Ultra-white and ultra-thick float glass and preparation method thereof

Through specific raw material combination and process optimization, the shortcomings of ultra-white and ultra-thick float glass in terms of light transmittance and mechanical properties are solved, and the production of high-performance ultra-white and ultra-thick float glass is realized.

CN120364948AActive Publication Date: 2025-07-25SHANDONG JINJING SCIENCE & TECHNOLOGY STOCK CO LTD +1
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Patent Information

Application Number
CN202510874197.X
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2025-06-27
Publication Date
2025-07-25
Estimated Expiration
2045-06-27

AI Technical Summary

Technical Problem

It is difficult for the prior art to produce ultra-white ultra-thick float glass with the same performance as the balanced thickness, especially when producing thicknesses of 19 mm or above, there are problems of insufficient light transmittance and mechanical properties.

Method used

The dense glass network structure is constructed using quartz sand, dodecanoic acid heptaalaluminate, titanium oxide whiskers, lanthanum hexaboride, barite, and lithium hydroxide as the main raw materials. A mixture of Ca3(SbO4)2, Mg2SnO4, zinc selenite and neodymium oxide is used as the clarification decolorizer. Through four-stage gradient melting, four-stage reduction and seven-stage ladder annealing processes, the network structure is optimized and internal stress is eliminated.

Benefits of technology

The high light transmittance and good bending strength of ultra-white and ultra-thick float glass are achieved, ensuring the stability of the mechanical properties and optical properties of the glass.

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Abstract

The invention belongs to the technical field of glass preparation, and particularly relates to ultra-white and ultra-thick float glass and a preparation method thereof. The ultra-white and ultra-thick float glass is prepared from the following raw materials: quartz sand, dodecacalcium heptaaluminate, titanium oxide whiskers, lanthanum hexaboride, barite, lithium hydroxide, Ca3 (SbO4) 2, Mg2SnO4, zinc selenite and neodymium oxide. According to the ultra-white and ultra-thick float glass, quartz sand, dodecacalcium heptaaluminate, titanium oxide whiskers, lanthanum hexaboride, barite and lithium hydroxide are used as main raw materials to construct a compact glass network structure, the mechanical performance of the ultra-white and ultra-thick float glass is ensured, a mixture of Ca3 (SbO4) 2, Mg2SnO4, zinc selenite and neodymium oxide is used as a clarification decolorizing agent, and the ultra-white and ultra-thick float glass is obtained. And the light transmittance of the prepared ultra-white and ultra-thick float glass is ensured. Therefore, the synergistic effect of the raw materials ensures that the prepared glass has very good bending strength and light transmittance.
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