Sterilization and purification equipment
The sterilization and purification device addresses the challenge of disinfecting and maintaining photocatalytic action by using a dual-light emitting element system to ensure effective ultraviolet light distribution across the filter, achieving efficient and cost-effective bacterial and viral inactivation.
Patent Information
- Application Number
- JP2021145960
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2021-09-08
- Publication Date
- 2025-04-10
- Estimated Expiration
- 2041-09-08
AI Technical Summary
Existing sterilization and purification devices face challenges in effectively disinfecting and inactivating bacteria and viruses attached to filters, while also maintaining the photocatalytic action over time, due to limited ultraviolet light reach and increased costs with additional light sources.
The device incorporates a photocatalyst filter with a sheet and supported photocatalyst, a light source with both first and second light emitting elements, and a filter opposed to the photocatalyst filter. The second light emitting element irradiates ultraviolet light with a shorter peak wavelength, which passes through the photocatalyst filter to disinfect the upstream filter, thereby maintaining photocatalytic action and reducing costs.
This configuration allows for effective disinfection and inactivation of bacteria and viruses on the filter with a simple structure, while suppressing the decrease in photocatalytic action over time, thus providing a cost-effective and efficient sterilization and purification solution.
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Abstract
Description
[Technical field]
[0001] An embodiment of the present invention relates to a sterilization and purification device. [Background technology]
[0002] Reflecting the growing health consciousness, there is an increasing demand for gas purification (e.g., air purification) and sterilization and inactivation of bacteria and viruses in so-called closed spaces such as the inside of trains and automobiles, inside refrigerators, living spaces, etc. For example, there is an increasing demand for the removal of ammonia and ethylene generated from food, the removal and deodorization of VOCs (volatile organic compounds) such as acetaldehyde contained in cigarette smoke, and the sterilization and inactivation of bacteria and viruses contained in gas.
[0003] For this reason, a photocatalyst device has been proposed that includes a light source having a plurality of light-emitting diodes and a photocatalyst filter carrying a photocatalyst. In addition, foreign matter such as dust contained in the atmosphere in which the sterilization and purification device is installed may be sucked into the sterilization and purification device together with the gas to be treated. If the foreign matter sucked into the sterilization and purification device adheres to the photocatalytic filter or the light-emitting diode, the function of the sterilization and purification device may be deteriorated. Therefore, a filter (also called a pre-filter) that captures foreign matter in the gas flow direction may be provided upstream of the photocatalytic filter.
[0004] In general, a photocatalyst filter carries a so-called ultraviolet light responsive photocatalyst. Therefore, a light emitting diode that irradiates ultraviolet light is used as a light source. Since ultraviolet light has a bactericidal effect, a photocatalyst device equipped with a light emitting diode that irradiates ultraviolet light can purify gas by active oxygen species generated by photocatalysis, and can sterilize or inactivate bacteria and viruses to a certain extent by the generated active oxygen species and ultraviolet light.
[0005] In this case, even if ultraviolet light is irradiated onto the filter installed upstream of the photocatalytic filter, the photocatalytic action does not occur. Therefore, in general, in order to increase the utilization efficiency of the ultraviolet light irradiated from the light-emitting diode, the amount of ultraviolet light passing through the photocatalytic filter is reduced. As a result, in general, the ultraviolet light irradiated from the light-emitting diode hardly reaches the filter installed upstream of the photocatalytic filter.
[0006] When gas is sucked into the sterilization and purification device, bacteria and viruses contained in the gas may adhere to the filter. Since the ultraviolet light emitted from the light-emitting diode hardly reaches the filter, bacteria and viruses cannot be sterilized or inactivated by ultraviolet light. Therefore, the infectiousness of bacteria and viruses attached to the filter is maintained for a certain period of time, so that if an operator touches the filter during maintenance, the operator may become infected with bacteria or viruses.
[0007] In this case, it is possible to further provide a light source for irradiating the filter with ultraviolet light, but this would result in an increase in size, cost, and installation space of the sterilization and purification device. Furthermore, when a photocatalytic filter and a light-emitting diode that irradiates ultraviolet light are provided, the photocatalytic effect may decrease over time. Therefore, it is possible to sterilize and inactivate bacteria and viruses attached to the filter with a simple configuration. In addition, the photocatalytic activity can be prevented from decreasing over time. There was a need for the development of a sterilization and purification device that could do this. [Prior art documents] [Patent documents]
[0008] [Patent Document 1] JP 2011-218073 A Summary of the Invention [Problem to be solved by the invention]
[0009] The problem to be solved by the present invention is to provide a method and apparatus for removing and inactivating bacteria and viruses attached to a filter using a simple structure. In addition, the photocatalytic activity can be prevented from decreasing over time.The object of the present invention is to provide a sterilization and purification device. [Means for solving the problem]
[0010] The sterilization and purification device according to the embodiment includes a photocatalytic filter having a sheet and a photocatalyst supported on the sheet; a light source facing the photocatalytic filter and having a first light-emitting element and a second light-emitting element; and a filter facing the photocatalytic filter and provided on the opposite side of the photocatalytic filter from the light source side. The first light-emitting element irradiates a first light toward the photocatalytic filter. The second light-emitting element irradiates a second light, which is ultraviolet light having a shorter peak wavelength than the first light, toward the photocatalytic filter. A part of the second light irradiated to the photocatalytic filter is transmitted through the photocatalytic filter and irradiated to the filter. When the light source irradiates light, gas is released from the light source. The gas to be treated flows from the filter side toward the light source side, and the flow of the gas to be treated prevents the released gas from reaching the photocatalyst filter. Effect of the Invention
[0011] According to the embodiment of the present invention, it is possible to sterilize or inactivate bacteria and viruses attached to a filter with a simple configuration. In addition, the photocatalytic activity can be prevented from decreasing over time. It is possible to provide a sterilization and purification device. [Brief description of the drawings]
[0012] [Figure 1] FIG. 2 is a schematic exploded view illustrating the sterilization and purification device according to the present embodiment. [Diagram 2] FIG. 2 is a schematic cross-sectional view of the sterilization and purification device in FIG. 1 taken along line AA. [Diagram 3] FIG. 11 is a schematic cross-sectional view illustrating a sterilization and purification device according to a comparative example. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0013] Hereinafter, an embodiment will be described with reference to the drawings. In the drawings, the same components are denoted by the same reference numerals, and detailed description thereof will be omitted as appropriate. FIG. 1 is a schematic exploded view illustrating a sterilization and purification device 1 according to this embodiment. FIG. 2 is a schematic cross-sectional view of the sterilization and purification device 1 in FIG. 1 taken along line AA. As shown in FIGS. 1 and 2, a sterilization and purification device 1 includes, for example, a frame 2, a lid 3, a light source 4, a photocatalytic filter 5, and a filter 6.
[0014] The frame 2 has a box shape. When viewed from the inflow side of the gas G, the outline of the frame 2 can be a substantially rectangular shape. The outline of the frame 2 can also be, for example, a substantially polygonal shape or a substantially circular shape. However, in consideration of the attachment and detachment of the light source 4, the photocatalytic filter 5, and the filter 6 described later and space efficiency, it is preferable that the outline of the frame 2 be a substantially rectangular shape.
[0015] One end 2a of the frame 2 is open. The end 2b of the frame 2 opposite the end 2a is closed. One side surface 2c of the frame 2 is provided with a hole 2c1. The side surface 2d of the frame 2 opposite the side surface 2c is provided with a hole 2d1.
[0016] The hole 2c1 in the side surface 2c and the hole 2d1 in the side surface 2d serve as an inlet or an outlet for the gas G to be treated. In this case, as shown in Fig. 2, for example, the hole 2c1 in the side surface 2c can serve as an inlet for the gas G, and the hole 2d1 in the side surface 2d can serve as an outlet for the gas G. When the hole 2d1 serves as an outlet, a fan 7 may be provided on the side surface 2d.
[0017] The fan 7 is provided on the opposite side of the light source 4 from the photocatalytic filter 5 side. The fan 7 exhausts the gas G inside the frame 2. The fan 7 forms a flow of the gas G that flows from the filter 6 side toward the light source 4 side. The fan 7 is not necessarily required and can be omitted. For example, when the sterilization and purification device 1 is provided in the flow of the gas G, the fan 7 can be omitted.
[0018] The hole 2c1 in the side surface 2c may be an outlet for the gas G, and the hole 2d1 in the side surface 2d may be an inlet for the gas G. In other words, it is only necessary that the gas G flows from the filter 6 side toward the light source 4 side.
[0019] The gas G may be, for example, a gas containing air as a main component and containing the substance to be treated, bacteria, viruses, etc. The substance to be treated may be any substance that can be purified by photocatalysis. The substance to be treated may be, for example, ammonia, ethylene, acetaldehyde, and other VOCs.
[0020] Furthermore, a lattice or the like may be provided on at least one of the side surface 2c and the side surface 2d of the frame 2. If a lattice is provided, it is possible to prevent fingers or foreign objects from entering the inside of the frame 2.
[0021] A plurality of grooves 2e1 are provided on a side surface 2e of the frame 2 that intersects with the side surface 2c. A plurality of grooves 2f1 are provided on a side surface 2f of the frame 2 that faces the side surface 2e. The plurality of grooves 2e1 and the plurality of grooves 2f1 open to the inside of the frame 2. The plurality of grooves 2e1 and the plurality of grooves 2f1 are provided side by side between the side surface 2c and the side surface 2d of the frame 2. The plurality of grooves 2e1 and the plurality of grooves 2f1 extend between the end portions 2a and 2b of the frame 2.
[0022] The groove 2e1 is provided approximately parallel to the opposing groove 2f1. A plurality of pairs of opposing grooves 2e1, 2f1 are provided. The plurality of pairs of grooves 2e1, 2f1 serve as slots into which the light source 4, the photocatalytic filter 5, and the filter 6 are inserted. In this case, the filter 6, the photocatalytic filter 5, and the light source 4 can be arranged in order from the upstream side of the flow of the gas G. The dimensions of the pair of grooves 2e1, 2f1 can be appropriately changed according to the dimensions of the light source 4, the photocatalytic filter 5, and the filter 6 to be inserted.
[0023] The light source 4, the photocatalytic filter 5, and the filter 6 inserted into the pair of grooves 2e1, 2f1 are approximately parallel to each other. When the photocatalytic filter 5 and the light source 4 are approximately parallel, the ultraviolet light irradiated from the light source 4 can be efficiently incident on the photocatalytic filter 5. Therefore, the photocatalytic filter 5 can efficiently purify the gas G, and can efficiently sterilize and inactivate bacteria and viruses attached to the photocatalytic filter 5.
[0024] If a pair of grooves 2e1, 2f1 into which the light source 4, the photocatalytic filter 5, and the filter 6 are inserted are provided, the light source 4, the photocatalytic filter 5, and the filter 6 can be freely inserted and removed inside the frame 2. This improves maintainability. In addition, it becomes easy to change the specifications of the light source 4 and the photocatalytic filter 5 according to the flow rate of the gas G, the amount of substances contained in the gas G, the light intensity (light amount) of the ultraviolet light irradiated from the light source 4, and the like, and to change the specifications of the filter 6 according to the amount and type of foreign matter contained in the gas G.
[0025] There is no particular limitation on the material of the frame 2. However, if the material of the frame 2 is a thermoplastic resin, the frame 2 can be formed by using an injection molding method, which can reduce the manufacturing cost.
[0026] For example, the material of the frame 2 can be ABS resin (acrylonitrile-butadiene-styrene copolymer synthetic resin). If the material of the frame 2 is ABS resin, it is possible to improve moldability and reduce costs. In this case, if the material of the frame 2 is reinforced ABS resin, it is possible to improve the strength of the frame 2. Note that reinforced ABS resin is ABS resin mixed with glass fiber and the like.
[0027] The material of the frame 2 may be, for example, polypropylene resin or acrylic resin (polymethyl methacrylate resin). In this case, if the material of the frame 2 is acrylic resin, the resistance to the ultraviolet light irradiated from the light source 4 and the resistance to VOCs contained in the gas G are improved. Furthermore, if the degree of polymerization of the acrylic resin is about 10,000 to 15,000, odor generation can be suppressed.
[0028] Furthermore, the frame 2 may be made of a metal. If the frame 2 is made of a metal, it is possible to increase the rigidity of the sterilization and purification device 1. The metal may be, for example, iron, stainless steel, or an aluminum alloy.
[0029] The lid 3 is provided at the end 2a of the frame 2. The lid 3 covers the opening provided at the end 2a. If the lid 3 is provided, the light source 4, the photocatalytic filter 5, and the filter 6 provided inside the frame 2 can be prevented from coming off. In addition, it is possible to prevent foreign matter from entering the inside of the frame 2. The lid 3 can be attached to the frame 2 using a screw or the like. Also, a hook or the like may be provided on the lid 3, and the hook may be held by a recess or a protrusion provided on the frame 2. If the lid 3 is provided detachably on the frame 2, it is possible to improve the maintainability. There is no particular limitation on the material of the lid 3. For example, the material of the lid 3 can be the same as the material of the frame 2.
[0030] At least one light source 4 can be provided. The light source 4 is provided inside the frame 2. The light source 4 faces the photocatalytic filter 5. In the flow direction of the gas G, the light source 4 is preferably provided downstream of the photocatalytic filter 5. The effect of the arrangement of the light source 4 and the photocatalytic filter 5 in the flow direction of the gas G will be described later.
[0031] The light source 4 includes, for example, a substrate 4a, a light emitting element 4b (corresponding to an example of a first light emitting element), and a light emitting element 4c (corresponding to an example of a second light emitting element). The substrate 4a has a plate shape. The substrate 4a is provided in the flow path of the gas G. Therefore, if the substrate 4a is provided, the flow of the gas G may be hindered. In this case, a plurality of holes penetrating in the thickness direction may be provided in the substrate 4a. However, if the size of the holes is small, the pressure loss increases, and the flow of the gas G is hindered. If the size of the holes is large, restrictions arise on the arrangement and number of the light emitting elements 4b and 4c and the wiring patterns.
[0032] 1, the width W1 of the substrate 4a is made smaller than the width W2 of the photocatalytic filter 5. The width is the dimension in the direction in which the pair of grooves 2e1, 2f1 extend. In this way, it is possible to ensure an appropriate flow of gas G and to prevent restrictions on the arrangement and number of the light emitting elements 4b, 4c and the wiring patterns. According to the knowledge obtained by the present inventors, if "W1 (mm) / W2 (mm)" is smaller than 0.5, it is easy to ensure an appropriate flow of gas G.
[0033] There is no particular limitation on the material or structure of the substrate 4a. For example, the substrate 4a can be made of inorganic materials (ceramics) such as aluminum oxide or aluminum nitride, or organic materials such as paper phenol or glass epoxy. The substrate 4a may also be a metal core substrate in which the surface of a metal plate is covered with an insulating material.
[0034] When the light emitting elements 4b and 4c generate a large amount of heat, it is preferable to form the substrate 4a using a material with high thermal conductivity from the viewpoint of heat dissipation. It is also preferable to form the substrate 4a using a material with high resistance to ultraviolet light irradiated from the light emitting elements 4b and 4c. For example, it is preferable to form the substrate 4a from ceramics such as aluminum oxide or aluminum nitride, a metal core substrate, or the like. Furthermore, the substrate 4a may have a single-layer structure or a multi-layer structure.
[0035] The light-emitting element 4b can be provided on the surface of the substrate 4a facing the photocatalytic filter 5. The light-emitting element 4b is electrically connected to, for example, a wiring pattern provided on the surface of the substrate 4a. The type of the light-emitting element 4b is not particularly limited. The light-emitting element 4b can be, for example, a surface-mount type light-emitting element such as a PLCC (Plastic Leaded Chip Carrier) type. The light-emitting element 4b can also be, for example, a light-emitting element having a lead wire such as a bullet type.
[0036] The light emitting element 4b may be mounted by COB (Chip On Board). In the case of mounting the light emitting element 4b by COB, a chip-shaped light emitting element, wiring electrically connecting the light emitting element and the wiring pattern, and a sealing part covering the chip-shaped light emitting element and the wiring can be provided on the substrate 4a.
[0037] At least one light-emitting element 4b may be provided. However, if multiple light-emitting elements 4b are provided, ultraviolet light can be irradiated over a wide area of the photocatalytic filter 5. The multiple light-emitting elements 4b may be connected in series. There is no particular limitation on the arrangement of the multiple light-emitting elements 4b, but it is preferable to provide them approximately evenly on the surface of the substrate 4a. If multiple light-emitting elements 4b are provided approximately evenly on the surface of the substrate 4a, it becomes easier to irradiate the surface of the photocatalytic filter 5 (sheet 5a) with ultraviolet light evenly.
[0038] Here, the reaction speed of the photocatalyst 5b provided in the photocatalyst filter 5 varies depending on the absorption wavelength region of the photocatalyst 5b and the intensity (amount of light) of the ultraviolet light. Therefore, the arrangement and number of the multiple light-emitting elements 4b can be determined based on the amount of ultraviolet light irradiated by one light-emitting element 4b, the surface area of the photocatalyst filter 5 (sheet 5a), and the distance between the light-emitting surface of the light-emitting element 4b and the photocatalyst filter 5 (sheet 5a).
[0039] The light-emitting element 4b irradiates ultraviolet light having a predetermined wavelength (corresponding to an example of the first ultraviolet light) toward the photocatalytic filter 5. In this case, if the material or composition of the photocatalyst 5b is changed, the absorption wavelength range of the photocatalyst 5b changes. Therefore, the light-emitting element 4b that irradiates ultraviolet light of an appropriate wavelength is selected according to the absorption wavelength range of the photocatalyst 5b.
[0040] For example, if the absorption wavelength region of the photocatalyst 5b is 365 nm or more and 405 nm or less, the light-emitting element 4b can be a light-emitting diode or a laser diode that irradiates ultraviolet light with a peak wavelength of 365 nm or more and 405 nm or less. For example, the light-emitting element 4b can be a light-emitting diode with a peak wavelength of 400 nm and an intensity (amount of light) of ultraviolet light of 700 mW.
[0041] The light emitting element 4c can be provided on the surface of the substrate 4a on which the light emitting element 4b is provided. As with the light emitting element 4b described above, the light emitting element 4c may be any of a surface mount type light emitting element such as a PLCC type, a light emitting element having a lead wire such as a bullet type, and a chip-shaped light emitting element mounted by COB.
[0042] At least one light emitting element 4c can be provided. However, if multiple light emitting elements 4c are provided, ultraviolet light can be irradiated onto a wide area of the photocatalytic filter 5. In addition, the intensity (light amount) of ultraviolet light that passes through the photocatalytic filter 5 and reaches the filter 6 can be increased, and ultraviolet light can be incident onto a wide area of the filter 6.
[0043] The light-emitting element 4c is electrically connected to, for example, a wiring pattern provided on the surface of the substrate 4a. In this case, for example, the light-emitting element 4c and the light-emitting element 4b can be connected in series, or the light-emitting element 4c and the light-emitting element 4b can be connected in parallel. Also, for example, a plurality of light-emitting elements 4c and a plurality of light-emitting elements 4b can be connected in series, or a plurality of light-emitting elements 4c and a plurality of light-emitting elements 4b can be connected in parallel.
[0044] Although there is no particular limitation on the arrangement of the light-emitting elements 4c, it is preferable to arrange them almost evenly on the surface of the substrate 4a. If the light-emitting elements 4c are arranged almost evenly on the surface of the substrate 4a, it becomes easy to irradiate the surface of the filter 6 with ultraviolet light evenly. For example, the light-emitting elements 4c and the light-emitting elements 4b can be arranged alternately, or a row of the light-emitting elements 4c and a row of the light-emitting elements 4b can be arranged in the width direction of the surface of the substrate 4a. In the case of the light source 4 illustrated in FIG. 1, one light-emitting element 4c is arranged approximately in the center of the substrate 4a, and two light-emitting elements 4b are arranged on either side of the light-emitting element 4c.
[0045] The number of light emitting elements 4c may be the same as or different from the number of light emitting elements 4b.
[0046] Here, when the gas G flows inside the frame 2, bacteria, viruses, etc. contained in the gas G may adhere to the surface of the photocatalytic filter 5 (sheet 5a). Since ultraviolet light has a sterilizing effect, for example, when ultraviolet light having a peak wavelength of 365 nm or more and 405 nm or less is irradiated from the light-emitting element 4b, bacteria and viruses can be sterilized or inactivated to a certain extent.
[0047] However, in recent years, there has been a demand for effective sterilization and inactivation of bacteria, viruses, etc. in addition to purification of gas G in closed spaces. In this case, the shorter the peak wavelength of ultraviolet light, the stronger the sterilization effect. Therefore, the light-emitting element 4c is configured to irradiate the photocatalytic filter 5 with ultraviolet light (corresponding to an example of second ultraviolet light) having a shorter peak wavelength than the ultraviolet light irradiated from the light-emitting element 4b. In this case, if only the light-emitting element 4c is provided in the light source 4, it is possible to purify the gas G and effectively sterilize and inactivate bacteria, viruses, and the like. However, the light-emitting element 4c that irradiates ultraviolet light with a short peak wavelength is more expensive than the light-emitting element 4b. Therefore, if only the light-emitting element 4c is provided in the light source 4, the manufacturing cost of the sterilization and purification device 1 will be high. The number of light-emitting elements 4c can be appropriately determined in consideration of the effect of sterilization and inactivation of bacteria and viruses and the manufacturing cost.
[0048] For example, the light-emitting element 4c may be a light-emitting diode or a laser diode that emits ultraviolet light having a peak wavelength of 265 nm or more and 280 nm or less. For example, the light-emitting element 4c may be a light-emitting diode having a peak wavelength of 280 nm and an intensity (amount of light) of ultraviolet light of 40 mW.
[0049] If the light-emitting element 4c is provided, the surface of the photocatalytic filter 5 (sheet 5a) can be irradiated with ultraviolet light having a stronger sterilizing effect than the ultraviolet light irradiated from the light-emitting element 4b, thereby enabling effective sterilization and inactivation of bacteria, viruses, etc. attached to the photocatalytic filter 5 (sheet 5a). In addition, effective sterilization and inactivation of bacteria, viruses, etc. contained in the gas G flowing inside the frame 2 can also be achieved.
[0050] For example, when only the light-emitting element 4b was provided, the removal rate of airborne bacteria 30 minutes after the start of energization was about 45%, but when the light-emitting elements 4b and 4c were provided, the removal rate of airborne bacteria 30 minutes after the start of energization was 99% or more. Furthermore, when the light-emitting elements 4b and 4c were provided, the time required for the removal rate of airborne bacteria to reach 99% could be shortened to about 1 / 5 compared to when only the light-emitting element 4b was provided.
[0051] The photocatalytic filter 5 includes, for example, a sheet 5a and a plurality of photocatalysts 5b. The sheet 5a may be, for example, a woven fabric including a plurality of linear bodies. Generally, a sheet carrying a photocatalyst is formed using a plurality of glass fibers. Since a sheet formed from a plurality of glass fibers has low rigidity, a frame-shaped member for holding the periphery of the sheet is required.
[0052] In recent years, there has been a demand for improved processing capacity, and the flow rate and flow speed of the gas G passing through the sheet tend to increase. Therefore, in order to suppress deformation of the central region of the sheet, a frame-shaped member may be provided with a crosspiece. If a frame-shaped member or a crosspiece is provided, an area where the ultraviolet light irradiated from the light-emitting elements 4b and 4c cannot enter or an area where the gas G cannot flow is generated, so that the processing capacity cannot be improved.
[0053] Therefore, the sheet 5a according to the present embodiment is formed of a plurality of linear bodies including a metal, for example, stainless steel, nickel, Monel, phosphor bronze, titanium, copper, copper alloy, silver, silver alloy, etc. The wire diameter (thickness) of the linear body can be, for example, 0.016 mm or more and 2.0 mm or less.
[0054] If the sheet 5a is formed using such linear bodies, the rigidity of the sheet 5a can be increased, and the flow rate and flow velocity of the gas G passing through the sheet 5a can be increased. In addition, there is no need to provide a frame-shaped member or a crosspiece for reinforcement. Therefore, the processing capacity of the sterilization and purification device 1 can be improved.
[0055] Here, if the linear body contains metal, the infectivity of bacteria, viruses, etc. attached to the surface of the linear body will be maintained for a certain period of time. However, as described above, the ultraviolet light emitted from the light-emitting element 4c has a high bactericidal effect, so that the bacteria and viruses attached to the surface of the linear body can be easily disinfected or inactivated. Furthermore, if the material of the linear body is a metal that generates copper ions, such as copper or a copper alloy, the copper ions can be used to disinfect or inactivate bacteria or viruses attached to the surface of the linear body. If the material of the linear body is a metal that generates silver ions, such as silver or a silver alloy, the silver ions can be used to disinfect or inactivate bacteria or viruses attached to the surface of the linear body.
[0056] When multiple linear bodies are woven, gaps are generated in the areas defined by the linear bodies. That is, multiple gaps penetrating the sheet 5a in the thickness direction are provided. If multiple gaps penetrating the sheet 5a in the thickness direction are provided, the multiple gaps become flow paths for the gas G. There is no particular limitation on the weaving method of the multiple linear bodies, and the weaving method of the multiple linear bodies can be, for example, plain weave, twill weave, plain tatami weave, twill tatami weave, etc.
[0057] Here, when the number of gaps per inch (25.4 mm), i.e., the number of meshes, increases, the gaps have a smaller cross-sectional area. When the cross-sectional area of the gap decreases, the pressure loss of the gas G passing through the gap increases. In this case, if the pressure loss exceeds 50 Pa, the flow rate of the gas G passing through the sheet 5a decreases, and there is a risk that the desired processing capacity cannot be obtained. According to the knowledge obtained by the present inventors, if the number of meshes is 500 or less, the pressure loss can be reduced to 50 Pa or less.
[0058] The photocatalysts 5b are supported on the sheet 5a. The photocatalysts 5b are, for example, granular bodies. The ultraviolet light irradiated from the light emitting element 4b is incident on the photocatalysts 5b. Therefore, the photocatalysts 5b can be ultraviolet light responsive photocatalysts. The ultraviolet light responsive photocatalysts include, for example, titanium oxide.
[0059] At least one photocatalytic filter 5 can be provided. When a plurality of photocatalytic filters 5 are provided, the plurality of photocatalytic filters 5 can be arranged side by side in the flow direction of the gas G. For example, the plurality of photocatalytic filters 5 can be arranged side by side between the side surface 2c and the side surface 2d of the frame 2.
[0060] In this case, increasing the number of photocatalytic filters 5 facilitates purification of the gas G and sterilization and inactivation of bacteria and viruses by active oxygen species. However, increasing the number of photocatalytic filters 5 increases pressure loss. Therefore, the number of photocatalytic filters 5 can be appropriately changed depending on the flow rate of the gas G, the required purification capacity (for example, the amount of substances contained in the gas G), the number of meshes of the sheet 5a, etc.
[0061] The photocatalytic filter 5 can be formed, for example, as follows. First, a plurality of linear bodies are woven to form a sheet 5a. Next, an emulsion solution is produced. For example, phosphoric acid or the like is added to pure water to produce an aqueous solution with a pH (hydrogen ion concentration) adjusted to 2 to 7. Next, a plurality of photocatalysts 5b are added to the aqueous solution. For example, the average particle size of the photocatalysts 5b may be about 200 nm. In this manner, an emulsion solution can be produced.
[0062] Next, the sheet 5a is immersed in the emulsion solution for about 10 minutes. Next, the sheet 5a is pulled out of the emulsion solution and dried. The drying can be performed by heating. For example, the heating temperature can be about 100° C. and the heating time can be about 2 hours. In this manner, the photocatalytic filter 5 can be formed.
[0063] The filter 6 faces the photocatalytic filter 5 and is provided on the side of the photocatalytic filter 5 opposite to the light source 4. The filter 6 is, for example, sheet-like and includes a plurality of linear bodies. The filter 6 can be, for example, a woven fabric including a plurality of linear bodies, or can be a stack of a plurality of linear bodies. There is no particular limitation on the material of the linear bodies as long as it is resistant to ultraviolet light. The material of the linear bodies can be, for example, glass fiber or metal.
[0064] In this case, if the filter 6 is formed of a linear body containing metal, the rigidity of the filter 6 can be increased. Therefore, the flow rate and flow velocity of the gas G passing through the filter 6 can be increased. In addition, there is no need to provide a frame-shaped member or a crosspiece for reinforcement. The linear body containing metal can be the same as the linear body used in the sheet 5a, for example. The dimensions of the filter 6 can be the same as the dimensions of the photocatalytic filter 5 (sheet 5a), for example. For example, the width dimension of the filter 6 can be W2.
[0065] When the filter 6 is a woven fabric including a plurality of linear bodies, the weaving method of the plurality of linear bodies is not particularly limited. The weaving method of the plurality of linear bodies can be, for example, plain weave, twill weave, plain tatami weave, twill tatami weave, etc. In this case, if the number of meshes is increased, the size of the foreign matter that can be captured can be reduced, but the pressure loss of the gas G passing through the filter 6 increases. Therefore, if the number of meshes is too large, the flow rate of the gas G passing through the filter 6 decreases, and there is a risk that the desired processing capacity cannot be obtained. For example, the number of meshes of the filter 6 can be about 100.
[0066] Next, the effects of the sterilization and purification device 1 according to this embodiment will be described. For example, when the sterilization and purification device 1 is operated for a long time, maintenance such as replacement and cleaning of elements may be required. For example, when the light emitting elements 4b and 4c break down or the function of the light emitting elements 4b and 4c deteriorates over time, replacement and cleaning of the light source 4 is required. For example, when the photocatalyst 5b becomes dirty or the function of the photocatalyst 5b deteriorates over time, replacement and cleaning of the photocatalyst filter 5 is required. For example, when the filter 6 is damaged or dirty, replacement and cleaning of the filter 6 is required.
[0067] In such a case, the worker will remove the light source 4, the photocatalytic filter 5, and the filter 6 from the frame 2. In this case, the ultraviolet light irradiated from the light emitting element 4c is directly incident on the light source 4 and the photocatalytic filter 5, so that bacteria and viruses adhering to the light source 4 and the photocatalytic filter 5 are sterilized and inactivated. Therefore, even if the worker touches the light source 4 or the photocatalytic filter 5, there is a low risk of the worker becoming infected with bacteria or viruses.
[0068] On the other hand, even if the filter 6 is irradiated with ultraviolet light, the photocatalytic action does not occur. Therefore, in general, in order to increase the utilization efficiency of the ultraviolet light irradiated from the light-emitting element, the photocatalytic filter is configured so that the amount of ultraviolet light passing through the photocatalytic filter is reduced. As a result, in general, the ultraviolet light irradiated from the light-emitting element hardly reaches the filter 6 provided upstream of the photocatalytic filter. In other words, in general, the ultraviolet light irradiated from the light-emitting element does not sterilize or inactivate the bacteria or viruses attached to the filter 6. If the bacteria or viruses are not sterilized or inactivated, the infectiousness of the bacteria or viruses will be maintained for a certain period of time, so if a worker touches the filter 6, the worker may be infected with the bacteria or viruses.
[0069] In this case, it is possible to further provide a light source for irradiating the filter 6 with ultraviolet light, but this would result in an increase in size of the sterilization and purification device 1, higher costs, and an increase in the installation space. In the sterilization and purification device 1 according to the present embodiment, a part of the ultraviolet light irradiated from the light emitting element 4c to the photocatalytic filter 5 is transmitted through the photocatalytic filter 5 and irradiated to the filter 6. If a part of the ultraviolet light irradiated from the light emitting element 4c is irradiated to the filter 6, bacteria and viruses attached to the filter 6 can be sterilized and inactivated. Therefore, even if an operator touches the filter 6, the operator can be prevented from being infected with bacteria or viruses. In addition, since there is no need to provide an additional light source for irradiating the filter 6 with ultraviolet light, the sterilization and purification device 1 can be made smaller, less expensive, and requires less installation space. That is, the sterilization and purification device 1 according to the present embodiment can sterilize and inactivate bacteria and viruses attached to the filter 6 with a simple configuration.
[0070] In addition, a part of the ultraviolet light irradiated from the light-emitting element 4b also passes through the photocatalytic filter 5 and is irradiated to the filter 6. Therefore, the ultraviolet light irradiated from the light-emitting element 4b can also sterilize and inactivate bacteria and viruses attached to the filter 6. However, as described above, the peak wavelength of the ultraviolet light irradiated from the light-emitting element 4c is shorter than the peak wavelength of the ultraviolet light irradiated from the light-emitting element 4b, so the bactericidal effect of the ultraviolet light irradiated from the light-emitting element 4c is higher than that of the ultraviolet light irradiated from the light-emitting element 4b. Therefore, the effect of sterilization and inactivation of bacteria and viruses attached to the filter 6 can be evaluated by the illuminance of the ultraviolet light irradiated from the light-emitting element 4c.
[0071] Here, since a part of the ultraviolet light irradiated from the light emitting element 4b also passes through the photocatalytic filter 5, if the amount of ultraviolet light passing through the photocatalytic filter 5 is too large, the photocatalytic action of the photocatalytic filter 5 may be insufficient. If the amount of ultraviolet light passing through the photocatalytic filter 5 is too small, the sterilization and inactivation of bacteria and viruses attached to the filter 6 may be insufficient.
[0072] According to the knowledge of the present inventor, the illuminance of the ultraviolet light irradiated from the light emitting element 4c to the photocatalytic filter 5 is set to L1 (mW / cm 2), and the illuminance of the ultraviolet light irradiated from the light-emitting element 4c to the filter 6 through the photocatalytic filter 5 is defined as L2 (mW / cm 2 ), it is preferable to set the relationship "0.2≦L2 / L1≦0.3". In this way, it is possible to suppress the deterioration of the photocatalytic activity of the photocatalytic filter 5, and it is also possible to effectively sterilize and inactivate bacteria and viruses adhering to the filter 6.
[0073] In this case, L2 / L1 can be adjusted by the number of meshes of the sheet 5a provided on the photocatalytic filter 5. For example, if the number of meshes is set to 300, the illuminance L1 described above can be reduced to 42.4 (mW / cm 2 ), and the illuminance L2 mentioned above is 10.8 (mW / cm 2 ) In this case, L2 / L1 is 0.25. The above-mentioned illuminance L1 and the above-mentioned illuminance L2 can be measured using an ultraviolet integrating actinometer (for example, UIT-250 (USHIO INC.)). According to the knowledge obtained by the present inventors, it is preferable that the mesh number of the sheet 5a is 50 or more and 400 or less.
[0074] As described above, the light source 4, the photocatalytic filter 5, and the filter 6 inserted into the pair of grooves 2e1 and 2f1 are approximately parallel to each other. Therefore, the ultraviolet light irradiated from the light source 4 is easily transmitted through the photocatalytic filter 5, and the ultraviolet light transmitted through the photocatalytic filter 5 can be efficiently incident on the filter 6. As a result, it becomes easier to sterilize and inactivate bacteria and viruses attached to the filter 6.
[0075] Next, the effect of the arrangement of the light source 4 and the photocatalytic filter 5 in the flow direction of the gas G will be described. FIG. 3 is a schematic cross-sectional view illustrating a sterilization and purification device 100 according to a comparative example. 3, the sterilization and purification device 100 has a frame 2, a lid 3, a light source 4, a photocatalytic filter 5, and a filter 6. In addition, like the sterilization and purification device 1 described above, a fan 7 may be further provided.
[0076] As shown in Fig. 3, the sterilizing and purifying apparatus 1 and the sterilizing and purifying apparatus 100 have different arrangements of the light source 4 and the photocatalytic filter 5. That is, in the case of the sterilizing and purifying apparatus 1, as shown in Fig. 2, the filter 6, the photocatalytic filter 5, and the light source 4 are arranged in order from the upstream side of the flow of the gas G. In contrast, in the case of the sterilizing and purifying apparatus 100, as shown in Fig. 3, the filter 6, the light source 4, and the photocatalytic filter 5 are arranged in order from the upstream side of the flow of the gas G.
[0077] Here, silicone resin is used as a sealant for the light-emitting elements 4b and 4c. Although silicone resin has high resistance to ultraviolet light, a part of the silicone resin may decompose when the light-emitting elements 4b and 4c are irradiated with ultraviolet light. In this case, the shorter the peak wavelength of the irradiated ultraviolet light, the easier it is for the silicone resin to decompose. Therefore, the silicone resin used for the light-emitting element 4c is more likely to decompose. Furthermore, heat is generated when the light emitting elements 4b and 4c irradiate ultraviolet light, and if the silicone resin is heated by the generated heat, the silicone resin becomes more likely to decompose.
[0078] When the silicone resin is decomposed, gas containing components of the silicone resin is released from the light emitting elements 4b and 4c. The gas released from the light emitting elements 4b and 4c is carried by the flow of gas G flowing inside the frame 2 and is discharged to the outside of the frame 2.
[0079] In this case, as shown in FIG. 3, if the light source 4 (light emitting elements 4b, 4c) is provided upstream of the flow of the gas G flowing inside the frame 2 and the photocatalytic filter 5 is provided downstream of the light source 4, the silicone resin component contained in the gas G is likely to adhere to the photocatalyst 5b of the photocatalytic filter 5. If the silicone resin component adheres to the photocatalyst 5b, it becomes difficult for ultraviolet light to enter the photocatalyst 5b, or for the gas G to come into contact with the photocatalyst 5b. Therefore, the functions of the sterilization and purification device 100 (gas purification, sterilization and inactivation of bacteria and viruses, etc.) decrease over time. For example, the deodorization performance maintenance rate after 1600 hours from the start of operation may be about 19%.
[0080] In contrast, in the sterilization and purification device 1 according to the present embodiment, as shown in FIG. 2, a photocatalytic filter 5 is provided upstream of the flow of gas G flowing inside the frame 2, and a light source 4 (light-emitting elements 4b, 4c) is provided downstream of the photocatalytic filter 5. Therefore, even if gas containing silicone resin components is released from the light-emitting elements 4b, 4c, the flow of gas G prevents the released gas from reaching the photocatalytic filter 5. As a result, it is possible to suppress the deterioration of the functions of the sterilization and purification device 1 (gas purification, sterilization and inactivation of bacteria and viruses, etc.) over time. For example, the deodorization performance maintenance rate after 1600 hours from the start of operation can be about 84%.
[0081] Although some embodiments of the present invention have been illustrated above, these embodiments are presented as examples and are not intended to limit the scope of the invention. These novel embodiments can be implemented in various other forms, and various omissions, substitutions, modifications, etc. can be made without departing from the gist of the invention. These embodiments and their modifications are included in the scope and gist of the invention, and are included in the scope of the invention and its equivalents described in the claims. In addition, the above-mentioned embodiments can be implemented in combination with each other. [Explanation of symbols]
[0082] 1 sterilization and purification device, 2 frame, 4 light source, 4a substrate, 4b light emitting element, 4c light emitting element, 5 photocatalytic filter, 5a sheet, 5b photocatalytic element, 6 filter, 7 fan, G gas
Claims
1. A photocatalytic filter having a sheet and a photocatalyst supported on the sheet; a light source facing the photocatalytic filter and having a first light-emitting element and a second light-emitting element; a filter disposed opposite the photocatalytic filter and on the opposite side of the photocatalytic filter from the light source; Equipped with The first light emitting element irradiates a first light toward the photocatalytic filter, The second light emitting element irradiates the second light, which is ultraviolet light having a shorter peak wavelength than the first light, toward the photocatalytic filter; A part of the second light irradiated to the photocatalytic filter is transmitted through the photocatalytic filter and irradiated to the filter, When the light source irradiates light, gas is released from the light source, A sterilization and purification device in which the gas to be treated flows from the filter side toward the light source side, and the flow of the gas to be treated prevents the released gas from reaching the photocatalyst filter.
2. The illuminance of the second light irradiated to the photocatalytic filter is L1 (mW / cm 2 ) and the illuminance of the second light irradiated to the filter is L2 (mW / cm 2 2. The sterilizing and purifying apparatus according to claim 1, which satisfies the following formula when 0.2≦L2 / L1≦0.3
3. The sheet is a woven fabric including a plurality of linear bodies, the plurality of linear bodies includes a metal, 3. The sterilization and purification device according to claim 1, wherein the sheet has a mesh number of 50 or more and 400 or less.
4. The sterilization and purification device according to any one of claims 1 to 3, wherein the peak wavelength of the second light is 265 nm or more and 280 nm or less.
5. The sterilization and purification device according to any one of claims 1 to 4, wherein the peak wavelength of the first light is 365 nm or more and 405 nm or less.
6. The sterilization and purification device according to any one of claims 1 to 5, further comprising a fan that forms a flow of the gas from the filter side toward the light source side.
Citation Information
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