700 nm, preferably less than 650 nm, more preferably less than 600 nm, even more preferably less than 500 nm, and most preferably less than 400 nm.

[0064] The device preferably further comprises a reading device configured to image the recorded data. A single write and read head can therefore be used both to encode (write) data in the layer of ceramic material and to decode (read) data encoded on such a data carrier. The use of the above-mentioned prism or semi-transparent mirror allows such a combined write and read head to be designed in a particularly compact form.

[0065] The device preferably further comprises a beam splitter between the prism or semitransparent mirror and the focusing optics to allow the light emitted from the substrate to pass through the reading device. The device preferably further comprises an additional light source (e.g., an LED) adapted to illuminate the substrate through the prism or semitransparent mirror and the DMD during reading / decoding. Preferably, the light source emits linearly polarized light.

[0066] The reading device may comprise a digital camera or other optical detector. Preferably, the reading device comprises a single optical sensor, where each "pixel" on the data carrier is addressed by a DMD, which allows each "pixel" to be illuminated at once. In an alternative reading mode utilizing SIM or SSIM, a specific illumination pattern ("structured illumination") may be generated by the DMD. In that case, the reading device should comprise a digital camera or other multi-pixel detector. In a further reading mode, planar illumination may be achieved by simply setting all micromirrors of the DMD "on." In that case, the reading device should also comprise a digital camera or other multi-pixel detector.

[0067] The device preferably further comprises a processor configured to decode the imaged and recorded data, which may be adapted, for example, to perform SIM and / or SSIM analysis and control the DMD accordingly.

[0068] Preferably, the one or more scanning devices include one or a combination of one or more galvo scanners, one or more polygon scanners, and one or more acousto-optic deflectors, preferably a combination of one galvo scanner and one polygon scanner.

[0069] Preferably, one or more scanning devices are disposed between the DMD and the focusing optics.

[0070] The focusing optics may include a focal reducer and an f-theta objective lens. Using a scanning system in combination with a standard lens results in a spherical focal plane, which may not be desirable. To achieve a flat focal plane, an f-theta objective lens may be used. Preferably, the focal reducer is disposed between the DMD and one or more scanning devices. Preferably, one or more scanning devices are disposed between the focal reducer and the f-theta objective lens.

[0071] The device may further comprise a controller adapted to control the laser source, the one or more scanning devices, and the digital micromirror device to generate several illumination patterns on adjacent areas of the substrate to form respective patterns of recesses.

[0072] Preferred embodiments of the present invention will be further described with reference to the following drawings. [Brief explanation of the drawings]

[0073] [Figure 1] 1 is a schematic diagram of a device for recording data illustrating the principles underlying the present invention; [Figure 2a] FIG. 1 is a diagram illustrating a first recording alternative. [Figure 2b] FIG. 10 is a schematic diagram of a second recording alternative. [Figure 3]1 shows a schematic diagram of a device for recording data according to a preferred embodiment; [Figure 4] FIG. 2 shows a schematic diagram of a device for recording data according to another preferred embodiment; [Figure 5] FIG. 1 shows a schematic diagram of a recording scheme for a large area. [Figure 6] FIG. 2 shows a schematic diagram of a device for recording data according to another preferred embodiment; DETAILED DESCRIPTION OF THE INVENTION

[0074] FIG. 1 shows a schematic diagram of a device for recording data in a layer of ceramic material, illustrating the principles underlying the present invention. The device includes a laser source 2 that emits laser light onto a DMD 3, which includes a plurality of micromirrors 3a arranged in an array. The DMD 3 is adapted to emit, for each micromirror in the "off" state, a plurality of laser beams 4 along either a first direction (i.e., for recording) or a second direction (indicated by reference numeral 9) and to divert the laser beams 9 to a beam dump (not shown). Typically, the device also includes collimating optics (not shown in FIG. 1) for collimating the laser light emitted by the laser source 2 onto the DMD 3. The device also includes a substrate holder 6 for mounting a substrate 6a and focusing optics 8 adapted to focus each of the plurality of laser beams 4 emitted by the DMD onto the substrate 6a mounted on the substrate holder 6. The focusing optics 8 may include, for example, standard microscope optics with a high numerical aperture. The substrate holder 6 is adapted to support, and preferably mount, a substrate 6a and may be mounted on or part of an XY stage.

[0075] As mentioned above, the device preferably includes a beam shaping device, for example, to achieve a Bessel beam. For example, a matrix of laser zone plates 12 can be provided between the DMD 3 and the focusing optics 8 to shape each of the laser beams 4 into a Bessel beam. Each Bessel beam is then focused onto the substrate 6a by an associated lens (e.g., a Fresnel lens). Additional collimating optics can be provided to properly illuminate the matrix of laser zone plates 12. By using such a Bessel beam, a focal length of at least four times the wavelength of the laser light can be achieved. Furthermore, the focal point has a more cylindrical shape than a Gaussian beam.

[0076] In the example shown in FIG. 1, the substrate 6a is provided with a ceramic coating or layer 1 (see FIG. 2a) of a ceramic material that is to be locally ablated by the focused laser beam 4. In FIG. 1, the ceramic coating 1 is provided on the top of the substrate 6a (see also FIG. 2a). Alternatively, the ceramic coating can be provided on the bottom or back surface of the substrate 6a, as shown in FIG. 2b. Since the laser beam 4 must pass through the substrate 6a, the material of the substrate 6a must be transparent to the wavelength of the laser light. Furthermore, in this case, the substrate holder 6 preferably includes a frame 6b that supports only the outer edge of the substrate 6a (the substrate can be fully supported in the case of top ablation, as shown in FIG. 2a). Therefore, the portion of the ceramic coating 1 that is exposed to ablation is unsupported by the free space 6c below it (see FIG. 2b).

[0077] This is a particularly preferred embodiment because the debris generated during ablation is separated from the focusing optics 8 by the substrate 6a. Rather, the material being ablated from the ceramic layer 1 is released into the free space 6c of the sample holder 6, from where it can be extracted or aspirated. The focusing optics 8 is therefore not adversely affected by said debris, and it is much easier to clean the surface of the ceramic coating 1 immediately after or even during recording.

[0078] Preferably, the thickness of the substrate is adapted to the focusing optics of the device being used, for example, the thickness of the substrate should be smaller than the focal length of the focusing optics in order to reach the ceramic coating.

[0079] Moreover, the arrangement shown in FIG. 2b also makes it possible to cool the ceramic coating 1 during ablation, for example by flowing a cooling fluid along the ceramic coating 1. This improves the precision of the ablation process, since heat transfer from the laser focus to the surrounding area can be eliminated. For example, for this purpose, a cross-jet of air (e.g., an air blade) or a liquid such as water or another immersion liquid can be used. Furthermore, the cross-jet can expel debris generated during ablation.

[0080] Such a cross-jet may also be implemented in the arrangement shown in Figure 2a. However, the cross-jet in this embodiment must be designed so as not to interfere with the optics. For example, if immersion optics are used, the immersion liquid may be provided in a cross-flow that is preferably laminar to avoid optical effects due to turbulence in the immersion liquid.

[0081] Because such a cross-jet of air or liquid can generate vibrations that could compromise recording accuracy and complicate the use of a cross-jet for the embodiment shown in Figure 2a, it is preferable to provide a negatively charged mesh or sheet 15 as shown in Figures 2a and 2b. As explained above, the use of a picosecond or femtosecond laser creates a plasma within the ceramic material to be ablated. Simply put, portions of the ceramic material's atomic shell are removed by interaction with the laser pulse. The remaining positively charged atomic cores are then released during a so-called Coulomb explosion. These positively charged atomic cores can then be attracted by the negatively charged mesh or sheet 15. This is particularly advantageous for the embodiment shown in Figure 2a, in which the laser beam 4 can pass through an opening in the mesh or plate. All debris is then collected by the charged mesh or plate, so that it does not adversely affect, for example, the focusing optics 8.

[0082] A preferred embodiment of the device of the present invention is shown in FIG. 3. In particular, the device shown in FIG. 3 includes two scanning devices 7a and 7b. As previously mentioned, these scanning devices 7a and 7b enable the pattern of multiple laser beams emitted by the DMD to be steered over relevant areas of the layer of ceramic material. In the preferred embodiment shown in FIG. 3, a combination of one galvo scanner (7b) and one polygon scanner (7a) is used. The use of two scanners enables scanning along two preferably perpendicular axes, such as the x-axis and the y-axis (see FIG. 5). In this case, scanning can be performed along a first axis, e.g., the y-axis. After completing one row along this first axis (e.g., DMD patterns 1-5 in FIG. 5), scanning can be performed along a second axis, e.g., the x-axis, before scanning a row along the first axis again (e.g., DMD patterns 6-10). As is clear from the scheme shown in FIG. 5, it can be beneficial to utilize a high-speed scanning process for the y-axis, while scanning along the x-axis can be performed at a reduced speed. Therefore, it is preferred to use a polygon scanner (7a) for the first axis and a galvo scanner (7b) for the second axis. Alternatively, an acousto-optic deflector can be used for either or both of these scanning devices.

[0083] Figure 3 illustrates additional preferred features, although not required in the context of the present invention. For example, Figure 3 illustrates collimating optics 5 for collimating the laser light emitted by laser source 2 onto DMD 3, as well as additional optical components such as actuator 10 and polarizer 11.

[0084] Figure 3 further shows an optional flat-top beam shaper 21 disposed between the collimating optics 5 and the DMD 3. More importantly, the preferred embodiment shown in Figure 3 includes a prism 16. The optional prism 16 (which may be replaced by a semi-transparent mirror) is disposed between the laser source 2 and the DMD 3 such that light emitted from the laser source 2 passes, in that order, through the prism 16, the λ / 4 plate 17a, strikes the DMD 3, and passes through the λ / 4 plate 17a and the prism 16 again before selectively irradiating multiple regions of the substrate 6a.

[0085] Linearly polarized light impinging on prism 16 from the upper optical path is reflected to the right, i.e., toward DMD 3. By passing through λ / 4 plate 17a twice, the polarization axis of the laser light is rotated by a total of 90°. Therefore, light impinging on prism 16 from the right optical path, which is again linearly polarized, passes through prism 16.

[0086] To convert linearly polarized light into circularly polarized light, an additional λ / 4 plate 17b can be provided (see FIG. 4), which is particularly suitable for forming Bessel beams in the laser zone plate 12. As mentioned above, Bessel beams allow the formation of well-defined cylindrical recesses. Of course, if the laser zone plate 12 already comprises an optical element 12a for forming circularly polarized light, the presence of the additional λ / 4 plate 17b is not required (see FIG. 3).

[0087] The preferred embodiment shown in FIG. 3 further comprises a reading device 18 configured to image the recorded data. Thus, a single write and read head can be utilized both for encoding (writing) data in the layer of ceramic material and for decoding (reading) data encoded on such a data carrier. Between the prism 16 and the focusing optics 8b, a wavelength-dependent beam splitter 19 reflects the wavelength of the laser light emitted by the laser source 2 and passes the wavelength emitted by the additional light source 20, allowing light emitted from the substrate having a wavelength different from that of the laser source 2 to pass to the reading device 18. The additional light source 20 (e.g., an LED) is adapted to illuminate the substrate through the beam splitter 24 during reading / decoding. By passing twice through the λ / 4 plate 17b, the polarization axis of the laser light emitted from the light source 20 is again rotated by 90°. Thus, the re-linearly polarized light impinging on the beam splitter 24 passes through the beam splitter 24 toward the reading device 18.

[0088] Of course, other arrangements of the optical components of the device shown in FIG. 3 are also possible. For example, the reading device 18 could also be arranged on the fourth face of the prism 16, as shown in FIG. 4, rather than on the optical axis of the focusing optics 8b as shown in FIG. 3. In this case, the beam splitter 19, still shown, is no longer needed and can be replaced by a constantly reflecting mirror. The λ / 4 plates 17a and 17b again ensure that the laser light emitted by the light source 20 is rotated by a total of 180°. Thus, the re-linearly polarized light impinging on the prism 16 is reflected towards the reading device 18. In the embodiment shown in FIG. 4, the mirror 23 should be a wavelength-dependent beam splitter that reflects the wavelength of the laser light emitted by the laser source 2 and passes the wavelength emitted by the further light source 20.

[0089] In the read mode, the DMD 3 can be utilized in a different way to illuminate the data carrier with light emitted by the further light source 20. As mentioned above, the data carrier can be illuminated pixel by pixel using the DMD 3. In this case, only a single detector is required in the read device and the scanning of the image is performed by the DMD 3.

[0090] In an alternative reading mode utilizing SIM or SSIM, a specific illumination pattern ("structured illumination") is generated by the DMD 3. In that case, the reading device 18 should comprise a digital camera or other multi-pixel detector.

[0091] In a further readout mode, planar illumination can be achieved by simply setting all micromirrors of DMD 3 "on." Again, readout device 18 should comprise a digital camera or other multi-pixel detector.

[0092] The focusing optics (8) may optionally include a focal reducer (8a) and an f-theta objective lens (8b), as shown in Figures 3 and 4. Utilizing a scanning system in combination with a standard lens results in a spherical focal plane, which may not be desirable. To achieve a flat focal plane, the f-theta objective lens (8b) may be utilized. Additionally, the focal reducer (8a) may be present to reduce the area of ​​the illumination pattern generated by the DMD 3 to a predetermined area size acceptable to the scanning devices 7a and 7b.

[0093] As mentioned above, the device of the present invention does not require two scanning devices, as shown in Figures 3 and 4. For example, if data is to be recorded on a long, narrow strip of material, such as a roll of thin ceramic material or a roll of substrate with a thin ceramic coating, the slow axis described above can be achieved by a transport mechanism for the long, narrow strip of material. For example, a roll of ceramic material 6a can be unwound and transported along the x-axis for recording, as shown in Figure 6. The fast y-axis can still be scanned by a scanning device 7a, preferably a polygon scanner 7a. However, if a single DMD pattern does not span the entire width of the strip of material, even the transport mechanism can be combined with two scanning devices, as shown in Figure 6. The other optical components described above with respect to Figures 3 and 4 can be similarly used in the context of Figure 6.

Claims

1. 1. A method for recording data in a layer of ceramic material, comprising: providing a layer of ceramic material; selectively irradiating a laser beam onto a plurality of regions of the layer of ceramic material using a digital micromirror device and at least one scanning device; wherein the laser beam and exposure time parameters for each of the selected regions are configured to ablate each of the selected regions to record data in the layer of ceramic material by forming a recess in the layer of ceramic material; The method, wherein the laser beam originates from a picosecond laser or a femtosecond laser, passes sequentially through a prism or a semi-transparent mirror, impinges on the digital micromirror device, and passes through the prism or the semi-transparent mirror again before selectively irradiating a plurality of regions of the layer of ceramic material.

2. 2. The method of claim 1, wherein the laser beam is a Bessel beam, preferably formed by a laser zone plate or a spatial light modulator.

3. The method according to claim 1 or 2, wherein the recess is open to the atmosphere.

4. 4. The method according to claim 1, wherein the laser beam passes through a λ / 4 plate disposed between the prism or semitransparent mirror and the digital micromirror device two more times.

5. The layer of the ceramic material is selected from the group consisting of CrN, CrAlN, TiN, TiCN, TiAlN, ZrN, AlN, VN, Si 3 N 4 , metal nitrides such as ThN, HfN, and BN, TiC, CrC, and Al 4 C 3 , VC, ZrC, HfC, ThC, B 4 Metal carbides such as C and SiC, Al 2 O 3 , TiO 2 , SiO 2 , ZrO 2 , ThO 2 , MgO, Cr 2 O 3 , Zr 2 O 3 , V 2 O 3 Metal oxides such as TiB 2 , ZrB 2 , CrB 2 , V.B. 2 , SiB 6 , ThB 2 , HfB 2 , W.B. 2 , W.B. 4 or metal borides such as TiSi 2 , ZrSi 2 , MoSi 2 , WSi 2 , PtSi, Mg 2 The method of any one of claims 1 to 4, comprising at least one of a metal silicide such as Si.

6. 6. The method of any one of claims 1 to 5, wherein the step of providing a layer of ceramic material comprises providing a ceramic substrate and coating the substrate with the layer of ceramic material different to a material of the ceramic substrate, wherein the layer of ceramic material preferably has a thickness of 10 μm or less, more preferably 5 μm or less, more preferably 2 μm or less, more preferably 1 μm or less, even more preferably 100 nm or less, and most preferably 10 nm or less.

7. The ceramic substrate is at least 90% by weight, preferably at least 95% by weight, of Al 2 O 3 , TiO 2 , SiO 2 , ZrO 2 , ThO 2 , MgO, Cr 2 O 3 , Zr 2 O 3 , V 2 O 3 and / or the ceramic substrate comprises at least 90 wt. %, preferably at least 95 wt. %, of CrN, CrAlN, TiN, TiCN, TiAlN, ZrN, AlN, VN, Si 3 N 4 , metal nitrides such as ThN, HfN, and BN, TiC, CrC, and Al 4 C 3 , VC, ZrC, HfC, ThC, B 4 C, metal carbides such as SiC, TiB 2 , ZrB 2 , CrB 2 , V.B. 2 , SiB 6 , ThB 2 , HfB 2 , W.B. 2 , W.B. 4 and metal borides such as TiSi 2 , ZrSi 2 , MoSi 2 , WSi 2 , PtSi, Mg 2 7. The method of claim 6, comprising one or a combination of metal silicides such as Si.

8. 8. The method according to claim 6 or 7, wherein the ceramic substrate has a thickness of less than 1 mm, preferably less than 500 μm, more preferably less than 200 μm and most preferably less than 100 μm, more preferably less than 50 μm and most preferably less than 10 μm.

9. The method according to any one of claims 6 to 8, wherein the ceramic substrate is transparent to the wavelength of the laser beam.

10. The ceramic substrate comprises a glassy transparent ceramic material or a crystalline ceramic material, and / or the ceramic substrate is made of sapphire (Al 2 O 3 ), silica (SiO 2 ), zirconium silicate (Zr(SiO 4 )), zirconium oxide (ZrO 2 ), boron monoxide (B 2 O), boron trioxide (B 2 O 3 ), sodium oxide (Na 2 O), potassium oxide (K 2 O), lithium oxide (Li 2 10. The method of claim 9, wherein the inorganic filler comprises one or a combination of: zinc oxide (ZnO), zinc oxide (ZnO), magnesium oxide (MgO).

11. 11. The method of claim 9 or 10, wherein selectively irradiating a plurality of regions of the layer of ceramic material with a laser beam using a digital micromirror device comprises irradiating the layer of ceramic material through the transparent substrate.

12. 12. The method of claim 6, wherein using a digital micromirror device to selectively irradiate a plurality of regions of the layer of ceramic material with a laser beam comprises ablating sufficient material in each of the regions such that the recess extends toward the substrate.

13. A method according to any one of claims 6 to 12, wherein the coated substrate is tempered before and / or after recording.

14. The method according to any one of claims 1 to 13, wherein the laser beam is further passed through a flat-top beam shaper before hitting the digital micromirror device.

15. A method according to any one of the preceding claims, wherein the wavelength of the laser beam is smaller than 700 nm, preferably smaller than 650 nm.

16. The method according to any one of claims 1 to 15, wherein the recesses are formed at some of the predetermined locations, and the predetermined locations are arranged in a regular matrix or array.

17. 17. The method of claim 16, wherein the regular matrix or array is a square or hexagonal pattern.

18. The method of any one of claims 1 to 17, wherein the recess has a circular cross section.

19. A method according to any preceding claim, further comprising the step of collecting positively charged debris using a negatively charged mesh or sheet.

20. 20. The method of claim 19, wherein the layer of the ceramic material is disposed between the digital micromirror device and the negatively charged mesh or sheet.

21. The method of claim 19 , wherein the negatively charged mesh or sheet is disposed between the digital micromirror device and the layer of ceramic material.

22. 22. The method of claim 21, wherein the negatively charged mesh or sheet comprises openings that allow the laser beam to pass through.

23. The method comprises: a) selectively irradiating a plurality of regions of the layer of ceramic material with the laser beam using the digital micromirror device, the plurality of regions being confined within a first area of ​​the layer of ceramic material; b) shifting a focal point with a first scanning device to a second area of ​​the layer of ceramic material adjacent to the first area of ​​the layer of ceramic material; c) selectively irradiating a plurality of regions of the layer of ceramic material with the laser beam using the digital micromirror device, the plurality of regions being confined within the second area of ​​the layer of ceramic material; The method of any one of claims 1 to 22, comprising:

24. 24. The method of claim 23, wherein steps b) and c) are repeated for additional adjacent areas of the layer of ceramic material, the areas being linearly disposed along the first axis.

25. The method comprises: d) shifting the focal point by a second scanning device to a third area of ​​the layer of ceramic material adjacent a line of areas including the first area and the second area of ​​the layer of ceramic material; e) selectively irradiating a plurality of regions of the layer of ceramic material with the laser beam using the digital micromirror device, the plurality of regions being confined within the third area of ​​the layer of ceramic material; 25. The method of claim 24, further comprising:

26. 26. The method of claim 25, wherein steps d) and e) are repeated for additional adjacent areas of the layer of ceramic material, the areas being linearly disposed along a second axis perpendicular to the first axis.

27. 25. The method of claim 23 or 24, further comprising shifting the layer of ceramic material along a second axis perpendicular to the first axis by a transport mechanism.

28. 28. The method of claim 27, wherein the shifting step is performed continuously by a conveyor belt.

29. The method according to any one of claims 23 to 28, wherein the first scanning device is a polygon scanner or an acousto-optical deflector.

30. The method of any one of claims 23 to 29, wherein the second scanning device is a galvo scanner.

31. A device for recording data in a layer (1) of ceramic material, comprising: a laser source (2) comprising a picosecond or femtosecond laser; a digital micromirror device (3) adapted to emit a plurality of laser beams (4); a prism (16) or semi-transparent mirror disposed between the laser source (2) and the digital micromirror device (3); a substrate holder (6) for mounting a substrate (6a); a focusing optical system (8) adapted to focus each of the plurality of laser beams (4) emitted by the digital micromirror device (3) onto a substrate (6 a) attached to the substrate holder (6); one or more scanning devices (7a, 7b) for steering the pattern of the plurality of laser beams (4) emitted by the digital micromirror device (3) onto the substrate; A device comprising:

32. 32. The device according to claim 31, wherein the focusing optics (8) comprises a lens having a numerical aperture of at least 0.5, more preferably at least 0.

8.

33. 33. The device according to claim 31 or 32, wherein the device further comprises a beam shaping device, preferably a flat-top beam shaper (21), a matrix of laser zone plates (12), or a spatial light modulator.

34. The device according to any one of claims 31 to 33, further comprising a λ / 4 plate (17a) arranged between the prism (16) or the semitransparent mirror and the digital micromirror device (3).

35. The device of any one of claims 31 to 34, further comprising a processor configured to control the digital micromirror device and, optionally, an XY positioning system to which the substrate holder is mounted.

36. The device of any one of claims 31 to 35, further comprising a collimating optical system (5) for collimating the laser light emitted by the laser source (2) onto the digital micromirror device (3).

37. A device according to any one of claims 31 to 36, further comprising a negatively charged mesh or sheet (15) for collecting positively charged debris.

38. 38. The device of claim 37, wherein the substrate holder (6) is positioned between the focusing optics (8) and the negatively charged mesh or sheet (15).

39. 38. The device of claim 37, wherein the negatively charged mesh or sheet (15) is placed between the focusing optics (8) and the substrate holder (6).

40. The fluence of each of the plurality of laser beams (4) emitted by the digital micromirror device (3) is 100 mJ / cm 2 40. The device of any one of claims 31 to 39, wherein the device is greater than

41. 41. The device of any one of claims 31 to 40, wherein the prism (16) or the semi-transparent mirror is positioned between the laser source (2) and the digital micromirror device (3) such that light emitted from the laser source (2) passes, in order, through the prism (16) or the semi-transparent mirror, strikes the digital micromirror device (3), and passes through the prism (16) or the semi-transparent mirror again before selectively irradiating multiple regions of the substrate.

42. The device according to any one of claims 31 to 41, further comprising a reading device (18) configured to image the recorded data.

43. 43. The device of claim 42, further comprising a beam splitter (19) between the prism (16) or the semi-transparent mirror and the focusing optical system (8) for allowing light emitted from the substrate to pass to the reading device (18).

44. 44. The device according to claim 42 or 43, further comprising a further light source (20) adapted to illuminate the substrate via the prism (16) or the semi-transparent mirror and the digital micromirror device (3) and / or via the beam splitter (19).

45. 44. The device of claim 43, wherein the reading device (18) comprises a single optical sensor.

46. 44. The device of claim 43, wherein the further light source (20) is arranged to illuminate the substrate through a further λ / 4 plate (17b) and through the beam splitter (19).

47. 47. The device according to claim 46, wherein the further λ / 4 plate (17b) and the beam splitter (19) are arranged between the reading device (18) and the focusing optics (8).

48. 45. The device of any one of claims 41 to 44, further comprising a processor configured to decode the imaged recorded data.

49. 49. The device of claim 48, wherein the processor is adapted to perform SIM and / or SSIM analysis.

50. 50. The device according to any one of claims 31 to 49, wherein the one or more scanning devices comprise one or a combination of one or more galvo scanners (7b), one or more polygon scanners (7a) and one or more acousto-optic deflectors, preferably a combination of one galvo scanner and one polygon scanner.

51. The device of any one of claims 31 to 50, wherein the one or more scanning devices are arranged between the DMD (3) and the focusing optics (8).

52. The device according to any one of claims 31 to 50, wherein the focusing optics (8) comprises a focal reducer (8a) and an fθ objective lens (8b).

53. 53. The device of claim 52, wherein the focal reducer (8a) is arranged between the DMD (3) and the one or more scanning devices (7).

54. 54. The device according to claim 52 or 53, wherein the one or more scanning devices (7) are arranged between the focal reducer (8a) and the f-theta objective lens (8b).

55. A device according to any one of claims 31 to 54, further comprising a transport mechanism for transporting the elongated layer of ceramic material.

56. 56. The device of any one of claims 31 to 55, further comprising a controller adapted to control the laser source (2), the one or more scanning devices, the digital micromirror device (3), and optionally the transport mechanism to generate several illumination patterns on adjacent areas of the substrate to form respective patterns of recesses.

57. A method according to any one of claims 1 to 30, utilizing a device according to any one of claims 31 to 54.

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