A middle-permeable ternary composite filter rod and a heated cigarette containing the same

Abstract

The present invention discloses an intermediate breathable ternary composite filter rod and a heated cigarette containing the same. From the far lip end to the near lip end, the intermediate breathable ternary composite filter rod comprises a support barrier section (6), a smoke extraction section (2) and a functional filter rod section (3); the support barrier section (6) and the functional filter rod section (3) do not have a breathable function; the smoke extraction section (2) itself has a breathable function; the tipping paper (5) only partially wraps the smoke extraction section (2), and the forming paper (4) is breathable, and the tipping paper (5) is not breathable. The present invention is the first to use the smoke extraction section (2) separated from the smoking section as a breathable section. After the heated cigarette designed by the present invention is inserted into a cigarette, both the cooling effect and the smoke volume are better. At the same time, the heated cigarette structure can adjust the air permeability and air permeability position of the smoke extraction section (2) by adjusting the size and position of the area covered by the tipping paper (5) on the smoke extraction section (2), thereby adjusting the air permeability and air permeability position of the heated cigarette.

Description

Technical Field

[0001] The invention belongs to the field of heated cigarettes, and in particular relates to a middle-permeable ternary composite filter rod and a heated cigarette containing the same. Background Art

[0002] As consumers pay more attention to health issues and demand for personalized experience of cigarette products, the tobacco industry continues to respond to the upgrading of consumer demand and develop various heated cigarettes with reduced tar and harm. Among them, heat-not-burn cigarettes are different from traditional cigarette products in that their heating method is different, which enables them to meet consumers' sensory needs for cigarette products while providing a healthier smoking experience.

[0003] Existing heated cigarettes mainly include a smoking core material section, a hollow support section, a cooling section and a filtering section. In order to introduce air, increase ventilation, and effectively reduce smoke temperature, heated cigarettes usually use an online laser punching method to punch holes in the hollow support section of the heated cigarette, punch through the hollow support section wall and the forming paper and tipping paper wrapping the hollow support section, form ventilation holes, and introduce air. However, this method still has the following problems: 1. The online laser punching process has high requirements on the material and thickness of the hollow support section wall. First, the material of the hollow support section wall cannot collapse during the online laser punching process, and the hollow support section wall cannot be particularly thick, so as to avoid the online laser 1. The holes cannot be punched through; 2. The online laser drilling process has very high requirements on laser power. If the laser drilling equipment fails to punch through the wall of the hollow support segment, the heated cigarettes will be unqualified and the smoke temperature will be too hot; 3. At present, ventilation holes are formed by punching through the hollow support segment and the forming paper and tipping paper that wrap the hollow support segment. The outside air directly enters the hollow support segment through the ventilation holes. The air is introduced into the ventilation holes at a fast speed, the contact area between the introduced air and the smoke is limited, and the mixing is uneven. As a result, although the amount of smoke inhaled into the consumer's mouth has increased, the smoke concentration is low, and a large amount of air is obviously mixed in the smoke, which seriously reduces the smoking quality.

[0004] In addition, existing heated cigarettes usually have holes in the outer wall of the supporting section adjacent to the smoking section so as to mix the hot smoke and air most directly. However, after the heated cigarette is inserted into the smoking device, the heated cigarette enters the smoking device at a deeper distance, which makes the ventilation holes also located deeper in the cigarette holding cavity of the smoking device, and the heated cigarette is in close contact with the inner wall of the cigarette holding cavity, which makes the amount of air introduced by the ventilation holes very small, and the effect of cooling the smoke and increasing the smoke volume is not obvious.

[0005] In addition, the use of physical perforation to make the heated cigarette tube wall ventilated also has the problem of unadjustable permeability and fixed permeability position. Since physical perforation can only introduce air where the hole is punched, and then the ambient air is introduced from there for ventilation and cooling, the permeability is fixed with the size of the hole. However, with the change of the smoking section material or the change of the adapted smoking device, the permeability and permeability position of the heated cigarette are expected to be adjustable.

[0006] Therefore, it is desirable to design a heated cigarette that can ensure both the cooling effect on smoke and the smoke volume and smoke quality, and the air permeability and air permeability of the heated cigarette can be adjusted.

[0007] In order to solve the above problems, the present invention is proposed. Summary of the invention

[0008] The first aspect of the present invention provides a middle air-permeable ternary composite filter rod, from the distal lip end to the proximal lip end, the middle air-permeable ternary composite filter rod comprises a support barrier section 6, a smoke extraction section 2 and a functional filter rod section 3;

[0009] The support barrier section 6 and the functional filter rod section 3 do not have a ventilation function; the smoke extraction section 2 itself has a ventilation function, and the outside air can enter the interior of the heated cigarette (intermediate ventilation type ternary composite filter rod) through the smoke extraction section 2;

[0010] The tipping paper 5 only partially wraps the smoke extraction section 2, and at least a part of the area on the far lip end of the smoke extraction section 2 only has the shaping paper 4 on the outside, and the tipping paper 5 is not wrapped;

[0011] The shaping paper 4 is air-permeable, and the tipping paper 5 is air-impermeable.

[0012] Preferably, the supporting and blocking section 6 is a hollow paper tube with a tube wall thickness of 0.1-0.6 mm; and the air permeability of the forming paper 4 is 1000-10000 CU.

[0013] Preferably, the length and position of the tipping paper 5 are adjustable, and the tipping paper 5 covers 1 / 6-5 / 6 of the axial length of the smoke extraction section 2 .

[0014] Preferably, the smoke extraction section 2 is a hollow structure, which includes a tube wall 21 and a tube cavity 22. The tube wall 21 does not need to be perforated, and it has a ventilation function. The tube wall 21 has a vent hole, and the outside air can enter the tube cavity 22 through the vent hole in the tube wall 21. The cross-sectional area of ​​the tube cavity 22 is not limited to a circle, and can also be any shape such as a triangle, a polygon, or a five-pointed star.

[0015] Preferably, the tube wall 21 can be formed by bonding and extruding particles, and the pores between the particles after forming serve as vents, so that the tube wall 21 itself has a breathable function;

[0016] The diameter of the particles is 200-25000 microns; after the particles form the wall of the hollow tube, the thickness of the tube wall 21 is 1.0-2.0 mm, and the pores between the particles in the tube wall 21 are dispersed, and the porosity is 50-80%.

[0017] Preferably, the particles are selected from organic particles or inorganic particles, the inorganic particles include alumina, zirconium oxide, calcium carbonate, glass beads, silicon dioxide, iron, copper, aluminum, gold, platinum, magnesium silicate balls or calcium sulfate; the organic particles include cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, sucrose powder, dextrin, lactose, powdered sugar, glucose, mannitol, starch, methyl cellulose, ethyl cellulose, polylactic acid, polyethylene, polypropylene, polyhydroxybutyrate, poly-ε-caprolactone, polyglycolic acid, polyhydroxyalkanoate, and at least one of starch-based thermoplastic resins.

[0018] Preferably, the binder between the particles includes: polyethylene, polypropylene, polylactic acid, polyolefin, polyester, polyamide, polyacrylic polyvinyl compound, polytetrafluoroethylene, polyetheretherketone, polyethylene terephthalate, polybutylene terephthalate, polycyclohexanedimethylene terephthalate, polypropylene terephthalate, polyacrylate, polymethyl methacrylate, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, styrene-butadiene, styrene-maleic acid, cellulose acetate, cellulose acetate butyrate, plasticized cellulose plastic, cellulose propionate, ethyl cellulose, any derivatives thereof, any copolymers thereof, and at least one thereof, and any combination thereof.

[0019] Preferably, the tube wall 21 is an acetate fiber bundle, and the amount of the acetate fiber bundle is medium-density. After the acetate fiber bundle forms the wall of the hollow tube, the thickness of the tube wall 21 is 1.0-3.0 mm. At this time, the amount of the acetate fiber bundle is medium-density, and when the size is a filter rod circumference of 19.8 mm, 2000-4500 strands are filled.

[0020] Preferably, the tube wall 21 is made of a breathable ceramic material.

[0021] The second aspect of the present invention provides a heating cigarette comprising the intermediate breathable ternary composite filter rod described in the first aspect of the present invention, wherein the heating cigarette further comprises a smoking section 1, wherein the smoking section 1 and the intermediate breathable ternary composite filter rod are assembled and formed by forming paper 4; the outer side of the forming paper 4 wrapping the intermediate breathable ternary composite filter rod also has a tipping paper 5. That is to say, in this heating cigarette structure, the forming paper 4 plays two assembly roles: (1) assembling the supporting barrier section 6, the smoke extraction section 2 and the functional filter rod section 3 to form the intermediate breathable ternary composite filter rod; (2) assembling the intermediate breathable ternary composite filter rod and the smoking section 1 to form the heating cigarette. The tipping paper does not play an assembly role, but controls the air permeability and air permeability position of the smoke extraction section 2 by controlling the length of the tipping paper, and the tipping paper also plays a conventional role such as printing patterns and logos.

[0022] In addition, the intermediate breathable ternary composite filter rod described in the present invention is not limited to only including the support barrier section 6, the smoke extraction section 2 and the functional filter rod section 3. According to actual needs, other functional sections can be added.

[0023] The third aspect of the present invention provides a method for adjusting the air permeability and air permeability position of the heated cigarette according to the second aspect of the present invention, which can adjust the air permeability and air permeability position of the smoke extraction section 2 by adjusting the size and position of the area covered by the tipping paper 5 on the smoke extraction section 2, thereby adjusting the air permeability and air permeability position of the heated cigarette.

[0024] Compared with the prior art, the present invention has the following beneficial effects:

[0025] 1. The present invention provides a middle-permeable ternary composite filter rod, wherein the middle section is a smoke extraction section 2 with its own ventilation function. On the one hand, the present invention does not use the support section adjacent to the smoking section as a ventilation section to introduce air as in the prior art, but for the first time uses the smoke extraction section separated from the smoking section as a ventilation section. Compared with the aforementioned structure, the heating cigarette designed by the present invention has better cooling effect and smoke volume after being inserted into the cigarette. On the other hand, the present invention does not simply perform mechanical perforation for ventilation, but uses a smoke extraction section with its own ventilation function. The air introduced by the smoke extraction section of the present invention is more dispersed. While ensuring that the amount of air introduced is cooled, it can also evenly introduce air into the heated cigarette, so that the introduced air and smoke are mixed more evenly, solving the problem that, as in the previous perforation, only a large amount of air is introduced to achieve a cooling effect, but the air and smoke are mixed unevenly and the smoke quality is poor.

[0026] 2. The heating cigarette of the present invention can adjust the air permeability and air permeability position of the tube wall, which includes a smoke extraction section 2 with its own air permeability function, and the outside air can enter the interior of the heating cigarette through the smoke extraction section 2; the tipping paper 5 only partially wraps the smoke extraction section 2, and the outer side of the partial area of ​​the smoke extraction section 2 close to the smoking section 1 has only the shaping paper 4, and the tipping paper 5 is not wrapped; while the shaping paper 4 is air permeable, the tipping paper 5 is airtight, and the length and position of the tipping paper 5 are adjustable, so that the air permeability and air permeability position of the smoke extraction section 2 can be adjusted by adjusting the size and position of the area covered by the tipping paper 5 on the smoke extraction section 2, thereby adjusting the air permeability and air permeability position of the heating cigarette. The cigarette structure of the present invention can more flexibly control the air permeability and air permeability position of the smoke extraction section 2 by controlling the length of the tipping paper 5.

[0027] 3. The heating cigarette filter rod with natural ventilation function of the present invention comprises a smoke extraction section 2, wherein the tube wall 21 of the smoke extraction section 2 does not need to be punched, and it has a ventilation function by itself. The tube wall 21 has ventilation holes, and the outside air can enter the tube cavity 22 through the ventilation holes in the tube wall 21. That is to say, the tube wall 21 itself has pores and has a natural ventilation effect. The forming paper 4 and the tipping paper 5 are used in combination to make the cooling section tube wall breathable. The outside air enters the interior of the heating cigarette through the pores and mixes with the smoke, thereby achieving the purpose of introducing air into the interior of the heating cigarette. No holes are needed to be punched, and the problems caused by punching holes in the tube wall 21 of the smoke extraction section 2 are avoided.

[0028] 4. In a preferred embodiment of the present invention, the tube wall 21 can be formed by extrusion of particles, and the pores between the particles after forming play a role of natural ventilation; after the particles form a hollow tube, the pores between the particles in the tube wall are dispersed. Compared with directly punching holes in the cooling section, the air introduced into the particle-form smoke extraction section of the present invention is more dispersed. While ensuring that the amount of air introduced can achieve cooling, it can also evenly introduce air into the heated cigarette, so that the introduced air and smoke are mixed more evenly, solving the problem that, like the previous punching, only a large amount of air is introduced to achieve a cooling effect, but it leads to uneven mixing of air and smoke and poor smoke quality.

[0029] 5. If the particles are used as solid cooling rods, although the cooling effect is good, the smoke has to pass through the particle gaps in the solid cooling rod to reach the filter tip for consumers to inhale, which results in the solid cooling rod adsorbing too much smoke. While the present invention introduces air to reduce the smoke temperature, the selection of particle materials is also critical. The particle materials of the present invention are selected from some materials with cooling effects. When the smoke passes through, the wall material of the smoke extraction section can also play the role of reducing the smoke temperature.

[0030] 6. In a preferred embodiment of the present invention, the tube wall 21 is an acetate fiber bundle, which is not a traditional acetate fiber bundle used for filter tips. The acetate fiber bundle used for the tube wall 21 in the present invention is a medium-branched one, which makes the acetate fiber bundle itself porous and breathable, just like a window screen with a mesh. Compared with directly punching holes in the cooling section, the air introduced into the smoke extraction section of the acetate fiber bundle of the present invention is more dispersed. While ensuring that the amount of air introduced is sufficient to achieve cooling, it can also evenly introduce air into the heated cigarette, so that the introduced air and smoke are mixed more evenly, solving the problem that, as in the previous punching, only a large amount of air is introduced to achieve a cooling effect, but the air and smoke are mixed unevenly and the smoke quality is poor.

[0031] 7. In a preferred embodiment of the present invention, the tube wall 21 can also be made of a breathable ceramic material, which can not only have its own breathable function but also play a supporting role. BRIEF DESCRIPTION OF THE DRAWINGS

[0032] Figure 1 This is a schematic diagram of the actual effect of the smoke extraction section in the heated cigarette in Example 1; wherein the tube wall of the smoke extraction section 2 is formed by extrusion of particles;

[0033] Figure 2 This is a schematic diagram of the theoretical effect structure of the smoke extraction section in the heated cigarette in Example 1;

[0034] Figure 3 This is a schematic diagram of the structure of a heated cigarette in Example 1 of the present invention;

[0035] Figure 4 This is a schematic diagram of the structure of a heated cigarette in Example 2;

[0036] The names of the accompanying drawings are: 1-smoking section, 2-smoke extraction section, 3-functional filter rod section, 4-forming paper, 5-tipping paper; 21-tube wall, 22-tube cavity. DETAILED DESCRIPTION

[0037] The present invention is further described in detail below in conjunction with embodiments.

[0038] Those skilled in the art will appreciate that the following examples are only used to illustrate the present invention and should not be considered to limit the scope of the present invention. If no specific techniques or conditions are specified in the examples, the techniques or conditions described in the literature in the art or the product specifications are used. If the manufacturer of the materials or equipment used is not specified, they are all conventional products that can be purchased.

[0039] Those skilled in the art will appreciate that, unless expressly stated otherwise, the singular forms "a", "an", "said" and "the" used herein may also include plural forms. It should be further understood that the term "comprising" used in the specification of the present invention refers to the presence of the features, integers, steps, operations, elements and / or components, but does not exclude the presence or addition of one or more other features, integers, steps, operations, elements, components and / or groups thereof. It should be understood that when we refer to an element as being "connected" to another element, it may be directly connected to the other element, or there may be intermediate elements. In addition, the "connection" used herein may include wireless connections.

[0040] In the description of the present invention, unless otherwise specified, "plurality" means two or more than two. The terms "inside", "upper", "lower", etc., indicating positions or state relationships, are based on the positions or state relationships shown in the drawings, and are only for the convenience of describing the present invention and simplifying the description, and do not indicate or imply that the device or element referred to must have a specific position, be constructed and operate in a specific position, and therefore cannot be understood as limiting the present invention.

[0041] In the description of the present invention, it should be noted that, unless otherwise clearly specified and limited, the terms "installed", "connected", and "provided with" should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium. For ordinary technicians in this field, the specific meanings of the above terms in the present invention will be understood according to specific circumstances.

[0042] It will be understood by those skilled in the art that, unless otherwise defined, all terms used herein, including technical and scientific terms, have the same meaning as those generally understood by those skilled in the art in the art to which the present invention belongs. It should also be understood that terms such as those defined in common dictionaries should be understood to have meanings consistent with the meanings in the context of the prior art, and will not be interpreted with idealized or overly formal meanings unless defined as herein.

[0043] Example 1

[0044] like Figure 1-3 This embodiment is a heating cigarette sample 1 with a middle air-permeable ternary composite filter rod, which includes a smoking section 1, a supporting barrier section 6, a smoke extraction section 2 and a functional filter rod section 3 in sequence from the far lip end to the near lip end;

[0045] The supporting barrier section 6 and the functional filter rod section 3 do not have a breathable function; the smoke extraction section 2 itself has a breathable function, and the outside air can enter the heated cigarette through the smoke extraction section 2; the tipping paper 5 only partially wraps the smoke extraction section 2, and the outer side of a part of the area on the far lip end of the smoke extraction section 2 is only the shaping paper 4, and the tipping paper 5 is not wrapped; the shaping paper 4 is breathable, and the tipping paper 5 is not breathable.

[0046] The smoke extraction section 2 is a hollow structure, which includes a tube wall 21 and a tube cavity 22. The tube wall 21 does not need to be punched, and it has a breathable function. There are ventilation holes in the tube wall 21, and external air can enter the tube cavity 22 through the ventilation holes in the tube wall 21.

[0047] The tipping paper 5 covers 1 / 2 of the axial length of the smoke extraction section 2. The air permeability of the shaping paper 4 is 1000 CU. The supporting and blocking section 6 is a hollow paper tube.

[0048] The tube wall 21 is formed by bonding and extruding particles, and the pores between the particles after forming play a role of natural ventilation;

[0049] The particle diameter is 200-25000 microns; after the particles form the wall of the hollow tube, the thickness of the tube wall 21 is 1.5 mm, and the pores between the particles in the tube wall 21 are dispersed, and the porosity is 50%. The particles are selected from inorganic particles of aluminum oxide. The binder between the particles is polylactic acid.

[0050] Example 2

[0051] like Figure 4 This embodiment is used as a comparative example to be compared with the embodiment 1. This embodiment has a heating cigarette sample 2 with a middle air-permeable ternary composite filter rod. Different from the embodiment 1, the heating cigarette sample 2 includes a smoking section 1, a smoke extraction section 2, a support barrier section 6 and a functional filter rod section 3 from the far lip end to the near lip end;

[0052] The supporting barrier section 6 and the functional filter rod section 3 do not have a breathable function; the smoke extraction section 2 itself has a breathable function, and the outside air can enter the heated cigarette through the smoke extraction section 2; the tipping paper 5 only partially wraps the smoke extraction section 2, and the outer side of a part of the area on the far lip end of the smoke extraction section 2 is only the shaping paper 4, and the tipping paper 5 is not wrapped; the shaping paper 4 is breathable, and the tipping paper 5 is not breathable.

[0053] The smoke extraction section 2 is a hollow structure, which includes a tube wall 21 and a tube cavity 22. The tube wall 21 does not need to be punched, and it has a breathable function. There are ventilation holes in the tube wall 21, and external air can enter the tube cavity 22 through the ventilation holes in the tube wall 21.

[0054] The tipping paper 5 covers 1 / 2 of the axial length of the smoke extraction section 2. The air permeability of the shaping paper 4 is 1000 CU. The supporting and blocking section 6 is a hollow paper tube.

[0055] The tube wall 21 is formed by bonding and extruding particles, and the pores between the particles after forming play a role of natural ventilation;

[0056] The particle diameter is 200-25000 microns; after the particles form the wall of the hollow tube, the thickness of the tube wall 21 is 1.5 mm, and the pores between the particles in the tube wall 21 are dispersed, and the porosity is 50%. The particles are selected from inorganic particles of aluminum oxide. The binder between the particles is polylactic acid.

[0057] Example 3

[0058] For the heated cigarette sample 1 prepared in Example 1 and the heated cigarette sample 2 prepared in Example 2, according to the QYNZY.J07.022-2015 standard, 20 professional sensory evaluators at or above the provincial level were asked to perform a sensory evaluation on the cigarette samples. The results were averaged after the evaluation and scoring, and the following Table 1 was obtained. At the same time, when the sensory evaluators were asked to perform a sensory evaluation on the cigarette samples, the smoke temperature entering the mouth of the sensory evaluators was measured and the average value was taken. Among them, the smoke temperature of the heated cigarette sample 1 entering the mouth of the sensory evaluator was 37.1°C, and the smoker felt that the temperature was just suitable for smoking. The smoke temperature of the heated cigarette sample 2 entering the mouth of the smoker was 39.6°C, and the smoker felt that the mouth was slightly hot, and the smoking experience was slightly worse than that of the heated cigarette sample 1 in Example 1.

[0059] Table 1 Sensory quality record of new cigarettes

[0060] Standard basis: QYNZY.J07.022-2015

[0061]

[0062] As can be seen from Table 1 above, the smoke volume of heated cigarette sample 1 is also larger, and the scores in aroma and taste are slightly higher than those of heated cigarette sample 2. In other words, appropriately moving the ventilation section closer to the lip end has a better effect on cooling the smoke and increasing the smoke volume in actual application, which is indeed unexpected.

Claims

1. A method for adjusting the air permeability and air permeability position of a heated cigarette containing a middle air permeable ternary composite filter rod, characterized in that: The heated cigarette comprises a middle air-permeable ternary composite filter rod and a smoking section (1), wherein the smoking section (1) and the middle air-permeable ternary composite filter rod are assembled and formed by means of a shaping paper (4); the shaping paper (4) wrapping the middle air-permeable ternary composite filter rod also has a tipping paper (5) on its outer side; From the distal lip end to the proximal lip end, the intermediate air-permeable ternary composite filter rod comprises a support barrier section (6), a smoke extraction section (2) and a functional filter rod section (3); The supporting barrier section (6) and the functional filter rod section (3) do not have a ventilation function; the smoke extraction section (2) itself has a ventilation function, and the outside air passes through the smoke extraction section (2) and enters the interior of the heated cigarette; The tipping paper (5) only partially wraps the smoke extraction section (2); at least a portion of the area on the far lip end of the smoke extraction section (2) only has the shaping paper (4) on the outside, and is not wrapped by the tipping paper (5); The shaping paper (4) is air-permeable, and the tipping paper (5) is air-impermeable; The smoke extraction section (2) is a hollow structure, comprising a tube wall (21) and a tube cavity (22); the tube wall (21) does not need to be perforated and has a ventilation function; the tube wall (21) has ventilation holes, and external air enters the tube cavity (22) through the ventilation holes in the tube wall (21); The tube wall (21) is formed by bonding and extruding particles, and the gaps between the particles after forming serve as vents, so that the tube wall (21) itself has a ventilation function; The particle diameter is 200-25000 microns; after the particles form the wall of the hollow tube, the thickness of the tube wall (21) is 1.0-2.0 mm, and the pores between the particles in the tube wall (21) are dispersed, and the porosity is 50-80%; The air permeability and air permeability position of the smoke extraction section (2) are adjusted by adjusting the size and position of the area covered by the tipping paper (5) on the smoke extraction section (2), thereby adjusting the air permeability and air permeability position of the heated cigarette.

2. The method for adjusting the air permeability and air permeability position of a heated cigarette comprising a middle air permeable ternary composite filter rod according to claim 1, characterized in that: The supporting and blocking section (6) is a hollow paper tube; the air permeability of the forming paper (4) is 1000-10000 CU.

3. The method for adjusting the air permeability and air permeability position of a heated cigarette comprising a middle air permeable ternary composite filter rod according to claim 1, characterized in that: The length and position of the tipping paper (5) are adjustable, and the tipping paper (5) covers 1 / 6-5 / 6 of the axial length of the smoke extraction section (2).

4. The method for adjusting the air permeability and air permeability position of a heated cigarette comprising a middle air permeable ternary composite filter rod according to claim 1, characterized in that: The particles are selected from organic particles or inorganic particles. The inorganic particles include aluminum oxide, zirconium oxide, calcium carbonate, glass beads, silicon dioxide, iron, copper, aluminum, gold, platinum, magnesium silicate balls or calcium sulfate; the organic particles include cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, microcrystalline cellulose, dextrin, lactose, powdered sugar, glucose, mannitol, starch, methyl cellulose, ethyl cellulose, polylactic acid, polyethylene, polypropylene, polyhydroxybutyrate, poly-ε-caprolactone, polyglycolic acid, polyhydroxyalkanoate, and at least one of starch-based thermoplastic resins; The binder between particles includes: at least one of polylactic acid, polyolefin, polyester, polyamide, polyacrylic acid polyvinyl compound, polytetrafluoroethylene, polyetheretherketone, polyethylene terephthalate, polybutylene terephthalate, polycyclohexanedimethylene terephthalate, polypropylene terephthalate, polyacrylate, polymethyl methacrylate, acrylonitrile-butadiene-styrene, styrene-acrylonitrile, styrene-butadiene, styrene-maleic acid, cellulose acetate, cellulose acetate butyrate, plasticized cellulose plastic, cellulose propionate, and ethyl cellulose, and any combination thereof.

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