A graphite-phase carbon nitride composite material covalently modified by a polymethyl methacrylate polymer containing a porphyrin group at the end group and a preparation method thereof
By covalently bonding porphyrin polymers with g-C3N4, the prepared composite material solves the application difficulties of g-C3N4 in nonlinear optical devices, achieves good dispersibility and nonlinear optical properties, and is suitable for the practical application of nonlinear optical devices.
Patent Information
- Application Number
- CN202411328647.7
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-09-24
- Publication Date
- 2025-09-19
- Estimated Expiration
- 2044-09-24
AI Technical Summary
The application of graphitic carbon nitride (g-C3N4) in nonlinear optical devices is limited by problems such as high photogenerated electron-hole pair recombination rate, narrow visible light absorption edge and poor dispersibility in organic solvents. Existing modification research has not yet effectively solved its practical application difficulties.
By covalently bonding porphyrin polymer with g-C3N4, a graphite phase carbon nitride composite material covalently modified with polymethyl methacrylate polymer containing porphyrin groups at the end groups was prepared. The polymer properties of porphyrin were utilized to improve its solubility and aggregation in the medium, thereby enhancing the nonlinear optical properties.
The prepared composite material has good dispersibility in solid organic reagents, exhibits good anti-saturation absorption characteristics and nonlinear optical properties, and is suitable for practical applications in nonlinear optical devices.