Biaxially oriented polyester film roll

Abstract

To provide a polyester film roll that has less wrinkles and defects on the film surface and no winding deviation and is suitable for secondary processing such as coating and vapor deposition.SOLUTION: A polyester film roll formed by winding a biaxially oriented polyester film around a core satisfies following requirements (1)-(3). (1) The polyester film roll has an average winding hardness of the surface in the range of 500 or more and 700 or less. (2) The polyester film roll has a degree of variability of winding hardness of the surface of 1% or more and 5% or less in the film width direction. (3) The polyester film roll has a degree of variability of winding hardness of 3% or more and 10% or less from the surface to the core.SELECTED DRAWING: Figure 4

Description

[Technical field]

[0001] The present invention relates to a film roll obtained by winding a biaxially oriented polyester film, which has few wrinkles or defects on the film surface, is free from winding slippage, and is suitable for secondary processing such as coating and deposition, etc. Furthermore, the present invention relates to a polyester film roll having excellent quality of the coated film after secondary processing. [Background technology]

[0002] Conventionally, polyester films have been widely used in a wide range of fields, such as packaging materials and industrial materials, due to their excellent mechanical strength, thermal properties, optical properties, etc. In particular, biaxially oriented polyester films have excellent oxygen barrier properties, and in packaging applications for food, retort products, pharmaceuticals, etc., there is an increasing demand for oxygen barrier properties and water vapor barrier properties related to the alteration and deterioration of the contents, which can cause the alteration and deterioration of the contents.

[0003] For this reason, measures are being taken to further improve the gas barrier properties of biaxially oriented polyester films used in packaging applications for food, retort products, pharmaceuticals, etc. Commonly used methods for improving gas barrier properties include laminating a film with good gas barrier properties, such as polyvinylidene chloride or a polyethylene vinyl alcohol copolymer, to the polyester film, and forming a thin film by evaporating a metal, such as aluminum, or a metal oxide, such as aluminum oxide, onto the biaxially oriented polyester film. In particular, the latter vapor-deposited polyester film having a metal or metal oxide on the film surface is excellent in heat resistance and transparency.

[0004] It is also known that the gas barrier performance of the obtained vapor-deposited polyester film is highly dependent on the surface condition of the biaxially oriented polyester film used as the substrate, and proposals have been made to specify the surface roughness and number of protrusions of the biaxially oriented polyester film substrate (see, for example, Patent Document 1), to specify the melting subpeak of the biaxially oriented polyester film (see, for example, Patent Document 2), and to specify the amount of oligomer generation in the film (see, for example, Patent Document 3).

[0005] However, even for biaxially oriented polyester films with the same characteristics, the quality of the coated film after processes such as coating and deposition varies and sometimes falls outside the acceptable range, and the cause of this is unknown.

[0006] One of the factors that reduces the quality of the coated film is wrinkles in the polyester film roll before it is unwound from a purchased polyester film roll. As a method for improving this problem, a polyester film roll with reduced core wrinkles and surface wrinkles has been proposed (Patent Document 4). [Prior art documents] [Patent documents]

[0007] [Patent Document 1] Japanese Patent Application Publication No. 10-119172 [Patent Document 2] Japanese Patent Application Publication No. 11-010725 [Patent Document 3] JP 2006-299078 A [Patent Document 4] Japanese Patent Publication No. 63-252853 DISCLOSURE OF THEINVENTION [Problem to be solved by the invention]

[0008] An object of the present invention is to provide a polyester film roll which overcomes these problems, has few wrinkles or defects on the film surface, is free from winding slippage, and is suitable for secondary processing such as coating and deposition. Another object of the present invention is to provide a polyester film roll which has excellent quality of the coated film after secondary processing. [Means for solving the problem]

[0009] As a result of extensive research conducted by the present inventors to achieve this object, it has been found that by making the variation in winding hardness from the winding core to the surface of a polyester film roll formed by winding a biaxially oriented polyester film around a winding core constant and by making the winding hardness of the surface of the film roll within a specific range, it is possible to provide a polyester film roll that has few wrinkles and defects on the film surface, is free from winding misalignment, and is suitable for secondary processing such as coating and vapor deposition. More preferably, a polyester film roll can be obtained which is less susceptible to winding wrinkles, winding misalignment, and spoked wrinkles on the roll end faces, and which has fewer quality defects due to static marks and discharge marks. This reduces problems such as deterioration in quality due to unevenness or loss of the coating or evaporated thin film after secondary processing, and poor appearance due to wrinkles after winding after secondary processing.

[0010] That is, the present invention comprises the following: 1. A polyester film roll obtained by winding a biaxially oriented polyester film around a core, the polyester film roll being characterized by satisfying the following requirements (1) to (3): (1) The average winding hardness of the surface of the polyester film roll is in the range of 500 or more and 700 or less. (2) The variation rate of the winding hardness of the surface of the polyester film roll in the film width direction is 1% or more and 5% or less. (3) The variation rate of winding hardness from the surface of the polyester film roll to the winding core is 3% or more and 10% or less.

[0011] 2. The polyester film roll according to 1, wherein the thickness variation rate in the width direction of the polyester film is 10% or less. 3. The polyester film roll according to 1 or 2, wherein the coefficient of dynamic friction of the outer surface and the inner surface of the biaxially oriented polyester film is both 0.2 or more and 0.60 or less. 4. The polyester film roll according to any one of 1 to 3, wherein the biaxially oriented polyester film has an arithmetic mean height of an inner surface of the roll of 0.010 μm or more and 0.050 μm or less.

[0012] 5. The polyester film roll according to any one of 1. to 4., wherein the biaxially oriented polyester film has a thickness of 5 μm or more and 40 μm or less. 6. The polyester film roll according to any one of 1. to 5., wherein the biaxially oriented polyester film has a roll length of 2,000 m or more and 65,000 m or less. 7. The polyester film roll according to any one of 1. to 6., wherein the width of the polyester film roll is 400 mm or more and 3,000 mm or less.

[0013] 8. The polyester film roll according to any one of 1. to 7., wherein the biaxially oriented polyester film is for use as a substrate for a vapor deposition film. Effect of the Invention

[0014] The polyester film roll of the present invention has few wrinkles or defects on the film surface, is free from winding slippage, and is suitable for secondary processing such as coating and deposition. More preferably, a polyester film roll is obtained which is less susceptible to wrinkles due to winding, misalignment due to winding, and spoked wrinkles, and which has less quality defects due to static markers and discharge marks. This reduces problems such as deterioration in quality due to unevenness or loss of the coating or evaporated thin film after secondary processing, and poor appearance due to wrinkles after winding after secondary processing.

[0015] More preferably, it is possible to obtain a polyester film roll that does not suffer from winding wrinkles or winding misalignment during winding, or spoked wrinkles on the roll end surface, and has few quality defects due to static marks or discharge marks caused by electrostatic charging. In this case, it is possible to reduce problems such as defects in appearance due to deposition spots during deposition processing, wrinkles during winding after deposition, and defects in post-processing such as spots or gaps due to partial repulsion of the deposited thin film. In particular, in recent years, polyester film rolls have been made wider and longer in order to improve the processing efficiency of biaxially oriented polyester films, but even if the initially wound large film roll is slit to divide it into smaller film rolls and then re-produced, the uniformity of quality between each film roll can be improved. In addition, when the film roll is made longer, since the polyester film has electrical insulation, it is prone to charging due to contact with and peeling from the transport roll during the film production process, but even so, the quality is easy to maintain. [Brief description of the drawings]

[0016] [Figure 1] A diagram showing the relationship between the surface layer, intermediate layer, and core layer as viewed from the end face of a film roll. [Diagram 2] A photograph of the film surface after it has been unwound from a film roll, where strongly charged areas on the surface have been visualized using a charge distribution assessment toner.Static marks can be observed. [Diagram 3] A photograph of the film surface after it has been unwound from a film roll, with the discharge marks visible using a toner for assessing charge distribution. Discharge marks are visible. [Figure 4] Diagram of film roll and contact roll during winding DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0017] The present invention will be described in detail below. The biaxially oriented polyester film in the present invention is made of the following polyester resin, preferably a polyester resin composition containing the following fine particles and / or the following additives. The polyester resin constituting the biaxially stretched polyester film in the present invention is a polymer synthesized from a dicarboxylic acid or its ester-forming derivative and a diol or its ester-forming derivative. Examples of the polyester resin include polyethylene terephthalate, polybutylene terephthalate, and polyethylene-2,6-naphthalate, and polyethylene terephthalate is preferred from the viewpoints of mechanical properties, heat resistance, cost, etc.

[0018] In addition, these polyesters may be copolymerized with other components as long as the object of the present invention is not impaired. Specifically, the copolymerization components include dicarboxylic acid components such as isophthalic acid, naphthalenedicarboxylic acid, 4,4-diphenyldicarboxylic acid, adipic acid, sebacic acid and their ester-forming derivatives. In addition, the diol components include diethylene glycol, hexamethylene glycol, neopentyl glycol, and cyclohexanedimethanol. In addition, polyoxyalkylene glycols such as polyethylene glycol and polypropylene glycol are also included. The copolymerization amount is preferably 10 mol% or less per constituent repeating unit, more preferably 5 mol% or less.

[0019] The polyester resin constituting the biaxially stretched polyester film of the present invention can be produced by, for example, first carrying out an esterification or transesterification reaction using the above-mentioned dicarboxylic acid or its ester-forming derivative and the diol or its ester-forming derivative as main starting materials in a conventional manner, and then carrying out a polycondensation reaction at high temperature and reduced pressure.

[0020] The intrinsic viscosity of the polyester resin constituting the biaxially oriented polyester film of the present invention is preferably in the range of 0.50 to 0.9 dl / g, more preferably 0.55 to 0.8 dl / g, from the viewpoints of film formability and recollection.

[0021] In the biaxially oriented polyester film of the present invention, it is preferable to add fine particles as a lubricant in order to improve the slipperiness during film production and secondary processing such as deposition. The coefficient of dynamic friction and the coefficient of static friction can be used as indicators of slipperiness. Examples of the fine particles used include inorganic fine particles and organic fine particles. Examples of the inorganic fine particles include particles made of silica, alumina, titanium dioxide, calcium carbonate, kaolin, and barium sulfate. Examples of the organic fine particles include particles made of acrylic resin particles, melamine resin particles, silicone resin particles, and crosslinked polystyrene. The average particle size of the fine particles is preferably within a range of 0.05 to 3.0 μm as measured by a Coulter counter. If the weight average particle size is 0.05 μm or more, the dynamic friction coefficient is easily increased, and if the weight average particle size is 3.0 μm or less, the dynamic friction coefficient is easily prevented from becoming too high.

[0022] As the microparticles for adjusting the dynamic friction coefficient and static friction coefficient of the biaxially oriented polyester film in the present invention, from the viewpoint of reducing the haze of the biaxially oriented polyester film, inorganic microparticles made of silica, calcium carbonate, or alumina, or organic microparticles made of polymethacrylate, polymethyl acrylate, or derivatives thereof are preferred, inorganic microparticles made of silica or calcium carbonate are more preferred, and inorganic microparticles made of silica are particularly preferred.

[0023] The method of blending the above-mentioned fine particles in the biaxially oriented polyester film of the present invention can be, for example, added at any stage of producing the polyester resin, but it is preferable to add the fine particles as a slurry dispersed in ethylene glycol or the like at the stage of esterification or after the completion of the transesterification reaction and before the start of the polycondensation reaction, and proceed with the polycondensation reaction. It is also preferable to blend the slurry of the particles dispersed in ethylene glycol or water or the like with the polyester resin raw material using a vented kneading extruder, or to blend the dried particles with the polyester resin raw material using a kneading extruder.

[0024] The lower limit of the content of the fine particles in the biaxially oriented polyester film in the present invention is preferably 100 ppm by weight, more preferably 900 ppm by weight, and particularly preferably 1500 ppm by weight. When the content of fine particles is 100 ppm by weight or more, the dynamic friction coefficient and static friction constant can be easily reduced, and the amount of air entrained when the master roll is slit and the film is wound around the core is reduced. Therefore, even after the air is released from the recesses between the protrusions formed on the film surface and between the film gaps in the film roll after winding, the film is less likely to sag or wrinkle. The upper limit of the content of the fine particles is preferably 20000 ppm by weight, more preferably 2000 ppm by weight, and particularly preferably 1800 ppm by weight. When the content of the fine particles is 20000 ppm by weight or less, not only is the transparency unlikely to decrease, but the dynamic friction coefficient of the film is not too low, and edge slippage is unlikely to occur.

[0025] In addition, the biaxially oriented polyester film of the present invention may contain small amounts of other polymers, antioxidants, heat stabilizers, antistatic agents, ultraviolet absorbers, plasticizers, pigments, or other additives, as long as the object of the present invention is not impaired.

[0026] [Manufacturing method of biaxially oriented polyester film] Suitable examples of the biaxially oriented polyester film in the present invention are described below, but the present invention is not limited to these. For example, the above-mentioned composition containing the polyester resin as a main component is melt-extruded by an extruder to form an unstretched film, and the unstretched film is produced by the method described below.

[0027] When the polyester resin composition is melt-extruded, it is preferable to dry the polyester resin composition using a dryer such as a hopper dryer or a paddle dryer, or a vacuum dryer. After drying the polyester resin composition in this way, it is melted at a temperature of 200 to 300 ° C. and extruded into a film using an extruder. Alternatively, the polyester resin, fine particles, and additives may be sent out by separate extruders, and after joining, they may be mixed and melted and extruded into a sheet. When extruding the molten resin composition, any existing method such as a T-die method or a tubular method may be used.

[0028] The sheet-like molten polyester resin composition after extrusion can be quenched to obtain an unstretched sheet. As a method for quenching the molten polyester resin composition, a method can be suitably adopted in which the molten polyester resin composition is cast onto a rotating drum from a die and quenched and solidified to obtain a substantially unoriented resin composition sheet. The temperature of the rotating drum is preferably set to 30° C. or lower.

[0029] Furthermore, the unstretched sheet obtained can be achieved by appropriately combining the following film-forming conditions, such as the longitudinal and transverse stretching conditions, heat setting conditions, and heat relaxation conditions, as described below. The longitudinal direction means the direction in which the unstretched sheet runs, and the transverse direction means the direction perpendicular thereto.

[0030] The stretching method may be simultaneous biaxial stretching in which stretching in the longitudinal direction and the width direction is performed simultaneously, or sequential biaxial stretching in which stretching in either the longitudinal direction or the width direction is performed first. From the viewpoint of a high film production speed and high productivity, sequential biaxial stretching is most preferable.

[0031] The longitudinal stretching temperature is preferably in the range of (Tg+15) to (Tg+55)° C., and the stretching ratio is preferably in the range of 3.3 to 4.7 times, from the viewpoint of making uniform the variation in the winding hardness of the film surface in the width direction. When the stretching temperature is (Tg+55)°C or lower and 3.3 times or more, the molecular orientation in the longitudinal direction and the transverse direction is well balanced, and the difference in physical properties between the longitudinal direction and the transverse direction is small, which is preferable. In addition, the flatness of the obtained biaxially stretched polyester film is also good, which is preferable. On the other hand, when the stretching temperature in the MD direction is (Tg+15)° C. or higher and the stretching ratio is 4.7 times or lower, the shrinkage stress does not increase too much and bowing is reduced, which is preferable.

[0032] In addition, in the longitudinal stretching, in a method of stretching in multiple stages between multiple rolls rather than in one stage, the film is gradually stretched in the longitudinal direction while controlling the stretching speed, so that the difference in physical properties in the film width direction can be further reduced. Two-stage to five-stage stretching is preferable from the viewpoints of effect, equipment, and cost.

[0033] When stretching in the width direction, the unstretched film is introduced into a tenter device that can heat the film by holding both ends of the film stretched in the longitudinal direction with clips, and the film is heated to a predetermined temperature with hot air.The film is then stretched in the width direction by increasing the distance between the clips while transporting it in the longitudinal direction. When the stretching temperature in the width direction is Tg+5°C or more, breakage during stretching is unlikely to occur, which is preferable. Also, when the temperature is Tg+40°C or less, uniform stretching in the width direction is easy to achieve, and thickness unevenness in the width direction is unlikely to increase, which is preferable because the variation in winding hardness of the film roll surface in the width direction is unlikely to increase. More preferably, the temperature is Tg+8°C or more and Tg+37°C or less, and even more preferably, the temperature is Tg+11°C or more and Tg+34°C or less. The stretching ratio in the width direction is preferably 2 times or more and 6 times or less. When the stretching ratio is 2 times or more, a high yield is easily obtained in terms of material balance, the mechanical strength is not decreased, thickness unevenness in the width direction is not likely to increase, and the winding hardness in the width direction of the film roll is not likely to vary, which is preferable. In addition, when the stretching ratio is 6 times or less, the film is less likely to break during stretching film formation, which is preferable.

[0034] The heat setting temperature of the film stretched in the width direction is preferably 220 to 245°C. When the heat setting temperature is 245°C or less, bowing is less likely to increase, which is preferable. On the other hand, when the heat setting temperature is 220°C or more, the heat shrinkage rate in both the longitudinal and width directions is not too high, which is preferable because the thermal dimensional stability during deposition processing is improved. In addition, when the TD heat setting temperature is 245°C or less, bowing is less likely to increase, which is preferable.

[0035] In the heat relaxation process, the film is in a state where it is very easy to move up and down because the binding force in the width direction is reduced and the film slackens under its own weight until it shrinks due to heat relaxation, and the film may expand due to the accompanying air current of the hot air blown from the nozzles installed above and below the film. Therefore, in this heat relaxation process, the change amount of the orientation angle and the oblique heat shrinkage difference of the obtained biaxially stretched polyester film varies greatly depending on the film transport state. As a method for reducing these, for example, the wind speed of the hot air blown from the nozzles at the top and bottom can be mentioned to keep the film parallel. The relaxation rate in the width direction is preferably 4 to 8%. When the heat relaxation rate is 4% or more, the heat shrinkage rate in the width direction of the obtained biaxially stretched polyester film is not too high, which is preferable because the dimensional stability during deposition processing is good. On the other hand, when the heat relaxation rate is 8% or less, the tensile stress (bowing phenomenon) applied in the opposite direction to the film advancement direction to the center part in the width direction of the film is not too large, and the variation rate of the film thickness in the width direction does not become large, which is preferable because the variation rate of the average winding hardness of the film roll surface in the width direction does not become large. The heat setting step and the heat relaxation step may be carried out separately or simultaneously.

[0036] The wide biaxially oriented polyester film stretched by the above method is wound up by a winder to produce a master roll. The width of the master roll is preferably 5000 mm or more and 10000 mm or less. If the roll width is 5000 mm or more, the cost per film area in the subsequent slitting process, deposition processing and printing processing is lower, which is preferable. The length of the master roll is preferably 10,000 to 100,000 mm. If the length of the roll is 5,000 mm or more, the cost per film area in the subsequent slitting process, deposition processing, and printing processing is preferably low.

[0037] The thickness of the biaxially oriented polyester film roll of the master roll is preferably 5 to 40 μm. If it is 5 μm or more, the strength and stiffness of the film are not reduced, and the film roll is less likely to wrinkle, which is preferable. On the other hand, even if the film thickness is thick, there is no problem as a film roll, but from the viewpoint of cost, it is preferable to make the film thinner. The film thickness is more preferably 8 to 30 μm, and particularly preferably 9 μm to 20 μm.

[0038] The thickness variation rate in the width direction of the biaxially oriented polyester film of the master roll is preferably 10% or less. The thickness variation rate is measured using a continuous contact type thickness meter as shown in the examples. The overall thickness unevenness in the width direction is calculated by the following formula 1. If the film thickness variation rate is 10% or less, the winding hardness in the width direction tends to be constant, which is preferable. The smaller the thickness variation rate value, the more preferable it is. Film thickness variation rate in the width direction = {(maximum thickness - minimum thickness) ÷ average thickness} × 100 (%) Formula 1

[0039] The static friction coefficient and dynamic friction coefficient between the outer and inner film surfaces of the biaxially oriented polyester film of the master roll are preferably 0.20 to 0.60, more preferably 0.23 to 0.50, and most preferably 0.25 to 0.40. If it is 0.20 or more, the film does not slip too much, and it is preferable that the film does not easily slip when it is wound around the core. If it is 0.60 or less, the amount of air entrained during slitting is not large, and even if air escapes between the films in the film roll after winding and between the protrusions formed on the film surface, the film is less likely to slacken or wrinkle.

[0040] The arithmetic mean height of the inner surface of the roll of the biaxially oriented polyester film of the master roll is preferably 0.010 to 0.050 μm. When the arithmetic mean height of the inner surface of the roll of the film surface is 0.010 μm or more, adhesion between the films in the film roll (blocking phenomenon) is unlikely to occur, and abnormal noise (sound of the adhered film peeling off) is unlikely to occur when unwinding from the master roll, and the film is unlikely to break, which is preferable. In addition, when the arithmetic mean height of the inner surface of the roll of the film surface is 0.050 μm or less, the surface protrusions on the surface of the biaxially oriented polyester film in the film roll that has been slit and wound around the core, which lead to missing or defects in the coat or vapor-deposited thin film after secondary processing, are reduced, and the quality of the coated film is unlikely to deteriorate, which is preferable. The arithmetic mean height of the outer surface of the roll of the film surface is also preferably in the same range.

[0041] [Film roll] In the slitting process described below, the master roll is slit to the width described below while applying tension in the longitudinal direction of the film and further applying pressure from a contact roll from above the film roll, and then wound up on a core and shipped as a polyester fill roll suitable for the product.

[0042] The width of the polyester film roll of the present invention is preferably 400 mm or more and 3000 mm or less. If the width of the film roll is 400 mm or more, the cost per film area in the subsequent deposition processing and printing processing is not high, which is preferable. In addition, if the width of the film roll is 3000 mm or less, it is preferable from the viewpoint of handling in secondary processing. The width of the film roll is more preferably 500 mm or more and 2500 mm or less, and particularly preferably 600 mm or more and 2300 mm or less. The length of the master roll is preferably 10,000 to 100,000 mm. If the length of the roll is 5,000 mm or more, the cost per film area in the subsequent slitting process, deposition processing, and printing processing is preferably low.

[0043] The biaxially oriented polyester film unwound from the obtained master roll is slit to a specified width and length using a slitter and wound around a core to obtain a polyester film roll. The core used for the biaxially oriented polyester film roll of the present invention is not particularly limited, and generally, a cylindrical core made of plastic, metal, or cardboard having a diameter of 3 inches (37.6 mm), 6 inches (152.2 mm), 8 inches (203.2 mm), etc. can be used.

[0044] The tension applied to the film in the longitudinal direction during the slitting process and the pressure applied from the contact roll from above the film roll (hereinafter referred to as surface pressure) are particularly important in controlling the winding hardness of the film roll surface and in the film roll. Examples of specific suitable slitting conditions will be described in the order of progression of the slitting process.

[0045] [When winding begins] (1) The winding tension (initial tension) applied to the film when winding onto the core is started is preferably 50 N / m to 100 N / m, more preferably 60 N / m to 80 N / m. If the initial tension is 50 N / m or less, the winding hardness of the core is low, which is preferable because wrinkles are less likely to occur when the film running speed increases at the start of winding. Also, if the initial tension is 110 N / m or less, the hardness is not too high, which is preferable because the paper tube that serves as the winding core of the film roll is less likely to deform.

[0046] (2) The surface pressure (initial surface pressure) of the contact roll at the start of winding is preferably 500N / m or more and 800N / m or less. If the initial surface pressure is 500N / m or more, it has the effect of pressing the film when the film running speed increases at the start of winding, and wrinkles are less likely to occur, which is preferable. Furthermore, the winding is not too soft, and when the film roll is stored for a long period of time (for example, six months) in a warehouse, the air caught in the film roll at the time of slitting escapes between the films, which causes distortion of the film roll, slackness and wrinkles of the film, which are less likely to occur, and it is preferable. In addition, if it is 800N / m or less, the hardness of the film roll is not too high, and the paper tube that is the core of the roll is less likely to deform, which is preferable. More preferably, it is 550N / m or more and 750N / m or less, and particularly preferably, it is 600N / m or more and 700N / m or less.

[0047] [From the start of winding, up to a winding diameter of 200-300 mm] (1) The acceleration of the film running speed from the start of winding to the winding diameter of 200 to 300 mm is 50 m / min. 2 More than 200m / min 2 Less than 75m / min is preferable. 2 More than 175m / min 2 More preferably, the film running speed is accelerated to 50 m / min. 2 If the acceleration is 200 m / min or more, wrinkles are less likely to occur near the core (core layer) when the film running speed is increased, which is preferable. 2If the thickness is less than this, edge misalignment is less likely to occur near the core (core layer) when the film running speed is increased, which is preferable. If wrinkles or edge misalignment occurs near the core (core layer), these wrinkles and edge misalignment will continue to occur thereafter. The winding diameter here means the distance (mm) obtained by subtracting the diameter of the winding core from the diameter of the wound film roll.

[0048] [From winding diameter 200-300mm to the end of winding] (1) The film running speed from a winding diameter of 200 to 300 mm is preferably constant, and the film running speed is preferably 400 m / min or more and 800 m / min or less, and more preferably 500 m / min or more and 700 m / min or less.

[0049] [From the start of winding to the end of winding] (1) The winding tension applied to the film from the start to the end of winding is preferably constant or gradually increased, and is preferably 50 N / m or more and 100 N / m or less, and more preferably 60 N / m or more and 80 N / m or less. (2) The contact roll surface pressure from the start of winding to the end of winding is preferably constant or gradually increased, and the surface pressure increase rate, which indicates the ratio of the contact roll surface pressure at the end of winding (final surface pressure) to the contact roll surface pressure at the start of winding (initial surface pressure), is preferably 100% or more and 190% or less. The surface pressure increase rate is calculated using the following formula 2. Surface pressure increase rate = (surface pressure at the end of winding ÷ initial surface pressure) × 100... Formula 2

[0050] If the surface pressure increase rate is 200% or less, the difference in the change in winding hardness when the surface pressure is changed from the initial surface pressure to the final surface pressure as the winding progresses is small, so that wrinkles in the shape of flower patterns or wheel spokes, called spoked wrinkles, are less likely to occur on the end surface of the film roll, which is preferable. More preferably, it is 110% to 180%, and particularly preferably 120% to 170%. It is presumed that the greater the surface pressure increase rate during winding, the greater the difference in the change in winding hardness in the radial direction of the film roll, and the greater the stress applied in the radial direction of the roll when the film is wound, which, in turn, is related to the stretching of the film in the width direction near the end face of the film roll, causing spoked wrinkles. It is preferable that the variation rate of winding hardness from the surface of the polyester film roll to the core is 3% to 10%.

[0051] [When winding is complete] The contact roll surface pressure at the end of winding (final surface pressure) is preferably 700 N / m to 950 N / m. If the final surface pressure is 700 N / m or more, the winding does not become too soft, and the end surface misalignment of the film roll surface layer is unlikely to occur.

[0052] [Characteristics of polyester film roll] [Roll length] The winding length of the polyester film roll of the present invention is preferably 2000 m or more and 65000 m or less. Here, the winding length refers to the length of the film in the longitudinal direction from the point where 5 m is removed from the film end of the film roll when the film is unwound from the film end of the film roll to the point 100 m in the longitudinal direction from the film end fixed to the core toward the film roll's outermost surface. If the winding length is 2000 m or more, the time and effort required for frequent film roll replacement during the printing process is reduced, which is preferable in terms of cost. In addition, the longer the winding length, the better, but if it is 65000 m or less, the roll diameter will not be too large and the roll weight will not be too heavy, which is preferable because handling properties will not be reduced. [Roll width] The winding width of the polyester film roll of the present invention is preferably 400 mm or more and 3000 mm or less. Here, the winding width refers to the shortest distance from one end to the other end of the film roll surface. When the winding width is 400 mm or more, the time and effort required for frequently replacing the film roll in the printing process is reduced, which is preferable in terms of cost. In addition, the winding width is preferably longer, but when it is 3000 mm or less, the roll width does not become too large and the roll weight does not become too heavy, which is preferable because handling properties are not reduced. The winding width is more preferably 1000 mm or more and 3000 mm or less, and even more preferably 1500 mm or more and 3000 mm or less.

[0053] [Roll hardness] The average winding hardness of the surface of the polyester film roll of the present invention is preferably in the range of 500 to 700 when measured at intervals of 200 mm in the width direction of the film. "Surface of the film roll" refers to the surface of the film roll after unwinding the film from the outermost film edge of the film roll and removing the area up to 5 m from the film edge. The measurement points in the width direction of the surface of the film roll shall be the position 5 cm in the width direction from the end of the film where the winding direction of the film from the core of the film roll to the outermost surface turns clockwise, and then the position further moved 200 mm from that position. If the final position is less than 5 cm from the end of the film, it shall be excluded from the calculation. The winding hardness is measured using a hardness tester, Parotester 2, manufactured by Proseo, Switzerland. When the average winding hardness in the width direction is 500 or more, the winding of the film roll is unlikely to come undone, or the end faces are unlikely to shift, and the end faces are likely to be aligned (so-called no winding shift). When the average winding hardness in the width direction is 700 or less, localized strong charging or discharge marks, called static marks, caused by electrostatic discharge, etc., are unlikely to occur on the film surface in the film roll, and spots or missing of the coating or vapor deposition thin film are unlikely to occur during secondary processing such as coating or vapor deposition, and the quality is unlikely to deteriorate, which is preferable. The average winding hardness is more preferably 650 or more and 690 or less. The winding hardness in the present invention is measured using a hardness tester, Parotester 2, manufactured by Proseo, Switzerland.

[0054] The variation rate of the winding hardness of the surface of the polyester film roll of the present invention, measured at intervals of 200 mm in the width direction of the film roll, is preferably 1% to 5%. The variation rate of the winding hardness is calculated by the following formula 3. Variation rate of winding hardness in the width direction of a film roll = (Maximum value of winding hardness - Minimum value of winding hardness) ÷ Hardness × 100 (%) Formula 3

[0055] If the variation rate of the winding hardness exceeds 5%, the film roll is likely to become misaligned during winding, which causes partial sagging in the film roll and makes it easier for the film to deform or wrinkle due to the tension applied during secondary processing such as coating or deposition, making it difficult to perform stable coating or deposition thin film, which is undesirable. Although a variation rate of the winding hardness of 0% is ideal, this is practically difficult to achieve, and the lower limit is thought to be 1% at most.

[0056] The polyester film roll of the present invention preferably has a hardness variation of 3% to 10% when measured at 10 sections in the longitudinal direction from the surface to the core. The hardness variation is calculated by the following formula 4. Hardness variation (longitudinal direction) = (maximum hardness - minimum hardness) ÷ hardness × 100 (%) Equation 4

[0057] Here, dividing the polyester film roll into 10 parts in the longitudinal direction from the surface to the core means that the film is unwound from the film end on the outermost surface of the film roll, and then divided into 10 parts from a point 5 m removed from the film end to a point 100 m longitudinally from the film end fixed to the core toward the outermost surface of the film roll. The film is wound up to each division position, and the winding hardness of the surface of the film roll is measured at intervals of 200 mm in the width direction of the film. The measurement points in the width direction of the surface of the film roll shall be the position 5 cm in the width direction from the end of the film where the winding direction of the film from the core of the film roll to the outermost surface turns clockwise, and then the position further moved 200 mm from that position. If the final position is less than 5 cm from the end of the film, it shall be excluded from the calculation. If the variation rate of winding hardness exceeds 10%, the difference in winding hardness between layers at different positions in the film roll will become large, so the stress applied in the roll radial direction during winding of the film will become large, making it easier for spoked wrinkles to occur and causing partial sagging in the film, which will make it easier for deformation and wrinkles to occur in the film due to tension during secondary processing such as coating and vapor deposition, and will tend to degrade the quality of the coated film, which is undesirable. Although a variation rate of winding hardness of 0% is ideal, this is practically difficult to achieve, and the lower limit is thought to be 3% at most.

[0058] [Film thickness] The arithmetic mean height of the inner surface of the polyester film roll of the present invention is preferably 0.010 to 0.050 μm. If the arithmetic mean height is 0.010 μm or less, adhesion (blocking phenomenon) between the films in the roll occurs, and when the polyester film roll is unwound for secondary processing, abnormal noise (sound of the adhered film peeling off) occurs or the film breaks, which is not preferable. In addition, if the arithmetic mean height of the film exceeds 0.050 μm, the quality of the coated film that is secondary processed by coating or deposition is likely to decrease, which is not preferable. The thickness of the polyester film roll of the present invention is preferably 5 to 40 μm. If it is 5 μm or more, the film is less likely to have insufficient strength or a significant decrease in stiffness, and is less likely to wrinkle in the film roll, which is preferable. On the other hand, even if the film thickness is thick, there is no problem as a film roll, but it is preferable to make the film thinner from the viewpoint of cost. The film thickness is more preferably 8 to 30 μm, and particularly preferably 9 to 20 μm.

[0059] [Film thickness variation rate] The thickness variation rate of the biaxially oriented polyester film in the width direction of the polyester film roll of the present invention is preferably 10% or less. The thickness variation rate is measured using a continuous contact type thickness meter as shown in the examples. The thickness variation rate in the width direction of the film is calculated by the following formula 1, by continuously measuring the thickness in the width direction at 5 m / sec using a continuous thickness meter. It is preferable that the thickness variation rate in the width direction of the film is 10% or less, since the film is less likely to wrinkle. The smaller the thickness variation rate in the width direction of the film, the more preferable it is. Thickness variation rate in the film's width direction = {(maximum thickness - minimum thickness) ÷ average thickness} × 100 (%) Formula 1

[0060] [Arithmetic mean height] The arithmetic mean height of the inner surface of the polyester film roll of the present invention is preferably 0.010 to 0.050 μm. If the arithmetic mean height is 0.010 μm or less, adhesion (blocking phenomenon) between the films in the roll occurs, and when the polyester film roll is unwound for secondary processing, abnormal noise (sound of the adhered film peeling off) occurs or the film breaks, which is not preferable. In addition, if the arithmetic mean height of the film exceeds 0.050 μm, the quality of the coated film that is secondary processed by coating or deposition is likely to decrease, which is not preferable. [Static friction coefficient, dynamic friction coefficient]

[0061] The static friction coefficient and dynamic friction coefficient between the film surfaces of the outer and inner winding surfaces of the biaxially oriented polyester film of the polyester film roll of the present invention are preferably 0.20 to 0.60, more preferably 0.23 to 0.50, and most preferably 0.25 to 0.40. If it is lower than 0.20, it is not preferable because it is too slippery and winding slippage occurs. On the other hand, if it is higher than 0.60, the amount of air entrained during slitting increases, and slack or wrinkles may easily occur due to air escaping from the recesses when the film is rolled.

[0062] [Film roll misalignment] The height of the unevenness on the end face of the film roll is preferably 3 mm or less, and more preferably 2 mm or less. If the height of the unevenness is 3 mm or less, the film is less likely to wrinkle and tends to run smoothly during secondary processing.

[0063] [Wrinkles in film roll] It is preferable that no wrinkles are visible when A4-sized film is taken from two locations: the outermost layer of the film roll immediately after production, and a location 100 m away from the end of the film fixed to the core after unwinding the film roll toward the surface of the film roll and observed under fluorescent lighting.

[0064] [Spoke wrinkles on the edge of the film roll] The length of the flower pattern or wheel spoke-like wrinkles on the edge of the film roll is measured, and it is preferable that there are no wrinkles with a length of 30 mm or more. In this case, there is less unevenness or loss of the coating or evaporated thin film after secondary processing.

[0065] [Static Mark] The film roll is placed on a slitter, the film is unwound from the film edge on the outermost surface of the film roll, and 4 m is removed from the film edge, after which the film is sampled at 10 cm in the center in the width direction and 10 cm in the length direction, and the charge state of the film surface is visualized using a charge distribution determination toner manufactured by Kasuga Electric Co., Ltd. It is preferable that no localized strong charge or discharge marks are visible. In this case, it is easy to reduce spots and voids in the coat and vapor-deposited thin film after secondary processing. EXAMPLES

[0066] The present invention will be described in more detail below with reference to examples. However, the present invention is not limited to the embodiments of the examples, and can be modified as appropriate without departing from the spirit of the present invention.

[0067] The polyester resin was evaluated as follows. [Glass transition temperature (Tg)] Using a differential scanning calorimeter (DSC6220, manufactured by SII NanoTechnology Inc.), the sample was melted to 280°C under a nitrogen atmosphere, held for 5 minutes, then rapidly cooled in liquid nitrogen and measured at a heating rate of 20°C / min from room temperature.

[0068] [Intrinsic viscosity (IV)] 0.2 g of polyester was dissolved in 50 ml of a mixed solvent of phenol / 1,1,2,2-tetrachloroethane (60 / 40 (weight ratio)), and the viscosity was measured using an Ostwald viscometer at 30° C. The unit is dl / g.

[0069] The polyester film roll was evaluated as follows. [Film thickness] The measurement was performed using a dial gauge in accordance with JIS K7130-1999 Method A.

[0070] [Film thickness variation rate] The film roll was placed on a slitter. The film was then unwound from the outermost end of the film roll, and 1 m was removed from the end of the film, after which the film was sampled over the entire width in the width direction and 40 mm in the length direction, and the thickness in the width direction was measured continuously at 5 m / sec using a film tester continuous thickness measuring device manufactured by Fujiwork Co., Ltd. The thickness variation rate was calculated using the following formula 1. Thickness variation rate in the film's width direction = {(maximum thickness - minimum thickness) ÷ average thickness} × 100 (%) Formula 1

[0071] [Arithmetic mean height] The film roll was placed on a slitter. After that, the film was unwound from the outermost edge of the film roll, and 2 m was removed from the edge. The film was then sampled at 10 cm from the center in the width direction and 10 cm in the length direction, and a white laser interferometer (NEW VIEW8300) manufactured by Zygo was used. A 20x lens was attached to the interferometer, scanning was performed, and the arithmetic mean height (μm) was measured. The measurement was performed over a range of 0.82μm in the MD direction and 0.82μm in the width direction on one surface, excluding unmelted material, dust, and other foreign matter. The measurement points were 10 randomly selected points on a 10 cm x 10 cm sample, and the average value was used as the measurement value.

[0072] [Coefficient of friction] The film roll was placed on a slitter. After that, the film was unwound from the film edge on the outermost surface of the film roll, and 3 m was removed from the film edge, after which the film was sampled at 10 cm in the center of the width direction and 10 cm in the length direction. In accordance with JIS K-7125, a tensile tester (A&D Tensilon RTG-1210) was used to determine the static and dynamic friction coefficients when the inner and outer surfaces of the film roll were joined together under an environment of 23°C and 65% RH. The weight of the thread (weight) on which the upper film was wrapped was 1.5 kg, and the size of the base area of ​​the thread was 39.7 mm2. The tensile speed during the friction measurement was 200 mm / min.

[0073] [Static Mark] The film roll was placed on a slitter. After that, the film was unwound from the outermost end of the film roll, and 4 m was removed from the end of the film, after which the film was sampled at a length of 10 cm from the center in the width direction and 10 cm in the longitudinal direction, and the charge state of the film surface was visualized using a charge distribution determination toner manufactured by Kasuga Electric Co., Ltd. When strong localized static charge or discharge marks were visible, it was judged as having static marks (×), and when no static marks were visible, it was judged as not having static marks (○). After the measurement, the film roll was rewound to the intermediate layer using a slitter, and the static charge evaluation of the film roll was performed using the method described above. The film roll was further rewound to the core layer, and the static charge evaluation of the film roll was repeated.

[0074] [Film roll surface hardness] The hardness of the film roll was measured using a hardness tester, Paro Tester 2, manufactured by Proseo, Switzerland. Specifically, the film roll of the present invention, which was wound on a slitter, was evaluated by repeatedly unwinding the roll and measuring the hardness using a film unwinder. The hardness of the outermost layer was measured at intervals of 200 mm in the roll width direction after removing 5 m of the film from the roll, and the average winding hardness was calculated. "Surface of the film roll" refers to the surface of the film roll after unwinding the film from the outermost film edge of the film roll and removing the area up to 5 m from the film edge. The measurement points in the width direction of the surface of the film roll shall be the position 5 cm in the width direction from the end of the film where the winding direction of the film from the core of the film roll to the outermost surface turns clockwise, and then the position further moved 200 mm from that position. If the final position is less than 5 cm from the end of the film, it shall be excluded from the calculation.

[0075] [Variation rate of winding hardness in the width direction of the film roll surface] The value obtained in (1) was used to calculate the value using the following formula 3. Variation rate of winding hardness in the width direction of the film roll surface = (Maximum value of winding hardness - Minimum value of winding hardness) ÷ Hardness × 100 (%) Formula 3

[0076] [Variation rate of winding hardness in the longitudinal direction of a film roll] The film was unwound from the film end on the outermost surface of the film roll, and divided into 10 sections from a point 5 m removed from the film end to a point 100 m in the longitudinal direction from the film end fixed to the core toward the outermost surface of the film roll. The film was wound up to each division position, and the winding hardness of the surface of the film roll was measured at intervals of 200 mm in the film width direction in the same manner as in (1) above, and the value was calculated using the following formula 42. Variation rate of winding hardness in the longitudinal direction of a film roll = (maximum hardness - minimum hardness) ÷ hardness × 100 (%) Equation 4

[0077] [Film roll misalignment] The presence or absence of irregularities and their height on the end face of the film roll were measured. If there were no irregularities on the end face of the roll, or if there were irregularities but the height was 3 mm or less, it was judged as no winding misalignment (○), and if there were irregularities exceeding 3 mm, it was judged as having winding misalignment (×).

[0078] [Wrinkles in film roll] To evaluate wrinkles, A4-sized film was taken from two locations: the outermost layer of the film roll immediately after production, and a location 100 m away from the end of the film fixed to the core after the film roll was unwound. When observed under fluorescent light, if wrinkles were visible, it was judged as having wrinkles (×), and if no wrinkles were visible, it was judged as not having wrinkles (○).

[0079] [Spoke wrinkles on the edge of the film roll] The length of the spoked wrinkles (floral patterns or wheel spoke-like wrinkles) on the end surface of the film roll was measured, and wrinkles longer than 30 mm were rated as NG (×), and those without wrinkles or those less than 30 mm in length were rated as OK (○).

[0080] [Example 1] Polyethylene terephthalate (intrinsic viscosity = 0.62 dl / g, Tg = 78 ° C) containing 0.15 wt % of silica with an average particle size of 2.4 μm was dried and then fed to an extruder, melted at 285 ° C, extruded from a T-shaped die, and cooled and solidified in a casting drum to obtain an unstretched polyethylene terephthalate sheet. This sheet was heated to 115 ° C and stretched in the longitudinal direction at a total stretch ratio of 4.5 times by three-stage stretching, with the first stage being 1.24 times, the second stage being 1.4 times, and the third stage being 2.6 times. Subsequently, the sheet was stretched in the width direction at a temperature of 140 ° C and a stretch ratio of 4.3 times, heat-set at 245 ° C, and heat-relaxed by 5% in the width direction. Next, both ends of the stretched film were cut and removed, and then the film was subjected to a corona discharge treatment and wound up into a roll using a winder to produce a master roll of biaxially oriented polyester film with a thickness of 12 μm (winding length 68,000 m, width 8,000 mm). The biaxially oriented polyester film was unwound from the obtained master roll and slit to a width of 2200 mm onto a core having a diameter of 6 inches (152.2 mm). The film roll was wound up while applying surface pressure to the film roll with a contact roll and tension to the film with a two-axis turret winder. The conditions at that time are shown in Table 1. The physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0081] [Example 2] The procedure was the same as in Example 1, except that the slit tension was 105 N / m, and the contact roll surface pressure was changed to an initial surface pressure of 700 N / m and a final surface pressure of 700 N / m. The slit conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film and master roll are shown in Table 2.

[0082] [Example 3] Except for changing the initial contact roll surface pressure to 700 N / m, the same procedure was followed as in Example 1. Table 1 shows the slitting conditions, and Table 2 shows the physical properties and evaluation results of the obtained film roll.

[0083] [Example 4] Slit acceleration: 100m / min 2The same procedures were carried out as in Example 1, except that the initial surface pressure of the contact roll was changed to 700 N / m. The slitting conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0084] [Example 5] Slit acceleration: 100m / min 2 The same procedure was followed as in Example 1, except that the slitting tension was 75 N / m, and the initial contact roll surface pressure was 700 N / m. The slitting conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0085] [Comparative Example 1] Except for changing the initial surface pressure of the contact roll to 450 N / m, the same procedure was followed as in Example 1. Table 1 shows the slitting conditions, and Table 2 shows the physical properties and evaluation results of the obtained film roll.

[0086] [Comparative Example 2] Except for changing the contact roll surface pressure to 300 N / m at the initial stage and 650 N / m at the final stage, the procedure was the same as in Example 1. Table 1 shows the slitting conditions, and Table 2 shows the physical properties and evaluation results of the obtained film roll.

[0087] [Comparative Example 3] Except for changing the final contact roll surface pressure to 500 N / m, the same procedure was followed as in Example 1. Table 1 shows the slitting conditions, and Table 2 shows the physical properties and evaluation results of the obtained film roll.

[0088] [Comparative Example 4] The winding tension was changed to 62 N / m during winding and 59 N / m at the end, but the same procedure was followed as in Example 1. The slitting conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0089] [Comparative Example 5] Slit acceleration: 250m / min 2The slitting conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0090] [Comparative Example 6] Slit acceleration: 50m / min 2 The same procedure was followed as in Example 1, except that the slit tension was 55 N / m, and the contact roll surface pressure was changed to an initial surface pressure of 350 N / m and a final surface pressure of 450 N / m. The slit conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0091] [Comparative Example 7] Slit acceleration: 50m / min 2 The same procedure was followed as in Example 1, except that the slit tension was 85 N / m, and the contact roll surface pressure was changed to an initial surface pressure of 900 N / m and a final surface pressure of 1100 N / m. The slit conditions are shown in Table 1, and the physical properties and evaluation results of the obtained film roll are shown in Table 2.

[0092] As a result of the evaluation, the films and master rolls of Examples 1 to 5 had average hardness, hardness variation, and arithmetic mean height of the film rolls that were within the specified ranges, so that no wrinkles occurred on the surface layer or core of the roll immediately after winding up through the slit, no winding shift, and no spoked wrinkles on the end faces, and no static marks or discharge marks were generated, making them film rolls with excellent vapor deposition processability.

[0093] In Comparative Example 1, the average hardness and variation of the outermost layer of the film roll were within the specified range, but the variation in hardness when measured in 10 sections from the outermost layer to the core was outside the specified range. Also, since the surface pressure increase rate was high, the difference in hardness when changing from the initial surface pressure to the final surface pressure as winding progressed was too large, resulting in spoked wrinkles, and the film roll had poor secondary processability.

[0094] In Comparative Example 2, the average hardness and variation of the outermost layer of the film roll were within the specified range, but the variation in hardness when measured in 10 sections from the outermost layer to the core was outside the specified range. The surface pressure increase rate was high, so the difference in hardness when changing from the initial surface pressure to the final surface pressure as winding progressed was too large, resulting in spoked wrinkles. In addition, the initial surface pressure of the contact roll was low, so winding misalignment occurred, resulting in a film roll with poor secondary processability.

[0095] In Comparative Example 3, the final surface pressure was too low, so that winding slippage and wrinkles occurred, resulting in a film roll with poor secondary processability.

[0096] In Comparative Example 4, the final winding tension was low, and the difference in hardness when changing to the final surface pressure was too large, resulting in spoked wrinkles, and the film roll had poor secondary processability.

[0097] In Comparative Example 5, the acceleration rate when the film speed increased at the start of winding was high, which resulted in large variations in the hardness of the outermost layer of the film roll, making the film roll more likely to sag and causing winding misalignment, resulting in a film roll with poor secondary processability.

[0098] The film of Comparative Example 6 had a low average hardness value of the film roll, and therefore, the film roll did not slip during winding, resulting in a film roll with poor secondary processability.

[0099] In Comparative Example 7, the average hardness of the film roll was high, so that static marks and discharge marks were generated, resulting in a film roll with poor secondary processability. [Industrial Applicability]

[0100] The biaxially oriented polyester film roll of the present invention has few wrinkles or defects on the film surface, is free from winding slippage, and is suitable for secondary processing such as coating and deposition. Furthermore, the quality of the coated film after secondary processing is excellent, and it can be suitably used as a food packaging film. It is particularly useful for film rolls that have been made wider and longer with improved productivity.

[0101]

Table 1

[0102]

Table 2

Claims

1. A polyester film roll for food packaging, which is obtained by winding a biaxially oriented polyester film made of a polyethylene terephthalate resin composition having a thickness of 9 μm or more and which may contain 10 mol % or less of a copolymerization component around a core, has a width of 1000 mm or more and a winding length of 2000 m to 65000 m, and is characterized in that the polyester film roll satisfies the following requirements (1) to (3): (1) The average winding hardness of the surface of the polyester film roll is in the range of 500 or more and 700 or less. (2) The variation rate of the winding hardness of the surface of the polyester film roll in the film width direction is 1% or more and 5% or less. (3) The variation rate of winding hardness from the surface of the polyester film roll to the winding core is 3% or more and 10% or less.

2. 2. The polyester film roll according to claim 1, wherein the biaxially oriented polyester film has a thickness variation rate in a width direction of 10% or less.

3. 3. The polyester film roll according to claim 1, wherein the coefficient of dynamic friction of the outer surface and the inner surface of the biaxially oriented polyester film is 0.2 or more and 0.60 or less.

4. 4. The polyester film roll according to claim 1, wherein the biaxially oriented polyester film has an arithmetic mean height of one of the inner roll surfaces of 0.010 μm or more and 0.050 μm or less.

5. 5. The polyester film roll according to claim 1, wherein the biaxially oriented polyester film has a thickness of 40 μm or less.

6. 6. The polyester film roll according to claim 1, wherein the width of the polyester film roll is 3000 mm or less.

7. 7. The polyester film roll according to claim 1, wherein the biaxially oriented polyester film is used as a substrate for a vapor deposition film.

Images