A polyphenylene ether polyamide glass fiber reinforced composite material and a preparation method and application thereof

By using specific formulations and processes, combined with primary and secondary compatibilizers and glass fiber, the compatibility problem of polyphenylene ether and polyamide blends has been solved, achieving a balance between high rigidity, toughness, heat resistance and low water absorption, making them suitable for automotive parts, electronic and electrical components and communication equipment structural parts.

CN122404949APending Publication Date: 2026-07-17GUANGDONG CHUANGYONGJIA NEW MATERIAL CO LTD
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Patent Information

Application Number
CN202610623475.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-05-08
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

In the existing technology, the blends of polyphenylene ether and polyamide have poor compatibility, resulting in weak interfacial bonding and poor mechanical properties. It is difficult to achieve an optimal balance of rigidity, toughness, heat resistance and processing performance while ensuring low water absorption and high dimensional stability.

Method used

The composite material formulation includes polyphenylene ether resin, polyamide resin, glass fiber, maleic anhydride-grafted polyphenylene ether PPO-g-MAH as the main compatibilizer, and maleic anhydride-grafted hydrogenated styrene-butadiene-styrene block copolymer SEBS-g-MAH as the auxiliary compatibilizer. Through specific ratios and surface treatments, combined with a gradient temperature and low shear twin-screw extrusion process, synergistic interfacial compatibilization and glass fiber reinforcement are achieved.

Benefits of technology

It achieves an excellent balance of rigidity and toughness, extremely low water absorption, high heat resistance, good high-temperature performance retention, and improved processing fluidity, meeting the requirements of high-performance structural components.

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Abstract

本发明属于高分子复合材料领域,涉及一种聚苯醚聚酰胺玻璃纤维增强复合材料及其制备方法和应用,所述聚苯醚聚酰胺玻璃纤维增强复合材料,以复合材料总重量为100重量份计,包括以下组分:聚苯醚树脂20~40份;聚酰胺树脂20~40份;玻璃纤维25~45份;相容剂3~10份;抗氧剂0.1~1.0份;润滑剂0.2~1.5份;其中,相容剂由主相容剂和辅助相容剂组成,主相容剂为马来酸酐接枝聚苯醚PPO‑g‑MAH,接枝率为0.5%~2.0%,占相容剂总重量的50%~80%;辅助相容剂为马来酸酐接枝氢化苯乙烯‑丁二烯‑苯乙烯嵌段共聚物SEBS‑g‑MAH。材料具有良好的高温性能保持率和改善的加工流动性和表面质量。
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