Pesticide compositions containing a compound containing a 1,2,4-triazole group and a 4-oxothiazole group and another pesticide

Abstract

The present disclosure relates to the field of molecules having pesticidal utility against pests of the phyla Arthropoda, Mollusca, and Nematoda, methods for making such molecules, intermediates used in such methods, and methods of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematocides.

Description

[Technical Field]

[0001] The present disclosure relates to the field of molecules having pesticidal utility against pests of the phyla Arthropoda, Mollusca, and Nematoda, methods for making such molecules, intermediates used in such methods, and methods of using such pesticidal compositions against such pests. These pesticidal compositions may be used, for example, as acaricides, insecticides, miticides, molluscicides, and nematocides.

[0002] Each year, over 40% of all food produced is damaged by insects, plant pathogens, and weeds. This damage occurs despite the application of pesticides and the use of a wide range of non-chemical control methods, such as crop rotation and biological control. If even a small portion of this food could be saved, it could be used to feed over 3 billion undernourished people around the world (Pimental, D., Pest Control in World Agriculture Agricultural Sciences-Vol. II, 2009).

[0003] Plant-parasitic nematodes are among the most prevalent pests, often cited as a silent and costly threat. Estimates of crop losses caused by nematodes range from approximately 9% in developed countries to approximately 15% in developing countries. However, in the United States, a study of various crops in 35 states indicated that nematodes account for as much as 25% of crop losses (Nicol et al., Current Nematode Threats to World Agriculture, Genomic and Molecular Genetics of Plant-Nematode Interactions, p. 21-43, 2011).

[0004] Although gastropods (slugs and snails) are pests of less economic importance than other arthropods or nematodes, it is noted that in some regions, gastropods can significantly reduce yields, seriously affect the quality of harvested products, and even transmit human, animal, and plant diseases. While only a few dozen gastropod species are significant regional pests, only a handful are important pests on a global scale. Specifically, gastropods affect a wide variety of agricultural and horticultural crops, including arable, livestock, and fiber crops; vegetables; shrub and tree fruits; medicinal herbs; and ornamental plants (Speiser, B., Molluscicides, Encyclopedia of Pest Management, Ch. 219, p. 506-508, 2002).

[0005] Termites cause damage to all types of private and public structures, as well as agricultural and forestry resources. In 2005, it was estimated that termite damages worldwide each year exceeded $50 billion in US dollars (Korb, J., Termites, Current Biology, Vol. 17, No. 23, 2007).

[0006] Consequently, for many reasons, including those mentioned above, new pesticide development is currently needed, which is costly (estimated at approximately $286 million USD per pesticide in 2014), time-consuming (an average of approximately 11.3 years per pesticide), and difficult (Phillips McDougall, The Cost of New Agrochemical Product Discovery, Development, and Registration in 1995, 2000, 2005-2008, and 2010-2014. R&D expenditure in 2014 and expectations for 2019, 2016). Summary of the Invention

[0007] The examples provided herein are not exhaustive and should not be construed as limiting. It is understood that substituents must comply with the chemical bonding rules and steric compatibility constraints pertaining to the particular molecule to which they are attached. These definitions are intended to be used solely for the purposes of this disclosure.

[0008] The term "active substance" or "active ingredient" means a pesticide selected from the following group of pesticides - AIGA-1, AIGA-2, or AI-1 or AI-2, each of which is considered an "active substance" or "active ingredient." These common names may be referenced in several places, such as the British Crop Production Council's "Compendium of Pesticide Common Names" at https: / / pesticidecompendium.bcpc.org / . These active ingredients may be used in mixtures with molecules disclosed below for a variety of reasons.

[0009] The term "AIGA-1" refers to abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acinonapyr, afidopiropen, alanycarb, aldicarb, allethrin, α-cypermethrin, aminopyralid, amitraz, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotine, azoxystrobin, bendiocarb, benfuracarb, bensultap, benzoximate, benzpyrimoxane, β-cyfluthrin, β-cypermethrin, bifenazate, bifenthrin, bioallethrin, and bio Resmethrin, bistrifluron, brofuranilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionate, chlorantraniliprole, chlordane, chlorethoxyphos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine, clopyralid, cloquintocet, clothianidin, copper hydroxide, kumafo s, cyanophos, cyantraniliprole, cyclaniliprole, cyclobutrifluram, cycloprothrin, cycloxapride, cyenopyrafen, cyflumetofen, cyfluthrin, cyhalothrin, cyhexatin, cymoxanil, cypermethrin, cyphenothrin, cyprofuranilide, cyromazine, d-cis-trans allethrin, DDVP, deltamethrin, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, dicofol, dicrotophos, difenoconazole, diflobidazin, diflubenzuron, dimethoate, dimethicone Rubinphos, dipropylidaz, dinotefuran, disulfoton, DNOC, d-trans allethrin, emamectin, emamectin benzoate, empenthrin, endosulfan, EPN, esfenvalerate, ethaboxam, ethiofencarb, ethion, ethiprole, ethoprophos, etofenprox, famoxadone, famfur, fenamiphos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, fenmezodithiaz, fenobucarb, fenoxycarb, fenpropathrin, fenpyroximate,Fenthion, fenvalerate, fipronil, flazasulfuron, flonicamid, florasulam, fluacrypyrim, fluazaindolizine, flubendiamide, flucycloxuron, flucythrinate, fludioxonil, fluensulfone, flufenoxuron, flumethrin, flumioxazin, fluopyram, fluoxapiprolin, fluoxastrobin, flupyradifuron, flupirimin, fluroxypyr, fluxamethamide, fluxapyroxad, formetanate, fosthiazate, furathiocarb, gamma-cyhalothrin, glyphosate, Haluxifen, Halfenprox, Halofenozide, Heptenophos, Hexaflumuron, Hexythiazox, Hydramethylnon, Hydroprene, Imazamox, Imazapyr, Imicyafos, Imidacloprid, Imiprothrin, Indazapiroxameth, Indoxacarb, Inpirfluxam, Ipconazole, Isocycloceram, Isofenphos, Isoflucipram, Isoprocarb, Isoxathion, Kadethrin, Kinoprene, λ-Cyhalothrin, Lepimectin, Lufenuron, Malathion, Mancozeb, MCPA, Mecarbam, Mefeno Xam, metaflumizone, metalaxyl, metconazole, methamidophos, methenamine, methidathion, methiocarb, methomyl, methoprene, methoxychlor, methoxyfenozide, metolcarb, metsulfuron, mevinphos, milbemectin, monocrotophos, myclobutanil, naled, nicosulfuron, nitrapyrin, novaluron, noviflumuron, omethoate, oxamyl, oxathiapiprolin, oxazosulfil, oxydemeton methyl, parathion, parathion methyl, penflufen, penthiopyrad, permethrin, fenothrix phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, picarbutrazox, picloram, picoxystrobin, pinoxaden, pirimicarb, pirimiphos-methyl, prallethrin, profenofos, propargite, propetamphos, propiconazole, propoxur, propyzamide, prothioconazole, prothiofos, spiflumetofen, piflubumid, pymetrozine, pyraclofos, pyraclostrobin, pyrethrum, pyridaben, pyridalyl, pyridaphenthion, pyrifluquinazon,Pyrimidifen, pyriproxyfen, pyroxasulfone, quinalphos, resmethrin, rimsulfuron, rotenone, sedaxane, silafluofen, spidoxamat, spinetoram, spinosad, spirobudifen, spirodiclofen, spiromesifen, spiropydione, spirotetramat, sulfuramide, sulfotep, sulfoxaflor, taufluvalinate, tebuconazole, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temephos, terbufos, tetrachlorvinphos, tetradifon, tetramethrin, tetraniliprole, θ-cypermethrin, thiabenda " refers to the following group of preferred mixing partners for forming agricultural multi-function mixtures selected from the group consisting of benzol, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, thiosultap sodium, thiram, thiolantraniliprole, thioxazaphen, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, triflumuron, trimethacarb, vamidothion, XMC, xylylcarb, zeta-cypermethrin, and 2,4-D. For the avoidance of doubt, each of these pesticides is an active ingredient.

[0010] The term "AIGA-2" refers to the following group of preferred mixing partners for forming mixtures that extend the use of pesticide compositions and perform multiple agricultural functions: abamectin, acetamiprid, benzpyrimoxan, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclobutrifluram, dimepropyridaz, fipronil, flonicamid, fluoxapiprolin, flupyradifurone, flupirimine, fluxamethamide, imidacloprid, indoxacarb, isocycloceram, lambda-cyhalothrin, methoxyfenozide, pymetrozine, pyriproxyfen, spidoxamat, spinetoram, spinosad, spiropydione, spirotetramat, sulfoxaflor, thiamethoxam, and triflumezopyrim.

[0011] The molecule named N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide is the active ingredient and, for purposes of this disclosure, is defined as "AI-1." [ka]

[0012] The molecule named N-(3-chloro-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide is the active ingredient and, for purposes of this disclosure, is defined as "AI-2." [ka]

[0013] The term "locus" means a habitat, breeding ground, plant matter, seeds, soil, material, or environment in which a pest is growing, may grow, or may traverse. For example, a locus may be where crops, trees, fruits, grains, forage seeds, vines, turf, and / or ornamental plants grow; where livestock live; the interior or exterior surfaces of buildings (such as where grain is stored); construction materials used in buildings (such as impregnated wood); and the soil surrounding buildings.

[0014] The term "pest" refers to organisms harmful to humans or human concerns (crops, food, livestock, etc.) and belonging to the phyla Arthropoda, Mollusca, or Nematoda. Particular examples are ants, aphids, bedbugs, beetles, silverfish, caterpillars, cockroaches, crickets, earwigs, fleas, flies, grasshoppers, grubs, wasps, killer bees, leafhoppers, lice, locusts, maggots, mealybugs, mites, moths, nematodes, mirid bugs, planthoppers, psyllids, sawflies, scale insects, silverfish, slugs, snails, spiders, springtails, stink bugs, symphytes, termites, thrips, mites, digger wasps, whiteflies, and wireworms.

[0015] Further examples are the following pests: (1) The subphyla Chelicerata, Myriapoda, and Hexapoda. (2) Arachnida, Symphyla, and Insecta. (3) Anoplura. A non-exhaustive list of detailed genera includes, but is not limited to, Haematopinus spp., Hoplopleura spp., Linognathus spp., Pediculus spp., Polyplax spp., Solenopotes spp., and Neohaematopinis spp. A non-exhaustive list of detailed species includes, but is not limited to, horse lice (Haematopinus asini), pig lice (Haematopinus suis), dog lice (Linognathus setosus), sheep lice (Linognathus ovillus), head lice (Pediculus humanus capitis), body lice (Pediculus humanus humanus), and pubic lice (Pthirus pubis). (4) Coleoptera. A non-exhaustive list of detailed genera includes, but is not limited to, Acanthoscelides spp., Agriotes spp., Anthonomus spp., Apion spp., Apogonia spp., Araecerus spp., Aulacophora spp., Bruchus spp., Cerosterna spp., Cerotoma spp., Ceutorhynchus spp., Chaetocnema spp., spp.), Colaspis spp., Ctenicera spp., Curculio spp., Cyclocephala spp., Diabrotica spp., Dinoderus spp., Gnathocerus spp., Hemicoelus spp., Heterobostruchus spp., Hypera spp., Ips spp., Lyctus spp., Megascelis spp. spp.), Meligethes spp., Mezium spp., Niptus spp., Otiorhynchus spp., Pantomorus spp., Phyllophaga spp., Phyllotreta spp., Ptinus spp., Rhizotrogus spp., Rhynchites spp., Rhynchophorus spp., Scolytus spp.spp.), Sphenophorus spp., Sitophilus spp., Tenebrio spp., and Tribolium spp. A detailed, non-exhaustive list of species includes, but is not limited to, Acanthoscelides obtectus, Agrilus planipennis, Ahasverus advena, Alphitobius diaperinus, Anoplophora glabripennis, Anthonomus grandis, Anthrenus verbasci, Anthrenus falvipes, Ataenius spretulus, Atomaria linearis, Attagenus unicolor, Bothynoderes punctiventris, pea weevil (Bruchus pisorum), common bean weevil (Callosobruchus maculatus), chestnut leaf beetle (Carpophilus hemipterus), Cassida vittata, tobacco leaf beetle (Cathartus quadricollis), Cerotoma trifurcata, Ceutorhynchus assimilis, Ceutorhynchus napi, Conoderus scalaris, Conoderus stigmosus, plum curculio (Conotrachelus nenuphar), Cotinis nitida, Asparagus beetle (Crioceris asparagi), Rust-wrapped small flathead beetle (Cryptolestesferrugineus, Cryptolestes pusillus, Cryptolestes turcicus, Cylindrocopturus adspersus, Deporaus marginatus, Dermestes lardarius, Dermestes maculatus, Epilachna varivestis, Euvrilletta peltata, Faustinus cubae, Hylobius pales, and Hylotrupes bajulus, alfalfa weevil (Hypera postica), coffee flea beetle (Hypothenemus hampei), cigarette beetle (Lasioderma serricorne), Colorado potato beetle (Leptinotarsa ​​decemlineata), Limonius canus, Liogenys fuscus, Liogenys suturalis, rice water weevil (Lissorhoptrus oryzophilus), narrow-legged grain beetle (Lophocateres pusillus), American flathead beetle (Lyctus planicollis), Maecolaspis joliveti, Melanotus communis, Meligethes aeneus aeneus, European cockchafer (Melolontha melolontha), red-legged star beetle (Necrobia rufipes), Oberea brevis, Oberea linearis, Taiwan rhinoceros beetle (Oryctes rhinoceros), giant sawtooth beetle (Oryzaephilusmercator, sawtoothed aphid (Oryzaephilus surinamensis), red-necked leaf beetle (Oulema melanopus), rice leaf beetle (Oulema oryzae), Phyllophaga cuyabana, Polycaon stoutti, Japanese beetle (Popillia japonica), large mealybug (Prostephanus truncatus), mealybug (Rhyzopertha dominica), red-legged weevil (Sitona lineatus), granary maize weevil (Sitophilus granarius), rice weevil (Sitophilus oryzae), maize weevil (Sitophilus zeamais), rice beetle (Stegobium These include the red flour beetle (Tenebroides mauritanicus), the red flour beetle (Tribolium castaneum), the broad-banded red flour beetle (Tribolium confusum), the small red flour beetle (Trogoderma granarium), the yellow-spotted red flour beetle (Trogoderma variabile), the spotted beetle (Xestobium rufovillosum), and Zabrus tenebrioides. (5) Dermaptera. A detailed, non-exhaustive list of species includes, but is not limited to, the European earwig (Forficula auricularia). (6) Blattaria. A detailed, non-exhaustive list of species includes, but is not limited to, Blattella germanica, Blattella asahinai, Blatta orientalis, Blatta lateralis, Parcoblatta pennsylvanica, Periplaneta americana, Periplaneta australasiae, Periplaneta brunnea, Periplaneta fuliginosa, Pycnoscelus surinamensis, and Supella longipalpa. (7) Diptera. A non-exhaustive list of detailed genera includes, but is not limited to, Aedes spp., Agromyza spp., Anastrepha spp., Anopheles spp., Bactrocera spp., Ceratitis spp., Chrysops spp., Cochliomyia spp., Contarinia spp., Culex spp., Culicoides spp., Dasineura, Delia spp., Drosophila spp. spp.), Fannia, Hylemya spp., Liriomyza spp., Musca spp., Phorbia spp., Pollenia spp., Psychoda spp., Simulium spp., Tabanus spp., and Tipula spp.A detailed, non-exhaustive list of species includes, but is not limited to, Agromyza frontella, Anastrepha suspensa, Anastrepha ludens, Anastrepha obliqua, Bactrocera cucurbitae, Bactrocera dorsalis, Bactrocera invadens, Bactrocera zonata, Ceratitis capitata, Dasineura brassicae, Delia platura, Fannia canicularis, Fannia scalaris, horse fly (Gasterophilus intestinalis), Gracillia perseae, horn fly (Haematobia irritans), kissing cow fly (Hypoderma lineatum), Liriomyza brassicae, Liriomyza sativa, sheep lice fly (Melophagus ovinus), Musca autumnalis, house fly (Musca domestica), sheep fly (Oestrus ovis), Oscinella frit, Pegomya betae, cheese fly (Piophila casei), carrot rust fly (Psila rosae), European cherry fruit fly (Rhagoletis cerasi), apple fruit fly (Rhagoletis pomonella), blueberry fruit fly (Rhagoletis mendax), wheat gall midge (Sitodiplosis mosellana), and stable fly (Stomoxys calcitrans). (8) Hemiptera. A non-exhaustive list of detailed genera includes, but is not limited to, Adelges spp., Aulacaspis spp., Aphrophora spp., Aphis spp., Bemisia spp., Ceroplastes spp., Chionaspis spp., Chrysomphalus spp., Coccus spp., Empoasca spp., Euschistus spp., Lepidosapheles spp., spp.), Lagynotomus spp., Lygus spp., Macrosiphum spp., Nephotettix spp., Nezara spp., Nilaparvata spp., Philaenus spp., Phytocoris spp., Piezodorus spp., Planococcus spp., Pseudococcus spp., Rhopalosiphum spp. spp., Saissetia spp., Therioaphis spp., Toumeyella spp., Toxoptera spp., Trialeurodes spp., Triatoma spp., and Unaspis spp. A non-exhaustive list of detailed species includes, but is not limited to, Acrosternum hilare, Acyrthosiphon pisum, Aleyrodes proletariat,proletella, Spiralling Whitefly (Aleurodicus dispersus), Woolly Whitefly (Aleurothrixus floccosus), Amrasca biguttula biguttula, Scale insect (Aonidiella aurantii), Black bean aphid (Aphis fabae), Cotton aphid (Aphis gossypii), Soybean aphid (Aphis glycines), Apple aphid (Aphis pomi), Potato aphid (Aulacorthum solani), Bactericera cockerelli, Bagrada hilaris, Silverleaf whitefly (Bemisia argentifolii), Tobacco whitefly (Bemisia tabaci, American longhorn bug (Blissus leucopterus), Boisea trivittata, Brachycorynella asparagi, Brevennia rehi, Radish aphid (Brevicoryne brassicae), Cacopsylla pyri, Cacopsylla pyricola, Calocoris norvegicus, Ruby wax moth (Ceroplastes rubens), Nettite whitefly (Cimex hemipterus), Bed bug (Cimex lectularius), Citrus scale (Coccus pseudomagnoliarum), Dagbertus fasciatus fasciatus, Dichelops furcatus, Russian wheat aphid (Diuraphis noxia), Asian citrus psyllid (Diaphorina citri), plantain aphid (Dysaphis plantaginea), Dysdercus streulosussuturellus, Edessa meditabunda, Green leafhopper (Empoasca vitis), Apple aphid (Eriosoma lanigerum), Erythroneura elegantula, Brown stink bug (Eurygaster maura), Western spotted stink bug (Euschistus conspersus), Neotropical brown stink bug (Euschistus heros), Euschistus servus, Brown marmorated stink bug (Halyomorpha halys), Helopeltis antonii, Peach aphid (Hyalopterus pruni), Helopeltis antonii, Helopeltis teivora theivora, Icerya scale (Icerya purchasi), Idioscopus nitidulus, Jacobiasca formosana, Laodelphax striatellus, Lecanium corni, Leptocorisa oratorius, Leptocorisa varicornis, Lygus hesperus, Maconellicoccus hirsutus, Macrosiphum euphorbiae, Macrosiphum granarium, Macrosiphum rosae rosae), Asian yellow leafhopper (Macrosteles quadrilineatus), Mahanarva frimbiolata, Taiwan spotted stink bug (Megacopta cribraria), wheat aphid (Metopolophium dirhodum), Mictis longicornislongicornis, green peach aphid (Myzus persicae), lettuce aphid (Nasonovia ribisnigri), green rice leafhopper (Nephotettix cincticeps), Neurocolpus longirostris, southern green stink bug (Nezara viridula), brown planthopper (Nilaparvata lugens), papaya mealybug (Paracoccus marginatus), Paratrioza cockerelli, black spotted scale (Parlatoria pergandii), Parlatoria ziziphi, corn planthopper (Peregrinus maidis), grape aphid (Phylloxera vitifoliae), Physokermes piceae piceae, Phytocoris californicus, Phytocoris relativus, Piezodorus guildinii, Planococcus citri, Planococcus ficus, Poecilocapsus lineatus, Psallus vaccinicola, Pseudacysta perseae, Pineapple mealybug, Quadraspidiotus perniciosus, Corn aphid, Rhopalosiphum maidis), wheat neck aphid (Rhopalosiphum padi), olive scale (Saissetia oleae), Scaptocoris castanea, wheat green aphid (Schizaphis graminum), wheat long-horn aphid (Sitobionavenae, Sogatella furcifera, Trialeurodes vaporariorum, Trialeurodes abutiloneus, Unaspis yanonensis, and Zulia entrerriana. (9) Hymenoptera. A non-exhaustive list of detailed genera includes, but is not limited to, Acromyrmex spp., Atta spp., Camponotus spp., Diprion spp., Dolichovespula spp., Formica spp., Monomorium spp., Neodiprion spp., Paratrechina spp., Pheidole spp., Pogonomyrmex spp., Polistes spp., Solenopsis spp. spp.), Technomyrmex spp., Tetramorium spp., Vespula spp., Vespa spp., and Xylocopa spp.A detailed, non-exhaustive list of species includes, but is not limited to, Athalia rosae, Texas leafcutter ant (Atta texana), cherry slug sawfly (Caliroa cerasi), Cimbex americana, Iridomyrmex humilis, Argentine ant (Linepithema humile), African honeybee (Mellifera scutellata), house ant (Monomorium minimum), house ant (Monomorium pharaonis), pine sawfly (Neodiprion sertifer), fire ant (Solenopsis invicta), red fire ant (Solenopsis geminata), Solenopsis molesta, black fire ant (Solenopsis richtery), and northern red fire ant (Solenopsis xyloni), Odorous house ant (Tapinoma sessile), and little fire ant (Wasmannia auropunctata). (10) Isoptera. A non-exhaustive list of detailed genera includes, but is not limited to, Coptotermes spp., Cornitermes spp., Cryptotermes spp., Heterotermes spp., Kalotermes spp., Incisitermes spp., Macrotermes spp., Marginitermes spp., Microcerotermes spp., Procornitermes spp., Reticulitermes spp., Schedorhinotermes spp., and spp.) and Zootermopsis spp.A detailed, non-exhaustive list of species includes, but is not limited to, Coptotermes acinaciformis, Coptotermes curvignathus, Coptotermes frenchi, Coptotermes formosanus, Coptotermes gestroi, Cryptotermes brevis, Heterotermes aureus, Heterotermes tenuis, Incisitermes minor, Incisitermes snyderi, Microtermes obesi, Nasutitermes corniga, These include the Formosan termite (Odontotermes formosanus), Odontotermes obesus, Reticulitermes banyulensis, Reticulitermes grassei, Reticulitermes flavipes, Reticulitermes hageni, Reticulitermes hesperus, Reticulitermes santonensis, Reticulitermes speratus, Reticulitermes tibialis, and Reticulitermes virginicus. (11) Lepidoptera. A non-exhaustive list of detailed genera includes, but is not limited to, Adoxophyes spp., Agrotis spp., Argyrotaenia spp., Cacoecia spp., Caloptilia spp., Chilo spp., Chrysodeixis spp., Colias spp., Crambus spp., Diaphania spp., Diatraea spp., Earias spp., Ephestia spp. spp.), Epimecis spp., Feltia spp., Gortyna spp., Helicoverpa spp., Heliothis spp., Indarbela spp., Lithocolletis spp., Loxagrotis spp., Malacosoma spp., Nemapogon spp., Peridroma spp., Phyllonorycter spp., Pseudaletia spp., Plutella spp. spp., Sesamia spp., Spodoptera spp., Synanthedon spp., and Yponomeuta spp. A non-exhaustive list of detailed species includes, but is not limited to, Achaea janata, Adoxophyes orana, Agrotis ipsilon, Alabama argillacea, Amorbia cuneana, and the like.cuneana, Walnut moth (Amyelois transitella), Anacamptodes defectaria, Peach leaf moth (Anarsia lineatella), Anomis sabulifera, Anticarsia gemmatalis, Archips argyrospila, Archips rosana, Argyrotaenia citrana, Cattail moth (Autographa gamma), Bonagota cranaodes, Ghost skipper (Borbo cinnara), Bucculatrix thurberiella, Capua reticulana reticulana, peach fruit moth (Carposina niponensis), Chlumetia transversa, lotus band moth (Choristoneura rosaceana), rice leafroller (Cnaphalocrocis medinalis), Conopomorpha cramerella, Japanese cephalonica moth (Corcyra cephalonica), large box moth (Cossus cossus), Cydia caryana, plum orchard moth (Cydia funebrana), pear fruit moth (Cydia molesta), pea moth (Cydia nigricana), codling moth (Cydia pomonella), Darna didducta, Diaphania nitidaris nitidalis), Sugarcane borer (Diatraea saccharalis), Southwestern corn borer (Diatraea grandiosella), Missjiao ring moth (Earias insulana), Weed moth (Earias vittella), Ecdytolopha aurantianum (Ecdytolophaaurantianum, corn moth (Elasmopalpus lignosellus), striped moth (Ephestia cautella), brown moth (Ephestia elutella), striped meal moth (Ephestia kuehniella), soybean axillary borer (Epinotia aporema), apple leaf moth (Epiphyas postvittana), banana skipper (Erionota thrax), white spotted fly moth (Estigmene acrea), grape leaf moth (Eupoecilia ambiguella), Euxoa auxiliaris, wax moth (Galleria mellonella), pear fruit moth (Grapholita molesta), white leaf moth (Hedylepta indicata, Helicoverpa armigera, Helicoverpa zea, Heliothis virescens, Hellula undalis, Keiferia lycopersicella, Leucinodes orbonalis, Leucoptera coffeella, Leucoptera malifoliella, Lobesia botrana, Loxagrotis albicosta, Lymantria dispar, Lymantria clerkella, Mahasena corbetti, Mamestra brassicae), tobacco hornworm (Manduca sexta), bean moth (Maruca testulalis), Metisa plana, Mythimna unipuncta, Neoleucinodes elegantaliselegantalis, rice water borer (Nymphula depunctalis), winter geometrid (Operophtera brumata), European corn borer (Ostrinia nubilalis), Oxydia vesulia, Pandemis cerasana, brown borer (Pandemis heparana), African swallowtail butterfly (Papilio demodocus), red cotton moth (Pectinophora gossypiella), false cutworm moth (Peridroma saucia), Perileucoptera coffeella, potato leaf moth (Pthorimaea operculella), citrus moth (Phyllocnistis citrella), Phyllonorycter blancardella, Cabbage white butterfly (Pieris rapae), Plathypena scabra, Platynota idaeusalis, Indian meal moth (Plodia interpunctella), Diamondback moth (Plutella xylostella), Grape borer moth (Polychrosis viteana), Price endocarpa (Prays endocarpa), Price oleae (Prays oleae), Pseudaletia unipuncta, Soybean looper (Pseudoplusia includens), Sunflower looper (Rachiplusia nu), Rice grain borer (Scirpophaga incertulas), Rice armyworm (Sesamia inferens), Sesamia nonagrioides nonagrioides), blue-striped green moth (Setora nitens), cereal moth (Sitotroga cerealella), Japanese bush moth (Sparganothis pilleriana), beet armyworm (Spodoptera exigua), and white armyworm (SpodopteraThese include the bur moth (Thecla basilides), the bur moth (Tineola bisselliella), the nettle looper moth (Trichoplusia ni), the tomato moth (Tuta absoluta), the coffee moth (Zeuzera coffeae), and the coffee moth (Zeuzea pyrina). (12) Order Mallophaga. A non-exhaustive list of detailed genera includes, but is not limited to, Anaticola spp., Bovicola spp., Chelopistes spp., Goniodes spp., Menacanthus spp., and Trichodectes spp. A detailed, non-exhaustive list of species includes, but is not limited to, the cattle louse (Bovicola bovis), the goat louse (Bovicola caprae), the sheep louse (Bovicola ovis), Chelopistes meleagridis, the cockroach louse (Goniodes dissimilis), Goniodes gigas, the chicken louse (Menacanthus stramineus), the chicken louse (Menopon gallinae), and the dog louse (Trichodectes canis). (13) Orthoptera. A non-exhaustive list of detailed genera includes, but is not limited to, Melanoplus spp. and Pterophylla spp. A detailed, non-exhaustive list of species includes, but is not limited to, Acheta domesticus, Anabrus simplex, Gryllotalpa africana, Gryllotalpa australis, Gryllotalpa brachyptera, Gryllotalpa hexadactyla, Locusta migratoria, Microcentrum retinerve, Schistocerca gregaria, and Scudderia furcata. (14) Psocoptera. A detailed, non-exhaustive list of species includes, but is not limited to, Liposcelis decolor, Liposcelis entomophila, Lachesilla quercus, and Trogium pulsatorium. (15) Siphonaptera. A detailed, non-exhaustive list of species includes, but is not limited to, Ceratophyllus gallinae, Ceratophyllus niger, Ctenocephalides canis, Ctenocephalides felis, and Pulex irritans. (16) Thysanoptera: A non-exhaustive list of detailed genera includes, but is not limited to, Caliothrips spp., Frankliniella spp., Scirtothrips spp., and Thrips spp. A detailed, non-exhaustive list of species includes, but is not limited to, Caliothrips phaseoli, Frankliniella bispinosa, Frankliniella fusca, Frankliniella occidentalis, Frankliniella schultzei, Frankliniella tritici, Frankliniella williamsi, Heliothrips haemorrhoidalis, Rhipiphorothrips cruentatus, Scirtothrips citri, and Scirtothrips dorsalis, Taeniothrips rhopalantennalis, Thrips hawaiiensis, Thrips nigropilosus, Thrips orientalis, Thrips palmi, and Thrips tabaci. (17) Thysanura. A non-exhaustive list of detailed genera includes, but is not limited to, Lepisma spp. and Thermobia spp. (18) Acarina. A non-exhaustive list of detailed genera includes, but is not limited to, Acarus spp., Aculops spp., Argus spp., Boophilus spp., Demodex spp., Dermacentor spp., Epitrimerus spp., Eriophyes spp., Ixodes spp., Oligonychus spp., Panonychus spp., Rhizoglyphus spp., and Tetranychus spp.A detailed, non-exhaustive list of species includes, but is not limited to, Acarapis woodi, Acarus siro, Aceria mangiferae, Aculops lycopersici, Aculus pelekassi, Aculus schlechtendali, Amblyomma americanum, Brevipalpus obovatus, Brevipalpus phoenicis, Dermacentor variabilis, Dermatophagoides pteronyssinus, Eotetranychus carpini, and carpini, Liponyssoides sanguineus, Notoedres cati, Oligonychus coffeae, Oligonychus ilicis, Ornithonyssus bacoti, Panonychus citri, Panonychus ulmi, Phyllocoptruta oleivora, Polyphagotarsonemus latus, Rhipicephalus sanguineus, Sarcoptes scabiei, Tegolophus perseaphroae These include Tetranychus urticae, Tyrophagus longior, and Varroa destructor. (19) Araneae. A non-exhaustive list of specific genera includes, but is not limited to, Loxosceles spp., Latrodectus spp., and Atrax spp. A non-exhaustive list of specific species includes, but is not limited to, Loxosceles reclusa, Latrodectus mactans, and Atrax robustus. (20) Symphyla. A detailed, non-exhaustive list of species includes, but is not limited to, Scutigerella immaculata. (21) Order Collembola (subclass Collembola). A detailed, non-exhaustive list of species includes, but is not limited to, Bourletiella hortensis, Onychiurus armatus, Onychiurus fimetarius, and Sminthurus viridis. (22) Nematoda. A non-exhaustive list of detailed genera includes, but is not limited to, Aphelenchoides spp., Belonolaimus spp., Criconemella spp., Ditylenchus spp., Globodera spp., Heterodera spp., Hirschmanniella spp., Hoplolaimus spp., Meloidogyne spp., Pratylenchus spp., and Radopholus spp. A detailed, non-exhaustive list of species includes, but is not limited to, Dirofilaria immitis, Globodera pallida, Heterodera glycines, Heterodera zeae, Meloidogyne incognita, Meloidogyne javanica, Onchocerca volvulus, Pratylenchus penetrans, Radopholus similis, and Rotylenchulus reniformis. (23) Mollusca. A detailed, non-exhaustive list of species includes, but is not limited to, Arion vulgaris, Cornu aspersum, Deroceras reticulatum, Limax flavus, Milax gagates, and Pomacea canaliculata.

[0016] In one embodiment, the pests to be controlled are sap-feeding pests. Sap-feeding pests generally have boring and / or sucking mouthparts and feed on plant sap and internal plant tissues. Examples of sap-feeding pests of particular concern to agriculture include, but are not limited to, aphids, leafhoppers, moths, scale insects, thrips, psyllids, mealybugs, stink bugs, and whiteflies. Specific examples of orders that include sap-feeding pests of concern in agriculture include, but are not limited to, Anoplura and Hemiptera. Specific examples of Hemiptera of concern in agriculture include, but are not limited to, Adelges spp., Aulacaspis spp., Aphrophora spp., Aphis spp., Bemisia spp., Coccus spp., Euschistus spp., Lygus spp., Macrosiphum spp., Nezara spp., and Rhopalosiphum spp.

[0017] In another embodiment, the pests to be controlled are chewing pests. Chewing pests generally have mouthparts that allow them to chew plant tissues, including roots, stems, leaves, buds, and reproductive tissues (including, but not limited to, flowers, fruits, and seeds). Examples of chewing pests of particular concern to agriculture include, but are not limited to, caterpillars, beetles, grasshoppers, and locusts. Specific examples of orders that include chewing pests of concern in agriculture include, but are not limited to, Coleoptera and Lepidoptera. Specific examples of Coleoptera of concern in agriculture include, but are not limited to, Anthonomus spp., Cerotoma spp., Chaetocnema spp., Colaspis spp., Cyclocephala spp., Diabrotica spp., Hypera spp., Phyllophaga spp., Phyllotreta spp., Sphenophorus spp., and Sitophilus spp.

[0018] The phrase "pesticidally effective amount" means the amount of pesticide required to achieve an observable effect on a pest, such as necrosis, killing, retardation, prevention, elimination, destruction, or some other effect that reduces the incidence and / or abundance of the pest in a locus. This effect can occur when the pest population is driven away from the locus, when the pest is unable to function in or around the locus, and / or when the pest is eradicated from or around the locus. Of course, a combination of these effects can also occur. Generally, the pest population, abundance, or both are desirably reduced by more than 50 percent, preferably by more than 90 percent, and most preferably by more than 99 percent. Generally, for agricultural purposes, a pesticidally effective amount is from about 0.0001 grams per hectare to about 5000 grams per hectare, preferably from about 0.0001 grams per hectare to about 500 grams per hectare, and even more preferably from about 0.0001 grams per hectare to about 50 grams per hectare.

[0019] All references mentioned in this specification, including publications, patent applications, and patents, are incorporated by reference herein to the same extent as if each reference was individually and specifically indicated to be incorporated by reference and was set forth in its entirety.

[0020] In the context of this disclosure (particularly in the context of the claims below), use of the terms "a," "an," "the," "at least one," and similar referents should be construed to encompass both the singular and the plural unless otherwise indicated herein or clearly contradicted by context. The use of the term "at least one" when followed by a list of one or more items (e.g., "at least one of A and B") should be construed to mean one item (A or B) selected from the listed items or any combination of two or more of the listed items (A and B), unless otherwise indicated herein or clearly contradicted by context. The terms "comprising," "having," "including," and "containing" should be construed as open-ended terms (i.e., meaning "including, but not limited to") unless otherwise noted. The recitation of ranges of values ​​herein is merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated herein by reference as if it were individually set forth herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. Any examples provided herein, or the use of illustrative language (e.g., "etc."), are intended merely to further clarify the disclosure and do not impose limitations on the scope of the disclosure unless specifically asserted. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of any embodiment herein. In this disclosure, the terms "molecule" and "compound" may be used interchangeably. DETAILED DESCRIPTION OF THE INVENTION

[0021] This document (A) Formula 1 [ka] (In the formula, R 1 is CF3, CHF2, CF2CF3, OCF3, OCF2CF3, SF5, or SO2CF3; R 2 is H, F, or CH3; R 3 is CH3 or OCH3; and R 4 is CH2OCH2CH3, CH2OCH2CF3, or CH2OCH2CH2F) A molecule having a structure according to and (B) A mixed partner: (1) Members of AIGA-1; (2) members of AIGA-2; (3) AI-1; or (4) AI-2 mixed partners A pesticide composition comprising:

[0022] Examples of molecules of Formula 1 are shown in Table 1.

[0023] [Table 1]

[0024] [Table 2]

[0025] [Table 3]

[0026] [Table 4]

[0027] [Table 5]

[0028] The molecules in portion (A) of Formula 1, and specifically molecules F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, and F16, can be prepared by one skilled in the art. See, for example, WO 2021 / 011722 A1, WO 2014 / 160031, and WO 2013 / 009791.

[0029] The pesticide composition can be mixed with active ingredients and other mixing partners to enhance the usefulness of the composition. Such active ingredients can have, for example, acaricidal activity, insecticidal activity, fungicidal activity, nematicidal activity, and other materials, compounds, and compositions that broaden the spectrum of pest control. The procedures for preparing such mixed compositions are known in the art.

[0030] In light of the above, further details are provided below.

[0031] 1d. A pesticide composition comprising: (A) Formula 1 [ka] (In the formula, R 1 is CF3, CHF2, CF2CF3, OCF3, OCF2CF3, SF5, or SO2CF3; R 2 is H, F, or CH3; R 3 is CH3 or OCH3; and R 4 is CH2OCH2CH3, CH2OCH2CF3, or CH2OCH2CH2F) A molecule having a structure according to and (B) A mixed partner: (1) AIGA members; (2) members of AIGA-1; (3) members of AIGA-2; (3) AI-1; or (4) AI-2 mixed partners 1. A pesticide composition comprising:

[0032] 2d. The pesticide composition according to detail 1d, wherein the molecule having a structure according to Formula 1 is F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

[0033] 3d. The composition of detail 2d, wherein the molecule is F1.

[0034] 4d. The composition of detail 2d, wherein the molecule is F2.

[0035] 5d. The composition of detail 2d, wherein the molecule is F3.

[0036] 6d. The composition of detail 2d, wherein the molecule is F4.

[0037] 7d. The composition of detail 2d, wherein the molecule is F5.

[0038] 8d. The composition of detail 2d, wherein the molecule is F6.

[0039] 9d. The composition of detail 2d, wherein the molecule is F7.

[0040] 10d. The composition of detail 2d, wherein the molecule is F8.

[0041] 11d. The composition of detail 2d, wherein the molecule is F9.

[0042] 12d. The composition of detail 2d, wherein the molecule is F10.

[0043] 13d. The composition of detail 2d, wherein the molecule is F11.

[0044] 14d. The composition of detail 2d, wherein the molecule is F12.

[0045] 15d. The composition of detail 2d, wherein the molecule is F13.

[0046] 16d. The composition of detail 2d, wherein the molecule is F14.

[0047] 17d. The composition of detail 2d, wherein the molecule is F15.

[0048] 18d. The composition of detail 2d, wherein the molecule is F16.

[0049] 19d. The composition of detail 2d, wherein the molecule is a stereoisomer of F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

[0050] 20d. The composition according to any one of details 1d to 19d, wherein the mixing partner is one selected from AIGA.

[0051] 21d. A composition according to any one of details 1d to 19d, wherein the mixing partner is one selected from AIGA-1.

[0052] 22d. The composition of any one of details 1d to 21d, wherein the mixing partner is abamectin.

[0053] 23d. A composition according to any one of details 1d to 21d, wherein the mixing partner is acephate.

[0054] 24d. The composition according to any one of details 1d to 21d, wherein the mixing partner is acequinocyl.

[0055] 25d. The composition according to any one of details 1d to 21d, wherein the mixing partner is acetamiprid.

[0056] 26d. A composition according to any one of details 1d to 21d, wherein the mixing partner is acrinathrin.

[0057] 27d. The composition of any one of details 1d to 21d, wherein the mixing partner is acinonapyr.

[0058] 28d. A composition according to any one of details 1d to 21d, wherein the mixing partner is afidopiropen.

[0059] 29d. The composition of any one of details 1d to 21d, wherein the mixing partner is alanycarb.

[0060] 30d. The composition of any one of details 1d to 21d, wherein the mixing partner is aldicarb.

[0061] 31d. The composition of any one of details 1d to 21d, wherein the mixing partner is allethrin.

[0062] 32d. A composition according to any one of details 1d to 21d, wherein the mixing partner is alpha-cypermethrin.

[0063] 33d. The composition according to any one of details 1d to 21d, wherein the mixing partner is aminopyralid.

[0064] 34d. The composition according to any one of details 1d to 21d, wherein the mixing partner is amitraz.

[0065] 35d. The composition of any one of details 1d to 21d, wherein the mixing partner is azadirachtin.

[0066] 36d. The composition of any one of details 1d to 21d, wherein the mixing partner is azamethiphos.

[0067] 37d. The composition of any one of details 1d to 21d, wherein the mixing partner is azinphos-ethyl.

[0068] 38d. The composition of any one of details 1d to 21d, wherein the mixing partner is azinphosmethyl.

[0069] 39d. The composition according to any one of details 1d to 21d, wherein the mixing partner is azocyclotine.

[0070] 40d. The composition according to any one of details 1d to 21d, wherein the mixing partner is azoxystrobin.

[0071] 41d. A composition according to any one of details 1d to 21d, wherein the mixing partner is bendiocarb.

[0072] 42d. The composition according to any one of details 1d to 21d, wherein the mixing partner is benfuracarb.

[0073] 43d. A composition according to any one of details 1d to 21d, wherein the mixing partner is bensultap.

[0074] 44d. The composition of any one of details 1d to 21d, wherein the mixing partner is a benzoximate.

[0075] 45d. The composition according to any one of details 1d to 21d, wherein the mixing partner is benzpyrimoxane.

[0076] 46d. The composition of any one of details 1d to 21d, wherein the mixing partner is β-cyfluthrin.

[0077] 47d. A composition according to any one of details 1d to 21d, wherein the mixing partner is β-cypermethrin.

[0078] 48d. The composition according to any one of details 1d to 21d, wherein the mixing partner is bifenazate.

[0079] 49d. The composition according to any one of details 1d to 21d, wherein the mixing partner is bifenthrin.

[0080] 50d. The composition according to any one of details 1d to 21d, wherein the mixing partner is bioallethrin.

[0081] 51d. The composition according to any one of details 1d to 21d, wherein the mixing partner is bioresmethrin.

[0082] 52d. A composition according to any one of details 1d to 21d, wherein the mixing partner is bistrifluron.

[0083] 53d. The composition of any one of details 1d to 21d, wherein the mixing partner is broflanilide.

[0084] 54d. The composition of any one of details 1d to 21d, wherein the mixing partner is bromopropylate.

[0085] 55d. The composition of any one of details 1d to 21d, wherein the mixing partner is buprofezin.

[0086] 56d. The composition of any one of details 1d to 21d, wherein the mixing partner is butocarboxim.

[0087] 57d. A composition according to any one of details 1d to 21d, wherein the mixing partner is butoxycarboxim.

[0088] 58d. The composition of any one of details 1d to 21d, wherein the mixing partner is cadusafos.

[0089] 59d. The composition of any one of details 1d to 21d, wherein the mixing partner is carbaryl.

[0090] 60d. The composition of any one of details 1d to 21d, wherein the mixing partner is carbofuran.

[0091] 61d. A composition according to any one of details 1d to 21d, wherein the mixing partner is carbosulfan.

[0092] 62d. The composition according to any one of details 1d to 21d, wherein the mixing partner is carboxin.

[0093] 63d. The composition according to any one of details 1d to 21d, wherein the mixing partner is cartap hydrochloride.

[0094] 64d. The composition according to any one of details 1d to 21d, wherein the mixing partner is quinomethionate.

[0095] 65d. A composition according to any one of details 1d to 21d, wherein the mixing partner is chlorantraniliprole.

[0096] 66d. The composition of any one of details 1d to 21d, wherein the mixing partner is chlordane.

[0097] 67d. The composition according to any one of details 1d to 21d, wherein the mixing partner is chlorethoxyphos.

[0098] 68d. The composition of any one of details 1d to 21d, wherein the mixing partner is chlorfenapyr.

[0099] 69d. The composition according to any one of details 1d to 21d, wherein the mixing partner is chlorfenvinphos.

[0100] 70d. The composition according to any one of details 1d to 21d, wherein the mixing partner is chlorfluazuron.

[0101] 71d. The composition of any one of details 1d to 21d, wherein the mixing partner is chlormephos.

[0102] 72d. The composition according to any one of details 1d to 21d, wherein the mixing partner is chlorpyrifos.

[0103] 73d. The composition according to any one of details 1d to 21d, wherein the mixing partner is chlorpyrifos-methyl.

[0104] 74d. The composition of any one of details 1d to 21d, wherein the mixing partner is chromafenozide.

[0105] 75d. The composition of any one of details 1d to 21d, wherein the mixing partner is clofentezine.

[0106] 76d. The composition of any one of details 1d to 21d, wherein the mixing partner is clopyralid.

[0107] 77d. The composition of any one of details 1d to 21d, wherein the mixing partner is cloquintocet.

[0108] 78d. The composition according to any one of details 1d to 21d, wherein the mixing partner is clothianidin.

[0109] 79d. The composition according to any one of details 1d to 21d, wherein the mixing partner is copper hydroxide.

[0110] 80d. The composition of any one of details 1d to 21d, wherein the mixing partner is coumaphos.

[0111] 81d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyanophos.

[0112] 82d. A composition according to any one of details 1d to 21d, wherein the mixing partner is cyantraniliprole.

[0113] 83d. A composition according to any one of details 1d to 21d, wherein the mixing partner is cyclaniliprole.

[0114] 84d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyclobutrifluram.

[0115] 85d. The composition of any one of details 1d to 21d, wherein the mixing partner is cycloprothrin.

[0116] 86d. The composition of any one of details 1d to 21d, wherein the mixing partner is cycloxapride.

[0117] 87d. A composition according to any one of details 1d to 21d, wherein the mixing partner is cyenopyrafen.

[0118] 88d. The composition according to any one of details 1d to 21d, wherein the mixing partner is cyflumetofen.

[0119] 89d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyfluthrin.

[0120] 90d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyhalothrin.

[0121] 91d. A composition according to any one of details 1d to 21d, wherein the mixing partner is cyhexatin.

[0122] 92d. The composition according to any one of details 1d to 21d, wherein the mixing partner is cymoxanil.

[0123] 93d. A composition according to any one of details 1d to 21d, wherein the mixing partner is cypermethrin.

[0124] 94d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyphenothrin.

[0125] 95d. The composition according to any one of details 1d to 21d, wherein the mixing partner is ciproflanilide.

[0126] 96d. The composition of any one of details 1d to 21d, wherein the mixing partner is cyromazine.

[0127] 97d. A composition according to any one of details 1d to 21d, wherein the mixing partner is d-cis-trans allethrin.

[0128] 98d. The composition of any one of details 1d to 21d, wherein the mixing partner is DDVP.

[0129] 99d. The composition according to any one of details 1d to 21d, wherein the mixing partner is deltamethrin.

[0130] 100d. The composition of any one of details 1d to 21d, wherein the mixing partner is demeton-S-methyl.

[0131] 101d. The composition of any one of details 1d to 21d, wherein the mixing partner is diafenthiuron.

[0132] 102d. The composition of any one of details 1d to 21d, wherein the mixing partner is diazinon.

[0133] 103d. The composition according to any one of details 1d to 21d, wherein the mixing partner is dichlorvos.

[0134] 104d. The composition of any one of details 1d to 21d, wherein the mixing partner is dicofol.

[0135] 105d. The composition according to any one of details 1d to 21d, wherein the mixing partner is dicrotophos.

[0136] 106d. The composition according to any one of details 1d to 21d, wherein the mixing partner is difenoconazole.

[0137] 107d. The composition of any one of details 1d to 21d, wherein the mixing partner is diflovidadin.

[0138] 108d. The composition according to any one of details 1d to 21d, wherein the mixing partner is diflubenzuron.

[0139] 109d. The composition according to any one of details 1d to 21d, wherein the mixing partner is dimethoate.

[0140] 110d. The composition according to any one of details 1d to 21d, wherein the mixing partner is dimethylvinphos.

[0141] 111d. The composition of any one of details 1d to 21d, wherein the mixing partner is dinpropylidaz.

[0142] 112d. The composition of any one of details 1d to 21d, wherein the mixing partner is dinotefuran.

[0143] 113d. The composition of any one of details 1d to 21d, wherein the mixing partner is disulfotone.

[0144] 114d. The composition of any one of details 1d to 21d, wherein the mixing partner is DNOC.

[0145] 115d. The composition of any one of details 1d to 21d, wherein the mixing partner is d-trans allethrin.

[0146] 116d. The composition according to any one of details 1d to 21d, wherein the mixing partner is emamectin.

[0147] 117d. A composition according to any one of details 1d to 21d, wherein the mixing partner is emamectin benzoate.

[0148] 118d. A composition according to any one of details 1d to 21d, wherein the mixing partner is empenthrin.

[0149] 119d. The composition according to any one of details 1d to 21d, wherein the mixing partner is endosulfan.

[0150] 120d. The composition of any one of details 1d to 21d, wherein the mixing partner is EPN.

[0151] 121d. The composition according to any one of details 1d to 21d, wherein the mixing partner is esfenvalerate.

[0152] 122d. The composition of any one of details 1d to 21d, wherein the mixing partner is ethaboxam.

[0153] 123d. The composition according to any one of details 1d to 21d, wherein the mixing partner is ethiofencarb.

[0154] 124d. The composition according to any one of details 1d to 21d, wherein the mixing partner is ethion.

[0155] 125d. A composition according to any one of details 1d to 21d, wherein the mixing partner is ethiprole.

[0156] 126d. The composition of any one of details 1d to 21d, wherein the mixing partner is ethoprophos.

[0157] 127d. The composition according to any one of details 1d to 21d, wherein the mixing partner is etofenprox.

[0158] 128d. The composition of any one of details 1d to 21d, wherein the mixing partner is famoxadone.

[0159] 129d. A composition according to any one of details 1d to 21d, wherein the mixing partner is Famful.

[0160] 130d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenamiphos.

[0161] 131d. A composition according to any one of details 1d to 21d, wherein the mixing partner is fenazaquin.

[0162] 132d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenbuconazole.

[0163] 133d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenbutatin oxide.

[0164] 134d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenitrothion.

[0165] 135d. The composition according to any one of details 1d to 21d, wherein the mixing partner is phenmezodithiaz.

[0166] 136d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenobucarb.

[0167] 137d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenoxycarb.

[0168] 138d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenpropathrin.

[0169] 139d. The composition of any one of details 1d to 21d, wherein the mixing partner is fenpyroximate.

[0170] 140d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fenthion.

[0171] 141d. The composition of any one of details 1d to 21d, wherein the mixing partner is fenvalerate.

[0172] 142d. A composition according to any one of details 1d to 21d, wherein the mixing partner is fipronil.

[0173] 143d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flazasulfuron.

[0174] 144d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flonicamid.

[0175] 145d. The composition according to any one of details 1d to 21d, wherein the mixing partner is florasulam.

[0176] 146d. The composition of any one of details 1d to 21d, wherein the mixing partner is fluacrypyrim.

[0177] 147d. The composition of any one of details 1d to 21d, wherein the mixing partner is fluazaindolizine.

[0178] 148d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flubendiamide.

[0179] 149d. A composition according to any one of details 1d to 21d, wherein the mixing partner is flucycloxuron.

[0180] 150d. The composition of any one of details 1d to 21d, wherein the mixing partner is flucythrinate.

[0181] 151d. The composition of any one of details 1d to 21d, wherein the mixing partner is fludioxonil.

[0182] 152d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fluensulfone.

[0183] 153d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flufenoxuron.

[0184] 154d. A composition according to any one of details 1d to 21d, wherein the mixing partner is flumethrin.

[0185] 155d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flumioxazin.

[0186] 156d. The composition of any one of details 1d to 21d, wherein the mixing partner is fluopyram.

[0187] 157d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fluoxapiproline.

[0188] 158d. The composition of any one of details 1d to 21d, wherein the mixing partner is fluoxastrobin.

[0189] 159d. The composition according to any one of details 1d to 21d, wherein the mixing partner is flupyradifurone.

[0190] 160d. The composition of any one of details 1d to 21d, wherein the mixing partner is flupirimine.

[0191] 161d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fluroxypyr.

[0192] 162d. A composition according to any one of details 1d to 21d, wherein the mixing partner is fluxametamide.

[0193] 163d. The composition according to any one of details 1d to 21d, wherein the mixing partner is fluxapyroxad.

[0194] 164d. The composition according to any one of details 1d to 21d, wherein the mixing partner is formetanate.

[0195] 165d. The composition of any one of details 1d to 21d, wherein the mixing partner is fosthiazate.

[0196] 166d. The composition of any one of details 1d to 21d, wherein the mixing partner is furathiocarb.

[0197] 167d. The composition of any one of details 1d to 21d, wherein the mixing partner is gamma-cyhalothrin.

[0198] 168d. A composition according to any one of details 1d to 21d, wherein the mixing partner is glyphosate.

[0199] 169d. A composition according to any one of details 1d to 21d, wherein the mixing partner is halaxifene.

[0200] 170d. The composition of any one of details 1d to 21d, wherein the mixing partner is Halfenprox.

[0201] 171d. The composition of any one of details 1d to 21d, wherein the mixing partner is halofenozide.

[0202] 172d. The composition of any one of details 1d to 21d, wherein the mixing partner is heptenophos.

[0203] 173d. The composition according to any one of details 1d to 21d, wherein the mixing partner is hexaflumuron.

[0204] 174d. The composition of any one of details 1d to 21d, wherein the mixing partner is hexythiazox.

[0205] 175d. The composition of any one of details 1d to 21d, wherein the mixing partner is hydramethylnon.

[0206] 176d. The composition of any one of details 1d to 21d, wherein the mixing partner is hydroprene.

[0207] 177d. The composition of any one of details 1d to 21d, wherein the mixing partner is imazamox.

[0208] 178d. The composition of any one of details 1d to 21d, wherein the mixing partner is imazapyr.

[0209] 179d. The composition of any one of details 1d to 21d, wherein the mixing partner is imidiaphos.

[0210] 180d. The composition of any one of details 1d to 21d, wherein the mixing partner is imidacloprid.

[0211] 181d. The composition according to any one of details 1d to 21d, wherein the mixing partner is imiprothrin.

[0212] 182d. The composition according to any one of details 1d to 21d, wherein the mixing partner is indazapiroxameth.

[0213] 183d. The composition of any one of details 1d to 21d, wherein the mixing partner is indoxacarb.

[0214] 184d. A composition according to any one of details 1d to 21d, wherein the mixing partner is inpirfluxam.

[0215] 185d. The composition according to any one of details 1d to 21d, wherein the mixing partner is ipconazole.

[0216] 186d. A composition according to any one of details 1d to 21d, wherein the mixing partner is isocycloceram.

[0217] 187d. The composition according to any one of details 1d to 21d, wherein the mixing partner is isofenphos.

[0218] 188d. The composition of any one of details 1d to 21d, wherein the mixing partner is isoflucipram.

[0219] 189d. The composition of any one of details 1d to 21d, wherein the mixing partner is isoprocarb.

[0220] 190d. The composition of any one of details 1d to 21d, wherein the mixing partner is isoxathion.

[0221] 191d. The composition of any one of details 1d to 21d, wherein the mixing partner is cadetrin.

[0222] 192d. The composition of any one of details 1d to 21d, wherein the mixing partner is kinoprene.

[0223] 193d. The composition of any one of details 1d to 21d, wherein the mixing partner is λ-cyhalothrin.

[0224] 194d. The composition according to any one of details 1d to 21d, wherein the mixing partner is lepimectin.

[0225] 195d. The composition according to any one of details 1d to 21d, wherein the mixing partner is lufenuron.

[0226] 196d. The composition of any one of details 1d to 21d, wherein the mixing partner is malathion.

[0227] 197d. A composition according to any one of details 1d to 21d, wherein the mixing partner is mancozeb.

[0228] 198d. The composition of any one of details 1d to 21d, wherein the mixing partner is MCPA.

[0229] 199d. The composition of any one of details 1d to 21d, wherein the mixing partner is mecarbam.

[0230] 200d. The composition of any one of details 1d to 21d, wherein the mixing partner is mefenoxam.

[0231] 201d. The composition of any one of details 1d to 21d, wherein the mixing partner is metaflumizone.

[0232] 202d. The composition of any one of details 1d to 21d, wherein the mixing partner is metalaxyl.

[0233] 203d. The composition according to any one of details 1d to 21d, wherein the mixing partner is metconazole.

[0234] 204d. The composition of any one of details 1d to 21d, wherein the mixing partner is methamidophos.

[0235] 205d. The composition of any one of details 1d to 21d, wherein the mixing partner is methenamine.

[0236] 206d. The composition according to any one of details 1d to 21d, wherein the mixing partner is methidathion.

[0237] 207d. The composition according to any one of details 1d to 21d, wherein the mixing partner is methiocarb.

[0238] 208d. The composition of any one of details 1d to 21d, wherein the mixing partner is methomyl.

[0239] 209d. The composition according to any one of details 1d to 21d, wherein the mixing partner is methoprene.

[0240] 210d. The composition of any one of details 1d to 21d, wherein the mixing partner is methoxychlor.

[0241] 211d. The composition of any one of details 1d to 21d, wherein the mixing partner is methoxyfenozide.

[0242] 212d. The composition according to any one of details 1d to 21d, wherein the mixing partner is metolcarb.

[0243] 213d. The composition of any one of details 1d to 21d, wherein the mixing partner is metsulfuron.

[0244] 214d. The composition of any one of details 1d to 21d, wherein the mixing partner is mevinphos.

[0245] 215d. The composition of any one of details 1d to 21d, wherein the mixing partner is milbemectin.

[0246] 216d. The composition of any one of details 1d to 21d, wherein the mixing partner is monocrotophos.

[0247] 217d. The composition of any one of details 1d to 21d, wherein the mixing partner is myclobutanil.

[0248] 218d. The composition of any one of details 1d to 21d, wherein the mixing partner is naled.

[0249] 219d. The composition of any one of details 1d to 21d, wherein the mixing partner is nicosulfuron.

[0250] 220d. The composition of any one of details 1d to 21d, wherein the mixing partner is nitrapyrin.

[0251] 221d. The composition according to any one of details 1d to 21d, wherein the mixing partner is Novaluron.

[0252] 222d. The composition according to any one of details 1d to 21d, wherein the mixing partner is noviflumuron.

[0253] 223d. A composition according to any one of details 1d to 21d, wherein the mixing partner is omethoate.

[0254] 224d. The composition of any one of details 1d to 21d, wherein the mixing partner is oxamyl.

[0255] 225d. The composition according to any one of details 1d to 21d, wherein the mixing partner is oxathiapiproline.

[0256] 226d. The composition of any one of details 1d to 21d, wherein the mixing partner is oxazosulfil.

[0257] 227d. The composition according to any one of details 1d to 21d, wherein the mixing partner is oxydemeton methyl.

[0258] 228d. A composition according to any one of details 1d to 21d, wherein the mixing partner is parathion.

[0259] 229d. The composition according to any one of details 1d to 21d, wherein the mixing partner is parathion-methyl.

[0260] 230d. A composition according to any one of details 1d to 21d, wherein the mixing partner is penflufen.

[0261] 231d. The composition of any one of details 1d to 21d, wherein the mixing partner is penthiopyrad.

[0262] 232d. The composition according to any one of details 1d to 21d, wherein the mixing partner is permethrin.

[0263] 233d. The composition according to any one of details 1d to 21d, wherein the mixing partner is phenothrin.

[0264] 234d. The composition of any one of details 1d to 21d, wherein the mixing partner is phenthoate.

[0265] 235d. The composition of any one of details 1d to 21d, wherein the mixing partner is phorate.

[0266] 236d. The composition according to any one of details 1d to 21d, wherein the mixing partner is phosalone.

[0267] 237d. The composition according to any one of details 1d to 21d, wherein the mixing partner is phosmet.

[0268] 238d. The composition according to any one of details 1d to 21d, wherein the mixing partner is phosphamidon.

[0269] 239d. A composition according to any one of details 1d to 21d, wherein the mixing partner is phoxim.

[0270] 240d. The composition of any one of details 1d to 21d, wherein the mixing partner is picarbutrazox.

[0271] 241d. The composition according to any one of details 1d to 21d, wherein the mixing partner is picloram.

[0272] 242d. The composition according to any one of details 1d to 21d, wherein the mixing partner is picoxystrobin.

[0273] 243d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pinoxaden.

[0274] 244d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pirimicarb.

[0275] 245d. The composition of any one of details 1d to 21d, wherein the mixing partner is pirimiphosmethyl.

[0276] 246d. The composition of any one of details 1d to 21d, wherein the mixing partner is prallethrin.

[0277] 247d. The composition according to any one of details 1d to 21d, wherein the mixing partner is profenofos.

[0278] 248d. A composition according to any one of details 1d to 21d, wherein the mixing partner is propargite.

[0279] 249d. The composition according to any one of details 1d to 21d, wherein the mixing partner is propetamphos.

[0280] 250d. A composition according to any one of details 1d to 21d, wherein the mixing partner is propiconazole.

[0281] 251d. The composition according to any one of details 1d to 21d, wherein the mixing partner is propoxur.

[0282] 252d. The composition according to any one of details 1d to 21d, wherein the mixing partner is propyzamide.

[0283] 253d. The composition according to any one of details 1d to 21d, wherein the mixing partner is prothioconazole.

[0284] 254d. The composition according to any one of details 1d to 21d, wherein the mixing partner is prothiofos.

[0285] 255d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pydiflumetofen.

[0286] 256d. The composition of any one of details 1d to 21d, wherein the mixing partner is piflubumid.

[0287] 257d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pymetrozine.

[0288] 258d. The composition of any one of details 1d to 21d, wherein the mixing partner is pyraclofos.

[0289] 259d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyraclostrobin.

[0290] 260d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyrethrum.

[0291] 261d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyridaben.

[0292] 262d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyridalyl.

[0293] 263d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyridaphenthion.

[0294] 264d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyrifluquinazone.

[0295] 265d. The composition of any one of details 1d to 21d, wherein the mixing partner is pyrimidifen.

[0296] 266d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyriproxyfen.

[0297] 267d. The composition according to any one of details 1d to 21d, wherein the mixing partner is pyroxasulfone.

[0298] 268d. The composition of any one of details 1d to 21d, wherein the mixing partner is quinalphos.

[0299] 269d. The composition of any one of details 1d to 21d, wherein the mixing partner is resmethrin.

[0300] 270d. The composition of any one of details 1d to 21d, wherein the mixing partner is rimsulfuron.

[0301] 271d. The composition of any one of details 1d to 21d, wherein the mixing partner is rotenone.

[0302] 272d. The composition according to any one of details 1d to 21d, wherein the mixing partner is sedaxane.

[0303] 273d. The composition of any one of details 1d to 21d, wherein the mixing partner is silafluofen.

[0304] 274d. The composition according to any one of details 1d to 21d, wherein the mixing partner is spidoxamat.

[0305] 275d. The composition of any one of details 1d to 21d, wherein the mixing partner is spinetoram.

[0306] 276d. The composition of any one of details 1d to 21d, wherein the mixing partner is spinosad.

[0307] 277d. The composition of any one of details 1d to 21d, wherein the mixing partner is spirobudifen.

[0308] 278d. A composition according to any one of details 1d to 21d, wherein the mixing partner is spirodiclofen.

[0309] 279d. The composition according to any one of details 1d to 21d, wherein the mixing partner is spiromesifen.

[0310] 280d. The composition according to any one of details 1d to 21d, wherein the mixing partner is spiropyridione.

[0311] 281d. The composition of any one of details 1d to 21d, wherein the mixing partner is a spirotetramate.

[0312] 282d. The composition according to any one of details 1d to 21d, wherein the mixing partner is sulfluramide.

[0313] 283d. The composition according to any one of details 1d to 21d, wherein the mixing partner is sulfotep.

[0314] 284d. The composition according to any one of details 1d to 21d, wherein the mixing partner is sulfoxaflor.

[0315] 285d. The composition of any one of details 1d to 21d, wherein the mixing partner is tau fluvalinate.

[0316] 286d. The composition according to any one of details 1d to 21d, wherein the mixing partner is tebuconazole.

[0317] 287d. The composition of any one of details 1d to 21d, wherein the mixing partner is tebufenozide.

[0318] 288d. The composition of any one of details 1d to 21d, wherein the mixing partner is tebufenpyrad.

[0319] 289d. The composition of any one of details 1d to 21d, wherein the mixing partner is tebupirimfos.

[0320] 290d. The composition of any one of details 1d to 21d, wherein the mixing partner is teflubenzuron.

[0321] 291d. The composition of any one of details 1d to 21d, wherein the mixing partner is tefluthrin.

[0322] 292d. The composition of any one of details 1d to 21d, wherein the mixing partner is temephos.

[0323] 293d. The composition of any one of details 1d to 21d, wherein the mixing partner is terbufos.

[0324] 294d. The composition of any one of details 1d to 21d, wherein the mixing partner is tetrachlorvinphos.

[0325] 295d. The composition according to any one of details 1d to 21d, wherein the mixing partner is tetradifon.

[0326] 296d. The composition according to any one of details 1d to 21d, wherein the mixing partner is tetramethrin.

[0327] 297d. A composition according to any one of details 1d to 21d, wherein the mixing partner is tetraniliprole.

[0328] 298d. The composition according to any one of details 1d to 21d, wherein the mixing partner is θ-cypermethrin.

[0329] 299d. A composition according to any one of details 1d to 21d, wherein the mixing partner is thiabendazole.

[0330] 300d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiamethoxam.

[0331] 301d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiocyclam.

[0332] 302d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiodicarb.

[0333] 303d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiofanox.

[0334] 304d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiometone.

[0335] 305d. A composition according to any one of details 1d to 21d, wherein the mixing partner is thiosultap sodium.

[0336] 306d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiram.

[0337] 307d. The composition of any one of details 1d to 21d, wherein the mixing partner is thiolanthraniliprole.

[0338] 308d. The composition of any one of details 1d to 21d, wherein the mixing partner is thioxazaphen.

[0339] 309d. The composition of any one of details 1d to 21d, wherein the mixing partner is tolfenpyrad.

[0340] 310d. The composition according to any one of details 1d to 21d, wherein the mixing partner is tralkoxydim.

[0341] 311d. The composition of any one of details 1d to 21d, wherein the mixing partner is tralomethrin.

[0342] 312d. The composition of any one of details 1d to 21d, wherein the mixing partner is transfluthrin.

[0343] 313d. The composition of any one of details 1d to 21d, wherein the mixing partner is a triazamate.

[0344] 314d. The composition of any one of details 1d to 21d, wherein the mixing partner is triazophos.

[0345] 315d. The composition of any one of details 1d to 21d, wherein the mixing partner is trichlorfon.

[0346] 316d. The composition of any one of details 1d to 21d, wherein the mixing partner is triclopyr.

[0347] 317d. The composition according to any one of details 1d to 21d, wherein the mixing partner is trifloxystrobin.

[0348] 318d. The composition according to any one of details 1d to 21d, wherein the mixing partner is triflumezopyrim.

[0349] 319d. The composition of any one of details 1d to 21d, wherein the mixing partner is triflumuron.

[0350] 320d. The composition of any one of details 1d to 21d, wherein the mixing partner is trimethacarb.

[0351] 321d. The composition according to any one of details 1d to 21d, wherein the mixing partner is vamidothion.

[0352] 322d. The composition of any one of details 1d to 21d, wherein the mixing partner is XMC.

[0353] 323d. The composition according to any one of details 1d to 21d, wherein the mixing partner is xylylcarb.

[0354] 324d. A composition according to any one of details 1d to 21d, wherein the mixing partner is zeta-cypermethrin.

[0355] 325d. The composition of any one of details 1d to 21d, wherein the mixing partner is 2,4-D.

[0356] 326d. The composition of any one of details 1d to 21d, wherein the mixing partner is methallyl picoxamide.

[0357] 327d. The mixing partner is N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide (AI-1). [ka] The composition according to any one of Details 1d to 21d,

[0358] 328d. The mixing partner is N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide (AI-2). [ka] The composition according to any one of Details 1d to 21d,

[0359] 329d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 50,000:1 to about 1:50,000.

[0360] 330d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 40,000:1 to about 1:40,000.

[0361] 331d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 10256:1 to about 1:10256.

[0362] 332d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 10,000:1 to about 1:10,000.

[0363] 333d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 2564:1 to about 1:2564.

[0364] 334d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from 1000:1 to about 1:1000.

[0365] 335d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 640:1 to about 1:640.

[0366] 336d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 500:1 to about 1:500.

[0367] 337d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 100:1 to about 1:100.

[0368] 338d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 50:1 to about 1:50.

[0369] 339d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 20:1 to about 1:20.

[0370] 340d. The composition of any one of Details 1d to 328d, wherein the weight ratio of said molecule to said mixing partner is from about 16:1 to about 1:16.

[0371] 341d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 10:1 to about 1:10.

[0372] 342d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 5:1 to about 1:5.

[0373] 343d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 3:1 to about 1:3.

[0374] 344d. The composition of any one of Details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is from 2:1 to about 1:2.

[0375] 345d. The composition of any one of details 1d to 238d, wherein the weight ratio of said molecule to said mixing partner is 1:1.

[0376] 346d. A method for controlling pests in their habitat by using a pesticide composition according to any one of details 1d to 345d in a pesticidal amount.

[0377] 347d. The method of detail 346d, wherein the pest is of the phylum Arthropoda, Mollusca, and / or Nematoda.

[0378] 348d. The method of detail 346d, wherein the pest is an ant, aphid, bedbug, beetle, silverfish, caterpillar, cockroach, cricket, earwig, flea, flies, grasshopper, grub, wasp, killer bee, leafhopper, lice, locust, maggot, mealybug, mite, moth, nematode, mirid, planthopper, psyllid, sawfly, scale insect, silverfish, slug, snail, spider, springtail, stink bug, symphytes, termite, thrips, tick, digger wasp, whitefly, and / or wireworm.

[0379] 349d. The method of detail 346d, wherein the pest is an aphid, a leafhopper, a moth, a scale insect, a thrip, a psyllid, a mealybug, a stink bug, and / or a whitefly.

[0380] 350d. The method of detail 346d, wherein the pest is a caterpillar, beetle, grasshopper, and / or locust.

[0381] 351d. The composition of detail 3d, wherein the mixing partner is one selected from AIGA.

[0382] 352d. The composition according to detail 3d, wherein the mixing partner is one selected from AIGA-1.

[0383] 353d. The composition of detail 3d, wherein the mixing partner is abamectin.

[0384] 354d. The composition according to detail 3d, wherein the mixing partner is acephate.

[0385] 355d. The composition of detail 3d, wherein the mixing partner is acequinocyl.

[0386] 356d. The composition of detail 3d, wherein the mixing partner is acetamiprid.

[0387] 357d. The composition according to detail 3d, wherein the mixing partner is acrinathrin.

[0388] 358d. The composition of detail 3d, wherein the mixing partner is acinonapyr.

[0389] 359d. The composition according to detail 3d, wherein the mixing partner is afidopiropen.

[0390] 360d. The composition of detail 3d, wherein the mixing partner is alanycarb.

[0391] 361d. The composition of detail 3d, wherein the mixing partner is aldicarb.

[0392] 362d. The composition of detail 3d, wherein the mixing partner is allethrin.

[0393] 363d. The composition of detail 3d, wherein the mixing partner is alpha-cypermethrin.

[0394] 364d. The composition according to detail 3d, wherein the mixing partner is aminopyralid.

[0395] 365d. The composition according to detail 3d, wherein the mixing partner is amitraz.

[0396] 366d. The composition of detail 3d, wherein the mixing partner is azadirachtin.

[0397] 367d. The composition of detail 3d, wherein the mixing partner is azamethiphos.

[0398] 368d. The composition of detail 3d, wherein the mixing partner is azinphos-ethyl.

[0399] 369d. The composition of detail 3d, wherein the mixing partner is azinphosmethyl.

[0400] 370d. The composition of detail 3d, wherein the mixing partner is azocyclotine.

[0401] 371d. The composition of detail 3d, wherein the mixing partner is azoxystrobin.

[0402] 372d. The composition according to detail 3d, wherein the mixing partner is bendiocarb.

[0403] 373d. The composition of detail 3d, wherein the mixing partner is benfuracarb.

[0404] 374d. The composition according to detail 3d, wherein the mixing partner is bensultap.

[0405] 375d. The composition of detail 3d, wherein the mixing partner is benzpyrimoxane.

[0406] 376d. The composition of detail 3d, wherein the mixing partner is β-cyfluthrin.

[0407] 377d. The composition according to detail 3d, wherein the mixing partner is β-cypermethrin.

[0408] 378d. The composition according to detail 3d, wherein the mixing partner is bifenazate.

[0409] 379d. The composition of detail 3d, wherein the mixing partner is bifenthrin.

[0410] 380d. The composition of detail 3d d, wherein the mixing partner is bioallethrin.

[0411] 381d. The composition of detail 3d, wherein the mixing partner is bioresmethrin.

[0412] 382d. The composition according to detail 3d, wherein the mixing partner is bistrifluron.

[0413] 383d. The composition of detail 3d, wherein the mixing partner is broflanilide.

[0414] 384d. The composition of detail 3d, wherein the mixing partner is bromopropylate.

[0415] 385d. The composition of detail 3d, wherein the mixing partner is buprofezin.

[0416] 386d. The composition of detail 3d, wherein the mixing partner is butocarboxim.

[0417] 387d. The composition according to detail 3d, wherein the mixing partner is butoxycarboxim.

[0418] 388d. The composition of detail 3d, wherein the mixing partner is cadusafos.

[0419] 389d. The composition of detail 3d, wherein the mixing partner is carbaryl.

[0420] 390d. The composition of detail 3d, wherein the mixing partner is carbofuran.

[0421] 391d. The composition according to any one of details 1d to 21d, wherein the mixing partner is carbosulfan.

[0422] 392d. The composition of detail 3d, wherein the mixing partner is carboxin.

[0423] 393d. The composition according to detail 3d, wherein the mixing partner is cartap hydrochloride.

[0424] 394d. The composition of detail 3d, wherein the mixing partner is quinomethionate.

[0425] 395d. The composition of detail 3d, wherein the mixing partner is chlorantraniliprole.

[0426] 396d. The composition of detail 3d, wherein the mixing partner is chlordane.

[0427] 398. The composition according to detail 3d, wherein the mixing partner is chlorfenapyr.

[0428] 399d. The composition according to detail 3d, wherein the mixing partner is chlorfenvinphos.

[0429] 400d. The composition of detail 3d, wherein the mixing partner is chlorfluazuron.

[0430] 401d. The composition of detail 3d, wherein the mixing partner is chlormephos.

[0431] 402d. The composition of detail 3d, wherein the mixing partner is chlorpyrifos.

[0432] 403d. The composition of detail 3d, wherein the mixing partner is chlorpyrifos-methyl.

[0433] 404d. The composition of detail 3d, wherein the mixing partner is chromafenozide.

[0434] 405d. The composition of detail 3d, wherein the mixing partner is clopyralid.

[0435] 406d. The composition of detail 3d, wherein the mixing partner is cloquintocet.

[0436] 407d. The composition according to detail 3d, wherein the mixing partner is clothianidin.

[0437] 408d. The composition of detail 3d, wherein the mixing partner is copper hydroxide.

[0438] 409d. The composition of detail 3d, wherein the mixing partner is coumaphos.

[0439] 410d. The composition of detail 3d, wherein the mixing partner is cyanophos.

[0440] 411d. The composition according to detail 3d, wherein the mixing partner is cyantraniliprole.

[0441] 412d. The composition according to detail 3d, wherein the mixing partner is cyclaniliprole.

[0442] 413d. The composition according to detail 3d, wherein the mixing partner is cyclobutrifluram.

[0443] 414d. The composition of detail 3d, wherein the mixing partner is cycloprothrin.

[0444] 415d. The composition according to detail 3d, wherein the mixing partner is cycloxapride.

[0445] 416d. The composition according to detail 3d, wherein the mixing partner is cyenopyrafen.

[0446] 417d. The composition according to detail 3d, wherein the mixing partner is cyflumetofen.

[0447] 418d. The composition of detail 3d, wherein the mixing partner is cyfluthrin.

[0448] 419d. The composition of detail 3d, wherein the mixing partner is cyhalothrin.

[0449] 420d. The composition of detail 3d, wherein the mixing partner is cyhexatin.

[0450] 421d. The composition according to detail 3d, wherein the mixing partner is cymoxanil.

[0451] 422d. The composition according to detail 3d, wherein the mixing partner is cypermethrin.

[0452] 423d. The composition of detail 3d, wherein the mixing partner is cyphenothrin.

[0453] 424d. The composition according to detail 3d, wherein the mixing partner is ciproflanilide.

[0454] 425d. The composition of detail 3d, wherein the mixing partner is cyromazine.

[0455] 426d. The composition of detail 3d, wherein the mixing partner is d-cis-trans allethrin.

[0456] 427d. The composition of detail 3d, wherein the mixing partner is DDVP.

[0457] 428d. The composition according to detail 3d, wherein the mixing partner is deltamethrin.

[0458] 429d. The composition according to detail 3d, wherein the mixing partner is demeton-S-methyl.

[0459] 430d. The composition of detail 3d, wherein the mixing partner is diafenthiuron.

[0460] 431d. The composition according to detail 3d, wherein the mixing partner is diazinon.

[0461] 432d. The composition according to detail 3d, wherein the mixing partner is dichlorvos.

[0462] 433d. The composition according to detail 3d, wherein the mixing partner is dicofol.

[0463] 434d. The composition according to detail 3d, wherein the mixing partner is dicrotophos.

[0464] 435d. The composition according to detail 3d, wherein the mixing partner is difenoconazole.

[0465] 436d. The composition of detail 3d, wherein the mixing partner is diflovidadin.

[0466] 437d. The composition according to detail 3d, wherein the mixing partner is diflubenzuron.

[0467] 438d. The composition according to detail 3d, wherein the mixing partner is dimethoate.

[0468] 439d. The composition according to detail 3d, wherein the mixing partner is dimethylvinphos.

[0469] 440d. The composition of detail 3d, wherein the mixing partner is dinpropylidaz.

[0470] 441d. The composition according to detail 3d, wherein the mixing partner is dinotefuran.

[0471] 442d. The composition according to detail 3d, wherein the mixing partner is disulfoton.

[0472] 443d. The composition of detail 3d, wherein the mixing partner is DNOC.

[0473] 444d. The composition of detail 3d, wherein the mixing partner is d-trans allethrin.

[0474] 445d. The composition according to detail 3d, wherein the mixing partner is emamectin.

[0475] 446d. The composition according to detail 3d, wherein the mixing partner is emamectin benzoate.

[0476] 447d. The composition according to detail 3d, wherein the mixing partner is empenthrin.

[0477] 448d. The composition according to detail 3d, wherein the mixing partner is endosulfan.

[0478] 449d. The composition according to detail 3d, wherein the mixing partner is EPN.

[0479] 450d. The composition of detail 3d, wherein the mixing partner is esfenvalerate.

[0480] 451d. The composition of detail 3d, wherein the mixing partner is ethaboxam.

[0481] 452d. The composition according to detail 3d, wherein the mixing partner is ethiofencarb.

[0482] 453d. The composition according to detail 3d, wherein the mixing partner is ethion.

[0483] 454d. The composition according to detail 3d, wherein the mixing partner is ethiprole.

[0484] 455d. The composition of detail 3d, wherein the mixing partner is ethoprophos.

[0485] 456d. The composition according to detail 3d, wherein the mixing partner is etofenprox.

[0486] 457d. The composition according to detail 3d, wherein the mixing partner is famoxadone.

[0487] 458d. The composition according to detail 3d, wherein the mixing partner is Famful.

[0488] 459d. The composition according to detail 3d, wherein the mixing partner is fenamiphos.

[0489] 460d. The composition according to detail 3d, wherein the mixing partner is fenazaquin.

[0490] 461d. The composition according to detail 3d, wherein the mixing partner is fenbuconazole.

[0491] 462d. The composition according to detail 3d, wherein the mixing partner is fenbutatin oxide.

[0492] 463d. The composition of detail 3d, wherein the mixing partner is fenitrothion.

[0493] 464d. The composition according to detail 3d, wherein the mixing partner is phenmezodithiaz.

[0494] 465d. The composition according to detail 3d, wherein the mixing partner is fenobucarb.

[0495] 466d. The composition according to detail 3d, wherein the mixing partner is fenoxycarb.

[0496] 467d. The composition according to detail 3d, wherein the mixing partner is fenpropathrin.

[0497] 468d. The composition of detail 3d, wherein the mixing partner is fenpyroximate.

[0498] 469d. The composition according to detail 3d, wherein the mixing partner is fenthion.

[0499] 470d. The composition of detail 3d, wherein the mixing partner is fenvalerate.

[0500] 471d. The composition according to detail 3d, wherein the mixing partner is fipronil.

[0501] 472d. The composition according to detail 3d, wherein the mixing partner is flazasulfuron.

[0502] 473d. The composition according to detail 3d, wherein the mixing partner is flonicamid.

[0503] 474d. The composition according to detail 3d, wherein the mixing partner is florasulam.

[0504] 475d. The composition according to detail 3d, wherein the mixing partner is fluacrypyrim.

[0505] 476d. The composition of detail 3d, wherein the mixing partner is fluazaindolizine.

[0506] 477d. The composition according to detail 3d, wherein the mixing partner is flubendiamide.

[0507] 478d. The composition according to detail 3d, wherein the mixing partner is flucycloxuron.

[0508] 479d. The composition according to detail 3d, wherein the mixing partner is flucythrinate.

[0509] 480d. The composition of detail 3d, wherein the mixing partner is fludioxonil.

[0510] 481d. The composition according to detail 3d, wherein the mixing partner is fluensulfone.

[0511] 482d. The composition according to detail 3d, wherein the mixing partner is flufenoxuron.

[0512] 483d. The composition according to detail 3d, wherein the mixing partner is flumethrin.

[0513] 484d. The composition according to detail 3d, wherein the mixing partner is flumioxazin.

[0514] 485d. The composition according to detail 3d, wherein the mixing partner is fluopyram.

[0515] 486d. The composition according to detail 3d, wherein the mixing partner is fluoxapiprolin.

[0516] 487d. The composition according to detail 3d, wherein the mixing partner is fluoxastrobin.

[0517] 488d. The composition of detail 3d, wherein the mixing partner is flupyradifurone.

[0518] 489d. The composition according to detail 3d, wherein the mixing partner is flupirimine.

[0519] 490d. The composition of detail 3d, wherein the mixing partner is fluroxypyr.

[0520] 491d. The composition according to detail 3d, wherein the mixing partner is fluxametamide.

[0521] 492d. The composition according to detail 3d, wherein the mixing partner is fluxapyroxad.

[0522] 493d. The composition according to detail 3d, wherein the mixing partner is formetanate.

[0523] 494d. The composition according to detail 3d, wherein the mixing partner is fosthiazate.

[0524] 495d. The composition according to detail 3d, wherein the mixing partner is furathiocarb.

[0525] 496d. The composition of detail 3d, wherein the mixing partner is gamma-cyhalothrin.

[0526] 497d. The composition described in detail 3d, wherein the mixing partner is glyphosate.

[0527] 498d. The composition according to detail 3d, wherein the mixing partner is halaxifene.

[0528] 499d. The composition according to detail 3d, wherein the mixing partner is Halfenprox.

[0529] 500d. The composition of detail 3d, wherein the mixing partner is halofenozide.

[0530] 501d. The composition of detail 3d, wherein the mixing partner is heptenophos.

[0531] 502d. The composition of detail 3d, wherein the mixing partner is hexaflumuron.

[0532] 503d. The composition of detail 3d, wherein the mixing partner is hexythiazox.

[0533] 504d. The composition of detail 3d, wherein the mixing partner is hydramethylnon.

[0534] 505d. The composition of detail 3d, wherein the mixing partner is hydroprene.

[0535] 506d. The composition of detail 3d, wherein the mixing partner is imazamox.

[0536] 507d. The composition of detail 3d, wherein the mixing partner is imazapyr.

[0537] 508d. The composition of detail 3d, wherein the mixing partner is imidiaphos.

[0538] 509d. The composition of detail 3d, wherein the mixing partner is imidacloprid.

[0539] 510d. The composition of detail 3d, wherein the mixing partner is imiprothrin.

[0540] 511d. The composition according to detail 3d, wherein the mixing partner is indazapiroxameth.

[0541] 512d. The composition of detail 3d, wherein the mixing partner is indoxacarb.

[0542] 513d. The composition according to detail 3d, wherein the mixing partner is inpirfluxam.

[0543] 514d. The composition according to detail 3d, wherein the mixing partner is ipconazole.

[0544] 515d. The composition according to detail 3d, wherein the mixing partner is isocycloceram.

[0545] 516d. The composition according to detail 3d, wherein the mixing partner is isofenphos.

[0546] 517d. The composition of detail 3d, wherein the mixing partner is isoflucipram.

[0547] 518d. The composition according to detail 3d, wherein the mixing partner is isoprocarb.

[0548] 519d. The composition of detail 3d, wherein the mixing partner is isoxathion.

[0549] 520d. The composition of detail 3d, wherein the mixing partner is kadethrin.

[0550] 521d. The composition of detail 3d, wherein the mixing partner is kinoprene.

[0551] 522d. The composition of detail 3d, wherein the mixing partner is λ-cyhalothrin.

[0552] 523d. The composition according to detail 3d, wherein the mixing partner is lepimectin.

[0553] 524d. The composition according to detail 3d, wherein the mixing partner is lufenuron.

[0554] 525d. The composition of detail 3d, wherein the mixing partner is malathion.

[0555] 526d. The composition according to detail 3d, wherein the mixing partner is mancozeb.

[0556] 527d. The composition of detail 3d, wherein the mixing partner is MCPA.

[0557] 528d. The composition of detail 3d, wherein the mixing partner is mecarbam.

[0558] 529d. The composition according to detail 3d, wherein the mixing partner is mefenoxam.

[0559] 530d. The composition according to detail 3d, wherein the mixing partner is metaflumizone.

[0560] 531d. The composition of detail 3d, wherein the mixing partner is metalaxyl.

[0561] 532d. The composition according to detail 3d, wherein the mixing partner is metconazole.

[0562] 533d. The composition according to detail 3d, wherein the mixing partner is methamidophos.

[0563] 534d. The composition of detail 3d, wherein the mixing partner is methenamine.

[0564] 535d. The composition according to detail 3d, wherein the mixing partner is methidathion.

[0565] 536d. The composition according to detail 3d, wherein the mixing partner is methiocarb.

[0566] 537d. The composition according to detail 3d, wherein the mixing partner is methomyl.

[0567] 538d. The composition according to detail 3d, wherein the mixing partner is methoprene.

[0568] 539d. The composition according to detail 3d, wherein the mixing partner is methoxychlor.

[0569] 540d. The composition of detail 3d, wherein the mixing partner is methoxyfenozide.

[0570] 541d. The composition according to detail 3d, wherein the mixing partner is metolcarb.

[0571] 542d. The composition described in detail 3d, wherein the mixing partner is metsulfuron.

[0572] 543d. The composition according to detail 3d, wherein the mixing partner is mevinphos.

[0573] 544d. The composition according to detail 3d, wherein the mixing partner is milbemectin.

[0574] 545d. The composition of detail 3d, wherein the mixing partner is monocrotophos.

[0575] 546d. The composition according to detail 3d, wherein the mixing partner is myclobutanil.

[0576] 547d. The composition according to detail 3d, wherein the mixing partner is naled.

[0577] 548d. The composition of detail 3d, wherein the mixing partner is nicosulfuron.

[0578] 549d. The composition according to detail 3d, wherein the mixing partner is nitrapyrin.

[0579] 550d. The composition according to detail 3d, wherein the mixing partner is Novaluron.

[0580] 551d. The composition of detail 3d, wherein the mixing partner is noviflumuron.

[0581] 552d. The composition according to detail 3d, wherein the mixing partner is omethoate.

[0582] 553d. The composition of detail 3d, wherein the mixing partner is oxamyl.

[0583] 554d. The composition according to detail 3d, wherein the mixing partner is oxathiapiproline.

[0584] 555d. The composition of detail 3d, wherein the mixing partner is oxazosulfil.

[0585] 556d. The composition according to detail 3d, wherein the mixing partner is oxydemeton methyl.

[0586] 557d. The composition according to detail 3d, wherein the mixing partner is parathion.

[0587] 558d. The composition according to detail 3d, wherein the mixing partner is parathion-methyl.

[0588] 559d. The composition according to detail 3d, wherein the mixing partner is penflufen.

[0589] 560d. The composition of detail 3d, wherein the mixing partner is penthiopyrad.

[0590] 561d. The composition according to detail 3d, wherein the mixing partner is permethrin.

[0591] 562d. The composition according to detail 3d, wherein the mixing partner is phenothrin.

[0592] 563d. The composition according to detail 3d, wherein the mixing partner is phenthoate.

[0593] 564d. The composition of detail 3d, wherein the mixing partner is phorate.

[0594] 565d. The composition according to detail 3d, wherein the mixing partner is phosalone.

[0595] 566d. The composition of detail 3d, wherein the mixing partner is phosmet.

[0596] 567d. The composition according to detail 3d, wherein the mixing partner is phosphamidon.

[0597] 568d. The composition according to detail 3d, wherein the mixing partner is phoxim.

[0598] 569d. The composition of detail 3d, wherein the mixing partner is picarbutrazox.

[0599] 570d. The composition of detail 3d, wherein the mixing partner is picloram.

[0600] 571d. The composition according to detail 3d, wherein the mixing partner is picoxystrobin.

[0601] 572d. The composition according to detail 3d, wherein the mixing partner is pinoxaden.

[0602] 573d. The composition according to detail 3d, wherein the mixing partner is pirimicarb.

[0603] 574d. The composition according to detail 3d, wherein the mixing partner is pirimiphosmethyl.

[0604] 575d. The composition of detail 3d, wherein the mixing partner is prallethrin.

[0605] 576d. The composition according to detail 3d, wherein the mixing partner is profenofos.

[0606] 577d. The composition according to detail 3d, wherein the mixing partner is propargite.

[0607] 578d. The composition according to detail 3d, wherein the mixing partner is propetamphos.

[0608] 579d. The composition according to detail 3d, wherein the mixing partner is propiconazole.

[0609] 580d. The composition according to detail 3d, wherein the mixing partner is propoxur.

[0610] 581d. The composition according to detail 3d, wherein the mixing partner is propyzamide.

[0611] 582d. The composition according to detail 3d, wherein the mixing partner is prothioconazole.

[0612] 584d. The composition according to detail 3d, wherein the mixing partner is pydiflumetofen.

[0613] 585d. The composition of detail 3d, wherein the mixing partner is piflubumid.

[0614] 586d. The composition according to detail 3d, wherein the mixing partner is pymetrozine.

[0615] 587d. The composition according to detail 3d, wherein the mixing partner is pyraclofos.

[0616] 588d. The composition according to detail 3d, wherein the mixing partner is pyraclostrobin.

[0617] 589d. The composition according to detail 3d, wherein the mixing partner is pyrethrum.

[0618] 590d. The composition according to detail 3d, wherein the mixing partner is pyridaben.

[0619] 591d. The composition according to detail 3d, wherein the mixing partner is pyridalyl.

[0620] 592d. The composition according to detail 3d, wherein the mixing partner is pyridaphenthion.

[0621] 593d. The composition according to detail 3d, wherein the mixing partner is pyrifluquinazone.

[0622] 594d. The composition according to detail 3d, wherein the mixing partner is pyrimidifen.

[0623] 595d. The composition according to detail 3d, wherein the mixing partner is pyriproxyfen.

[0624] 596d. The composition according to detail 3d, wherein the mixing partner is pyroxasulfone.

[0625] 597d. The composition according to detail 3d, wherein the mixing partner is quinalphos.

[0626] 598d. The composition according to detail 3d, wherein the mixing partner is resmethrin.

[0627] 599d. The composition described in detail 3d, wherein the mixing partner is rimsulfuron.

[0628] 600d. The composition of detail 3d, wherein the mixing partner is rotenone.

[0629] 601d. The composition of detail 3d, wherein the mixing partner is sedaxane.

[0630] 602d. The composition of detail 3d, wherein the mixing partner is silafluofen.

[0631] 603d. The composition of detail 3d, wherein the mixing partner is spidoxamat.

[0632] 604d. The composition of detail 3d, wherein the mixing partner is spinetoram.

[0633] 605d. The composition of detail 3d, wherein the mixing partner is spinosad.

[0634] 606d. The composition of detail 3d, wherein the mixing partner is spirobudifen.

[0635] 607d. The composition of detail 3d, wherein the mixing partner is spirodiclofen.

[0636] 608d. The composition of detail 3d, wherein the mixing partner is spiromesifen.

[0637] 609d. The composition of detail 3d, wherein the mixing partner is spiropyridione.

[0638] 610d. The composition of detail 3d, wherein the mixing partner is spirotetramat.

[0639] 611d. The composition of detail 3d, wherein the mixing partner is sulfluramide.

[0640] 612d. The composition of detail 3d, wherein the mixing partner is sulfotep.

[0641] 613d. The composition of detail 3d, wherein the mixing partner is sulfoxaflor.

[0642] 614d. The composition of detail 3d, wherein the mixing partner is tau fluvalinate.

[0643] 615d. The composition according to detail 3d, wherein the mixing partner is tebuconazole.

[0644] 618d. The composition according to detail 3d, wherein the mixing partner is tebupirimfos.

[0645] 619d. The composition according to detail 3d, wherein the mixing partner is teflubenzuron.

[0646] 620d. The composition of detail 3d, wherein the mixing partner is tefluthrin.

[0647] 621d. The composition according to detail 3d, wherein the mixing partner is temephos.

[0648] 622d. The composition according to detail 3d, wherein the mixing partner is terbufos.

[0649] 623d. The composition according to detail 3d, wherein the mixing partner is tetrachlorvinphos.

[0650] 624d. The composition according to detail 3d, wherein the mixing partner is tetradifon.

[0651] 625d. The composition according to detail 3d, wherein the mixing partner is tetramethrin.

[0652] 626d. The composition according to detail 3d, wherein the mixing partner is tetraniliprole.

[0653] 627d. The composition of detail 3d, wherein the mixing partner is theta-cypermethrin.

[0654] 628d. The composition according to detail 3d, wherein the mixing partner is thiabendazole.

[0655] 629d. The composition of detail 3d, wherein the mixing partner is thiamethoxam.

[0656] 630d. The composition of detail 3d, wherein the mixing partner is thiocyclam.

[0657] 631d. The composition of detail 3d, wherein the mixing partner is thiodicarb.

[0658] 632d. The composition of detail 3d, wherein the mixing partner is thiofanox.

[0659] 633d. The composition according to detail 3d, wherein the mixing partner is thiometon.

[0660] 634d. The composition according to detail 3d, wherein the mixing partner is thiosultap sodium.

[0661] 635d. The composition according to detail 3d, wherein the mixing partner is thiram.

[0662] 636d. The composition of detail 3d, wherein the mixing partner is thiolanthraniliprole.

[0663] 637d. The composition according to detail 3d, wherein the mixing partner is thioxazaphen.

[0664] 638d. The composition according to detail 3d, wherein the mixing partner is tolfenpyrad.

[0665] 639d. The composition according to detail 3d, wherein the mixing partner is tralkoxydim.

[0666] 640d. The composition of detail 3d, wherein the mixing partner is tralomethrin.

[0667] 641d. The composition according to detail 3d, wherein the mixing partner is transfluthrin.

[0668] 642d. The composition according to detail 3d, wherein the mixing partner is a triazamate.

[0669] 643d. The composition according to detail 3d, wherein the mixing partner is triazophos.

[0670] 644d. The composition of detail 3d, wherein the mixing partner is trichlorfon.

[0671] 645d. The composition of detail 3d, wherein the mixing partner is triclopyr.

[0672] 646d. The composition according to detail 3d, wherein the mixing partner is trifloxystrobin.

[0673] 647d. The composition according to detail 3d, wherein the mixing partner is triflumezopyrim.

[0674] 648d. The composition according to detail 3d, wherein the mixing partner is triflumuron.

[0675] 649d. The composition according to detail 3d, wherein the mixing partner is trimethacarb.

[0676] 650d. The composition according to detail 3d, wherein the mixing partner is triticonazole.

[0677] 651d. The composition of detail 3d, wherein the mixing partner is vamidothion.

[0678] 652d. The composition of detail 3d, wherein the mixing partner is XMC.

[0679] 653d. The composition of detail 3d, wherein the mixing partner is xylylcarb.

[0680] 654d. The composition according to detail 3d, wherein the mixing partner is zeta-cypermethrin.

[0681] 655d. The composition of detail 3d, wherein the mixing partner is 2,4-D.

[0682] 656d. The composition according to detail 3d, wherein the mixing partner is methallyl picoxamide.

[0683] 657d. The mixing partner is N-(4-chloro-2-(pyridin-3-yl)thiazol-5-yl)-N-ethyl-3-(methylsulfonyl)propanamide (AI-1). [ka] 3d. The composition of claim 3d,

[0684] 658d. The mixing partner is N-(3-chloro-1-(pyridin-3-yl)-1H-pyrazol-4-yl)-2-(methylsulfonyl)propanamide (AI-2). [ka] 3d. The composition of claim 3d,

[0685] 659d. The composition of detail 3d, wherein the mixing partner is heat-killed Burkholderia spp.

[0686] 660d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 40000:1 to about 1:40000.

[0687] 661d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 10256:1 to about 1:10256.

[0688] 662d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 10000:1 to about 1:10000.

[0689] 663d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 2564:1 to about 1:2564.

[0690] 664d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 1000:1 to about 1:1000.

[0691] 665d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 640:1 to about 1:640.

[0692] 666d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 500:1 to about 1:500.

[0693] 667d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 100:1 to about 1:100.

[0694] 668d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 50:1 to about 1:50.

[0695] 669d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 20:1 to about 1:20.

[0696] 670d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from about 16:1 to about 1:16.

[0697] 671d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 10:1 to about 1:10.

[0698] 672d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 5:1 to about 1:5.

[0699] 673d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 3:1 to about 1:3.

[0700] 674d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 2:1 to about 1:2.

[0701] 675d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is 1:1.

[0702] 676d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:20,000 to 20,000:1.

[0703] 677d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:2,000 to 2,000:1.

[0704] 678d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:160,000 to 160,000:1.

[0705] 679d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:80,000 to 80,000:1.

[0706] 680d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:16,000 to 16,000:1.

[0707] 681d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is 1:8,000 to 8,000:1.

[0708] 682d. A composition according to any one of details 351d to 659d, in which the weight ratio of F1 to said mixing partner is from 1:250 to 250:1.

[0709] 683d. A composition according to any one of details 351d to 659d, wherein the weight ratio of F1 to said mixing partner is from 1:25 to 25:1.

[0710] 684d. A method for controlling pests in their habitat by using a pesticide composition according to any one of details 351d to 683d in an amount effective as a pesticide.

[0711] 685d. The method of detail 684d, wherein the pest is of the phylum Arthropoda, Mollusca, and / or Nematoda.

[0712] 686d. The method of detail 684d, wherein the pest is an ant, aphid, bedbug, beetle, silverfish, caterpillar, cockroach, cricket, earwig, flea, flies, grasshopper, grub, wasp, killer bee, leafhopper, lice, locust, maggot, mealybug, mite, moth, nematode, mirid, planthopper, psyllid, sawfly, scale insect, silverfish, slug, snail, spider, springtail, stink bug, symphysodon, termite, thrips, tick, digger wasp, whitefly, and / or wireworm.

[0713] 687d. The method of detail 684d, wherein the pest is an aphid, a leafhopper, a moth, a scale insect, a thrip, a psyllid, a mealybug, a stink bug, and / or a whitefly.

[0714] 688d. The method of detail 684d, wherein the pest is a caterpillar, beetle, grasshopper, and / or locust.

[0715] In some embodiments of the pesticide compositions disclosed herein, the molecule having the structure of Formula 1 is F1. In some embodiments, the pesticide compositions disclosed herein comprise F1 and at least one active ingredient selected from AIGA-1. In some other embodiments, the pesticide compositions disclosed herein comprise F1 and at least two active ingredients selected from AIGA-1. In some other embodiments, the pesticide compositions disclosed herein comprise F1 and at least three active ingredients selected from AIGA-1. In certain other embodiments, the pesticide compositions disclosed herein comprise F1 and at least four active ingredients selected from AIGA-1. In some embodiments, the pesticide compositions disclosed herein comprise F1 and AI-2. In some other embodiments, the pesticide compositions disclosed herein comprise F1 and AI-1.

[0716] In some embodiments, the pesticide composition disclosed herein comprises F1 and another active ingredient selected from the group consisting of cyclobutrifluram, isocycloceram, spidoxamato, spiropyridione, dinpropylidaz, and phenmezodithiaz, wherein the ratio of F1 to any of these ingredients is 1:100 to 100:1.

[0717] In some embodiments, the pesticide composition disclosed herein comprises F1 and cyclobutrifluram. The ratio of F1 to cyclobutrifluram is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with cyclobutrifluram can be expected at certain ratios within this range. In this context, "enhanced efficacy" means higher than expected efficacy as calculated by the Colby formula.

[0718] In some embodiments, the pesticide composition disclosed herein comprises F1 and isocycloceram. The ratio of F1 to isocycloceram is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with isocycloceram can be expected at certain ratios within this range. In this context, "enhanced efficacy" means higher than expected efficacy as calculated by the Colby formula.

[0719] In some embodiments, the pesticide composition disclosed herein comprises F1 and spidoxamat. The ratio of F1 to spidoxamat is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with spidoxamat can be expected at certain ratios within this range. In this context, "enhanced efficacy" means higher efficacy than expected as calculated by the Colby formula.

[0720] In some embodiments, the pesticide composition disclosed herein comprises F1 and spiropidione. The ratio of F1 to spiropidione is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with spiropidione can be expected at certain ratios within this range. In this context, "enhanced efficacy" means higher than expected efficacy as calculated by the Colby formula.

[0721] In some embodiments, the pesticide composition disclosed herein comprises F1 and dinpropylidaz. The ratio of F1 to dinpropylidaz is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with dinpropylidaz can be expected at certain ratios within this range. In this context, "enhanced efficacy" means greater than expected efficacy as calculated by the Colby formula.

[0722] In some embodiments, the pesticide composition disclosed herein comprises F1 and phenmezodithiaz. The ratio of F1 to phenmezodithiaz is 1:200 to 200:1. Enhanced efficacy when F1 is mixed with phenmezodithiaz can be expected at certain ratios within this range. In this context, "enhanced efficacy" means higher than expected efficacy as calculated by the Colby formula.

[0723] In some embodiments, the pesticide compositions disclosed herein comprise F1 and at least one active ingredient selected from AIGA-2. In other embodiments, the pesticide compositions disclosed herein comprise F1 and at least two active ingredients selected from AIGA-2. In other embodiments, the pesticide compositions disclosed herein comprise F1 and at least three active ingredients selected from AIGA-2. In certain other embodiments, the pesticide compositions disclosed herein comprise F1 and at least four active ingredients selected from AIGA-2.

[0724] In certain embodiments, the combination of F1 and at least one other active substance can be used for foliar treatment, seed treatment, soil treatment, or furrow treatment. In some preferred embodiments, the combination of F1 and at least one other active substance can be used for seed treatment. In some embodiments, the seed treatment mixture comprises F1 and at least two active substances. In some other embodiments, the seed treatment mixture comprises F1 and at least three active substances. In certain other embodiments, the seed treatment mixture comprises F1 and at least four active substances.

[0725] In some embodiments, the combination of F1 with another active agent may be any one of the following: 1.F1, imidacloprid, metalaxyl, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 2.F1, metalaxyl, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 3.F1, mefenoxam, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 4.F1, pydiflumetofen, oxathiapiprolin 5.F1, imidacloprid, isocycloceram, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 6.F1, isocycloceram, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 7.F1, cyclobutrifluram, picoxystrobin, ethaboxam, ipconazole, oxathiapiprolin 8.F1, fludioxonil, mefenoxam, thiabendazole, azoxystrobin 9.F1, impilfluxam, ethaboxam, metalaxyl 10.F1, prothioconazole, fluoxastrobin, metalaxyl 11.F1, fludioxonil, thiabendazole, azoxystrobin, mefenoxam, sedaxane 12.F1, penflufen, prothioconazole, metalaxyl 13.F1, difenoconazole, impirfluxam, ipconazole, mefenoxam

[0726] Aspect A: One aspect of the pesticide composition disclosed herein is (A)F1; [ka] B) Abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acinonapyr, afidopiropen, alanycarb, aldicarb, allethrin, α-cypermethrin, aminopyralid, amitraz, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotine, azoxystrobin, bendiocarb, benfuracarb, bensultap, benzoximate, benzpyrimoxane, β-cyfluthrin, β-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin, bist Lifluron, brofuranilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionate, chlorantraniliprole, chlordane, chlorethoxyphos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine, clopyralid, cloquintocet, clothianidin, copper hydroxide, coumaphos, cyanophos, cyanophos Antraniliprole, cyclaniliprole, cyclobutrifluram, cycloprothrin, cycloxapride, cyenopyrafen, cyflumetofen, cyfluthrin, cyhalothrin, cyhexatin, cymoxanil, cypermethrin, cyphenothrin, cyprofuranilide, cyromazine, d-cis-trans allethrin, DDVP, deltamethrin, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, dicofol, dicrotophos, difenoconazole, diflobidazin, diflubenzuron, dimethoate, dimethylvinphos, gin Propyridaz, dinotefuran, disulfoton, DNOC, d-trans allethrin, emamectin, emamectin benzoate, empenthrin, endosulfan, EPN, esfenvalerate, ethaboxam, ethiofencarb, ethion, ethiprole, ethoprophos, etofenprox, famoxadone, famfur, fenamiphos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, fenmezodithiaz, fenobucarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion,Fenvalerate, fipronil, flazasulfuron, flonicamid, florasulam, fluacrypyrim, fluazaindolizine, flubendiamide, flucycloxuron, flucythrinate, fludioxonil, fluensulfone, flufenoxuron, flumethrin, flumioxazin, fluopyram, fluoxapiprolin, fluoxastrobin, flupyradifuron, flupirimin, fluroxypyr, fluxamethamide, fluxapyroxad, formetanate, fosthiazate, furathiocarb, gamma-cyhalothrin, glyphosate, halaximidine Fen, Halfenprox, Halofenozide, Heptenophos, Hexaflumuron, Hexythiazox, Hydramethylnon, Hydroprene, Imazamox, Imazapyr, Imicyafos, Imidacloprid, Imiprothrin, Indazapiroxameth, Indoxacarb, Inpirfluxam, Ipconazole, Isocycloceram, Isofenphos, Isoflucipram, Isoprocarb, Isoxathion, Kadethrin, Kinoprene, λ-Cyhalothrin, Lepimectin, Lufenuron, Malathion, Mancozeb, MCPA, Mecarbam, Mefenoxam, Metaflumizone, metalaxyl, metconazole, methamidophos, methenamine, methidathion, methiocarb, methomyl, methoprene, methoxychlor, methoxyfenozide, metolcarb, metsulfuron, mevinphos, milbemectin, monocrotophos, myclobutanil, naled, nicosulfuron, nitrapyrin, novaluron, noviflumuron, omethoate, oxamyl, oxathiapiprolin, oxazosulfil, oxydemeton methyl, parathion, parathion methyl, penflufen, penthiopyrad, permethrin, fenothrin, Phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, picarbutrazox, picloram, picoxystrobin, pinoxaden, pirimicarb, pirimiphos-methyl, prallethrin, profenofos, propargite, propetamphos, propiconazole, propoxur, propyzamide, prothioconazole, prothiofos, spiflumetofen, piflubumid, pymetrozine, pyraclofos, pyraclostrobin, pyrethrum, pyridaben, pyridalyl, pyridaphenthion, pyrifluquinazon,Pyrimidifen, pyriproxyfen, pyroxasulfone, quinalphos, resmethrin, rimsulfuron, rotenone, sedaxane, silafluofen, spidoxamat, spinetoram, spinosad, spirobudifen, spirodiclofen, spiromesifen, spiropidione, spirotetramat, sulfuramide, sulfotep, sulfoxaflor, taufluvalinate, tebuconazole, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temephos, terbufos, tetrachlorvinphos, tetradifon, tetramethrin, tetraniliprole, θ-cyperme agrochemical compositions comprising mixing partners selected from the group consisting of thiazolinone, thiabendazole, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, thiosultap sodium, thiram, thiolantraniliprole, thioxazaphen, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, triflumuron, trimethacarb, vamidothion, XMC, xylylcarb, zeta-cypermethrin, AI-1, AI-2, and 2,4-D.

[0727] Aspect B Another embodiment is a pesticide composition comprising F1 and a mixing partner, wherein the mixing partner is selected from the group consisting of abamectin, acetamiprid, benzpyrimoxan, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclobutrifluram, dimepropyridaz, fipronil, flonicamid, fluoxapiprolin, flupyradifurone, flupirimine, fluxamethamide, imidacloprid, indoxacarb, isocycloceram, lambda-cyhalothrin, methoxyfenozide, pymetrozine, pyriproxyfen, spidoxamat, spinetoram, spinosad, spiropydione, spirotetramat, sulfoxaflor, thiamethoxam, and triflumezopyrim.

[0728] Aspect C Another embodiment is an agrochemical composition comprising F1 and a mixing partner, wherein the mixing partner is selected from the group consisting of azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxapyroxad, inpirfluxam, ipconazole, isoflucipram, mefenoxam, mefentrifluconazole, metalaxyl, myclobutanil, oxathiapiprolin, picoxystrobin, propiconazole, prothiaconazole, pydiflumetofen, pyroclostrobin, seda Xanthane, tebuconazole, thiabendazole, thiram, titriconazole, trifloxystrobin, abamectin, acetamiprid, afidopiropen, AI-1, AI-2, benzpyrimoxan, bifenthrin, brofuranilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, fluazaindolizine, fluensulfone, flupyradifurone, flupirimine, fluxamethamide, heat-killed Burkholderia species spp. strain A396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramet, sulfoxaflor, tetraniliprole, thiamethoxam, and triflumezopyrim.

[0729] Aspect D Another embodiment is an agrochemical composition comprising F1 and a mixing partner, wherein the mixing partner is selected from the group consisting of azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxapyroxad, impilfluxam, ipconazole, isoflucipram, mefenoxam, mefentrifluconazole, metalaxyl, myclobutanil, oxathiapiprolin, picoxystrobin, propiconazole, prothiaconazole, pydiflumetofen, pyroclostrobin, sedaxane, tebuconazole, thiabendazole, thiram, titriconazole and trifloxystrobin.

[0730] Aspect E Another embodiment is a pesticide composition comprising F1 and a mixing partner, wherein the mixing partner is selected from the group consisting of abamectin, acetamiprid, afidopiropen, AI-1, AI-2, benzpyrimoxan, bifenthrin, brofuranilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, fluazaindolizine, fluensulfone, flupyradifurone, flupirimine, fluxamethamide, heat-killed Burkholderia spp. spp. strain A396, imidacloprid, indoxacarb, lambda-cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramet, sulfoxaflor, tetraniliprole, thiamethoxam, and triflumezopyrim.

[0731] In any of the pesticide compositions according to aspects A to E, the ratio of F1 to mixing partner B) is 1:160,000-160,000:1, 1:80,000-80,000:1, 1:40,000-40,000:1, 1:20,000-20,000:1, 1:10,000-10,000:1, 1:8000 1:100-100:1; 1:50-50:1; 1:25-25:1; 1:10-1 ...

[0732] Also disclosed herein are methods for controlling pests that attack plants, plant parts, or plant habitats, comprising contacting the plants, plant parts, or plant habitats with a composition of any of embodiments A through E.

[0733] Also disclosed herein are methods for controlling pests that attack plants, plant reproductive sites, or plant habitats, comprising contacting the pest or its habitat, food supply, breeding ground, or growing location with a composition of any of embodiments A-E.

[0734] Disclosed herein is a method of treating seeds comprising contacting seeds with a composition of embodiments AE.

[0735] Also disclosed herein are seeds treated with the compositions of embodiments A-E.

[0736] These combinations containing three or more active substances can, when mixed in an appropriate ratio, exhibit enhanced activity when all active substances are used together with F1 compared to when they are used alone. For example, a specific F1 mixture containing three or more active substances, F1, impirfluxam, ethaboxam, and metalaxyl, can exhibit enhanced activity for this combination of active substances compared to the activity of any of these active substances alone, when calculated using Colby's formula (i.e., predicted efficacy is calculated using Colby's formula and compared to observed efficacy; if observed efficacy is higher than predicted efficacy calculated using Colby's formula, the composition exhibits enhanced efficacy) or any other method. In addition to providing enhanced activity, these combinations can also provide additional, unexpectedly advantageous properties. Improved useful plant properties including, for example, desirable decomposition characteristics, improved toxicological and / or ecotoxicological profile, emergence, crop yield, more developed root system, increased tillering, increased plant height, vivid green colour, increased leaf blade, reduced basal leaf dieback, enhanced tillering, earlier flowering (flowing), earlier grain maturity, increased shoot growth, improved essential nutrient content, improved plant vigour and earlier germination.

[0737] While the enhanced activity of the compositions disclosed herein is unexpected, surprising, and surprising, such activity also broadens the spectrum of action of F1 alone or any of the active substances alone in two ways: activity remains good or even better, while the application rate of F1 and any of the other active substances is reduced, and the mixture still provides high pest control even when the two individual components alone are ineffective at such low application rates. In addition, such mixtures can provide a substantial broadening of the spectrum of pests that can be controlled.

[0738] Biological assays The following bioassays are good indicators for a wide range of agricultural pests: green peach aphid (Myzus persicae), sweet potato whitefly (Bemisia tabaci), western flower thrips (Frankliniella occidentalis), brown planthopper (Nilaparvata lugens), neotropical brown stinkbug (Euschistus heros), tobacco budworm (Helicoverpa zea), fall armyworm (Spodoptera frugiperda), and soybean looper (Chrysodeixis inculdens). These indicator species results demonstrate the broad utility of combining a variety of pesticides (also called active ingredients) with the molecules of Formula 1 in pest control.

[0739] Bioassay 1: Green peach aphid (Myzus persicae, MYZUPE, "GPA"). The green peach aphid (Myzus persicae) is the most serious aphid pest of peach trees, causing stunted growth, leaf dwarfism, and death of various tissues. The peach aphid is also dangerous because it acts as a vector for plant viruses, such as potato virus Y and potato leaf curl virus on members of the nightshade / potato family (Solanaceae), and various mosaic viruses on many other food crops. GPA attacks plants such as broccoli, burdock, cabbage, carrots, cauliflower, radish, eggplant, green beans, lettuce, macadamia, papaya, pepper, sweet potato, tomato, watercress, and zucchini, among others. GPA also attacks many ornamental crops, such as carnations, chrysanthemums, snap peas, poinsettias, and roses. GPA has developed resistance to many pesticides. Currently, GPA is the third most frequently reported pest for which insect resistance has emerged (Sparks et al.). Consequently, the control of this pest is important due to the factors mentioned above. Furthermore, molecules that control GPA, a sap-feeding pest, may also be useful in controlling other pests that feed on plant sap.

[0740] Stock solutions of F1 and the various active ingredients were initially prepared using a 1:1 mixture of acetone:methanol as the diluent, at concentrations of 4 milligrams per milliliter (mg / mL) for F1 and 0.1 mg / mL for the active ingredients, respectively. Separate stock solutions were prepared for F1 and for each of the active ingredients. Test solutions were prepared from the stock solutions. Test solutions containing F1, the individual active ingredients, and mixtures of F1 with each of the active ingredients were prepared. Test solutions of F1 and the individual active ingredients were prepared by adding 750 microliters (μL) of stock solution to a 25 mL glass vial, then adding 750 μL of 1:1 acetone:methanol solvent, followed by 13.5 mL of water containing 0.025% Tween® 20 to create a 0.0005% (weight / volume (w / v)) solution. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 750 μL of the active ingredient stock solution to a 25 mL glass vial, followed by 750 μL of F1 stock solution, followed by 13.5 mL of water containing 0.025% Tween® 20 to create test solutions containing 0.0005% (w / v) F1 and 0.0005% (w / v) of the active ingredient. Each test solution was serially diluted to create the desired test solution dosages: 0.0005% (w / v), 0.000125% (w / v), 0.00003125% (w / v), 0.0000078% (w / v), 0.00000195% (w / v), and 0.0000005% (w / v). In test solutions containing a mixture of F1 and the active ingredient, the active ingredient was diluted as described above, but the concentration of F1 was kept constant (0.04% (w / v)).

[0741] The test solutions were tested against GPA using the following procedure: Cabbage seedlings with two to three small (3-5 centimeter (cm)) true leaves grown in 3-inch pots were used as test substrates. The day before chemical application, the seedlings were infested with 20 to 50 GPA (wingless adult and nymph stages). Four individual pots containing seedlings were used for each treatment. Using a handheld suction sprayer, the solution was sprayed onto both sides of the cabbage leaves until overflowing and runoff. Reference plants (solvent control) were sprayed with diluent only (0.025% Tween® 20 in water and 10% acetone:methanol (1:1)). Treated plants were kept in a storage room at approximately 25°C and ambient relative humidity (RH approximately 20% to approximately 45%) for three days until grading. Evaluation was performed by counting the number of live aphids per plant under a microscope three days after treatment. The control rate was determined using Abbott's correction formula as follows (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of live aphids on solvent control plants and Y = number of live aphids on treated plants. The "Expected % Control" in Table B1 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are presented in Table 1 in the Tables section.

[0742] Bioassay 2: Sweet potato whitefly (Bemisia tabaci, BEMITA, "SPW"). The sweet potato whitefly (SPW) is a major destructive pest of cotton. It is also a serious pest of many vegetable crops, such as melons, crucifers, tomatoes, and head lettuce, as well as ornamental plants. SPW causes damage both through direct feeding and virus transmission. SPW are sap-feeding insects, and their feeding removes nutrients from the plant. This can result in stunted growth, defoliation, reduced yield, and drop of cotton. SPW produce large amounts of nectar, which supports the growth of sooty mold fungi on plant leaves. SPW are also vectors of viruses, such as cotton leaf curl virus and tomato yellow leaf curl virus.

[0743] Stock solutions of F1 and one or more active ingredients were prepared at a concentration of 0.2 mg / mL using acetone as a diluent. Separate stock solutions were prepared for F1 and for each active ingredient. Test solutions were prepared from the stock solutions. Test solutions containing F1, individual active ingredients, and mixtures of F1 and each active ingredient were prepared. Test solutions of F1 and individual active ingredients were prepared by adding 500 μL of stock solution to a 25 mL glass vial, then adding 500 μL of acetone, followed by adding 9 mL of water containing 0.025% Tween® 20 to create a 0.001% (w / v) solution. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 500 μL of the active ingredient stock solution to a 25 mL glass vial, followed by 500 μL of F1 stock solution, followed by 9 mL of water containing 0.025% Tween® 20 to create test solutions containing 0.001% (w / v) F1 and 0.001% (w / v) of the active ingredient. Each test solution was serially diluted to create the desired dosages of test solutions: 0.001% (w / v), 0.0001% (w / v), 0.00001% (w / v), 0.000001% (w / v), 0.0000001% (w / v), and 0.00000001% (w / v).

[0744] The test solution was tested against SPW using the following procedure: Cotton seedlings grown in 3-inch pots and pruned to one true leaf were used as test substrates. Adult B. tabaci were allowed to settle on the cotton plants and lay eggs for 24 hours, after which all adults were removed from the plants using compressed air. Plants were monitored for egg development, and when caterpillar emergence began (greater than 25% emergence by visual inspection using a microscope), the plants were sprayed using the test solution and the method described above for Green peach aphid (GPA). Treated plants were kept in a storage room at approximately 25°C and ambient relative humidity (RH) until grading. Evaluation was performed 7-9 days after treatment by counting the number of developed second- to third-instar nymphs per plant under a microscope. The control rate was determined using Abbott's correction formula as follows (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of surviving nymphs on solvent control plants and Y = number of surviving nymphs on treated plants. The "Expected % Control" in Table B2 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are presented in Table 2 in the Tables section.

[0745] Bioassay 3: Western flower thrips (Frankliniella occidentalis, FRANOC, "WFT"). Western flower thrips (WFT) are major destructive pests of a wide variety of commercially relevant plant species (over 500 host plant species have been recorded), including many fruit, vegetable, and ornamental plants. WFT are sap-feeding insects that feed on a variety of plant parts, destroying plant cells as they feed. WFT are also known to act as vectors of plant diseases and are one of the primary vectors of the tomato spotted wilt virus.

[0746] Stock solutions of F1 and the various active ingredients were initially prepared at a concentration of 0.1 mg / mL using acetone as a diluent. Separate stock solutions were prepared for F1 and for each of the active ingredients. Test solutions were prepared from the stock solutions. Test solutions containing F1, each active ingredient, and a mixture of F1 and each active ingredient were prepared. Test solutions of F1 and each active ingredient were prepared by adding 500 μL of the stock solution to a 25 mL glass vial, then adding 500 μL of acetone, followed by adding 9 mL of water containing 0.025% Tween® 20 to create a 0.0005% (w / v) solution. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 500 μL of the active ingredient stock solution to a 25 mL glass vial, followed by 500 μL of F1 stock solution, followed by 9 mL of water containing 0.025% Tween® 20 to create test solutions containing 0.0005% (w / v) F1 and 0.0005% (w / v) of the active ingredient. Each test solution was serially diluted to create the desired test solution dosages: 0.0005% (w / v), 0.000125% (w / v), 0.00003125% (w / v), 0.0000078% (w / v), and 0.00000195% (w / v).

[0747] The test solutions were tested against WFT using the following procedure: Leaf discs (2.7 cm diameter) were cut from the true leaves of cotton plants. The leaf discs were immersed in the test solution, shaken to ensure complete coverage, and then placed in Millipore® PetriSlides containing filter paper discs. The treated leaf discs were allowed to air dry for approximately 1 hour. Each leaf disc was infested by placing five WFT (9-10 day old nymphs) on each leaf disc, and the PetriSlide lid was closed to prevent escape. Each treatment was replicated three times, and the test treatments were maintained at approximately 26°C and ambient relative humidity (RH) until grading. Reference discs (solvent controls) were treated with diluent only. Evaluation was performed by counting the number of live WFT under magnification 3 days after treatment. The control rate was determined using Abbott's correction formula as follows (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of surviving nymphs on the solvent control leaf discs and Y = number of surviving nymphs on the treated leaf discs. The "Expected % Control" in Table B3 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are presented in Table 3 in the Tables section.

[0748] Bioassay 4: tobacco budworm (Helicoverpa zea, HELIZE, "CEW"), armyworm (Spodoptera frugiperda, LAPHFR, "FAW"), and soybean looper (Chrysodeixis includens, PSEPIN, "SBL"). The tobacco budworm (CEW) is listed as one of the most damaging crop pests in North America, typically attacking the post-harvest portions of many high-value crops. In addition to corn and tomatoes, CEW larvae also attack artichoke, asparagus, cabbage, cantaloupe, collard greens, cowpeas, cucumbers, eggplant, lettuce, lima beans, melons, okra, peas, peppers, potatoes, pumpkins, green beans, spinach, squash, sweet potatoes, and watermelon. Other crops affected by the tobacco budworm include alfalfa, clover, cotton, flax, oats, millet, rice, sorghum, soybeans, sugarcane, sunflowers, tobacco, vetch, and wheat. The armyworm (Coleoptera: Noctuidae) is a worldwide pest of many agriculturally important plant species, including alfalfa, barley, buckwheat, cotton, clover, corn, oats, foxtail millet, peanuts, rice, ryegrass, sorghum, sugar beet, soybean, sugarcane, timothy grass, tobacco, wheat, and many more. FAW larvae damage plants by feeding on leaves and fruits, resulting in yield loss and even death of the host plant. Similarly, soybean loopers are common and destructive pests of soybeans, but they also feed on other agronomic crops, such as peanuts, cotton, and corn, as well as vegetable crops, including peas, crucifers, sweet potatoes, tomatoes, peppers, runner beans, cucumbers, and watermelons, among others. CEW, FAW, and SBL are good examples of harmful larval lepidopteran pests.

[0749] Stock solutions of F1 and one or more active ingredients were prepared using a 9:1 mixture of acetone:water as the diluent at concentrations of 0.4 mg / mL for F1 and 4 mg / mL for the active ingredient. Separate stock solutions were prepared for F1 and for each of the active ingredients. Test solutions were prepared from the stock solutions. Test solutions containing F1, individual active ingredients, and mixtures of F1 and each of the active ingredients were prepared. Test solutions for F1 were prepared by adding 500 μL of the stock solution to a 25 mL glass vial, followed by 500 μL of a 9:1 mixture of acetone:water. Individual active ingredients were prepared by adding 500 μL of the stock solution to a 25 mL glass vial, followed by 500 μL of a 9:1 mixture of acetone:water. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 500 μL of the active ingredient stock solution to a 25 mL glass vial, followed by 500 μL of F1 stock solution to make test solutions containing 0.04% (w / v) F1 and 0.4% (w / v) of the active ingredient. Each test solution was serially diluted to prepare test solutions with the desired dosage (F1: 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) and the active ingredient: 0.4% (w / v), 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), and 0.000004% (w / v)).

[0750] Test solutions were tested against CEW, FAW, and SBL using the following procedure: Artificial diet for lepidopteran insects (Multispecies Lepidopteran Diet, Southland Products) was dispensed into a 128-cell bioassay tray (Frontier Agricultural Sciences™). 50 μL of test solution was pipetted into the cells of the bioassay tray. (Test solution doses of 0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) were 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 μg / cm, respectively. 2 The control rate was calculated using Abbott's formula (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of surviving larvae in the solvent control and Y = number of surviving larvae in the treated diet. The "Expected % Control" in Table B4 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are listed in Table 4 in the Tables section.

[0751] Bioassay 5: Neotropical brown stink bug (Euschistus heros), EUSCHE, "BSB"). The neotropical brown stink bug (BSB) is a major pest of soybean, cotton, sunflower, and other economically important crops. BSB is a sap-feeding insect that damages plant cells and seeds during feeding. As it feeds on plant seeds, it can reduce seed viability and reduce yields.

[0752] Stock solutions of F1 and one or more active ingredients were prepared at a concentration of 0.2 mg / mL using dimethyl sulfoxide (DMSO) as the solvent. Separate stock solutions were prepared for F1 and for each of the active ingredients. Test solutions were prepared from the stock solutions. Test solutions containing F1, individual active ingredients, and mixtures of F1 and each active ingredient were prepared. Test solutions for F1 and individual active ingredients were prepared by adding 30 μL of the stock solution to a single well of a 96-well plate, followed by 30 μL of DMSO, followed by 140 μL of a 2:1 mixture of acetone:water as the diluent to create a 0.03% (w / v) solution. Test solutions containing mixtures of F1 and individual active ingredients were prepared by adding 30 μL of F1 stock solution to a single well of a 96-well plate, followed by 30 μL of each individual active ingredient stock solution to the same well, followed by 140 μL of a 2:1 mixture of acetone:water as diluent to create test solutions containing 0.03% (w / v) F1 and 0.03% (w / v) active ingredient. Each test solution was serially diluted to create the desired test solution dosages: 0.03%, 0.0075%, 0.001875%, 0.000469%, 0.000117%, and 0.000029% (w / v).

[0753] Test solutions were tested against BSB using the following procedure: an agar artificial diet (2% agar, 12% sucrose) was dispensed into a 48-well plastic plate (Fisher Scientific™). 25 μL of test solution was pipetted into a cell in a bioassay tray. (Test solution doses of 0.03% (w / v), 0.0075% (w / v), 0.001875% (w / v), 0.000469% (w / v), 0.000117% (w / v), and 0.000029% (w / v) were 36, 9, 2.25, 0.5625, 0.140625, and 0.035156 μg / cm, respectively. 2(The concentration of BSB nymphs is converted to the bait concentration in the control well. The reference treatment (solvent control) was treated with diluent only. Each treatment was replicated three times, and the test treatments were maintained at approximately 26°C and ambient relative humidity (RH) until grading. Three to five BSB nymphs were added and confined to each well with a transparent, perforated adhesive lid. The total number of surviving BSB nymphs was recorded four days after application. Scoring was based on the total number of surviving nymphs from all three replicates. The percent control was determined using Abbott's correction formula (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of surviving nymphs in the solvent control and Y = number of surviving nymphs in the treated bean sections. The "Expected % Control" in Table B5 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are listed in Table 5 in the Tables section.

[0754] Bioassay 6: Brown planthopper (Nilaparvata lugens, NILALU, "BPH"). The brown planthopper (BPH) is a highly destructive pest of rice found throughout the Asia-Pacific region. BPH is a sap-feeding insect that can cause mechanical damage to rice plants sufficient to kill them, and it is a vector of viral pathogens that reduce rice production yields. In addition, BPH has developed resistance to several insecticides that have been used to control outbreaks. These factors make BPH management important, along with the development of novel technologies to control this major pest species.

[0755] F1 and one or more active ingredients were tested at 50, 12.5, 3.125, and 0.78 grams active ingredient per hectare (g / ha). At these rates, F1 and the individual active ingredients were tested at a 1:1 ratio. Due to the high potency of triflumezopyrim against BPH, this chemical was tested at lower rates of 0.78, 0.19, 0.049, and 0.012 g / ha. F1 and triflumezopyrim were tested at a 16:1 ratio. Test solutions containing F1, individual active ingredients, and mixtures of F1 with each active ingredient were prepared by weighing 5 mg of each test chemical (either alone or in combination, depending on the treatment) into 25 mL glass vials. Next, 1 mL of acetone was added to each vial to dissolve the test chemical, followed by 19 mL of water containing 0.125% Tween 20 adjuvant. This test solution corresponded to a 50 g / ha treatment, which was then serially diluted four-fold to produce three lower rates: 12.5, 3.125, and 0.78 g / ha. Triflumezopyrim was prepared in a similar manner, except that two additional serial dilutions were made to produce solutions equivalent to six rates: 12.5, 3.125, 0.78, 0.19, 0.049, and 0.012 g / ha. The two higher doses were discarded, and the four lower doses were used in the study. Four replicates were performed at each rate, and a solvent blank was used as a control treatment.

[0756] Five rice seedlings (10–12 days old) planted in 3-inch pots were used as test plants. The rice seedlings were grown in soil and covered with a 2% agar solution. The test solution was applied to the test plants using a Devries laboratory sprayer set to spray 200 liters per hectare (L / ha) using a TeeJet hollow cone nozzle. After application, the rice seedlings were allowed to dry for 1 hour, and then each pot was covered with a single clear plastic tube (2 inches in diameter x 12 inches in height). The tube was pressed into the agar to create a sealed test chamber. The agar prevented insects from hiding in the soil and facilitated adult collection and grading. Ten to fifteen fifth-instar BPH nymphs were transferred to each test chamber using a vacuum aspirator. Immediately after infestation, the test chamber was sealed by covering it with a piece of grade 90 cheesecloth and securing it with a rubber band. The test chambers were kept at 25°C for 6 days, after which the total number of surviving insects per test chamber was counted. The control rate was determined using Abbott's correction formula as follows (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 where X = number of surviving insects in the solvent control and Y = number of surviving insects in the treated chamber. The "Expected % Control" in Table B6 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are listed in Table 6 in the Tables section.

[0757] Bioassay 7: tobacco budworm (Helicoverpa zea, HELIZE, "CEW"), fall armyworm (Spodoptera frugiperda, LAPHFR, "FAW"), beet armyworm (Spodoptera exigua, LAPHEG, "BAW"), and soybean looper (Chrysodeixis includens, PSEPIN, "SBL"). The test solution was tested against CEW, FAW, BAW, and SBL using the following procedure: An artificial diet for lepidopteran insects (Multispecies Lepidopteran Diet, Southland Products) was dispensed into a 96-well plate, and 20 μL of the test solution was pipetted into the cells of the bioassay plate. The test solution doses were 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 mg / cm² of diet (0.04% (w / v), 0.004% (w / v), 0.0004% (w / v), 0.00004% (w / v), 0.000004% (w / v), and 0.0000004% (w / v) test solution doses were converted to diet concentrations of 5, 0.5, 0.05, 0.005, 0.0005, and 0.00005 mg / cm², respectively). The reference treatment (solvent control) was treated with diluent only. Each treatment was replicated five times for each species. Approximately five first-instar CEW, FAW, BAW, or SBL larvae were placed on the diet in each cell and confined with a transparent, perforated adhesive lid. The test trays were maintained at approximately 25°C and ambient relative humidity until grading. After 5 days, the number of cells in which all larvae were killed was recorded as 100% and averaged across all replicates; control was then determined using Abbott's correction formula as follows (WS Abbott, J. Econ. Entomol. 18 (1925), pp. 265-267): Corrected control rate % = (1-(Y / X)) x 100 Where X = number of surviving larvae in the solvent control and Y = number of surviving larvae in the treated diet.

[0758] The "Expected % Control" in Table 7 was calculated using the method described in Colby SR, Weeds, 1967, 15, 20-22. The results are presented in Table 7.

[0759] Bioassay 8: Western corn rootworm (Diabrotica virgifera virgifera, DIABVI, "WCR") The Western Corn Rootworm (WCR) is one of the most destructive beetle (Coleoptera) pests in North America and Europe each year, attacking the roots of corn plants. The larval stage feeds on corn roots early in the season, disrupting normal growth and compromising the structural integrity of the plant. This reduces yield and causes plant lodging. The WCR is a good example of a soil pest that feeds on the plant's root system and seeds.

[0760] Corn seeds were planted in greenhouse pots filled with steam-sterilized soil. Western corn rootworm (Diabrotica virgifera virgifera) eggs, supplied by Corteva Agriscience, Johnston, IA, USA, were suspended in a 0.08% agar solution and added to the soil. Stock solutions of F1 and active ingredient were prepared using a 1:1 acetone:water solution as the diluent at concentrations of either 250 or 500 ugai / 10 mL, with ratios of F1 and active ingredient (F1:AI) of 1:0.004; 1:0.01; 1:0.02; 1:0.04; 1:0.08; 1:0.1; 1:0.15; 1:0.2; 1:0.4; 1:2; or 1:4. Soil applications were made as a 10 mL soil drench. After the plants were grown for 13 days in a greenhouse at 25°C, the roots were removed from the soil, washed, and measured to determine the median nodal root length. The measured lengths were compared to infested and uninfested untreated controls to determine the average percent control provided by corn root protection. The results are shown in Table 8.

[0761] Agriculturally acceptable acid addition salts, salt derivatives, solvates, ester derivatives, polymorphs, isotopes, and radionuclides The molecules of Formula 1 can be formulated into agriculturally acceptable acid addition salts. By way of non-limiting example, amine functional groups can form salts with hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid, acetic acid, benzoic acid, citric acid, malonic acid, salicylic acid, malic acid, fumaric acid, oxalic acid, succinic acid, tartaric acid, lactic acid, gluconic acid, ascorbic acid, maleic acid, aspartic acid, benzenesulfonic acid, methanesulfonic acid, ethanesulfonic acid, hydroxymethanesulfonic acid, and hydroxyethanesulfonic acid. Additionally, by way of non-limiting example, acid functional groups can form salts, including those derived from alkali metals or alkaline earth metals and those derived from ammonia and amines. Preferred examples of cations include sodium, potassium, and magnesium.

[0762] The molecule of formula 1 can be formulated into a salt derivative. As a non-limiting example, a salt derivative can be prepared by contacting the free base with a sufficient amount of the desired acid to produce the salt. The free base can be regenerated by treating the salt with a suitable dilute aqueous base solution, such as dilute aqueous sodium hydroxide, potassium carbonate, ammonia, and sodium bicarbonate. For example, pesticides such as 2,4-D are often made more water-soluble by converting them to their dimethylamine salts.

[0763] The molecules of formula 1 can be formulated into stable complexes with solvents such that the complex remains intact after removal of the uncomplexed solvent. Such complexes are often referred to as "solvates." However, it is particularly desirable to form stable hydrates with water as the solvent.

[0764] Molecules of Formula 1 bearing acid functional groups may be ester-derivatives, which may then be applied in the same manner as the molecules disclosed herein are applied.

[0765] Molecules of Formula 1 may be produced in various polymorphic forms. Polymorphism is important in agrochemical development because different polymorphic forms or structures of the same molecule can result in significantly different physical properties and biological performance.

[0766] The molecules of formula 1 may be made up of different isotopes. Of particular importance are: 1 Instead of H 2 H (aka deuterium) or 3 H (also known as tritium). Molecules of formula 1 may be made with different radionuclides. Of particular interest are: 14 C (also known as radiocarbon) is a molecule containing deuterium, tritium, or 14 Molecules of formula 1 having C may be used in biological studies to allow for the tracing of chemical and physiological processes, and may be used in half-life studies, as well as mode of action studies.

[0767] Formulation It may not be suitable to apply a pesticide in its pure form. Usually, other substances must be added to a pesticide so that it can be used at the required concentration and in an appropriate form to facilitate application, handling, transportation, storage, and maximize pesticidal activity. Therefore, pesticides are formulated into, for example, baits, emulsions, dusts, emulsifiable concentrates, fumigants, gels, granules, microcapsules, seed treatments, SCs, suspoemulsions, tablets, water-soluble liquids, water-dispersible granules, dry flowables, wettable powders, or ultra-low-volume sprays.

[0768] Pesticides are most often applied as aqueous suspensions or emulsions prepared from concentrated formulations of such pesticides. Such water-soluble, water-suspendable, or emulsifiable formulations are either solids, usually known as wettable powders; liquids, usually known as emulsifiable concentrates, as wettable granules; or aqueous suspensions. Wettable powders, which can be compressed to form wettable granules, contain a homogeneous mixture of pesticide, carrier, and surfactant. The pesticide concentration is usually about 10% to about 90% by weight. The carrier is usually selected from attapulgite clay, montmorillonite clay, diatomaceous earth, or purified silicates. Effective surfactants, comprising about 0.5% to about 10% of the wettable powder, are found among nonionic surfactants, such as sulfonated lignin, condensed naphthalene sulfonates, naphthalene sulfonates, alkylbenzene sulfonates, alkyl sulfates, and ethylene oxide adducts of alkylphenols.

[0769] Pesticide emulsifiable concentrates contain a convenient concentration of pesticide, such as about 50 to about 500 grams per liter of liquid, dissolved in a carrier that is either a water-miscible solvent or a mixture of a water-immiscible organic solvent and an emulsifier. Useful organic solvents include aromatic compounds, particularly xylenes, and petroleum fractions, especially the high-boiling naphthalene and olefinic portions of petroleum, such as heavy aromatic naphtha. Other organic solvents, such as terpene solvents including rosin derivatives, aliphatic ketones such as cyclohexanone, and complex alcohols such as 2-ethoxyethanol, can also be used. Suitable emulsifiers for emulsifiable concentrates are selected from conventional anionic and nonionic surfactants.

[0770] Aqueous suspensions include suspensions of water-insoluble pesticides dispersed in an aqueous carrier at concentrations ranging from about 5% to about 50% by weight. The suspensions are prepared by finely grinding the pesticide and vigorously mixing it into a carrier composed of water and surfactants. Ingredients such as inorganic salts and synthetic or natural gums may also be added to increase the density and viscosity of the aqueous carrier. In many cases, it is most effective to simultaneously grind and mix the pesticide by preparing an aqueous mixture and homogenizing it with equipment such as a sand mill, ball mill, or piston-type homogenizer. The pesticide in suspension may also be microencapsulated in a plastic polymer.

[0771] Oil dispersions (ODs) comprise suspensions of finely dispersed organic solvent-insoluble pesticides in a mixture of organic solvent and emulsifier at concentrations ranging from about 2% to about 50% by weight. One or more pesticides may be dissolved in the organic solvent. Useful organic solvents include aromatic compounds, particularly xylenes, and petroleum fractions, especially the high-boiling naphthalene and olefin portions of petroleum, such as heavy aromatic naphtha. Other solvents include vegetable oils, seed oils, and esters of vegetable and seed oils. Suitable emulsifiers for oil dispersions are selected from conventional anionic and nonionic surfactants. Thickeners or gelling agents are added to oil dispersion formulations to improve the rheological or flow properties of the liquid and to prevent separation and settling of dispersed particles or droplets.

[0772] Pesticides may also be applied as granular compositions, particularly useful for application to soil. Granular compositions typically contain about 0.5% to about 10% by weight of the pesticide dispersed in a carrier comprising clay or similar material. Such compositions are typically prepared by dissolving the pesticide in a suitable solvent and applying it to a granular carrier preformed to the appropriate particle size, ranging from about 0.5 mm to about 3 mm. Such compositions may also be formulated by creating a dough or paste of the carrier and molecules, followed by crushing and drying to achieve the desired granule particle size. Another form of granule is the water-emulsifiable granule (EG). This is a formulation consisting of granules that are to be applied as a conventional oil-in-water emulsion after disintegration and dissolution of any one or more active ingredients, either solubilized or diluted in an organic solvent, in water. Water-emulsifiable granules contain one or more active ingredients, either solubilized or diluted in a suitable organic solvent, absorbed in a water-soluble polymer shell or some other type of soluble or insoluble matrix.

[0773] Dusts containing pesticides are prepared by homogeneously mixing the pesticide in powder form with a suitable powdered agricultural carrier, such as kaolin clay, crushed volcanic rock, etc. Dusts may suitably contain from about 1% to about 10% pesticide. Dusts may be applied as seed dressings or as foliar sprays with a dust blower machine.

[0774] It is equally practical to apply the pesticide in the form of a solution in a suitable organic solvent, usually petroleum, such as the spray oils widely used in agricultural chemistry.

[0775] Pesticides can also be applied in the form of aerosol compositions, in which the pesticide is dissolved or dispersed in a carrier that is a pressure-generating propellant mixture. The aerosol composition is packaged in a container from which the mixture is dispensed through an atomizing valve.

[0776] Pesticide baits are formed when a pesticide is mixed with bait or attractant or both. When a pest eats the bait, it also ingests the pesticide. Baits can be in the form of granules, gels, flowable powders, liquids, or solids. Baits can be applied to pest habitats.

[0777] Fumigants are pesticides that have a relatively high vapor pressure and can therefore exist as gases in concentrations sufficient to kill pests in soil or confined spaces. The toxicity of a fumigant is proportional to its concentration and exposure time. Fumigants are characterized by their excellent ability to act by diffusion, either by penetrating the respiratory system of pests or by being absorbed through the pest's cuticle. Fumigants are applied to control stored food pests in airtight sheets, gas-sealed rooms or buildings, or special chambers.

[0778] Pesticides can be microencapsulated by suspending pesticide particles or droplets in various types of plastic polymers. Microcapsules can be formed with various sizes, solubility, wall thickness, and permeability by changing the chemistry of the polymer or by modifying processing factors. These factors affect the release rate of the active ingredient contained therein, which in turn affects the residual performance, speed of action, and odor of the product. Microcapsules can be formulated as SCs or wettable granules.

[0779] Oil concentrates are made by dissolving the pesticide in a solvent that will keep the pesticide in solution. Oil solutions of pesticides usually result in faster pest knockdown and kill than other formulations because the solvent itself is pesticidal and the dissolution of the waxy coating increases the rate of pesticide uptake. Other advantages of oil solutions include good storage stability, good crevices penetration, and good adhesion to oily surfaces.

[0780] Another embodiment is an oil-in-water emulsion, comprising dispersed in an aqueous phase oily droplets each provided with a lamellar liquid crystalline coating, each oily droplet comprising at least one agriculturally active molecule, and each oily droplet having an average particle diameter of less than 800 nanometers and individually coated with a single or multiple layers comprising: (1) at least one non-ionic lipophilic surfactant, (2) at least one non-ionic hydrophilic surfactant, and (3) at least one ionic surfactant.

[0781] Other formulation ingredients Generally, when a molecule disclosed in Formula 1 is used in a formulation, such formulation can also contain other ingredients, including, but not limited to, wetting agents, spreading agents, adhesives, penetrating agents, buffers, sequestering agents, drift reducing agents, compatibilizers, antifoaming agents, detergents, and emulsifiers (this is a non-exhaustive and non-mutually exclusive list). Some ingredients are described immediately below.

[0782] Wetting agents are substances that, when added to a liquid, increase the spreading or penetration power of the liquid by decreasing the interfacial tension between the liquid and the surface on which it spreads. Wetting agents are used in agrochemical formulations for two primary functions: to increase the wetting rate of powders in water during processing and manufacturing to create concentrates for soluble liquids or SC formulations; and to shorten the wetting time of wettable powders and improve the penetration of water into water-dispersible granules when the product is mixed with water in the spray tank. Examples of wetting agents used in wettable powder, SC, and water-dispersible granule formulations are sodium lauryl sulfate, sodium dioctyl sulfosuccinate, alkylphenol ethoxylates, and fatty alcohol ethoxylates.

[0783] Dispersants are substances that adsorb to particle surfaces, helping to maintain particle dispersion and preventing particle reagglomeration. Adding dispersants to agricultural chemical formulations facilitates dispersion and suspension during manufacturing and ensures particle redispersion in the water in the spray tank. Dispersants are widely used in wettable powders, SC formulations, and water-dispersible granules. Surfactants used as dispersants have the ability to strongly adsorb onto particle surfaces and provide a charged or steric barrier to particle reagglomeration. The most commonly used surfactants are anionic, nonionic, or a mixture of the two. For wettable powder formulations, the most common dispersant is sodium lignosulfonate. For SC formulations, the use of polyelectrolytes such as sodium-naphthalene-sulfonate-formaldehyde condensates provides excellent adsorption and stabilization. Tristyrylphenol ethoxylate phosphate esters are also used. Nonionic materials such as alkylarylethylene oxide condensates and EO-PO block copolymers are sometimes combined with anionic materials as dispersants for SC formulations. In recent years, a new type of ultra-high molecular weight polymer surfactant has been developed as a dispersant. It has a very long hydrophobic "backbone" and many ethylene oxide chains that form the "teeth" of the surfactant "comb." This high molecular weight polymer can impart excellent long-term stability to SC agents because the hydrophobic backbone provides many anchoring points on the particle surface. Examples of dispersants used in agricultural chemical formulations include sodium lignosulfonate, sodium naphthalene sulfonate formaldehyde condensate, tristyrylphenol-ethoxylate-phosphate ester, fatty alcohol ethoxylate, alkyl ethoxylate, EO-PO block copolymer, and graft copolymer.

[0784] Emulsifiers are substances that stabilize suspensions of droplets of one liquid phase within another. Without an emulsifier, these two liquids would separate into two immiscible liquid phases. The most commonly used emulsifier blends contain an alkylphenol or aliphatic alcohol with 12 or more ethylene oxide units and an oil-soluble calcium salt of dodecylbenzenesulfonic acid. A hydrophile-lipophile balance ("HLB") value in the range of about 8 to about 18 usually provides a stable emulsion. Emulsion stability can sometimes be improved by adding a small amount of an EO-PO block copolymer surfactant.

[0785] Solubilizers are surfactants that will form micelles in water at concentrations above their critical micelle concentration. The micelles are then able to dissolve or solubilize water-insoluble materials within the hydrophobic interior of the micelles. The types of surfactants commonly used for solubilization are nonionics, sorbitan monooleate, sorbitan monooleate ethoxylate, and methyl oleate.

[0786] Surfactants are sometimes used as adjuvants to spray tank mixtures, either alone or in conjunction with other additives such as mineral or vegetable oils, to improve the biological performance of pesticides on their targets. The type of surfactant used for bioenhancement generally depends on the nature and mode of action of the pesticide. However, such surfactants are often nonionic, such as alkyl ethoxylates, linear fatty alcohol ethoxylates, and fatty amine ethoxylates.

[0787] Carriers or diluents in agricultural formulations are materials added to pesticides to provide the desired strength of the product. Carriers are usually materials with high absorption capacity, while diluents are generally materials with low absorption capacity. Carriers and diluents are used in the formulation of dusts, wettable powders, granules, and water-dispersible granules.

[0788] Organic solvents are primarily used in the formulation of emulsifiable concentrates, oil-in-water emulsions, suspoemulsions, oil-based dispersions, and ultra-low-volume spray formulations, and, to a lesser extent, granular formulations. Sometimes, mixtures of solvents are used. The first major group of solvents are aliphatic paraffinic oils, such as kerosene or refined paraffin. The second major group (and the most common) includes aromatic solvents such as xylene and the higher molecular weight fractions of C9 and C10 aromatic solvents. Chlorinated hydrocarbons are useful as cosolvents to prevent crystallization of pesticides when the formulation is emulsified in water. Alcohols are sometimes used as cosolvents to increase solvent power. Other solvents can include vegetable oils, seed oils, and esters of vegetable and seed oils.

[0789] Thickeners or gelling agents are primarily used in the formulation of scaffolding agents, oil dispersions, emulsions, and suspoemulsions to improve the rheological or flow properties of liquids and to prevent separation and settling of dispersed particles or droplets. Thickeners, gelling agents, and anti-settling agents are broadly divided into two categories: water-insoluble particles and water-soluble polymers. Clays and silicas can be used to formulate scaffolding agents and oil dispersions. Examples of this type of material include, but are not limited to, montmorillonite, bentonite, magnesium aluminum silicate, and attapulgite. Water-soluble polysaccharides have long been used as thickening and gelling agents in aqueous scaffolding agents. The most commonly used polysaccharide types are natural extracts of seeds and seaweeds, or synthetic cellulose derivatives. Examples of this type of material include, but are not limited to, guar gum, locust bean gum, carrageenan, alginate, methylcellulose, sodium carboxymethylcellulose (SCMC), and hydroxyethylcellulose (HEC). Other types of anti-settling agents are based on modified starch, polyacrylates, polyvinyl alcohol, and polyethylene oxide. Another good anti-settling agent is xanthan gum.

[0790] Microorganisms can cause spoilage of formulated products. Therefore, preservatives are used to eliminate or reduce their effectiveness. Examples of such agents include, but are not limited to, propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxybenzoic acid sodium salt, methyl p-hydroxybenzoate, and 1,2-benzisothiazolin-3-one (BIT).

[0791] The presence of surfactants often causes foaming in aqueous formulations during mixing operations during production and application through spray tanks. To reduce foaming tendency, defoamers are often added either during production or before filling into bottles. Generally, there are two types of defoamers: silicone-based and non-silicone-based. Silicone-based defoamers are usually aqueous emulsions of dimethylpolysiloxane, while non-silicone defoamers are water-insoluble oils such as octanol and nonanol, or silica. In either case, the function of the defoamer is to displace surfactants from the air-water interface.

[0792] "Green" agents (e.g., adjuvants, surfactants, solvents) can reduce the overall environmental footprint of crop protection formulations. Green agents are biodegradable and generally derived from natural and / or sustainable sources, such as plant and animal sources. Specific examples are vegetable oils, seed oils, and their esters, as well as alkoxylated alkyl polyglucosides.

[0793] application The molecules of Formula 1 disclosed herein, and combinations thereof, can be applied to any locus, including those where alfalfa, almonds, apples, barley, beans, canola, corn, cotton, crucifers, flowers, forage species (ryegrass, sudangrass, tall fescue, Kentucky bluegrass, and clover), fruits, lettuce, oats, oilseed crops, oranges, peanuts, pears, peppers, potatoes, rice, sorghum, soybeans, strawberries, sugarcane, sugarbeets, sunflowers, tobacco, tomatoes, wheat (e.g., hard red winter wheat, soft red winter wheat, white winter wheat, hard red spring wheat, and durum spring wheat), and other high-value crops are growing or the seeds of which are to be planted.

[0794] The molecules of Formula 1 and combinations thereof disclosed herein can also be applied to growing plants, such as crops, where levels of pests that can commercially harm such plants are low (or even absent). Applying such molecules to such loci can provide benefits to plants growing in such loci. Such benefits can include, but are not limited to, helping plants develop better root systems; helping plants better tolerate stressful growing conditions; improving plant health; improving plant yield (e.g., increased biomass and / or increased content of valuable components); improving plant vigor (e.g., improved plant growth and / or greener leaf color); improving plant quality (e.g., improved content or composition of certain components); and improving plant resistance to abiotic and / or biotic stress.

[0795] The molecules of Formula 1 disclosed herein and combinations thereof can be applied in conjunction with ammonium sulfate during the growth of various plants, as this may provide additional benefits.

[0796] The molecules of Formula 1 disclosed herein and combinations thereof may be applied on, to, or around genetically modified plants to express specialized traits, such as those expressing Bacillus thuringiensis (e.g., Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb, Cry34Ab1 / Cry35Ab1), other insecticidal toxins, or herbicide resistance, or "stacked" with exogenous genes expressing insecticidal toxins, herbicide resistance, nutrient enhancement, or any other beneficial trait.

[0797] The molecules of Formula 1 and combinations thereof disclosed herein can be applied to the foliage and / or fruiting parts of plants for pest control, either by coming into direct contact with the pest or by the pest ingesting the molecule when feeding on the plant or while extracting sap or other nutrients from the plant.

[0798] The molecules of Formula 1 and combinations thereof disclosed herein may also be applied to the soil and, when so applied, may control root- and stem-feeding pests, as the roots may absorb the molecules, thereby incorporating them into the foliage of the plant, thereby controlling above-ground chewing and sap-feeding pests.

[0799] Systemic movement of pesticides in plants can be used to control pests in one part of a plant by applying a molecule of Formula 1 to another part of the plant (e.g., by spraying the locus). For example, control of foliar-feeding insects can be achieved by drip irrigation or furrow application, by treating the soil with a soil drench, for example, before or after planting, or by treating plant seeds before planting.

[0800] The molecules of Formula 1 disclosed herein and combinations thereof can be used with baits. Generally, when used with baits, the baits are placed underground, where, for example, termites can come into contact with and / or be attracted to the bait. The baits can also be applied to building surfaces (horizontal, vertical, or inclined surfaces), where, for example, ants, termites, cockroaches, and flies can come into contact with and / or be attracted to the bait.

[0801] The molecules of Formula 1 and combinations thereof disclosed herein may be encapsulated inside or placed on the surface of capsules, which may range in size from nanometer size (approximately 100-900 nanometers in diameter) to micrometer size (approximately 10-900 microns in diameter).

[0802] The molecules of Formula 1 and combinations thereof disclosed herein may be applied to pest eggs, and repeated applications of such molecules may be desirable to control newly emerged larvae due to the unique ability of some pest eggs to resist certain pesticides.

[0803] The molecules of Formula 1 disclosed herein and combinations thereof can be applied as seed treatments. Seed treatments can be applied to any type of seed, including seeds from which plants genetically modified to express specialized traits will germinate. Representative examples include seeds expressing proteins toxic to invertebrate pests, such as Bacillus thuringiensis or other insecticidal toxins, seeds expressing herbicide resistance, such as "Roundup Ready" seeds, or seeds "stacked" with exogenous genes expressing insecticidal toxins, herbicide resistance, nutrient enhancement, drought tolerance, or any other beneficial trait. Furthermore, such seed treatments of molecules of Formula 1 can further enhance plants' ability to tolerate stressful growing conditions. This can result in healthier, more vigorous plants, which can lead to higher yields at harvest time. Generally, about 1 gram to about 500 grams of such molecules per 100,000 seeds are expected to provide good benefits, with about 10 grams to about 100 grams per 100,000 seeds being expected to provide better benefits, and about 25 grams to about 75 grams per 100,000 seeds being expected to provide even better benefits.

[0804] Component A (the molecule of Formula 1) is present in the seed treatment formulation in an agriculturally effective amount, for example, 1% to about 60% by weight, based on the total weight of the seed treatment mixture. Each compound of component B is present in an agriculturally effective amount of about 1% to about 60% by weight, based on the total weight of the seed treatment mixture. Components A and B can be applied to the seeds sequentially or simultaneously.

[0805] The seed treatment agent may contain two or more active compounds as component B, such as compounds with additional fungicidal, insecticidal, acaricidal, and / or nematicidal properties. As used herein, the term "seed" refers to any dormant stage of a plant that is physically separated from the vegetative state of the plant and / or may be stored for an extended period of time and / or used to regenerate another plant of the same species. The term "dormancy" refers to a state in which a plant retains viability within reasonable limits despite the absence of light, water, and / or nutrients essential for the vegetative (i.e., non-seed) state. In a specific embodiment, this term refers to true seeds.

[0806] The molecules of Formula 1 disclosed herein and combinations thereof may be applied with one or more active ingredients in soil amendments.

[0807] The molecules of formula 1 and combinations thereof disclosed herein can be used in the veterinary sector or in the field of non-human animal husbandry for combating endo- and ectoparasites. Such molecules can be applied by oral administration, for example, in the form of tablets, capsules, drinks, or granules; by dermal application, for example, in the form of baths, sprays, pour-ons, spot applications, and dustings; and by parenteral administration, for example, in the form of injections.

[0808] The molecules of formula 1 and combinations thereof disclosed herein can also be advantageously used in livestock breeding, for example, cattle, chickens, geese, goats, pigs, sheep, and turkeys. They can also be advantageously used in pets, such as horses, dogs, and cats. Specific pests to be controlled would be flies, fleas, and ticks, which are a nuisance to such animals. Suitable formulations are administered orally to animals with drinking water or feed. Suitable dosages and formulations depend on the species.

[0809] The molecules of formula 1 and combinations thereof disclosed herein may also be used to combat helminth parasites, particularly intestinal helminth parasites, in the animals listed above.

[0810] The molecules of Formula 1 and combinations thereof disclosed herein may also be utilized in human medical treatments, including, but not limited to, oral administration in the form of tablets, capsules, drinks, granules, and via dermal application.

[0811] The molecules of Formula 1 and combinations thereof disclosed herein may also be applied to invasive pests. Pests around the world migrate to new environments (for such pests) and then become new invasive species in such new environments. Such molecules can be used against such new invasive species for their control in such new environments.

[0812] The table section follows below. The % increase over expected values ​​in the table below was calculated according to the following formula: ((Actual % control rate of mixture - Predicted % control rate) / Predicted % control rate) x 100 Thus, in some instances, an * indicates that the % increase over expected is too large to be calculated using the above formula (e.g., when expected % control = 0).

[0813] [Table 6]

[0814] [Table 7]

[0815] [Table 8]

[0816] [Table 9]

[0817] [Table 10]

[0818] Table 11

[0819] Table 12

[0820] Table 13

[0821] Table 14

[0822] Table 15

[0823] Table 16

[0824] Table 17

[0825] Table 18

[0826] Table 19

[0827] Table 20

[0828] Table 21

[0829] Table 22

[0830] Table 23

[0831] Table 24

[0832] Table 25

[0833] Table 26

[0834] Table 27

Claims

1. 1. A pesticide composition comprising: (A) A molecule having a structure according to formula 1 【Chemistry 1】 (In the formula, R １ is CF ３ , CHF ２ , C.F. ２ CF ３ , OCF ３ , OCF ２ CF ３ , SF ５ , or SO ２ CF ３ and R ２ is H, F, or CH ３ and R ３ is CH ３ or OCH ３ and R ４ is -CH ２ OCH ２ CH ３ , -CH ２ OCH ２ CF ３ , or -CH ２ OCH ２ CH ２ F); and B) A mixed partner, (1) Members of AIGA; (2) Members of AIGA-1; (3) Members of AIGA-2; (3) AI-1; or (4) AI-2 mixed partners 1. A pesticide composition comprising:

2. 2. The pesticide composition of claim 1, wherein the molecule having a structure according to Formula 1 is F1, F2, F3, F4, F5, F6, F7, F8, F9, F10, F11, F12, F13, F14, F15, or F16.

3. The composition of claim 2 , wherein the molecule is F1.

4. (A) F1; 【Chemistry 2】 B) Abamectin, acephate, acequinocyl, acetamiprid, acrinathrin, acinonapyr, afidopiropen, alanycarb, aldicarb, allethrin, α-cypermethrin, aminopyralid, amitraz, azadirachtin, azamethiphos, azinphos-ethyl, azinphos-methyl, azocyclotine, azoxystrobin, bendiocarb, benfuracarb, bensultap, benzoximate, benzpyrimoxane, β-cyfluthrin, β-cypermethrin, bifenazate, bifenthrin, bioallethrin, bioresmethrin, bist Lifluron, brofuranilide, bromopropylate, buprofezin, butocarboxim, butoxycarboxim, cadusafos, carbaryl, carbofuran, carbosulfan, carboxin, cartap hydrochloride, chinomethionate, chlorantraniliprole, chlordane, chlorethoxyphos, chlorfenapyr, chlorfenvinphos, chlorfluazuron, chlormephos, chlorpyrifos, chlorpyrifos-methyl, chromafenozide, clofentezine, clopyralid, cloquintocet, clothianidin, copper hydroxide, coumaphos, cyanophos, cyanophos Antraniliprole, cyclaniliprole, cyclobutrifluram, cycloprothrin, cycloxapride, cyenopyrafen, cyflumetofen, cyfluthrin, cyhalothrin, cyhexatin, cymoxanil, cypermethrin, cyphenothrin, cyprofuranilide, cyromazine, d-cis-trans allethrin, DDVP, deltamethrin, demeton-S-methyl, diafenthiuron, diazinon, dichlorvos, dicofol, dicrotophos, difenoconazole, diflobidazin, diflubenzuron, dimethoate, dimethylvinphos, gin Propyridaz, dinotefuran, disulfoton, DNOC, d-trans allethrin, emamectin, emamectin benzoate, empenthrin, endosulfan, EPN, esfenvalerate, ethaboxam, ethiofencarb, ethion, ethiprole, ethoprophos, etofenprox, famoxadone, famfur, fenamiphos, fenazaquin, fenbuconazole, fenbutatin oxide, fenitrothion, phenmezodithiaz, fenobucarb, fenoxycarb, fenpropathrin, fenpyroximate, fenthion,Fenvalerate, fipronil, flazasulfuron, flonicamid, florasulam, fluacrypyrim, fluazaindolizine, flubendiamide, flucycloxuron, flucythrinate, fludioxonil, fluensulfone, flufenoxuron, flumethrin, flumioxazin, fluopyram, fluoxapiprolin, fluoxastrobin, flupyradifuron, flupirimin, fluroxypyr, fluxamethamide, fluxapyroxad, formetanate, fosthiazate, furathiocarb, gamma-cyhalothrin, glyphosate, halaxix Fen, halfenprox, halofenozide, heptenophos, hexaflumuron, hexythiazox, hydramethylnon, hydroprene, imazamox, imazapyr, imiciafos, imidacloprid, imiprothrin, indazapiroxameth, indoxacarb, inpirfluxam, ipconazole, isocycloceram, isofenphos, isoflucipram, isoprocarb, isoxathion, kadethrin, kinoprene, lambda-cyhalothrin, lepimectin, lufenuron, malathion, mancozeb, MCPA, mecarbam, mefenoxam, Metaflumizone, metalaxyl, metconazole, methamidophos, methenamine, methidathion, methiocarb, methomyl, methoprene, methoxychlor, methoxyfenozide, metolcarb, metsulfuron, mevinphos, milbemectin, monocrotophos, myclobutanil, naled, nicosulfuron, nitrapyrin, novaluron, noviflumuron, omethoate, oxamyl, oxathiapiprolin, oxazosulfil, oxydemeton methyl, parathion, parathion methyl, penflufen, penthiopyrad, permethrin, fenothrin, Phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, picarbutrazox, picloram, picoxystrobin, pinoxaden, pirimicarb, pirimiphos-methyl, prallethrin, profenofos, propargite, propetamphos, propiconazole, propoxur, propyzamide, prothioconazole, prothiofos, spiflumetofen, piflubumid, pymetrozine, pyraclofos, pyraclostrobin, pyrethrum, pyridaben, pyridalyl, pyridaphenthion, pyrifluquinazon,Pyrimidifen, pyriproxyfen, pyroxasulfone, quinalphos, resmethrin, rimsulfuron, rotenone, sedaxane, silafluofen, spidoxamat, spinetoram, spinosad, spirobudifen, spirodiclofen, spiromesifen, spiropidione, spirotetramat, sulfuramide, sulfotep, sulfoxaflor, taufluvalinate, tebuconazole, tebufenozide, tebufenpyrad, tebupirimfos, teflubenzuron, tefluthrin, temephos, terbufos, tetrachlorvinphos, tetradifon, tetramethrin, tetraniliprole, θ mixing partners selected from the group consisting of cypermethrin, thiabendazole, thiamethoxam, thiocyclam, thiodicarb, thiofanox, thiometon, thiosultap sodium, thiram, thiolantraniliprole, thioxazaphen, tolfenpyrad, tralkoxydim, tralomethrin, transfluthrin, triazamate, triazophos, trichlorfon, triclopyr, trifloxystrobin, triflumezopyrim, triflumuron, trimethacarb, vamidothion, XMC, xylylcarb, zeta-cypermethrin, AI-1, AI-2 and 2,4-D; The composition of claim 3 comprising:

5. 2. The pesticide composition of claim 1, wherein the mixing partner is selected from the group consisting of abamectin, acetamiprid, benzpyrimoxan, bifenthrin, chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyclobutrifluram, dimepropylidaz, fipronil, flonicamid, fluoxapiprolin, flupyradifurone, flupirimine, fluxamethamide, imidacloprid, indoxacarb, isocycloceram, lambda-cyhalothrin, methoxyfenozide, pymetrozine, pyriproxyfen, spidoxamat, spinetoram, spinosad, spiropydione, spirotetramat, sulfoxaflor, thiamethoxam, and triflumezopyrim.

6. The mixing partners may be azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxapyroxad, inpirfluxam, ipconazole, isoflucipram, mefenoxam, mefentrifluconazole, metalaxyl, myclobutanil, oxathiapiprolin, picoxystrobin, propiconazole, prothioconazole, pydiflumetofen, pyraclostrobin, sedaxane, tebuconazole, thiabendazole ru, thiram, titriconazole, trifloxystrobin, abamectin, acetamiprid, afidopiropen, AI-1, AI-2, benzpyrimoxan, bifenthrin, brofuranilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, fluazaindolizine, fluensulfone, flupyradifurone, flupirimine, fluxamethamide, heat-killed Burkholderia species spp. strain A396, imidacloprid, indoxacarb, λ-cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramet, sulfoxaflor, tetraniliprole, thiamethoxam, and triflumezopyrim.

7. 6. The pesticide composition according to claim 5, wherein the mixing partners are selected from the group consisting of azoxystrobin, copper hydroxide, difenoconazole, ethaboxam, fludioxonil, fluopyram, fluoxastrobin, fluxapyroxad, impilfluxam, ipconazole, isoflucipram, mefenoxam, mefentrifluconazole, metalaxyl, myclobutanil, oxathiapiprolin, picoxystrobin, propiconazole, prothioconazole, pydiflumetofen, pyraclostrobin, sedaxane, tebuconazole, thiabendazole, thiram, titriconazole and trifloxystrobin.

8. The mixing partners may be abamectin, acetamiprid, afidopiropen, AI-1, AI-2, benzpyrimoxan, bifenthrin, brofuranilide, chlorantraniliprole, chlorfenapyr, clothianidin, cyantraniliprole, deltamethrin, dinotefuran, fipronil, flonicamid, fluazaindolizine, fluensulfone, flupyradifurone, flupirimine, fluxamethamide, heat-killed Burkholderia spp. spp. strain A396, imidacloprid, indoxacarb, λ-cyhalothrin, methoxyfenozide, oxamyl, pyriproxyfen, spinosad, spinetoram, spiromesifen, spirotetramet, sulfoxaflor, tetraniliprole, thiamethoxam, and triflumezopyrim.

9. the ratio of F1 to said mixing partner B) is 1:160,000-160,000:1, 1:80,000-80,000:1, 1:40,000-40,000:1, 1:20,000-20,000:1, 1:10,000-10,000:1, 1:8000-8000:1, 1:5000-5000:1, 9. The pesticide composition according to any one of claims 1 to 8, wherein the pesticide composition is selected from 1:2000 to 2000:1, 1:1000 to 1000:1, 1:500 to 500:1, 1:250 to 250:1, 1:100 to 100:1; 1:50 to 50:1, 1:25 to 25:1, 1:10 to 10:1, 1:5 to 5:1, and 1:

1.

10. A method for controlling pests that attack plants, plant reproductive parts, or plant habitats, the method comprising the step of contacting the plants, plant reproductive parts, or plant habitats with a composition according to any one of claims 1 to 8.

11. 9. A method for controlling pests that attack plants, plant reproductive parts or plant habitats, the method comprising the step of contacting the pests or their habitats, food supply, breeding grounds or growing areas with a composition according to any one of claims 1 to 8.

12. A method for treating seeds, comprising the step of contacting said seeds with a composition according to any one of claims 1 to 5.

13. Seeds treated with a composition according to any one of claims 1 to 8.

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