Ether metal complex as well as preparation method and application thereof

By combining ether-based metal complex catalysts with low-cost co-catalysts, the problems of low activity and high cost of existing olefin catalysts have been solved, enabling the efficient preparation and molecular weight control of low molecular weight polyethylene.

CN122103188APending Publication Date: 2026-05-29CHINA ENERGY GRP NINGXIA COAL IND CO LTD +2
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Patent Information

Application Number
CN202610026262.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-01-09
Publication Date
2026-05-29

AI Technical Summary

Technical Problem

Existing olefin catalysts exhibit low catalytic activity, low ethylene monomer utilization, wide molecular weight distribution of polyethylene wax, and high cost in olefin polymerization reactions. In particular, metallocene catalysts require harsh conditions and are expensive co-catalysts in the production of low molecular weight polyethylene.

Method used

Ether-based metal complexes were used as catalysts to prepare complexes containing sterically hindered substituents via complexation reactions. Inexpensive co-catalysts such as sesquiethylaluminum chloride were combined to regulate the molecular weight and distribution of the polymer.

Benefits of technology

The method achieves efficient preparation of low molecular weight polyethylene under mild reaction conditions, with a simple synthesis process, low cost, high catalytic activity, good thermal stability, and strong polymer molecular weight control performance.

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Abstract

The invention relates to the technical field of olefin polymerization, and discloses an ether metal complex as well as a preparation method and application thereof. The structural formula of the ether metal complex is as shown in formula (I), wherein R1, R2, R3 and R4 are respectively and independently selected from one of hydrogen, C1-C10 alkyl and halogen; each X is selected from O or S; m is selected from IVB group metal. The ether metal complex is used as a catalyst to be applied to ethylene polymerization reaction, has high reaction activity and good thermal stability, shows extremely strong regulation and control performance on the molecular weight of polyethylene wax, and obtains highly linear low-molecular-weight polyethylene. Formula (I)
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