A sulfur-containing high refractive index multifunctional mercaptan compound

By controlling the side reaction of thiol oxidation coupling under inert gas protection and liquid sealing operation, sulfur-containing high refractive index multifunctional thiols were prepared, solving the problems of high equipment requirements, many side reactions and low purity in the existing technology, and realizing the preparation of optical materials with high transmittance and low yellowing.

CN122404191APending Publication Date: 2026-07-17FUZHOU UNIV
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Patent Information

Application Number
CN202610516030.0
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-04-19
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing technologies for preparing polythiol compounds suffer from problems such as high equipment requirements, numerous side reactions, low product purity, high yellowing index, and difficulty in meeting the requirements for high transmittance and color.

Method used

Inert gas protection and liquid sealing were used to control the oxidative coupling side reaction of thiols. Thioether bonds and multiple thiol end groups were introduced through the thiol conversion stage to prepare sulfur-containing high refractive index multifunctional thiols. The skeleton was constructed by classic haloalcohol ring opening and nucleophilic substitution, and the thiourea method was used for thiol conversion.

Benefits of technology

This improves the purity and stability of the product, meeting the requirements of high transmittance and low yellowing index for advanced optical lenses and microlens arrays, and endows the polymer with good refractive index and thermomechanical stability.

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Abstract

本发明公开了一种含硫高折光率多官能度硫醇化合物及其制备方法与应用,属于高分子先进光学树脂材料的合成与制备技术领域。作为全有机聚合物光学材料的核心单体,该化合物具有结构,通过在分子骨架中精密引入硫醚键、芳香环及3‑4个活性巯基官能团,实现了高折射率、高交联密度与良好的加工性能的平衡。由于独特的分子设计,该化合物表现出优异的折射率和良好的透光性;同时,其多巯基结构使其在与含双键单体进行聚合时,能够提供良好的交联能力,改善固化树脂的硬度和玻璃化转变温度。本发明合成工艺路线清晰,产物室温加工性好,在制备高级光学树脂镜片、光学薄膜及微透镜阵列等领域具有广阔的应用前景。
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Citation Information

Patent Citations

  • Polythiol, process for producing same, sulfur-containing urethane-base resin prepared from polythiol, process for producing the resin, and lens

    CN1215737A