Cosmetic containing polyorganosiloxane having block structure

Abstract

The present invention addresses the problem of providing a cosmetic that has high coating film uniformity and a high secondary adhesion-less effect, and that is excellent in makeup durability.　A cosmetic that solves the problem to be addressed by the present invention is characterized by containing a polyorganosiloxane having a block structure. The polyorganosiloxane is characterized by: being represented by general formula (1); having a weight average molecular weight of 500,000 or greater; and, when at room temperature and containing no solvent, constituting a solid that has a softening point of 50°C or higher. (In the formula: R1, R2, R3, R4, and R5 are C1-20 saturated or unsaturated hydrocarbon groups that may have a hydrogen atom or a substituent; m indicates the number of repetitions of diorganosiloxy units, where 50≥m≥0 is satisfied; a, b, c, d, and e indicate the abundance mole fractions of the respective diorganosiloxy units, where 0.3≥a≥0, 0.3≥b>0, 0.5≥c≥0, 0.95≥d>0.5, 0.3≥e≥0, and a+b×(2+m)+c+d+e=1 are satisfied; and x and y are the numbers of hydroxy groups or alkoxy groups bound to the diorganosiloxy units a-e per mol of Si atoms, where 0.1 ≥ x > 0 and 0.1 ≥ y > 0 are satisfied.)

Description

Cosmetics containing polyorganosiloxanes having a block structure

[0001] The present invention relates to a cosmetic composition containing a polyorganosiloxane having a block structure.

[0002] In the cosmetics industry, improving the longevity of makeup is crucial, and various technologies are being developed to enhance user satisfaction. One such technology involves the use of film-forming agents, including silicone resins.

[0003] Silicone resin is measured in units of M (R3SiO １／２ ), D unit (R2SiO ２／２ ), T units (RSi0 ３／２ ), Q unit (Si0 ４／２ (R represents an organic group such as an alkyl group or a phenyl group) and various silicone resins with different properties can be obtained by combining these constituent units and organic groups.

[0004] For example, Patent Document 1 discloses a skin cosmetic containing an organic silicone resin composed of M units and Q units, which is described as having excellent water resistance and transfer resistance. Patent Document 2 discloses a cosmetic composition containing a copolymer having a resin structure mainly composed of M units and Q units and a linear structure composed of D units, which is described as having excellent film conformability and flexibility. Patent Document 3 discloses a cosmetic containing a silicone resin composed of M units and T units, which is described as having excellent water repellency and makeup longevity.

[0005] However, with conventional silicone resin compositions, attempts to further improve the durability of cosmetics by increasing the polymer content to enhance film continuity and uniformity tend to result in a high crosslinking density and gelation, which is difficult to control.

[0006] Japanese Patent Publication No. 06-15448 WO2018 / 0066572 Japanese Patent Publication No. 4-312511

[0007] The present invention aims to provide a cosmetic product that exhibits high coating film uniformity and secondary adhesion-free effect, and has excellent makeup retention.

[0008] As a result of intensive studies to solve the above problems, the present inventors have found that a cosmetic containing a polyorganosiloxane having a block structure into which a predetermined polydiorganosiloxane structure is introduced and having a high molecular weight has high coating film uniformity and secondary adhesion resistance effect, and excellent makeup retention, and thus have completed the present invention.

[0009] Means for solving the above problems include the following aspects. [1] A cosmetic containing a polyorganosiloxane having a block structure, which is represented by the following general formula (1), has a weight average molecular weight of 500,000 or more, and is a solid having a softening point of 50°C or more at room temperature in a solvent-free state. (In the formula, R １ , R ２ , R ３ , R ４ , R ５ is a hydrogen atom or a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms which may have a substituent, m represents the repeating number of diorganosiloxy units, 50 ≥ m ≥ 0, a, b, c, d, e represent the existing molar ratios of the respective siloxane units, 0.3 ≥ a ≥ 0, 0.2 ≥ b > 0, 0.5 ≥ c ≥ 0, 0.95 ≥ d > 0.5, 0.3 ≥ e ≥ 0, a + b×(2 + m) + c + d + e = 1, x, y are the numbers of hydroxy groups or alkoxy groups bonded to 1 mole of Si atoms of the siloxane units of a to e, and represent 0.1 ≥ x > 0, 0.1 ≥ y > 0.) [2] The cosmetic according to [1], wherein 0.05 ≥ x > 0 for x and 0.05 ≥ y > 0 for y. [3] The cosmetic according to [1] or [2], wherein m > 10, 0.1 ≥ a > 0 for a, 0.3 ≥ b > 0 for b, 0.3 ≥ c > 0 for c, and e = 0 for e. [4] The cosmetic according to any one of [1] to [3], wherein R １ , R ２ , R ３ , R ４ is any monovalent hydrocarbon group of a hydrogen atom, a methyl group, an ethyl group, or a vinyl group, and R ５ is a saturated hydrocarbon group having 1 to 4 carbon atoms. [5] ２９A cosmetic composition according to any one of [1] to [4], characterized in that the chemical shift of the signal attributed to the diorganosiloxane unit is detected in the range of -15 to -25 ppm in Si-NMR, and the detection width of the signal peak (the difference between the chemical shift at the detection start point and the chemical shift at the detection end point) is 3 to 7 ppm. [6] A cosmetic composition according to any one of [1] to [5], wherein the content of the polyorganosiloxane having the block structure is 0.1 to 40% by mass. [7] A cosmetic composition according to any one of [1] to [6], further containing a volatile oil agent.

[0010] The cosmetic composition of the present invention contains a polyorganosiloxane that maintains a linear structure while having a high ratio of T units that form a three-dimensional crosslinked structure, thus possessing film flexibility and excellent secondary adhesion-free effect. Furthermore, the cosmetic composition of the present invention contains a polyorganosiloxane with a significantly larger molecular weight compared to conventional polyorganosiloxanes, thus possessing film continuity and excellent coating film uniformity.

[0011] The polyorganosiloxane having a block structure obtained in Manufacturing Example 1 ２９ The Si-NMR spectrum chart is shown.

[0012] The present invention will be described in detail below. The description of the present invention below may be based on preferred embodiments of the present invention, but the present invention is not limited to such embodiments. In this specification, the "~" indicating a numerical range is used to mean that the numbers before and after it are included as the lower limit and upper limit.

[0013] The cosmetic composition of the present invention contains a polyorganosiloxane having a block structure, represented by the following formula (1), having a weight-average molecular weight of 500,000 or more, and being a solid with a softening point of 50°C or higher at room temperature in the absence of a solvent (hereinafter also referred to as "polyorganosiloxane having a block structure").

[0014]

[0015] In the formula, R １ , R ２ , R ３ , R ４ , R５ is a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, which may have hydrogen atoms or substituents; m represents the number of repeating diorganosiloxy units, where 50 ≥ m ≥ 0; a, b, c, d, and e represent the molar ratios of their respective siloxane units, where 0.3 ≥ a ≥ 0, 0.3 ≥ b > 0, 0.5 ≥ c ≥ 0, 0.95 ≥ d > 0.5, 0.3 ≥ e ≥ 0, and a + b × (2 + m) + c + d + e = 1; and x and y represent the number of hydroxyl or alkoxy groups bonded to 1 mole of Si atoms in the siloxane units a to e, where 0.1 ≥ x > 0 and 0.1 ≥ y > 0.

[0016] R １ , R ２ , R ３ , R ４ , R ５ Each of these is a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, which may each independently have a hydrogen atom or a substituent, and preferably a saturated or unsaturated hydrocarbon group having 1 to 10 carbon atoms. Specific examples include methyl group, chloromethyl group, methoxymethyl group, ethyl group, ethoxyethyl group, vinyl group, propyl group, (meth)acryloxypropyl group, mercaptopropyl group, chloropropyl group, glycidyloxypropyl group, epoxycyclohexylethyl group, allyl group, butyl group, pentyl group, cyclopentyl group, hexyl group, hexenyl group, cyclohexyl group, phenyl group, heptyl group, octyl group, octylenyl group, (meth)acryloxyoctyl group, mercaptooctyl group, chloroctyl group, glycidyloxyoctyl group, decyl group, etc., but among these, R １ , R ２ , R ３ , R ４ For this group, methyl, ethyl, propyl, and phenyl groups are preferred, methyl and ethyl groups are more preferred, and methyl groups are even more preferred. ５ For this, saturated hydrocarbon groups having 1 to 4 carbon atoms are preferred, with examples including methyl, ethyl, n-propyl, i-propyl, n-butyl, s-butyl, i-butyl, and t-butyl groups, and more preferably n-butyl, s-butyl, and i-butyl groups.

[0017] a, b, c, d, and e represent the molar ratios of each siloxane unit, with 0.3≧a≧0, 0.3≧b>0, 0.5≧c≧0, 0.95≧d>0.5, 0.3≧e≧0, and a+b×(2+m)+c+d+e=1. x and y represent the number of hydroxyl groups or alkoxy groups bonded to 1 mole of Si atoms in the siloxane units a to e, with 0.1≧x>0 and 0.1≧y>0.

[0018] With respect to the hydroxyl or alkoxy groups bonded to the Si atoms of a polydiorganosiloxane having a block structure, it is preferable that x and y are 0.05 ≥ x > 0 and 0.05 ≥ y > 0, respectively, from the viewpoint of polymer stability. When x = y = 0, it means that there are no structural groups that undergo dehydration, dealcoholization, condensation, and crosslinking. Although the polymer stability is excellent, it becomes a component that does not cure, which is undesirable as it reduces the durability of the coating film. On the other hand, when x or y is greater than 0.1, the aforementioned curability is excellent, but the polymer stability is likely to decrease, and in particular, when x > 0.1, the stability is low, which is undesirable.

[0019] Regarding the ratio of siloxane units in the polydiorganosiloxane having the block structure of the present invention, from the viewpoint of polymer stability, high degree of polymerization, and film flexibility, it is preferable that 40 > m > 10, 0.1 ≥ a > 0, 0.3 ≥ b > 0, 0.3 ≥ c > 0, and 0.05 ≥ e ≥ 0. Furthermore, in addition to the above, it is even more preferable that 0.9 ≥ d > 0.7.

[0020] The polydiorganosiloxane having a block structure has a weight-average molecular weight of 500,000 or more, preferably 1,000,000 or more, and more preferably 2,000,000 or more, from the viewpoint of film-forming ability, film continuity, and lack of stickiness of the coating film. There is no particular upper limit to the weight-average molecular weight, but from the viewpoint of suppressing gelation, for example, a weight-average molecular weight of 16,000,000 or less is preferred, more preferably 10,000,000 or less, and even more preferably 8,000,000 or less. As a range that balances the performance of the coating film and the stability of the siloxane polymer, 500,000 to 16,000,000 is preferred, 1,000,000 to 10,000,000 is more preferred, and even more preferably 2,000,000 to 8,000,000 is preferred.

[0021] The weight-average molecular weight in the present invention is a value obtained by converting polystyrene with a known molecular weight as a standard substance by gel permeation chromatography (GPC) measured under the conditions shown below. [Measurement conditions] Flow rate: 0.5 mL / min Detector: Differential refractive index detector (RI) Column: The following two columns are connected in series and used. TSKgel GMHH-R-H(30) (7.8 mm I.D. × 30 cm × 1) (manufactured by Tosoh Corporation) Column temperature: 40 °C Sample injection volume: 200 μL (THF solution with a concentration of 20 g / L)

[0022] It is preferable that a polydiorganosiloxane having a block structure has a linear polydiorganosiloxane structure introduced from the viewpoints of non-stickiness of the coating film and film flexibility. As an index of the state in which such a structure is introduced while being maintained ２９ Signal analysis by Si-NMR is one method. Specifically, it can be determined by detecting a signal attributed to polydiorganosiloxane corresponding to a range of a predetermined chemical shift. Generally, it is detected in the range of -10 to -50 ppm. However, the polydiorganosiloxane having a block structure contained in the cosmetic of the present invention ２９ In Si-NMR, the chemical shift of the signal attributed to the diorganosiloxane unit is detected in the range of -15 to -25 ppm, and the detection width of the signal peak (the difference between the chemical shift at the detection start point and the chemical shift at the detection end point) is 3 to 7 ppm. The narrower the detection width of the signal peak, the more it indicates that it is introduced into the polymer while maintaining a linear siloxane structure. When the detection width is larger than 10 ppm, it is introduced into the polymer in a form that hardly contains a linear structure, so it is difficult to obtain the desired coating film properties. In the present invention ２９ Si-NMR was measured using a 300 MHz-NMR manufactured by JEOL Ltd. under the condition of 25 °C for a solution sample with a sample concentration of 20 wt%.

[0023] The composition in which the polyorganosiloxane having a block structure of the present invention is dissolved in an organic solvent is characterized in that the pH of the extracted water thereof shows acidity of 3.5 to 6. Generally, it is known that the pH of the extracted water of a liquid in which a polyorganosiloxane is dissolved in an organic solvent shows neutrality unless the solvent itself shows acidity or basicity. By controlling the pH within the above range, it becomes possible to obtain a stable solution without causing gelation or the like over a long period even for a high molecular weight polyorganosiloxane such as the present invention. Such control of the pH of the extracted water includes the use of an acid, a buffer, etc., preferably the blending of an acid, and more preferably the blending of an organic carboxylic acid.

[0024] Examples of the acid include inorganic acids such as hydrochloric acid, nitric acid, sulfuric acid, and organic carboxylic acids such as formic acid, acetic acid, propionic acid, citric acid, succinic acid, maleic acid, methanesulfonic acid, trifluoromethanesulfonic acid, but are not limited to those exemplified herein.

[0025] The composition in which the polyorganosiloxane having a block structure of the present invention is dissolved in an organic solvent preferably has an organic solvent that is not an aromatic hydrocarbon. This is because aromatic hydrocarbons typified by benzene, toluene, and xylene are organic solvents with a large environmental load.

[0026] The polyorganosiloxane having a block structure contained in the cosmetic of the present invention can be produced, for example, through the following steps 1 to 3. Step 1: A silane monomer capable of constituting a siloxane unit of the above formula (1) having a chlorosilyl group or an alkoxysilyl group having 1 to 2 carbon atoms as a hydrolyzable group and a polydiorganosiloxane having hydrolyzable silyl groups at both ends are dropped into a mixed medium layer composed of water and a hydrophilic organic solvent having a water solubility of 50 to 1000 g / L at 25°C and a hydrophobic organic solvent having a water solubility of 1 g / L or less at 25°C, and hydrolytic condensation is performed. Step 2: After removing the generated hydrogen chloride and alcohol, condensation polymerization is carried out under strongly acidic conditions with a pH of 3 or less until the weight average molecular weight becomes 500,000 or more. Step 3: The acid is neutralized or removed, and the pH of the extracted water is adjusted to 3.5 to 6.

[0027] Examples of hydrophilic organic solvents with a water solubility of 50 to 1000 g / L at 25°C include alcohols, ketones, esters, and ether compounds. Specifically, examples include n-propanol, isopropanol, n-butanol, secondary butanol, isobutanol, tertiary butanol, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, ethyl acetate, butyl acetate, methyl ethyl ketone, and cyclohexanone. Among these, n-propanol, isopropanol, n-butanol, and isobutanol are preferred from the viewpoint of controlling the reaction during hydrolysis condensation and suppressing the formation of insoluble substances.

[0028] Examples of hydrophobic organic solvents with a water solubility of 1 g / L or less at 25°C include aliphatic hydrocarbon solvents such as hexane, heptane, octane, cyclohexane, methylcyclohexane, ethylcyclohexane, decane, isododecane, and isoparaffin compounds derived from olefin gases, as well as aromatic hydrocarbon solvents such as toluene and xylene. Among these, hexane, heptane, octane, cyclohexane, methylcyclohexane, and ethylcyclohexane are preferred from the viewpoint of reaction control during hydrolysis condensation, maintenance of block structure, and solubility of the resulting resin, and hexane, heptane, and ethylcyclohexane are more preferred.

[0029] The preferred weight ratio of a mixed medium consisting of water, a hydrophilic organic solvent with a water solubility of 50 to 1000 g / L at 25°C, and a hydrophobic organic solvent with a water solubility of 1 g / L or less at 25°C is 10 to 30 parts hydrophilic organic solvent and 10 to 30 parts hydrophobic organic solvent, with water being 100 parts. Exceeding this upper limit reduces productivity because it requires the use of more organic solvent than necessary. On the other hand, if it falls below this lower limit, it becomes difficult to control the reaction during hydrolysis condensation, and solvent-insoluble substances are generated.

[0030] As the silane and siloxane materials to be hydrolyzed and condensed, it is preferable to use silane monomers that can constitute the siloxane unit of formula (1) having a chlorosilyl group or an alkoxysilyl group having 1 to 2 carbon atoms as a hydrolyzable group, and polydiorganosiloxanes having hydrolyzable silyl groups at both ends. In particular, for polydiorganosiloxanes having hydrolyzable silyl groups at both ends, α,ω-dimethylchlorosiloxypolydimethylsiloxane, shown in formula (2) below, is preferred from the viewpoint of reactivity during hydrolysis. Furthermore, regarding the silane monomer, it is more preferable from the viewpoint of reaction control and production efficiency that the compound has only a chlorosilyl group as a hydrolyzable group.

[0031]

[0032] During the hydrolysis condensation reaction, the weight concentration of the reactive silane and siloxane material is preferably 10 to 30% by weight relative to the total amount of the mixed medium including water and the reactive silane and siloxane material. If this upper limit is exceeded, it becomes difficult to control the reaction during hydrolysis condensation, and insoluble matter is generated in the solvent. On the other hand, if it falls below this lower limit, it is undesirable because it reduces productivity due to the use of more organic solvent than necessary.

[0033] The temperature during the hydrolysis condensation reaction is preferably between 0 and 40°C. If the temperature is higher than 40°C, it becomes difficult to control the reaction during hydrolysis condensation, and there is a risk of generating solvent-insoluble substances. If the temperature is below 0°C, the aforementioned reaction control effect becomes excessive, and it becomes inefficient in terms of the cooling energy required for temperature control.

[0034] In a method for producing polyorganosiloxanes having a block structure, after removing the generated hydrogen chloride and alcohol, condensation polymerization is carried out under strongly acidic conditions with a pH of 3 or less until the weight-average molecular weight reaches 500,000 or more. From the viewpoint of reaction control, the reaction temperature is preferably in the range of 10 to 80°C. Furthermore, from the viewpoint of reaction control, the pH is preferably between 1 and 3. If the reaction temperature is higher than the upper limit of the range and the pH is lower than the lower limit of the range, the condensation polymerization proceeds excessively quickly and becomes difficult to control. On the other hand, if the reaction temperature is lower than the lower limit of the range and the pH is higher than the upper limit, the polymerization rate decreases significantly, and productivity deteriorates.

[0035] The content of polyorganosiloxane having a block structure contained in the cosmetic composition of the present invention is not particularly limited, but from the viewpoint of uniformity of the coating film, it is preferably 0.1 to 40% by mass, and more preferably 0.3 to 30% by mass, as resin content relative to the total amount of the cosmetic composition.

[0036] The cosmetic composition of the present invention preferably further contains a volatile oil. A volatile oil means a liquid oil that has a boiling point of 260°C or lower at normal pressure and is fluid at room temperature (25°C). It is not particularly limited as long as it is commonly used in cosmetics, and examples include hydrocarbon oils such as light liquid isoparaffin, isododecane, and isohexadecane, and silicone oils such as decamethylcyclopentasiloxane, octamethylcyclotetrasiloxane, dodecamethylcyclohexasiloxane, methyl trimethicone, dimethylpolysiloxane, decamethyltetrasiloxane, and ethyl trisiloxane, and one or more of these can be used in combination.

[0037] The content of the volatile oil agent in the cosmetic composition of the present invention is not particularly limited, but is preferably, for example, 0.1 to 80% by mass, and more preferably in the range of 0.5 to 60% by mass, based on the total amount of the cosmetic composition.

[0038] The cosmetic composition of the present invention may contain other optional components besides those described above, as long as they do not impair the effects of the present invention. Examples of other optional components include water, alcohol, oily components other than those described above, powders, surfactants, pH adjusters, emulsifiers, UV absorbers, colorfastness inhibitors, antioxidants, preservatives, vitamins, beauty ingredients, and moisturizers.

[0039] The method for producing the cosmetic composition of the present invention is not particularly limited and can be produced by known methods. For example, it can be obtained by mixing a polyorganosiloxane having a block structure with a volatile oil agent, and then adding other components to this mixture as needed and mixing them together.

[0040] The dosage form of the cosmetic composition of the present invention is not particularly limited and can be appropriately selected depending on the purpose. Examples include oily cosmetics, water-in-oil cosmetics, oil-in-water cosmetics, oil-in-oil-water cosmetics, water-in-oil cosmetics, etc. The shape is also not particularly limited and examples include liquid, gel, emulsion, cream, ointment, paste, solid paste, solid form, etc.

[0041] The uses of the cosmetic composition of the present invention are not particularly limited, and include, for example, skincare cosmetics such as lotions, emulsions, serums, facial washes, and cleansing products; makeup cosmetics such as makeup bases, foundations, concealers, face powders, lipsticks, lip balms, eyeshadows, eyeliners, mascaras, nail polishes, and body powders; sunscreen cosmetics; and hair care cosmetics.

[0042] The present invention will be described in detail below with reference to examples, but the present invention is not limited to these examples. In these examples, unless otherwise specified, "parts" and "%" mean "parts by mass" and "% by mass," respectively. The apparatus used in the examples is as follows.

[0043] (1) GPC measurement conditions Instrument: HLC-8320GPC manufactured by Tosoh Corporation Developing solvent: Tetrahydrofuran (THF) Flow rate: 0.5 mL / min Detector: Differential refractive index detector (RI) Column: Two of the following columns are used in direct connection. TSKgel GMHHR-H(30) (7.8 mm I.D. × 30 cm × 1) (manufactured by Tosoh Corporation) Column temperature: 40°C Sample injection volume: 200 μL (THF solution with a concentration of 20 g / L) Standard: Monodisperse polystyrene (2) Silicon nuclear magnetic resonance spectrum ( ２９ Si-NMR) Measurement conditions Equipment: 300MHz-NMR manufactured by JEOL Ltd. Solvent: CDCl ３ Sample concentration: 20% Internal standard: Tetramethylsilane (TMS)

[0044] In the following, the kinematic viscosity of the product was measured at 25°C using a Cannon-Fenske viscometer according to the method described in JIS Z 8803:2011, and the content of silanol hydroxyl groups in the product (mass%), hereinafter referred to as silanol content, was quantified from the amount of methane gas generated when the product was reacted with a Grignard reagent (methylmagnesium iodide).

[0045] Manufacturing Example 1 [Synthesis of Polyorganosiloxane Having a Block Structure] 2700 g of deionized water, 400 g of isobutanol, and 300 g of heptane were charged into a 5 L three-necked flask equipped with a stirrer, condenser, dropping funnel, and thermometer, and stirred. 650 g (4.3 mol) of methyltrichlorosilane at 25°C, 70 g (0.9 mol Si equivalent) of α,ω-dimethylchlorosiloxypolydimethylsiloxane (formula 3) below, and 300 g of heptane were added dropwise over 2 hours while controlling the temperature so that the internal temperature did not exceed 40°C. After the addition was complete, the hydrochloric acid aqueous phase, in which hydrogen chloride generated by the hydrolysis of the chlorosilyl group dissolved in the deionized water, was separated from the organic phase. This organic phase was washed multiple times with saline solution until the water-washed phase became neutral. The resulting organic phase had a kinematic viscosity of 2.7 mm. ２ Under drying conditions of 0.5°C for 3 hours at 105°C, the non-volatile residue was 33%, and the organic solution contained an organosiloxane with a molecular weight of approximately 7600 as determined by GPC. 20 g of concentrated hydrochloric acid was added to this organic solution, and a condensation polymerization reaction was carried out by heating at 60°C for 3 hours. Subsequently, heptane was added to adjust the concentration so that the drying residue was 20%, and after washing multiple times with saline solution until the water washing phase was neutral, 0.03% citric acid was added to the organic solution and dissolved to obtain an organic solution in which the polyorganosiloxane having the desired block structure was dissolved in an organic solvent. The kinematic viscosity of this organic solution was 14.4 mm². ２ Under drying conditions of 105°C for 3 hours at s, the non-volatile residue was 21%, and the molecular weight was approximately 1.43 million according to GPC. ２９ Si-NMR measurements revealed signals attributed to diorganosiloxane units (D units) in the range of -16 to -23 ppm, with a detection width of 5 ppm for the main signal peak. The resulting NMR spectrum chart is shown in Figure 1.

[0046]

[0047] Manufacturing Example 2 [Synthesis of Polyorganosiloxane Having a Block Structure] A polyorganosiloxane having a block structure with a weight-average molecular weight of 3.1 million was obtained in the same manner as in Manufacturing Example 1, except that the condensation polymerization reaction conditions were changed to 60°C for 4 hours.

[0048] Manufacturing Example 3 [Synthesis of Polyorganosiloxane Having a Block Structure] A polyorganosiloxane having a block structure with a weight-average molecular weight of 590,000 was obtained in the same manner as in Manufacturing Example 1, except that the condensation polymerization reaction conditions were changed to 60°C for 2 hours.

[0049] Manufacturing Example 4 [Synthesis of Polyorganosiloxane with Block Structure] 500 g of the 20% dry residue polysiloxane solution obtained in Manufacturing Example 1 was mixed with 16 g (0.16 mol) of triethylamine and 13 g (0.12 mol) of trimethylchlorosilane. The mixture was then heated at 60°C for 3 hours to carry out the trimethylsiloxylation reaction of the silanol in the polysiloxane. Subsequently, the mixture was washed multiple times with saline solution until the water washing phase became neutral to obtain an organic solution in which a polyorganosiloxane with a weight-average molecular weight of 1.56 million, trimethylsiloxy-bound and block structure, was dissolved in an organic solvent.

[0050] [Examples 1-4 and Comparative Examples 1-3; Oily Cosmetics (Liquid Rouge)] Oily cosmetics with the formulations shown in Table 1 below were prepared according to the following manufacturing method. The obtained oily cosmetics were evaluated for (a) uniformity of application and (b) secondary adhesion reduction effect by the following method. The results are also shown in Table 1. In Table 1, the content of components 8-14 indicates the resin purity.

[0051]

[0052] [Methods for preparing oily cosmetic compositions in Examples 1-4 and Comparative Examples 1-3] A: Dissolve 8-14 in a portion of 1 by heating to 100°C. B: Add the remainder of 1 and 2-7 to A and mix with a roller. C: Fill B into a container to obtain an oily cosmetic composition.

[0053] (i) Coating film uniformity Each sample was coated onto a glass plate using a 200 μm doctor blade and then dried at 25°C. After drying, cracks in the entire coating film were observed using an optical microscope (VHX-7100, manufactured by Keyence Corporation) under the conditions of tilt angle: 1 degree, lens E100: ×200, and evaluated according to the following evaluation criteria.

[0054] [Evaluation Criteria] ○: No cracks larger than 200 μm present ×: Cracks larger than 200 μm present

[0055] (b) Secondary adhesion reduction effect Each sample was applied to a 2 cm square piece of artificial leather (PBZ13001 KAKI, manufactured by Ideatex Japan Co., Ltd.), dried overnight at room temperature, and then rubbed three times back and forth at 1 mm / sec using a 25 g flow of a friction tester (Friction Tester KES-SE, manufactured by Kato Tech Co., Ltd.) with a tissue wrapped around it, and the color transfer was photographed. The obtained images were binarized (threshold: 195), the percentage of the color-transferred area was calculated, and it was evaluated according to the evaluation criteria below.

[0056] [Evaluation Criteria] ○: No color transfer (0% color transfer rate) △: Color transfer present (0% < color transfer rate < 3%) ×: Color transfer present (3% or more color transfer rate)

[0057] As shown in Table 1, Examples 1 to 4 were confirmed to have excellent coating uniformity and secondary adhesion-free effect. On the other hand, Comparative Example 1, which used a polyorganosiloxane composed of M units and Q units, Comparative Example 2, which used a polyorganosiloxane composed of M units and T units, and Comparative Example 3, which used a high-viscosity silicone oil instead of polyorganosiloxane, showed inferior results in coating uniformity and secondary adhesion-free effect.

[0058] [Examples 5-8 and Comparative Examples 4-6; Water-in-Oil Emulsified Cosmetics (Liquid Foundation)] Water-in-oil emulsion cosmetics with the formulations shown in Table 2 below were prepared according to the following manufacturing method. The obtained water-in-oil emulsion cosmetics were evaluated for (a) film uniformity and (b) secondary adhesion reduction effect using the same method as above. The results are also shown in Table 2. In Table 2, the content of components 4-10 indicates the resin purity.

[0059]

[0060] [Methods for preparing water-in-oil emulsion cosmetics in Examples 5-8 and Comparative Examples 4-6] A: Dissolve 4-7 by heating them in 1 at 100°C. B: Mix 2-3 and 14-20 with a roller. C: Mix A, B, and 8-13. D: Add 21-25 to C and emulsify at 25°C. E: Fill D into a container to obtain a water-in-oil emulsion cosmetic.

[0061] As shown in Table 2, Examples 5 to 8 were confirmed to have excellent coating uniformity and secondary adhesion-free effect. On the other hand, Comparative Example 4, which used a polyorganosiloxane composed of M units and Q units, showed inferior coating uniformity and secondary adhesion-free effect. Comparative Example 5, which used a polyorganosiloxane composed of M units and T units, and Comparative Example 6, which used a high-viscosity silicone oil instead of polyorganosiloxane, showed excellent coating uniformity but inferior secondary adhesion-free effect.

[0062] The following describes examples of cosmetic formulations. In Manufacturing Example 4, after drying with a spray dryer to obtain a solid, the solid is dissolved in 70% isododecane at a rate of 30%, and this is used as MDT resin (30% ISD solution).

[0063] [Example 9] Oil-based mascara <Preparation of cosmetic> A: Components 1 to 9 were heated to 95°C and mixed uniformly. B: Components 10 to 14 were mixed uniformly in a disperser. C: The mixture obtained in B was added to the mixture obtained in A and mixed uniformly at 90°C, then slowly cooled. D: C was filled into a container to obtain oil-based mascara. <Composition> % 1. MDT resin (30% ISD solution) 12 2. Trimethylsiloxysilicate solution (manufactured by Shin-Etsu Chemical Co., Ltd.: X-21-5595) 10 3. Dextrin palmitate (manufactured by Chiba Flour Milling Co., Ltd.: Leopal KL2) 2 4. Paraffin wax 6 5. Microcrystalline wax 7 6. Isododecane 20 7. Silicone-treated black iron oxide (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909 treatment) 5 8. 5 9. Silicone-treated talc (Shin-Etsu Chemical Co., Ltd.: KF-9909 treatment) 5 10. Polymethylsilsesquioxane (Shin-Etsu Chemical Co., Ltd.: KMP-590) 5 11. Disteardimonium hectorite 6 12. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 1.5 12. Propylene carbonate 1.6 13. Methyl parahydroxybenzoate 0.1 14. Total amount of isododecane remaining 100 <Evaluation> The oil-based mascara produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0064] [Example 10] Oil-based mascara <Preparation of cosmetic> A. Mix and dissolve components 1 to 9 uniformly (90°C). B. Mix components 10 to 17 uniformly into A (90°C). C. Fill containers with B. <Composition> % 1. MDT resin (30% ISD solution) 10 2. Dextrin palmitate (Chiba Flour Milling Co., Ltd.: Leopard TL) 2 3. Sunflower seed wax (Yokozeki Oil & Fat Industry Co., Ltd.: Refined sunflower wax) 5 4. Rice bran wax (Toa Chemical Co., Ltd.: Rice wax TOWAX-3P3) 5 5. Carnauba wax 1.5 6. Microcrystalline wax 1.5 7. Lecithin 0.5 8. Disteardimonium hectorite 8 9. Propylene carbonate 1 10. Decyltetradecanol 1 11. Trimethylsiloxysilicate solution (Shin-Etsu Chemical Co., Ltd.: X-21-5595) 10 12. (Acrylates / Dimethicone) Copolymer Solution (Shin-Etsu Chemical Co., Ltd.: KP-549) 1 13. Polymethylsilsesquioxane (Momentive Co., Ltd.: Tospar 2000B) 5 14. Silicone Composite Powder (Shin-Etsu Chemical Co., Ltd.: KSP-300) 0.5 15. Anhydrous Silicic Acid (Note 7) (Fuji Silicia Chemical Co., Ltd.: Silicia 550) 0.5 16. Black Iron Oxide (Average particle size 0.3 μm) 5 17. Total remaining amount of Isododecane 100 <Evaluation> The oil-based mascara produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0065] [Example 11] Oil-in-Water Mascara <Preparation of Cosmetic Composition> A: Heat components 1 to 7 to 95°C and mix uniformly. B: Mix components 11 to 14 uniformly in a disperser and add to A, then heat to 90°C. C: Add components 8 to 10 to B, heat to 85°C, and mix uniformly. D: Heat components 15 to 17 to 85°C and mix uniformly. E: Add D to C, emulsify at 85°C, then slowly cool to 40°C. F: Fill E into a container to obtain oil-in-water mascara. Composition % 1. MDT resin (30% ISD solution) 8 2. Acrylic-silicone graft copolymer solution (Shin-Etsu Chemical Co., Ltd.: KP-550) 9 3. (Palmitic acid / ethylhexanoic acid) dextrin (Chiba Flour Milling Co., Ltd.: Leopal TT2) 3 4. 11. Silicone wax (Shin-Etsu Chemical Co., Ltd.: KP-561P) 5 5. Ceresin 2.5 6. Beeswax 4 7. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 3 8. Silicone-treated black iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-9901 treatment) 5 9. Silicone-treated talc (Shin-Etsu Chemical Co., Ltd.: KF-9901 treatment) 4.5 10. Amorphous anhydrous silicic acid (Nippon Aerosil Co., Ltd.: AEROSIL972) 2.7 11. Isododecane residue 12. Disteardimonium hectorite 4 13. Branched polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6017) 2.2 14. Propylene carbonate 1.3 15. Phenoxyethanol 0.2 16.1,3-Butylene glycol 2 17. Purified water 12.8 Total 100 <Evaluation> The oil-in-water mascara produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0066] [Example 12] Oil-in-water mascara <Preparation of cosmetic> A. Mix and dissolve components 1 to 16 uniformly (90°C). B. Mix components 17 to 32 uniformly (90°C). C. Add A to B and emulsify at 90°C, then slowly cool to 40°C. D. Fill C into a container to obtain oil-in-water mascara. Composition % 1. Stearic acid 2 2. Glyceryl monostearate 2 3. MDT resin (30% ISD solution) 7 4. Dextrin palmitate (Chiba Flour Milling Co., Ltd.: Leopard KL) 0.1 5. Sunflower seed wax (Yokozeki Oil & Fat Industry Co., Ltd.: Refined sunflower wax) 3.5 6. Rice bran wax (Toa Chemical Co., Ltd.: Rice wax TOWAX-3P3) 3.5 7. Microcrystalline wax 3.5 8. Carnauba wax 3.5 9. Hydrogenated isoparaffin 0.5 10. Mineral oil 0.5 11. Decyltetradecanol 1 12. Trimethylsiloxysilicate solution (Shin-Etsu Chemical Co., Ltd.: KF-7312L) 2 13. Trimethylsiloxysilicate solution (Shin-Etsu Chemical Co., Ltd.: KF-9021L) 2 14. Polysorbate 80 1 15. Sorbitan sesquioleate 0.5 16. (Acrylates / Dimethicone) copolymer (Shin-Etsu Chemical Co., Ltd.: KP549) 5 17. Polymethylsilsesquioxane (Momentive Co., Ltd.: Tospar 2000B) 1.5 18. Polymethylsilsesquioxane (Momentive: Tospar 150KA) 1.5 19. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-100) 1.5 20. Nylon fiber 6 denier, 2 mm 1.5 21. Anhydrous silicic acid (Fuji Silysia Chemical Co., Ltd.: Silysia 550) 0.5 22. Amorphous anhydrous silicic acid23. Amorphous anhydrous silicic acid (manufactured by Nippon Aerosil Co., Ltd.: AEROSIL 300) 0.5 24. Black iron oxide (average particle size 0.3 μm) 5 25. Purified water remaining 26. Alkali thickening polymer emulsion (manufactured by Rohm & Haas: ACULLYN 33A) 2 27. Triethanolamine 2 28. Alkyl acrylate copolymer emulsion (manufactured by AkzoNobel: YODOSOL 810F) 5 29. Alkyl acrylate copolymer emulsion (manufactured by AkzoNobel: YODOSOL 800F) 5 30. Alkyl acrylate / vinyl acetate copolymer emulsion (manufactured by Daido Chemical Industries, Ltd.: Vinizol 2140L) 5 31. Alkyl acrylate / vinyl acetate copolymer emulsion (manufactured by Daido Chemical Industries, Ltd.: Vinizol 1086WP) 5 32. Ethanol 5 Total 100 <Evaluation> The oil-in-water mascara produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0067] [Example 13] Gel Eye Color <Preparation of Cosmetic Composition> A: Heat 1 to 5 to 80°C and mix uniformly. B: Add 6 to 9 to A and heat to 90°C and mix uniformly. C: Pour B into a container at 25°C to obtain gel eye color. Composition % 1. Crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-16) 10.5 2. Squalane 17 3. Dextrin palmitate (Chiba Flour Milling Co., Ltd.: Leopal KL2) 8.5 4. Isotridecyl isononanoate residue 5. MDT resin (30% ISD solution) 3 6. Amorphous anhydrous silicic acid (Nippon Aerosil Co., Ltd.: AEROSIL972) 0.1 7. Silicone composite powder (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-100) 5 8. Barium sulfate 9 9. Silicone-treated titanium mica (manufactured by Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 32.5 Total 100 <Evaluation> The gel eye color produced using the above method exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0068] [Example 14] Water-in-oil eye color <Preparation of cosmetic> A. Heat and dissolve components 1-6 at 100°C, then add components 7-10 to the dissolved mixture and mix uniformly. B. After mixing components 11-17, add to A and emulsify at 90°C. C: Pour B into a container at 90°C and cool overnight to obtain a water-in-oil eye color. Composition % 1. (Palmitic acid / octanoic acid) dextrin 2 2. Sunflower seed wax 2 3. Fischer-Tropsch wax 2 4. 2-Decyltetradecanol 1 5. MDT resin (30% ISD solution) 50 6. Polyisobutylene 5 7. Dimethyldistearylammonium hectorite 3 8. Red iron oxide (short diameter: average particle size 0.07 μm) 0.01 9. Red No. 226 0.5 10. Carbon Black 4 11. Purified Water Remaining Amount 12. Disodium Edetate 0.01 13. 1,2-Pentanediol 1 14. Sorbitan Sesquioleate 0.5 15. Chlorphenesin 0.3 16. Ethylhexylglycerin 0.1 17. Fragrance 0.1 Total 100 <Evaluation> The water-in-oil eye color produced as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0069] [Example 15] Eyeliner <Preparation of Cosmetic> A. Heat and dissolve components 1 to 6 at 90°C. B. Add components 7 to 11 to A and mix uniformly. C. Melt and fill B into a container at 95°C and cool to 25°C to obtain eyeliner. Composition % 1. (Acrylates / Dimethicone) Copolymer Solution (Shin-Etsu Chemical Co., Ltd.: KP-549) 10 2. Polybutene (JX Nippon Oil & Energy Corporation: Nippon Oil Polybutene HV-1900) 20 3. Trimethylsiloxysilicate (Asahi Kasei Wacker Silicone Co., Ltd.: BELSIL TMS 803) 5 4. 2-Decyltetradecanol 15 5. MDT Resin (30% ISD Solution) 10 6. Methyl Trimethicone Remaining Amount 7. Phenoxyethanol 1 8. Polymethylsilsesquioxane (Momentive: Tosper 2000B) 5 9. Carbon black 10 10. Sericite 10 11. (Linoleic acid / oleic acid) tocopherol 0.1 Total 100 <Evaluation> The eyeliner produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0070] [Example 16] Eyeliner <Preparation of Cosmetic> A. Heat and dissolve components 1 to 7 at 90°C. B. Add components 8 to 13 to A and mix uniformly at 90°C. C. Melt and fill B into a container at 95°C and cool to 25°C to obtain eyeliner. Composition % 1. Polybutene (manufactured by JX Nippon Oil & Energy Corporation: Nippon Oil Polybutene HV-1900) 6 2. (Acrylates / Dimethicone) Copolymer Solution (manufactured by Shin-Etsu Chemical Co., Ltd.: KP-549) 5 3. Liquid Paraffin 1 4. 2-Decyltetradecanol 3 5. MDT Resin (30% ISD Solution) 10 6. Methyl Trimethicone Remainder 7. Trimethylsiloxysilicate (manufactured by Momentive: SR1000) 10 8. 9. Ethylhexylglycerin 0.1 10. Hydrogenated isoparaffin 3 11. Black iron oxide (average particle size 0.3 μm) 25 12. Methylsiloxane network polymer (Momentive: TOSPEARL 150KA) 2 13. Lecithin 0.5 14. Rosemary extract 0.1 Total 100 <Evaluation> The eyeliner produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0071] [Example 17] Oil-based eye color <Preparation of cosmetic> A. Heat components 1 to 5 to 100°C and dissolve uniformly. B. Add components 6 to 13 to A and disperse uniformly at 100°C. C. Pour B into a container at 90°C and cool overnight to obtain oil-based eye color. Composition % 1. Trimethylsiloxysilicate (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-7021L) 1 2. Methylphenylpolysiloxane 5 3. Glyceryl tri-2-ethylhexanoate residue 4. Candelilla wax 5 5. Carnauba wax 3 6. N-Lauroyl-L-Lysine (manufactured by Ajinomoto Co., Ltd.: Amihope LL) 2 7. Methylsiloxane network polymer 15 8. Cross-linked dimethylpolysiloxane composition (manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-16) 5 9. MDT resin (30% ISD solution) 15 10. Titanium mica (CQV Corporation: COSMETICA SUPER RED N-5401S) 10 11. Red No. 202 0.1 12. Tocopherol acetate 0.1 13. Phenoxyethanol 0.5 Total 100 <Evaluation> The oil-based eye color produced by the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0072] [Example 18] Oil-based eyebrow powder <Preparation of cosmetic product> A: Components 1 to 6 are uniformly heated and dissolved at 90°C, and components 7 to 13 are added and mixed uniformly. B: Components 14 to 17 are added to A and mixed and dispersed uniformly. C: B is melted and filled into a container at 95°C and cooled to 25°C to obtain an oil-based eyebrow powder.Composition % 1. Fischer-Tropsch wax (CIREBELLE 109L) 8 2. Microcrystalline wax (SONNEBORN MULTIWAX W445) 10 3. Diglyceryl triisostearate residue 4. MDT resin (30% ISD solution) 10 5. Methyl trimethicone 15 6. Diisostearyl malate 2 7. 2,6-Di-tert-butyl-paracresol 0.1 8. Amorphous anhydrous silicic acid (Aerosil 380S) 3 9. Methylsiloxane network polymer (TOSPEARL 150KA) 5 10. Yellow No. 4 0.01 11. Titanium dioxide (average particle size 0.27 μm (aluminum hydroxide coated)) 1 12. Titanium dioxide coated borosilicate (Ca / Al) (manufactured by Nippon Sheet Glass Co., Ltd.: Microglass Metashine MT1080RR) 3 13. Titanium mica (manufactured by BASF: TIMICA EXTRA BRIGHT 1500) 5 14. Red iron oxide coated titanium mica (manufactured by BASF: Cloisonné Rouge Flambé) 2% dimethicone treatment 5 15. Humus extract 3 16. (Linoleic acid / oleic acid) tocopherol 0.1 17. Fragrance 0.1 Total 100 <Evaluation> The oil-based eyebrow product manufactured using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0073] [Example 19] Oil-based eyeshadow <Preparation of cosmetic> A. Heat components 1 to 3 to 70°C and dissolve uniformly. B. Add components 4 to 20 to A and disperse uniformly at 70°C. C. Pour B into a container to obtain oil-based eyeshadow.Composition % 1. Diglyceryl triisostearate 5 2. Glyceryl tri-2-ethylhexanoate 20 3. Neopentyl glycol di-2-ethylhexanoate (remainder) 4. MDT resin (30% ISD solution) 10 5. Methyl trimethicone 5 6. Dipropylene glycol 0.1 7. Tripropylene glycol 10 8. Dimethicone-impregnated porous silica (Cosme Silica CQ4 (manufactured by Fuji Silicia Chemical) impregnated with KF-96-100CS in a mass ratio of 1:1) 3 9. Titanium dioxide (average particle size 0.27 μm) 0.3 10. Black iron oxide (average particle size 0.3 μm) 0.01 11. Red iron oxide (short diameter: average particle size 0.07 μm) 0.01 12. Yellow iron oxide (short diameter: average particle size 0.07 μm) 0.01 13. Titanium mica (CQV Corporation: COSMETICA SUPER RED N-5401S) 5 14. Titanium dioxide coated borosilicate (Ca / Al) (Nippon Sheet Glass Co., Ltd.: Microglass Metashine MT1080RR) 5 15. Methylsiloxane network polymer 10 16. Synthetic fluorphlogopite (average particle size 20 μm) 10 17. (HDI / trimethylol hexyllactone) crosspolymer (Toshoku Pigment Co., Ltd.: D-400) 5 18. Methyl parahydroxybenzoate 0.1 19. Lecithin 0.1 20. Fragrance 0.1 Total 100 <Evaluation> The oil-based eyeshadow produced as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0074] [Example 20] Eye Cream <Preparation of Cosmetic Composition> A: Components 1 to 4 were uniformly mixed. B: Components 8 to 12 were uniformly mixed. C: B was added to A and emulsified at 60°C, components 5 to 7 were added and heated to 60°C and mixed uniformly, and cooled to 25°C to obtain eye cream. Composition % 1. Silicone-alkyl-modified-crosslinked polyether-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-350Z) 4 2. Silicone-alkyl-modified-crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-045Z) 6 3. Silicone-alkyl-branched polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 0.5 4. Dimethicone (6CS) 12 5. 6. Vaseline (SONNEBORN: SNOW WHITE SPECIAL) 4.5 7. MDT resin (30% ISD solution) 2.5 8. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-441) 2 9. 1,3-Butylene glycol 7 10. Phenoxyethanol 0.25 11. Sodium citrate 0.2 12. Sodium chloride 0.5 13. Total amount of purified water remaining 100 <Evaluation> The eye cream produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0075] [Example 21] Powdered solid cosmetic (eyeshadow) <Preparation of cosmetic> A: Mix 1 to 15 in a Henschel mixer. B: Add 16 to 18 to A and mix in a Henschel mixer. C: Grind B in a pulverizer. D: Fill C into a resin dish and then compress and mold to obtain powdered solid cosmetic (eyeshadow).Composition % 1. Talc (Asada Flour Milling Co., Ltd.: Talc JA-46R) Remaining amount 2. Mica (Yamaguchi Mica Co., Ltd.: MICA POWDER Y-2300) 15 3. Sericite (Sanshin Mining Industry Co., Ltd.: Sericite FSE-S) 10 4. Zinc myristate 1 5. Synthetic fluorophlogopite (Topy Industries Co., Ltd.: TLF-64) 10 6. Zinc oxide (Sakai Chemical Co., Ltd.: XZ-3000F) 5 7. Spherical corn starch (Nippon Denko Chemical Co., Ltd.: Corn starch ST-C) 3 8. (Hydroxybutyric acid / hydroxypentanoic acid) copolymer 3 9. Higher alcohol-treated spherical silica (anhydrous silicic acid) 3 10. Red iron oxide 2 11. Yellow iron oxide 0.01 12. Black iron oxide 0.01 13. Zinc laurate-treated titanium oxide 1 14. Titanium mica (Merck: TIMIRON SUPER GOLD) 5 15. Red iron oxide-coated titanium mica (BASF: CLOISONNE ROUGE FLAMBE) 2 16. Chlorphenesin 0.2 17. MDT resin (30% ISD solution) 4.8 18. Liquid paraffin (SONNEBORN LCC: KLEAROL WHITE MINERAL OIL) 4.5 Total 100 <Evaluation> The powdered solid cosmetic (eyeshadow) produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0076] [Example 22] Powdered Solid Cosmetic (Eyeshadow) <Preparation of Cosmetic> A: Heat 1 to 6 to 90°C and mix and dissolve uniformly. B: After cooling to 25°C, add 7 to 15 to A in a planetary mixer and knead under reduced pressure. C: After filling B into a resin dish, compress and mold to obtain powdered solid cosmetic (eyeshadow). Composition % 1. Dextrin palmitate (Chiba Flour Milling Co., Ltd.: Leopal KL2) 4 2. Cetyl ethylhexanoate 6 3. MDT resin (30% ISD solution) 15 4. Methyl trimethicone 10 5. Diglyceryl tetraisostearate 10 6. Diphenyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-54) 5 7. Plate-shaped zinc oxide (average particle size 0.3 μm) 0.2 8. 15. Titanium mica (Merck: TIMIRON STARLUSTER MP-115) 15 9. Titanium oxide coated borosilicate (Nippon Sheet Glass: Microglass Metashine MT1080RS) 10 10. Synthetic fluorophlogopite (Topy Industries: PDM-20L) Remaining amount 11. Amorphous anhydrous silicic acid (Nippon Aerosil: AEROSIL 200) 0.2 12. Yellow iron oxide (short diameter: average particle size 0.07 μm) 0.01 13. Red iron oxide (short diameter: average particle size 0.07 μm) 0.01 14. Black iron oxide (average particle size 0.3 μm) 0.01 15. (HDI / Trimethylol Hexyllactone) Crosspolymer (Manufactured by Toshoku Pigment Co., Ltd.: D-400) 5 Total 100 <Evaluation> The powdered solid cosmetic (eyeshadow) produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0077] [Example 23] Powdered solid cosmetic (eyeshadow) <Preparation of cosmetic> A: Heat 1 to 6 to 90°C and mix and dissolve uniformly. B: After cooling to 25°C, add 7 to 15 to A in a planetary mixer and knead under reduced pressure. C: After filling B into a resin dish, compress and mold to obtain powdered solid cosmetic (eyeshadow). Composition % 1. (Vinyl dimethicone / lauryl dimethicone) crosspolymer mixture (manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-43) 11.7 2. 2-Cetyl ethylhexanoate 8.3 3. MDT resin (30% ISD solution) 15 4. Methyl trimethicone 5 5. Diglyceryl tetraisostearate 10 6. Methylphenylpolysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-54) 5 7. Plate-shaped zinc oxide (average particle size 0.3 μm) 0.2 8. Titanium oxide-coated synthetic fluorphlogopite (manufactured by Topy Industries Co., Ltd.: HELIOS R10B) 15 9. Titanium oxide-coated borosilicate (manufactured by Nippon Sheet Glass Co., Ltd.: Microglass Metashine MT1080RR) 10 10. Synthetic fluorophlogopite (manufactured by Topy Industries Co., Ltd.: PDM-20L) Remaining amount 11. Amorphous anhydrous silicic acid (manufactured by Nippon Aerosil Co., Ltd.: AEROSIL 300) 0.2 12. Yellow iron oxide (short diameter: average particle size 0.07 μm) 0.01 13. Red iron oxide (short diameter: average particle size 0.07 μm) 0.01 14. Black iron oxide (average particle size 0.3 μm) 0.01 15. (HDI / Trimethylol Hexyllactone) Crosspolymer (Manufactured by Toshoku Pigment Co., Ltd.: D-400) 5 Total 100 <Evaluation> The powdered solid cosmetic (eyeshadow) produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0078] [Example 24] Powdered Solid Cosmetic (Eyeshadow) <Preparation of Cosmetic> A: Heat 1 to 4 to 90°C and mix and dissolve uniformly. B: After cooling to 25°C, add 5 to 13 to A in a planetary mixer and knead under reduced pressure. C: After filling B into a resin dish, compress and mold to obtain powdered solid cosmetic (eyeshadow). Composition % 1.2-Cetyl ethylhexanoate residue 2. MDT resin (30% ISD solution) 10 3. Diglyceryl tetraisostearate 15 4. Methylphenylpolysiloxane (Shin-Etsu Chemical Co., Ltd.: KF-54) 5 5. Plate-shaped zinc oxide (average particle size 0.3 μm) 0.2 6. Titanium mica (Merck Company: TIMIRON STARLUSTER MP-115) 15 7. Titanium dioxide coated borosilicate (manufactured by Nippon Sheet Glass Co., Ltd.: Microglass Metashine MT1080RY) 10 8. Synthetic fluorophlogopite (manufactured by Topy Industries Co., Ltd.: Synthetic fluorphlogopite PDM-10L) 18 9. Amorphous anhydrous silicic acid (manufactured by Nippon Aerosil Co., Ltd.: AEROSIL 300) 0.2 10. Yellow iron oxide (short diameter: average particle size 0.07 μm) 0.01 11. Red iron oxide (short diameter: average particle size 0.07 μm) 0.01 12. Black iron oxide (average particle size 0.3 μm) 0.01 13. (HDI / Trimethylol Hexyllactone) Crosspolymer (Manufactured by Toshoku Pigment Co., Ltd.: D-400) 5 Total 100 <Evaluation> The powdered solid cosmetic (eyeshadow) produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0079] [Example 25] Powdered solid cosmetic (eyebrow) <Preparation of cosmetic> A: Mix 1 to 13 in a Henschel mixer. B: Add 14 to 17, which have been mixed and dissolved at 80°C, to A and mix in a Henschel mixer. C: Crush B in a pulverizer. D: After filling C into a resin dish, compress and mold to obtain powdered solid cosmetic (eyebrow). Composition % 1. Talc (Matsumura Sangyo Co., Ltd.: Crown Talc K-12) Remainder 2. Sericite 20 3. Boron nitride (Mizushima Iron Alloy Co., Ltd.: SHP-3) 5 4. Zinc myristate 3 5. Zinc oxide (Sakai Chemical Industry Co., Ltd.: Hexagonal plate-shaped zinc oxide XZ-300F-LP) 5 6. Spherical corn starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 2 7. 10. (Hydroxybutyric acid / hydroxypentanoic acid) copolymer 3 8. Higher alcohol-treated spherical silica (anhydrous silicic acid) 1 9. Red iron oxide 5 10. Yellow iron oxide 0.01 11. Black iron oxide 0.01 12. Zinc laurate-treated titanium dioxide 1 13. Chlorphenesin 0.2 14. Dextrin isostearate 0.2 15. 2-ethylhexyl hydroxystearate (manufactured by Higher Alcohol Industry: Lithocasta IOHS) 5 16. MDT resin (30% ISD solution) 4.5 17. Dimethicone (10CS) 2 Total 100 <Evaluation> The powder solid cosmetic (eyebrow) produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0080] [Example 26] Powdered Solid (Slurry) Eye Color <Preparation of Cosmetic Product> A: Mix 1 to 12 in a Henschel mixer. B: Heat 13 to 19 to 60°C and mix uniformly. C: Add 50 parts of B and isododecane to A and mix uniformly with a universal stirrer. D: Place 4.0 g in a round metal dish container (3 cm in diameter) and press with a pressure of 2.0 kgf / cm ２The mixture was compressed twice under the conditions of a press time of 4 seconds and 6 sheets of paper, partially removing isododecane. E:D was dried overnight at 70°C to obtain a powdered solid (slurry) eye color.Composition % 1. Talc (Matsumura Sangyo Co., Ltd.: Crown Talc K-20) Remaining amount 2. Mica (Sanshin Kogyo Co., Ltd.: JS-1) 15 3. Synthetic fluorphlogopite (20 μm) 10 4. Zinc oxide (Sakai Chemical Industry Co., Ltd.: Hexagonal plate-shaped zinc oxide XZ-300F-LP) 1 5. Approximately spherical corn starch 3 6. (Hydroxybutyric acid / hydroxypentanoic acid) copolymer 3 7. Higher alcohol-treated spherical silica (anhydrous silicic acid) 3 8. Black iron oxide 0.01 9. Zinc laurate-treated titanium dioxide 1 10. Titanium-coated mica (CQV Co., Ltd.: COSMETIGA SHIMARING WHITE N-8000E) 10 11. Ultramarines / Titanium Dioxide Coated Mica (BASF: CLOISONNE BLUE 626C) 5 12. Titanium Dioxide Coated Borosilicate (Ca / Al) (Nippon Sheet Glass: Microglass Metashine MT1080RY) 10 13. Sorbitan Sesquiisostearate (Nisshin Oillio Group: Cosmoll 182V) 5 14. Diisostearyl Malate (Nisshin Oillio: Cosmoll 222) 10 15. Dimethicone (20CS) 5 16. MDT Resin (30% ISD Solution) 5 17. Fragrance 1 18. Methylparaben 0.2 19. (Dimethicone / Vinyl Dimethicone) Crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16) 4 Total 100 <Evaluation> The powdered solid (slurry) eye color produced by the above method exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0081] [Example 27] Powdered Solid (Slurry) Eye Color <Preparation of Cosmetic Product> A: Mix 1 to 12 in a Henschel mixer. B: Heat 13 to 19 to 60°C and mix uniformly. C: Add 50 parts of B and isododecane to A and mix uniformly with a universal stirrer. D: Place 4.0 g in a round metal dish container (3 cm in diameter) and press with a pressure of 2.0 kgf / cm ２The mixture was compressed twice under the conditions of a press time of 4 seconds and 6 sheets of paper, partially removing isododecane. E:D was dried overnight at 70°C to obtain a powdered solid (slurry) eye color.Composition % 1. Talc (Matsumura Sangyo Co., Ltd.: Crown Talc K-20) Remaining amount 2. Mica (Sanshin Kogyo Co., Ltd.: JS-1) 15 3. Synthetic fluorphlogopite (20 μm) 10 4. Hexagonal plate-shaped zinc oxide (Sakai Chemical Industry Co., Ltd.: Hexagonal plate-shaped zinc oxide XZ-300F-LP) 1 5. Spherical corn starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 0.5 6. (Hydroxybutyric acid / hydroxypentanoic acid) copolymer 0.5 7. Spherical cellulose powder (Daito Chemical Industry Co., Ltd.: CELLULOBEADS D-10) 0.5 8. Red iron oxide 0.01 9. Ultramarines 1 10. Titanium-coated mica (Merck: TIMIRON SPLENDID RED) 10 11. Ultramarines-coated titanium dioxide mica (BASF: CLOISONNE SUPER GREEN 827C) 5 12. Titanium dioxide-coated borosilicate (Ca / Al) (Nippon Sheet Glass: Microglass Metashine MT1080RS) 10 13. Sorbitan sesquiisostearate (Nisshin Oillio Group: Cosmoll 182V) 5 14. Diisostearyl malate 5 15. Dimethicone (6CS) 5 16. MDT resin (30% ISD solution) 5 17. Fragrance 1 18. Synthetic wax (manufactured by Nippon Surfactant Industry Co., Ltd.: PERFORMA SW-87) 0.2 19. (Dimethicone / vinyl dimethicone) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-16) 4 Total 100 <Evaluation> The powder solid (slurry) eye color produced as described above exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0082] [Example 28] Lipstick <Preparation of Cosmetic Composition> A: Disperse components 9-16 in a three-roll mill. B: Heat components 1-8 to 95°C and mix uniformly. C: Mix A, B, and components 17-18 uniformly and heat to 85°C. D: Fill C into a stick container and cool to 25°C to obtain a lipstick. Composition % 1. Synthetic wax (manufactured by Nippon Natural Products Co., Ltd.: LIPWAX A-4) 7 2. Paraffin 3 3. Silicone wax (manufactured by Shin-Etsu Chemical Co., Ltd.: KP-561P) 10.5 4. Triethylhexanoin 15.5 5. Neopentyl glycol diethylhexanoate 14 6. Neopentyl glycol dicaprate 7 7. Hydrogenated polyisobutene (manufactured by NOF Corporation: Pearlream 18) 20 8. Diphenyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-54HV) 7.5 9. Talc 0.7 10. Red No. 201 0.01 11. Red No. 202 0.01 12. Yellow No. 4 Aluminum Lake 0.01 13. Silicone-treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: KF-574 treatment) 3 14. Silicone-treated black iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-574 treatment) 0.01 15. Silicone-treated red iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-574 treatment) 0.01 16. Diglyceryl triisostearate 4 17. Silicone-treated mica (Shin-Etsu Chemical Co., Ltd.: KF-574 treatment) 5.5 18. MDT resin (30% ISD solution) 1 Total 100 <Evaluation> The lipstick manufactured using the above method exhibited excellent coating uniformity and secondary adhesion-free effect.

[0083] [Example 29] Oil-based solid cosmetic (stick lipstick) <Preparation of cosmetic> A: Heat 1 to 5 at 110°C and mix uniformly. B: Mix A and 6 to 12 with a roller. C: Add 13 to 18 to B and mix uniformly at 90°C. D: Heat C to a container and fill, then cool to 25°C to obtain an oil-based solid cosmetic (stick lipstick). Composition % 1. (Ethylene / propylene) copolymer (manufactured by Nippon Natural Products Co., Ltd.: EPS wax) 3 2. Paraffin 1 3. Microcrystalline wax mixture (manufactured by PARAMELT: PARACERA 14728) 1 4. Isotridecyl isononanoate 12 5. MDT resin (30% ISD solution) 10 6. Dimethicone (10CS) Remainder 7. 10. Diglyceryl triisostearate 8. Polyhydroxystearic acid 5 9. (Dimethicone / vinyl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16F) 5 10. Lecithin (J-Oil Mills: Lecithin CLO) 1 11. Dipropylene glycol 1 12. Pigment (Red No. 202, Yellow No. 4, and yellow iron oxide mixed in a mass ratio of 2:2:1) 3 13. Spherical silica (anhydrous silicic acid) 15 14. Approximately spherical corn starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 3 15. Biodegradable spherical polylactic acid (average particle size: 20 μm, oil absorption: 70 ml / 100 g) 15 16. Lavender oil 1 17. Fragrance 0.2 18. Hyaluronic acid 0.2 Total 100 <Evaluation> The oil-based solid cosmetic (stick-type lipstick) manufactured as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0084] [Example 30] Oil-based solid cosmetic (lip balm) <Preparation of cosmetic> A: A solid cosmetic (lip balm) was obtained by heating and mixing A:1 to 20 at 110°C, then filling into a container and cooling. Composition % 1. Diisostearyl malate residue 2. Diglyceryl triisostearate 20 3. Polybutene (manufactured by JX Nippon Oil & Energy Corporation: Nippon Oil Polybutene HV-1900) 15 4. Microcrystalline wax (manufactured by SONNEBORN: MULTIWAX W445) 10 5. Stearyl glycyrrhetinate 0.5 6. Sucrose fatty acid ester (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.: DK ester S-160) 7 7. Amorphous anhydrous silicic acid (manufactured by Nippon Aerosil Co., Ltd.: AEROSIL R972) 0.2 8. MDT resin (30% ISD solution) 1 9. Linalool 0.002 10. Farnesol 0.002 11. Anisic Alcohol 0.002 12. Eugenol 0.002 13. Citronellol 0.002 14. Geraniol 0.002 15. Linalyl acetate 0.002 16. α-Terpineol 0.002 17. Geranyl acetate 0.002 18. α-Pinene 0.002 19.1-Hexen-1-ol 0.002 20. Cedryl acetate 0.002 Total 100 <Evaluation> The oily solid cosmetic (lip balm) produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0085] [Example 31] Oil-based solid cosmetic (lip balm) <Preparation of cosmetic> A: 1 to 22 were heated and mixed at 110°C, then filled into a container and cooled to obtain an oil-based solid cosmetic (lip balm).Composition % 1. Diisostearyl malate remaining amount 2. Diglyceryl triisostearate 20 3. Polybutene (manufactured by Nippon Natural Products Co., Ltd.: Purified Polybutene HV-100F (SB)) 15 4. Microcrystalline wax (manufactured by SONNEBORN: MULTIWAX W445) 10 5. Stearyl glycyrrhetinate 0.5 6. Sucrose fatty acid ester (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.: DK ester S-160) 7 7. Amorphous anhydrous silicic acid (manufactured by Nippon Aerosil Co., Ltd.: AEROSIL R972) 0.2 8. MDT resin (30% ISD solution) 1 9. Iso E Super 0.002 10. 11. Sandalore 0.002 12. Ambroxan 0.002 13. γ-Terpinene 0.002 14. Ambrettolide 0.002 15. β-ionone 0.002 16. Borneol 0.002 17. Isobutylquinoline 0.002 18. Citral 0.002 19. Guaicaol 0.002 20. Patchouli alcohol 0.002 21. Cedrol 0.002 22. Ethyl Vanillin 0.002 33. Maltol 0.002 Total 100 <Evaluation> The oily solid cosmetic (lip balm) produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0086] [Example 32] Oily liquid cosmetic (liquid rouge) <Preparation of cosmetic> A: Heat 1 to 6 at 100°C and mix uniformly. B: Add 7 to 18 to A and mix. C: Fill B into a container to obtain an oily liquid cosmetic (liquid rouge). Composition % 1. Dextrin palmitate 1 2. Diisostearyl malate 8 3. Dimer dilinoleate (phytosteryl / isostearyl / cetyl / stearyl / behenyl) 3 4. Pentaerythrityl tetraethylhexanoate 5 5. MDT resin (30% ISD solution) 5 6. Polybutene (manufactured by JX Nippon Oil & Energy Corporation: Nippon Oil Polybutene HV-1900) 1 7. Isododecane 25 8. Trimethylsiloxysilicate 5 9. Disteardimonium hectorite 2 10. Titanium-coated mica (Merck: TIMIRON SPLENDID RED) 1 11. Titanium oxide-coated borosilicate (Ca / Al) (Nippon Sheet Glass: Microglass Metashine MT1080RR) 10 12. Dipropylene glycol 0.3 13. Tocopherol 0.1 14. Dimethicone (10CS) 1 15. Spherical cellulose powder (Daito Chemical Industries: CELLULOBEADS D-10) 5 16. Approximately spherical corn starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 5 17. (Hydroxybutyric acid / hydroxypentanoic acid) copolymer 5 18. Atomized silica 2 Total 100 <Evaluation> The oily liquid cosmetic (liquid rouge) produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0087] [Example 33] Nail Enamel Overcoat <Preparation of Cosmetic Composition> A: Mix 5 to 8, add 4 and mix uniformly. B: Add 1 to 3 to A and mix, then fill into a container to obtain a nail enamel overcoat. Composition % 1. MDT resin (30% ISD solution) 5 2. Nitrocellulose 17 3. Alkyd resin 4 4. Acetyl triethyl citrate 5 5. Butyl acetate residue 6. Ethyl acetate 25 7. Isopropyl alcohol 3 8. n-Butyl alcohol 1 Total 100 <Evaluation> The nail enamel overcoat produced as described above exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0088] [Example 34] Oil-based solid concealer <Preparation of cosmetic> A: Heat 1-3 at 110°C and mix uniformly. B: Mix A and 4-8 with a roller. C: Add 9-18 to B and mix uniformly at 90°C. D: Heat C to a container and fill, then cool to 25°C to obtain an oil-based solid concealer. Composition % 1. Synthetic wax (melting point 74°C) 2 2. Candelilla wax (manufactured by Nippon Natural Products Co., Ltd.: refined candelilla wax SR-3) 2 3. PG dicaprate 3 4. Meadowfoam oil 3 5. MDT resin (30% ISD solution) 3 6. Remainder of diglyceryl triisostearate 7. Diglyceryl tetraisostearate yellow iron oxide 3 8. (Dimethicone / Vinyl Dimethicone) Crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16) 5 9. (Dimethicone / Vinyl Dimethicone) Crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16) 10 10. Stearoyl Glutamate Treated Titanium Dioxide 20 11. Dipropylene Glycol 1 12. Spherical Cellulose Powder (Daito Chemical Industries, Ltd.: CELLULOBEADS D-10) 1 13. Spherical Silica (Anhydrous Silicic Acid) 1 14. Approximately Spherical Corn Starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 1 15. Biodegradable Spherical Polylactic Acid (Average Particle Size: 20 μm, Oil Absorption: 70 ml / 100 g) 1 16. Lavender Oil 1 17. Fragrance 0.2 18. Hyaluronic acid 0.2 Total 100 <Evaluation> The oil-based solid concealer manufactured as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0089] [Example 35] Non-aqueous concealer <Preparation of cosmetic> A. Heat 1 to 6 to 110°C and mix uniformly. B. Add 7 to 12 and knead uniformly. C. Add B to A and stir until uniform. D. Heat C to 90°C, fill into a jar container, and cool to 25°C to obtain a non-aqueous concealer. Composition % 1. Hydrogenated isoparaffin 3 2. MDT resin (30% ISD solution) 20 3. Hydrogenated polyisobutene (Idemitsu Kosan Co., Ltd.: IP Solvent 1620MU) 5 4. Methyltrimethicone residue 5 (Dimethicone / vinyl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16) 3 6. Microcrystalline wax (SONNEBORN: MULTIWAX W445) 3.8 7. Polyhydroxystearic acid 2 8. 2% silicone-treated titanium dioxide 20 9. 2% silicone-treated iron oxide (red) 0.5 10. 2% silicone-treated iron oxide (yellow) 3.5 11. 2% silicone-treated iron oxide (yellow) 0.2 12. Polylactic acid 10 Total 100 <Evaluation> The non-aqueous concealer produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0090] [Example 36] Oil-in-water primer <Preparation of cosmetic> A: Mix 1 to 4 uniformly. B: Mix 5 to 14 uniformly. C: Add A to B, emulsify at 25°C, fill into a container to obtain an oil-in-water primer. Composition % 1. MDT resin (30% ISD solution) 3 2. Partially crosslinked silicone mixture (Shin-Etsu Chemical Co., Ltd.: KSG-19) 5 3. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 5 4. Fine particle titanium dioxide dispersion (Shin-Etsu Chemical Co., Ltd.: SPD-T7) 10 5. 1,3-Butylene glycol 10 6. Betaine 1 7. Polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6043) 1.5 8. Sodium acrylate / sodium acryloyldimethyl taurate copolymer composition (SEPPIC: SIMULGEL EG) 1 9. (Acrylates / C10-30 alkyl acrylate) crosspolymer (2% aqueous solution) 20 10. Arginine (10% aqueous solution) 0.01 11. Bisabolol 0.1 12. Ethylhexylglycerin 0.1 13. EDTA-2Na (10% aqueous solution) 0.1 14. Total remaining water 100 <Evaluation> The oil-in-water primer produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0091] [Example 37] Oil-in-water primer <Preparation of cosmetic> A: Heat 1 to 9 uniformly at 70°C and mix uniformly. B: Mix 10 to 18 uniformly at 70°C. C: Add B to A while stirring with a desper at 70°C and emulsify. D: Cool C to 25°C. E: Mix 19 to 24 uniformly with a roller. F: Add E and 25 to 36 to D and mix uniformly, then fill into a container to obtain an oil-in-water primer. Composition % 1. Stearic acid 2 2. Sucrose polystearate 1 3. Cetostearyl alcohol 1 4. Behenyl alcohol 1 5. Polysorbate 80 0.5 6. Polysorbate 85 0.5 7. Ethylhexyl methoxycinnamate 6 8. Diethylamino hydroxybenzoyl hexyl benzoate 1 9. MDT resin (30% ISD solution) 1 10. Purified water remaining 11. Triethanolamine 1 12. Phenoxyethanol 0.3 13. Fragrance 0.1 14. Carbomer 0.2 15. Xanthan gum 0.2 16. Hydroxypropyl methylcellulose (Shin-Etsu Chemical Co., Ltd.: Metroze 65SH-400) 0.1 17. Dipropylene glycol 5 18. Glycerin 5 19.1,3-Butylene glycol 10 20. Lecithin 1 21. Triceteareth-4-phosphate 1 22. Sorbitan sesquioleate 1 23. Lecithin-treated titanium dioxide (Powder of titanium dioxide (manufactured by Ishihara Sangyo Co., Ltd.: Titanium CR-50) surface-treated with 1% lecithin) 5 24. Red iron oxide 2 25. (Fluoride / Hydroxide / Oxide) (Mg / K / Silicate) (manufactured by Katakura Coop Agri Co., Ltd.: Micromica MK-200K) 2 26. Lauroyl lysine-treated spherical cellulose particles (Powder of spherical cellulose with an average particle size of 30 μm and an oil absorption capacity of 50 ml / 100 g treated with 2% lauroyl lysine) 1 27. Spherical biodegradable polyamide particles (average particle size of 10 μm) 1 28. Non-porous silica (AGC SI-TECH: NP-30) 1 29. Dimethicone-impregnated porous silica (Cosme Silica CQ4 (Fuji Silicia Chemical) impregnated with KF-96-100CS in a mass ratio of 1:1) 1 30. Hydrolyzed hyaluronic acid 1 31. Niacinamide 2 32. Succinic acid 0.5 33. Disodium succinate 0.25 34. BHT 0.05 35. EDTA-2Na 0.05 36. Sodium pyrosulfite 0.05 Total 100 <Evaluation> The oil-in-water primer produced as described above exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0092] [Example 38] Oil-in-water primer <Preparation of cosmetic> A: Process 1 to 8 uniformly with a three-roller. B: Process 9, part of 16 and part of 17 uniformly with a three-roller. C: Add 21 to 30 to A and mix uniformly at 75°C. D: Mix 10 to 15, the remainder of 16 and the remainder of 17, and 18 to 20 uniformly at 75°C. E: Add B and D to C and emulsify at 75°C. F: Cool E to 40°C. G: After filling F into a container, an oil-in-water primer was obtained. Composition % 1. 1,3-Butylene glycol 10 2. Glycerin 5 3. Triceteareth-4 phosphate 0.1 4. Polysorbate-80 0.1 5. Silicone-treated titanium dioxide 1 6. 1. Silica-treated red iron oxide (manufactured by Nikki Catalytic Chemical Co., Ltd.: Symphorite RW-TE) 0.02 7. Silica-treated yellow iron oxide (manufactured by Nikki Catalytic Chemical Co., Ltd.: Symphorite YW-TE) 0.02 8. Silica-treated black iron oxide (manufactured by Nikki Catalytic Chemical Co., Ltd.: Symphorite BW-TE) 0.02 9. OTS-treated zinc oxide (manufactured by Teika Co., Ltd.: MZX-508OTS) 15 10. Cetostearyl alcohol 0.3 11. Sorbitan sesquioleate 0.3 12. MDT resin (30% ISD solution) 2 13. Drometrizole trisiloxane 3 14. Neopentyl glycol dicaprate 5 15. Alkyl benzoate (C12-15) 5 16. Tri(caprylic / capric acid)glyceryl 5 17. Dicaprylyl carbonate 8 18. 2,4-bis[{4-(2-ethylhexyloxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-(1,3,5) Triazine 3 19. Diethylamino hydroxybenzoyl hexyl benzoate 3 20. (Dimethicone / vinyl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-15) 2 21. (Acrylates / beheneth-25 methacrylate) copolymer (Lubrizol Corporation: NOVETHIX L-10 POLYMER) 0.08 22. (Hydroxyethyl acrylate / sodium acryloyldimethyl taurate) copolymer (SEPPIC Corporation: SIMULGEL FL) 0.4 23. Triethanolamine 0.9 24. Purified water remaining 25. Ascorbic acid 2-glucoside 0.3 26. Fragrance 0.1 27. Cellulose 1 28. Hollow silica 0.7 29. Titanium dioxide-coated mica 1 30. Phenoxyethanol 0.1 Total 100 <Evaluation> The oil-in-water primer produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0093] [Example 39] Oil-in-Water Liquid Foundation <Preparation of Cosmetic Composition> A. Dissolve 1 to 12 at 80°C and mix uniformly. B. Mix 13 to 20 uniformly at 75°C. C. Add A to B and emulsify, then cool to 40°C. D. Mix 21 to 33 uniformly. E. Add D to C and mix, then fill into a container to obtain an oil-in-water liquid foundation. Composition % 1. Stearic acid 1.5 2. Glyceryl stearate 0.5 3. Cetearyl alcohol 0.5 4. Behenyl alcohol 0.5 5. PEG-10 Hydrogenated Castor Oil 0.1 6. PRG-60 Hydrogenated Castor Oil 0.3 7. Polysorbate 80 0.2 8. Ethylhexyl Methoxycinnamate 6 9. Bis-ethylhexyloxyphenol methoxyphenyl triazine 1 10. PG dicaprate 3 11. Isotridecyl isinonoate 3 12. MDT resin (30% ISD solution) 10 13. Triethanolamine 0.8 14. Purified water 20 15.13-Butylene glycol 4 16. Ethanol 1.5 17. Dipropylene glycol 2 18. Carbomer 0.09 19. Xanthan gum 0.05 20. Purified water remaining 21. 1. Silicone-treated pigment-grade titanium dioxide (average particle size 0.27 μm (aluminum hydroxide coated)) 9 22. Silicone-treated fine particle titanium dioxide (average particle size 35 nm) 4 23. Silicone-treated red iron oxide (short diameter: average particle size 0.07 μm) 0.3 24. Silicone-treated yellow iron oxide (short diameter: average particle size 0.09 μm) 1.2 25. Silicone-treated black iron oxide (average particle size 0.3 μm) 0.1 26. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (particle size 5 μm) 1 27. Lecithin-treated talc (average particle size 5 μm) 5 28. PEG-60 hydrogenated castor oil 0.5 29. PEG-10 hydrogenated castor oil 0.35 30. Hydrogenated lecithin 0.1 31. 1,3-butylene glycol 11 32. Triceteareth-4 phosphate 0.1 33. Purified water 1.5 Total 100 <Evaluation> The oil-in-water liquid foundation produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0094] [Example 40] Oil-in-Water Foundation <Preparation of Cosmetic Composition> A: Mix 20% of 6-8 and 9 and 10, and disperse in a three-roll mill. B: Mix 2-5, part of 11, 12, 21, 24, and 25 with the remainder of 6-8, and dissolve uniformly at 70°C. C: Mix the remainder of 11 and 15-20 and 27, and disperse in a three-roll mill. D: Disperse 1, 13, 14, 28-31, and part of 26 uniformly at 70°C. E: Add A to B and disperse uniformly at 70°C. F: Add C to D, then add E and emulsify at 70°C. G: Cool F to 25°C, add the remainder of 26 and 22 and 23, fill into a container to obtain an oil-in-water foundation. Composition % 1. Crystalline cellulose (manufactured by Daiichi Kogyo Seiyaku Co., Ltd.: Reocrysta C-2EP) 0.2 2. Ethylhexyl methoxycinnamate 7 3. Diethylamino hydroxybenzoyl hexyl benzoate 2 4. 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-Triazine 2 5. Polysilicone-15 (DSM: PARSOL SLX) 1 6. MDT resin (30% ISD solution) 2 7. Isododecane 3 8. 2-Cetyl ethylhexanoate 5 9. Polyhydroxystearic acid 0.25 10. Triethoxyoctylsilane-treated zinc oxide (Teika: MZX-304OTS) 10 11. PEG-10 hydrogenated castor oil (HLB: 6.5) (Nikko Chemicals: Nikko HCO-10) 0.15 12. Polyglyceryl-10 stearate (HLB: 12.0) (Nikko Chemicals: NIKKOL Decaglyn 1-SV) 0.5 13. 14. (Sodium acrylate / sodium acryloyldimethyl taurate) copolymer (SEPPIC: SIMULGEL EG) 0.3 15. (Acrylates / beheneth-25 methacrylate) copolymer (LUBRIZOL: NOVETHIX L-10) 0.2 16. Sorbitan sesquioleate (HLB: 3.7) (Kao Corporation: Rheodol AO-15V) 0.05 17. Silica-treated red iron oxide (Nikki Shokubai Kasei Co., Ltd.: Symphorite RW-TE) 2 18. Silica-treated yellow iron oxide (Nikki Shokubai Kasei Co., Ltd.: Symphorite YW-TE) 2 19. Silica-treated black iron oxide (Nikki Shokubai Kasei Co., Ltd.: Symphorite BW-TE) 1 20. Silicone-treated sericite 2 Silica-treated titanium oxide (TiO, ２Silica treatment of MP-1133 (manufactured by Teika Co., Ltd.) (surface treatment 3.0%) 3 21. Inulin stearate (manufactured by Chiba Flour Milling Co., Ltd.: Leopal ISK2) 1 22. Talc 2 23. Silica (manufactured by Suzuki Oil & Fat Industry Co., Ltd.: Godball D11-796C) 1 24. Olive oil 0.1 25. Diethylhexyl succinate (manufactured by Croda Co., Ltd.: CRODAMOL OSU) 1 26. Purified water remaining 27. 1,3-Butylene glycol 2 28. Ethanol 10 29. Hyaluronic acid 0.15 30. Trehalose 0.05 31. Artemisia capillaris extract 0.01 Total 100 <Evaluation> The oil-in-water foundation produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0095] [Example 41] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 6 uniformly using a roller. B: Mix 17 to 19 uniformly. C: Mix A and 7 to 16 uniformly using a disperser. D: Add B to C, emulsify at 25°C, stir with a disperser, fill into a container to obtain a water-in-oil primer.Composition % 1. Dimethicone / silica-treated fine particle titanium dioxide 3 2. Silicone-treated titanium dioxide (Manufactured by Miyoshi Chemical Industries Co., Ltd.: SA-Titanium MP-1133) 3 3. Silicone-treated fine particle zinc oxide (Manufactured by Teika Co., Ltd.: MZY-500S) 5 4. Silicone-treated iron oxide (A mixture of red iron oxide, yellow iron oxide, and black iron oxide, surface-treated with 5% dimethicone, in a mass ratio of 3:5:1) 1 5. Zinc oxide / seric mica / hydroxyapatite composite powder (Manufactured by Miyoshi Chemical Industries Co., Ltd.: MIYOSTAY Z20) 5 6. (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer 0.5 7. Ethylhexyl methoxycinnamate 5 8. PEG-9 dimethicone (Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6019) 2 9. 10. Silicone-alkyl branched polyether modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 2 11. MDT resin (30% ISD solution) 5 12. Dimethicone (2CS) 10 13. Isododecane 5 14. Spherical silica (anhydrous silicic acid) (Suzuki Oil & Fat Industry Co., Ltd.: Godball E-90C) 3 15. Approximately spherical corn starch (Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 3 16. Spherical biodegradable polyamide (average particle size: 20 μm, oil absorption: 70 ml / 100 g) 3 17. Fine particle titanium dioxide / corn starch composite powder (Hayate Material Co., Ltd.: MTXO70-CS) 3 18. Purified water remaining 5 19. Ethanol 5 Methylenebisbenzotriazolyltetramethylbutylphenol 2 Total 100 <Evaluation> The water-in-oil primer produced as described above exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0096] [Example 42] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 6 uniformly using a roller. B: Mix 17 to 19 uniformly. C: Mix A and 7 to 16 uniformly using a disperser. D: Add B to C, emulsify at 25°C, stir with a disperser, fill into a container to obtain a water-in-oil primer.Composition % 1. Stearoyl glutamate disodium-treated fine particle titanium dioxide 3 2. Stearoyl glutamate disodium-treated titanium dioxide 3 3. Stearoyl glutamate disodium-treated fine particle zinc oxide 5 4. Stearoyl glutamate disodium-treated iron oxide (a mixture of red iron oxide, yellow iron oxide, and black iron oxide surface-treated with 2% stearoyl glutamate in a mass ratio of 3:6:1) 0.01 5. Methyl trimethicone 5 6. (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer 0.5 7. Ethylhexyl methoxycinnamate 5 8. PEG-9 dimethicone 2 9. Lauryl PEG-9 polydimethylsiloxyethyl dimethicone 2 10. MDT resin (30% ISD solution) 5 11. 12. Methyltrimethicone 5 13. Isododecane 10 14. Spherical silica (5 μm) 1.5 15. Approximately spherical corn starch (manufactured by Nippon Corn Starch Co., Ltd.: Pearl Starch (H)) 1.5 16. Biodegradable spherical polylactic acid (average particle size: 20 μm, oil absorption: 70 ml / 100 g) 1.5 17. Fine particle titanium dioxide / corn starch composite powder (manufactured by Hayate Material Co., Ltd.: MTXO70-CS) 1.5 18. Purified water remaining 19. Ethanol 5 10. Methylenebisbenzotriazolyltetramethylbutylphenol 2 Total 100 <Evaluation> The water-in-oil type primer produced by the above method exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0097] [Example 43] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 8. B: Mix 9 to 21 in a disper. (Use 11 which has been swollen in 12 beforehand) C: Add A to B and emulsify. D: Add 22 to 31 to C and mix, then fill into a container to obtain a water-in-oil primer. Composition % 1. Purified water residue 2. Disodium EDTA 0.1 3. Monohydrogen phosphate 0.1 4. Dihydrogen phosphate 0.1 5. Sodium chloride 0.5 6. Sodium pyrosulfite 0.02 7.13-Butylene Glycol 1 8. Tranexamic Acid 4 9. Titanium Dioxide 1 10. Zinc Oxide 3 11. Dimethyldistearylammonium Hectorite 0.3 12. Methyl Trimethicone 3 13. 2-Ethylhexyl Paramethoxycinnamate 5 14. MDT Resin (30% ISD Solution) 3 15. Methylpolysiloxane (10CS) 2 16. Methylphenylpolysiloxane 1 17. PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028P) 3 18. Polyhydroxystearic Acid 0.5 19. Sorbitan Sesquioleate (Kao Corporation: Leodol AO-15V) 0.5 20. 21. Sorbitan sesquiisostearate (manufactured by Nisshin Oillio Group: Cosmoll 182V) 0.5 22. Stearyl glycyrrhetinate 1.5 23. Ethanol 5 24. Farnesol 0.02 25. Anisic alcohol 0.02 26. Eugenol 0.02 27. Citronellol 0.02 28. α-Pinene 0.02 29. 1-Hexen-1-ol 0.02 20. Linalool 0.02 31. Cedryl acetate 0.02 Iso E Super 0.02 Total 100 <Evaluation> The water-in-oil primer produced using the above method exhibited excellent coating uniformity and secondary adhesion reduction effects.

[0098] [Example 44] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 8. B: Mix 9 to 21 in a disper. (Use 11 which has been swollen in 12 beforehand) C: Add A to B and emulsify. D: Add 22 to 31 to C and mix, then fill into a container to obtain a water-in-oil primer. Composition % 1. Purified water residue 2. Disodium edetate 0.1 3. Monohydrogen phosphate 0.1 4. Dihydrogen phosphate 0.1 5. Sodium chloride 0.5 6. Sodium pyrosulfite 0.02 7.13-Butylene Glycol 1 8. Tranexamic Acid 4 9. Titanium Dioxide 1 10. Zinc Oxide 3 11. Dimethyldistearylammonium Hectorite 0.3 12. Methyl Trimethicone 3 13. 2-Ethylhexyl Paramethoxycinnamate 5 14. MDT Resin (30% ISD Solution) 3 15. Methylpolysiloxane (10CS) 2 16. Methylphenylpolysiloxane 1 17. PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028P) 3 18. Polyhydroxystearic Acid 0.5 19. Sorbitan Sesquioleate (Kao Corporation: Leodol AO-15V) 0.5 20. 21. Sorbitan sesquiisostearate (manufactured by Nisshin Oillio Group: Cosmoll 182V) 0.5 22. Stearyl glycyrrhetinate 1.5 23. Ethanol 5 24. Sandalore 0.02 25. Ambroxan 0.02 26. γ-Terpinene 0.02 27. Ambrettolide 0.02 28. β-ionone 0.02 29. Borneol 0.02 30. Isobutylquinoline 0.02 Citral 0.02 31. Guaical 0.02 Total 100 <Evaluation> The water-in-oil primer produced as described above exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0099] [Example 45] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 8. B: Mix 9 to 21 in a disper. (Use 11 which has been swollen in 12 beforehand) C: Add A to B and emulsify. D: Add 22 to 33 to C and mix, then fill into a container to obtain a water-in-oil primer. Composition % 1. Purified water residue 2. Disodium edetate 0.1 3. Monohydrogen phosphate 0.1 4. Dihydrogen phosphate 0.1 5. Sodium chloride 0.5 6. Sodium pyrosulfite 0.02 7. 1,3-Butylene glycol 1 8. Tranexamic acid 4 9. Titanium dioxide 1 10. Zinc oxide 3 11. Dimethyldistearylammonium hectorite 0.3 12. Methyl trimethicone 3 13. 14. 2-ethylhexyl paramethoxycinnamate 5 15. MDT resin (30% ISD solution) 3 16. Methylpolysiloxane (10CS) 2 17. Methylphenylpolysiloxane 1 18. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028P) 3 19. Polyhydroxystearic acid 0.5 10. Sorbitan sesquioleate (Kao Corporation: Leodol AO-15V) 0.5 21. Sorbitan sesquiisostearate (Nisshin Oillio Group Co., Ltd.: Cosmoll 182V) 0.5 22. Stearyl glycyrrhetinate 1.5 23. Ethanol 5 24. Patchouli alcohol 0.0224. Cedrol 0.02 25. Ethyl Vanillin 0.02 26. Maltol 0.02 27. Linalyl Acetate 0.02 28. α-Terpineol 0.02 29. Benzyl Benzoate 0.02 30. Damascenone 0.02 31. Anisaldehyde 0.02 32. Benzaldehyde 0.02 33. Magnolan 0.02 Total 100 <Evaluation> The water-in-oil primer produced using the above method exhibited excellent coating uniformity and secondary adhesion-free effect.

[0100] [Example 46] Water-in-oil primer <Preparation of cosmetic> A: Mix 1 to 8. B: Mix 9 to 21 in a disper. (Use 11 which has been swollen in 12 beforehand) C: Add A to B and emulsify. D: Add 22 to 33 to C and mix, then fill into a container to obtain a water-in-oil primer. Composition % 1. Purified water residue 2. Disodium edetate 0.1 3. Monohydrogen phosphate 0.1 4. Dihydrogen phosphate 0.1 5. Sodium chloride 0.5 6. Sodium pyrosulfite 0.02 7. 1,3-Butylene glycol 1 8. Tranexamic acid 4 9. Titanium dioxide 1 10. Zinc oxide 3 11. Dimethyldistearylammonium hectorite 0.3 12. Methyl trimethicone 3 13. 20. 21. 2-ethylhexyl paramethoxycinnamate 5 14. MDT resin (30% ISD solution) 3 15. 2 methylpolysiloxane (10CS) 2 16. 17. 18. 18. 19. PEG-9 polydimethylsiloxyethyl dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6028P) 3 19. 10. 11. 12. 13. 14. 15. 16. 17. 18. 19. 19. 10. 10. 10. 11. 12. 11. 12. 13. 14. 15. 11. 12. 11. 12. 13. 14. 15. 11. 12. 11. 12. 12. 13. 14. 15. 11. 12. 11. 12. 11. 12. 12. 11. 12. 13. 11. 121. 12. 11. 11. 12. 11. 11. 11. 12. 11. Phenylacetaldehyde Dimethyl Acetal0.02 25. Nerol 0.02 26. Dimethylbenzylcarbinol 0.02 27. Bacdanol 0.02 28. Methyl anthranilate 0.02 29. Muscenone 0.02 30. Benzyl acetate 0.02 31. Phenyleethyl alcohol 0.02 32. Phenyleethyl acetate 0.02 33. Heliotropin 0.02 Total 100 <Evaluation> The water-in-oil primer produced as described above exhibited excellent coating uniformity and secondary adhesion-free effect.

[0101] [Example 47] Water-in-oil cream foundation <Preparation of cosmetic> A: Disperse 9-12 in a three-roll mill. B: Mix 3-5 uniformly, add 1, 2, 6-8 and mix uniformly. C: Mix 13-17 uniformly. D: Add C to B and emulsify, add A to this, fill into a container to obtain a water-in-oil cream foundation. Composition % 1. Alkyl-modified / crosslinked polyether-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-330) 3.5 2. Alkyl-modified / crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-41A) 6 3. Alkyl-branched polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6048) 3 4. Disteardimonium hectorite 1.2 5. Decamethylcyclopentasiloxane 20 6. 13. 2-ethylhexyl paramethoxycinnamate 7.5 7. MDT resin (30% ISD solution) 2 8. Silicone composite powder (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-300) 2 9. Ethylhexyl palmitate 7 10. Acrylic-silicone graft copolymer (manufactured by Shin-Etsu Chemical Co., Ltd.: KP-578) 0.2 11. Silicone-treated titanium dioxide (manufactured by Shin-Etsu Chemical Co., Ltd.: KTP-09W) 8.5 12. Silicone-treated iron oxide (manufactured by Shin-Etsu Chemical Co., Ltd.: KTP-09Y, R, B) 0.01 13. 1,3-butylene glycol 5 14. Methyl parahydroxybenzoate 0.15 15. Sodium citrate 0.2 16. Sodium chloride 0.5 17. Total amount of purified water remaining: 100 <Evaluation> The water-in-oil cream foundation produced as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0102] [Example 48] Water-in-oil foundation <Preparation of cosmetic> A: Disperse 7-13 in a disperser. B: Mix 4-6 uniformly at 25°C, add 1-3 and mix uniformly. C: Mix 14-19 uniformly. D: Add C to B and emulsify, add A to this, fill into a container and obtain a water-in-oil foundation.Composition % 1. Crosslinked polyether-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-210) 3.5 2. Phenyle-modified, crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-18A) 5 3. Diphenylsiloxyphenyl trimethicone (KF-56A) 9 4. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 3 5. Disteardimonium hectorite 0.8 6. Decamethylcyclopentasiloxane 15 7. Isopropyl myristate 6 8. MDT resin (30% ISD solution) 1 9. Metal soap-treated fine particle titanium dioxide (average primary particle size: 20 nm) 5 10. Alkylsilane-treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment) 6.5 11. Alkylsilane-treated yellow iron oxide (Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment) 0.01 12. Alkylsilane-treated red iron oxide (Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment) 0.01 13. Alkylsilane-treated black iron oxide (Shin-Etsu Chemical Co., Ltd.: AES-3083 treatment) 0.01 14. Glycerin 2 15. Dipropylene glycol 3 16. Phenoxyethanol 0.2 17. Sodium citrate 0.2 18. Sodium chloride 0.5 19. Total amount of purified water remaining 100 <Evaluation> The water-in-oil foundation produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0103] [Example 49] Water-in-oil foundation <Preparation of cosmetic> A: Mix 2 to 9 uniformly. B: Mix 10 to 13 uniformly using a high-pressure mixer. C: Mix 14 to 17 uniformly. D: Add C to A and emulsify, then add B and 1 and mix, and fill into a container to obtain water-in-oil foundation.Composition % 1. MDT resin (30% ISD solution) 3 2. Crosslinked polyglycerin-modified silicone mixture (Shin-Etsu Chemical Co., Ltd.: KSG-830) 4 3. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 3 4. Silicone-alkyl branched polyglycerin-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6105) 3 5. Phenyl-modified, partially crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-18A) 2 6. Ethyl methicone (Shin-Etsu Chemical Co., Ltd.: KF-4422) Remainder 7. Ethylhexyl salicylate 5 8. Bis-ethylhexyloxyphenol methoxyphenyl triazine 1 9. Disteardimonium hectorite 1.2 10. 11. Isononyl isononanoate 5.7 12. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-105) 1 13. Acrylic silicone (Shin-Etsu Chemical Co., Ltd.: KP-578) 0.2 14. Silicone treated pigment (Shin-Etsu Chemical Co., Ltd.: KTP-09W, Y, R, B) 10 15. 1,3-Butylene glycol 8 16. Sodium citrate 0.2 17. Sodium chloride 0.5 18. Water 44.9 Total 100 <Evaluation> The water-in-oil foundation produced by the above method exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0104] [Example 50] Water-in-oil Foundation <Preparation of Cosmetic Composition> A: Mix 1-6 uniformly using a roller. B: Mix 20-22 uniformly. C: Mix 23-32 uniformly. D: Mix A, B, and 7-19 uniformly using a disperser. E: Add C to D, emulsify at 25°C, stir with a disperser, and fill into a container to obtain a water-in-oil foundation. Composition % 1. Diglyceryl tetraisostearate treated titanium dioxide 5 2. Lecithin treated titanium dioxide 5 3. Sodium dilauroyl glutamate lysine treated iron oxide 2 4. Methyl trimethicone 3 5. (Acrylates / Ethylhexyl acrylate / Dimethicone methacrylate) copolymer (Shin-Etsu Chemical Co., Ltd.: KP-578P) 0.5 6. PEG-9 polydimethylsiloxyethyl dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6028P) 0.5 7. MDT resin (30% ISD solution) 5 8. Dimethicone (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.: BELSIL DM 1 PLUS) 10 9. Trimethylsiloxysilicate 5 10. Isododecane 5 11. PEG-9 polydimethylsiloxyethyl dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6028) 1 12. Ethylhexyl methoxycinnamate 6 13. Diethylamino hydroxybenzoyl hexyl benzoate 1 14. Tocopherol 0.1 15. Fragrance 0.2 16. Biodegradable spherical polylactic acid (average particle size: 20 μm, oil absorption capacity: 70 ml / 100 g) 1 17. Spherical biodegradable polyamide (average particle size: 5 μm, oil absorption capacity: 100 ml / 100 g) 1 18. Spherical silica (anhydrous silicic acid) (HCS160M5 (manufactured by JGC Catalysts & Chemicals Co., Ltd.)) 1 19. Olive fruit oil 120. Disteardimonium hectorite (Elementis: BENTON 38V BC) 1 21. Isododecane 5 22. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 1 23. Purified water remaining 24. Sodium chloride 0.1 25. Phenoxyethanol 0.2 26. Niacinamide 2 27. Ethanol 5 28. Succinic acid 0.5 29. Disodium succinate 0.25 30. BHT 0.05 31. EDTA-2Na 0.05 32. Sodium pyrosulfite 0.05 Total 100 <Evaluation> The water-in-oil foundation produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0105] [Example 51] Water-in-oil Foundation <Preparation of Cosmetic Composition> A. Mix 1 to 9 uniformly. B. Dissolve and mix 18 to 20 at 80°C, cool to 25°C, then add A and 10 to 17, 21 to 25 and disperse. C. Mix 26 to 29 uniformly. D. Add C to B and emulsify, then fill into a container to obtain a water-in-oil foundation. Composition % 1. Triethoxycaprylylsilane treated fine particle titanium dioxide (average particle size 35 nm) 4 2. Triethoxycaprylylsilane silica coated fine particle zinc oxide (average particle size 25 nm) 2 3. Triethoxycaprylylsilane titanium dioxide (average particle size 0.25 μm) 10 4. Triethoxycaprylylsilane red iron oxide (short diameter: average particle size 0.07 μm) 0.3 5. Triethoxycaprylylsilane yellow iron oxide (short diameter: average particle size 0.09 μm) 1.2 6. Triethoxycaprylylsilane black iron oxide (average particle size 0.3 μm) 0.1 7. Triethoxycaprylylsilane mica (average particle size 5-15 μm) 2 8. (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer 1 9. MDT resin (30% ISD solution) 10 10. Dimethylpolysiloxane (2CS) 5 11. Isotridecyl isononanoate 3 12. Diisostearyl malate 1 13. Trimethylsiloxysilicate 2 14. Disteardimonium hectorite 1 15. Sorbitan sesquiisostearate (manufactured by Nisshin Oillio Group: Cosmoll 182V) 0.516. Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 3 17. PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 3 18. 2-Ethylhexyl Paramethoxycinnamate 5 19. Diethylamino Hydroxybenzoyl Hexyl Benzoate 2.5 20. Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine 0.5 21. Polymethylsilsesquioxane (average particle size 5 μm) 3 22. Spherical Cellulose (average particle size 5 μm) 2 23. Spherical Silica (average particle size 5 μm) 1 24. Boron Nitride (Mizushima Iron Alloy Co., Ltd.: SHP-6) 2 25. Hydrogenated Lecithin 0.1 26. Ethanol 5 27. 1,3-Butylene glycol 1 28. Glycerin 1 29. Total amount of purified water remaining 100 <Evaluation> The water-in-oil foundation produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0106] [Example 52] Oil-in-water primer (aerosol) <Preparation of cosmetic> A. Mix 1 to 5 uniformly. B. Mix 6 to 7 uniformly. C. Disperse 8 to 11 uniformly. D. Add B to A and emulsify at 25°C, then add C and 12 and 13 and mix uniformly to obtain the stock solution. E. Fill 6 g of the stock solution obtained in D into an aluminum pressure vessel, then attach the valve, and fill the pressure vessel with 0.15 LPG 6 g through the valve to obtain the oil-in-water primer (aerosol). Composition % 1. Carboxyvinyl polymer 0.3 2. Hydroxypropyl methylcellulose 0.3 3. Poloxamer 407 / (PPG-12 / SMDI) copolymer mixture (manufactured by Polymerexpert: EXPERTGEL EG412) 0.1 4. 1,3-Butylene glycol 0.1 5. Ethanol 20 6. Polyoxyethylene hydrogenated castor oil isostearate 0.1 7. MDT resin (30% ISD solution) 5 8. Polyoxyethylene sorbitan monooleate (20 E.O.) 0.1 9. Glycerin 1 10. Silica (average particle size 3 μm) 0.5 11. Mica (average particle size 1 μm) 1 12. Triethanolamine 0.3 13. Total amount of purified water remaining: 100 <Evaluation> The oil-in-water primer (aerosol) produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0107] [Example 53] Oil-in-Water Liquid Foundation (Aerosol) <Preparation of Cosmetic Composition> A. Dissolve 1 to 12 at 80°C and mix uniformly. B. Mix 13 to 20 uniformly at 75°C. C. Add A to B and emulsify, then cool to 40°C. D. Mix 21 to 33 uniformly. E. Add D to C and mix to obtain the stock solution. F. Fill 6 g of the stock solution obtained in E into an aluminum pressure vessel, then attach the valve, and fill the pressure vessel with 0.15 LPG 6 g through the valve to obtain the oil-in-water liquid foundation (aerosol). Composition % 1. Stearic acid 1.5 2. Glyceryl stearate 0.5 3. Cetearyl alcohol 0.5 4. Behenyl alcohol 0.5 5. PEG-10 hydrogenated castor oil 0.1 6. PEG-60 Hydrogenated Castor Oil 0.3 7. Polysorbate 80 0.2 8. Ethylhexyl Methoxycinnamate 6 9. Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine 1 10. Propylene Glycol Dicaprate 3 11. Isotridecyl Isononanoate 3 12. MDT Resin (30% ISD Solution) 8 13. Triethanolamine 0.8 14. Purified Water 20 15.13-Butylene glycol 4 16. Ethanol 1.5 17. Dipropylene glycol 2 18. Carbomer 0.09 19. Xanthan gum 0.05 20. Purified water remaining 21. Silicone-treated pigment-grade titanium dioxide (average particle size 0.27 μm) 9 22. Silicone-treated fine particle titanium dioxide (average particle size 35 nm) 4 23. Silicone-treated red iron oxide (short diameter: average particle size 0.07 μm) 0.3 24. Silicone-treated yellow iron oxide (short diameter: average particle size 0.09 μm) 1.2 25. Silicone-treated black iron oxide (average particle size 0.3 μm) 0.1 26. (Vinyl dimethicone / methicone silsesquioxane) crosspolymer (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-100) 1 27. Lecithin-treated mica (average particle size 5 μm) 5 28. PEG-60 hydrogenated castor oil 0.5 29. PEG-10 hydrogenated castor oil 0.35 30. Hydrogenated lecithin 0.1 31. 1,3-butylene glycol 11 32. Triceteareth-4 phosphate 0.1 33. Purified water 1.5 Total 100 <Evaluation> The oil-in-water liquid foundation (aerosol) produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0108] [Example 54] Water-in-oil primer (aerosol) <Preparation of cosmetic> A. Mix 1 to 9 uniformly. B. Dissolve and mix 18 to 22 at 80°C, cool to 25°C, then add A and 10 to 17, 23 to 27 and disperse. C. Mix 28 to 32 uniformly. D. Add C to B and emulsify to obtain the stock solution. E. Fill 6 g of the stock solution obtained in D into an aluminum pressure vessel, then fix the valve, and fill the pressure vessel with 0.15 LPG 6 g through the valve to obtain the water-in-oil primer (aerosol). Composition % 1. Stearoyl glutamate disodium treated fine particle titanium dioxide (average particle size 35 nm) 2 2. Stearoyl glutamate disodium treated fine particle zinc oxide (average particle size 25 nm) 2 3. 1. Stearoyl glutamate disodium treated titanium dioxide (average particle size 0.27 μm) 2 4. Stearoyl glutamate disodium treated red iron oxide (short diameter: average particle size 0.07 μm) 0.01 5. Stearoyl glutamate disodium treated yellow iron oxide (short diameter: average particle size 0.09 μm) 0.01 6. Stearoyl glutamate disodium treated black iron oxide (average particle size 0.3 μm) 0.01 7. Stearoyl glutamate disodium treated mica (average particle size 20 μm) 2 8. (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer 1 9. MDT resin (30% ISD solution) 15 10. Dimethylpolysiloxane (6CS) 5 11. 12. Isotridecyl isononanoate 3 13. Diisostearyl malate 1 14. Trimethylsiloxysilicate 2 15. Disteardimonium hectorite 1 16. Sorbitan isostearate(Manufactured by Nippon Surfactant Industry Co., Ltd.: NIKKOL SI-10RV) 0.5 16. Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6038) 3 17. PEG-9 Polydimethylsiloxyethyl Dimethicone (Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6028) 1 18. 2-Ethylhexyl Paramethoxycinnamate 5 19. Diethylamino Hydroxybenzoyl Hexyl Benzoate 2.5 20. Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine 0.5 21. Stearyl Dimethicone (Melting point 40℃) 1 22. Dextrin Palmitate 0.1 23. Polymethylsilsesquioxane (Average particle size 5μm) 1 24. Spherical cellulose (average particle size 5 μm) 1 25. Silica (average particle size 5 μm) 1 26. Boron nitride (average particle size 6 μm) 2 27. Polyethylene (average particle size 10 μm) 1 28. Ethanol 5 29. 1,3-Butylene glycol 1 30. Glycerin 1 31. Hydroxypropyl methylcellulose 0.1 32. Total amount of purified water remaining 100 <Evaluation> The water-in-oil primer (aerosol) produced as described above exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0109] [Example 55] Water-in-oil Foundation (Aerosol) <Preparation of Cosmetic Composition> A. Mix 1 to 9 uniformly. B. Dissolve and mix 18 to 20 at 80°C, cool to 25°C, then add A and 10 to 17, 21 to 26 and disperse. C. Mix 27 to 30 uniformly. D. Add C to B and emulsify to obtain the stock solution. E. Fill 6 g of the stock solution obtained in D into an aluminum pressure vessel, then fix the valve, and fill the pressure vessel with 0.15 LPG 6 g through the valve to obtain the water-in-oil foundation (aerosol). Composition % 1. Silicone-treated fine particle titanium dioxide (average particle size 35 nm) 4 2. Silicone-treated silica-coated fine particle zinc oxide (average particle size 25 nm) 2 3. Silicone-treated titanium dioxide (average particle size 0.27 μm (aluminum hydroxide coated)) 10 4. 1. Silicone-treated red iron oxide (short diameter: average particle size 0.07 μm) 0.3 5. Silicone-treated yellow iron oxide (short diameter: average particle size 0.09 μm) 1.2 6. Silicone-treated black iron oxide (average particle size 0.3 μm) 0.1 7. Silicone-treated mica (average particle size 5 μm) 2 8. (Acrylates / ethylhexyl acrylate / dimethicone methacrylate) copolymer 1 9. MDT resin (30% ISD solution) 15 10. Dimethylpolysiloxane (2CS) 5 11. Isotridecyl isononanoate 3 12. Diisostearyl malate 1 13. Trimethylsiloxysilicate 2 14. Disteardimonium hectorite 1 15. 16. Sorbitan sesquiisostearate (manufactured by Nisshin Oillio Group: Cosmoll 182V) 0.5 17. Lauryl PEG-9 polydimethylsiloxyethyl dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6028) 3 18. PEG-9 polydimethylsiloxyethyl dimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6038) 318. 2-Ethylhexyl paramethoxycinnamate 5 19. Diethylaminohydroxybenzoyl hexyl benzoate 2.5 20. Bis-ethylhexyloxyphenol methoxyphenyl triazine 0.5 21. (Dimethicone / vinyl dimethicone) crosspolymer 3 22. Polymethylsilsesquioxane (average particle size 5 μm) 3 23. Spherical cellulose (average particle size 5 μm) 2 24. Silica (average particle size 5 μm) 1 25. Boron nitride (Mizushima Iron Alloy Co., Ltd.: SHP-3) 2 26. Hydrogenated lecithin 0.1 27. Ethanol 5 28. 1,3-Butylene glycol 1 29. Glycerin 1 30. Total amount of purified water remaining: 100 <Evaluation> The water-in-oil foundation (aerosol) manufactured as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0110] [Example 56] Oil-in-water cushion base <Preparation of cosmetic> A. Disperse 1 to 3 uniformly at 70°C. B. Dissolve and mix 4 to 6 uniformly, then add 7 to 12 and disperse. C. Disperse 13 to 19 uniformly. D. Heat B to 70°C, add A and emulsify and mix at 70°C. E. After cooling D to 25°C, add C and 20 to 22 and mix uniformly. F. Fill a container supporting polyether-impregnated foam with E to obtain an oil-in-water cushion base.Composition % 1. MDT resin (30% ISD solution) 4 2. Dimethicone / (Dimethicone / Vinyl Dimethicone) Crosspolymer Mixture 10 3. 2-Ethylhexyl Paramethoxycinnamate 4 4. Hydrogenated Soybean Phospholipid 1 5. Stearoyl Glutamate 1.1 6. 1,3-Butylene Glycol 5 7. Acrylic Acid / Alkyl Methacrylate Copolymer 0.3 8. Sodium Acrylate / Sodium Acryloyldimethyl Taurate Copolymer / Isohexadecane / Polysorbate 80 Mixture (SEPPIC: SIMULGEL EG QD) 1 9. Ethanol / Polyquaternium-104 Mixture (Shin-Etsu Chemical Co., Ltd.: X-22-8341C) 2 10. Sodium Hydroxide 0.2 11. 12. Ethanol 10 13. Purified water remaining 14. Polyoxyethylene sorbitan monooleate (20 E.O.) 0.1 15. Polyoxyethylene cetyl ether phosphate 0.2 16. Glycerin 1 17. Silicone-treated mica (average particle size 9 μm) 0.5 18. Titanium dioxide (average particle size 0.27 μm) 0.5 19. Red iron oxide (short diameter: average particle size 0.07 μm) 0.1 20. Yellow iron oxide (short diameter: average particle size 0.07 μm) 0.1 21. Silica (average particle size 4 μm) 5 22. Polymethyl methacrylate (average particle size 10 μm) 10 Polymethylsilsesquioxane (average particle size 6 μm) (Momentive Co., Ltd.: TOSPEARL 3000A) 5 Total 100 <Evaluation> The oil-in-water cushion substrate produced as described above exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0111] [Example 57] Oil-in-Water Cushion Foundation <Preparation of Cosmetic Composition> A. Disperse 1 to 7 uniformly using a three-roller. B. Heat and dissolve 15 to 21 while uniformly mixing, then add A and mix. C. Heat and dissolve 8 to 12 uniformly at 70°C. D. Heat and dissolve 13 and 14 uniformly at 70°C, add to C, emulsify at 70°C, and cool to 40°C while stirring. E. Add D to B and mix, then degas after cooling to 25°C. F. After dissolving E at 80°C, fill a container carrying impregnated foam at 60°C, and cool to 25°C to obtain an oil-in-water cushion foundation.Composition % 1. Lecithin-treated mica (average particle size 5 μm) 3 2. Stearoyl glutamate disodium-treated pigment-grade titanium dioxide (average particle size 0.27 μm) 9 3. Stearoyl glutamate disodium-treated fine particle titanium dioxide (average particle size 35 nm) 4 4. Stearoyl glutamate disodium-treated red iron oxide (short diameter: average particle size 0.07 μm) 0.3 5. Stearoyl glutamate disodium-treated yellow iron oxide (short diameter: average particle size 0.09 μm) 1.2 6. Stearoyl glutamate disodium-treated black iron oxide (average particle size 0.3 μm) 0.1 7. 1,3-Butylene glycol 8 8. MDT resin (30% ISD solution) 5 9. Ethylhexyl methoxycinnamate 3 10. PG dicaprate 1.5 11. Behenyl alcohol 0.3 12. Hydrogenated lecithin 1 13. 1,3-Butylene glycol 5 14. Purified water 20 15. Fragrance 0.01 16. Methyl parahydroxybenzoate 0.1 17. Dipropylene glycol 10 18. Agar 0.5 19. Hydrophobic modified polyether urethane (ADEKA: Adekanol GT-700) 0.5 20. (Acrylates / alkyl acrylates) copolymer 0.25 21. Total remaining purified water 100 <Evaluation> The oil-in-water cushion foundation produced as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0112] [Example 58] Water-in-oil cushion foundation <Preparation of cosmetic> A. Mix 1 to 9 uniformly. B. Dissolve and mix 18 to 22 at 80°C, and after cooling to room temperature, add A and 10 to 17, 23 to 27 and disperse. C. Mix 28 to 32 uniformly. D. Add C to B and emulsify to obtain a water-in-oil base. E. Fill the bulk obtained in D into a polyether-impregnated foam-supported container to obtain a water-in-oil cushion foundation. Composition % 1. Triethoxycaprylylsilane-treated fine particle titanium dioxide (average particle size 35 nm) 2 2. Triethoxycaprylylsilane-treated fine particle zinc oxide (average particle size 50 nm) 2 3. Triethoxycaprylylsilane-treated titanium dioxide (average particle size 0.27 μm) 2 4. Triethoxycaprylylsilane-treated red iron oxide (short diameter: average particle size 0.07 μm) 0.1 5. Triethoxycaprylylsilane-treated yellow iron oxide (short diameter: average particle size 0.09 μm) 0.2 6. Triethoxycaprylylsilane-treated black iron oxide (average particle size 0.3 μm) 0.05 7. Triethoxycaprylylsilane-treated mica (average particle size 15 μm) 2 8. (Acrylates / Ethylhexyl Acrylate / Dimethicone Methacrylate) Copolymer 1 9. MDT Resin (30% ISD solution) 15 10. Dimethylpolysiloxane (6CS) 5 11. Isotridecyl Isononanoate 3 12. Diisostearyl Malate 1 13. Trimethylsiloxysilicate 2 14. Disteardimonium hectorite 1 15. Sorbitan isostearate16. Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 3 17. PEG-9 Polydimethylsiloxyethyl Dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 1 18. 2-Ethylhexyl Paramethoxycinnamate 5 19. Diethylamino Hydroxybenzoyl Hexyl Benzoate 2.5 20. Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine 0.5 21. Tribehenin (Croda Japan Co., Ltd.: SYNCROWAX HR-C-FL-(JP)) 0.3 22. Dextrin Palmitate 0.5 23. Polymethylsilsesquioxane (average particle size 5 μm) 1 24. Spherical cellulose (average particle size 5 μm) 1 25. Silica (average particle size 5 μm) 1 26. Boron nitride (average particle size 5 μm) 2 27. Nylon powder (average particle size 5 μm) 1 28. Ethanol 5 29. 1,3-Butylene glycol 1 30. Glycerin 1 31. Xanthan gum 0.1 32. Total amount of purified water remaining 100 <Evaluation> The water-in-oil cushion foundation produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0113] [Example 59] Non-aqueous foundation <Preparation of cosmetic> A: Mix 1 to 11 uniformly. B: Mix 12 to 15 uniformly in a homomixer. C: Add B to A and mix uniformly, add 16 and fill into a container to obtain a non-aqueous foundation. Composition % 1. MDT resin (30% ISD solution) 12 2. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-100) 8 3. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 3 4. Silicone-alkyl branched polyether modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 2 5. Acrylic silicone (Shin-Etsu Chemical Co., Ltd.: KP-550) 1.5 6. Disteardimonium hectorite 1.5 7. Dimethylsilylated silica 1.6 8. Homosalate 3 9. Cetyl ethylhexanoate 3 10. Isododecane 10 11. Dimethicone (2CS) Remaining amount 12. Dimethicone (6CS) 10 13. Silicone-alkyl branched polyglycerin modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6115) 0.75 14. Metal soap treated fine particle titanium dioxide 2.25 15. Silicone treated pigment (Shin-Etsu Chemical Co., Ltd.: KTP-09W, Y, R, B) 10 16. Ethanol 6 Total 100 <Evaluation> The non-aqueous foundation produced by the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0114] [Example 60] Oil-based solid foundation <Preparation of cosmetic> A: Disperse 10 to 14 in a roll mill. B: Disperse 1 to 7 in a disperser, add 8 and 9, heat to 95°C and mix uniformly. C: Add A to B and mix uniformly, heat to 85°C. D: Fill C into a container to obtain an oil-based solid foundation. Composition % 1. PG dicaprate Remainder 2. MDT resin (30% ISD solution) 1 3. Silicone composite powder (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-101) 10 4. Silicone composite powder (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-105) 4 5. Crosslinked dimethylpolysiloxane composition (manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-16) 6 6. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 12 7. Silicone-alkyl branched polyglycerin modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6105) 0.5 8. Paraffin wax 6 9. Polyethylene wax 2 10. Dimethicone (6CS) 11 11. Silicone-branched polyglycerin modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6106) 1 12. Metal soap treated fine particle zinc oxide (average primary particle size: 30 nm) 8 13. Silicone treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: KTP-09W) 8.5 14. Silicone-treated iron oxide (manufactured by Shin-Etsu Chemical Co., Ltd.: KTP-09R, Y, B) 1.5 Total 100 <Evaluation> The oil-based solid foundation produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0115] [Example 61] Water-in-oil Stick Foundation <Preparation of Cosmetic Composition> A: Disperse 10-14 in a three-roll mill. B: Heat 1-9 to 95°C and mix uniformly. C: Mix A and 15-16 uniformly and heat to 85°C. D: Add C to B and emulsify at 85°C. After filling into a stick container, slowly cool to 25°C to obtain a water-in-oil stick foundation. Composition % 1. Crosslinked polyglycerin-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-710) 4.5 2. Silicone-alkyl branched polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 1.5 3. Inulin stearate (Chiba Flour Milling Co., Ltd.: Leopal ISK2) 1.8 4. Ceresin 6 5. Neopentyl glycol diethylhexanoate 6 6. 1. Cetyl ethylhexanoate 4 7. Dimethylpolysiloxane (6CS) 11.5 8. Polymethylsilsesquioxane (Shin-Etsu Chemical Co., Ltd.: KMP-590) 1.5 9. MDT resin (30% ISD solution) 1 10. Silicone-treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: KTP-09W) 6.5 11. Silicone-treated iron oxide (Shin-Etsu Chemical Co., Ltd.: KTP-09R, Y, B) 0.01 12. Polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6011) 0.2 13. Polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6013) 0.3 14. Dipropylene glycol 5 15. Methyl parahydroxybenzoate 0.1 16. Total amount of purified water remaining: 100 <Evaluation> The water-in-oil stick foundation manufactured as described above exhibited excellent film uniformity and reduced secondary adhesion.

[0116] [Example 62] Wrinkle Concealer <Preparation of Cosmetic Composition> A: Mix 1 to 7 uniformly. B: Add 8 to A and mix, then fill into a container to obtain wrinkle concealer. Composition % 1. Crosslinked polyether-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-210) 5 2. Crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-15) 55 3. Crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-016F) 15 4. Methyltrimethicone residue 5. High polymerization dimethylpolysiloxane / D5 mixed solution (Shin-Etsu Chemical Co., Ltd.: KF-9028) 5 6. MDT resin (30% ISD solution) 1 7. Silicone-modified polysaccharide compound solution (Shin-Etsu Chemical Co., Ltd.: TSPL-30-D5) 1 8. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-411) 12 Total 100 <Evaluation> The wrinkle concealer produced by the above method exhibited excellent coating film uniformity and secondary adhesion-free effect.

[0117] [Example 63] Powder Foundation <Preparation of Cosmetic Composition> A: Heat 1 to 4 to 50°C and mix uniformly, then cool to 25°C. B: Mix 5 to 14 uniformly. C: Add A to B and mix uniformly using a Henschel mixer. D: Pass C through a 1 mmΦ mesh and then press it into a metal dish using a mold to obtain powder foundation. Composition % 1. 2-ethylhexyl paramethoxycinnamate 4 2. Diphenylsiloxyphenyl trimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-56A) 4.5 3. Triethylhexanoin 1.5 4. Silicone wax (manufactured by Shin-Etsu Chemical Co., Ltd.: KP-561P) 1 5. MDT resin (30% ISD solution) 1 6. Silicone-treated mica (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-9909 treated) 30 7. 10. Barium sulfate (particle size 7 μm) 8. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-300) 5 9. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-100) 4 10. Silicone-treated talc (Shin-Etsu Chemical Co., Ltd.: KF-9909 treated) Remaining amount 11. Silicone-treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: KF-9909 treated) 6 12. Silicone-treated yellow iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-9909 treated) 0.01 13. Silicone-treated red iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-9909 treated) 0.01 14. Silicone-treated black iron oxide (Shin-Etsu Chemical Co., Ltd.: KF-9909 treatment) 0.01 Total 100 <Evaluation> The powder foundation produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0118] [Example 64] Powder Foundation <Preparation of Cosmetics> A: Mix 1 to 12 in a Henschel mixer. B: Add 13 to 17, heated to 60°C, to A and mix in a Henschel mixer. C: Grind B in a pulverizer. D: Compress C into a resin dish to obtain powder foundation.Composition % 1. Silicone-treated hexagonal plate-shaped zinc oxide (Sakai Chemical Co., Ltd.: Hexagonal plate-shaped zinc oxide XZ-300F-LP) 5 2. Spherical biodegradable polyamide particles (average particle size: 5 μm, oil absorption: 100 ml / 100 g) 5 3. Stearoyl glutamic acid-treated synthetic fluorphlogopite 10 4. Titanium dioxide (Teika Co., Ltd.: MP-701) 10 5. Fine particle titanium dioxide / corn starch composite powder (Hayate Material Co., Ltd.: MTXO70-CS) 10 6. Silicone-treated iron oxide (a mixture of red iron oxide, yellow iron oxide, and black iron oxide, surface-treated with 2% dimethicone, in a mass ratio of 3:6:1) 3 7. Plate-shaped barium sulfate residue 8. 15. Silicone elastomer coated talc (talc (particle size: 10 μm) coated with 5% (dimethicone / vinyl dimethicone) crosspolymer) 15 9. Boron nitride (Mizushima Iron Alloy Co., Ltd.: SHP-3) 10 10. Hollow spherical silica (JGC Catalysts & Chemicals Co., Ltd.: SILICA MICRO BEAD BA-1) 5 11. Lauroyl lysine treated spherical silica (anhydrous silicic acid) 5 12. Higher alcohol treated spherical silica (anhydrous silicic acid) (Teika Co., Ltd.: TMS-05DCB) 5 13. Ethylhexyl methoxycinnamate 5 14. Isotridecyl isononanoate 3 15. Sorbitan sesquistearate (Nippon Surfactant Industry Co., Ltd.: NIKKOL SS-15V) 1 16. MDT resin (30% ISD solution) 1 17. Fragrance 0.2 Total 100 <Evaluation> The powder foundation produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0119] [Example 65] Face Powder <Preparation of Cosmetic Composition> A: Mix 1 to 12 in a Henschel mixer. B: Add 13 to 16 to A and mix in a Henschel mixer. C: Crush B in a pulverizer. D: Compress C into a resin dish to obtain face powder. Composition % 1. (HDI / PPG / Polycaprolactone) Crosspolymer (Negami Kogyo Co., Ltd.: CS-400) 25 2. Spherical Corn Starch (Nichiden Chemical Co., Ltd.: Corn Starch ST-C) 3 3. Cocoa Butter Treated Hollow Spherical Silica (Anhydrous Silicic Acid) (Particle Size 5 μm) 3 4. Dimethiconol Stearate Treated Talc (Particle Size 5 μm) 10 5. Zinc Myristate 2 6. Dextrin Isostearate Treated Talc (Particle Size 5 μm) 2 7. 10. Silicone elastomer treated synthetic fluorphlogopite (particle size 10 μm) Remaining amount 8. Petrolatum treated mica (particle size 10 μm) 10 9. Dimethiconol treated talc (particle size 5 μm) 10 10. Calcium alginate 3 11. Lecithin treated talc (particle size 5 μm) 8.8 12. MDT resin (30% ISD solution) 4 13. Triethylhexanoin 4 14. Diphenylsiloxyphenyl trimethicone 4 15. Ethylhexylglycerin 0.4 16. Tocopherol 0.1 Total 100 <Evaluation> The face powder produced by the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0120] [Example 66] Slurry Cheek <Preparation of Cosmetic Product> A: Mix 1 to 11 in a Henschel mixer. B: Heat 12 to 17 at 110°C and mix uniformly. C: Add 50 parts of B and isododecane to A and mix uniformly with a universal stirrer. D: Place 4.0 g in a round metal dish container (3 cm in diameter) and press with a pressure of 2.0 kgf / cm ２The mixture was compressed twice under the conditions of a press time of 4 seconds and 6 sheets of paper, partially removing isododecane. E:D was dried overnight at 70°C to obtain slurry teak.Composition % 1. Dimethicone-treated mica (particle size 10 μm) 5 2. Silicone-treated fine zinc oxide particles (Teika Co., Ltd.: MZY-505M) 5 3. Boron nitride (Mizushima Iron Alloy Co., Ltd.: SHP-3) 5 4. High polymerization dimethicone-treated mica (mica treated with 2% high polymerization dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-96H-1,000,000 CS) (average particle size: 20 μm)) 5 5. Aluminum starch octenyl succinate (Nichiden Chemical Co., Ltd.: Octie) 2 6. Spherical silica (anhydrous silicic acid) (Momentive Co., Ltd.: HARMONIE LUXE 4 powder) 5 7. Synthetic fluorphlogopite (5 μm) 5 8. Sericite (5 μm) Remaining amount 9. 5. Iron oxide 5 10. Red 226 2 11. Iron oxide coated titanium mica (CQV: BLONDIEE METALIC GOLD N-2000S) 5 12. Ethyl cellulose (ASHLAND: AQUALON EC N-14) 1 13. Octyldodecanol 5 14. Propylene glycol dicaprate 5 15. (Dimethicone / vinyl dimethicone) crosspolymer (Shin-Etsu Chemical Co., Ltd.: KSG-16) 5 16. MDT resin (30% ISD solution) 5 17. (PEG-15 / Lauryl Dimethicone) Crosspolymer / Liquid Paraffin Mixture (Shin-Etsu Chemical Co., Ltd.: KSG-310) 20 Total 100 <Evaluation> The slurry teak produced by the above method exhibited excellent coating uniformity and secondary adhesion reduction effect.

[0121] [Example 67] Medicated skincare powder <Preparation of cosmetic> A: Mix 1 to 5 in a super mixer. B: Mix 6 to 20 at room temperature. C: Add B to A and mix in a super mixer. D: Crush C in a pulverizer and fill into a container to obtain medicated skincare powder.Composition % 1. (Fluoride / Hydroxide / Oxide) (Mg / K / Silicate) (Manufactured by Katakura Coop Agri Co., Ltd.: Micromica MK-200K) Remaining amount 2. (Styrene / DVB) Copolymer (Manufactured by Aica Kogyo Co., Ltd.: Gantzpearl GS-0605) 10 3. Methylpolysiloxane (Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96A-6CS) 10 4. Boron Nitride (Manufactured by Mizushima Iron Alloy Co., Ltd.: SHP-3) 5 5. Stearyl Glycyrrhetinate 0.3 6. Liquid Paraffin (Manufactured by SONNEBORN Co., Ltd.: CARNATION) 0.1 7. MDT Resin (30% ISD solution) 2 8. 1,3-Butylene Glycol 1 9. 10. Linalool 0.002 11. Farnesol 0.002 12. Anisic Alcohol 0.002 13. Eugenol 0.002 14. Citronellol 0.002 15. Geraniol 0.002 16. Linalyl acetate 0.002 17. α-Terpineol 0.002 18. Geranyl acetate 0.002 α-Pinene 0.002 19.1-Hexen-1-ol 0.002 20. Cedryl acetate 0.002 Total 100 <Evaluation> The medicated skincare powder produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0122] [Example 68] Medicated skincare powder <Preparation of cosmetic> A: Mix 1 to 5 in a super mixer. B: Mix 6 to 22 at room temperature. C: Add B to A and mix in a super mixer. D: Crush C in a pulverizer and fill into a container to obtain medicated skincare powder.Composition % 1. (Fluoride / Hydroxide / Oxide) (Mg / K / Silicate) (Manufactured by Katakura Coop Agri Co., Ltd.: Micromica MK-200K) Remaining amount 2. (Styrene / DVB) Copolymer (Manufactured by Aica Kogyo Co., Ltd.: Gantzpearl GS-0605) 10 3. Methylpolysiloxane (Manufactured by Shin-Etsu Chemical Co., Ltd.: KF-96A-6CS) 10 4. Boron Nitride (Manufactured by Mizushima Iron Alloy Co., Ltd.: SHP-3) 5 5. Stearyl Glycyrrhetinate 0.3 6. Liquid Paraffin (Manufactured by SONNEBORN Co., Ltd.: CARNATION) 0.1 7. MDT Resin (30% ISD solution) 2 8. 1,3-Butylene Glycol 1 9. 10. Iso E Super 0.002 11. Sandalore 0.002 12. Ambroxan 0.002 13. γ-Terpinene 0.002 14. Ambrettolide 0.002 15. β-ionone 0.002 16. Borneol 0.002 17. Isobutylquinoline 0.002 18. Citral 0.002 19. Guaical 0.002 Patchouli alcohol 0.002 20. Cedrol 0.002 21. Ethyl vanillin 0.002 22. Maltol 0.002 Total 100 <Evaluation> The medicated skincare powder produced using the above method exhibited excellent film uniformity and reduced secondary adhesion.

[0123] [Example 69] Mousse Cheek <Preparation of Cosmetic Composition> A: Heat 1 to 6 to 80°C and mix uniformly. B: Mix 7 to 12 uniformly in a Henschel kettle. C: Add B to A and mix uniformly at 80°C, then slowly cool to 25°C and fill into containers to obtain mousse cheek. Composition % 1. Crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-16) 32 2. Decamethylcyclopentasiloxane 30 3. Neopentyl glycol diisostearate 7 4. Inulin stearate (Chiba Flour Milling Co., Ltd.: Leopal ISK2) 8 5. Amorphous anhydrous silicic acid (Nippon Aerosil Co., Ltd.: AEROSIL200) 0.5 6. MDT resin (30% ISD solution) 1.5 7. 10. Silicone-treated titanium dioxide (Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 0.2 8. Red No. 202 0.01 9. Silicone-treated yellow iron oxide (Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 0.01 10. Silicone-treated black iron oxide (Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 0.01 11. Silicone-treated mica (Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 5.4 12. Silicone-treated sericite (Shin-Etsu Chemical Co., Ltd.: KP-574 treatment) 10 Total 100 <Evaluation> The mousse teak produced using the above method exhibited excellent coating uniformity and reduced secondary adhesion.

[0124] [Example 70] Oil-in-water sunscreen <Preparation of cosmetic composition> A: Heat 1 to 6 to 85°C and mix uniformly. B: Heat 7 to 15 to 85°C and mix uniformly. C: Add B to A and emulsify at 85°C, then slowly cool to 25°C while stirring, fill into containers to obtain an oil-in-water sunscreen. Composition % 1. Sodium hyaluronate 0.1 2. Ethanol 10 3. 1,3-Butylene glycol 6 4. Methyl parahydroxybenzoate 0.1 5. Sodium acrylate / sodium acryloyldimethyl taurate copolymer composition (SEPPIC: SIMULGEL EG) 2.5 6. Purified water remaining 7. MDT resin (30% ISD solution) 1 8. Diphenylsiloxyphenyl trimethicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-56A) 3 9. Cross-linked dimethylpolysiloxane composition (manufactured by Shin-Etsu Chemical Co., Ltd.: KSG-016F) 1 10. Cetanol 2 11. 2-ethylhexyl paramethoxycinnamate 5 12. 2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine 1 13. Polyoxyethylene (60) hydrogenated castor oil 1 14. Polyether-modified silicone (manufactured by Shin-Etsu Chemical Co., Ltd.: KF-6011) 0.5 15. Tocopherol 0.05 Total 100 <Evaluation> The oil-in-water type sunscreen produced by the above method exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0125] [Example 71] Oil-in-water sunscreen <Preparation of cosmetic> A: Mix 1 to 8 uniformly. B: Mix 9 to 15 uniformly. C: Add B to A, emulsify at 25°C, fill into a container to obtain an oil-in-water sunscreen. Composition % 1. Alkyl-modified / crosslinked polyglycerin-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-840) 3 2. Alkyl-modified / crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-43) 3 3. Silicone / alkyl-branched polyglycerin-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6105) 1.5 4. Diphenylsiloxyphenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 11 5. 2-ethylhexyl paramethoxycinnamate 6 6. Octyl salicylate 1 7. 10. Silicone composite powder (manufactured by Shin-Etsu Chemical Co., Ltd.: KSP-100) 2 8. MDT resin (30% ISD solution) 3 9. Xanthan gum 0.3 10. Dipropylene glycol 5 11. Glycerin 3 12. Methyl parahydroxybenzoate 0.1 13. Dipotassium glycyrrhizate 0.2 14. Sodium chloride 0.5 15. Total amount of purified water remaining 100 <Evaluation> The oil-in-water type sunscreen produced by the above method exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0126] [Example 72] Oil-in-Water Sunscreen <Preparation of Cosmetic Composition> A: Mix 20% by mass of 12, 13 and 8-10 and disperse in a roll mill. B: Mix and disperse the remaining A, 4-7, 11, 14, 15 and 8-10 at 70°C. C: Mix and disperse 50% by mass of 1-3 and component 18 at 70°C. D: Add B to C and emulsify, then mix and disperse uniformly. E: Cool D to 25°C, add the remaining 18 and 16, 17, 19-24 and mix, then fill into a container to obtain an oil-in-water sunscreen. Composition % 1. (Acrylates / Beheneth-25 Methacrylate) Copolymer (Lubrizol: NOVETHIX L-10 POLYMER) 0.5 2. Xanthan Gum 0.5 3. Sodium hydroxide 0.05 4. Ethylhexyl methoxycinnamate 5 5. Diethylamino hydroxybenzoyl hexyl benzoate 1 6. 2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-Triazine 1 7. Ethylhexyltriazone 1 8. MDT resin (30% ISD solution) 1 9. Diisopropyl sebacate 1 10. Diethylhexyl succinate 1 11. Olive oil 0.1 12. Triethoxyoctylsilane-treated zinc oxide 10 13. Polyhydroxystearic acid 0.2 14. PEG-80 hydrogenated castor oil 0.5 15. PEG-10 hydrogenated castor oil 0.05 16. Silica (particle size 5 μm) 1 17. Crystalline cellulose (particle size 5 μm) 0.5 18. Purified water remaining 19. Ethanol 10 20. Hyaluronic acid 0.15 21. Trehalose 0.05 22. Artemisia capillaris extract 0.01 23. Niacinamide 6 24. Tranexamic acid 4 Total 100 <Evaluation> The oil-in-water sunscreen produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0127] [Example 73] Oil-in-water sunscreen <Preparation of cosmetic composition> A: Mix 20% by mass of 12, 13 and 7-11 and disperse in a roll mill. B: Mix and disperse the remaining A, 3-6, 17, 18 and 7-11 at 70°C. C: Mix and disperse 50% by mass of 1, 2, 14, 15 and 19 at 70°C. D: Add B to C and emulsify, then mix and disperse uniformly. E: Cool D to 25°C, add the remaining 19 and 16, 20-25 and mix, then fill into a container to obtain an oil-in-water sunscreen.Composition % 1. (Sodium Acrylate / Sodium Acryloyldimethyl Taurate) Copolymer (SEPPIC: SIMULGEL EG QD) 1.5 2. Xanthan Gum 0.5 3. Ethylhexyl Methoxycinnamate 7 4. Diethylamino Hydroxybenzoyl Hexyl Benzoate 1 5. 2,4-Bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-Triazine 1 6. Ethylhexyl Triazone 1 7. Cetyl 2-Ethylhexanoate 1 8. MDT Resin (30% ISD Solution) 5 9. Di(Caprylic / Capric Acid) PG 5 10. Alkyl Benzoate (C12-15) 1 11. Diisopropyl Sebacate 1 12. Triethoxyoctylsilane-treated zinc oxide 10 13. Polyhydroxystearic acid 0.2 14. PEG-80 hydrogenated castor oil 0.5 15. PEG-10 hydrogenated castor oil 0.05 16. Silica 1 17. Olive oil 0.1 18. Di-2-ethylhexyl succinate 1 19. Purified water remaining 20. Ethanol 5 21. Hyaluronic acid 0.15 22. Trehalose 0.05 23. Artemisia capillaris extract 0.01 24. Niacinamide 4 25. Tranexamic acid 3 Total 100 <Evaluation> The oil-in-water type sunscreen produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0128] [Example 74] Oil-in-Water Sunscreen <Preparation of Cosmetic Composition> A: Mix 20% of 6-7 and 8-10 and disperse in a three-roll mill. B: Mix 2-5, 11, 12, 15, 18, and 19 with the remainder of 6-8 and dissolve uniformly at 70°C. C: Disperse 1, 13, 14, 21-24, and part of 20 uniformly at 70°C. D: Add A to B and disperse uniformly at 75°C. E: Add D to C and emulsify at 75°C. F: Cool E to 25°C, add the remainder of 20, 16, and 17 and mix, then fill into a container to obtain an oil-in-water sunscreen. Composition % 1. Crystalline Cellulose (Daiichi Kogyo Seiyaku Co., Ltd.: Rheocrysta C-2EP) 0.2 2. Ethylhexyl Methoxycinnamate 7 3. Diethylaminohydroxybenzoyl hexyl benzoate 2 4.2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-Triazine 2 5. Polysilicone-15 (DSM: PARSOL SLX) 1 6. Isotridecyl isononanoate 2 7. Isododecane 3 8. MDT resin (30% ISD solution) 5 9. Polyhydroxystearic acid 0.25 10. Triethoxyoctylsilane-treated zinc oxide (Teika: MZX-304OTS) 10 11. PEG-10 hydrogenated castor oil (HLB: 6.5) (Nikko Chemicals: Nikko HCO-10) 0.05 12. Polyglyceryl-10 stearate (HLB: 12.0) (Nikko Chemicals: IKKOL Decaglyn 1-SV) 0.5 13. 14. (Sodium acrylate / sodium acryloyldimethyl taurate) copolymer (SEPPIC: SIMULGEL EG) 0.2 15. (Acrylates / beheneth-25 methacrylate) copolymer (LUBRIZOL: NOVETHIX L-10) 0.2 16. Inulin stearate (Chiba Flour Milling Co., Ltd.: Leopal ISK2) 1 17. Polymethylsilsesquioxane 2 18. Silica (Godball D11-796C (Suzuki Oil & Fat Industry Co., Ltd.)) 1 19. Olive oil 0.1 10. Diethylhexyl succinate (CRODAMOL OSU) 1 21. Purified water remaining 22. Ethanol 10 Hyaluronic acid 0.15 23. Trehalose 0.05 24. Artemisia capillaris extract 0.01 Total 100 <Evaluation> The oil-in-water sunscreen produced using the above method exhibited excellent film uniformity and secondary adhesion-free effect.

[0129] [Example 75] Oil-in-Water Sunscreen <Preparation of Cosmetic Composition> A: Dissolve and mix 1 to 7 uniformly at 75°C. B: Dissolve and mix 8 to 12 uniformly at 70°C. C: Dissolve and mix 13 to 22 uniformly at 80°C. D: After mixing A and B, add C and emulsify at 70°C. E: After adding 23 to 30 to D and mixing, cool to 40°C and fill into containers to obtain an oil-in-water sunscreen. Composition % 1.13-Butylene Glycol 5 2. Dipropylene Glycol 5 3. Behentrimonium Chloride 0.1 4. Hydrogenated Lecithin (Nikko Chemicals: Nikko Resinol S-10) 0.5 5. Cholesterol (Nippon Suisan Kairei Marine Cholesterol) 0.6 6. Phytosterol 0.1 7. PEG / PPG / Polyglycol / 8 / 5 / 3 Glycerin (NOF Corporation: Willbride S-753D) 1 8. Purified Water Remaining Amount 9. Niacinamide 3 10. Tranexamic Acid 2 11. (Acrylates / C10-30 Alkyl Acrylate) Copolymer (Lubrisol: PEMULEN TR-1) 0.4 12. Triethanolamine 0.4 13. Dimethicone diethyl benzalmalonate 1.2 14.4-tert-butyl-4'-methoxydibenzoylmethane 2 15. 2-ethylhexyl paramethoxycinnamate 7 16. Diethylamino hydroxybenzoyl hexyl benzoate 2.5 17. MDT resin (30% ISD solution) 1 18. Hydrogenated castor oil stearate (National Mimatsu Co., Ltd.: Castride MS) 0.5 19. Propylene glycol dicaprate 5 20. Ethyl oleate 0.3 21. (Linoleic acid / oleic acid) tocopherol 0.1 22. Rosemary oil 0.01 23.12-Pentanediol 0.1 24. Zinc Oxide (manufactured by Daito Chemical Industries, Ltd.: SI06-4 ZnO V1) 2 25. Water-soluble Collagen 0.01 26. Chamomile Flower Extract 0.05 27. Calendula Flower Extract 0.05 28. Glycerin 1 29. Ethanol 7 30. Fragrance 0.1 Total 100 <Evaluation> The oil-in-water sunscreen produced as described above exhibited excellent film uniformity and secondary adhesion-free effect.

[0130] [Example 76] Water-in-oil sunscreen <Preparation of cosmetic> A: Mix 1 to 12 uniformly. B: Mix 15 to 21 uniformly. C: Add B to A and emulsify, then add 13 and 14 and mix uniformly, then fill into a container to obtain a water-in-oil sunscreen.Composition % 1. MDT resin (30% ISD solution) 3 2. Phenylen-modified cross-linked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-18A) 3 3. Alkyl-silicone branched polyether-modified silicone (Shin-Etsu Chemical Co., Ltd.: KF-6038) 2 4. Decamethylcyclopentasiloxane 20 5. Diphenylsiloxy phenyl trimethicone (Shin-Etsu Chemical Co., Ltd.: KF-56A) 5.5 6. Isononyl isononanoate 5 7. Stearyl glycyrrhetinate 0.2 8. BHT 0.1 9. 2-ethylhexyl paramethoxycinnamate 7.5 10. Octocrylene 2.5 11. 2-[4-(diethylamino)-2-hydroxybenzoyl]hexyl benzoate 1 12. 13. Silicone composite powder (Shin-Etsu Chemical Co., Ltd.: KSP-105) 0.5 14. Fine particle titanium oxide dispersion (Shin-Etsu Chemical Co., Ltd.: SPD-T7) 5 15. Fine particle zinc oxide dispersion (Shin-Etsu Chemical Co., Ltd.: SPD-Z5) 10 16. 1,3-Butylene glycol 3 17. Ethanol 6 18. Sodium citrate 0.2 19. Sodium hydroxide 0.01 10. Ascorbic acid 2-glucoside 2 21. Ethylenediaminetetraacetate 0.1 22. Total amount of purified water remaining 100 <Evaluation> The water-in-oil type sunscreen produced by the above method exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0131] [Example 77] Water-in-oil sunscreen <Preparation of cosmetic> A: Mix 1 to 7 uniformly. B: Mix 10 to 13 uniformly. C: Add B to A and emulsify, add 8 and 9 and mix uniformly, fill into a container to obtain a water-in-oil sunscreen. Composition % 1. MDT resin (30% ISD solution) 2 2. Crosslinked polyether-modified silicone composition (Shin-Etsu Chemical Co., Ltd.: KSG-210) 3 3. Crosslinked dimethylpolysiloxane composition (Shin-Etsu Chemical Co., Ltd.: KSG-19) 2 4. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 1 5. Dimethylpolysiloxane (6CS) 5 6. Decamethylcyclopentasiloxane 3 7. 4. Isotridecyl isononanoate 8. Fine particle titanium dioxide dispersion (Shin-Etsu Chemical Co., Ltd.: SPD-T5) 25 9. Fine particle zinc oxide dispersion (Shin-Etsu Chemical Co., Ltd.: SPD-Z5) 35 10. Dipropylene glycol 2 11. Sodium citrate 0.2 12. Sodium chloride 1 13. Total amount of purified water remaining 100 <Evaluation> The water-in-oil type sunscreen produced by the above method exhibited excellent coating film uniformity and secondary adhesion reduction effect.

[0132] [Example 78] Water-in-oil sunscreen <Preparation of cosmetic composition> A: Mix and dissolve half of 2-6 and 11, 9, 10, and 12-15 uniformly. B: Disperse 1 and the remaining amount of components 7-9 and 11 in a roll mill. C: Add B to A and mix and disperse uniformly. D: Add components 16 and 17 to C and mix and disperse uniformly. E: Mix 18-27 uniformly. F: Add E to D and emulsify, then fill into a container to obtain a water-in-oil sunscreen. Composition % 1. Triethoxyoctylsilane-treated zinc oxide (Teika Co., Ltd.: MZX-508OTS) 15 2. Ethylhexyl methoxycinnamate 5 3. Diethylaminohydroxybenzoyl hexyl benzoate 1 4.2,4-bis{[4-(2-ethylhexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-Triadi 1 5. Ethylhexyltriazone 1 6. Polysilicone-15 (DSM: PARSOL SLX) 3 7. Polyhydroxystearic acid 0.3 8. PEG-9 polydimethylsiloxyethyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6028) 0.2 9. MDT resin (30% ISD solution) 10 10. Diisopropyl sebacate 5 11. Dimethicone (6CS) 5 12. Diphenyl dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-54) 5 13. Diphenylsiloxyphenyl trimethicone 5 14. PEG-9 dimethicone (Shin-Etsu Chemical Co., Ltd.: KF-6019) 0.7 15. (Dimethicone / (PEG-10 / 15)) Crosspolymer 1 16. Talc (average particle size: 15 μm) 5 17. Mica (average particle size: 19 μm) 1 18. Ethanol 7 19. Purified water remaining 20. Sodium chloride 0.3 21. 1,3-Butylene glycol 5 22. Glycerin 1 23. Dipropylene glycol 0.5 24. Hyaluronic acid 0.15 25. Trehalose 0.05 26. Artemisia capillaris extract 0.01 27. Phenoxyethanol 0.3 Total 100 <Evaluation> The water-in-oil type sunscreen produced as described above exhibited excellent film uniformity and secondary adhesion reduction effect.

[0133] [Example 79] Water-in-oil sunscreen <Preparation of cosmetic> A: Mix 1-4 and disperse in a roll mill. B: Mix 5-8, add A, and mix and disperse. C: Mix 9-12 uniformly, add to B and emulsify, fill into a container to obtain a water-in-oil sunscreen. Composition % 1. Stearic acid (10% by mass treatment) / Aluminum hydroxide treated fine particle titanium dioxide (10 nm) 5 2. Lauroyl lysine treated (20% by mass treatment) fine particle zinc oxide (25 nm) 15 3. Polyhydroxystearic acid 2 4. Isononyl isononanoate 10 5. Isopropyl palmitate 8 6. PEG-30 dipolyhydroxystearate 1 7. PEG-9 dimethicone 2 8. MDT resin (30% ISD solution) 10 9. Purified water remaining 10. 1,3-Butylene glycol 3 11. Glycerin 4 12. Sodium hyaluronate (Food Chemifa Co., Ltd.: Hyaluronic acid FCH-SU) 3 Total 100 <Evaluation> The water-in-oil type sunscreen produced as described above exhibited excellent coating uniformity and secondary adhesion reduction effect.

Claims

1. A cosmetic composition containing a block-structured polyorganosiloxane, represented by the following general formula (1), having a weight-average molecular weight of 500,000 or more, and exhibiting properties as a solid at room temperature with a softening point of 50°C or higher when not containing a solvent. (In the formula, R １ , R ２ , R ３ , R ４ , R ５ (where m is a saturated or unsaturated hydrocarbon group having 1 to 20 carbon atoms, which may have hydrogen atoms or substituents; m represents the number of repeating diorganosiloxy units, where 50 ≥ m ≥ 0; a, b, c, d, and e represent the molar ratios of their respective siloxane units, where 0.3 ≥ a ≥ 0, 0.3 ≥ b > 0, 0.5 ≥ c ≥ 0, 0.95 ≥ d > 0.5, 0.3 ≥ e ≥ 0, and a + b × (2 + m) + c + d + e = 1; and x and y represent the number of hydroxyl or alkoxy groups bonded to 1 mole of Si atoms in the siloxane units a to e, where 0.1 ≥ x > 0 and 0.1 ≥ y > 0.) 2. The cosmetic composition according to claim 1, wherein x is 0.05 ≥ x > 0 and y is 0.05 ≥ y > 0.

3. The cosmetic composition according to claim 1, wherein m is m > 10, a is 0.1 ≥ a > 0, b is 0.2 ≥ b > 0, c is 0.3 ≥ c > 0, and e is e = 0.

4. The R １ , R ２ , R ３ , R ４ is any monovalent hydrocarbon group of a hydrogen atom, a methyl group, an ethyl group, or a vinyl group, and the R ５ is a saturated hydrocarbon group having 1 to 4 carbon atoms. The cosmetic according to claim 1.

5. In the polyorganosiloxane having the block structure described above, ２９ The cosmetic composition according to claim 1, characterized in that the chemical shift of the signal attributed to the diorganosiloxane unit is detected in the range of -15 to -25 ppm in Si-NMR, and the detection width of the signal peak (the difference between the chemical shift at the detection start point and the chemical shift at the detection end point) is 3 to 7 ppm.

6. The cosmetic composition according to any one of claims 1 to 5, wherein the content of the polyorganosiloxane having the block structure is 0.1 to 40% by mass.

7. The cosmetic composition according to claim 6, further comprising a volatile oil agent.

Images