Eyebrow makeup composition comprising non-glycerolated silicone resin, glycerolated silicone resin, silicone gum, volatile hydrocarbon oil, and thickener.
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Applications
- Current Assignee / Owner
- LOREAL SA
- Filing Date
- 2024-05-27
- Publication Date
- 2026-06-25
Smart Images
Figure 2026521052000001 
Figure 2026521052000002 
Figure 2026521052000003
Abstract
Claims
1. Preferably, a keratin material, in particular a composition for caring for and / or makeup the eyebrows including eyebrow hairs, the skin for implanting the eyebrows and their contours, in particular in a physiologically acceptable medium. (a) at least one non-glycerolated silicone resin, (b) at least one glycerol-containing silicone resin, (c) at least one silicone gum and (d) at least one oily phase comprising at least one volatile hydrocarbon oil, (e) A composition comprising a lipophilic thickener.
2. The composition according to claim 1, wherein the non-glycerolated silicone resin (a) is selected from MQ-type silicone resins, T-type silicone resins, MQT-type silicone resins, and mixtures thereof.
3. The composition according to claim 1 or 2, comprising at least one non-glycerolated silicone resin (a) selected from MQ-type, particularly trimethylsiloxysilicate-type, silicone resins.
4. The composition according to claim 3, wherein the trimethylsiloxysilicate type non-glycerolated silicone resin (a) is a solution in isododecane, particularly a solution containing 75% by mass of the active material in isododecane.
5. The composition according to any one of claims 1 to 4, wherein the non-glycerol-containing silicone resin (a) is present in an active material content in the range of 4% to 35% by mass, preferably in the range of 6% to 30% by mass, and more preferably in the range of 8% to 25% by mass, based on the total mass of the composition.
6. The composition according to any one of claims 1 to 5, wherein the glycerol-modified silicone resin (b) is present in an active material content of 0.1% to 40% by mass, preferably 0.2% to 30% by mass, and more preferably 0.5% to 15% by mass, relative to the total mass of the composition.
7. The glycerol-modified silicone resin (b) is RR'R''SiO １／２ The composition according to any one of claims 1 to 6, comprising at least one organosiloxane unit of type, wherein R, R', and R'' are the same or different, represent hydrocarbon groups, at least one of which contains a monoglycerol group or a polyglycerol group.
8. The glycerol-containing silicone resin (b) comprises at least one dimethylsiloxane R (CH4) containing a hydrocarbon group R that includes a monoglycerol group. ３ ) ２ SiO １／２ The composition according to claim 7, comprising units.
9. The glycerol-modified silicone resin (b) is selected from those of the following formula (1): (R １ ３ Yes １／２ ) ａ (R ２ (CH) ３ ) ２ Yes １／２ ) ｂ (R ３ ３ Yes １／２ ) ｃ (R １ ２ Yes ２／２ ) ｄ (R １ Yes ３／２ ) ｅ (Yes) ４／２ ) ｆ (1) (In the formula, - each R １ These are identical or different alkyl groups, aryl groups, or aralkyl groups having 1 to 30 carbon atoms, or halogen-substituted groups, amino-substituted groups, or the latter carboxyl-substituted groups. -Each R ２ is a monoglycerol or polyglycerol group of the following general formula (2): -(CH ２ ) ２ -C ｌ H ２ｌ -O-(CH ２ CH(OH)CH ２ O) ｉ R ４ (2)、 During the ceremony, -R ４ is a substituted or unsubstituted monovalent hydrocarbon group or hydrogen atom, and the subscripts l and i are integers satisfying the conditions 0 ≤ l ≤ 15 and 0 < i ≤ 5, and each R ３ These are the same or different groups of the following general formulas (3), (4), (5), or (6): -(H) ２ ) ２ -C ｍ H ２ｍ -(SiPR １ ２ )j-SiR １ ３ (3) -(CH ２ ) ２ -C ｍ H ２ｍ -SiR １ ｋ１ -(OSiR １ ３ ) ３－ｋ１） (4) -(CH ２ ) ２ -C ｍ H ２ｍ -SiR １ ｋ１ -(OSiR １ ｋ２ (OSiR １ ３ ) ３－ｋ２）３－ｋ１ (5) -(CH ２ ) ２ -C ｍ H ２ｍ -SiR １ ｋ１ -(OSiR １ ｋ２ (OSiR １ ｋ３ (OSiR １ ３ ) ３－ｋ３）３－ｋ２）３－ｋ１ (6)、 During the ceremony, -Each R １ These are identical or different alkyl groups, aryl groups, or aralkyl groups having 1 to 30 carbon atoms, or halogen-substituted groups, amino-substituted groups, or the latter carboxyl-substituted groups. - Subscripts m, j and k １ ~k ３ The conditions are 0 ≤ m ≤ 5, 0 ≤ j ≤ 500, and 0 ≤ k １ ≤ 2, 0 ≤ k ２ ≤2 and ≤k ３ An integer that satisfies the condition ≤ 2, - The subscripts a, b, c, d, e, and f are numbers that satisfy the conditions 0 ≤ a ≤ 400, 0 < b ≤ 200, 0 ≤ c ≤ 400, 0 ≤ d ≤ 320, 0 ≤ e ≤ 320, 0 < f ≤ 1000, and 0.5 ≤ (a + b + c) / f ≤ 1.5), the composition according to any one of claims 1 to 8.
10. The glycerol-containing silicone resin (b) of formula (1) satisfies the conditions 0 < b ≤ 30 and 0 ≤ c ≤ 30, and the polyglycerol group R ２ The composition according to claim 9, wherein the subscript i in the general formula (2) is selected from integers that satisfy the condition 0 < i ≤ 3.
11. The composition according to claim 9 or 10, wherein the glycerol-modified silicone resin (b) of formula (1) preferably has a weight-average molecular weight in the range of 1,000 to 100,000, more preferably in the range of 3,000 to 50,000.
12. The glycerol-containing silicone resin (b) in the average formula (1) satisfies the condition that the subscript c is 0 < c ≤ 400, and R ３ The composition according to any one of claims 9 to 11, wherein is the base of general formula (3), and is in solid form at 25°C when the subscript j satisfies the condition 0 ≤ j ≤ 10.
13. The composition according to any one of claims 9 to 12, wherein the glycerol-silicone resin (b) has a hydrophilic-lipophilic balance (HLB) determined by Griffin's formula in the range of 0.1 to 15, more preferably 1.0 to 8.
0.
14. The following equation (21): [(CH ３ ) ３ Yes １／２ ] ａ [R(CH) ３ ) ２ Yes １／２ ] ｂ (Yes) ４／２ ) ｆ (21) (In the formula, -R is, -C ３ H ６ OCH ２ -CH(OH)CH ２ The OH structure shows the 3-glyceroxypropyl group. The composition according to any one of claims 9 to 13, comprising at least one glycerolated silicone resin (b) of formula (1) of the (3-glyceroxypropyl)dimethylsiloxytrimethylsiloxysilicate type, corresponding to the subscripts a, b, and f (where a, b, and f are integers satisfying the conditions 0 ≤ a ≤ 400, 0 < b ≤ 30, 0 < f ≤ 1000, and 0.5 ≤ (a + b) / f ≤ 1.5).
15. The composition according to claim 14, wherein the glycerol-modified silicone resin (b) of the (3-glyceroxypropyl)dimethylsiloxytrimethylsiloxysilicate type of formula (21) is in the form of a solution in at least one volatile oil.
16. The composition according to claim 15, wherein the glycerol-modified silicone resin of the (3-glyceroxypropyl)dimethylsiloxytrimethylsiloxysilicate type of formula (21) is in the form of a solution containing 49.5% by mass of the active material in isododecane.
17. The composition according to any one of claims 1 to 16, comprising at least one glycerol-containing silicone resin (a) and at least one non-glycerol-containing silicone resin (b) in a mass ratio of the amount of glycerol-containing silicone resin to the amount of non-glycerol-containing silicone resin of 0.8 or more, more preferably 1.0 or more.
18. The composition according to any one of claims 1 to 17, comprising at least one volatile hydrocarbon oil selected from petroleum-derived C8-C16 isoalkanes, particularly isododecane.
19. The composition according to any one of claims 1 to 18, wherein the volatile hydrocarbon oil is preferably present in an amount of 80% by mass or less, and more preferably 40% to 70% by mass, relative to the total mass of the composition.
20. The silicone gum (c) is given by formula: 【Chemistry 1】 (In the formula, R1, R2, R5, and R6 are alkyl groups containing 1 to 6 carbon atoms, either together or separately. R3 and R4 together or separately are alkyl groups, vinyl groups, amine groups, or hydroxyl groups containing 1 to 6 carbon atoms. X is an alkyl group, hydroxyl group, or amine group containing 1 to 6 carbon atoms. The composition according to any one of claims 1 to 19, wherein n and p are integers selected from silicones such that the molecular weight of the silicone gum (c) is 180,000 g / mol or more.
21. The composition according to claim 20, where n and p are in the range of 0 to 3000, and it should be noted that n and p are not both zero at the same time.
22. The composition according to any one of claims 1 to 21, wherein the silicone gum (c) is preferably in the form of a solution in an organic solvent, selected from volatile silicones, polydimethylsiloxane oil, polyphenylmethylsiloxane oil, isoparaffins, particularly C8 to C16 isoparaffins, such as isododecane, methylene chloride, pentane, dodecane, tridecane, tetradecane, or mixtures thereof, and more specifically, the solvent is isododecane.
23. The composition according to claim 22, wherein the proportion of silicone gum (c) in the organic solvent solution is 5% to 40% by mass, more preferably 10% to 30% by mass, based on the total mass of the solution.
24. The composition according to any one of claims 1 to 23, wherein the silicone gum (c) is present in an active material content in the range of 5% to 30% by mass, more specifically in the range of 8% to 15% by mass.
25. The silicone gum (c) is a polydimethylsiloxane having dimethicone (DIMETHICONE) with the following INCI name: 【Chemistry 2】 The composition according to any one of claims 1 to 24, wherein n is 3000 or less, and more specifically the gum is in the form of a solution in isododecane, and more specifically the form of a 25% by mass solution in isododecane.
26. The composition according to any one of claims 1 to 25, wherein the lipophilic thickener (e) is a lipophilic clay, more specifically, hectorite modified with distearyldimethylammonium chloride, having the INCI name: disteardimonium hectorite.
27. The composition according to any one of claims 1 to 26, wherein the lipophilic thickener is present in a concentration of preferably 0.5% to 10% by mass, more preferably 1% to 6% by mass, based on the total mass of the composition.
28. Preferably, the composition according to any one of claims 1 to 27 further comprises at least one colorant selected from powdered colorants, lipid-soluble dyes, and mixtures thereof.
29. The composition according to claim 28, wherein the powdered coloring agent is present in an amount of 50.0% by mass or less, preferably 25% to 40% by mass, and more specifically 3% to 15% by mass, based on the total mass of the composition.
30. The composition according to claim 28 or 29, wherein the powdered colorant is selected from metal oxides, more particularly from coated or uncoated titanium dioxide or black, red, or yellow iron oxide, and mixtures thereof.
31. The composition according to claim 30, comprising titanium dioxide coated with isopropyltriisostearyl titanate, black, red, or yellow iron oxide coated with isopropyltriisostearyl titanate, and at least one powdered colorant selected from mixtures thereof.
32. The composition according to any one of claims 1 to 31, characterized by being anhydrous.
33. An assembly or kit for packaging and applying cosmetic compositions for coating keratin materials, - A packaging apparatus comprising the composition according to any one of claims 1 to 32, - An assembly or kit comprising an applicator for the composition.
34. A method for coating, particularly eyebrows and the skin around the eyes and eyebrows, with a keratin material, and especially for curling, the method comprising applying the composition according to any one of claims 1 to 32 to the keratin fibers.