Process for providing keratin materials with printed ink deposit having improved water resistance

Abstract

The present invention relates to a process comprising the steps of: (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material; (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and (iii) applying an anhydrous composition on the ink design, preferably on the printed ink design to provide a coating layer on the ink design, wherein the anhydrous composition comprises at least one oil-soluble film forming agent. The process according to the present invention can make up design with improved water resistance.

Description

[0001] DESCRIPTION

[0002] TITLE OF INVENTION

[0003] PROCESS FOR PROVIDING KERATIN MATERIALS WITH PRINTED INK DEPOSIT HAVING IMPROVED WATER RESISTANCE

[0004] TECHNICAL FIELD

[0005] The present invention relates to a process for providing a keratin material with printed ink deposit having improved water resistance. The present invention also relates to a composition for improving water resistance of ink deposit printed on a keratin material.

[0006] BACKGROUND OF THE INVENTION

[0007] The traditional tattoo is a method of infiltrating the pigment to the dermal layer of the skin, and the initial treatment cost is also expensive, but it is not easy to remove because it is permanent once treated.

[0008] Recently, after the traditional tattoo procedure, Henna Tattoo (a method of drawing on the body using ink), a water transfer sticker (a form of attaching a transfer paper to the body using water), and other body painting using ink in various methods have been proposed, such as a method of stamping a pattern.

[0009] Among temporary body painting methods, a method for printing on skin with a two-liquid skin print ink is reported in KR101655978 Bl and KR20180057953 A.

[0010] However, there remains a need for improving water resistance of temporary ink depositions printed on skin.

[0011] DISCLOSURE OF INVENTION

[0012] An objective of the present invention is to provide a new process for providing a keratin material with temporary printed ink depositions having improved water resistance.

[0013] The above objective of the present invention can be achieved by a new process comprising steps of:

[0014] (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material;

[0015] (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and

[0016] (iii) applying an anhydrous composition on the ink design, preferably on the printed ink design to provide a coating layer on the ink design, wherein the anhydrous composition comprises at least one oil-soluble film forming agent.

[0017] The oil-soluble film forming agent may comprise at least one silicone resin.

[0018] The silicone resin may be selected from silsesquioxane, siloxysilicate, and mixtures thereof. The anhydrous composition may further comprises at least one oil.

[0019] The oil may comprise at least one hydrocarbon oil and / or at least one silicone oil.

[0020] The oil may be non-volatile or non-volatile.

[0021] The oil may be present in the anhydrous composition in an amount of from 10% to 70% by weight, preferably from 15% to 65% by weight, and more preferably from 20% to 60% by weight, relative to the total weight of the composition.

[0022] The oil-soluble film forming agent may be present in the anhydrous composition in an amount of from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition.

[0023] The ink composition may comprise at least one solvent and at least one colorant.

[0024] The primer composition may comprise at least one water-soluble polymer.

[0025] The process according to the present invention may be a process of printing a temporary tattoo on the keratin material.

[0026] The anhydrous composition may further comprise at least one silicone gum.

[0027] The anhydrous composition may further comprise at least one filler and / or lipophilic gelling agent.

[0028] The present invention also relates to an anhydrous composition comprising at least one oilsoluble film forming agent, for use in providing an ink design applied on a keratin material with improved water resistance.

[0029] The present invention also relates to a use of the anhydrous composition according to the present invention for making up an ink design on a keratin material with improved water resistance.

[0030] DETAILED DESCRIPTION OF THE INVENTION

[0031] After diligent research, the inventors have discovered that at least one oil-soluble film forming agent can provide an ink deposition of a keratin material with improved water resistance, and thus completed the invention.

[0032] Thus, the process according to the present invention is a process comprising steps of:

[0033] (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material;

[0034] (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and

[0035] (iii) applying an anhydrous composition on the ink design, preferably on the printed ink design. Thus, the process according to the present invention can make up a design applied by the ink composition, preferably a design printed by the ink composition on the keratin materials with improved water resistance. Keratin material here means a material containing keratin as a main constituent element, and examples thereof include the skin, scalp, nails, lips, hair, eyebrow, eyelash and the like.

[0036] Preferably, the keratin material here indicates the skin, hair, eyebrow, and eyelash. Thus, in a preferred embodiment, the process according to the present invention is a cosmetic process for providing skin with printed ink having improved water resistance.

[0037] In one embodiment, the ink deposit is a temporary tattoo. Thus, the process according to the present invention can be a process for printing a temporary tattoo on the keratin material.

[0038] The term “temporary” here indicates that the tattoo is not permanent and can be removed by, for example, rubbing it with soapy water. This temporary tattoo printed through the process according to the present invention has an improved water resistance. Thus, it can be said that the temporary tattoo provided by the present invention can possess longer lastingness.

[0039] In one preferred embodiment, keratin materials includes areas that the temporary tattoo is intended to be applied, preferably to be printed, such as face, body, brow area, and the like. Thus, the keratin materials may be facial skin, body skin, and skin and eye brow in the brow area.

[0040] Hereinafter, the process and composition according to the present invention will be explained in a more detailed manner.

[0041] [Process]

[0042] The process according to the present invention comprises steps of:

[0043] (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material; and

[0044] (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and

[0045] (iii) applying an anhydrous composition on the ink design, preferably on the printed ink design to provide a coating layer on the ink design.

[0046] The process according to the present invention is for the purpose of providing the keratin material, such as skin, hair, eyebrow, and eyelash, with a design applied by the ink composition, preferably with a design printed by the ink composition having improved water resistance.

[0047] For the purpose of the present invention, the expression "ink design" here is intended to mean a design prepared by an ink composition.

[0048] {Step (i)}

[0049] The process according to the present invention comprises an optional step (i) to apply a primer composition on a keratin material to provide a primer layer on the keratin material.

[0050] The primer layer can provide the ink depositions temporary printed by the present invention with improved smudge resistance and abrasion resistance.

[0051] The primer composition may be in the form of aqueous compositions, loose powder, compact powder, anhydrous compositions, alcoholic compositions, semi-solid compositions, jelly, or film.

[0052] The application of the primer composition may be performed by any means, for example, an inkjet method, a spraying method, a dropping method, or by contacting the primer composition with the keratin material using a finger, a gauze, a cotton, a sponge, a puff, and / or a cosmetic applicator such as flocked applicator, elastomeric applicator, fiber applicator, and comb applicator. In one embodiment of the present invention, the application of the primer composition can be carried out by contacting the primer composition with the keratin material using fingers, a gauze, a cotton, a sponge, a puff, and / or a cosmetic applicator such as flocked applicator, elastomeric applicator, fiber applicator, and comb applicator.

[0053] The primer composition may be dried after the application to form the primer layer. The drying can be performed under an ambient condition for 0.1 to 120 seconds, preferably for 1 to 60 seconds. The drying may be performed by heating the applied ink composition, or simply keeping the applied primer composition under an ambient condition. The temperature of heating may range from 10 °C to 110 °C. The ambient condition here may be at a temperature ranging from 10 °C to 40 °C, in particular from 15 °C to 30 °C to and under atmospheric pressure (105Pa).

[0054] The primer composition may comprise at least one water-soluble polymer.

[0055] The water-soluble polymer included in the primer composition may be selected from a carboxyvinyl polymer, carboxymethylcellulose, methylcellulose, ethylcellulose, hydroxyalkylcellulose, hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethyl cellulose, alkyl cellulose, polyurethane, polyurethane and acrylate copolymer, polyester urethane, polyvinylpyrrolidone, polyvinyl acetate, vinylpyrrolidone-vinyl acetate copolymer, polyvinyl alcohol, polyacrylic acid, sodium polyacrylate, acrylate polymer, acrylate copolymer, such as Polyacrylate Crosspolymer-6, polyacrylic acid partially hydrogenated, polyacrylic acid starch, sodium camellose, carboxyvinyl polymer, N-vinylacetate amide, alkyl olefinic acid, alkyl olefinic acid ester copolymer, amide / olefinic acid, amide / olefinic acid copolymer, native gums, such as xanthan gum, and mixtures thereof.

[0056] The primer composition may comprise 0.1 to 30 parts by weight, preferably 1 to 15 parts by weight, of the water-soluble polymer based on 100 parts by weight of the solvent in the primer composition.

[0057] The primer composition of the present invention can be prepared by mixing the ingredients as explained above. In one embodiment of the present invention, the primer composition can be prepared by stirring the solvent(s) and the water-soluble polymer(s) at 300 to 1000 rpm, preferably 400 to 600 rpm, for 20 to 40 minutes.

[0058] {Step (ii)}

[0059] Step (ii) is to apply an ink composition on the primer layer if the step (i) is carried out, or on the keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material.

[0060] The application of the ink composition may be performed by any means, for example, an inkjet method, a spraying method, a dropping method, or by contacting the ink composition with the keratin material using a finger, a stick, a tip, an applicator, a gauze or a cotton. When the primer composition in the powder format is used in step (i), then the application of the ink composition is preferably performed by using a puff, a brush, or a sponge.

[0061] Preferably the application of the ink composition is performed by an inkjet method, for example using skin transfer print, such as Prinker M manufactured by Prinker.

[0062] According to one embodiment of the present invention, the ink composition is applied to all or a part of the primer layer prepared in step (i).

[0063] The ink composition may be dried after the application to form the ink layer. The drying can be performed under an ambient condition for 0.1 to 120 seconds, preferably for 1 to 60 seconds. The drying may be performed by heating the applied ink composition, fanning to dry, or simply keeping the applied ink composition under an ambient condition. The temperature of heating may range from 10 °C to 110 °C . The ambient condition here may be at a temperature ranging from 10 °C to 40 °C, in particular from 15 °C to 30 °C to and under atmospheric pressure (105Pa).

[0064] The ink composition comprises at least one colorant.

[0065] The colorant used in the present invention may be selected from dyes and pigments.

[0066] The pigments here may be white or colored, and mineral and / or organic particles. The pigments may be may be of any shape: platelet-shaped, spherical or oblong, irrespective of the crystallographic form (for example lamellar, cubic, hexagonal, orthorhombic, etc.)

[0067] Among the mineral pigments that may be mentioned are titanium dioxide, such as pigmentary titanium dioxide rutile type, optionally surface-treated, zirconium oxide or cerium oxide, and also zinc oxide, iron (black, yellow, gold or red) oxide or chromium oxide, manganese violet, ultramarine blue, chromium hydrate and ferric blue, and metal powders, for instance aluminum powder and copper powder.

[0068] The organic pigments may be chosen from the materials below, and mixtures thereof: carbon black, organic pigments of azo dyes, anthraquinone dyes, indigoid dyes, xanthene dyes, pyrene dyes, quinoline dyes, triphenylmethane dyes and fluorane dyes.

[0069] The dyes may be selected from water-soluble acidic dyes.

[0070] For the purpose of the present invention, the acidic dye can be also represented as an acidic direct dye. For the purpose of the present invention, the acidic dye can be also represented as an anionic dye. Thus, the acidic dye can be also represented as "anionic dye", "acidic direct dye", and / or "anionic direct dye". A direct dye means a colored substance which does not require the use of an oxidizing agent in order to develop its color.

[0071] The water-soluble acidic dye may be natural and / or synthetic dyes.

[0072] The expression "natural direct dye" is understood to mean any dye or dye precursor that is naturally occurring and is produced by extraction (and optionally purification) from a plant matrix or an animal such as an insect, optionally in the presence of natural compounds such as ash or ammonia.

[0073] Natural direct dyes are not limited as long as they are acidic direct dyes. As natural direct dyes, mention may be made of quinone dyes (such as lawsone and juglone), alizarin, purpurin, laccaic acid, carminic acid, kermesic acid, purpurogallin, protocatechaldehyde, indigoids such as indigo, sorghum, isatin, betanin, curcuminoids (such as curcumin), spinulosin, various types of chlorophyll and chlorophyllin, hematoxylin, hematein, brazilein, brazilin, safflower dyes (such as carthamin), flavonoids (such as rutin, quercetin, catechin, epicatechin, morin, apigenidin, and sandalwood), anthocyans (such as apigeninidin and apigenin), carotenoids, tannins, orceins, santalins and cochineal carmine.

[0074] The expression "synthetic direct dye" is understood to mean any dye or dye precursor that is produced by chemical synthesis.

[0075] Synthetic direct dyes are not limited as long as they are acidic direct dyes. Examples of synthetic dyes include azo, methine, carbonyl, nitro(hetero)aryl types or tri(hetero)arylmethane direct dyes, alone or as mixtures.

[0076] The ink composition may comprise at least one solvent and at least one colorant.

[0077] The solvent included in the ink composition is not particularly limited as long as it is a solvent commonly used in cosmetics, and preferably comprises water and at least one organic solvent.

[0078] The organic solvent is not limited as long as it is an organic solvent usually used in cosmetics, and is preferably selected from ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, sec-butyl alcohol, , Isobutyl alcohol, ethyl lactate, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, butylene glycol, 1 ,4-butanediol, pentanediol, 1,6-hexanediol, 1,2-hexanediol, 1,2,6-hexanetriol, hexyleneglycol, glycerol, glycerol ethoxylate, trimethylolpropane ethoxylate, sodium 2-methylpyrrolidone, caprylyl pyrrolidone, etiol, diethylene glycol methyl ether, diethylene glycol ethyl ether, triethylene glycol mono-methyl ether, triethylene glycol dimethyl ether, dimethyl sulfoxide, tetramethylene sulfone, thioglycol and polyethylene glycol having a weight average molecular weight of 150 to 1000, and more preferably at least one selected from diethylene glycol, glycerol, polyethylene glycol, isopropyl alcohol, and butylene glycol, and more preferably at least one selected from the group consisting of glycerol, isopropyl alcohol and polyethylene glycol.

[0079] The coloring agent can be used without limitation as long as it is a component commonly used in cosmetics, and may preferably include pigments and dyes.

[0080] The ink composition may contain 0.01 to 20 parts by weight, preferably 0.1 to 15 parts by weight, of the colorant(s) based on 100 parts by weight of the composition.

[0081] The ink composition of the present invention can be prepared by mixing the ingredients as explained above. In one embodiment of the present invention, the ink composition can be prepared by stirring the solvent(s), the colorant(s) and the surfactant(s) at 100 to 500 rpm, preferably 200 to 400 rpm, for 20 to 40 minutes, preferably for 25 to 35 minutes, and then filtering the mixture through a filter with a pore size of 0.1 to 0.6 pm, preferably 0.35 to 0.55 pm, to prepare the ink composition. {Step (iii)}

[0082] Step (iii) is to apply an anhydrous composition on the design applied by the ink composition, preferably the design printed by the ink composition in step (ii), to provide a coating layer on the printed design.

[0083] The application of the anhydrous composition may be performed by any means, for example, an inkjet method, a spraying method, a dropping method, or by contacting the ink composition with the keratin material using a finger, a gauze, a cotton, a sponge, a puff, a cosmetic applicator such as flocked applicator, elastomeric applicator, fiber applicator, and comb applicator.

[0084] According to one embodiment of the present invention, the anhydrous composition is applied to all of the applied, preferably printed design or a larger part than the applied, preferably printed design.

[0085] The anhydrous composition may be dried after the application to form the coating layer. The drying can be performed under an ambient condition for 0.1 to 120 seconds, preferably for 1 to 60 seconds. The drying may be performed by heating the applied anhydrous composition, or simply keeping the applied anhydrous composition under an ambient condition. The temperature of heating may range from 10 °C to 110 °C. The ambient condition here may be at a temperature ranging from 10 °C to 40 °C, in particular from 15 °C to 30 °C to and under atmospheric pressure (105Pa). In one embodiment of the present invention, there is no drying step after the step (iii).

[0086] The anhydrous composition comprises at least one oil-soluble film forming agent.

[0087] (Oil-soluble Film Forming Agent)

[0088] The anhydrous composition comprises at least one oil-soluble film forming agent. A single type of oil-soluble film forming agent may be used, or two or more different types of oilsoluble film forming agents may be used in combination.

[0089] The term “oil-soluble” here means a substance which is soluble in oil, such as isododecane, at a concentration of at least 1 % by weight, for example at least 5% by weight or 10% by weight, relative to the total weight of the oils at room temperature (25°C) and atmospheric pressure (105Pa).

[0090] The term “film-forming” means a substance that is capable of forming, by itself or in the presence of an auxiliary film-forming agent, a macroscopically continuous film that adheres to a support, where the film can show a water-resistant property.

[0091] The oil-soluble film forming agent may be oil-soluble film film-forming polymer. For the purposes of the present invention, the term “polymer” means a compound corresponding to the repetition of one or more units (these units being derived from compounds known as monomers). This or these units(s) are repeated at least twice and preferably at least three times.

[0092] The oil-soluble film forming agent can be hydrophobic, and thus can improve or enhance the durability of the anhydrous composition against water. For the present invention, the oil-soluble film forming agent is preferably selected from silicone resins.

[0093] - Silicone Resin

[0094] As the silicone resin, mention can be made of silsesquioxane, siloxysilicate and a resin obtained by hydroxysilylation. In particular, the silicone resin is selected from silsesquioxane, siloxysilicate, and mixtures thereof.

[0095] The nomenclature of the silicone resin is known in the art under the name of “MDTQ” nomenclature, by which a silicone resin is described according to the various repeating siloxane monomer moieties which constitute the polymer. Each letter of “MDTQ” corresponds to a different type of moiety.

[0096] The symbol “M” corresponds to the monofunctional moiety Rh-SiOi / z. This moiety is regarded as monofunctional because the silicon atom shares only one oxygen for the formation of the chain. The R1group indicates a hydrocarbon group, preferably an alkyl group or aryl group, and more preferably Ci-Cio alkyl group, in particular C1-C4 alkyl group, such as a methyl group, an ethyl group, a propyl group, or a butyl group. The “M” moiety can be represented by the following structure.

[0097] At least one of the methyl groups can be replaced so as to, for example, produce a moiety with the following formula: [R(CH3)2] SiOi / 2, such as that represented by the following structure: in which R is other than a methyl group.

[0098] The symbol “D” corresponds to the difunctional moiety R*2-SiO2 / 2 in which two of the available bonds on the silicon atom are used to bond with oxygen for the formation of the polymer chain. The R1group indicates the same as explained above. The “D” moiety, which is the essential component element of the dimethicone oils, can be represented by the following formula.

[0099] The symbol “T” corresponds to the trifunctional moiety R’-SiCh / z, in which three of the available bonds on the silicon atom are used to bond with oxygen for the formation of the polymer chain. The R1group indicates the same as explained above. The “T” moiety can be represented by the following structure.

[0100] As in the “M” moiety, any one of the methyl groups can be replaced in “D” or “T” by an R group which is other than methyl.

[0101] Finally, the symbol “Q” corresponds to a quadrifunctional moiety SiC>4 / 2, in which all four available bonds on the silicon atom are used to bond with oxygen for the formation of the polymer chain. The “Q” moiety can be represented by the following structure.

[0102] As described above, in one embodiment of the present invention, the silicone resin may be selected from the siloxysilicate, silsesquioxane and a resin obtained by hydroxysililation. Any siloxysilicate, silsesquioxane or resin obtained by hydroxysilylation, which acts as a film-forming polymer, can be used in the anhydrous composition of the present invention. Preferably, the silicone resin is crosslinked.

[0103] According to one embodiment of the present invention, the silicone resin may be selected from substituted siloxysilicate, silsesquioxane and resin obtained by hydroxysilylation. A substituted siloxysilicate or a substituted silsesquioxane may be, for example, a siloxysilicate or a silsesquioxane in which a methyl group has been replaced by a longer carbon chain, such as an ethane, propane or butane chain. The carbon chain may be saturated or nonsaturated.

[0104] According to one embodiment of the present invention, the silicone resin may be selected from siloxysilicate, such as MQ resins, which may substantially consist of M moieties and Q moieties. The MQ resin can be represented by the following formula:

[0105] [(R'sSiO MSiO^y (MQ moieties) in which x and y may have values ranging from 10 to 150, preferably from 20 to 120, more preferably from 40 to 100, and in particular from 50 to 80; and R1indicates a hydrocarbon group, preferably an alkyl group or an aryl group, and more preferably Ci-Cio alkyl group, in particular C1-C4 alkyl group, such as a methyl group.

[0106] According to another embodiment of the present invention, a siloxysilicate may be selected from all the combinations of M and of Q moieties such as, for example, [(R)3Si]x(SiOa / 2)y, in which R is selected from a methyl group and a longer carbon chain.

[0107] In one preferred embodiment, the siloxysilicate is trimethylsiloxysilicate, which is represented by [(CH3)3SiO]x(SiO4 / 2)y in which x and y represent from 10 to 150, preferably from 20 to 120, more preferably from 40 to 100, and in particular from 50 to 80, for example, sold by the company Momentive Performance Materials under the name SR 1000 MQ Resin.

[0108] According to another embodiment of the present invention, the silicone resin may be selected from silsesquioxane, which may substantially consist of T moieties. The silsesquioxane can be represented by the following formula:

[0109] (R*SiO3 / 2)x (T moieties), in which x has a value which can range up to several thousands and R1indicates a hydrocarbon group, preferably an alkyl group or an aryl group, and more preferably Ci-Cio alkyl group, in particular Ci-C4alkyl group, such as a methyl group.

[0110] Mention may be made, among the silsesquioxane, of the alkyl silsesquioxane resins which are silsesquioxane homopolymers and / or copolymers having an average siloxane unit of formula R2nSiO(4-n) / 2, where each R2independently denotes a hydrogen atom or a C1-C10 alkyl group, where more than 80 mol% of the R1radicals represent a C3-C10 alkyl group, and n is a number from 1.0 to 1.4, and more particularly use will be made of a silsesquioxane copolymer in which more than 60 mol% comprises R2SiO3 / 2 units in which R2has the definition indicated above.

[0111] Preferably, the silsesquioxane resin is chosen so that R2is a C1-C10 alkyl group, preferably a C2-C4 alkyl group and more particularly a propyl group. Use will more particularly be made of a poly(propyl silsesquioxane) or t-propyl silsesquioxane resin (INCI name: Polypropylsilsesquioxane (and) Isododecane), such as the product sold under the trade name Dow Corning® 670 Fluid by Dow Coming.

[0112] According to another embodiment of the present invention, the silicone resin may be selected from MQT resins, which, which may substantially consist of M moieties, T moieties, and Q moieties.

[0113] Thus, in another embodiment, the silicone resin is selected from MQ resins, T resins, and MQT resins.

[0114] The amount of the oil-soluble film forming agent(s) in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 5% by weight or more, and more preferably 10% by weight or more, relative to the total weight of the composition.

[0115] The amount of the oil-soluble film forming agent(s) in the anhydrous composition according to the present invention may be 30% by weight or less, preferably 25% by weight or less, and more preferably 20% by weight or less, relative to the total weight of the composition.

[0116] The amount of the oil-soluble film forming agent(s) in the anhydrous composition according to the present invention may be from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition.

[0117] (Optional Ingredients)

[0118] - Oil The anhydrous composition may comprise at least one oil. A single type of oil may be used, or two or more different types of oils may be used in combination.

[0119] Here, “oil” means a compound or substance which is in the form of a liquid, a paste, or a solid at room temperature (25°C) under atmospheric pressure (105Pa).

[0120] The oil may be volatile or non-volatile.

[0121] For the purpose of the present invention, the term "non-volatile oil" is intended to mean to an oil of which the vapour pressure at ambient temperature and atmospheric pressure is non-zero and is less than 103mmHg (0.13 Pa).

[0122] For the purposes of the invention, the term “volatile oil” is intended to mean any oil that is capable of evaporating on contact with the skin in less than one hour, at ambient temperature and atmospheric pressure. The volatile oil is a volatile cosmetic compound, which is liquid at ambient temperature, in particular having a non-zero vapour pressure, at ambient temperature and atmospheric pressure, in particular having a vapour pressure ranging from 0.13 Pa to 40000 Pa (IO-3to 300 mmHg), in particular ranging from 1.3 Pa to 13 000 Pa (0.01 to 100 mmHg), and more particularly ranging from 1.3 Pa to 1300 Pa (0.01 to 10 mmHg).

[0123] In this context, the volatile oil also includes an oil which has a flash point ranging from -20°C to 120°C.

[0124] It is preferable that the oil be selected from hydrocarbon oils and silicone oils.

[0125] The term “hydrocarbon oil” (or “hydrocarbonated oil”, or “hydrocarbon-based oil”) means an oil formed essentially from, or even constituted by, carbon and hydrogen atoms, and optionally oxygen and nitrogen atoms, and not containing any silicon or fluorine atoms. It may contain alcohol, ester, ether, carboxylic acid, amine and / or amide groups.

[0126] According to one preferred embodiment, the volatile hydrocarbon oil has a flash point of greater than 25°C, and better still greater than 35°C.

[0127] The volatile hydrocarbon oils may be chosen from hydrocarbon oils containing from 8 to 16 carbon atoms, and especially Cs-Cie branched alkanes (also known as isoparaffins), for instance isododecane (also called 2,2,4,4,6-pentamethylheptane), isodecane and isohexadecane, and mixture thereof.

[0128] The volatile hydrocarbon oil may also be a linear volatile alkane containing 7 to 17 carbon atoms, in particular 9 to 15 carbon atoms and more particularly 11 to 13 carbon atoms. Mention may be made especially of n-nonadecane, n-decane, n-undecane, n-dodecane, n- tridecane, n-tetradecane, n-pentadecane and n-hexadecane, and mixtures thereof.

[0129] The volatile hydrocarbon oil may preferably be selected from the group consisting of C7-10 paraffins, petrolatum, isododecane, isohexadecane, undecane, tridecane and mixtures thereof.

[0130] The term "silicone oil" here refers to an oil comprising at least one silicon atom, and especially at least one Si-0 group, and more particularly an organopoly siloxane. The silicone oil can be also represented as "silicon-based oil". The volatile silicone oil may be chosen from those having a boiling point of between 60°C and 260°C, and even more particularly from:

[0131] (i) cyclic polydialkylsiloxanes comprising from 3 to 7 and preferably 4 to 5 silicon atoms. These are, for example, octamethylcyclotetrasiloxane sold in particular under the name Volatile Silicone® 7207 by Union Carbide or Silbione® 70045 V2 by Rhodia, decamethylcyclopentasiloxane sold under the name Volatile Silicone® 7158 by Union Carbide, Silbione® 70045 V5 by Rhodia, and dodecamethylcyclopentasiloxane sold under the name Silsoft 1217 by Momentive Performance Materials, and mixtures thereof. Mention may also be made of cyclocopolymers of the type such as dimethylsiloxane / methylalkylsiloxane, such as Silicone Volatile® FZ 3109 sold by the company Union Carbide, of formula:

[0132] Mention may also be made of mixtures of cyclic polydialkylsiloxanes with organosilicon compounds, such as the mixture of octamethylcyclotetrasiloxane and tetratrimethylsilylpentaerythritol (50 / 50) and the mixture of octamethylcyclotetrasiloxane and oxy- 1 , 1 ’ -bis(2,2,2’ ,2 ’ ,3 ,3 ’ -hexatrimethylsilyloxy)neopentane; and

[0133] (ii) linear volatile polydialkylsiloxanes containing 2 to 9 silicon atoms and having a viscosity of less than or equal to 5 x 10"6m2 / s at 25°C. An example is decamethyltetrasiloxane sold in particular under the name SH 200 by the company Toray Silicone. Silicones belonging to this category are also described in the article published in Cosmetics and Toiletries, Vol. 91, Jan. 76, pp. 27-32, Todd & Byers, Volatile Silicone Fluids for Cosmetics. The viscosity of the silicones is measured at 25°C according to ASTM standard 445 Appendix C.

[0134] The volatile silicone oil may be selected from cyclic silicones, preferably selected from the group consisting of cyclopentasiloxane, cyclohexasiloxane and mixtures thereof.

[0135] The silicone oils may be organomodified. The organomodified silicones that can be used for the present invention are silicone oils as defined above and comprise in their structure one or more organofunctional groups attached via an organic group, such as hydrocarbon group.

[0136] As an organomodified silicone, mention can be made of phenyl silicones, in particular nonvolatile phenyl silicones.

[0137] Representative examples of these non-volatile phenyl silicone oils that may be mentioned include:

[0138] - the phenyl silicone oils corresponding to the following formula; in which formula (I) the groups R represent, independently of each other, a methyl or a phenyl, with the proviso that at least one group R represents a phenyl. Preferably, in this formula, the phenyl silicone oil comprises at least three phenyl groups, for example at least four, at least five or at least six,

[0139] - the phenyl silicone oils corresponding to the following formula;

[0140] R R R

[0141] R - Si - 0 - Si - 0 - Si - R

[0142] R R R (II) in which formula (II) the groups R represent, independently of each other, a methyl or a phenyl, with the proviso that at least one group R represents a phenyl. Preferably, in this formula, the said organopolysiloxane comprises at least three phenyl groups, for example at least four or at least five. Mixtures of the phenyl organopolysiloxanes described previously may be used. Examples that may be mentioned include mixtures of triphenyl, tetraphenyl or pentaphenyl organopolysiloxanes,

[0143] - the phenyl silicone oils corresponding to the following formula; in which formula (III) Me represents methyl, Ph represents phenyl. Such a phenyl silicone is especially manufactured by Dow Corning under the reference PH-1555 HRI or Dow Corning 555 Cosmetic Fluid (chemical name: l,3,5-trimethyl-l,l,3,5,5-pentaphenyl trisiloxane; INCI name: trimethyl pentaphenyl trisiloxane). The reference Dow Coming 554 Cosmetic Fluid may also be used,

[0144] - the phenyl silicone oils corresponding to the following formula; l e Me in which formula (IV) Me represents methyl, y is between 1 and 1000 and X represents -CH2- CH(CH3)(Ph).

[0145] - the phenyl silicone oils corresponding to formula (V) below; in which formula (V) Me is methyl and Ph is phenyl, OR' represents a group -OSiMes and y is 0 or ranges between 1 and 1000, and z ranges between 1 and 1000, such that compound (V) is a non-volatile oil. According to a first embodiment, y ranges between 1 and 1000. Use may be made, for example, of trimethyl siloxyphenyl dimethicone, sold especially under the reference Belsil PDM 1000 sold by the company Wacker. According to a second embodiment, y is equal to 0. Use may be made, for example, of phenyl trimethylsiloxy in which formula (VI):

[0146] - Ri to Rio, independently of each other, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon-based radicals,

[0147] - m, n, p and q are, independently of each other, integers between 0 and 900, with the proviso that the sum m+n+q is other than 0; preferably, the sum m+n+q is between 1 and 100. Preferably, the sum m+n+p+q is between 1 and 900 and better still between 1 and 800. Preferably, q is equal to 0,

[0148] - the phenyl silicone oils corresponding to formula (VII) below, and mixtures thereof; in which formula (VII):

[0149] - Ri to Re, independently of each other, are saturated or unsaturated, linear, cyclic or branched C1-C30 hydrocarbon-based radicals,

[0150] - m, n and p are, independently of each other, integers between 0 and 100, with the proviso that the sum n+m is between 1 and 100; preferably, Ri to Re, independently of each other, represent a saturated, linear or branched C1-C30 and especially C1-C12 hydrocarbon-based radical and in particular a methyl, ethyl, propyl or butyl radical; Ri to Re may especially be identical, and in addition may be a methyl radical; Preferably, m = 1 or 2 or 3, and / or n = 0 and / or p = 0 or 1 may apply, in formula (VII),

[0151] - the phenyl silicone oils corresponding to formula (VIII), and mixtures thereof: in which formula (VIII):

[0152] - R is a C1-C30 alkyl radical, an aryl radical or an aralkyl radical,

[0153] - n is an integer ranging from 0 to 100, and

[0154] - m is an integer ranging from 0 to 100, with the proviso that the sum n+m ranges from 1 to 100. In particular, the radicals R of formula (VIII) and Ri to Rio defined previously may each represent a linear or branched, saturated or unsaturated alkyl radical, especially of C2- C20, in particular C3-C16 and more particularly C4-C10, or a monocyclic or polycyclic Cs-Cu and especially C10-C13 aryl radical, or an aralkyl radical whose aryl and alkyl residues are as defined previously. Preferably, R of formula (VIII) and Ri to Rio may each represent a methyl, ethyl, propyl, isopropyl, decyl, dodecyl or octadecyl radical, or alternatively a phenyl, tolyl, benzyl or phenethyl radical. According to one embodiment, a phenyl silicone oil of formula (VIII) with a viscosity at 25°C of between 5 and 1500 mm2 / s (i.e. 5 to 1500 cSt), and preferably with a viscosity of between 5 and 1000 mm2 / s (i.e. 5 to 1000 cSt) may be used.

[0155] As phenyl silicone oils of formula (VIII), it is especially possible to use phenyl trimethicones such as DC556 from Dow Corning (22.5 cSt), the oil Silbione 70663V30 from Rhone- Poulenc (28 cSt) or diphenyl dimethicones such as Belsil oils, especially Belsil PDM1000 (1000 cSt), Belsil PDM 200 (200 cSt) and Belsil PDM 20 (20 cSt) from Wacker. The values in parentheses represent the viscosities at 25°C.

[0156] - the phenyl silicone oils corresponding to the following formula, and mixtures thereof: in which formula (IX):

[0157] Ri, R2, Rs and Re are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, together or separately, an alkyl radical containing from 1 to 6 carbon atoms or an aryl radical,

[0158] X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or a vinyl radical, n and p being chosen so as to give the oil a weight-average molecular mass of less than 200 000 g / mol, preferably less than 150 000 g / mol and more preferably less than 100 000 g / mol.

[0159] The phenyl silicones that are most particularly suitable for use in the present invention may be those corresponding to formulae (II) and especially to formulae (III), (V) and (VIII) hereinabove. More particularly, the phenyl silicones may be chosen from phenyl trimethicones, phenyl dimethicones, phenyl-trimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes and 2-phenylethyl trimethylsiloxysilicates, and mixtures thereof.

[0160] Preferably, the weight-average molecular weight of the phenyl silicone oil used according to the present invention may range from 500 to 10 000 g / mol.

[0161] The amount of the oil(s) in the anhydrous composition may be 10% by weight or more, preferably 15% by weight or more, and more preferably 20% by weight or more, relative to the total weight of the anhydrous composition.

[0162] The amount of the oil(s) in the anhydrous composition may be 60% by weight or less, preferably 55% by weight or less, and more preferably 50% by weight or less, relative to the total weight of the composition.

[0163] The amount of the oil(s) in the anhydrous composition may be from 10% to 60% by weight, preferably from 15% to 55% by weight, and more preferably from 20% to 50% by weight, relative to the total weight of the anhydrous composition.

[0164] - Silicone Gum

[0165] The anhydrous composition of the present invention may comprise at least one silicone gum. If two or more silicone gums are used, they may be the same or different.

[0166] The silicone gum may have a dynamic viscosity at 25 °C of 400,000 cSt or more, preferably 600,000 cSt or more, and more preferably 800,000 cSt or more.

[0167] The silicone gum may have a dynamic viscosity at 25 °C of 10,000,000 cSt or less, preferably 5,000,000 cSt or less, and more preferably 3,000,000 cSt or less.

[0168] The silicone gum may have a dynamic viscosity at 25 °C of from 300,000 to 10,000,000 cSt, preferably from 500,000 to 5,000,000 cSt or less, and more preferably from 700,000 to 3,000,000 cSt.

[0169] The dynamic viscosity of the silicone gum can be measured according to standard ASTM D- 445.

[0170] It may be preferable that the silicone gum has no functional group such as an amino group.

[0171] The silicone gum may be chosen especially from the silicones of formula: in which: Rl, R2, R5 and R6 are, together or separately, an alkyl radical containing 1 to 6 carbon atoms, R3 and R4 are, together or separately, an alkyl radical containing from 1 to 6 carbon atoms, a vinyl radical, an amine radical or a hydroxyl radical,

[0172] X is an alkyl radical containing from 1 to 6 carbon atoms, a hydroxyl radical or an amine radical, and n and p being integers chosen such that the dynamic viscosity at 25 °C of the compound is 400,000 cSt or more, preferably 600,000 cSt or more, and more preferably 800,000 cSt or more.

[0173] As silicone gums that may be used according to the present invention, mention may be made of those for which:

[0174] - the substituents Rl to R6 represent a methyl group, the group X represents a methoxy group, and n and p are such that the molecular weight of the polymer is 600 000 g / mol, such as the product sold under the name Mirasil C-DPDM by the company Bluestar;

[0175] - the substituents Rl to R6 represent a methyl group, the group X represents a hydroxyl group, and n and p are such that the molecular weight of the polymer is 600 000 g / mol, such as the product sold under the name SGM 36 by the company Dow Coming; and

[0176] - dimethicones of the (polydimethylsiloxane) (methylvinylsiloxane) type, such as SE63 sold by GE Bayer Silicones, poly(dimethylsiloxane)(diphenyl)(methylvinylsiloxane) copolymers, and mixtures thereof.

[0177] The molecular mass of the silicone gum may be greater than 350,000 g / mol, between 350,000 and 800,000 g / mol, and preferably from 450,000 to 700,000 g / mol.

[0178] It is preferable that the silicone gum be selected from polydimethylsiloxane gum.

[0179] The amount of the silicone gum in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 3% by weight or more, and more preferably 5% by weight or more, relative to the total weight of the composition.

[0180] The amount of the silicone gum in the anhydrous composition according to the present invention may be 25% by weight or less, preferably 20% by weight or less, and more preferably 15% by weight or less, relative to the total weight of the composition.

[0181] Thus, the amount of the silicone gum in the anhydrous composition according to the present invention may be from 1% to 25% by weight, preferably from 3% to 20% by weight, and more preferably from 5% to 15% by weight, relative to the total weight of the composition.

[0182] - Filler

[0183] The anhydrous composition may comprise at least one filler. If two or more fillers are used, they may be the same or different.

[0184] The term “filler” should be understood as meaning mineral or synthetic particles of any shape, which are insoluble in the medium of the anhydrous composition, irrespective of the temperature at which the composition is manufactured.

[0185] The filler(s) of the present invention can increase a thickness of the anhydrous layer formed by the anhydrous composition. The filler may be of any shape, platelet-shaped, spherical or oblong, irrespective of the crystallographic form (for example lamellar, cubic, hexagonal, orthorhombic, etc.).

[0186] The filler can be inorganic or organic powder, which may or may not be surface-coated.

[0187] The average particle size of the filler is not limited, but in general is 100 pm or less, preferably 50 pm or less, and more preferably 10 pm or less. The average particle size of the filler is 0.01 pm or more, preferably 0.05 pm or more, and more preferably 0.1 pm or more. The term “average particle size” used herein represents a number-average size mean diameter which is given by the statistical particle size distribution to half of the population, referred to as D50. For example, the number-average size mean diameter can be measured by a laser diffraction particle size distribution analyzer, such as Mastersizer 2000 by Malvern Corp.

[0188] As the inorganic filler, mention may be made of talc, mica, silica, magnesium aluminium silicate, silica aerogel, such as silica silylate, kaolin, bentone, calcium carbonate, magnesium hydrogen carbonate, hydroxyapatite, boron nitride, fluorphlogopite, sericite, calcinated talc, calcinated mica, calcinated sericite, synthetic mica, perlite, metal soap, bismuth oxychloride, barium sulfate, magnesium carbonate, magnesium hydrocarbonate, hydroxyapatite, hollow silica microspheres (Silica Beads® from Maprecos), glass or ceramic microcapsules, and mixtures thereof, optionally hydrophilic- or hydrophobic-treated. The metal soap can be metal soaps derived from organic carboxylic acids containing from 8 to 22 carbon atoms, preferably from 12 to 18 carbon atoms, for example, zinc stearate, magnesium stearate, lithium stearate, zinc laurate, or magnesium myristate.

[0189] As the organic filler, mention may be made of acrylic polymer powders, silicone powders, polyamide powders, urethane polymer powders, tetrafluoroethylene polymer powders, polyacrylonitrile powders, poly-p-alanine powders, polyethylene powders, polytetrafluoroethylene powders, lauroyl lysine, starch, cellulose powder, tetrafluoroethylene polymer powders, hydrophobically-modified starch, and mixtures thereof.

[0190] As the acrylic polymer powders, mention may be made of polymethyl methacrylate powders, polymethyl methacrylate / ethylene glycol dimethacrylate powders, polyallyl methacrylate / ethylene glycol dimethacrylate powders, lauryl methacrylate / ethylene glycol dimethacrylate powders, acrylate / ethylhexyl acrylate powders, and expanded hollow particles of acrylonitrile (co-) polymer, such as acrylonitrile / methacrylate / vinylidene chloride copolymer.

[0191] As examples of the acrylic polymer powder, mention may be made of: powder of crosslinked polymethyl methacrylate, for instance “Covabead LH85” sold by the company LC Wackherr, or of noncrosslinked polymethyl methacrylate, such as SJ Touch 1 sold by the company Nihon Junyaku; powder of methyl methacrylate / butyl acrylate copolymer sold under the name Sepipress M by the company Seppic; powder of methyl acrylate / ethylene copolymer sold under the name EMAA by the company Kobo Products Inc.; powder of methyl methacrylate / ethylene glycol dimethacrylate crosslinked copolymer sold under the name Ganzpearl GMP 0820 by the company Ganz Chemical, under the name Techpolymer MBP-8 by the company Sekisui Plastics, or else under the name SUNPMMA-S by the company Sunjin Chemical; powder of polymethyl methacrylate / ethylene glycol dimethacrylate, for example “Dow Coming 5640 Microsponge Skin Oil Adsorber” sold by the company Dow Coming; powder of methyl methacrylate / ethylene glycol dimethacrylate crosslinked copolymer sold under the name Ganzpearl PM 030 by the company Ganz Chemical; powder of polyallyl methacrylate / ethylene glycol dimethacrylate, for instance “Poly-Pore L200” or “Poly-Pore E200” sold by the company Amcol, powder of lauryl methacrylate / ethylene glycol dimethacrylate copolymer, for instance "Polytrap 6603" sold by the company Dow Coming; powder of acrylate / ethylhexyl acrylate copolymer, for instance "Techpolymer ACP-8C" sold by the company Sekisui Plastics; powder of acrylonitrile / methacrylate / vinylidene chloride copolymer sold under the name Expancel by the company Expancel under the references 551 DE 50, 551 DE 20, 551 DE 12, 551 DE 80, and 461 DE 50.

[0192] As the polyurethane powders, mention may be made of powders of crosslinked polyurethane comprising a copolymer, the said copolymer comprising trimethylol hexyl lactone, for instance the hexamethylene diisocyanate / trimethylol hexyl lactone polymer sold under the name Plastic Powder D-400® or Plastic Powder D-800® by the company Toshiki.

[0193] As the silicone powders, mention may be made of organopolysilsesquioxane powders, organopolysiloxane powders, and silicone resin powders.

[0194] The organopolysilsesquioxane powders are preferably polymethylsilsesquioxane powders. Materials sold by the company Momentive Performance Materials, under the tradename "TOSPEARL" and materials sold by NIKKO RICA under the name MSP-N050 and MSP- N080 are examples of such polymethylsilsesquioxane powders.

[0195] The organopolysiloxane powders may be elastomeric or non-elastomeric. It is preferable to use elastomeric organopolysiloxane powder or organopolysiloxane elastomer powder.

[0196] The elastomeric organopolysiloxane may, for example, be crosslinked and may be obtained via a crosslinking addition reaction of diorganopolysiloxane comprising at least one hydrogen linked to silicon and of diorganopolysiloxane comprising at least one ethylenically unsaturated group linked to silicon, preferably, in the presence of, for example, a platinum catalyst; or via a dehydrogenation crosslinking condensation reaction between a diorganopolysiloxane comprising at least one hydroxyl end group and a diorganopolysiloxane comprising at least one hydrogen linked to silicon, preferably, in the presence of, for example, an organotin compound; or via a crosslinking condensation reaction of a diorganopolysiloxane comprising at least one hydroxyl end group and of a hydrolysable organopolysilane; or via thermal crosslinking of organopolysiloxane, preferably, in the presence of, for example, an organoperoxide catalyst; or via crosslinking of organopolysiloxane by high-energy radiation such as gamma rays, ultraviolet rays or an electron beam.

[0197] Elastomer organopolysiloxane powders that may be used include those sold under the names "Dow Coming 9505 Powder" and "Dow Coming 9506 Powder" by the company Dow Coming. These powders have the INCI name: dimethicone / vinyl dimethicone crosspolymer. The elastomeric organopolysiloxane powder may, for example, be chosen from elastomeric organopolysiloxane powders coated with silicone resin, for example, with silsesquioxane resin, as described, for example, in U.S. Patent No. 5,538,793, the content of which is incorporated by reference. Such elastomeric powders are sold under the names "KSP-100", "KSP-101", "KSP-102", "KSP-103", "KSP-104" and "KSP-105" by the company Shin-Etsu, and have the INCI name: vinyl dimethicone / methicone silsesquioxane crosspolymer.

[0198] Other elastomeric organopolysiloxanes in the form of spherical powders may be powders of hybrid silicone functionalized with fluoroalkyl groups, sold, for example, under the name "KSP-200" by the company Shin-Etsu and powders of hybrid silicones functionalized with phenyl groups, sold, for example, under the name "KSP-300" by the company Shin-Etsu.

[0199] As the polyamide powders, mention may be made of those sold under the name "Orgasol" by the company Atochem. These polyamide powder particles are moreover known according to their various physicochemical properties under the name “Nylon 12” or “Nylon 6”. The polyamide powders useful in the present invention may also include those sold under the name SP500 by the company TORAY.

[0200] The hydrophobical ly-modified starches may be esterified starches. The term “hydrophobically-modified” means that, at least, the surface of starches has been treated to be hydrophobic.

[0201] The esterified starch preferably used in the present invention may be selected from the group consisting of phosphorylated starch, starch acetate, oxidized starch acetate, starch laurate, sodium starch phosphate, alkyl or alkenyl succinated starch, such as calcium starch octenylsuccinate, sodium starch octenylsuccinate, aluminum starch octenylsuccinate which is the starch esterified with octenylsuccinic anhydride and salts thereof, for example, sold under the name “Dry Flo Plus” from AKZO NOVEL, the potato starch esterified with a carboxymethyl group, sold under the name “Supramyl P 60” by Amylum, the com starch esterified with a hydroxypropyl group, sold under the name “Merigel EF6” by Amylum, the com starch esterified with dodecenylsuccinic anhydride (INCI name: CORN STARCH MODIFIED), and the potato starch esterified with halogenated methyl amino dipropionate acid (INCI name: POTATO STARCH MODIFIED).

[0202] As the preferred filler of the present invention, mention can be made of inorganic fillers, in particular spherical inorganic fillers, such as silica, silica silylate, and hollow silica microsphere, and hydrophobically-modified starch, such as esterified starch powders, and mixtures thereof.

[0203] The amount of the filler(s) in the anhydrous composition of the present invention may be 1% by weight or more, preferably 5% by weight or more, and more preferably 10% by weight or more, relative to the total weight of the composition.

[0204] The amount of the filler(s) in the anhydrous composition of the present invention may be 30% by weight or less, preferably 25% by weight or less, and more preferably 20% by weight or less, relative to the total weight of the composition.

[0205] Thus, the amount of the filler(s) in the anhydrous composition of the present invention may be from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition. - Lipophilic Gelling Agent

[0206] The anhydrous composition of the present invention may comprise at least one lipophilic gelling agent. If two or more lipophilic gelling agents are used, they may be the same or different.

[0207] The term "lipophilic gelling agent" means an agent capable of increase viscosity of the anhydrous composition, leading an increase of the coating layer formed by the anhydrous composition.

[0208] The term “lipophilic” here means a substance which is soluble in oil, such as isododecane, at a concentration of at least 1 % by weight, for example at least 5% by weight or 10% by weight, relative to the total weight of the oils at room temperature (25°C) and atmospheric pressure (105Pa).

[0209] The composition according to the present invention comprises at least one lipophilic gelling agent which is preferably particulate.

[0210] The term “particulate” lipophilic gelling agent means a lipophilic gelling agent in the form of particles or of crystals (particulate or crystalline).

[0211] According to the present invention, the lipophilic gelling agent is preferably selected from organomodified clays.

[0212] The clay denotes a material based on hydrated silicates and / or aluminosilicates, of lamellar structure.

[0213] The clays can be natural or synthetic, and they are rendered lipophilic by treatment with an alkylammonium salt, such as a CIO to C22 ammonium chloride, in particular stearalkonium chloride or distearyldimethylammonium chloride.

[0214] They may be chosen from bentonites, in particular bentonites, hectorites and montmorillonites, beidellites, saponites, nontronites, sepiolites, biotites, attapulgites, vermiculites and zeolites.

[0215] Organomodified clays may be clays treated with compounds chosen especially from quaternary amines and tertiary amines. Organomodified clays that may be mentioned include organomodified bentonites, such as the product sold under the name Bentone 34 by the company Rheox, and organomodified hectorites such as the products sold under the names Bentone 27 and Bentone 38 by the company Rheox. Mention may be made especially of modified clays such as modified magnesium silicate (Bentone gel VS38 from Rheox), modified hectorites such as hectorite modified with a CIO to C22 fatty acid ammonium chloride, for instance hectorite modified with distearyldimethylammonium chloride, for instance the product sold under the name Bentone 38VCG by the company Elementis or the product sold under the name Bentone 38 CE by the company Rheox, or the product sold under the name Bentone Gel V5 5V by the company Elementis.

[0216] The lipophilic gelling agents may also be selected from hydrophobic fumed silicas, which may be obtained by modification of the surface of the silica via a chemical reaction that generates a reduction in the number of silanol groups, these groups possibly being substituted especially with hydrophobic groups. The hydrophobic groups can be trimethylsiloxyl groups, which are obtained especially by treating fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are known as "Silica silylate" according to the CTFA Dictionary (6th edition, 1995). They are sold, for example, under the references Aerosil R812® by the company Degussa and Cab-O-Sil TS-530® by the company Cabot. The hydrophobic groups can be dimethylsilyloxyl or polydimethylsiloxane groups, which are obtained especially by treating fumed silica in the presence of polydimethylsiloxane or dimethyldichlorosilane. Silicas thus treated are known as "Silica dimethyl silylate" according to the CTFA Dictionary (6th edition, 1995). They are sold, for example, under the references Aerosil R972® and Aerosil R974® by the company Degussa and Cab-O-Sil TS- 610® and Cab-O-Sil TS-720® by the company Cabot.

[0217] The lipophilic gelling agents may also be selected from hydrophobic silica aerogels, such as the products sold under the name VM-2260 (INCI name: Silica silylate) by the company Dow Corning, the particles of which have a mean size of about 1000 microns and a specific surface area per unit of mass ranging from 600 to 800 m2 / g; mention may also be made of the aerogels sold by the company Cabot under the references Aerogel TLD 201 , Aerogel OGD 201, Aerogel TLD 203, Enova® Aerogel MT 1100, EnovaAerogel MT 1200.

[0218] The lipophilic gelling agents also may be selected from lipophilic polymer thickeners which may be chosen from carboxyvinyl polymers such as the Carbopol products (carbomers) and the Pemulen products (acrylate / C10-C30-alkyl acrylate copolymer) or polymers having the INCI name "Poly C10-30 Alkyl Acrylate", such as the Intelimer® products from Air Products, such as the product Intelimer® IPA 13-1, which is a polystearyl acrylate, or the product 30 Intelimer® IPA 13-6 which is a behenyl polymer.

[0219] It may be preferable that the lipophilic gelling agent be an organomodified clays, in particular disteardimonium hectorite.

[0220] The amount of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention may be 1% by weight or more, preferably 3% by weight or more, and more preferably 5% by weight or more, relative to the total weight of the composition.

[0221] The amount of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention may be 14% by weight or less, and may be preferably 12% by weight or less, and more preferably 10% by weight or less, relative to the total weight of the composition.

[0222] Thus, the amount of the lipophilic gelling agent(s) in the anhydrous composition according to the present invention may be from 1% to 14% by weight, preferably from 3% to 12% by weight, and more preferably from 5% to 10% by weight, relative to the total weight of the composition.

[0223] - Additives

[0224] The anhydrous composition may also comprise any other additive(s) usually used in the field of cosmetics, chosen from, for example, solvents, resins, dispersants, surfactants, thickening agents, antioxidants, preserving agents, fragrances, UV-screening agents, and mixtures thereof. The total amount of the additive(s) in the anhydrous composition of the present invention may be from 0.01% to 30% by weight, preferably from 0.05% to 20% by weight, and more preferably from 0.1% to 15% by weight, relative to the total weight of the composition.

[0225] The anhydrous composition of the present invention can be prepared by mixing the oilsoluble film forming agent, as essential ingredients, as well as other optional ingredient(s), as explained above.

[0226] According to a preferred embodiment, the process according to the invention is a process comprising the steps of:

[0227] (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material;

[0228] (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and

[0229] (iii) applying an anhydrous composition on the ink design, preferably on the printed ink design to provide a coating layer on the ink design, wherein the anhydrous composition comprises, relative to the total weight of the composition, from 1% to 30% by weight of the at least one oil-soluble film forming agent selected from silicone resins.

[0230] According to a preferred embodiment, the process according to the invention is a process comprising the steps of:

[0231] (i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material;

[0232] (ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and

[0233] (iii) applying an anhydrous composition on the ink design, preferably the printed ink design to provide a coating layer on the ink design, wherein the anhydrous composition comprises, relative to the total weight of the composition, from 10% to 20% by weight of the at least one oil-soluble film forming agent selected from silsesquioxane, siloxysilicate, and mixtures thereof.

[0234] [Composition]

[0235] The present invention relates to an anhydrous composition comprising at least one oil-soluble film forming agent, for use in providing a design applied by an ink composition, preferably a design printed by an ink composition on the keratin material with improved water resistance.

[0236] The ink deposit can be the ink layer or the printed ink as a temporary tattoo explained above. Thus, the composition according to the present invention is the anhydrous composition as explained in the process according to the present invention above.

[0237] The composition according to the present invention can be used in improving water resistance of the ink deposit printed on the keratin material.

[0238] The oil-soluble film forming agent in the anhydrous composition is the same as those explained in the anhydrous composition in the process according to the present invention above. In addition, the anhydrous composition according to the present invention can include other optional ingredients those explained in the anhydrous composition in the process according to the present invention above. Also, the anhydrous composition according to the present invention can be prepared as explained in the anhydrous composition in the process according to the present invention above.

[0239] [Use]

[0240] The present invention relates to a use of the anhydrous composition according to the present invention for providing the ink deposit applied, preferably printed on the keratin material with improved water resistance.

[0241] Thus, the present invention also relates to a use of the anhydrous composition according to the present invention for improving water resistance of the ink deposit applied, preferably printed on the keratin material.

[0242] The use of the anhydrous composition of the present invention is as described in the process and composition according to the present invention above.

[0243] EXAMPLES

[0244] The present invention will be described in a more detailed manner by way of examples.

[0245] However, these examples should not be construed as limiting the scope of the present invention. The examples below are presented as non-limiting illustrations in the field of the present invention.

[0246] (Manufacturing Procedure)

[0247] A primer composition used in the examples was prepared by mixing the ingredients listed in Table 1 below until it became homogeneous. The numerical values for the amounts of the ingredients are all based on “% by weight” as active raw materials.

[0248] Table 1

[0249] An ink composition used in the examples was prepared by mixing the ingredients listed in Table 2 below until it became homogeneous. The numerical values for the amounts of the ingredients are all based on “% by weight” as active raw materials. Table 2

[0250] Anhydrous compositions 1 and 2 were prepared by mixing the ingredients shown in Table 3 until they became homogeneous. The numerical values for the amounts of the ingredients are all based on “% by weight” as active raw materials.

[0251] Example 1

[0252] The primer composition was filled in a plunged applicator. The ink composition was placed in a cartridge of a skin transfer printer (Prinker M, Prinker). Anhydrous composition 1 was filled in a plunged applicator. The primer composition was applied to a face with a flocky tip, then dried at 25°C for 1 minute, to prepare a primer layer on the facial skin. The design was then printed on the primer layer with the ink composition by using a skin transfer printer (Prinker M, Prinker), then the design was dried at 25°C for 1 minute. Finally, the coating composition was applied to the printed design, dried 1 minute to form a coating layer on the design. All steps were done at 25°C.

[0253] Comparative Example 1 Example 1 was repeated, but the anhydrous composition 2 was used instead of the anhydrous composition 1.

[0254] Comparative Example 2

[0255] Example 1 was repeated, but no anhydrous composition was used. Thus, in this comparative example, no coating layer was prepared.

[0256] [Evaluations]

[0257] (Water resistance)

[0258] Water resistance was evaluated for each of Examples 1 and 2 and Comparative Example 1. Specifically, 5 minutes after the final printing, 10 ml of water was applied to each of the samples at a rate of 1 ml / s. After rubbing 5 times with a tester (Rub. Tester, Sketch-On), the ratio of the remaining area to the area before rubbing was measured. The evaluation was made under the following criteria.

[0259] Good: More than 90% of the area was remained.

[0260] Fair: 70 to 90% of the area was remained.

[0261] Bad: Less than 70% of the area was remained.

[0262] The results are shown in Table 4.

[0263] Table 4

[0264] As shown in Table 4, the process according to the present invention using the anhydrous composition of the present invention could improve water resistance of the ink deposition.

[0265] On the other hand, the process according to Comparative Example 1 , which did not use an anhydrous composition of the present invention, could not exhibit improved water resistance. In addition, the process according to Comparative Example 2, which lacked the step of applying anhydrous composition of the present invention, could not exhibit improved water resistance.

[0266] Accordingly, it can be it can be concluded that the process according to present invention can make up design printed with an ink composition on keratin material, such as temporary tattoo, with an improved water resistance.

Claims

CLAIMS1. A process comprising the steps of:(i) optionally applying a primer composition on a keratin material to provide a primer layer on the keratin material;(ii) applying an ink composition on the primer layer if the step (i) is carried out, or on a keratin material if the step (i) is not carried out, to provide an ink design, preferably to print an ink design on the primer layer or the keratin material; and(iii) applying an anhydrous composition on the ink design, preferably on the printed ink design to provide a coating layer on the ink design, wherein the anhydrous composition comprises at least one oil-soluble film forming agent.

2. The process according to Claim 1, wherein the oil-soluble film forming agent comprises at least one silicone resin.

3. The process according to Claim 2, wherein the silicone resin is selected from silsesquioxane, siloxysilicate, and mixtures thereof.

4. The process according to any one of Claims 1 to 3, wherein the anhydrous composition further comprises at least one oil.

5. The process according to Claim 4, wherein the oil comprises at least one hydrocarbon oil and / or at least one silicone oil.

6. The process according to Claim 4 or 5, wherein the oil is non-volatile or non-volatile.

7. The process according to any one of Claims 43 to 6, wherein the oil is present in the anhydrous composition in an amount of from 10% to 70% by weight, preferably from 15% to 65% by weight, and more preferably from 20% to 60% by weight, relative to the total weight of the composition.

8. The process according to any one of Claims 1 to 7, wherein the oil-soluble film forming agent is present in the anhydrous composition in an amount of from 1% to 30% by weight, preferably from 5% to 25% by weight, and more preferably from 10% to 20% by weight, relative to the total weight of the composition.

9. The process according to any one of Claims 1 to 8, wherein the ink composition comprises at least one solvent and at least one colorant.

10. The process according to any one of Claims 1 to 9, wherein the primer composition comprises at least one water-soluble polymer.

11. The process according to any one of Claims 1 to 10, being a process of printing a temporary tattoo on the keratin material.

12. The composition according to any one of Claims 1 to 11, wherein the anhydrous composition further comprises at least one silicone gum.

13. The composition according to any one of Claims 1 to 12, wherein the anhydrouscomposition further comprises at least one filler and / or lipophilic gelling agent.

14. An anhydrous composition comprising at least one oil-soluble film forming agent, for use in providing an ink design applied, preferably printed on a keratin material with improved water resistance.

15. A use of the composition according to Claim 14, for making up the ink design on the keratin material with improved water resistance.

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