Current collector for secondary battery and cylindrical battery cell including same

Abstract

The present invention discloses a current collector for a secondary battery. The current collector for a secondary battery has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 According to the present invention, the current collector elongation rate and tensile strength are optimally set, so that the camber length during the manufacture of the electrode plate is reduced to less than 20 mm, and no meandering or breakage occurs during the winding process of the jelly roll.

Description

[Technical Field]

[0001] The present invention relates to a current collector for use in a secondary battery and a battery cell including the same, and also to a battery pack and a vehicle including such a battery cell.

[0002] This application claims priority based on Korean Patent Application No. 10-2021-0152634 filed on November 8, 2021, Korean Patent Application No. 10-2021-0166230 filed on November 26, 2021, and Korean Patent Application No. 10-2022-0089235 filed on July 19, 2022, and the contents disclosed in the specifications and drawings of those applications are incorporated into this application in their entirety. [Background technology]

[0003] As technological development and demand for mobile devices and electric vehicles increases, the demand for secondary batteries as energy sources is rapidly increasing. Currently, the most widely used secondary battery is the lithium-ion battery, and the operating voltage of a unit battery cell is approximately 2.5V to 4.5V. If a higher output voltage is required, a battery pack may be configured by connecting multiple battery cells in series, or, depending on the charge / discharge capacity required of the battery pack, multiple battery cells may be connected in parallel to configure the battery pack.

[0004] Known types of unit battery cells include cylindrical, prismatic, and pouch types. Cylindrical battery cells include a jelly-roll type electrode assembly. A jelly-roll type electrode assembly has a structure in which sheet-shaped positive and negative electrode plates are wound with a separator interposed therebetween.

[0005] FIG. 1 is a plan view showing the structure of an electrode plate, and FIG. 2 is a diagram showing the process of winding the electrode plate to manufacture a jelly roll type electrode assembly.

[0006] 1 and 2, the positive electrode plate 10 and the negative electrode plate 11 have a structure in which an active material layer 21 is coated on a sheet-shaped current collector 20, and may include an uncoated portion 22 on one long side along the winding direction X. The electrode assembly is fabricated by sequentially stacking the positive electrode plate 10 and the negative electrode plate 11 together with two separators 12 as shown in FIG. 2, and then winding the stack in one direction (X direction) around the core. In this case, the uncoated portions 22 of the positive electrode plate 10 and the negative electrode plate 11 may be arranged in opposite directions.

[0007] The positive electrode plate 10 and the negative electrode plate 11 may include a current collector 20 extending in the winding direction (X direction) and an active material layer 21 coated on the upper and / or lower surfaces of the current collector 20. A predetermined width of the edge of the current collector 20 is not coated with the active material layer 21. In the art, the region not coated with the active material layer 21 is referred to as an uncoated portion 22, and the region coated with the active material layer 21 is referred to as a coated portion.

[0008] The electrode plate manufacturing process includes the steps of coating an active material layer 21 on a current collector 20 to a designed thickness, drying the coated active material layer 21, and compressing the active material layer 21 to a desired density by a rolling process using a roller.

[0009] FIG. 3 is a schematic diagram illustrating the process of rolling the electrode plate using rollers.

[0010] 3, the electrode plate 1, in which the upper and lower surfaces of the current collector 20 are coated with the active material layer 21, is rolled by passing between a pair of rollers 30. As a result, it can be said that the deformation force that essentially stretches the electrode plate 1 acts along the longitudinal direction of the electrode plate 1 (the same as the X direction in FIG. 1). When the active material layer 21 is compressed, the coated portion and the non-coated portion 22 are stretched to different amounts.

[0011] Therefore, the actual electrode plate 1 deviates from the ideal shape shown in Figure 1, and as shown in Figure 4, unlike the state before compression shown in (a), after the rolling process is performed and compression is performed as shown in (b), undulations occur in the electrode plate 1 in the longitudinal direction (the direction of travel of the rollers 30), resulting in the camber phenomenon shown in Figure 5. The camber phenomenon refers to the warping toward the non-coated portion 22 due to the difference in elongation rate between the non-coated portion 22 and the maintained portion when the electrode plate 1 is unfolded.

[0012] The stretching ratio is defined by the following equation 1.

number

[0013] That is, elongation is the degree of increase in length when an object with length L is deformed to a length L', expressed as a percentage. Elongation refers to the degree to which a material stretches in a tensile test, and the higher the elongation, the greater the material's ability to stretch without breaking due to external impact. That is, elongation is used as a measure of a material's fracture performance. Therefore, the lower the elongation, the greater the tendency for a material to be broken by external impact, and the higher the elongation, the greater the tendency for a material to stretch without breaking due to external impact.

[0014] For reference, the camber length is defined as the maximum deformation amount measured at each point on the lower end of the electrode plate 1 when the electrode plate 1 with undulations is spread out in a straight line. As shown in FIG. 5, the maximum deformation amount is the deformation amount measured at the point where the rolling process of the active material layer 21 is completed (see "Camber Length").

[0015] If the electrode plate 1 with the camber is used as it is, it may cause a meandering defect during the notching operation of the non-coated portion 22 or the winding process of the electrode plate 1. Furthermore, the meandering defect may cause an internal short circuit between the positive electrode plate 10 and the negative electrode plate 11 that face each other with the separator 12 sandwiched therebetween in a jelly roll type electrode assembly.

[0016] Conventionally, to reduce the difference in elongation rate between the non-coated portion 22 and the maintained portion, the active material loading amount in the maintained portion may be reduced, or an additional heat treatment may be performed on the electrode plate 1 after rolling. However, reducing the active material loading amount reduces the energy density. Furthermore, performing an additional heat treatment complicates the process and increases costs.

[0017] Therefore, in the technical field to which the present invention pertains, there is a need for a technology that can minimize the camber phenomenon that occurs during the rolling process of the active material layer by adjusting the physical properties of the current collector itself. Summary of the Invention [Problem to be solved by the invention]

[0018] The present invention has been made in light of the background of the prior art as described above, and aims to provide a current collector for a secondary battery that can mitigate the camber phenomenon during the manufacturing process of an electrode plate by adjusting the elongation rate and tensile strength.

[0019] Another object of the present invention is to provide an electrode plate including the current collector, an electrode assembly including the same, a battery cell, a battery pack, and a vehicle.

[0020] However, the technical problems that the present invention aims to solve are not limited to the above-mentioned problems, and other problems not mentioned will be clearly understood by those of ordinary skill in the art from the following description of the invention. [Means for solving the problem]

[0021] To achieve the above object, the current collector for a secondary battery according to the present invention has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 It is characterized in that:

[0022] As is well known, the tensile strength and elongation are values ​​obtained by a tensile strength test based on IPC-TM-650, and in particular, can be measured by the IPC-TM-650 (2.4.19) method.

[0023] Preferably, the current collector is an aluminum current collector.

[0024] The present invention also provides an electrode plate for a secondary battery including such a current collector for a secondary battery. The electrode plate for a secondary battery according to the present invention has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 and an active material layer formed on the current collector.

[0025] The current collector may be in the form of a sheet having short and long sides, and may include a non-coated portion at the end of the long side of the current collector where the active material layer is not formed.

[0026] The electrode plate may have a width along the short sides of the current collector of 60 to 110 mm, a length along the long sides of the current collector of 3 to 5 m, and a camber length of less than 20 mm.

[0027] Preferably, the length of the non-coated portion measured along the short side of the current collector is 2 to 20 mm. The length of the non-coated portion is measured in the width direction of the current collector. The width direction of the current collector is a direction perpendicular to the length direction of the current collector.

[0028] At least a portion of the non-application section may be divided into a plurality of segmented pieces.

[0029] In this case, the non-coated portion may be notched in a direction along a short side of the current collector.

[0030] Preferably, the non-coated portion of the notched area does not include any breaks or cracks.

[0031] The energy density per unit area of ​​the active material layer is 1 to 6 mAh / cm 2 It could be.

[0032] The current collector may be an aluminum current collector, and the active material may include a lithium transition metal oxide. Thus, the electrode plate may be a positive electrode plate.

[0033] The electrode assembly according to the present invention is a jelly-roll type electrode assembly having a structure in which sheet-like first and second electrode plates and a separator interposed therebetween are wound in one direction, and at least one of the first and second electrode plates includes a current collector and an uncoated portion at a long side end of the current collector where an active material layer is not coated, and at least a part of the uncoated portion is exposed to the outside of the separator and used as an electrode tab, and the current collector has an elongation of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 It is characterized in that:

[0034] Preferably, in the assembly, the current collector may be an aluminum current collector, and the first electrode plate or the second electrode plate may have a width of 60 to 110 mm along the short side of the current collector, a length of 3 to 5 m along the long side of the current collector, and a camber length of less than 20 mm.

[0035] In the electrode assembly, the non-coated portion includes a core-side non-coated portion adjacent to the core of the electrode assembly, an outer-periphery-side non-coated portion adjacent to the outer peripheral surface of the electrode assembly, and an intermediate non-coated portion interposed between the core-side non-coated portion and the outer-periphery-side non-coated portion, and at least a portion of the intermediate non-coated portion can be divided into a plurality of segmented pieces.

[0036] The segmented piece may have a shape in which the width at the top is smaller than the width at the bottom.

[0037] On the one hand, each of the plurality of segmented pieces may have a rectangular, trapezoidal, triangular, parallelogram, semicircular or semi-elliptical structure, and the outer peripheral non-coated portion and the core peripheral non-coated portion may not have a segmented structure of the non-coated portion.

[0038] Alternatively, the shape of the segment may be such that the width at the bottom is greater than the width at the top, and decreases stepwise and / or gradually from bottom to top.

[0039] The plurality of segment pieces may be folded in a radial direction of the electrode assembly, for example, toward the core, and overlapped in multiple layers.

[0040] There are no breaks or cracks between the segments.

[0041] The cylindrical battery cell according to the present invention includes a jelly-roll-type electrode assembly having a structure in which sheet-like first and second electrode plates and a separator interposed therebetween are wound in one direction; a battery can that houses the electrode assembly and is electrically connected to one of the first and second electrode plates and has a first polarity; a sealing body that seals an open end of the battery can; and a terminal that is electrically connected to the other of the first and second electrode plates and has an exposed surface and has a second polarity; at least one of the first and second electrode plates includes a current collector and an uncoated portion at a long side end of the current collector where an active material layer is not coated, and at least a portion of the uncoated portion is exposed to the outside of the separator and used as an electrode tab; and the current collector has an elongation of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 It is characterized in that:

[0042] In the cylindrical battery cell, the non-coated portion includes a core-side non-coated portion adjacent to the core of the electrode assembly, an outer-periphery-side non-coated portion adjacent to the outer peripheral surface of the electrode assembly, and an intermediate non-coated portion interposed between the core-side non-coated portion and the outer-periphery-side non-coated portion, and at least a portion of the intermediate non-coated portion is divided into a plurality of segmented pieces.

[0043] At least a portion of the intermediate non-coating portion is bent from the outer periphery toward the core, and a cavity is provided in the core of the electrode assembly, and the cavity is not closed by the bent structure of the intermediate non-coating portion.

[0044] The cylindrical battery cell may further include a current collecting plate electrically connected to an uncoated portion of the second electrode plate having the first polarity, and at least a portion of an edge of the current collecting plate being attached to a sidewall of the battery can.

[0045] The sealing body may include a non-polar cap plate and a gasket that surrounds the edge of the cap plate and is crimped onto the top end of the battery can.

[0046] The battery can may include a rivet terminal insulatively installed in a through-hole formed in a center of a closed surface, electrically connected to the first electrode plate, and having the second polarity.

[0047] The technical object of the present invention can also be achieved by a battery pack including at least one cylindrical battery cell as described above, and a vehicle including at least one such battery pack. [Effects of the Invention]

[0048] According to one aspect of the present invention, the elongation ratio and tensile strength of the current collector are optimally controlled, thereby minimizing the occurrence of camber in an electrode plate manufactured from the current collector, and preventing the occurrence of meandering defects when a jelly-roll type electrode assembly is manufactured using the electrode plate.

[0049] The current collector according to the present invention has an optimally adjusted elongation ratio and tensile strength, so that it is less likely to waviness even when a large-area current collector is pattern-coated with a strip-shaped active material layer and rolled. As a result, slitting along the uncoated portions between the pattern-coated active material layers becomes easy, making it highly suitable for producing multiple electrode plates, and the produced electrode plates have minimal camber.

[0050] The current collector according to the present invention is suitable for the manufacture of large-sized batteries. In particular, it is very suitable for the manufacture of cylindrical secondary batteries, so-called tab-less cylindrical secondary batteries, in which a jelly-roll-type electrode assembly is designed to have positive and negative uncoated portions at the top and bottom, respectively, and current collecting plates are welded to these uncoated portions to achieve improved current collection efficiency. This is because such jelly-roll-type electrode assemblies are manufactured by notching and bending the uncoated portions, and the current collector according to the present invention has good notching processability, since breakage of the segments can be minimized when the uncoated portions are notched.

[0051] According to another aspect of the present invention, the non-coated portions protruding upward and downward from the electrode assembly are used as electrode tabs, thereby reducing the internal resistance of the battery cell and increasing the energy density.

[0052] According to another aspect of the present invention, the structure of the non-coated portion of the electrode assembly is improved to prevent interference between the inner surfaces of the electrode assembly and the battery can during the process of forming the beading portion of the battery can, thereby preventing an internal short circuit in a cylindrical battery cell due to partial deformation of the electrode assembly.

[0053] According to yet another aspect of the present invention, the structure of the non-coated portion of the electrode assembly is improved to prevent the non-coated portion from breaking when bent, and the number of overlapping layers of the non-coated portion is sufficiently increased to improve welding strength.

[0054] According to yet another aspect of the present invention, the structure of the non-coated portion adjacent to the core of the electrode assembly is improved to prevent the cavity in the core of the electrode assembly from being blocked when the non-coated portion is bent, facilitating the process of injecting the electrolyte and the process of welding the battery can and the current collecting plate.

[0055] According to yet another aspect of the present invention, it is possible to provide a cylindrical battery cell having a structure in which internal resistance is low, internal short circuits are prevented, and welding strength between a current collecting plate and an uncoated portion is improved, as well as a battery pack and a vehicle including the same.

[0056] The following drawings attached to this specification illustrate preferred embodiments of the present invention and, together with the detailed description of the invention, serve to further understand the technical concept of the present invention, so the present invention should not be interpreted as being limited to the matters described in the drawings. [Brief explanation of the drawings]

[0057] [Figure 1] FIG. 1 is a plan view showing the structure of the electrode plate. [Figure 2] 10A and 10B are views showing a winding process of an electrode plate for manufacturing a jelly roll type electrode assembly. [Figure 3] FIG. 2 is a schematic diagram illustrating a process of rolling an electrode plate using a roller. [Figure 4] 1 is a diagram illustrating a phenomenon in which undulations occur along the longitudinal direction of an electrode plate when an active material layer coated on a current collector is pressed in accordance with a conventional technique. [Figure 5] 10 is a diagram illustrating a camber phenomenon in which an electrode plate warps toward a non-coated portion when a wavy electrode plate is spread out in a straight line. FIG. [Figure 6] 1 is a plan view showing the structure of a first embodiment of an electrode plate manufactured from a current collector according to an embodiment of the present invention. [Figure 7] FIG. 10 is a plan view showing the structure of an electrode plate according to a second embodiment of the present invention. [Figure 8] 8 is a diagram showing the definitions of the width, height and spacing pitch of the segment pieces in the electrode plate of FIG. 7. FIG. [Figure 9] 10 is a photograph showing the results of an experiment to confirm whether cracks occur due to running tension depending on the spacing pitch and shape of the divided pieces. [Figure 10] FIG. 10 is a plan view showing the structure of an electrode plate according to a third embodiment of the present invention. [Figure 11] 11 is a diagram showing the definitions of the width, height and spacing pitch of the segment pieces in the electrode plate of FIG. 10. FIG. [Figure 12]6 is a photograph comparing the degree of occurrence of camber when an electrode plate is manufactured using a current collector whose elongation rate and tensile strength are optimized according to an embodiment of the present invention and when an electrode plate is manufactured using a current collector according to the prior art. [Figure 13] 1 is a cross-sectional view of a jelly-roll type electrode assembly in which the electrode plates of the first embodiment are applied to a first electrode plate (positive electrode plate) and a second electrode plate (negative electrode plate), taken along the Y-axis direction (winding axis direction). FIG. [Figure 14] FIG. 10 is a cross-sectional view of a jelly-roll type electrode assembly in which one of the electrode plates of the second embodiment and the third embodiment (modifications thereof) is used as the first electrode plate (positive electrode plate) and the second electrode plate (negative electrode plate) taken along the Y-axis direction (winding axis direction). [Figure 15] 10 is a cross-sectional view of an electrode assembly according to another embodiment of the present invention taken along the Y-axis direction (winding axis direction). [Figure 16] 2 is a cross-sectional view of a cylindrical battery cell according to an embodiment of the present invention taken along a Y-axis direction. FIG. [Figure 17] FIG. 4 is a cross-sectional view of a cylindrical battery cell according to another embodiment of the present invention taken along the Y-axis direction. [Figure 18] 1 is a diagram illustrating a schematic configuration of a battery pack according to an embodiment of the present invention; [Figure 19] 1 is a schematic diagram of a vehicle including a battery pack according to an embodiment of the present invention. DETAILED DESCRIPTION OF THE INVENTION

[0058] Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the accompanying drawings. Prior to this, the terms and words used in the specification and claims should not be construed as being limited to their ordinary or dictionary meanings, but should be construed as having meanings and concepts corresponding to the technical ideas of the present invention, in accordance with the principle that the inventor himself can appropriately define the concepts of terms in order to best explain the invention.

[0059] Therefore, it should be understood that the embodiments described in this specification and the configurations shown in the drawings are merely the most preferred embodiment of the present invention and do not represent the entire technical idea of ​​the present invention, and that there may be various equivalents and modifications that can be substituted for them at the time of this application.

[0060] In order to facilitate understanding of the invention, the accompanying drawings may be drawn not to scale but with some components exaggerated. The same reference numerals may be used to refer to the same components in different embodiments.

[0061] The current collector of the present invention has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 As is well known, the tensile strength and elongation are values ​​obtained by a tensile strength test based on IPC-TM-650. In particular, they can be measured by the IPC-TM-650 (2.4.19) method. The current collector according to the present invention has an elongation of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm, as measured by the IPC-TM-650 (2.4.19) method. 2 It is characterized in that:

[0062] Considering that the usual elongation rate of materials used for current collectors is 10 to 15%, the current collector of the present invention has a very low elongation rate. Tensile strength is the value obtained by dividing the maximum tensile load until a test piece breaks in a tensile test of the material by the cross-sectional area of ​​the test piece before the test. Although it varies depending on the manufacturing method, pure aluminum foil usually has a tensile strength of 50 to 100 MPa, i.e., 5.1 to 10.2 kgf / mm 2 Range (1kgf=9.8N, N / mm 2 = MPa). In view of this, the current collector according to the present invention has a high tensile strength.

[0063] The current collector according to the present invention may be used as a current collector for a secondary battery. The current collector may be coated with an active material layer. The current collector according to the present invention may be used as a current collector when manufacturing a positive electrode plate and a negative electrode plate of a jelly-roll type electrode assembly. Hereinafter, the current collector according to the present invention will be described in detail by describing an electrode plate including such a current collector.

[0064] FIG. 6 is a plan view showing the structure of a first example of an electrode plate manufactured from a current collector according to an embodiment of the present invention.

[0065] The electrode plate 50 includes a current collector 41 and an active material layer 42. The current collector 41 is appropriately selected depending on the polarity of the electrode plate 50. The material of the current collector 41 may be, but is not limited to, aluminum, copper, nickel, or stainless steel, and any metal or metal alloy commonly used as a current collector material may be used. For example, if the current collector 41 is an aluminum current collector, it is used as a positive current collector in a secondary battery, the active material layer 42 is a positive electrode active material layer, and the electrode plate 50 is a positive electrode plate. If the current collector 41 is a copper current collector, it is used as a negative current collector in a secondary battery, the active material layer 42 is a negative electrode active material layer, and the electrode plate 50 is a negative electrode plate.

[0066] The current collector 41 is in the form of a sheet having short and long sides. The active material layer 42 is formed on at least one surface of the current collector 41 and may include an uncoated portion 43 at the end of the long side in the winding direction X. The uncoated portion 43 is an area not coated with active material, i.e., an area where the active material layer 42 is not formed. An insulating coating layer 44 may be further formed at the boundary between the active material layer 42 and the uncoated portion 43. The insulating coating layer 44 may be formed so that at least a portion of the insulating coating layer 44 overlaps the boundary between the active material layer 42 and the uncoated portion 43. The insulating coating layer 44 includes a polymer resin and may include an inorganic filler such as Al2O3, AlOOH, or Al(OH)3. The insulating coating layer 44 is optional.

[0067] The electrode plate 50 can be manufactured by coating the active material layer 42 on the current collector 41 to a designed thickness, drying the coating, and compressing the active material layer 42 to a desired density through a rolling process.

[0068] In this case, a large-area current collector is pattern-coated with a strip-shaped active material layer 42 along the longitudinal direction and rolled, and then slit along the longitudinal direction along the non-coated portions between the pattern-coated active material layers 42, and cut in the width direction to the required length, so that a plurality of electrode plates 50 can be manufactured at once from the large-area current collector. Here, the longitudinal direction of the current collector 41 and the electrode plate 50 refers to the winding direction (X direction) in which the electrode plate 50 is wound when the electrode plate 50 is used to manufacture a jelly-roll type electrode assembly. It also refers to the direction in which the rollers move when the active material layer 42 is rolled using rollers to compress it to a desired density.

[0069] The current collector 41 is a current collector for a secondary battery according to the present invention, and as described above, has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm 2 The electrode plate 50 may have a width of 60 to 110 mm in a direction along the short side of the current collector 41, and a length of 3 to 5 m in a direction along the long side of the current collector 41. The electrode plate 50 is formed by subjecting the active material layer 42 formed on the current collector 41 to a rolling process and crimping it, and the camber length after crimping is less than 20 mm. Because the camber length is reduced to less than 20 mm, no meandering defects occur during the winding process of the electrode plate 50.

[0070] The smaller the elongation ratio, the more likely the current collector 41 is to break. If the elongation ratio of the current collector 41 is less than 1.5%, the rolling processability of the current collector 41 is reduced, and when the electrode plate 50 manufactured by coating the current collector 41 with the active material layer 42 is rolled, breaks or cracks may occur in the current collector 41. A break refers to a state in which the continuity of the material is broken, and the broken portion is physically completely separated. A crack refers to a state in which the continuity of the material is broken only in the surface portion, while the continuity is maintained in the portion below. On the other hand, if the elongation ratio of the current collector 41 exceeds 3.0%, the elongation of the maintenance portion of the electrode plate 50 (the portion where the active material layer 42 is formed) becomes large, and the camber increases significantly.

[0071] The tensile strength of the current collector 41 is 25 kgf / mm 2 Less than or 35kgf / mm 2 If the thickness exceeds this value, it is impossible to ensure the electrode processability of the electrode plate 50, for example, the notching processability in the case described below with reference to FIGS.

[0072] In order to achieve the desired elongation and tensile strength of the current collector 41, the manufacturing process of the current collector 41 and / or the material of the current collector 41 may be modified. The elongation can be determined from the degree of elongation due to the pressure applied to the electrode plate when rolling an electrode plate having an active material layer formed thereon using a roller. Since current collectors are typically made of metals with good ductility and malleability, the greater the pressure applied during rolling, the greater the elongation. Furthermore, the higher the rolling temperature, the greater the elongation. The greater the hardness of the rolling rollers used during rolling, the greater the elongation. The elongation also depends on the material and thickness of the current collector. The elongation of the current collector 41 of the present invention, which is 1.5 to 3.0%, indicates the degree of increase after the rolling process within the typical ranges of pressure, temperature, hardness of the rolling rollers, material and thickness of the current collector, etc.

[0073] For example, aluminum foil used in existing current collectors is produced by rolling strip-shaped aluminum into a foil of a target thickness, and the elongation rate can be changed by adjusting the conditions (pressure, temperature) and recovery of the rolling process. In another example, when producing copper foil for use in conventional current collectors, it can be realized by adjusting the temperature and time of an additional heat treatment. In yet another example, when producing copper foil for use in conventional current collectors by electroplating, the amount of organic additives and / or the amount of specific ions contained in the electroplating solution can be adjusted. For example, increasing the amount of organic additives can improve tensile strength and reduce elongation. Increasing the amount of chloride ions added can increase elongation.

[0074] The camber phenomenon is particularly problematic in the positive electrode current collector, which is a conventional aluminum current collector. 2Using an aluminum current collector that achieves this characteristic can suppress the camber phenomenon. This current collector is desirable because it can be used as a positive electrode plate by forming an active material layer containing a lithium transition metal oxide on it. Another example of achieving a desired range of elongation and tensile strength from this aluminum current collector is to use an aluminum alloy instead of pure aluminum and vary its composition. That is, while Al is the main raw material, the elongation and tensile strength can be controlled by adjusting the content of other elements contained therein. For example, the Al content of the alloy can be 97.5 to 99.5%. When the Al content falls within this range, the elongation is lower and the tensile strength is higher compared to pure aluminum. An Al content of less than 97.5% is undesirable because it may degrade battery properties, while an Al content of more than 99.5% is undesirable because it reduces tensile strength and eliminates the camber prevention effect. Other elements that can be included in the aluminum alloy include, for example, Si, Fe, Cu, Mg, Mn, Zn, Ni, Sn, and Cr. For example, the addition of Si or Mg can decrease the elongation ratio, and the addition of Cu can increase the tensile strength. The elongation ratio and tensile strength of the current collector 41 can be adjusted by a skilled artisan through other means, but the present invention is significant in that it presents particularly desirable ranges for the elongation ratio and tensile strength.

[0075] The current collector 41 may be cut from a large-area raw current collector. The raw current collector is manufactured into a rectangular thin foil having a predetermined width and length, and is then wound up and used to manufacture the electrode plate 50. A standard-width raw current collector may have a width of 400 to 800 mm. A wide-width raw current collector may have a width of 1,000 to 1,800 mm. Such raw current collectors may have a length of several to several hundred meters and may be used in a rolled state.

[0076] The size of the electrode plate 50 may vary depending on the size of the jelly-roll-type electrode assembly to be manufactured and the size of the cylindrical battery cell to be manufactured. The size of the electrode plate to be used in a large cylindrical battery cell having a 46800 form factor needs to be larger than the size of the electrode plate to be used in a small cylindrical battery cell having an 18650 or 21700 form factor. The current collector 41 according to an embodiment of the present invention is suitable for manufacturing such large electrode plates.

[0077] Here, the form factor refers to values ​​indicating the diameter and height of a cylindrical battery cell. Cylindrical battery cells according to an embodiment of the present invention may be, for example, 46110 cells, 48750 cells, 48110 cells, 48800 cells, and 46800 cells. In the numerical value indicating the form factor, the first two digits indicate the diameter of the cell, the next two digits indicate the height of the cell, and the last digit 0 indicates that the cross section of the cell is circular.

[0078] In a preferred embodiment, the form factor of the cylindrical battery cell is 46800, and the electrode plate 50 is included in a jelly-roll-type electrode assembly included in such a cylindrical battery cell. In the electrode plate 50, the current collector 41 is an aluminum current collector, and the length of the uncoated portion 43 is 2 to 20 mm. The length of the uncoated portion 43 is measured in the width direction of the current collector 41, i.e., the direction along the short side. The width direction of the current collector 41 is the direction perpendicular to the longitudinal direction of the current collector 41. The width of the electrode plate 50 may be 60 to 110 mm, and the length may be 3 to 5 m.

[0079] The current collector 41 according to the present invention has an optimally adjusted elongation ratio and tensile strength, so that it is less likely to undulate even when a large-area current collector is pattern-coated with a strip-shaped active material layer 42 and rolled. This facilitates slitting along the uncoated portions between the pattern-coated active material layers 42, making it highly suitable for producing multiple electrode plates 50.

[0080] The current collector 41 may be rectangular and strip-shaped, and the non-coated portion 43 may also be strip-shaped. The present invention also features the shape of the non-coated portion 43. The non-coated portion 43 includes a core-side non-coated portion B1 adjacent to the core side of the electrode assembly, an outer-periphery-side non-coated portion B3 adjacent to the outer periphery of the electrode assembly, and an intermediate non-coated portion B2 interposed between the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3. In the first embodiment, the height of the non-coated portion 43 is not constant but varies relative to the winding direction (X direction). That is, the height (length in the Y-axis direction) of the outer-periphery-side non-coated portion B3 is relatively smaller than the core-side non-coated portion B1 and the intermediate non-coated portion B2. By ensuring that the elongation and tensile strength of the current collector 41 fall within a predetermined range, the non-coated portion 43 can be differentiated in height as described above, ensuring a process suitable for cutting. The non-coated portion 43 can be cut using known metal foil cutting processes such as ultrasonic cutting or punching. The electrode plate 50, in which the height of the non-coated portion 43 is not constant but is relatively different in the winding direction (X direction), is designed so that the positive electrode non-coated portion and the negative electrode non-coated portion are located at the upper and lower ends of the electrode assembly, respectively, and current collecting plates are welded to these non-coated portions, thereby providing a cylindrical secondary battery with a structure that improves current collection efficiency, i.e., a so-called tabless cylindrical secondary battery.

[0081] The heights of the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3 are equal to or greater than 0 and are relatively smaller than the intermediate non-coated portion B2. The heights of the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3 may be the same or different.

[0082] Preferably, the height of the intermediate non-coated portion B2 may be stepped, increasing stepwise from the core side toward the outer periphery.

[0083] Patterns 1 to 7 are obtained by dividing the intermediate non-coating portion B2 around the position where the height of the non-coating portion 43 changes. Preferably, the number of patterns and the height (length in the Y-axis direction) and width (length in the X-axis direction) of each pattern can be adjusted to maximize stress dispersion during the bending process of the non-coating portion 43. The purpose of stress dispersion is to prevent the non-coating portion 43 from breaking.

[0084] The width dB1 of the core-side non-coated portion B1 is designed so that the cavity of the electrode assembly core is not blocked when the pattern of the intermediate non-coated portion B2 is bent toward the core side.

[0085] In one example, the width dB1 of the core-side uncoated portion B1 can increase in proportion to the bending length of the pattern 1. The bending length is the height of the pattern based on the bending point of the pattern.

[0086] Preferably, the width dB1 of the core-side non-coated portion B1 can be set so that the radial width of the wound turn formed by the core-side non-coated portion B1 is equal to or greater than the bent length of the pattern 1.

[0087] In a specific example, when the electrode plate 50 is used to manufacture an electrode assembly for a large cylindrical cell having a form factor of approximately 46110, 46800, 48750, 48110, or 48800, the width dB1 of the core-side non-coated portion B1 can be set to 180 to 350 mm depending on the diameter of the core of the electrode assembly.

[0088] In one embodiment, the width of each pattern can be designed to accommodate the same winding turn of the electrode assembly.

[0089] In one variation, the height of the intermediate non-coated portion B2 may be stepped, increasing and then decreasing as it progresses from the core side to the outer periphery side.

[0090] In another modification, the height of the peripheral non-coated portion B3 may gradually decrease as it moves toward the outer periphery.

[0091] In yet another variant, the pattern structure applied to the middle non-coated portion B2 can be extended to the outer peripheral non-coated portion B3 (see dotted lines).

[0092] On the other hand, by setting the elongation rate and tensile strength of the current collector 41 within a predetermined range, the length of the camber after rolling is shortened even if the load density of the active material layer 42 is sufficient. As a result, in the present invention, the energy density per unit area of ​​the active material layer 42 is set to 1 to 6 mAh / cm. 2The energy density of the active material layer 42 can be increased to a desired value. When the energy density of the active material layer 42 satisfies the above range, it can be suitably used in medium- to large-sized, high-capacity battery cells. This reduces the load per electrode weight, resulting in a thinner electrode. The thickness of the active material layer 42 can be 15 μm to 200 μm. As the thickness of the current collector 41 increases, the tensile strength decreases, and conversely, the elongation increases. Therefore, the thickness of the current collector 41 can also be within an appropriate range to maintain the elongation and tensile strength within a predetermined range. For example, the current collector 41 can have a thickness of 3 μm to 500 μm, although a thickness that is too thick is undesirable during winding. For example, the current collector 41 can have a thickness of 7 μm to 20 μm. Fine irregularities can be formed on the surface of the current collector 41 to strengthen the bonding force with the active material. For example, the current collector 41 can be in various forms, such as a film, sheet, foil, net, porous material, foam, or nonwoven fabric.

[0093] FIG. 7 is a plan view showing the structure of an electrode plate according to a second embodiment of the present invention.

[0094] The electrode plate 60 in Fig. 7 differs from the electrode plate 50 in Fig. 6 only in the shape of the non-coated portion 43, and the remaining configuration is substantially the same. The electrode plate 60 is further suitable for manufacturing a tabless cylindrical secondary battery.

[0095] As shown in FIG. 7 , the non-coated portion 43 may be divided into a plurality of segments 61 by a notching process. The segments 61 may be notched using a laser. That is, the non-coated portion 43 may be notched in a direction along the short side of the current collector 41. Alternatively, the segments 61 may be formed by a known metal foil cutting process, such as ultrasonic cutting or punching. In the present invention, the elongation and tensile strength of the current collector 41 are designed, so that when the segments 61 are notched, breaks or cracks can be minimized at the notched portions, i.e., in the non-coated portion 43 at the notched portions. Preferably, the non-coated portion 43 at the notched portions in the electrode plate 60 according to the present invention does not have breaks or cracks.

[0096] The heights of the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3 may be relatively smaller than that of the intermediate non-coated portion B2. The heights of the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3 may be the same or different.

[0097] Preferably, at least a portion of the middle non-coated portion B2 may include a plurality of segment pieces 61. The height of the plurality of segment pieces 61 may increase stepwise from the core side to the outer periphery side.

[0098] After being wound, the segments 61 may be folded in the radial direction of the electrode assembly, for example, toward the core, and stacked. By welding current collecting plates to the folded and stacked segments 61, a battery cell with a structure improved in current collection efficiency can be manufactured. By setting the elongation rate and tensile strength of the current collector 41 within a predetermined range, the segments 61 can be folded smoothly without tearing, breaking, stress concentration, or disconnection at the corresponding locations.

[0099] In one aspect, the shape of the segment pieces 61 may be such that the width at the top is smaller than the width at the bottom. The segment pieces 61 may be rectangular, trapezoidal, parallelogram, triangular, semicircular, or semi-elliptical. In another aspect, at least one of the sides forming the periphery of the segment pieces may be curved, and the shape of the vertex may also be rounded. In yet another aspect, the pattern of the segment pieces may be such that the width at the bottom is larger than the width at the top, and the width may decrease stepwise and / or gradually as going from bottom to top.

[0100] To prevent damage to the active material layer 42 and / or the insulating coating layer 44 during bending of the non-coated portion 43, a predetermined gap is preferably provided between the lower end of the cut groove (C4 in FIG. 8) between the segment pieces 61 and the active material layer 42. This is because stress concentrates near the lower end of the cut groove when the non-coated portion 43 is bent. The gap is preferably 0.2 mm to 4 mm. Adjusting the gap within this range can prevent damage to the active material layer 42 and / or the insulating coating layer 44 near the lower end of the cut groove due to stress generated during bending of the non-coated portion 43. In addition, the gap can prevent damage to the active material layer 42 and / or the insulating coating layer 44 due to tolerances during notching or cutting of the segment pieces 61. Preferably, when the electrode plate 60 is wound into an electrode assembly, at least a portion of the insulating coating layer 44 may be exposed to the outside of the separator. In this case, the insulating coating layer 44 can support the bending point when the segment pieces 61 are bent.

[0101] The segment pieces 61 may be divided into a plurality of segment piece groups from the core side to the outer periphery side. The width, height, and spacing pitch of the segment pieces belonging to the same segment piece group may be substantially the same.

[0102] FIG. 8 is a diagram showing the definitions of the width, height and spacing pitch of the segment pieces 61 in the electrode plate 60 of FIG.

[0103] 8, the width C1, height C2, and spacing pitch C3 of the segment pieces 61 are designed to prevent tearing of the non-coated portion 43 during bending and to improve weld strength by sufficiently increasing the number of overlapping layers of the non-coated portion 43 to prevent abnormal deformation of the non-coated portion 43. Abnormal deformation refers to the non-coated portion below the bending point collapsing and becoming irregularly deformed, instead of maintaining a straight line. The number of overlapping layers may be preferably 10 or more.

[0104] The segment 61 is bent at or above point C4, which passes through the lower end of the cutting groove 62. The cutting groove 62 allows the segment 61 to be smoothly and easily bent in the radial direction of the electrode assembly.

[0105] The width C1 of the segment piece 61 is defined as the length between two points where two straight lines extending from both side edges 62b of the segment piece 61 intersect with a straight line extending from the bottom 62a of the cutting groove 62. The height C2 of the segment piece 61 is defined as the shortest distance between the top edge of the segment piece 61 and a straight line extending from the bottom 62a of the cutting groove 62. The separation pitch C3 of the segment pieces 61 is defined as the length between two points where a straight line extending from the bottom 62a of the cutting groove 62 intersects with a straight line extending from the two side edges 62b where the bottom 62a intersects. If the side edges 62b and / or the bottom edge 62a are curved, the straight lines may be replaced by tangent lines extending from the side edges 62b and / or the bottom edge 62a at the intersections where the side edges 62b and the bottom edge 62a intersect.

[0106] Preferably, the width C1 of the segment 61 can be adjusted within a range of 1 to 6 mm. If C1 is less than 1 mm, a non-overlapping area or space (gap) will be generated when the segment 61 is bent toward the core, ensuring sufficient welding strength. On the other hand, if C1 exceeds 6 mm, the non-coated portion 43 near the bending point may be torn by stress when the segment 61 is bent.

[0107] The height of the segment 61 can be adjusted within the longitudinal range of the non-coated portion 43. For example, the length of the non-coated portion 43 is 2 to 20 mm. Preferably, the height of the segment 61 can be adjusted within a range of 2 to 20 mm or 2 to 10 mm. If C2 is less than 2 mm, when the segment 61 is bent toward the core, a non-overlapping region or space (gap) is generated to a degree that ensures sufficient welding strength. Since the elongation and tensile strength of the current collector 41 are optimized, C2 is less restricted than when using a conventional current collector. With conventional current collectors, increasing C2 requires increasing the length of the non-coated portion. As the non-coated portion becomes longer, it becomes difficult to manufacture an electrode plate while maintaining uniform flatness of the non-coated portion in the winding direction (X direction). That is, as the height of the non-coated portion increases, waviness occurs. However, in the present invention, the current collector 41 with optimized elongation and tensile strength is used, so the range of C2 can be increased while suppressing waviness. The larger C2 is, the easier the subsequent bending process becomes, and a larger overlapping area and welding area, and therefore a stronger weld, can be secured.

[0108] Furthermore, the spacing pitch C3 of the segment pieces 61 can be adjusted within a range of 0.05 to 1 mm. If C3 is less than 0.05 mm, the non-coated portion 43 near the bending point C4 may break due to stress when the segment pieces 61 are bent. On the other hand, if C3 exceeds 1 mm, regions or spaces (gaps) may be generated where the segment pieces 61 do not overlap each other to a degree that would ensure sufficient welding strength when the segment pieces 61 are bent.

[0109] By using a current collector 41 with an optimized elongation rate and tensile strength, the segments 61 can be formed without cracks or breaks by adjusting the spacing pitch C3 of the segments 61 within a range of 0.05 to 1 mm. Even if no cracks occurred during the formation of the segments 61, cracks may occur due to the running tension when the electrode plate 60 is wound up in a process after the segments 61 are formed. It has been experimentally confirmed that, in a current collector 41 having an elongation rate and tensile strength within the ranges proposed by the present invention, if the spacing pitch C3 of the segments 61 is 0.5 mm or more, cracks due to the running tension are prevented, as will be described later with reference to FIG. 9.

[0110] A cutting groove 62 is interposed between two segment pieces 61 adjacent in the winding direction (X direction). The cutting groove 62 is a space created by removing the non-coating portion 43. Preferably, the corners at both ends of the lower portion of the cutting groove 62 are rounded. That is, the cutting groove 62 includes a substantially flat bottom portion 62a and a rounded portion 62c. The rounded portion 62c connects the bottom portion 62a to a side edge 62b of the segment piece 61. In a modified example, the bottom portion 62a of the cutting groove 62 can be replaced with an arc-shaped portion. In this case, the side edge 62b of the segment piece 61 can be smoothly connected by the arc-shaped portion of the bottom portion 62a.

[0111] The radius of curvature of the rounded portion 62c may be greater than 0 and less than or equal to 0.5 mm, preferably greater than 0 and less than or equal to 0.1 mm, and more preferably 0.01 mm to 0.05 mm. It has been experimentally confirmed that when the radius of curvature of the rounded portion 62c satisfies this range, cracks can be prevented from occurring below the cutting groove 62 while the electrode plate 60 is traveling during a winding process, etc., and this will be described with reference to FIG.

[0112] Figure 9 shows photographs of the results of an experiment to determine whether cracks occur due to running tension depending on the spacing pitch and shape of the segment pieces.

[0113] In Figures 9(a) and (b), the segment separation pitch C3 was 0.1 mm and 0.3 mm, respectively, and cracks occurred due to running tension (the locations where cracks occurred are indicated by dotted circles). Also, in (a) and (b), the bottom 62a of the cutting groove 62 was arc-shaped, and it was confirmed that maximum stresses of 14.4 MPa and 10.9 MPa, respectively, occurred at the center of the bottom 62a. Cracks occurred at the locations where these maximum stresses occurred.

[0114] In (c), (d), and (e) of Figure 9, the segment spacing pitch C3 was 0.5 mm, 0.7 mm, and 0.9 mm, respectively, and no cracks were generated due to the running tension. In particular, (c), (d), and (e) show cases where the cut groove 62 includes a substantially flat bottom portion 62a and a rounded portion 62c. It was confirmed that (c) generated a maximum stress of 10.3 MPa in the bottom portion 62a, and (d) and (e) generated a maximum stress of 9.5 MPa and 8.5 MPa in the rounded portion 62c, respectively. This maximum stress was not only smaller than (a) and (b), but also did not induce cracks. Therefore, it can be seen that a segment spacing pitch C3 of 0.5 mm or more is desirable.

[0115] In particular, in (d) and (e), where the separation pitch C3 is greater than 0.5 mm and the division between the bottom portion 62a and the rounded portion 62c is more secure, the maximum stress is not concentrated on the bottom portion 62a but is dispersed toward the rounded portion 62c, and the bottom portion 62a acts as a stress relief section, which is superior in terms of preventing crack generation. Also, in (d) and (e), the radius of curvature of the rounded portion 62c is 0.02 mm, and the maximum stress, which reaches 14.4 MPa in the state of (a), can be reduced to 9.5 MPa and 8.5 MPa, respectively, which is very desirable in terms of preventing crack generation.

[0116] Further referring to FIG. 7, the width d of the core-side non-coated portion B1 B1 is designed under the condition that the cavity in the core of the electrode assembly is not blocked when the segment piece 61 of the middle non-coated portion B2 is bent toward the core side. The cavity in the core is formed at the location where the winding core used in the winding process of the electrode assembly is removed, and this cavity is used as a passage for injecting the electrolyte. However, if this passage is blocked, it becomes difficult to inject the electrolyte. Therefore, the width d of the core-side non-coated portion B1 adjacent to the core of the electrode assembly is set to 0.5 mm so that the cavity in the core of the electrode assembly is not blocked entirely or substantially partially when the core-side non-coated portion B1 is bent. B1 can be determined.

[0117] For example, the width d of the core-side non-coated portion B1B1 may increase in proportion to the bending length of the segment piece 61 of group 1. The bending length is the height of the segment piece 61 based on the bending point (63 in FIG. 8). Referring to FIG. 8, C4 indicates the lowest bending point. The bending point may be appropriately set above C4. With respect to the bending point, C4 is the lowest point at which bending can be performed, and the bending point may move higher than that shown. The bending length is the length from the lowest point of the bending portion to the top end of the segment piece 61. Specifically, the bending point may be set at a predetermined point of height C2 of the segment piece 61 based on C4. The predetermined point can be set to prevent stress generated when bending the segment 61 from causing physical damage to the active material layer 42 or the insulating coating layer 44, and to ensure a sufficient number of layers that overlap radially when the segment 61 is bent in the radial direction of the electrode assembly, thereby ensuring sufficient welding strength when a collecting plate is welded to the bent area of ​​the segment 61.

[0118] Preferably, the predetermined point may be set at a height of at least 20% or more, at least 30% or more, at least 40% or more, at least 50% or more, at least 60% or more, at least 70% or more, or at least 80% or more based on the height C2 of the segment piece 61.

[0119] In a specific example, when the electrode plate 60 is used to manufacture an electrode assembly for a large cylindrical battery cell having a form factor such as 46110, 46800, 48750, 48110, or 48800, the width d of the core-side non-coated portion B1 is B1 can be set to 180 to 350 mm depending on the diameter of the electrode assembly core.

[0120] As described above, according to the present invention, the structure of the non-coated portion 43 adjacent to the core of the electrode assembly is improved to prevent the cavity in the core of the electrode assembly from being blocked when the non-coated portion 43 is bent, facilitating the electrolyte injection process and the welding process of the battery can and the current collecting plate.

[0121] In one embodiment, the width of each segment group can be designed to accommodate the same winding turn of the electrode assembly.

[0122] Here, the winding turns can be counted based on the end of the core-side non-coated portion B1 when the electrode plate 60 is in a wound state.

[0123] In another variation, the width of each segment group can be designed to accommodate at least one or more winding turns of the electrode assembly.

[0124] In other variations, the width and / or height and / or spacing pitch of segment pieces 61 belonging to the same segment piece group may increase or decrease gradually and / or stepwise and / or irregularly within the group.

[0125] 7, groups 1 to 8 are merely examples of segment groups. The number of groups and the number of segment pieces 61 included in each group can be adjusted so that the segment pieces 61 are overlapped in multiple layers to maximize stress dispersion during the bending process of the non-coated portion 43 and ensure sufficient welding strength.

[0126] In other variations, the height of the outer peripheral non-coated portion B3 may decrease gradually or in steps. The segmented structure of the intermediate non-coated portion B2 may extend to the outer peripheral non-coated portion B3 (see dotted lines). In this case, the outer peripheral non-coated portion B3 may also include multiple segmented pieces, similar to the intermediate non-coated portion B2. In this case, the segmented pieces of the outer peripheral non-coated portion B3 may have a larger width, height, and / or spacing pitch than the intermediate non-coated portion B2.

[0127] In a specific example, when the electrode plate 60 is used to manufacture an electrode assembly for a large cylindrical battery cell having a form factor such as 46110, 46800, 48750, 48110, or 48800, the segment pieces may be formed in groups of eight. B1may be 180 to 350 mm. The width of group 1 may be 35 to 40% of the width of the core-side non-coating portion B1. The width of group 2 may be 130 to 150% of the width of group 1. The width of group 3 may be 120 to 135% of the width of group 2. The width of group 4 may be 85 to 90% of the width of group 3. The width of group 5 may be 120 to 130% of the width of group 4. The width of group 6 may be 100 to 120% of the width of group 5. The width of group 7 may be 90 to 120% of the width of group 6. The width of group 8 may be 115 to 130% of the width of group 7.

[0128] The reason why the widths of groups 1 to 8 do not show a constant increasing or decreasing pattern is that although the width of the segments gradually increases from group 1 to group 8, the number of segments included in a group is limited to an integer. Therefore, the number of segments may decrease in a particular segment group. Therefore, the width of the group may show an irregular change as it progresses from the core side to the outer periphery side, as shown in the example above.

[0129] The segmented structure of the middle non-coating portion B2 can also be applied to the core-side non-coating portion B1. However, if a segmented structure is applied to the core-side non-coating portion B1, when the segmented pieces 61 of the middle non-coating portion B2 are bent due to the curvature radius of the core, a reverse forming phenomenon may occur in which the end of the core-side non-coating portion B1 is warped toward the outer periphery. Therefore, it is preferable that the core-side non-coating portion B1 does not have a segmented structure.

[0130] When the elongation and tensile strength of the current collector 41 are within a predetermined range and the non-coated portion 43 is segmented as described above, the present invention has the advantage of ensuring excellent processability, for example, notching processability. Because no breaks or cracks occur in the notched portion, the structural rigidity of the electrode plate 60 and the electrode assembly including the electrode plate 60 is ensured, and unnecessary electrical contacts or current paths are not created.

[0131] Such an electrode plate 60 is highly suitable for manufacturing a tabless cylindrical secondary battery. As a result, the current collector 41 according to the present invention and the electrode plate 60 including the same are highly suitable for manufacturing large-sized batteries such as cylindrical battery cells with form factors of 46110, 48750, 48110, 48800, 46800, etc.

[0132] FIG. 10 is a plan view showing the structure of an electrode plate according to still another embodiment of the present invention.

[0133] Referring to FIG. 10, the electrode plate 70 of FIG. 10 is substantially identical in configuration to the electrode plate 60 of FIG. 7, except that the shape of the segment 61' has been changed from a square to a trapezoid compared to the electrode plate 60 of FIG. 7.

[0134] FIG. 11 shows the definition of the width, height and spacing pitch of the trapezoidal segment pieces 61'.

[0135] 11, the width D1, height D2, and spacing pitch D3 of the segment pieces 61' may be the same as those of the width C1, height C2, and spacing pitch C3 of the segment pieces 61 described with reference to FIG. 8. The width of the segment pieces 61' at their top may be 0.5 mm to 6 mm. The segment pieces 61' are bent at or above point D4, where they pass through the lower end of the cutting groove 62.

[0136] The lower interior angle θ of the trapezoid of the segments 61' may increase as the segment moves from the core side toward the outer periphery. The curvature increases as the radius of the electrode assembly increases. If the lower interior angle θ of the segments 61' increases as the radius of the electrode assembly increases, stresses generated in the radial and circumferential directions when the segments 61' are bent can be alleviated. Furthermore, as the lower interior angle θ increases, the overlapping area and number of overlapping layers with the inner segments 61' also increase when the segments 61' are bent, ensuring uniform welding strength in the radial and circumferential directions and allowing the bent surfaces to be formed flat.

[0137] In one example, when the electrode plate 70 is used to manufacture an electrode assembly for a cylindrical battery cell having a form factor such as 46110, 48750, 48110, 48800, or 46800, the interior angle of the segment piece 61' may increase stepwise between 60° and 85° as the radius of the electrode assembly increases from 4 mm to 22 mm. When the non-coated portion 43 is deformed to have the segment piece 61' as described above due to the elongation and tensile strength of the current collector 41 falling within a predetermined range, the present invention achieves excellent processability, i.e., notching processability. No breaks or cracks occur in the notched portion.

[0138] The following experimental results show the results of measuring the camber length and notching processability according to the change in elongation rate and tensile strength of the aluminum current collector.

[0139] After the active material layer is coated on the aluminum current collector, the uncoated portion of the aluminum current collector is notched along the length of the uncoated portion, as described in Figures 7 and 10, and divided into multiple segments. The notching process can be evaluated based on whether or not cracks occur at the notched portion. If cracks occur, the result is "failed," and if no cracks occur, the result is "passed," as shown in Table 1.

[0140] The elongation can be measured by attaching a current collector sample to the sample grip of a universal testing machine (e.g., Instron 3345, 3365 UTM) and pulling it at a constant speed to measure the tensile deformation. The tensile deformation at which the sample breaks is defined as the elongation. Tensile strength can also be measured using such a universal testing machine according to the IPC-TM-650 measurement method. The elongation can be calculated from the deformation at which the sample breaks in a tensile strength test based on IPC-TM-650 at room temperature. IPC-TM-650 standards for tensile strength testing include sections 2.4.18 and 2.4.19. For example, the elongation can be measured according to the IPC-TM-650 (2.4.19) method.

[0141] Specifically, the current collector sample was 12.7 mm wide and 150 mm long, and the measurement speed was 20 mm / min. Because the measurement was performed so that stretching occurred at the center of the sample, a 50 mm gauge length was marked at the center of the sample (for example, a 50 mm line was marked at the center of the sample along the length of the sample), and the equipment used was a UTM. The prepared current collector sample was loaded into the UTM and tested at a standard speed (20 mm / min). The force at which breakage occurred at the center of the sample was divided by the cross-sectional area of ​​the sample (sample width x sample thickness) to determine the tensile strength value. The broken samples were then lined up lengthwise, and the stretch rate was calculated using Equation 1 based on the increase in the initially marked 50 mm gauge length.

[0142] [Table 1]

[0143] According to the experimental results, when electrode plates were fabricated from aluminum current collectors with a centrifugal ratio exceeding 3.0% (Comparative Examples 1, 3, and 4), the camber length was measured at approximately 20 mm or more. On the other hand, when electrode plates were fabricated from aluminum current collectors with an elongation ratio in the range of 1.5 to 3.0% (Examples 1 and 2), the camber lengths were measured at 16 mm and 11 mm, respectively. When the measured camber length exceeded 20 mm, poor meandering occurred and wire breakage occurred. On the other hand, in Comparative Example 2, although the elongation ratio did not exceed 3.0%, wire breakage occurred at the notched portion, resulting in poor notching processability. This is because the tensile strength was 25 kgf / mm 2 This is because the elongation ratio is smaller than the tensile strength of the current collector. This problem did not occur in Examples 1 and 2. As described above, according to the present invention, by designing the elongation ratio and tensile strength of the current collector, it is possible to minimize not only the occurrence of camber but also the occurrence of wire breakage when the segment pieces are notched.

[0144] 12 is a set of photographs for comparing the degree of waviness when electrode plates were manufactured from the current collector of Comparative Example 3 and the current collector of Example 1. The photograph shown in (a) is the electrode plate (positive electrode plate) manufactured from the current collector of Comparative Example 3, and the photograph shown in (b) is the electrode plate (positive electrode plate) manufactured from the current collector of Example 1.

[0145] Referring to FIG. 12, it can be visually confirmed that the electrode plate manufactured from the current collector of Example 1 had little waviness.

[0146] The structure of the electrode plates 40, 60, and 70 of the above-described embodiment (variant) may be applied to at least one of the first and second electrode plates having different polarities included in a jelly-roll type electrode assembly. Furthermore, when the electrode structure of the embodiment (variant) is applied to one of the first and second electrode plates, a conventional electrode plate structure may be applied to the other. Furthermore, the electrode plate structures applied to the first and second electrode plates may not be the same, but may be different.

[0147] In one example, when the first electrode plate and the second electrode plate are a positive electrode plate and a negative electrode plate, respectively, one of the embodiments (variant examples) may be applied to the first electrode plate, and a conventional electrode plate structure (see FIG. 1) may be applied to the second electrode plate.

[0148] In another example, when the first electrode plate and the second electrode plate are a positive electrode plate and a negative electrode plate, respectively, any one of the embodiments (variants) may be selectively applied to the first electrode plate, and any one of the embodiments (variants) may be selectively applied to the second electrode plate.

[0149] In the present invention, the positive electrode active material and the negative electrode active material coated on the current collector may be any active material known in the art without any limitations.

[0150] As an example, the positive electrode active material has the general chemical formula A[A x M y ]O 2+z(A includes at least one element selected from Li, Na, and K; M includes at least one element selected from Ni, Co, Mn, Ca, Mg, Al, Ti, Si, Fe, Mo, V, Zr, Zn, Cu, Al, Mo, Sc, Zr, Ru, and Cr; x≧0, 1≦x+y≦2, −0.1≦z≦2; and the stoichiometric coefficients x, y, and z are selected to maintain electrical neutrality of the compound.)

[0151] Preferably, the positive electrode active material includes a lithium transition metal oxide, such as a nickel-cobalt-manganese-based lithium oxide, especially a high-concentration nickel-cobalt-manganese-based lithium oxide having a high nickel content among the transition metals.

[0152] In another example, the positive electrode active material is an alkali metal compound xLiM disclosed in US Pat. No. 6,677,082, US Pat. No. 6,680,143, etc. 1 O2‐(1‐x)Li2M 2 O3(M 1 contains at least one element having an average oxidation state of 3; M 2 may contain at least one element having an average oxidation state of 4; 0≦x≦1).

[0153] In yet another example, the positive electrode active material has the general chemical formula Li a M 1 x Fe 1‐x M 2 y P 1‐y M 3 z O 4‐z (M 1 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Mg, and Al; M 2 contains at least one element selected from Ti, Si, Mn, Co, Fe, V, Cr, Mo, Ni, Nd, Mg, Al, As, Sb, Si, Ge, V, and S; M 3contains a halogen group element selectively containing F; 0 < a ≤ 2, 0 ≤ x ≤ 1, 0 ≤ y < 1, 0 ≤ z < 1; the stoichiometric coefficients a, x, y, and z are selected so that the compound maintains electrical neutrality.), or can be a lithium metal phosphate represented by Li3M2(PO4)3 [M contains at least one element selected from Ti, Si, Mn, Fe, Co, V, Cr, Mo, Ni, Mg, and Al.].

[0154] Desirably, the positive electrode active material may contain primary particles and / or secondary particles formed by aggregation of primary particles.

[0155] In one example, the negative electrode active material can use a carbon material, a lithium metal or a lithium metal compound, silicon or a silicon compound, tin or a tin compound, etc. Metal oxides such as TiO2 and SnO2 with a potential less than 2V can also be used as the negative electrode active material. As the carbon material, low-crystalline carbon, high-crystalline carbon, etc. can all be used.

[0156] The separation membrane can be used alone or in a laminated form a porous polymer film, for example, a porous polymer film made from polyolefin-based polymers such as polyethylene homopolymer, polypropylene homopolymer, ethylene / butene copolymer, ethylene / hexene copolymer, ethylene / methacrylate copolymer, etc. In another example, the separation membrane can use a normal porous non-woven fabric, for example, a non-woven fabric made from high-melting glass fibers, polyethylene terephthalate fibers, etc.

[0157] At least one surface of the separation membrane may include a coating layer of inorganic particles. Also, the separation membrane itself can be composed of a coating layer of inorganic particles. The particles constituting the coating layer can have a structure bonded to a binder so that an interstitial volume exists between adjacent particles.

[0158] The inorganic particles can be composed of an inorganic substance with a dielectric constant of 5 or more. As a non-limiting example, the inorganic particles are Pb(Zr,Ti)O3 (PZT), Pb1-x La x Zr 1-y Ti y O3(PLZT), Pb(Mg 1 / 3 Nb 2 / 3 )O3-PbTiO3 (PMN-PT), BaTiO3, hafnia (HfO2), SrTiO3, TiO2, Al2O3, ZrO2, SnO2, CeO2, MgO, CaO, ZnO, and Y2O3.

[0159] Fig. 13 is a cross-sectional view of an electrode assembly according to an embodiment of the present invention, taken along the Y-axis (winding axis direction) of a jelly-roll type electrode assembly in which the electrode plate 50 of the first embodiment shown in Fig. 6 is used as the first electrode plate (positive electrode plate) and the second electrode plate (negative electrode plate).

[0160] The electrode assembly 80 may be manufactured using the winding method described with reference to FIG. 2. It has a structure in which sheet-like first and second electrode plates and a separator interposed therebetween are wound in one direction. For ease of explanation, the protruding structure of the non-coated portions 43a and 43b extending outward from the separator is illustrated in detail, while the winding structure of the first and second electrode plates and separator is not illustrated. The non-coated portion 43a protruding upward extends from the first electrode plate, and the non-coated portion 43b protruding downward extends from the second electrode plate. At least a portion of the upper non-coated portion 43a and the lower non-coated portion 43b are exposed to the outside of the separator and used as electrode tabs.

[0161] Referring to Figure 13, the non-coated portion 43a of the first electrode plate includes a core-side non-coated portion B1 adjacent to the core of the electrode assembly 80, an outer-periphery-side non-coated portion B3 adjacent to the outer peripheral surface of the electrode assembly 80, and an intermediate non-coated portion B2 interposed between the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3.

[0162] The height (length in the Y-axis direction) of the outer peripheral uncoated portion B3 is relatively smaller than the height of the middle uncoated portion B2. Therefore, it is possible to prevent an internal short circuit caused by the outer peripheral uncoated portion B3 being pressed against the beading portion of the battery can. As such, according to the present invention, the structure of the uncoated portions 43a, 43b is improved to prevent interference between the electrode assembly 80 and the inner surface of the battery can during the formation of the beading portion of the battery can, thereby preventing an internal short circuit of the cylindrical battery cell due to partial deformation of the electrode assembly 80.

[0163] The lower non-coating portion 43b has the same structure as the upper non-coating portion 43a. In one variation, the lower non-coating portion 43b may have a conventional electrode plate structure or an electrode plate structure of another embodiment (variation).

[0164] The ends 81 of the upper non-coated portion 43a and the lower non-coated portion 43b may be bent in the radial direction of the electrode assembly 80, for example, from the outer periphery toward the core. At this time, the outer periphery non-coated portion B3 is not substantially bent.

[0165] FIG. 14 is a cross-sectional view of a jelly-roll type electrode assembly 100 in which either one of the electrode plates 60 and 70 of the second and third embodiments is applied to the first electrode plate (positive electrode plate) and the second electrode plate (negative electrode plate), taken along the Y-axis direction (winding axis direction).

[0166] Referring to Figure 14, the non-coated portion 43a of the first electrode plate includes a core-side non-coated portion B1 adjacent to the core of the electrode assembly 100, an outer-periphery-side non-coated portion B3 adjacent to the outer peripheral surface of the electrode assembly 100, and an intermediate non-coated portion B2 interposed between the core-side non-coated portion B1 and the outer-periphery-side non-coated portion B3.

[0167] The varying heights of the non-coated portions 43a, 43b are shown only schematically. That is, the heights of the non-coated portions 43a, 43b may vary irregularly depending on where the cross section is cut. For example, when the side portions of the trapezoidal segments 61, 61' are cut, the height of the non-coated portions in the cross section will be lower than the height of the segments 61, 61'. Therefore, it is understood that the height of the non-coated portions 43a, 43b shown in the cross-sectional views of the electrode assembly corresponds to the average height of the non-coated portions included in each winding turn (C2 in FIG. 8, D2 in FIG. 11).

[0168] The height of the core-side non-coating portion B1 is relatively smaller than the height of the middle non-coating portion B2. The bending length of the innermost non-coating portion 43a in the middle non-coating portion B2 is equal to or smaller than the radial length R of the core-side non-coating portion B1. The bending length H corresponds to the height of the non-coating portion 43a based on the bending point (h in FIG. 8, h in FIG. 11). D4 is the lowest point of the bending point, and the bending point can be set above D4.

[0169] Therefore, even if the middle non-coated portion B2 is bent, the bent portion does not block the cavity 102 in the core of the electrode assembly 100. If the cavity 102 is not blocked, the electrolyte injection process is not difficult and the efficiency of the electrolyte injection is improved. In addition, a welding jig can be inserted through the cavity 102 to easily perform the welding process between the negative electrode current collecting plate and the battery can.

[0170] The height of the outer non-coated portion B3 is relatively smaller than the height of the middle non-coated portion B2, which prevents the outer non-coated portion B3 from being pressed by the beading portion of the battery can, thereby preventing the occurrence of an internal short circuit.

[0171] In one variation, the height of the outer peripheral non-coated portion B3 may decrease gradually or in steps, unlike that shown in Figure 14. Also, in Figure 14, the height of the middle non-coated portion B2 is the same at a portion on the outer peripheral side, but the height of the middle non-coated portion B2 may increase gradually or in steps from the boundary between the core side non-coated portion B1 and the middle non-coated portion B2 to the boundary between the middle non-coated portion B2 and the outer peripheral non-coated portion B3.

[0172] The lower non-coating portion 43b has the same structure as the upper non-coating portion 43a. In one variation, the lower non-coating portion 43b may have the structure of a conventional electrode plate or the electrode plate structure of another embodiment (variation).

[0173] The ends 101 of the upper non-coated portion 43a and the lower non-coated portion 43b may be bent in the radial direction of the electrode assembly 100, for example, from the outer periphery to the core side. In this case, the core-side non-coated portion B1 and the outer periphery-side non-coated portion B3 are not substantially bent.

[0174] When the middle non-coated portion B2 includes multiple segments, bending stress is alleviated, preventing tearing or abnormal deformation of the non-coated portion 43a near the bending point. Furthermore, when the width, height, and / or spacing of the segments are adjusted within the ranges of the above-described embodiments, the segments are folded toward the core, overlapping each other to a degree that ensures sufficient welding strength and prevents holes (gaps) from forming on the folded surface (surface viewed from the Y-axis). Furthermore, to optimize the elongation and tensile strength of the current collector 41, there are no breaks or cracks between the multiple segments.

[0175] FIG. 15 is a cross-sectional view of an electrode assembly 110 according to yet another embodiment of the present invention, taken along the Y-axis (winding axis) direction.

[0176] 15, the electrode assembly 110 has substantially the same configuration as the electrode assembly 100 of FIG. 14, except that the height of the outer peripheral non-coated portion B3 is substantially the same as the height of the outermost intermediate non-coated portion B2. The outer peripheral non-coated portion B3 may include multiple segment pieces.

[0177] The peripheral non-application portion B3 may include a plurality of segment pieces. The configuration relating to the plurality of segment pieces is substantially the same as that of the above-described embodiment (variation).

[0178] In the electrode assembly 110, the height of the core-side non-coating portion B1 is relatively smaller than the height of the middle non-coating portion B2. In addition, the bending length H of the innermost non-coating portion of the middle non-coating portion B2 is equal to or smaller than the radial length R of the core-side non-coating portion B1.

[0179] Therefore, even if the middle non-coated portion B2 is bent, the bent portion does not block the cavity 112 in the core of the electrode assembly 110. If the cavity 112 is not blocked, the electrolyte injection process is easy and the efficiency of the electrolyte injection is improved. In addition, a welding jig can be inserted through the cavity 112 to easily perform the welding process between the negative electrode current collecting plate and the battery can.

[0180] In one variation, the structure in which the height of the intermediate non-coated portion B2 increases gradually or in steps from the core side toward the outer periphery side may be extended to the outer periphery non-coated portion B3. In this case, the height of the non-coated portion 43a may increase gradually or in steps from the boundary between the core side non-coated portion B1 and the intermediate non-coated portion B2 to the outermost surface of the electrode assembly 110.

[0181] The lower non-coating portion 43b has the same structure as the upper non-coating portion 43a. In one variation, the lower non-coating portion 43b may have a conventional electrode plate structure or the electrode plate structure of another embodiment (variation).

[0182] The ends 111 of the upper non-coated portion 43a and the lower non-coated portion 43b may be bent from the outer periphery side to the core side of the electrode assembly 110. At this time, the core-side non-coated portion B1 is not substantially bent.

[0183] When the middle non-coated portion B2 and the outer peripheral non-coated portion B3 include multiple segments, bending stress is alleviated, preventing tearing or abnormal deformation of the non-coated portions 43a, 43b near the bending points. Furthermore, when the width, height, and / or spacing of the segments are adjusted within the ranges of the above-described embodiments, the segments are overlapped to an extent that sufficient welding strength is ensured as they are bent toward the core, preventing holes (gaps) from forming on the bending surface (surface viewed from the Y axis). Furthermore, the elongation and tensile strength of the current collector 41 are optimized, preventing breaks or cracks between the multiple segments.

[0184] Various electrode assembly structures according to embodiments of the present invention may be applied to jelly-roll type cylindrical battery cells.

[0185] Desirably, the cylindrical battery cell may be, for example, a cylindrical battery cell having a form factor ratio (defined as the diameter of a cylindrical battery divided by its height, i.e., the ratio of the diameter Φ to the height H) of greater than about 0.4.

[0186] When an electrode assembly having a tabless structure is applied to a cylindrical battery cell with a form factor ratio exceeding 0.4, bending the non-coated portion can easily cause the non-coated portion to break due to the large radial stress applied. Furthermore, when welding a current collecting plate to the bent surface of the non-coated portion, the number of overlapping layers of the non-coated portion must be increased to ensure sufficient welding strength and reduce resistance. These requirements can be achieved by the electrode plate and electrode assembly according to an embodiment (variant) of the present invention.

[0187] A battery cell according to one embodiment of the present invention may be a cylindrical battery cell that is approximately cylindrical, with a diameter of about 46 mm, a height of about 110 mm, and a form factor ratio of about 0.418.

[0188] Another example battery cell may be a cylindrical battery cell that is approximately cylindrical, with a diameter of about 48 mm, a height of about 75 mm, and a form factor ratio of about 0.640.

[0189] In addition, the battery cell according to another embodiment may be a cylindrical battery cell that is approximately cylindrical, with a diameter of about 48 mm, a height of about 110 mm, and a form factor ratio of about 0.436.

[0190] Furthermore, a battery cell according to yet another embodiment may be a cylindrical battery cell that is approximately cylindrical, with a diameter of approximately 48 mm, a height of approximately 80 mm, and a form factor ratio of approximately 0.600.

[0191] In yet another embodiment, the battery cell may be a cylindrical battery cell that is approximately cylindrical, with a diameter of about 46 mm, a height of about 80 mm, and a form factor ratio of about 0.575.

[0192] Conventionally, battery cells with a form factor ratio of approximately 0.4 or less have been used. For example, 18650 cells and 21700 cells have been used. 18650 cells have a diameter of approximately 18 mm, a height of approximately 65 mm, and a form factor ratio of 0.277. 21700 cells have a diameter of approximately 21 mm, a height of approximately 70 mm, and a form factor ratio of 0.300.

[0193] Hereinafter, a cylindrical battery cell according to an embodiment of the present invention will be described in detail.

[0194] FIG. 16 is a cross-sectional view of a cylindrical battery cell 170 according to an embodiment of the present invention taken along the Y axis.

[0195] 16, a cylindrical battery cell 170 according to an embodiment of the present invention includes an electrode assembly 141 including a first electrode plate, a separator, and a second electrode plate. The cylindrical battery cell 170 also includes a battery can 171 having a rivet terminal 172 passing therethrough. The battery can 171 is made of a conductive metal material such as aluminum or steel. The battery can 171 accommodates the electrode assembly 141 in its inner space, along with an electrolyte.

[0196] The electrolyte is A + B - The salt may have the structure: + Li + , Na + , K. + or a combination thereof. - is F - , Cl - , Br - , I - , NO3 - , N(CN)2 - , BF4 - , ClO4 - , AlO4 - , AlCl4 - , PF6 - , SbF6 - , AsF6 - , BF2C2O4 - , BC4O8 - , (CF3)2PF4 - , (CF3)3PF3 - , (CF3)4PF2 - , (CF3)5PF - , (CF3)6P - , CF3SO3 - , C4F9SO3 - , CF3CF2SO3 - , (CF3SO2)2N - , (FSO2)2N - , CF3CF2(CF3)2CO - , (CF3SO2)2CH - , (SF5)3C - , (CF3SO2)3C - , CF3(CF2)7SO3 -, CF3CO2 - , CH3CO2 - , SCN- and (CF3CF2SO2)2N - The anion comprises one or more anions selected from the group consisting of:

[0197] Alternatively, the electrolyte may be dissolved in an organic solvent, such as propylene carbonate (PC), ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), dipropyl carbonate (DPC), dimethyl sulfoxide, acetonitrile, dimethoxyethane, diethoxyethane, tetrahydrofuran, N-methyl-2-pyrrolidone (NMP), ethyl methyl carbonate (EMC), γ-butyrolactone, or a mixture thereof.

[0198] The electrode assembly 141 may have a jelly-roll shape. As shown in FIG. 2, the electrode assembly 141 may be manufactured by sequentially stacking a lower separator, a first electrode plate, an upper separator, and a second electrode plate at least once, and winding the stacked body around a winding center C.

[0199] The first and second electrode plates have opposite polarities. That is, one has a positive polarity and the other has a negative polarity. At least one of the first and second electrode plates may have an electrode plate structure according to the above-described embodiment (variant). Furthermore, the remaining one of the first and second electrode plates may have a conventional electrode plate structure or an electrode plate structure according to the embodiment (variant).

[0200] For example, the first polarity is a negative electrode and the second polarity is a positive electrode. The battery can 171 is electrically connected to one of the first electrode plate and the second electrode plate and has a first polarity. The first polarity is a negative electrode, and the battery can 171 is connected to the electrode plate having the negative polarity. For example, the battery can 171 is connected to the second electrode plate.

[0201] An uncoated portion 146a of the first electrode plate and an uncoated portion 146b of the second electrode plate protrude from the top and bottom of the electrode assembly 141, respectively. A rivet terminal 172 is provided on the closed surface (top surface in the drawing) of the battery can 171. The rivet terminal 172 is riveted into a through-hole in the battery can 171 with an insulating second gasket 173 interposed therebetween. The rivet terminal 172 is exposed to the outside in the direction opposite to the direction of gravity. The surface of the rivet terminal 172 is exposed to the outside.

[0202] The rivet terminal 172 includes a terminal exposed portion 172a and a terminal inserted portion 172b. The terminal exposed portion 172a is exposed to the outside of the closed surface of the battery can 171. The terminal exposed portion 172a may be located approximately at the center of the closed surface of the battery can 171. The maximum diameter of the terminal exposed portion 172a may be larger than the maximum diameter of the through-hole formed in the battery can 171. The terminal inserted portion 172b may penetrate approximately the center of the closed surface of the battery can 171 to be electrically connected to the uncoated portion 146a of the first electrode plate. The terminal inserted portion 172b may be rivet-connected to the inner surface of the battery can 171. That is, an end of the terminal inserted portion 172b may be bent toward the inner surface of the battery can 171. The maximum diameter of the end of the terminal inserted portion 172b may be larger than the maximum diameter of the through-hole in the battery can 171. The rivet terminal 172 is electrically connected to the other of the first and second electrode plates that is not connected to the battery can 171. For example, the rivet terminal 172 is connected to the first electrode plate having a positive polarity, and thereby has a positive polarity, which is the second polarity.

[0203] The cylindrical battery cell 170 may further include a first current collecting plate 144. The first current collecting plate 144 is made of a conductive metal material such as aluminum, copper, or nickel, and is electrically connected to the uncoated portion 146a of the first electrode plate. The first current collecting plate 144 may have a plurality of radially formed protrusions and recesses (not shown) on its lower surface. If the radial protrusions and recesses are provided, the first current collecting plate 144 may be pressed against the uncoated portion 146a of the first electrode plate to press the protrusions and recesses into the uncoated portion 146a of the first electrode plate.

[0204] The first current collecting plate 144 is bonded to an end of the uncoated portion 146a of the first electrode plate. The uncoated portion 146a and the first current collecting plate 144 may be bonded together by, for example, laser welding. Laser welding may be performed by partially melting the base material of the current collecting plate. In a modified example, the first current collecting plate 144 and the uncoated portion 146a may be welded together using solder. In this case, the solder may have a lower melting point than the first current collecting plate 144 and the uncoated portion 146a. Laser welding may be replaced by resistance welding, ultrasonic welding, etc.

[0205] Preferably, the rivet terminal 172 electrically connected to the non-coated portion 146a of the first electrode plate is used as the first electrode terminal. If the first electrode plate has a positive polarity, the rivet terminal 172 connected thereto becomes the positive terminal.

[0206] The lower end surface of the terminal insertion portion 172b may be welded to the first current collecting plate 144 connected to the uncoated portion 146a of the first electrode plate. An insulating cap 174 made of an insulating material may be interposed between the first current collecting plate 144 and the inner surface of the battery can 171. The insulating cap 174 covers the upper portion of the first current collecting plate 144 and the upper edge of the electrode assembly 141. This prevents the outer peripheral uncoated portion B3 of the electrode assembly 141 from coming into contact with the inner surface of the battery can 171 having the opposite polarity, causing a short circuit. The terminal insertion portion 172b of the rivet terminal 172 may be welded to the first current collecting plate 144 through the insulating cap 174.

[0207] The second gasket 173 is interposed between the battery can 171 and the rivet terminal 172 to prevent the battery can 171 and the rivet terminal 172, which have opposite polarities, from coming into electrical contact with each other. As a result, the upper surface of the battery can 171, which has a substantially flat shape, can function as a second electrode terminal of the cylindrical battery cell 170. For example, it can be a negative electrode terminal.

[0208] The second gasket 173 includes a gasket exposing portion 173a and a gasket inserting portion 173b. The gasket exposing portion 173a is interposed between the terminal exposing portion 172a of the rivet terminal 172 and the battery can 171. The gasket inserting portion 173b is interposed between the terminal inserting portion 172b of the rivet terminal 172 and the battery can 171. The gasket inserting portion 173b is deformed during riveting of the terminal inserting portion 172b and may adhere to the inner surface of the battery can 171. The second gasket 173 may be made of, for example, an insulating polymer resin.

[0209] The gasket exposing portion 173a of the second gasket 173 may extend to cover the outer peripheral surface of the terminal exposing portion 172a of the rivet terminal 172. When the second gasket 173 covers the outer peripheral surface of the rivet terminal 172, it is possible to prevent a short circuit from occurring during the process of connecting an electrical connection part, such as a bus bar, to the upper surface of the battery can 171 and / or the rivet terminal 172. Although not shown, the gasket exposing portion 173a may extend to cover not only the outer peripheral surface of the terminal exposing portion 172a but also a portion of the upper surface.

[0210] When the second gasket 173 is made of a polymer resin, the second gasket 173 can be joined to the battery can 171 and the rivet terminal 172 by thermal welding. In this case, the airtightness can be strengthened at the joining interface between the second gasket 173 and the rivet terminal 172 and at the joining interface between the second gasket 173 and the battery can 171. Meanwhile, when the gasket exposed portion 173a of the second gasket 173 extends to the upper surface of the terminal exposed portion 172a, the rivet terminal 172 can be joined integrally with the second gasket 173 by insert injection.

[0211] On the top surface of the battery can 171 , the remaining area 175 excluding the area occupied by the rivet terminal 172 and the second gasket 173 becomes a second electrode terminal of opposite polarity to the rivet terminal 172 .

[0212] The second current collecting plate 176 is coupled to the lower part of the electrode assembly 141. The second current collecting plate 176 is made of a conductive metal material such as aluminum, steel, copper, or nickel, and is electrically connected to the non-coated portion 146b of the second electrode plate.

[0213] Preferably, the second current collecting plate 176 is electrically connected to the battery can 171. To this end, the second current collecting plate 176 may be fixed with at least a portion of its edge interposed between the inner surface of the battery can 171 and the first gasket 178b. In one example, at least a portion of the edge of the second current collecting plate 176 may be fixed to the beading portion 180 by welding while being supported by the lower end surface of the beading portion 180 formed at the lower end of the battery can 171. The beading portion 180 is formed by press-fitting the outer peripheral surface of the battery can 171. In a modified example, at least a portion of the edge of the second current collecting plate 176 may be directly welded to the inner wall surface of the battery can 171.

[0214] The second current collecting plate 176 may have a plurality of projections and recesses (not shown) formed radially on the surface facing the non-coated portion 146b. When the projections and recesses are formed, the second current collecting plate 176 may be pressed against the non-coated portion 146b to press the projections and recesses into the non-coated portion 146b. Preferably, the ends of the second current collecting plate 176 and the non-coated portion 146b may be joined by welding, for example, laser welding.

[0215] The non-coating portions 146a, 146b are not limited to the structure shown in the figure, and therefore, the non-coating portions 146a, 146b may selectively have not only the structure of a conventional non-coating portion but also the structure of a non-coating portion of an electrode plate according to an embodiment (variant).

[0216] The sealing body 178 that seals the lower open end of the battery can 171 includes a cap plate 178a and a first gasket 178b. The first gasket 178b electrically separates the cap plate 178a from the battery can 171. A crimping portion 181 secures the edge of the cap plate 178a and the first gasket 178b together.

[0217] The cap plate 178a is provided with a vent portion 179. The vent portion 179 is a region of the cap plate 178a that is thinner than the surrounding region. The vent portion 179 is structurally weaker than the surrounding region. Therefore, if an abnormality occurs in the cylindrical battery cell 170 and the internal pressure increases above a certain level, the vent portion 179 may burst, allowing gas generated inside the battery can 171 to be released to the outside. The vent portion 179 may be formed continuously or discontinuously in a circular pattern on the cap plate 178a. In a modified example, the vent portion 179 may be formed in a linear pattern or other patterns.

[0218] Preferably, the cap plate 178a is made of a conductive metal material. However, the cap plate 178a does not have electrical polarity because the first gasket 178b is interposed between the cap plate 178a and the battery can 171. The cap plate 178a seals the open end of the lower part of the battery can 171 and functions to release gas when the internal pressure of the battery cell 170 increases above a critical value.

[0219] The remaining region 175 of the upper surface of the battery can 171, excluding the rivet terminal 172, electrically connected to the uncoated portion 146b of the second electrode plate via the second current collecting plate 176 is used as a second electrode terminal having a polarity opposite to that of the first electrode terminal. When the first and second electrode terminals are located at the top of the cylindrical battery cell 170, electrical connection components such as bus bars can be disposed on only one side of the cylindrical battery cell 170. This simplifies the battery pack structure and improves energy density. Furthermore, the region 175 used as the second electrode terminal has a substantially flat shape, ensuring a sufficient bonding area for bonding electrical connection components such as bus bars. This allows the cylindrical battery cell 170 to reduce resistance at the bonding locations of electrical connection components to a desired level.

[0220] Such a cylindrical battery cell 170 can reduce the internal resistance of the battery cell and increase the energy density by using the uncoated portions 146a and 146b protruding upward and downward of the electrode assembly 141 as electrode tabs.

[0221] Meanwhile, the structure of the electrode assembly 141 and the structure of the non-application portion are not limited to those shown in the drawings, and can be replaced with the structures of the above-described embodiment (variations).

[0222] FIG. 17 is a cross-sectional view of a cylindrical battery cell according to another embodiment of the present invention taken along the Y-axis direction.

[0223] Referring to FIG. 17, a cylindrical battery cell 200 includes the electrode assembly 110 shown in FIG. 15, and the remaining configuration except for the electrode assembly 110 is substantially the same as the cylindrical battery cell 170 shown in FIG. 16.

[0224] 17, the non-coated portions 146a and 146b of the electrode assembly 110 are bent in the radial direction of the electrode assembly 110, for example, from the outer periphery to the core. At this time, the core-side non-coated portion B1 is not substantially bent because its height is lower than the other portions. The first current collecting plate 144 may be welded to the bent surface of the non-coated portion 146a, and the second current collecting plate 176 may be welded to the bent surface of the non-coated portion 146b.

[0225] The height of the core-side non-coating portion B1 is relatively lower than the other portions of the electrode assembly 110. Also, as shown in Fig. 15, the bending length H of the innermost non-coating portion of the middle non-coating portion B2 is equal to or smaller than the radial length R of the core-side non-coating portion B1.

[0226] Therefore, even if the non-coating portions 146a and 146b are bent toward the core side, the cavity 112 of the core of the electrode assembly 110 can be opened at the top without being closed.

[0227] If cavity 112 is not blocked, the process of injecting the electrolyte becomes easier, improving the efficiency of injecting the electrolyte. Also, a welding jig can be inserted through cavity 112 to easily weld second current collecting plate 176 and battery can 171 together.

[0228] When the non-coated portions 146a, 146b have a segmented structure, adjusting the width and / or height and / or spacing of the segments to satisfy the numerical ranges of the above-described embodiment allows the segments to be folded so that they overlap each other to a degree that ensures sufficient welding strength and does not form gaps on the folded surfaces. In addition, the elongation and tensile strength of the current collector 41 are optimized, so that there are no breaks or cracks between the segments.

[0229] The structure of the non-application portions 146a and 146b may be modified as desired to the structure of the above-described embodiment (variation) different from that shown in the drawings. In addition, there is no restriction on applying the structure of a conventional non-application portion to either one of the non-application portions 146a and 146b.

[0230] The cylindrical battery cells according to the above-described embodiments (variations) have a structure with low internal resistance, prevention of internal short circuits, and improved welding strength between the current collecting plates and the non-coated portions. Such battery cells can be used in manufacturing battery packs.

[0231] FIG. 18 is a diagram schematically illustrating the configuration of a battery pack according to an embodiment of the present invention.

[0232] A battery pack 300 according to an embodiment of the present invention includes an assembly of electrically connected cylindrical battery cells 301 and a pack housing 302 that accommodates the assembly. The cylindrical battery cells 301 may be any one of the battery cells according to the above-described embodiments (variants). For ease of illustration, components such as bus bars for electrically connecting the cylindrical battery cells 301, a cooling unit, and external terminals are omitted from the drawings.

[0233] The battery pack 300 may be mounted on a vehicle as shown in Fig. 19. Fig. 19 is a diagram schematically illustrating a vehicle including a battery pack according to an embodiment of the present invention. The vehicle may be, for example, an electric vehicle, a hybrid vehicle, or a plug-in hybrid vehicle. The vehicle may be a four-wheeled vehicle or a two-wheeled vehicle.

[0234] 19, a vehicle V according to an embodiment of the present invention includes a battery pack 300 according to an embodiment of the present invention. The vehicle V operates by receiving power from the battery pack 300 according to an embodiment of the present invention.

[0235] Although the present invention has been described above with reference to limited embodiments and drawings, it goes without saying that the present invention is not limited thereto, and various modifications and variations can be made by a person having ordinary skill in the art to which the present invention pertains within the scope of the technical concept of the present invention and the equivalent scope of the claims. [Explanation of symbols]

[0236] 41 Current collector 42 Active material layer 43, 43a, 43b, 146a, 146b Non-coated area 44 insulating coating layer 50, 60, 70 electrode plate 61, 61' segmental piece 80, 100, 110, 141 electrode assembly 102, 112 hollow 144 First current collecting plate 170, 301 cylindrical battery cells 171 Battery Can 172 Rivet terminal 173 Second gasket 174 Insulating Cap 176 Second current collecting plate 178 Sealed body 178a Cap Plate 178b First gasket 179 Vent 180 Beading section 181 Crimping section 300 battery pack 302 Pack Housing B1 Non-coated part on core side B2 Intermediate non-applied area B3 Non-coated outer periphery C Winding center V Automobile

Claims

1. The elongation ratio is 1.5 to 3.0%, and the tensile strength is 25 to 35 kgf / mm ２ a current collector for a secondary battery, an active material layer formed on the current collector, the current collector includes a non-coated portion at an end of the current collector where the active material layer is not formed, 1. An electrode plate for a secondary battery, wherein at least a portion of the non-coated portion is divided into a plurality of segmented pieces.

2. In the electrode plate, the current collector is in the form of a sheet having short sides and long sides, and the non-coated portion is provided at an end of the long side of the current collector, 2. The electrode plate for a secondary battery according to claim 1, wherein the width in a direction along the short sides of the current collector is 60 to 110 mm, the length in a direction along the long sides of the current collector is 3 to 5 m, and the length of the camber is less than 20 mm.

3. A jelly-roll type electrode assembly having a structure in which sheet-shaped first and second electrode plates and a separator interposed therebetween are wound in one direction, At least one of the first electrode plate and the second electrode plate includes a current collector and a non-coated portion on a long side end of the current collector where the active material layer is not coated, At least a portion of the non-coated portion is exposed to the outside of the separator and used as an electrode tab; The current collector has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm ２ and An electrode assembly, wherein at least a portion of the non-application portion is divided into a plurality of segmented pieces.

4. the non-coated portion includes a core-side non-coated portion adjacent to a core of the electrode assembly, an outer periphery-side non-coated portion adjacent to an outer periphery surface of the electrode assembly, and an intermediate non-coated portion interposed between the core-side non-coated portion and the outer periphery-side non-coated portion, The electrode assembly according to claim 3 , wherein the plurality of segmented pieces are formed in at least a portion of the middle non-coating portion.

5. 5. The electrode assembly according to claim 4, wherein the segment pieces have an upper width smaller than a lower width.

6. The electrode assembly according to claim 4 or 5, wherein the outer peripheral non-coated portion and the core non-coated portion do not have a segmented structure.

7. 6. The electrode assembly according to claim 4, wherein the plurality of segment pieces are folded in a radial direction of the electrode assembly and overlapped in multiple layers.

8. 6. The electrode assembly according to claim 4, wherein there are no breaks or cracks between the plurality of segments.

9. The energy density per unit area of ​​the active material layer is 1 to 6 mAh / cm ２ 6. The electrode assembly according to claim 4 or 5,

10. a jelly-roll type electrode assembly having a structure in which sheet-like first and second electrode plates and a separator interposed therebetween are wound in one direction; a battery can that houses the electrode assembly and is electrically connected to one of the first electrode plate and the second electrode plate to have a first polarity; a sealing body that seals the open end of the battery can; a terminal electrically connected to the remaining one of the first electrode plate and the second electrode plate, the terminal having a second polarity and an externally exposed surface, At least one of the first electrode plate and the second electrode plate includes a current collector and a non-coated portion at a long side end of the current collector where the active material layer is not coated, At least a portion of the non-coated portion is exposed to the outside of the separator and used as an electrode tab; The current collector has an elongation ratio of 1.5 to 3.0% and a tensile strength of 25 to 35 kgf / mm ２ and A cylindrical battery cell, wherein at least a portion of the uncoated portion is divided into a plurality of segmented pieces.

11. 11. The cylindrical battery cell according to claim 10, wherein the first electrode plate or the second electrode plate has a width of 60 to 110 mm in a direction along the short side of the current collector, a length of 3 to 5 m in a direction along the long side of the current collector, and a camber length of less than 20 mm.

12. the non-coated portion includes a core-side non-coated portion adjacent to a core of the electrode assembly, an outer periphery-side non-coated portion adjacent to an outer periphery surface of the electrode assembly, and an intermediate non-coated portion interposed between the core-side non-coated portion and the outer periphery-side non-coated portion, The cylindrical battery cell according to claim 10 or 11, wherein the plurality of segment pieces are formed in at least a portion of the middle uncoated portion.

13. The cylindrical battery cell according to claim 12 , wherein there are no breaks or cracks between the plurality of segment pieces.

14. At least a portion of the intermediate non-coated portion is bent from the outer periphery side toward the core side, The electrode assembly has a core having a cavity therein. The cylindrical battery cell according to claim 12 , wherein the cavity is not closed by a folded structure of the middle uncoated portion.

15. 12. The cylindrical battery cell according to claim 10, further comprising a current collecting plate electrically connected to the uncoated portion of the second electrode plate having the first polarity, and at least a portion of an edge of the current collecting plate being attached to a side wall of the battery can.

16. 12. The cylindrical battery cell according to claim 10, wherein the sealing body includes a non-polar cap plate and a gasket that surrounds an edge of the cap plate and is crimped to an upper end of the battery can.

17. 12. The cylindrical battery cell according to claim 10, wherein the battery can includes a rivet terminal insulatively installed in a through-hole formed in a center of a closed surface, electrically connected to the first electrode plate, and having the second polarity.

18. A battery pack comprising at least one battery cell according to claim 10 or 11.

19. 20. A motor vehicle comprising at least one battery pack according to claim 18.

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