Method for inducing crystal transformation of phosphogypsum by coupling biological-inorganic inducer

By using a biological-inorganic inducing agent coupling method to regulate the nucleation and growth of phosphogypsum crystals, the problems of low conversion rate and long reaction time in the phosphogypsum crystallization process were solved, and efficient and low-consumption phosphogypsum resource utilization was achieved.

CN122403485APending Publication Date: 2026-07-17HUBEI THREE GORGES LAB
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Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
HUBEI THREE GORGES LAB
Filing Date
2026-04-01
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing phosphogypsum crystallization processes suffer from low conversion rates, long reaction times, and poor product quality, making it difficult to achieve high-efficiency, low-consumption, and environmentally friendly high-value-added utilization.

Method used

A biological-inorganic inducing agent coupling method was adopted. After calcium oxide pretreatment, inorganic inducing agents such as lysine and calcium formate were added to regulate the crystal nucleation and growth of phosphogypsum, improve the crystal transformation rate and conversion rate, and improve the crystal morphology.

Benefits of technology

It significantly improved the crystallization rate and conversion rate of phosphogypsum, shortened the reaction cycle, improved product quality, and realized the efficient and low-consumption resource utilization of phosphogypsum.

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Abstract

本发明提供一种生物‑无机诱导剂耦合诱导磷石膏转晶的方法及其产品。具体包括:先用去离子水和氧化钙对磷石膏进行预处理,将预处理后的磷石膏加入水溶液中,再加入生物诱导剂和有机诱导剂,调节体系pH为6‑9,搅拌均匀,以40‑90℃恒温反应2‑24h,即可得到半水石膏。反应介质和无机诱导剂为甲酸钙、对氨基苯磺酸纳、草酸钠、二乙烯三胺五乙酸五钠中的一种或两种,提供高离子浓度环境以促进磷石膏脱水转晶,调控晶体成核与生长;生物诱导剂为赖氨酸,协同调控晶体形貌与结构。该工艺温和低耗、绿色环保,生物‑无机诱导剂协同作用可提升磷石膏转化效率、缩短反应周期,制得的半水石膏纯度高、形貌优良。
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