Batteries and modules
The battery design uses a laminate sheet structure with non-contact portions and welded edges to prevent separator shrinkage, effectively suppressing short circuits and enhancing thermal stability.
Patent Information
- Authority / Receiving Office
- JP · JP
- Patent Type
- Patents
- Current Assignee / Owner
- Filing Date
- 2023-08-08
- Publication Date
- 2026-03-04
AI Technical Summary
Existing battery designs are prone to short circuits due to separator shrinkage near electrode tabs, which is not adequately addressed by existing technologies.
The battery design incorporates a laminate sheet structure with non-contact portions and welded portions to securely fix the separator edges, using a laminate sheet with a metal and resin layer to prevent shrinkage and contact between electrodes.
The design effectively suppresses short circuits by securely fixing the separator edges, enhancing thermal stability and reducing the likelihood of contact between positive and negative electrodes.
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Abstract
Description
[Technical Field]
[0001] The present disclosure relates to batteries and modules. [Background technology]
[0002] BACKGROUND ART Lithium secondary batteries (hereinafter also referred to as "batteries") using non-aqueous electrolytes are used in information and communication technology (for example, personal computers, smartphones, etc.), in-vehicle applications, power storage, and the like.
[0003] A battery has an electrode assembly in which positive and negative electrodes are alternately stacked with separators interposed therebetween. Electrode tabs are formed on the electrode assembly. The electrode tabs, through which current passes during charging and discharging of the battery, generate a large amount of heat. Separators are generally porous resin films. Therefore, the portions of the separator adjacent to the electrode tabs are prone to shrinkage. If the separator shrinks, the positive and negative electrodes may come into contact with each other, potentially causing a short circuit.
[0004] Patent Document 1 discloses a battery assembly 900 capable of suppressing shrinkage of a portion of a separator adjacent to an electrode tab. The battery assembly 900 is disposed in a battery case of a battery. As shown in FIGS. 6 and 7, the battery assembly 900 includes a plurality of electrode plates 910 (positive or negative electrodes), a separator 920, and an insulation reinforcement portion 930 for suppressing thermal shrinkage of the separator 920. The separator 920 is interposed between each of the plurality of electrode plates 910. An electrode tab 911 is formed on each of the plurality of electrode plates 910. The separator 920 has an excess outer periphery that is larger than the outer periphery of the electrode plate 910. The insulation reinforcement portion 930 is formed in a portion of the excess outer periphery of the separator 920 that is adjacent to the electrode tab 911. The insulation reinforcement portion 930 has a width W. The insulation reinforcement portion 930 connects the outer periphery of the electrode plate 910 and the excess outer periphery of the separator 920 to each other. [Prior art documents] [Patent documents]
[0005] [Patent Document 1] US Patent Application Publication No. 2018 / 0145376 Summary of the Invention [Problem to be solved by the invention]
[0006] However, Patent Document 1 does not disclose anything about the relationship between the battery assembly 900 and the battery case. If the battery assembly 900 is simply housed in a battery case, there is a risk that the edges E920 (see FIG. 6) of the separator 920 will shrink when the battery generates abnormal heat, causing a short circuit.
[0007] The present disclosure has been made in consideration of the above circumstances. An object of one embodiment of the present disclosure is to provide a battery and a module in which the occurrence of short circuits is suppressed. [Means for solving the problem]
[0008] The means for solving the above problems include the following embodiments.
[0009] <1> The battery of the first aspect of the present disclosure comprises: a flat electrode assembly formed by alternately stacking positive electrodes and negative electrodes with separators interposed therebetween; an exterior housing that houses the electrode assembly; a positive electrode tab that protrudes from the exterior body in a first direction perpendicular to the thickness direction of the electrode body and is electrically connected to the positive electrode; a negative electrode tab that protrudes from the exterior body toward the first direction or a direction opposite to the first direction and is electrically connected to the negative electrode; Equipped with The exterior body has at least one laminate sheet, the electrode body has non-contact portions at both edges in the thickness direction and a second direction perpendicular to the first direction, where the positive electrode and the negative electrode are not in contact with the separator, In the battery, the exterior body has a welded portion where the laminate sheets are welded together via at least a part of the non-contact portion.
[0010] In the present disclosure, a "laminate sheet" refers to a sheet having at least a metal layer, a first resin layer laminated on one main surface of the metal layer, and a second resin layer laminated on the other main surface of the metal layer. In this disclosure, when the exterior body has one laminate sheet, "the laminate sheets" refers to the first and second portions of the single laminate sheet. When the exterior body has multiple laminate sheets, "the laminate sheets" refers to the first and second laminate sheet portions.
[0011] In the first embodiment, the outer casing has a welded portion where the laminate sheets are welded together via at least a portion of the non-contact portion. That is, the portions of the separator corresponding to both edge portions of the electrode assembly in the second direction (hereinafter also referred to as "edge portions") are sandwiched between the laminate sheets and fixed to the welded portion. Therefore, the edge portions of the separator in the first embodiment are less likely to shrink when the battery abnormally heats up than when the edge portions of the separator are not sandwiched between the laminate sheets. As a result, the occurrence of short circuits is suppressed in the battery of the first embodiment.
[0012] <2> The battery according to the second aspect of the present disclosure comprises: the positive electrode includes a plurality of positive electrode sheets, the negative electrode includes a plurality of negative electrode sheets, the separator includes a plurality of separator sheets; the electrode body is formed by stacking the positive electrode sheets and the negative electrode sheets alternately with the separator sheets interposed therebetween along the thickness direction, the uncontacted portion extends along the first direction, <1> The battery is described in
[0013] The battery of the second embodiment is a so-called stacked-type battery.
[0014] <3> The battery of the third aspect of the present disclosure comprises: When the exterior body is viewed in the thickness direction, the ratio of the area of the uncontacted portion in the welded portion (hereinafter also referred to as "SR10A") to the area of the welded portion (hereinafter also referred to as "SR20") (hereinafter also referred to as "ratio (SR10A / SR20)") is 10% or more. <1> or <2> The battery is described in
[0015] As a result, both edge portions of the separator of the third embodiment are more strongly fixed to the welded portion than when the ratio (SR10A / SR20) is less than 10%. Therefore, both edge portions of the separator of the third embodiment are less likely to shrink when the battery abnormally heats up. As a result, the occurrence of short circuits is further suppressed in the battery of the third embodiment.
[0016] <4> The battery of the fourth aspect of the present disclosure comprises: The surface of the uncontacted portion (hereinafter also referred to as "first portion") in the welded portion of the separator is rougher than the surface of a portion (hereinafter also referred to as "second portion") of the separator that is different from the uncontacted portion in the welded portion. <1> ~ <3> 1. The battery according to claim 1, wherein the
[0017] In the present disclosure, "rough surface" means a surface having a large surface roughness value. The surface roughness can be measured by arithmetic mean roughness (Ra) according to JIS B 0601:2013.
[0018] As a result, the contact area of the first portion with the welded portion in the fourth embodiment is larger than when the surface of the first portion is not rougher than the surface of the second portion. As a result, both edge portions of the separator in the fourth embodiment are more strongly fixed to the welded portion. As a result, the occurrence of short circuits is further suppressed in the battery of the fourth embodiment.
[0019] <5> The battery of the fifth aspect of the present disclosure comprises: the thickness of the uncontacted portion in the welded portion of the separator is thinner than the thickness of a portion of the separator that is different from the uncontacted portion in the welded portion; <1> ~ <4> 1. The battery according to claim 1, wherein the
[0020] As a result, the contact area of the first portion with the welded portion in the fifth embodiment is larger than when the thickness of the first portion is not greater than the thickness of the second portion. As a result, both edge portions of the separator in the fifth embodiment are more strongly fixed to the welded portion. As a result, the occurrence of short circuits is further suppressed in the battery of the fifth embodiment.
[0021] <6> The module of the sixth aspect of the present disclosure comprises: The aforementioned <1> ~ <5> a plurality of batteries according to any one of the preceding claims; a case housing the plurality of batteries; The module comprises:
[0022] As a result, the occurrence of short circuits is suppressed in the module of the sixth aspect. [Effects of the Invention]
[0023] According to the present disclosure, a battery and a module are provided in which the occurrence of short circuits is suppressed. [Brief explanation of the drawings]
[0024] [Figure 1] FIG. 1 is a front view of a battery according to an embodiment of the present disclosure. [Figure 2] FIG. 2 is a cross-sectional view of the battery of FIG. 1 taken along line II-II. [Figure 3] FIG. 3 is a perspective view of a module according to an embodiment of the present disclosure. [Figure 4] FIG. 4 is a top view of a module according to an embodiment of the present disclosure with the case lid removed. [Figure 5] FIG. 5 is a schematic diagram of a vehicle equipped with a module according to an embodiment of the present disclosure. [Figure 6] FIG. 6 is a front view of a battery assembly disposed in a battery case of a conventional battery. [Figure 7] FIG. 7 is a side view of a battery assembly disposed within a battery case of a conventional battery. DETAILED DESCRIPTION OF THE INVENTION
[0025]
[0023] The following describes embodiments of the present disclosure. These descriptions and examples are intended to illustrate the embodiments and are not intended to limit the scope of the embodiments. In the present disclosure, a combination of two or more preferred embodiments is a more preferred embodiment. In the present disclosure, a numerical range expressed using "to" means a range that includes the numerical values before and after "to" as the lower and upper limits. In the numerical ranges described in stages in this disclosure, the upper or lower limit value described in one numerical range may be replaced with the upper or lower limit value of another numerical range described in stages. In the numerical ranges described in this disclosure, the upper or lower limit value of that numerical range may be replaced with the value shown in the examples.
[0026] Hereinafter, embodiments of the battery and module of the present disclosure will be described with reference to the drawings. In the drawings, the same or corresponding parts are designated by the same reference numerals, and description thereof will not be repeated.
[0027] (1)Battery 1, a battery 1 according to an embodiment of the present disclosure includes a flat electrode assembly 10, an outer casing 20, a positive electrode tab 30, a negative electrode tab 40, and a non-aqueous electrolyte (not shown). The battery 1 is a rectangular parallelepiped.
[0028] In this embodiment, one side of the short-side direction of the main surface of the battery 1 is defined as the X-axis positive direction, and the opposite side is defined as the X-axis negative direction. The positive electrode tab 30 side of the long-side direction of the main surface of the battery 1 is defined as the Y-axis positive direction, and the opposite side is defined as the Y-axis negative direction. One side of the thickness direction of the battery 1 is defined as the Z-axis positive direction, and the opposite side is defined as the Z-axis negative direction. The X-axis, Y-axis, and Z-axis are each perpendicular to one another. The Y-axis is an example of a first direction. The X-axis is an example of a second direction. The Z-axis is an example of the thickness direction of the electrode body. Note that these directions do not limit the orientation of the battery of the present disclosure during use.
[0029] The exterior body 20 accommodates the electrode assembly 10 and a nonaqueous electrolyte. The exterior body 20 has two welded portions R20. The positive electrode tab 30 protrudes from the exterior body 20 in the positive direction of the Y axis. The negative electrode tab 40 protrudes from the exterior body 20 in the negative direction of the Y axis.
[0030] The length L1 of the battery 1 in the X-axis direction (see FIG. 1) is, for example, 80 mm to 110 mm. The length L2 of the battery 1 in the Y-axis direction (see FIG. 1) is, for example, 530 mm to 600 mm. The length L3 of the battery 1 in the Z-axis direction (see FIG. 2) is, for example, 7.0 mm to 9.0 mm.
[0031] (1.1) Electrode body The electrode assembly 10 has a laminated structure. As shown in FIG. 2, the electrode assembly 10 includes a plurality of positive electrode sheets 11, a plurality of negative electrode sheets 12, and a plurality of separator sheets 13. The electrode assembly 10 is formed by alternately stacking the positive electrode sheets 11 and the negative electrode sheets 12 with the separator sheets 13 interposed therebetween. The positive electrode sheets 11 are an example of a positive electrode. The negative electrode sheets 12 are an example of a negative electrode. The separator sheets 13 are an example of a separator.
[0032] The number of each of the positive electrode sheets 11, negative electrode sheets 12, and separator sheets 13 is not particularly limited and is selected appropriately depending on the application of the battery 1, etc.
[0033] 1, the electrode body 10 has a pair of uncontacted portions R10A and an electrode portion R10B. The pair of uncontacted portions R10A are located at both ends in the X-axis direction of the electrode body 10. The electrode portion R10B is located between the pair of uncontacted portions R10A in the X-axis direction.
[0034] The electrode portion R10B is a portion that generates electricity. In the electrode portion R10B, positive electrode sheets 11 and negative electrode sheets 12 are alternately laminated with separator sheets 13 interposed therebetween. In this embodiment, the outermost layer of the electrode portion R10B is formed by the separator sheet 13. The length L4 (see FIG. 1) of the electrode portion R10B in the X-axis direction is, for example, 60 mm to 105 mm. The length L5 (see FIG. 1) of the electrode portion R10B in the Y-axis direction is, for example, 500 mm to 520 mm.
[0035] The uncontacted portion R10A is a portion that does not generate electricity. The uncontacted portion R10A is a portion of the electrode assembly 10 where the positive electrode sheet 11 and the negative electrode sheet 12 are not in contact with the separator sheet 13. In other words, the uncontacted portion R10A is made up of only a plurality of separator sheets 13. The uncontacted portion R10A extends along the Y-axis direction. The length L6 of the uncontacted portion R10A in the X-axis direction (see FIG. 1) is, for example, 1 mm to 20 mm. The length of the uncontacted portion R10A in the Y-axis direction is the same as the length L5 of the electrode portion R10B in the Y-axis direction (see FIG. 1).
[0036] (1.1.1) Positive electrode sheet The positive electrode sheet 11 has a positive electrode current collector (for example, aluminum foil, etc.) and a positive electrode active material layer supported on the positive electrode current collector. The positive electrode active material layer contains a positive electrode active material. The positive electrode active material releases lithium ions into the non-aqueous electrolyte or absorbs lithium ions from the non-aqueous electrolyte. The positive electrode active material may be a known positive electrode active material (for example, LiNiO2, LiNi 1 / 3 Co 1 / 3 Mn 1 / 3 The positive electrode active material layer may further contain a known conductive material (for example, carbon black, etc.), trilithium phosphate, and a known binder (for example, polyvinylidene fluoride, etc.).
[0037] (1.1.2) Negative electrode sheet The negative electrode sheet 12 has a negative electrode current collector (e.g., copper foil) and a negative electrode active material layer supported on the negative electrode current collector. The negative electrode active material layer contains a negative electrode active material. The negative electrode active material absorbs and releases lithium ions, which are charge carriers, from a non-aqueous electrolyte solution during charging and discharging. The negative electrode active material may be a known negative electrode active material (e.g., artificial graphite, a lithium alloy (e.g., LiXM, where M is C, Si, Sn, Sb, Al, Mg, Ti, Bi, Ge, Pb, P, or the like, and X is a natural number), etc.). The negative electrode active material layer may further contain a known binder (e.g., styrene-butadiene copolymer, etc.).
[0038] (1.1.3) Separator sheet The separator sheet 13 electrically insulates the positive electrode from the negative electrode and provides a path for lithium ions to move between the positive electrode active material layer and the negative electrode active material layer. The separator sheet 13 may be a porous membrane or the like. Examples of materials for the porous membrane include polyethylene and polypropylene. The separator sheet 13 may have a single-layer structure or a multi-layer structure.
[0039] The surface of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is rougher than the surface of a portion of the separator sheet 13 other than the uncontacted portion R10A in the welded portion R20 (i.e., the electrode portion R10B). The welded portion R20 is usually formed by heat pressing. During heat pressing, creep occurs in the uncontacted portion R10A of the separator sheet 13. "Creep" refers to a phenomenon in which strain increases over time for a constant stress when an external force is applied to an object. In other words, the surface of the uncontacted portion R10A of the separator sheet 13 is more stretched than the surface before heat pressing (i.e., a surface equivalent to the surface of the electrode portion R10B). Therefore, the surface of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is rougher than the surface of the electrode portion R10B.
[0040] The thickness of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is thinner than the thickness of a portion of the separator sheet 13 other than the uncontacted portion R10A in the welded portion R20 (i.e., the electrode portion R10B). The welded portion R20 is usually formed by heat pressing. Therefore, the thickness of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is thinner than the thickness of the electrode portion R10B.
[0041] (1.2) Exterior body The exterior body 20 covers the electrode body 10 and seals the electrode body 10 and the non-aqueous electrolyte together with the positive electrode tab 30 and the negative electrode tab 40.
[0042] In this embodiment, the exterior body 20 has one laminate sheet 200. One laminate sheet 200 has two embossed sections 210 (see FIG. 2) for accommodating the electrode assembly 10. The exterior body 20 is obtained by folding one laminate sheet 200 and sandwiching and sealing the electrode assembly 10 between the two embossed sections 210.
[0043] The exterior body 20 has two welded portions R20. In this embodiment, in the welded portion R20, the laminate sheets 200 are welded to each other via the entire non-contact portion R10A.
[0044] In this embodiment, when the outer casing 20 is viewed from the Z-axis direction, the ratio (hereinafter also referred to as "ratio (SR10A / SR20)") of the area SR10A (see Figure 1) of the uncontacted portion R10A in the welded portion R20 to the area SR20 (see Figure 1) of the welded portion R20 is 10% or more.
[0045] (1.2.1) Laminated sheet 2, the laminate sheet 200 has a metal layer 201, an inner resin layer 202, and an outer resin layer 203. The inner resin layer 202 is laminated on a surface S201A of the metal layer 201 facing the electrode body 10. The outer resin layer 203 is laminated on a surface S201B of the metal layer 201 opposite the electrode body 10 side.
[0046] The metal layer 201 blocks the passage of gas (for example, moisture, air, etc.) between the outside and the inside of the battery 1. The material of the metal layer 201 is a metal (for example, aluminum, etc.).
[0047] The inner resin layer 202 constitutes the welded portion R20. In addition, the inner resin layer 202 electrically insulates the electrode body 10, the positive electrode tab 30, and the negative electrode tab 40 from the metal layer 201. The inner resin layer 202 may contain a thermoplastic resin. Examples of the thermoplastic resin include olefin-based resins (e.g., polypropylene, polyethylene, etc.), polyvinyl chloride, polyvinylidene chloride, polystyrene-based resins, acrylonitrile-styrene copolymer (AS) resins, acrylonitrile-butadiene-styrene copolymer (ABS) resins, polyester-based resins, poly(meth)acrylic-based resins, polyvinyl alcohol, polycarbonate-based resins, polyamide-based resins, polyimide-based resins, polyether-based resins, polyacetal-based resins, fluorine-based resins, polysulfone-based resins, polyphenylene sulfide resins, and polyketone-based resins.
[0048] In particular, the thermoplastic resin preferably contains a resin that is compatible with the separator sheet 13. This improves the adhesion between the welded portion R20 and the separator sheet 13. "Compatible" means that the first resin and the second resin mix without separating in an atmosphere in which they melt. The resin that is compatible with the separator sheet 13 is selected appropriately depending on the material of the separator sheet 13. When the separator sheet 13 contains polyethylene, the inner resin layer 202 preferably contains polyethylene. When the separator sheet 13 contains polypropylene, the inner resin layer 202 preferably contains polypropylene.
[0049] The inner resin layer 202 may contain compounding agents as needed, such as heat stabilizers, antioxidants, pigments, weathering agents, flame retardants, plasticizers, dispersants, lubricants, release agents, and antistatic agents.
[0050] The outer resin layer 203 improves the durability of the laminate sheet 200. The outer resin layer 203 may contain a thermoplastic resin. The thermoplastic resin of the outer resin layer 203 is not particularly limited, and examples thereof include the same thermoplastic resins as those exemplified as the thermoplastic resin of the inner resin layer 202. The thermoplastic resin of the outer resin layer 203 may be the same as or different from the thermoplastic resin of the inner resin layer 202. The outer resin layer 203 may contain compounding agents as necessary. Examples of compounding agents include heat stabilizers, antioxidants, pigments, weathering agents, flame retardants, plasticizers, dispersants, lubricants, release agents, and antistatic agents.
[0051] (1.3) Positive electrode tab The positive electrode tab 30 is electrically connected to a plurality of positive electrode sheets 11 .
[0052] The positive electrode current collector has a positive electrode lead portion extending in the positive direction of the Y axis. A positive electrode active material layer is not formed on the positive electrode lead portion. The positive electrode tab 30 may consist of only a plurality of positive electrode lead portions. The positive electrode tab 30 may include a plurality of positive electrode lead portions and positive electrode leads connected to the plurality of positive electrode lead portions. The length L7 of the positive electrode tab 30 in the X axis direction (see FIG. 1) is, for example, 40 mm to 50 mm.
[0053] (1.4) Negative electrode tab The negative electrode tab 40 is electrically connected to a plurality of negative electrode sheets 12 .
[0054] The negative electrode current collector has a negative electrode lead portion extending in the negative direction of the Y axis. No negative electrode active material layer is formed on the negative electrode lead portion. The negative electrode tab 40 may consist of only a plurality of negative electrode lead portions. The negative electrode tab 40 may include a plurality of negative electrode lead portions and a negative electrode lead connected to the plurality of negative electrode lead portions. The length L7 (see FIG. 1) of the negative electrode tab 40 in the X axis direction is, for example, 40 mm to 50 mm.
[0055] (1.5) Non-aqueous electrolyte The battery 1 includes a non-aqueous electrolyte solution. The non-aqueous electrolyte solution is housed in an exterior body 20 together with the electrode assembly 10. The non-aqueous electrolyte solution may be a non-aqueous solvent (e.g., ethyl carbonate) in which a supporting salt (e.g., LiPF6) serving as an electrolyte is dissolved or dispersed. The non-aqueous electrolyte may contain various additives (e.g., lithium bis(oxalato)borate).
[0056] (1.6)Applications The use of the battery 1 is not particularly limited, and examples thereof include a power source for a vehicle, a power source for an information processing device (for example, a personal computer, a smartphone, etc.), a power source for storing electricity, and the like.
[0057] (1.7) Action and effect As described with reference to Figures 1 and 2, the battery 1 includes an electrode assembly 10, an exterior housing 20, a positive electrode tab 30, and a negative electrode tab 40. The exterior housing 20 includes one laminate sheet 200. The electrode assembly 10 has uncontacted portions R10A at both edges in the X-axis direction. The exterior housing 20 has a welded portion R20 via the uncontacted portions R10A. That is, the portions of the separator sheet 13 corresponding to both edge portions in the X-axis direction of the electrode body 10 (hereinafter also referred to as "edge portions") are sandwiched between the laminate sheets 200 and fixed to the welded portion R20. Therefore, when the battery 1 abnormally heats up, the edge portions of the separator sheet 13 are less likely to shrink than when the edge portions of the separator sheet 13 are not sandwiched between the laminate sheets 200. As a result, the occurrence of short circuits in the battery 1 is suppressed.
[0058] 1 and 2, in the battery 1, the electrode assembly 10 includes a plurality of positive electrode sheets 11, a plurality of negative electrode sheets 12, and a plurality of separator sheets 13. The electrode assembly 10 is formed by stacking the positive electrode sheets 11 and the negative electrode sheets 12 alternately along the Z-axis direction with the separator sheets 13 interposed therebetween. The uncontacted portion R10A extends along the Y-axis direction. In other words, the battery 1 is a so-called stacked battery.
[0059] As described with reference to FIGS. 1 and 2, in the battery 1, when the exterior body 20 is viewed from the Z-axis direction, the ratio (SR10A / SR20) is 10% or more. As a result, both edge portions of the separator sheet 13 in the X-axis direction are more strongly fixed to the welded portion R20 than when the ratio (SR10A / SR20) is less than 10%. Therefore, both edge portions of the separator sheet 13 in the X direction are less likely to shrink when the battery 1 abnormally heats up. As a result, the occurrence of short circuits in the battery 1 is further suppressed.
[0060] As explained with reference to Figures 1 and 2, in battery 1, the surface of uncontacted portion R10A in welded portion R20 of separator sheet 13 is rougher than the surface of a portion of separator sheet 13 other than uncontacted portion R10A in welded portion R20 (i.e., electrode portion R10B). As a result, the contact area between the uncontacted portion R10A of the separator sheet 13 and the welded portion R20 is larger than when the surface of the uncontacted portion R10A is not rougher than the surface of the electrode portion R10B. As a result, both edge portions of the separator sheet 13 are more strongly fixed to the welded portion R20. As a result, the occurrence of short circuits in the battery 1 is further suppressed.
[0061] As explained with reference to Figures 1 and 2, in battery 1, the thickness of the uncontacted portion R10A in the welded portion R20 of separator sheet 13 is thinner than the thickness of the portion of separator sheet 13 other than the uncontacted portion R10A in the welded portion R20 (i.e., the electrode portion R10B). As a result, the contact area between the uncontacted portion R10A of the separator sheet 13 and the welded portion R20 is larger than when the thickness of the uncontacted portion R10A is not thinner than the thickness of the electrode portion R10B. As a result, both edge portions of the separator sheet 13 are more strongly fixed to the welded portion R20. As a result, the occurrence of short circuits in the battery 1 is further suppressed.
[0062] (2) Module 3 and 4, a module 2 according to an embodiment of the present disclosure includes a plurality of batteries 1 and a case 50. The case 50 houses the plurality of batteries 1.
[0063] 2, the module 2 is a rectangular parallelepiped object. The length L10 of the module 2 in the Y-axis direction is, for example, 350 mm to 600 mm. The length L11 of the module 2 in the Z-axis direction is, for example, 150 mm to 250 mm. The length L12 of the module 2 in the X-axis direction is, for example, 80 mm to 110 mm.
[0064] A pair of voltage terminals 61 and a connector 62 are provided at each end of the module 2 in the Y-axis direction. A flexible printed circuit board 63, which will be described later, is connected to the connector 62. Bus bars (not shown) are welded to each end of the module 2 in the Y-axis direction.
[0065] The case 50 has a case body 51 and a case lid 52. The case 50 is made of an aluminum alloy. For example, the case 50 is formed by joining aluminum die-casting to both ends of an extruded aluminum alloy material by laser welding or the like.
[0066] As shown in Figure 3, a plurality of batteries 1 are housed in an array inside the module 2. In this embodiment, 24 batteries 1 are arranged along the Z-axis direction. Adjacent batteries 1 are adhered to each other.
[0067] A flexible printed circuit (FPC) 63 is placed on the battery 1. The flexible printed circuit 63 is formed in a strip shape with the X-axis direction as the longitudinal direction, and a thermistor 64 is provided at each end of the flexible printed circuit 63. In the module 2, the thermistor 64 is not adhered to the battery 1, but is pressed toward the battery 1 by the case lid 52.
[0068] One or more cushioning materials (not shown) are housed inside the module 2. For example, the cushioning materials are elastically deformable thin plate-like members that are arranged between adjacent batteries 1 with the arrangement direction of the batteries 1 as the thickness direction. In this embodiment, as an example, cushioning materials are arranged at both longitudinal ends of the module 2 and in the longitudinal center.
[0069] (2.2) Usage example The module 2 is suitable for use as a battery pack 310 that is a power source for a vehicle 300. As shown in Fig. 5, the vehicle 300 is a battery electric vehicle (BEV) that has a battery pack 310 mounted under the floor.
[0070] In this embodiment, the positive X-axis direction, the positive Z-axis direction, and the positive Y-axis direction indicate the upper side in the vehicle vertical direction, the front side in the vehicle longitudinal direction, and the left side in the vehicle width direction, respectively.
[0071] In the vehicle 300 of this embodiment, for example, a DC / DC converter 301, an electric compressor 302, and a PTC (Positive Temperature Coefficient) heater 303 are arranged on the vehicle front side of a battery pack 310. In addition, a motor 304, a gearbox 305, an inverter 306, and a charger 307 are arranged on the vehicle rear side of the battery pack 310.
[0072] The direct current output from the battery pack 310 has its voltage adjusted by a DC / DC converter 301, and is then supplied to an electric compressor 302, a PTC heater 303, an inverter 306, etc. Furthermore, power is supplied to a motor 304 via the inverter 306, causing the rear wheels to rotate and causing the vehicle 300 to travel.
[0073] A charging port 308 is provided on the right side at the rear of the vehicle 300, and by connecting a charging plug of an external charging facility (not shown) to the charging port 308, power can be stored in the battery pack 310 via the charger 307.
[0074] The arrangement and structure of each component constituting vehicle 300 are not limited to the above-described configuration. For example, the present invention may be applied to a hybrid vehicle (HV) or a plug-in hybrid electric vehicle (PHEV) equipped with an engine. In this embodiment, the vehicle is a rear-wheel drive vehicle in which motor 304 is mounted at the rear of the vehicle, but the present invention is not limited to this. The vehicle may be a front-wheel drive vehicle in which motor 304 is mounted at the front of the vehicle, or a pair of motors 304 may be mounted at the front and rear of the vehicle. Furthermore, the vehicle may be equipped with an in-wheel motor on each wheel.
[0075] The battery pack 310 includes a plurality of modules 2. In this embodiment, ten modules 2 are provided. Specifically, five modules 2 are arranged in the longitudinal direction of the vehicle on the right side of the vehicle 300, and five modules 2 are arranged in the longitudinal direction of the vehicle on the left side of the vehicle 300. Each of the plurality of modules 2 is electrically connected.
[0076] (2.3) Action and Effects As described with reference to FIGS. 1 to 4, the module 2 includes a plurality of batteries 1 and a case 50. As a result, the occurrence of short circuits in module 2 is suppressed.
[0077] (3) Variations In this embodiment, the structure of the electrode assembly 10 is a laminated type, but the present disclosure is not limited to this. The electrode assembly of the present disclosure may have a wound type structure.
[0078] In this embodiment, the ratio (SR10A / SR20) is 10% or more, but the present disclosure is not limited thereto. The ratio (SR10A / SR20) in the present disclosure may be less than 10%.
[0079] In this embodiment, the surface of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is rougher than the surface of the electrode portion R10B, but the present disclosure is not limited to this. In the present disclosure, the surface of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 does not have to be rougher than the surface of the electrode portion R10B.
[0080] In this embodiment, the thickness of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 is thinner than the thickness of the electrode portion R10B, but the present disclosure is not limited to this. In the present disclosure, the thickness of the uncontacted portion R10A in the welded portion R20 of the separator sheet 13 does not have to be thinner than the thickness of the electrode portion R10B.
[0081] In this embodiment, the exterior body 20 is made up of one laminate sheet 200, but the present disclosure is not limited to this. The exterior body 20 may be made up of multiple laminate sheets 200.
[0082] In this embodiment, the laminate sheets 200 are welded to each other at the welded portion R20 via the entire non-contact portion R10A, but the present disclosure is not limited to this. The laminate sheets 200 may be welded to each other at the welded portion R20 via a part of the non-contact portion R10A.
[0083] In this embodiment, the exterior body 20 has a double-cup embossed structure, but the present disclosure is not limited thereto. The exterior body 20 may also have a single-cup embossed structure. [Explanation of symbols]
[0084] 1 battery, 2 module, 10 electrode body, 11 positive electrode sheet, 12 negative electrode sheet, 13 separator sheet, 20 exterior body, 30 positive electrode tab, 40 negative electrode tab, 50 case, 51 case body, 52 case lid, 61 voltage terminal, 62 connector, 63 flexible printed circuit board, 64 thermistor, 200 laminate sheet, 201 metal layer, 202 inner resin layer, 203 outer resin layer, 210 embossed portion, 300 vehicle, 301 converter, 302 electric compressor, 303 heater, 304 motor, 305 gearbox, 306 inverter, 307 charger, 308 charging port, 310 battery pack, R10A uncontacted portion, R10B electrode portion, R20 welded portion
Claims
1. An electrode body having a plurality of positive electrode sheets, a plurality of negative electrode sheets, and a plurality of separator sheets, wherein the positive electrode sheets and the negative electrode sheets are alternately stacked along the thickness direction of the electrode body with the separator sheets interposed therebetween, forming a flat electrode body; an exterior housing that houses the electrode assembly; a positive electrode tab that protrudes from the exterior body in a first direction perpendicular to the thickness direction of the electrode body and is electrically connected to the positive electrode sheet; a negative electrode tab that protrudes from the exterior body toward the first direction or a direction opposite to the first direction and is electrically connected to the negative electrode sheet; Equipped with The exterior body has at least one laminate sheet, the electrode body has uncontacted portions at both edge portions in a second direction perpendicular to the thickness direction and the first direction, where the positive electrode sheet and the negative electrode sheet are not in contact with the separator sheet, the uncontacted portion extends along the first direction, the exterior body has a welded portion where the laminate sheets are welded to each other via at least a part of the non-contact portion, the laminate sheet has a metal layer and an inner resin layer laminated on the surface of the laminate sheet facing the electrode body, the inner resin layer contains a thermoplastic resin that is compatible with the separator sheet, A battery, wherein the plurality of uncontacted portions at both edge portions are independently welded to the welded portion.
2. The battery according to claim 1 , wherein when the exterior body is viewed in the thickness direction, a ratio of an area of the uncontacted portion in the welded portion to an area of the welded portion is 10% or more.
3. 2. The battery of claim 1, wherein the surface of the uncontacted portion in the welded portion of the separator sheet is rougher than the surface of a portion of the separator sheet other than the uncontacted portion in the welded portion.
4. The battery according to claim 1 , wherein the thickness of the uncontacted portion in the welded portion of the separator sheet is thinner than the thickness of a portion of the separator sheet that is different from the uncontacted portion in the welded portion.
5. A battery as described in claim 1, wherein both outermost layers of the electrode body are composed of the separator sheet.
6. A plurality of batteries according to any one of claims 1 to 5; a case housing the plurality of batteries; A module comprising:
Citation Information
Patent Citations
Nonaqueous electrolyte battery
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Secondary battery
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Electrode assembly comprising separator having insulation-enhancing part formed on edge portion of electrode
US20180145376A1