Liquid herbicide composition

Abstract

This invention provides a liquid pesticide composition, a process for preparing a liquid pesticide composition, the use of a liquid pesticide composition for weed control, and a method for weed control using a liquid pesticide composition. [Solution] A liquid pesticide composition comprising a) an electrolytic pesticide, b) a non-hydrotropic phosphorus derivative, c) a surfactant, and d) an electrolyte that is not a surfactant.

Description

[Technical Field]

[0001] This disclosure relates to a liquid pesticide composition containing an electrolytic pesticide as an active ingredient, a process for preparing the liquid pesticide composition, and a method for controlling weeds using the liquid pesticide composition. [Background technology]

[0002] Water-soluble herbicides used as non-selective foliar herbicides are widely used and effective crop protectants. For example, U.S. Patent No. 4,168,963 discloses 2-amino-4-[hydroxy(methyl)phosphinoyl]butyric acid (glufosinate). Salts and isomers of glufosinate have good and broad activity against weeds of many plant species. Glufosinate is a non-selective contact herbicide with several systemic effects. When glufosinate is applied to weeds, glutamine levels in the weed tissue decrease, ammonia levels increase, photosynthesis stops, and the weed plants die.

[0003] The L-enantiomer of glufosinate is considered a biologically active isomer. The herbicidal activity of the L-isomer is twice that of the racemic mixture, and the use of the L-isomer offers clear advantages such as reduced application rates and fewer side effects.

[0004] Glufosinate is used to control persistent weeds such as morning glory, hemlock sesbania (Sesbania bispinosa), Pennsylvania smartweed (Polygonum pensylvanicum), and yellow nut edulis.

[0005] Glufosinate is most frequently used as a directional spray for weed control in crops, including genetically modified crops, and as a crop desiccant to facilitate harvesting.

[0006] In the case of water-soluble herbicides such as glufosinate, the properties and amount of adjuvants mixed with glufosinate can affect the activity of the mixture.

[0007] For example, there is still a need to find a suitable adjuvant that effectively enhances the performance of a pesticide composition containing glufosinate and / or L-glufosinate.

[0008] Object of the present disclosure An object of the present disclosure is to provide a highly effective liquid pesticide composition.

[0009] Yet another object of the present disclosure is to provide a highly effective liquid pesticide composition having a specific dynamic surface tension (DST).

[0010] Yet another object of the present disclosure is to provide the use of an effective liquid pesticide composition having a specific DST for weed control.

[0011] Yet another object of the present disclosure is to provide a method for controlling weeds using a liquid pesticide composition. Summary of the Invention

[0012] The present disclosure provides a) an electrolytic pesticide; b) a non-hydrotropic phosphorus derivative; c) at least one surfactant; d) an electrolyte that is not a surfactant; and provides a liquid pesticide composition comprising the same.

[0013] The present disclosure provides a) an electrolytic pesticide; b) a non-hydrotropic phosphorus derivative; c) at least one surfactant; d) an electrolyte that is not a surfactant; and provides a liquid pesticide composition comprising the same, which is diluted in a spray solution and the spray dilution of the liquid pesticide composition has a dynamic surface tension of less than 60 mN / m with a surface lifetime of 20 to 50 milliseconds.

[0014] This disclosure relates to a process for preparing a disclosed liquid pesticide composition, To obtain a dispersion by combining an electrolytic pesticide, a solvent, and optionally an excipient, and A liquid pesticide composition is obtained by combining a non-hydrotropic phosphorus derivative, a surfactant, a non-surfactant electrolyte, and water in the above dispersion. It provides a process that includes this.

[0015] This disclosure relates to the use of a liquid pesticide composition for controlling weeds, wherein the liquid pesticide composition is a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) at least one surfactant, d) Electrolytes that are not surfactants, It provides usage, including

[0016] This disclosure provides a method for controlling weeds, comprising applying an effective amount of the disclosed liquid pesticide composition to plants or to the growing area or planned growing area of ​​plants. [Modes for carrying out the invention]

[0017] In the following detailed description, please understand that this disclosure may be subject to various alternative modifications (unless expressly otherwise provided). Furthermore, unless otherwise stated, except in any example of operation, all numbers representing quantities of materials / components used herein should be understood in all cases as being modified by the term “approximately”.

[0018] Unless otherwise defined, all technical and scientific terms used herein have the same meanings as those generally understood by those skilled in the art in which this disclosure pertains. In case of any conflict, the definitions in this document shall prevail.

[0019] Unless otherwise indicated herein, the enumeration of value ranges is intended merely as a simplified way of referring individually to each distinct value that falls within that range, and each distinct value is incorporated herein as if it were individually enumerated herein. The endpoints of all ranges are contained within that range and can be combined independently. Where used herein, all numbers or numerical ranges include integers within such range and their fractional parts, or integers within such range, unless the context clearly indicates otherwise. Thus, for example, a reference to the range 90–100% includes 91%, 92%, 93%, 94%, 95%, 95%, 97%, etc., as well as 91.1%, 91.2%, 91.3%, 91.4%, 91.5%, etc., 92.1%, 92.2%, 92.3%, 92.4%, 92.5%, etc. All methods described herein may be performed in an appropriate order, unless otherwise indicated herein or unless it is clearly inconsistent with the context.

[0020] Where used herein, “a,” “an,” “the,” and “at least one” are intended to encompass both singular and plural, without implying a limitation of quantity unless the context clearly indicates otherwise. For example, “element” is synonymous with “at least one element” unless the context clearly indicates otherwise. Where used herein, terms such as “first,” “second,” etc., do not imply a specific order, but simply mean, for convenience, multiple, e.g., layers. Where used herein, terms such as “comprising,” “including,” “having,” “containing,” and “involving” should be understood as non-restrictive unless otherwise specified; that is, “including” should be understood as meaning not limited to. Where used herein, “about” or “approximately” means including the stated value and being within the range of acceptable deviations of a particular value as determined by a person skilled in the art, taking into account the measurement in question and the error associated with the measurement of a particular quantity (i.e., the limits of the measurement system). For example, “about” may mean within one or more standard deviations, or within ±10% or ±5% of the stated value. The use of any and all examples or illustrative language (e.g., "etc.") is intended solely to better illustrate the invention and, unless otherwise claimed, does not limit the scope of the invention. Nothing in this specification should be construed as indicating an unclaimed element essential to the practice of the invention as used herein.

[0021] In any aspect or embodiment described below in this specification, the phrase "includes," "consists of," "essentially consists of," or "substantially consists of." In these aspects or embodiments, the compositions described contain or have, or consist of, essentially consist of, or substantially consist of, the specific components listed therein, excluding other components or excipients not specifically listed therein.

[0022] While the present invention has been described with reference to exemplary embodiments, those skilled in the art will understand that various modifications can be made without departing from the scope of the invention, and that equivalents can be used in place of certain elements. In addition, many modifications can be made without departing from the essential scope of the invention to adapt the teachings of the invention to specific situations or materials. Thus, the present invention is not limited to the specific embodiments disclosed as the best mode intended for carrying out the invention, but is intended to include all embodiments that fall within the scope of the appended claims. Any combination of the elements described above in all possible variations is incorporated into the invention unless otherwise specifically indicated herein or unless it is clearly inconsistent with the context.

[0023] "Alkyl" refers to a linear or branched saturated aliphatic hydrocarbon having a specified number of carbon atoms, specifically 1 to 12 carbon atoms, and more specifically 1 to 6 carbon atoms. Alkyl groups include, for example, groups having 1 to 50 carbon atoms (C1 to C50 alkyl groups).

[0024] "Aryl" means a cyclic moiety in which all ring members are carbon and at least one ring is aromatic, having a specified number of carbon atoms, specifically 6 to 24 carbon atoms, more specifically 6 to 12 carbon atoms. There may be two or more rings, and any additional rings may independently be aromatic, saturated or partially unsaturated, and may be condensed, pendanted, spirocyclic, or a combination thereof.

[0025] "Alkylene" refers to a straight-chain or branched-chain saturated divalent aliphatic hydrocarbon group (e.g., methylene (-CH2-) or propylene (-(CH2)3-)).

[0026] When used throughout this disclosure, electrolytic pesticides or other active ingredients include their salts, esters, ethers, isomers, and polymorphs such as solvates and hydrates. Salts include salts that retain the biological efficacy and properties of the active ingredient and are not biologically or otherwise undesirable, and include derivatives of disclosed compounds in which the parent compound is modified to produce its inorganic and organic non-toxic acid or base addition salts. Salts can be synthesized from parent compounds by conventional chemical methods. "Solvate" means a herbicide or an agriculturally acceptable salt thereof in which molecules of a suitable solvent are incorporated into the crystal lattice. A suitable solvent is one that is physiologically acceptable at the dose administered. Examples of suitable solvents include ethanol and water. When water is the solvent, its molecules are referred to as a "hydrate." The formation of solvates varies depending on the compound and the solvate. Generally, solvates are formed by dissolving the compound in a suitable solvent and then cooling or isolating the solvate using a poor solvent. Solvates are typically dried or azeotropic under ambient conditions. In one embodiment, the solvate is a hydrate.

[0027] The term "plant" refers to all physical parts of a plant, including seeds, seedlings, young trees, roots, tubers, stems, stalks, branches, leaves, and fruits. The term "plant" includes both transgenic and non-transgenic plants.

[0028] As used herein, the term “habitat” means the place where a plant grows, where plant propagation material for a plant is planted (e.g., placed in the soil), and / or where plant propagation material for a plant is intended to be planted, its vicinity, or an area of ​​land.

[0029] The term "plant propagation material" refers to the reproductive parts of plants (e.g., seeds), plant materials (e.g., cuttings or tubers), roots, fruits, tubers, bulbs, rhizomes, and other parts of plants, germinating plants, and / or seedlings that are transplanted after germination or emergence from the soil. These seedlings may be protected before transplanting by a full immersion treatment / system or a partial immersion treatment / system.

[0030] As used herein, “effective amount” is the amount of an active ingredient (e.g., a disclosed combination) that has a harmful effect on weeds and / or controls weeds in plants. Harmful effects may include weed death (herbicide), prevention of weed growth, blockage of biosynthetic pathways, or a combination thereof.

[0031] As used herein, “agriculturally permissible salt” means salt that is permitted for use in agriculture or horticulture.

[0032] As used herein, the term “electrolytic pesticide” means a pesticide that forms ions when dissolved in water at 20°C. The term “pesticide” refers to an active ingredient that can kill, repel, or inhibit the growth or reproduction of undesirable organisms ("harmful organisms"), or that can protect or promote the healthy growth or reproduction of desirable organisms such as plants (e.g., crops, ornamental plants), and can be used for application to fields, crops, orchards, gardens, forestry, shrublands, parks, industrial parks, construction sites, airports, roads, railways, rivers, lakes, ponds, canals, irrigation and drainage projects. An electrolytic pesticide may be a pesticide, such as a herbicide, fungicide, or insecticide. In this disclosure, an electrolytic pesticide is a herbicide.

[0033] Glufosinate has the chemical name 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid. L-glufosinate, also commercially known as glufosinate-P, is an isomer of glufosinate.

[0034] Surprisingly and unexpectedly, a liquid composition comprising an electrolytic pesticide, a non-hydrotropic phosphorus derivative, a surfactant, and a non-surfactant electrolyte was found to yield a composition with the best dynamic surface tension profile and a highly bioactive formulation. Furthermore, a liquid composition comprising an electrolytic pesticide, a non-hydrotropic phosphorus derivative, a surfactant, and a non-surfactant electrolyte was found to pin droplets of the formulation to the plant surface, preventing them from bouncing off and / or rolling off. As used herein, droplet "pinning" involves retaining at least a portion or substantially all of the liquid present in the droplet on the plant surface for a period sufficient to provide the effectiveness of the pesticide (herbicide) present in the formulation.

[0035] Aqueous formulations of water-soluble herbicides such as glufosinate tend to be washed away by rain or may not remain on the leaf surface for a long enough period to be absorbed by plants. For effectiveness, pinning the formulation droplets to the plant surface is crucial to ensure that contact occurs between the herbicide and the plant for a sufficient period to promote wetting and spreading of the droplets on the leaf surface, thereby facilitating the penetration and transfer of the herbicide into the leaves.

[0036] The action of surfactants is a result of their partially hydrophilic and partially hydrophobic nature, which allows them to adsorb to interfaces separating media of different polarities. For example, a liquid film is generally intended to spread across a solid surface or another liquid surface, and this action is generally called "wetting." This occurs spontaneously when the liquid film or droplet has a lower surface tension than the surface it covers. Therefore, by reducing surface tension, surfactants promote wetting.

[0037] Dynamic surface tension (DST) directly affects the quality of wetting, spreading, and adhesion of components to plant surfaces. Dynamic surface tension correlates considerably with the dynamic wetting conditions of plant surfaces in real-world spray environments. The concentration and activity of surfactants are determined not only by how much surface tension decreases, but also by the rate at which diffusion occurs and how quickly wetting occurs. Formulators can improve the movement, wetting, diffusion, and adhesion of formulations by determining the optimal surfactant concentration through the determination of the dynamic critical micelle concentration (CMC), and by selecting a combination of surfactants and additives that provides the best dynamic surface tension profile for their specific applications.

[0038] Surface wetting occurs on a timescale of milliseconds; therefore, the adsorption kinetics of surfactant molecules to plant surfaces are crucial when selecting a combination of surfactants and additives. Contact angle measurement or contact angle hysteresis is another important tool for understanding the effect of surfactants on the surface tension properties of the formulation, as well as on the diffusion and adhesion properties required for the active ingredients. It further predicts the optimal droplet deposition pattern of the formulation on the leaf surface necessary to produce a uniform distribution of the active ingredients, resulting in better performance.

[0039] It was advantageously discovered that highly effective formulations can be achieved when the combination of surfactants and additives, and the final formulation thereof, result in a spray solution having a specific range of DST.

[0040] The inventors have found that a combination of a specific surfactant that yields the formulation and a spray solution having the best dynamic surface tension profile improves wetting of the plant surface, ensuring that the active substance adheres to the plant surface for a longer period and / or is better taken up by the plant, resulting in a highly effective product.

[0041] In relation to this disclosure, the terms “composition” and “formulation” are used interchangeably.

[0042] The advantages and novel features of this disclosure will become apparent from the following detailed description of various non-limiting embodiments of this disclosure, when considered in conjunction with the attached examples.

[0043] Therefore, this disclosure is, a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) at least one surfactant, d) Electrolytes that are not surfactants, The present invention provides a liquid pesticide composition containing the following:

[0044] In one embodiment, the liquid pesticide composition comprises one or more additional active ingredients.

[0045] In one embodiment, the non-hydrotropic phosphorus derivative is a compound composed of a hydrophilic moiety and a hydrophobic moiety, wherein the hydrophobic moiety is large enough to spontaneously aggregate into micelles or other aggregates. In one embodiment, the non-hydrotropic phosphorus derivative has a hydrophobic moiety of C8-C 20 Contains alkyl groups.

[0046] In one embodiment, the non-hydrotropic phosphorus derivative is a compound that can solubilize hydrophobic compounds in aqueous solution by micelle solubilization.

[0047] In one embodiment, the non-hydrotropic phosphorus derivative is a compound having a specific critical micelle concentration. The critical micelle concentration (CMC) is defined as the concentration above which micelle formation of the non-hydrotropic phosphorus derivative occurs spontaneously, and above which all additional surfactants present in the system also form micelles.

[0048] In this disclosure, the terms dynamic surface tension (DST) or interfacial tension (IFT) refer to a specific surface lifetime or interfacial lifetime value. Surface lifetime is the period from the start of surface formation to the time of observation or measurement. Interfacial lifetime is the period from the start of interface formation to the time of observation or measurement. The time-dependent value is called dynamic surface tension (DST). In the case of liquids containing surfactants, DST differs from static measurements and measurements of equilibrium surface tension values, which are non-time-dependent.

[0049] In this disclosure, the terms “surface life,” “interface life,” and “bubble life” are used interchangeably. Dynamic surface tension (DST) is expressed as force per unit width, specifically as millinewtons per meter (mN / m).

[0050] In one embodiment, the dynamic surface tension is measured over a surface lifetime range of 10 to 200 milliseconds, or over a range of 10 to 100 milliseconds, or over a range of 20 to 50 milliseconds.

[0051] In one embodiment, the dynamic surface tension is measured over a surface lifetime range of 10 to 100 milliseconds.

[0052] In one embodiment, dynamic surface tension is measured over a surface lifetime range of 20 to 50 milliseconds.

[0053] In one embodiment, the active ingredient of the electrolytic pesticide exists in an aqueous solution in a neutralized form.

[0054] In one embodiment, the active ingredient of the electrolytic pesticide exists in salt form.

[0055] In one embodiment, the active ingredient of an electrolytic pesticide in salt form is obtained by neutralization of the acid form and subsequent conversion to the salt form.

[0056] In one embodiment, the active ingredient of the electrolytic pesticide is a water-soluble salt of glufosinate, its isomers, or a combination thereof.

[0057] In one embodiment, the active ingredient of the electrolytic pesticide is an optically active isomer of glufosinate (hereinafter referred to as L-glufosinate) or its water-soluble salt, or a combination thereof.

[0058] In one embodiment of the present disclosure, the active ingredient of the electrolytic pesticide comprises a water-soluble salt of glufosinate, which may be a hydrochloride salt, monosodium salt, disodium salt, monopotassium salt, dipotassium salt, monocalcium salt, ammonium salt, NH3(CH3)+ salt, or NH2(CH3)2 + This includes salts, NH(CH3)3+ salts, NH(CH3)2(C2H4OH)+ salts, NH2(CH3)(C2H4OH)+ salts, or combinations thereof.

[0059] In one embodiment, the active ingredient of the electrolytic pesticide is the water-soluble sodium salt and / or water-soluble ammonium salt of glufosinate. In another embodiment, the active ingredient of the electrolytic pesticide is glufosinate sodium, glufosinate ammonium, or a combination thereof.

[0060] In one embodiment of the present disclosure, the active ingredient of the electrolytic pesticide comprises a water-soluble salt of L-glufosinate, which may be a hydrochloride salt, monosodium salt, disodium salt, monopotassium salt, dipotassium salt, monocalcium salt, ammonium salt, or NH3(CH3) + Salt, NH2(CH3)2 + Salt, -NH(CH3)3 + Salt, NH(CH3)2(C2H4OH) + Salt, -NH2(CH3)(C2H4OH) + Contains salt, or a combination thereof.

[0061] In one embodiment of the present disclosure, the electrolytic pesticide active ingredient comprises a water-soluble sodium salt and / or water-soluble ammonium salt of L-glufosinate. In one embodiment, the electrolytic pesticide active ingredient is L-glufosinate sodium, L-glufosinate ammonium, or a combination thereof.

[0062] In one embodiment, the liquid pesticide composition contains, based on the total weight of the liquid pesticide composition, about 0.1% to about 99% by weight of a water-soluble salt or isomer thereof of glufosinate.

[0063] In one embodiment, the liquid pesticide composition contains about 1 to about 50% by weight of glufosinate or its isomers, based on the total weight of the liquid pesticide composition.

[0064] In one embodiment, the liquid pesticide composition contains about 5 to about 40% by weight of a water-soluble salt or isomer of glufosinate, based on the total weight of the liquid pesticide composition.

[0065] In one embodiment, the liquid pesticide composition contains about 10 to about 30% by weight of a water-soluble salt or isomer of glufosinate, based on the total weight of the liquid pesticide composition.

[0066] In one embodiment, this disclosure, a) Neutralized form of electrolytic pesticide, b) C8~C 20 Non-hydrotropic phosphorus derivatives containing alkyl groups, c) Surfactants and, d) Electrolytes that are not surfactants, The present invention provides a liquid pesticide composition containing the following:

[0067] In one embodiment, the active ingredient of the electrolytic pesticide is a salt of glufosinate, its isomers, or a combination thereof.

[0068] In one embodiment, the electrolytic pesticide is glufosinate ammonium.

[0069] In one embodiment, the liquid pesticide composition is diluted in a spray solution containing an agriculturally effective amount of electrolytic pesticide per liter of spray solution.

[0070] In one embodiment, the liquid pesticide composition is diluted to a spray solution containing an agriculturally effective amount of glufosinate per liter of spray solution.

[0071] In one embodiment, the spray dilution of the liquid pesticide composition during spray dilution has a surface lifetime of 20 to 50 milliseconds, i.e., a dynamic surface tension (DST) of less than 60 mN / m at each time over the range from 20 to 50 milliseconds.

[0072] In one embodiment, the liquid pesticide composition is diluted into a spray solution containing from about 0.1 g to about 10 g of an electrolytic pesticide per liter of the spray solution. In one embodiment, the electrolytic pesticide is a water-soluble salt of glufosinate or an isomer thereof or a combination thereof.

[0073] In one embodiment, the liquid pesticide composition is diluted into a spray solution containing from about 0.1 g to about 5 g of an electrolytic pesticide per liter of the spray solution. In one embodiment, the electrolytic pesticide is a water-soluble salt of glufosinate or an isomer thereof or a combination thereof.

[0074] In one embodiment, the liquid pesticide composition is diluted into a spray solution using a solvent, preferably water.

[0075] In one embodiment, the present disclosure a) l-glufosinate ammonium, l-glufosinate sodium or a combination thereof, and b) a non-hydrotropic phosphorus derivative containing a C8-C 20 alkyl group, and c) a surfactant, and d) an electrolyte that is not a surfactant, and provides a liquid pesticide composition in which the spray dilution of the liquid pesticide composition during spray dilution has a DST of less than 60 mN / m with a surface lifetime of 20 to 50 milliseconds.

[0076] In one embodiment, the liquid pesticide composition is diluted into a spray solution containing an agronomically effective amount of L-glufosinate per liter of the spray solution.

[0077] ​In one embodiment, the liquid pesticide composition is diluted in a spray solution containing about 0.1 g to about 10 g of L-glufosinate per liter of spray solution.

[0078] In one embodiment, the liquid pesticide composition is diluted in a spray solution containing about 0.1 g to about 2.5 g of L-glufosinate per liter of spray solution.

[0079] In one embodiment, the composition is diluted to a spray solution using a solvent, preferably water.

[0080] In one embodiment, the non-hydrotropic phosphorus derivative is C8-C8, where the degree of alkoxylation is in the range of about 3 to about 15 moles per mole of alcohol. 20 It is a fatty alcohol alkoxylate phosphate.

[0081] In one embodiment, the non-hydrotropic phosphorus derivative is C8-C 20 It is a fatty alcohol ethoxylate phosphate, and in this specification, interchangeably C8-C 20 Also known as fatty alcohol alkyl ether phosphate derivatives.

[0082] In one embodiment, the non-hydrotropic phosphorus derivative is a tridecyl alcohol ethoxylate phosphate ester, a polyethylene glycol monotridecyl ether phosphate, or a combination thereof.

[0083] In one embodiment, the composition contains a non-hydrotropic phosphorus derivative in an amount of about 0.1% to about 30% by weight, based on the total weight of the liquid pesticide composition.

[0084] In one embodiment, the composition contains a non-hydrotropic phosphorus derivative in an amount of about 5% to about 25% by weight, based on the total weight of the liquid pesticide composition.

[0085] In one embodiment, the composition contains a non-hydrotropic phosphorus derivative in an amount of about 10% to about 20% by weight, based on the total weight of the liquid pesticide composition.

[0086] In one embodiment, the composition according to the present disclosure comprises at least one surfactant. As disclosed in U.S. Patent No. 6,642,177, glufosinate is generally formulated with a high concentration of surfactant, for example, about 110 parts of surfactant (such as taloamine ethoxylate) per 100 parts of glufosinate active ingredient. However, in the compositions according to the present disclosure, the amount of surfactant is substantially reduced.

[0087] In one embodiment, the composition contains a surfactant in an amount ranging from about 0.1% to about 50% by weight, based on the total weight of the liquid pesticide composition.

[0088] In one embodiment, the composition contains a surfactant in an amount of about 1% to about 40% by weight, based on the total weight of the liquid pesticide composition.

[0089] In one embodiment, the composition contains a surfactant in an amount of about 5% to about 30% by weight, based on the total weight of the liquid pesticide composition.

[0090] In one embodiment, the surfactant is C8~C 15 Alkyl polyglycosides, N-alkyl glucamides, C8-C 20 This includes alkyldimethylamine N-oxides, or combinations thereof.

[0091] In one embodiment, the surfactant has an average degree of polymerization of 1 to 3 C8-C 15 It is an alkyl polyglycoside.

[0092] In one embodiment, the surfactant has an average degree of polymerization of 1 to 2 C8-C 11 It is an alkyl polyglycoside.

[0093] In one embodiment, the composition contains C8-C in an amount of about 0.1% to about 30% by weight of the composition. 15 Contains alkyl polyglycosides.

[0094] In one embodiment, N-alkylglucamide is D-glucitol, 1-deoxy-1-(C1~C5 alkyl-amino)-N-(C5~C 10 It is an acyl derivative.

[0095] In one embodiment, N-alkylglucamide is D-glucitol, 1-deoxy-1-(C1~C3 alkyl-amino)-N-(C8~C 10 It is an acyl derivative.

[0096] In one embodiment, the composition contains N-alkylglucamide in an amount ranging from about 0.1% to about 30% by weight, based on the total weight of the liquid pesticide composition.

[0097] In one embodiment, the composition contains N-alkylglucamide in an amount of about 1% to about 25% by weight, based on the total weight of the liquid pesticide composition.

[0098] In one embodiment, the composition contains N-alkylglucamide in an amount of about 2% to about 20% by weight, based on the total weight of the liquid pesticide composition.

[0099] In one embodiment, the surfactant is an amine oxide with at least one C8-C nitrogen atom. 20 C8~C substituted with long-chain aliphatic groups 20 It is an alkyldimethylamine N-oxide. C8~C 20 Examples of alkyldimethylamine N-oxides include decyl, dodecyl, tetradecyl, pentadecyl, hexadecyl, and octadecyldimethylamine N-oxides.

[0100] In one embodiment, the composition contains C8-C in an amount of about 0.1% to about 50% by weight of the composition. 20 Contains alkyldimethylamine N-oxide.

[0101] In one embodiment, the composition contains an amount of C8 to C8 in an amount of about 5% to about 45% by weight of the composition. 20 Contains alkyldimethylamine N-oxide.

[0102] In one embodiment, the composition contains about 10% to about 30% by weight of C8-C based on the weight of the composition. 20 Contains alkyldimethylamine N-oxide.

[0103] In one embodiment, the liquid pesticide composition contains an electrolyte, and the electrolyte is not a surfactant.

[0104] In one embodiment, the electrolyte includes an inorganic salt of an alkali metal or alkaline earth metal.

[0105] In one embodiment, the inorganic salt of an alkali metal salt or alkaline earth metal salt includes magnesium chloride, magnesium sulfate, potassium chloride, potassium sulfate, potassium carbonate, sodium chloride, sodium carbonate, sodium chlorate, sodium nitrate, sodium sulfate, calcium chloride, calcium carbonate, calcium nitrate, or a combination thereof.

[0106] In one embodiment, the liquid pesticide composition contains an electrolyte in an amount of about 0.1% to about 20% by weight, based on the total weight of the liquid pesticide composition.

[0107] In one embodiment, the liquid pesticide composition contains an electrolyte in an amount of about 0.1% to about 10% by weight, based on the total weight of the liquid pesticide composition.

[0108] In one embodiment, the liquid pesticide composition contains an electrolyte in an amount of about 0.2 to about 2% by weight, based on the total weight of the liquid pesticide composition.

[0109] In one embodiment, this disclosure, a) Glufosinate salt, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) Surfactants and, d) Alkali metal salts, The present invention provides a liquid pesticide composition containing the following:

[0110] In one embodiment, this disclosure, a) Glufosinate salt, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) Surfactants and, d) containing alkali metal salts, The present invention provides a liquid pesticide composition in which the spray dilution of the liquid pesticide composition, when spray-diluted, has a dynamic surface tension of less than 60 mN / m with a surface life of 20 to 50 milliseconds.

[0111] In one embodiment, the liquid pesticide composition is a) Glufosinate ammonium and, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c)C8~C 10 Alkyl polyglycosides and d) Contains potassium chloride, The spray dilution of the composition has a dynamic surface tension of less than 60 mN / m during a surface life of 20 to 50 milliseconds.

[0112] In one embodiment, the liquid pesticide composition is a) l-glufosinate salt, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) at least one surfactant, d) containing alkali metal salts.

[0113] In one embodiment, the liquid pesticide composition is a) l-glufosinate salt, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) at least one surfactant, d) containing alkali metal salts, The spray dilution of the liquid pesticide composition has a dynamic surface tension of less than 60 mN / m with a surface life of 20 to 50 milliseconds.

[0114] In one embodiment, the liquid pesticide composition is a) Sodium l-glufosinate, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) D-glucitol 1-deoxy-1-(C1~C3 alkyl-amino)-N-(C8~C 10 ) Acyl derivatives, d) containing potassium sulfate, The spray dilution of the liquid pesticide composition has a dynamic surface tension of less than 60 mN / m with a surface life of 20 to 50 milliseconds.

[0115] In one embodiment, the liquid pesticide composition is a) l-glufosinate ammonium and, b) Non-hydrotropic C8~C 20 Fatty alcohol alkoxylate phosphate and c) Decylamine oxide and, d) Contains magnesium chloride, When spray-diluted, the spray dilution of the liquid pesticide composition has a dynamic surface tension of less than 60 mN / m during a surface life of 20 to 50 milliseconds.

[0116] In one embodiment, the liquid pesticide composition further comprises at least one solvent.

[0117] In one embodiment, the solvent is selected from, but is not limited to, water-miscible polar / nonpolar solvents or water-immiscible polar / nonpolar solvents. For example, organic solvents include alkyl esters of phthalic acid and trimellitic acid; aromatic hydrocarbons such as xylene and alkylbenzenes; methylnaphthalene; mixtures of aromatic, aliphatic and / or alicyclic hydrocarbons such as hexane and heptane; ketones such as saturated or unsaturated cyclic ketones such as cyclohexanone, 2-octanone, acetophenone, methyl isobutyl ketone, and isophorone; chlorinated hydrocarbons; vegetable oils such as castor oil and modified vegetable oils; glycols and their derivatives; aliphatic alcohols; alkoxyaliphatic alcohols; glycols and their derivatives such as propylene glycol, dipropylene glycol, polypropylene glycol, monoethylene glycol, diethylene glycol, and polyethylene glycol; alkoxyaliphatic alcohols such as 1-methoxy-2-propanol and butoxyethanol; C8-C 20 Examples include esters such as methyl esters of fatty acids; or combinations containing at least one of the aforementioned solvents.

[0118] The processes for formulating the highly effective liquid pesticide formulations disclosed herein are not limited.

[0119] The process for preparing the spray solution according to this disclosure is also not limited.

[0120] In one embodiment, the spray solution can be prepared by processes such as in-can compounding and tank mixing with other compound products, although this is not limited to these processes. The spray solution may be applied before or after budding.

[0121] It is preferable to apply a spray solution containing the formulations of this disclosure after germination. Such a spray solution may be prepared by simple dilution of the liquid pesticide composition, or by mixing the individual components of the composition and adding further individual herbicides or mixtures of herbicides. The spray solution containing the formulations of this disclosure may further contain other components that are desirable to be applied to the plant or its environment.

[0122] Preferably, such final use mixing is performed in the tank into which the formulation is sprayed, or alternatively, in a storage tank for filling the spray tank.

[0123] In one embodiment of the present disclosure, the liquid pesticide composition may further comprise additional active ingredients selected from various classes of pesticides, including herbicides, insecticides, and fungicides. In one embodiment, the additional active ingredient is a herbicide.

[0124] The active ingredient may be a water-soluble or water-insoluble herbicide, for example, Diphenyl ether herbicides such as oxyfluorphene, acialorphene, lactofen, fomesaphene, and their salts; Pyrimidinyl oxybenzoic acid analog herbicides such as pyrithiobac sodium and bispyribac sodium; Organophosphate herbicides such as glyphosate, viranafos, biaphos, and their salts; Bipyridinium herbicides such as paraquat, diquat, and their salts; Aryloxyalkanoic acid herbicides such as 2,4-D, MCPA, MCPB and their salts; Aryloxyphenoxypropion herbicides such as haloxyhop, its isomers and esters, and clodinahop and its esters; Pyridine herbicides such as triclopyr, picloram, aminopyralide, and their salts; Aromatic herbicides such as dicamba, 2,3,6-TBA, tricamba, and their salts; Pyridinecarboxylic acid herbicides such as clopyralide and triclopyr; Imidazolinones such as imazameth, imazamethabenz, imazamox, imazapic, imazapyr, imazaquin, and imazethapyr; Sulfonylurea herbicides such as flazasulfuron, limsulfuron, bensulfuron, ethoxysulfuron, mesosulfuron, oxasulfuron, pyrazosulfuron ethyl and their salts; Cyclohexanedione oxime herbicides such as cretodym and its salts; Chloroacetamide herbicides such as metrachlor and its salts and isomers; Phenylphthalimide herbicides such as flumioxazine, mesotrione, topramason, tenbotrione, quinotrione and their salts; Dinitroaniline herbicides such as oryzalin, benzimethalin, profluralin, trifluralin, and their salts; Bicyclic dicarboxylic acid herbicides such as endotol, haloxifen, pyrifuraxifen, prosulfuron and primisulfuron, simmeline, pyroxasulfone and their salts; Alternatively, a combination including at least one of the aforementioned herbicides may be used.

[0125] In one embodiment, the disclosed liquid pesticide composition further comprises at least one agrochemically acceptable excipient.

[0126] The liquid pesticide compositions according to this disclosure may further contain other agriculturally appropriate excipients such as surfactants, solvents, fertilizers, pH adjusters, crystallization inhibitors, viscosity modifiers, suspension agents, spray droplet modifiers, pigments, antioxidants, foaming agents, light-shielding agents, compatibilizers, defoaming agents, metal ion chelating agents, neutralizing agents, corrosion inhibitors, dyes, odorants, spreading agents, penetration aids, micronutrients, emollients, lubricants, adhesives, dispersants, thickeners, freezing point depressants, and antimicrobial agents.

[0127] In one embodiment of the present invention, the surfactant may be selected from anionic, cationic, or zwitterionic surfactants and / or nonionic surfactants. Examples of anionic surfactants include anionic derivatives of fatty alcohols having 10 to 24 carbon atoms in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal salts and alkaline earth metal salts) and organic salts (e.g., salts based on amines or alkanolamines); and EO (ethylene oxide), PO (propylene oxide), and / or in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal salts and alkaline earth metal salts) and organic salts (e.g., salts based on amines or alkanolamines). Examples include anionic derivatives of copolymers consisting of BO (butylene oxide) units; derivatives of alkylene oxide adducts of alcohols in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal salts and alkaline earth metal salts) and organic salts (e.g., salts based on amines or alkanolamines); and derivatives of fatty acid alkoxylates in the form of ether carboxylates, sulfonates, sulfates and phosphates, and their inorganic salts (e.g., alkali metal salts and alkaline earth metal salts) and organic salts (e.g., salts based on amines or alkanolamines).

[0128] Examples of cationic surfactants or zwitterionic surfactants include alkylene oxide adducts of fatty amines, which have 8 to 22 carbon atoms (C8-C 22 Examples include quaternary ammonium compounds, as well as surface-active zwitterionic compounds such as taurides, betaines, and sulfobetaines.

[0129] Examples of nonionic surfactants include fatty alcohols having 10 to 24 carbon atoms with 0 to 60 EO units and / or 0 to 20 PO units and / or 0 to 15 BO units in any order; fatty acid alkoxylates and triglyceride alkoxylates; fatty acid amido alkoxylates; alkylene oxide adducts of alkyne diols; sugar derivatives such as amino sugars and amide sugars; polyacrylic and polymethacrylic derivatives; polyamides such as modified gelatin or derivatized polyaspartic acid; surfactant polyvinyl compounds such as modified PVP; polyol-based alkylene oxide adducts; polyglycerides, and their derivatives.

[0130] Examples of defoaming agents include, but are not limited to, silicone-based and non-silicone-based agents. Examples of silicone-based agents include silicone oil, polydimethylsiloxane, and modified siloxane, while examples of non-silicone-based agents include mineral oil-based defoaming agents, vegetable oils, fatty acids and fatty acid derivatives, fatty amines and fatty amine derivatives, fatty acid amides, substituted fatty acid amides and fatty acid amide derivatives, polyalkylene glycols, and tributyl phosphate.

[0131] The colorants are not limited and can be selected from a variety of known dye formulations in the art.

[0132] In one embodiment, the present disclosure relates to the use of a disclosed liquid pesticide composition for controlling weeds, wherein the liquid pesticide composition is a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) Surfactants and, d) Electrolytes that are not surfactants, It provides usage, including

[0133] In one embodiment, the disclosure provides a use of a disclosed liquid pesticide composition for controlling weeds, wherein the liquid pesticide composition is diluted in a spray solution containing about 0.1 g to about 10 g of glufosinate or its isomers per liter of spray solution. In one embodiment, the liquid pesticide is diluted in a spray solution containing about 0.1 g to about 5 g of glufosinate or its isomers per liter of spray solution.

[0134] In one embodiment, the present disclosure further includes a method for controlling weeds, comprising applying an agriculturally effective amount of a liquid pesticide composition to a plant, or to a growing area or planned growing area of ​​a plant, wherein the liquid pesticide composition is a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) Surfactants and, d) Electrolytes that are not surfactants, This provides a method that includes [something].

[0135] In one embodiment, the Disclosure provides a method for controlling undesirable plants from burn-down sections (segments) before planting, or from crops that are resistant or tolerant to glufosinate or its isomers (e.g., L-glufosinate), the method comprising applying an agriculturally effective amount of a liquid pesticide composition to the undesirable plants or crops, or to the growing area or planned growing area where such plants or crops are growing, wherein the liquid pesticide composition is a) A salt of glufosinate or its isomer, b) C8~C 20 Non-hydrotropic phosphorus derivatives containing alkyl groups, c) Surfactants and, It contains an electrolyte that is not a surfactant.

[0136] In one embodiment, a method for controlling undesirable plants from burn-down plots before planting, or from crops that are resistant or tolerant to glufosinate or its isomers (e.g., L-glufosinate), comprising applying an effective amount of a liquid pesticide composition to the undesirable plants or crops, or to the growing area or planned growing area where such plants or crops grow, wherein the liquid pesticide composition is a) l-glufosinate salt, b) C8~C 20 Non-hydrotropic phosphorus derivatives containing alkyl groups, c) Surfactants and, d) an electrolyte that is not a surfactant, The spray dilution of the composition has a dynamic surface tension of less than 60 mN / m during a surface life of 20 to 50 milliseconds.

[0137] In one embodiment, the present disclosure provides a method for controlling weeds and / or broadleaf species, comprising applying an effective amount of the liquid pesticide composition disclosed herein to weeds and / or broadleaf species, or to a growing area in which weeds and / or broadleaf species are growing.

[0138] Examples of crops in which this composition may be used include corn, rice, wheat, barley, rye, oats, sorghum, cotton, soybeans, peanuts, buckwheat, beets, rapeseed, sunflowers, sugarcane, tobacco, etc.; vegetables: nightshade vegetables such as eggplant, tomato, pimento, pepper, and potato; cucurbitaceous vegetables such as cucumber, pumpkin, zucchini, watermelon, melon, and tomato; radish, turnip, horseradish, kohlrabi, etc. Brassicaceae vegetables such as Chinese cabbage, cabbage, mustard greens, broccoli, and cauliflower; Asteraceae vegetables such as burdock, garland chrysanthemum, Korean thistle, and lettuce; Liliaceae plants such as leeks, onions, garlic, and asparagus; Apiaceae vegetables such as carrots, parsley, celery, and angelica tree; Chenopodiaceae vegetables such as spinach and chard; Lamiaceae vegetables such as perilla, mint, and basil; strawberries, sweet potatoes, and wild vegetables. Taro, flowers, ornamental plants, grass, fruits: pome fruits such as apples, pears, and quince; stone fruits such as peaches, plums, nectarines, Japanese apricots, cherries, apricots, and prunes; citrus fruits such as oranges, lemons, limes, and grapefruits; nuts such as chestnuts, walnuts, hazelnuts, almonds, pistachios, cashews, and macadamia nuts; blueberries, cranberries, blackberries, and raspberries. Trees other than fruit trees, such as berries, grapes, persimmons, olives, plums, bananas, coffee, dates, and coconuts; trees such as tea, mulberry, flowering plants, ash, birch, dogwood, eucalyptus, ginkgo, lilac, maple, oak, poplar, judas tree, sweetgum, plane tree, zelkova, Japanese cypress, fir, poison hemlock, juniper, pine, spruce, and Japanese yew, are listed, but are not limited to these.

[0139] In one embodiment, weeds controlled by the composition of the present invention include, but are not limited to, chinoza album, amaranthus palmeri, brachiaria plantaginea, amaranthus viridis, foxtail grass, morning glory, wild soybean, brachiaria decumbens, and eleusine indica.

[0140] The liquid pesticide composition may be sold as a pre-mixed composition. Alternatively, the components of the liquid pesticide may be provided individually as separate parts of a kit and mixed together before spraying. In another embodiment, at least one adjuvant may also be included in the kit and mixed together with the electrolytic pesticide.

[0141] The compositions of this disclosure may be applied simultaneously as a tank mix of a formulation containing both an electrolytic pesticide and additional active ingredients, or the liquid pesticide composition and additional active ingredients may be applied sequentially.

[0142] The advantages of this invention include the following:

[0143] a) The liquid pesticide compositions described herein are very effective in controlling weeds. b) The electrolytic pesticide in the liquid pesticide composition remains stable over a long period of time when stored at various temperatures. c) The liquid pesticide composition provides consistent weed control under different meteorological conditions such as application time, temperature, wind speed, and humidity. d) The liquid pesticide composition provides consistent weed control across a wide area of ​​weeds. e) The liquid pesticide composition provides consistent weed control regardless of the morphological structure of the weed leaves.

[0144] Further advantages and other parameters of this disclosure are demonstrated by the following embodiments. However, the scope of this disclosure is not limited in any way by the embodiments. Those skilled in the art will understand that this disclosure includes the examples described above and can be further modified and changed within the technical scope of this disclosure. [Examples]

[0145] Examples 1-6, 8-11, and 14-20 are compositions of the present invention according to this disclosure and are shown in Tables 1-5 below. Comparative examples (compositions not according to the present invention) (Comparative Examples 7, 12, 13, and 21) are also shown in Table 6. The processes used to prepare the compositions in Tables 1-6 are described in further detail below.

[0146] Example 1

[0147] [Table 1]

[0148] Preparation process of the composition of Example 1: Mix the required amount of L-glufosinate ammonium with water, propylene glycol, and ethylene glycol monobutyl ether, then add the calculated amount of C 8 / 10 Alkyl glucamide, polyethylene glycol monotridecyl ether phosphate, decylamine oxide, and potassium chloride were added. The resulting mixture was homogenized to obtain a liquid herbicide composition.

[0149] [Table 2]

[0150] The compositions of Examples 2 to 6 were prepared according to the process of Example 1.

[0151] [Table 3]

[0152] The compositions of Examples 8 to 11 were prepared according to the process of Example 1.

[0153] [Table 4]

[0154] Preparation process of compositions in Examples 14-18: The required amounts of L-glufosinate ammonium, propylene glycol, and ethylene glycol monobutyl ether were slowly mixed in a mixing container while stirring to obtain a dispersion. Then, C8~C 10 Alkyl polyglucosides and / or alkyl glucamides, alkyl ether phosphates, C 10 Alkylamine oxide, C 13 ~C 15 Alkylamine oxide and potassium chloride were added to the dispersion. Then, water was added to the resulting mixture, and the mixture was stirred at a temperature of 20-35°C for 90 minutes to obtain a liquid herbicide composition.

[0155] [Table 5]

[0156] The compositions of Examples 19-20 were prepared according to the process of Example 14.

[0157] [Table 6]

[0158] The compositions of Examples 7, 12, 13, and 21 were prepared according to the process of Example 1.

[0159] Measurement of Dynamic Surface Tension (DST) The dynamic surface tension (DST) of the samples in the examples and comparative examples was determined by the foam pressure method using a foam pressure tensile meter, Model BP100 (KRUSS), for a period of 20 to 50 milliseconds (surface lifetime or foam lifetime) corresponding to the spraying of pesticides in aqueous dilutions. Samples of the above formulations for analysis were prepared by diluting the formulations in water at concentrations of L-glufosinate ammonium at 150 to 400 grams of active ingredient per hectare (g ai / h) and glufosinate ammonium at 300 to 900 g of active ingredient per hectare. Dynamic surface tension was measured from the foam lifetime of 20 to 50 milliseconds at room temperature (25 ± 2°C) and relative humidity (rH) = 65 to 75%.

[0160] Tables 7 and 8 below summarize the DSTs of the example formulations. The spray compositions corresponding to the samples used in the tests are shown in parentheses in the table. Table 8 shows the DSTs of the comparative compositions (compositions not according to the present invention).

[0161] [Table 7]

[0162] [Table 8]

[0163] [Table 9]

[0164] From the above results, it is clear that spray dilutions of formulations of L-glufosinate ammonium containing a combination of a non-hydrotropic phosphorus derivative such as an alkyl ether phosphate, a surfactant (e.g., alkyldimethylamine oxide), and an alkali metal salt have a dynamic surface tension of less than 60 mN / m over a foam surface lifetime of 20 to 50 milliseconds when tested by spray dilution. Samples prepared for the compositions of Examples 7, 12, 13, and 21, which do not contain the compositions according to this disclosure, have a dynamic surface tension of more than 60 mN / m over a foam surface lifetime of 20 to 50 milliseconds when tested by spray dilution.

[0165] Biological efficacy of the formulations disclosed herein: Field tests were conducted using compositions prepared according to this disclosure as broad-area herbicides. The compositions were diluted with water and optionally with other tank mix additives and applied to cultivated and uncultivated land containing many broadleaf weeds, grasses, and sedges at application rates of 150-400 g of L-glufosinate ammonium as the active ingredient per hectare, and 300-900 g of glufosinate ammonium as the active ingredient per hectare, respectively. Various samples prepared according to the present invention were tested for their effectiveness in weed control. The corresponding compositions used to prepare the samples are shown in the table (in parentheses). Samples prepared for biological efficacy determination are unrelated to samples prepared for DST determination, and therefore the sample numbers may not match; for example, sample 5 for DST determination was prepared from a composition of one example, and sample 5 for biological efficacy determination was prepared from a composition of another example. The effectiveness of comparative examples is shown in Table 20 for comparison with the effectiveness of example compositions.

[0166] The test protocols for Sample 1 and Sample 2 are shown in Table 10, and the weed control results are shown in Table 11.

[0167] [Table 10]

[0168] [Table 11]

[0169] Table 12 shows the protocol for testing samples 3-5, and Table 13 shows the weed control results.

[0170] [Table 12]

[0171] [Table 13]

[0172] The test protocol for sample 6 is shown in Table 14, and the weed control results are shown in Table 15.

[0173] [Table 14]

[0174] [Table 15]

[0175] Table 16 shows the protocol for testing samples 7-10, and Tables 17 and 18 show the weed control results.

[0176] [Table 16]

[0177] [Table 17]

[0178] [Table 18]

[0179] Table 19 shows the protocol for testing sample 11, and Table 20 shows the weed control results.

[0180] [Table 19]

[0181] [Table 20]

[0182] Analysis of the data in the table above shows that the L-glufosinate ammonium formulations prepared according to the present invention demonstrated good weed control when tested at various treatment doses. Even more surprisingly, the effectiveness of the formulations could be controlled by adjusting the dynamic surface tension, and formulations with a dynamic surface tension of less than 60 mN / m during a surface lifetime of 20–50 milliseconds were found to yield remarkably high effectiveness. When tested at a treatment dose of 157.5 g ai / ha, the compositions according to this disclosure demonstrated acceptable weed control, while the comparative compositions were found to be insufficiently effective even when tested at a higher treatment dose of 250 g ai / ha.

Claims

1. a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) Surfactants and, d) Electrolytes that are not surfactants, A liquid pesticide composition containing the following:

2. The composition according to claim 1, wherein the electrolytic pesticide comprises a water-soluble salt of glufosinate or an isomer thereof, or a combination thereof.

3. The water-soluble salt of the glufosinate or its isomer is a hydrochloride, monosodium salt, disodium salt, monopotassium salt, dipotassium salt, monocalcium salt, ammonium salt, NH ３ (CH ３ ) ＋ 、NH ２ (CH ３ ) ２ ＋ salt, NH(CH ３ ) ３ ＋ salt, -NH(CH ３ ) ２ (C ２ H ４ OH) ＋ salt, and -NH ２ (CH ３ )(C ２ H ４ OH) ＋ salt, and the composition according to claim 1.

4. The non-hydrotropic phosphorus derivative is C ８ ~C ２０ The composition according to claim 1, comprising an alkyl group.

5. The composition according to claim 1, wherein the non-hydrotropic phosphorus derivative is polyethylene glycol monotridecyl ether phosphate.

6. The surfactant is alkyl polyglycoside, N-alkyl glucamide, C ８ ~C ２０ The composition according to claim 1, comprising alkyldimethylamine N-oxide or a combination thereof.

7. The composition according to claim 1, wherein the electrolyte comprises an inorganic salt of an alkali metal or an inorganic salt of an alkaline earth metal.

8. The composition according to claim 1, wherein the composition is diluted in a spray solution containing an agriculturally effective amount of an electrolytic pesticide per liter of spray solution.

9. The composition according to claim 8, wherein the spray dilution of the liquid pesticide composition has a dynamic surface tension of less than 60 mN / m with a surface life of 20 to 50 milliseconds.

10. l-glufosinate salt, Non-hydrotropic C ８ ~C ２０ Fatty alcohol alkoxylate phosphate and Surfactants and Alkali metal salts and The composition according to claim 1, comprising:

11. Glufosinate salt and, Non-hydrotropic C ８ ~C ２０ Fatty alcohol alkoxylate phosphate and Surfactants and Alkali metal salts and The composition according to claim 1, comprising:

12. The composition according to claim 1, wherein the liquid pesticide composition further comprises an additional active ingredient.

13. A process for preparing a liquid pesticide composition, To obtain a dispersion by combining an electrolytic pesticide, a solvent, and optionally an excipient, and A non-hydrotropic phosphorus derivative, a surfactant, a non-surfactant electrolyte, and water are combined in the dispersion to obtain the liquid pesticide composition. A process that includes this.

14. The use of a liquid pesticide composition for controlling weeds, wherein the composition is a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) at least one surfactant, d) Electrolytes that are not surfactants, Includes, use.

15. In plants or their growing areas, a) Electrolytic pesticides and, b) Non-hydrotropic phosphorus derivatives, c) Surfactants and, d) Electrolytes that are not surfactants, A method for controlling weeds, comprising applying a liquid pesticide composition containing [a specific substance].

16. The method for controlling weeds according to claim 15, wherein the liquid pesticide composition is a spray solution containing 0.1 to 10 g of glufosinate per liter of spray solution.

17. The method for controlling weeds according to claim 15, wherein the electrolytic pesticide is glufosinate ammonium and is applied at an application rate of 300 to 900 grams of the active ingredient per hectare.

18. The method for controlling weeds according to claim 15, wherein the electrolytic pesticide is l-glufosinate ammonium and is applied at an application rate of 150 to 400 grams of the active ingredient per hectare.

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