A nickel-based magnetic hollow fiber self-supporting electrode, a preparation method thereof and application thereof in a magnetic field reinforced water decomposition reaction

Nickel-based magnetic hollow fiber self-supporting electrodes were prepared by multi-metal co-doping and Kirkendall effect. Combined with multiple magnetic field enhancement modes, the activity and stability problems of nickel-based catalysts in alkaline water electrolysis were solved, improving the efficiency and stability of water electrolysis reaction, making them suitable for industrial applications.

CN122406260APending Publication Date: 2026-07-17ZHONGBEI UNIV
View PDF 0 Cites 0 Cited by

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
ZHONGBEI UNIV
Filing Date
2026-06-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

Existing nickel-based catalysts exhibit insufficient catalytic activity, are prone to corrosion, have poor stability, and are susceptible to failure under dynamic operating conditions. Furthermore, their limited water dissociation capacity leads to low efficiency in water electrolysis.

Method used

A nickel-based magnetic hollow fiber self-supporting electrode was prepared by employing a multi-metal co-doping strategy and the Kirkendall effect. By combining external magnetic field enhancement, internal field enhancement and magnetocaloric assisted mode, the surface morphology and magnetic properties of the electrode were controlled to improve catalytic activity.

Benefits of technology

It significantly reduces the overpotentials of hydrogen and oxygen evolution, improves the efficiency of alkaline water electrolysis, reduces the overpotential of the electrode by 5-30% under magnetic field assistance, and enhances stability, making it suitable for industrial mass production.

✦ Generated by Eureka AI based on patent content.

Smart Images

  • Figure CN122406260A_ABST
    Figure CN122406260A_ABST
Patent Text Reader

Abstract

本发明提供了一种镍基磁性中空纤维自支撑电极及其制备方法和在磁场强化水分解反应中的应用,属于电催化功能材料技术领域。本发明通过在镍基体中引入至少一种不同还原电位和扩散速率的过渡金属,利用分子配位调控水热自组装过程,并结合后续热扩散处理,利用不同金属原子热扩散速率差异引发的柯肯达尔效应,在纤维内部形成中空结构,最终实现对纤维表面亚结构形貌、内部中空程度以及磁性能的协同调控,将该电极用于电解水反应时,可采用外磁场增强模式、内场增强模式或磁热辅助模式三种磁场增强模式,显著提升碱性电解水析氢和析氧反应的效率。
Need to check novelty before this filing date? Find Prior Art