A cooling preparation

Abstract

A cooling preparation containing phenylalkenal and homovanillate is proposed.

Description

Field of the Invention

[0001] The present invention belongs to the field of cosmetics and oral compositions and discloses new physiological cooling preparations and their use. Background Art

[0002] To meet consumer demand for new olfactory and taste experiences, the flavor and fragrance industry is in urgent need of substances with excellent sensory properties and the ability to achieve new effects. Besides pure olfactory and taste properties, additional properties are also important, such as the ability to suppress or enhance olfactory and taste perceptions.

[0003] Flavor compositions with a cooling effect impart, for example, a typical, fresh and pleasant taste to oral hygiene products, such as toothpaste and mouthwash, and sweets, such as candies and chewing gum.

[0004] Substances widely used to produce such aroma or flavor compositions with a cooling effect are, for example, eucalyptol (1,8-cineole) and menthol. However, the use of these substances has some disadvantages. In addition to its cooling effect, eucalyptol also has a very strong medicinal eggy taste, which many consumers find objectionable, especially when used in higher doses. When menthol is used, the cooling effect begins with a certain delay, and at higher doses, menthol produces its own bitter, astringent, and pungent taste, which has a rather unpleasant effect.

[0005] Related existing technologies

[0006] WO 2013 171018 A1 (SYMRISE) discloses physiological cooling compositions comprising phenylalkenal and at least one additional agent capable of providing a cooling sensation.

[0007] WO 2015 158677A1 (SYMRISE) relates to the use of homovanillic acid esters to provide a warming sensation when taken orally. Summary of the Invention

[0008] It was therefore an object of the present invention to provide preparations with an improved physiological cooling effect and low or reduced undesirable properties, ie also to improve the taste perception of the cooling agent, in particular with regard to a long-lasting cooling sensation.

[0009] A first object of the present invention relates to a cooling preparation comprising, consisting of or essentially consisting of the following ingredients:

[0010] (a) at least one phenylalkenal according to formula (I)

[0011]

[0012] wherein R1 and R2 independently represent hydrogen, methyl or phenyl, R3 represents hydrogen, phenyl, alkenyl or a straight-chain or branched alkyl group having 1 to 5 carbon atoms, and the dotted double lines independently represent a single bond or a double bond,

[0013] (b) at least one homovanillic acid ester according to formula (II)

[0014]

[0015] in

[0016] (i)R 1 and R 2 independently represent a hydrogen atom or an alkyl group having 1 to 2 carbon atoms, R 3 and R 4 independently of one another represent a hydrogen atom or a straight-chain or branched alkyl group, phenyl group, alkylphenyl group or phenylalkyl group having 1 to 5 carbon atoms or a straight-chain or branched alkenyl group, alkenylphenyl group or phenylalkenyl group having 2 to 4 carbon atoms, or

[0017] (ii)R 1 and R 3 Together with the carbon atoms to which they are attached, they form a cyclohexyl ring which can be replaced by another group R 5 replace,

[0018] where R 5 is an alkyl group having 1 to 2 carbon atoms,

[0019] R 4 represents a hydrogen atom or a straight-chain or branched alkyl group, phenyl group, alkylphenyl group or phenylalkyl group having 1 to 5 carbon atoms or a straight-chain or branched alkenyl group or alkenylphenyl group or phenylalkenyl group having 2 to 4 carbon atoms or a physiologically acceptable salt thereof,

[0020] wherein the phenolic hydroxyl group in formula (I) is deprotonated, or comprises one or more different compounds of formula (I) and / or

[0021] or a mixture of one or more physiologically acceptable salts thereof, wherein each phenolic hydroxyl group in formula (II) is deprotonated, or consisting of a plurality of different compounds of formula (II) and / or salts thereof, wherein each phenolic hydroxyl group in formula (II) is deprotonated, and optionally (c) at least one physiological cooling agent different from components (a) and (b).

[0022] Surprisingly, it has been observed that the addition of homovanillic acid esters, which represent typical warming agents, can improve the physiological cooling effect of phenylalkenals, in particular with regard to a long-lasting cooling effect on the mucous membranes.

[0023] Phenyl enal

[0024] The phenylalkenals constituting component (a) are known from WO 2013 171018 A2 (SYM-RISE) and follow the general formula (I). These substances can be obtained by relevant methods of organic chemistry, for example as described by Maruoka et al. in JACS 11, p. 7922-7924 (1988).

[0025] 2-phenyl-but-2-enal has been used in a variety of compositions. Therefore, the use of 2-phenyl-but-2-enal in deodorizing compositions is described in WO 2010 146258A, and its use as a preservative is described in WO 2008 149102A. In WO 2008 049581A, 2-phenyl-but-2-enal is disclosed in milk flavorings, and in WO 2008 011742A, it is disclosed as a flavor precursor for food. JP 2006 121958A, JP 2006 025706A, JP 200 020526A, JP 2004 135522A and DE 1921560 A disclose that 2-phenyl-but-2-enal is used to improve the taste of cocoa, nuts, coffee and fish.

[0026] Particularly preferred in the present invention are phenylalkenals according to formula (I) in which R1 and R2 are different and represent hydrogen or phenyl, R3 represents hydrogen, alkenyl or a straight-chain or branched alkyl group having 1 to 5 carbon atoms, and the dotted double lines independently represent a single bond or a double bond.

[0027] In a very particularly preferred embodiment of the present invention, the phenylenaldehyde according to formula (I) is selected from the group consisting of

[0028] 2-Phenyl-but-2-enal,

[0029] 2-Phenyl-pent-2-enal,

[0030] ●3-phenyl-pent-4-enal,

[0031] 2-Phenyl-pent-4-enal

[0032] and mixtures thereof.

[0033] The formulas and CAS numbers of particularly preferred compounds are given in Table A below:

[0034] Table A

[0035] Preferred CAS number and structure of ingredient (a)

[0036]

[0037]

[0038] Homovanillate

[0039] Homovanillic acid esters forming component (b) are known from WO 2015 158677 B1 (SYMRISE) and follow the formula (II). This type of ester also occurs in nature. For example, methyl homovanillate has been detected in various woods used for storing wines and spirits (e.g., Fernandez de Simon et al., J. AGRIC. FOOD CHEM. 2009, 57, 3217-3227). In contrast, ethyl homovanillate has been detected in wines and spirits themselves, typically due to storage in oak barrels (e.g., Cabaroglu, Tet al., J. FOOD SCI. 1997, 62, 680-692; van Jaarsveld, FP et al., J. ENOL. VITIC. 2009, 30, 24-37).

[0040] US2009 0170942A1 discloses specific ester derivatives of homovanillic acid and various (medical) applications thereof.

[0041] In a nociceptive study of different capsaicin derivatives in rat eyes, methyl, propyl, octyl, nonyl and dodecyl esters of homovanillic acid were tested and evaluated as active (Szolcsanyi, J. et al., DRUG RESEARCH 1975, 25, 1877-1881).

[0042] In the context of the present invention, preference is given to those homovanillic acid esters of formula (II) in which R 4 represents a hydrogen atom or a straight or branched alkyl group having 1 to 5 carbon atoms (for example, selected from the group consisting of methyl, ethyl, 1-propyl, 2-propyl, 1-butyl, 2-butyl, tert-butyl, 2-methylprop-1-yl, 1-, 2- or 3-pentyl, 2-methylbut-1-yl, 2-methylbut-2-yl, 3-methylbut-1-yl and 3-methylbut-2-yl, preferably methyl, ethyl, 1-propyl, 2-propyl, 1-butyl, 2-butyl, tert-butyl, 2-methylprop-1-yl and 1-pentyl), phenyl, alkylphenyl or phenylalkyl or a straight or branched alkene group having 2 to 4 carbon atoms yl (e.g., selected from the group consisting of vinyl, prop-2-en-1-yl, prop-1-en-1-yl, prop-1-en-2-yl, 1- or 2-cyclopropenyl, but-1-en-1-yl, but-1-en-2-yl, 4-but-1-en-3-yl, but-2-en-1-yl, but-3-en-1-yl, but-2-en-2-yl, 2-methylprop-1-en-1-yl, 2-methylprop-2-en-1-yl, 1,3-butadien-1-yl, 1,3-butadien-2-yl and possible Z and E isomers) or alkenylphenyl or phenylalkenyl, or a physiologically acceptable salt thereof.

[0043] Particularly preferred are those homovanillic acid esters according to formula (II) wherein (i) R 1 and R 2 independently represent a hydrogen atom or a methyl group,

[0044] R 3 and R 4 Each of the radicals independently represents a hydrogen atom or a linear or branched alkyl radical or a phenyl radical having 1 to 5 carbon atoms, an alkyl radical

[0045] phenyl or phenylalkyl or alkenylphenyl or phenylalkenyl (for example as described above), or (ii) formula (II) corresponds to the following formula (lIa)

[0046]

[0047] where R 2 represents a hydrogen atom, and R 4 Represents 2-propyl.

[0048] Also preferred are homovanillic esters, wherein the compound of formula (II) and / or the compounds of formula (II) in the mixture independently of one another, several or all of them are suitable for:

[0049] R 1 and R 2 Each represents a hydrogen atom,

[0050] R 3 represents a hydrogen atom or a straight-chain or branched alkyl group or a phenyl group, an alkylphenyl group or a phenylalkyl group or an alkenylphenyl group or a phenylalkenyl group having 1 to 4 carbon atoms,

[0051] R 4 Represents a hydrogen atom.

[0052] More preferably, the compound of formula (I) and / or one or more or all of the compounds of formula (II) are selected from a mixture or from the following group:

[0053]

[0054]

[0055]

[0056]

[0057] Physiological cooling agents

[0058] In a particularly preferred embodiment, the preparations according to the invention may comprise, in addition to components (a) and (b), one or more substances having a physiological cooling effect (cooling agents) as optional components (c).

[0059] These physiological cooling agents are preferably selected from the following list: menthol and menthol derivatives (e.g. L-menthol, D-menthol, racemic menthol, isomenthol, neoisomenthol, neomenthol), menthyl ethers (e.g. (1-menthoxy)-1,2-propanediol, (1-menthoxy)-2-methyl-1,2-propanediol, 1-menthyl-methyl ether), menthyl esters (e.g. menthyl formate, menthyl acetate, menthyl isobutyrate, menthyl lactate, L-menthyl L-lactate, L-menthyl D-lactate, menthyl-(2-methoxy)-menthyl)-1,2-propanediol, menthyl-2-methyl-1,2-propanediol, menthyl-methyl ether), acetate, menthyl (2-methoxyethoxy) acetate, menthyl pyroglutamate), menthyl carbonates (e.g. menthyl propylene glycol carbonate, menthyl ethylene glycol carbonate, menthyl glycerol carbonate or mixtures thereof), half esters of menthol with dicarboxylic acids or derivatives thereof (e.g. monomenthyl succinate, monomenthyl glutarate, monomenthyl malonate, O-menthyl succinate-N,N-(dimethyl)amide, O-menthyl succinate amide), menthanecarboxylic acid amides (in this case preferably menthanecarboxylic acid-N-acetamide [WS3] or N-menthyl succinate ... α -(Menthylcarbonyl)glycine ethyl ester [WS5], as described in US 4,150,052, menthanecarboxylic acid-N-(4-cyanophenyl)amide or menthanecarboxylic acid-N-(4-cyanomethylphenyl)amide, as described in WO 2005049553A1, menthanecarboxylic acid-N-(alkoxyalkyl)amides), menthone and menthone derivatives (e.g., L-menthone glycerol acetal / ketal), 2,3-dimethyl-2-(2-propyl)-butyric acid derivatives (e.g., 2,3-dimethyl-2-(2-propyl)-butyric acid N-methylamide [WS23]), isopulegol or its esters (1-(-)-isopulegol, 1-(-)-isopulegol acetate), menthane derivatives (e.g., p-menthane-3,8-diol), cubebol or synthetic or natural mixtures containing cubebol, pyrrolidone derivatives of cycloalkyldione derivatives (e.g., 3-methyl-2(1-pyrrolidinyl)-2-cyclopenten-1-one) or tetrahydropyrimidin-2-ones (e.g., iciline or related compounds, as described in WO 2005049553A1). 2004 / 026840), other carboxamides (e.g., N-(2-(pyridin-2-yl)-3-p-menthanecarboxamide or related compounds), (1R,2S,5R)-N-(4-methoxyphenyl)-5-methyl-2-(1-isopropyl)cyclohexanecarboxamide [WS12], oxalic acid esters (preferably those described in EP 2033688 A2).

[0060] When combining ingredients (a) and (b) with menthyl lactate, menthyl acetate and in particular L-menthone glycerol acetal / ketal, additional synergistic effects were found:

[0061]

[0062] Typically, the formulations according to the invention comprise, consist of or consist essentially of the following ingredients:

[0063] (a) about 1:99 to about 99:1 weight percent, preferably about 1:90 to 90:1 weight percent, more preferably about 25:75 to about 75:25 weight percent, and most preferably about 40:60 to about 60:40 weight percent of at least one phenylenal according to formula (I); and

[0064] (b) from about 99:1 to about 1:99 weight percent, preferably from about 90:10 to about 10:90 weight percent, more preferably from about 75:25 to about 25:75, and most preferably from about 40:60 to about 60:40 weight percent of at least one homovanillic acid ester of formula (II),

[0065] The condition is that the amount is added up to 100 wt.-%.

[0066] In another embodiment, the formulation according to the invention comprises, consists of or consists essentially of:

[0067] (a) about 0.2:2 to about 2.0:2 weight percent, preferably about 0.5:1 to 1:0.5 weight percent, more preferably about 0.6:0.8 to about 0.8:0.6 weight percent of at least one phenylenal according to formula (I); and

[0068] (b) from about 2.0:2 to about 0.2:2 weight percent, preferably from about 1:0.5 to about 0.5:1 weight percent, more preferably from about 0.8:0.6 to about 0.6:0.8 weight percent of at least one homovanillic acid ester of formula (II), and

[0069] (c) up to 97.8% by weight of an additional physiological cooling agent in addition to components (a) and (b),

[0070] Provided that the amount is added to 100% by weight.

[0071] Cosmetic and personal care compositions

[0072] Another subject matter of the present invention relates to cosmetic and / or personal care compositions containing the aforementioned cooling agent, wherein the cooling agent is present in an amount of from about 0.1 to about 8% by weight, preferably from about 0.5 to about 5% by weight, and more preferably from about 1 to about 2% by weight, based on the composition. Cosmetic or personal care compositions are, for example, cosmetic creams, lotions, sprays, emulsions, ointments, gels, or mousses. Typical examples are shampoos, conditioners, and corresponding two-in-one products.

[0073] The compositions according to the present invention may contain anti-dandruff agents, anti-irritants, anti-irritants, antioxidants, astringents, antiperspirants, bactericides, antistatic agents, binders, buffers, carriers, chelating agents, cell stimulants, cleansing agents, conditioning agents, deodorants, antiperspirants, softeners, emulsifiers, enzymes, essential oils, fibers, film formers, color fixatives, foam formers, foam stabilizers, defoamers, foam boosters, gelling agents, gel formers, hair care agents, hair setting agents, hair straightening agents, moisturizers, wetting agents, moisturizers, bleaching agents, strengthening agents, stain repellents, optical brighteners, impregnating agents, stain repellents, friction reducers, lubricants, moisturizing creams, ointments, sunscreens, plasticizers, covering agents, polishes, glossing agents, polymers, powders, proteins, re-oiling agents, As additional auxiliaries and additives, there can be used, for example, glycerol, niacin, niacinamide, niacinamide, niacinamide-containing products, emulsifiers ...

[0074] surfactants

[0075] Preferred adjuvants and additives are anionic and / or amphoteric or zwitterionic surfactants. Nonionic and cationic surfactants may also be present in the composition. Suitable examples are mentioned in the paragraph concerning emulsifiers.

[0076] Typical examples of anionic and zwitterionic surfactants include: almond amidopropylamine oxide, almond amidopropyl betaine, aminopropyl lauryl glutamine, ammonium C12-15 alkyl sulfate, ammonium C12-16 alkyl sulfate, ammonium capryleth sulfate, ammonium monococoglyceryl sulfate, ammonium cocoyl sulfate, ammonium cocoyl isethionate, ammonium cocoyl sarcosinate, ammonium C12-15 alkylene sulfate, ammonium C9-10 perfluoroalkylsulfonate, dinonyl ammonium sulfosuccinate, ammonium dodecylbenzenesulfonate, ammonium isostearate, ammonium laureth-6 carboxylate, ammonium laureth-8 carboxylate, ammonium laureth sulfate, ammonium laureth-5 sulfate, ammonium laureth-7 sulfate, ammonium laureth-9 Ammonium sulfate, ammonium laureth-12 sulfate, ammonium lauroyl sarcosinate, ammonium lauryl sulfate, ammonium lauryl sulfosuccinate, ammonium myristyl sulfate, ammonium myristyl sulfate, ammonium nonylphenol ether-4 sulfate, ammonium nonylphenol ether-30 sulfate, ammonium oleate, ammonium palm kernel sulfate, ammonium stearate, ammonium tall oil acid, isostearyl hydrolyzed collagen AMPD, rosin (acyl) hydrolyzed collagen AMPD, isostearyl hydrolyzed collagen AMP, isostearyl hydrolyzed keratin AMP, isostearyl hydrolyzed soy protein AMP, isostearyl hydrolyzed wheat protein AMP, apricot oleamidopropyl betaine, arachidic acid, hexyldecyl arginine phosphate, avocado oleamidopropyl betaine, avocado oil glyceryl ether -8 Esters, Babassu Seed Acid, Babassu Amidopropylamine Oxide, Babassu Amidopropyl Betaine, Beeswax Acid, Behenamidopropyl Betaine, Behenamine Oxide, Beheneth-25, Beheneth-30, Behenic Acid, Behenyl Betaine, Bis-Butyl Dimethicone Polyglyceryl-3, Butylphenol Eth-5 Carboxylic Acid, Butylphenol Eth-19 Carboxylic Acid, Butyldimethyl (Hydroxypropyl Butyl Glucoside) Ammonium Chloride, Butyldimethyl (Hydroxypropyl Lauryl Glucoside) Ammonium Chloride, Butyl Glucoside, Butyl Glucoside Caprate, Butyl Glucoside Hydroxypropyltrimonium Chloride, Butyl Caprylate, C18-36 Acid, C20-40 Acid, C30-50 Acid, C16-22 Acid Amide MEA, Calcium Dodecylbenzenesulfonate, Calcium Lauroyl Taurate, C9-16 Alkane / Cycloalkane, C10-14 Alkylbenzenesulfonic Acid, C12-14 Alkyl Di(Aminoethyl) Glycine HCl, C9-15 Alkyl Phosphate, Candida / Glucose / Rapeseed Methyl Ester Ferment, Canola Amidopropyl Betaine, Capric Acid, Caproic Acid, Caproyl Ethyl Glucoside, Capryloyl / Caprylamidopropyl Betaine, Octeth-4 Carboxylic Acid, Octeth-6 Carboxylic Acid, Octeth-9 Carboxylic Acid, Caprylic Acid, Capryloyl Collagen Amino Acids, Capryloyl Glycine, Capryloyl Hydrolyzed Collagen, Capryloyl Hydrolyzed Keratin, Capryloyl Keratin Amino Acids, Capryloyl Silk Amino Acids, Capryl / Decyl Glucoside, Capryl / Decyl Wheat Bran / Straw Glycosides, Capryl Glucoside, Caprylyl Glyceryl Ether, Caprylpyrrolidone, Carnitine,Ceteareth-20, Ceteareth-23, Ceteareth-24, Ceteareth-25, Ceteareth-27, Ceteareth-28, Ceteareth-29, Ceteareth-30, Ceteareth-33, Ceteareth-34, Ceteareth-40, Ceteareth-50, Ceteareth-55, Ceteareth-60, Ceteareth-80, Ceteareth-100, Ceteareth-25 Carboxylic Acid, Ceteareth-2 Phosphate, Cetearyl Alcohol Ceteth-4 Phosphate, Ceteareth-5 Phosphate, Diceteareth-10 Phosphate, Ceteth-20, Ceteth-23, Ceteth-24, Ceteth-25, Ceteth-30, Ceteth-40, Ceteth-45, Ceteth-150, Ceteth-8 Phosphate, Ceteth-10 Phosphate, Ceteth-20 Phosphate, Ceteth-22, Ceteth-24, Ceteth-25, Ceteth-30, Cetyl Betaine, Chrysanthemum SINENSE flower extract, C12-14 hydroxyalkyl hydroxyethyl beta-alanine, C12-14 hydroxyalkyl hydroxyethyl sarcosine, cocamidoethyl betaine, cocamidopropylamine oxide, cocamidopropyl betainamide MEA chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cocamine oxide, cocoaminobutyric acid, cocoaminopropionic acid, coceth-7 carboxylic acid, cocopolysaccharide Ethylhexyl Glucoside, Cocoamphopropionic Acid, Coco-Betaine Amidoamphopropionate, Coco-Betaine, Cocodimonium Hydroxypropyl Hydrolyzed Rice Protein, Cocodimonium Hydroxypropyl Hydrolyzed Soy Protein, Cocodimonium Hydroxypropyl Hydrolyzed Wheat Protein, Coco-Glucoside, Coco-Glucoside Hydroxypropyltrimonium Chloride, Coco-Hydroxysultaine, Coco-Morpholine Oxide, Coco Acid, Coco-Glycereth-8 Esters, Cocoyl / Oleamidopropyl Betaine, Cocoyl Sultaine, (Coconut Oil / Sunflower Seed Oil) Amidopropyl Betaine, Cocoyl Choline Methylsulfate, Cocoyl Glutamic Acid, Cocoyl Hydrolyzed Collagen, Cocoyl Hydrolyzed Keratin, Cocoyl Hydrolyzed Oat Protein, Cocoyl Hydrolyzed Rice Protein, Cocoyl Hydrolyzed Silk, Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Wheat Protein, Cocoyl Sarcosine, Corn Oil Acid, Cottonseed Oil Seed oil acid, cottonseed oil glyceryl polyether-8 esters, C10-16 pareth-1, C10-16 pareth-2, C11-13 pareth-6, C11-13 pareth-9, C11-13 pareth-10, C11-15 pareth-30, C11-15 pareth-40, C12-13 pareth-1, C12-13 pareth-23,C12-14 Pareth-5, C12-14 Pareth-9, C13-15 Pareth-21, C14-15 Pareth-8, C20-22 Pareth-30, C20-40 Pareth-40, C20-40 Pareth-95, C22-24 Pareth-33, C30-50 Pareth-40, C9-11 Pareth-6 Carboxylic Acid, C9-11 Pareth-8 Carboxylic Acid, C11-15 Pareth-7 Carboxylic acid, C12-13 Pareth-5 carboxylic acid, C12-13 Pareth-7 carboxylic acid, C12-13 Pareth-8 carboxylic acid, C12-13 Pareth-12 carboxylic acid, C12-15 Pareth-7 carboxylic acid, C12-15 Pareth-8 carboxylic acid, C12-15 Pareth-12 carboxylic acid, C14-15 Pareth-8 carboxylic acid, C6-10 Pareth-4 phosphate, C12-13 Pareth-2 phosphate, C12-13 Alkanol Pareth-10 Phosphate, C12-15 Pareth-6 Phosphate, C12-15 Pareth-8 Phosphate, C12-15 Pareth-10 Phosphate, C12-16 Pareth-6 Phosphate, C4-18 Perfluoroalkylethylmercaptopropyltrimonium Chloride, Cocoamidopropyl Betaine, C12-13 Alcohol Sulfate DEA Salt, C12-15 Alcohol Sulfate DEA Salt, Ceteareth-2 Phosphate DEA Salt, Cetyl Alcohol Sulfate DEA Salt, Cocoyl DEA amphoteric dipropionate, DEA C12-13 alkyl ether sulfate, DEA cyclopentyl oleate, DEA dodecylbenzenesulfonate, DEA isostearate, DEA laureth sulfate, DEA lauryl sulfate, DEA linoleate, DEA myristate methyl sulfonate, DEA myristyl ether sulfate, DEA myristate, DEA myristyl sulfate, DEA oleth-5 phosphate, DEA oleth-20 phosphate, DEA PG-oleate, Deceth-7 Carboxylic Acid, Deceth-7 Glucoside, Deceth-9 Phosphate, Decylamine Oxide, Decyl Betaine, Undecyl Glucoside, Decyltetradeceth-30, Decyltetradeceth-30, Decyltetradeceth-30, Lauramide-MEA Diammonium Sulfosuccinate, Lauryl Sulfosuccinate Diammonium, Oleamido PEG-2 Diammonium Sulfosuccinate, Dibutoxymethane, DiC12-15 Pareth-2 Phosphate, Di-C12-15 Pareth-4 Phosphate, Di-C12-15 Pareth-6 Phosphate, Di-C12-15 Pareth-8 Phosphate, Di-C12-15 Pareth-10 Phosphate, Didoyl Butane Tetracarboxylate, Diethylamine Laureth Sulfate, Sodium Diethylhexyl Sulfosuccinate, Di(Hydroxyethyl) C8-10 Alkoxypropylamine Oxide, Di(Hydroxyethyl) C9-11 Alkoxypropylamine Oxide,Di(hydroxyethyl) C12-15 alkoxypropylamine oxide, di(hydroxyethyl) cocamine oxide, di(hydroxyethyl) laurylamine oxide, di(hydroxyethyl) stearamine oxide, di(hydroxyethyl) tallowamine oxide, dimethicone PEG-7 phosphate, dimethicone PEG-10 phosphate, dimethicone PEG / PPG-7 / 4 phosphate, dimethicone PEG / PPG-12 / 4 phosphate, dimethicone / polyglyceryl-3 crosspolymer, dimethicone propyl PG-betaine, dimyristyl phosphate, dioleamidoethyl hydroxyethyl Methylammonium Methylsulfate, Hydrogenated Cocoate DIPA Salt, Lanolinate DIPA Salt, Myristate DIPA Salt, Dipotassium Capryloyl Glutamate, Dipotassium Laureth Sulfosuccinate, Dipotassium Undecylenoyl Glutamate, Disodium Babassuamido MEA-Sulfosuccinate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloamphodiacetate, Disodium Capryloamphodipropionate, Disodium Capryloyl Glutamate, Disodium Cetearyl Sulfosuccinate, Disodium Cetyl Phenyl Ether Disulfonate, Disodium Cetyl Sulfosuccinate, Disodium Cocamido MEA-Sulfosuccinate, Cocamido MIPA Disodium PEG-4 Sulfosuccinate, Disodium Cocamido MIPA-Sulfosuccinate, Disodium Cocamido PEG-3 Sulfosuccinate, Disodium Cocoeth-3 Sulfosuccinate, Disodium Cocoamphocarboxyethyl Hydroxypropyl Sulfonate, Disodium Cocoamphodiacetate, Disodium Cocoamphodipropionate, Disodium Coco-Glucoside Sulfosuccinate, Disodium Coco-Sulfosuccinate, Cocoyl Disodium butyl gluceth-10 sulfosuccinate, disodium cocoyl glutamate, disodium C12-14 pareth-1 sulfosuccinate, disodium C12-14 pareth-2 sulfosuccinate, disodium C12-15 pareth sulfosuccinate, disodium C12-14 sec-pareth-3 sulfosuccinate, disodium C12-14 sec-pareth-5 sulfosuccinate, C12-1 4-Secondary Alkyl Pareth-7 Sulfosuccinate Disodium, C12-14 Secondary Alkyl Pareth-9 Sulfosuccinate Disodium, C12-14 Secondary Alkyl Pareth-12 Sulfosuccinate Disodium, Decyl Ethylene Glycol Sulfosuccinate Disodium, Decyl Ethylene Glycol Sulfosuccinate Disodium, Decyl Phenyl Ether Disulfonate Disodium, Dihydroxyethyl Sulfosuccinyl Undecylenate Disodium, Disodium Dicocoyl Ethylenediamine PEG-15 Disulfate, Disodium Hydrogenated Cottonseed Glycerides Sulfosuccinate, Disodium Hydrogenated Tallowyl Glutamate, Disodium Hydroxydecyl Sorbitan Citrate, Disodium Isodecyl Sulfosuccinate, Disodium Isostearamide MEA-Sulfosuccinate, Disodium Isostearamide MIPA-MEA-Sulfosuccinate, Disodium Isostearylamphodiacetate, Disodium Isostearylamphodipropionate, Disodium Isostearyl Sulfosuccinate, Disodium Lanolin Ether-5 Sulfosuccinate,Disodium lauramido MEA-sulfosuccinate, disodium lauramido MIPA glycol sulfosuccinate, disodium lauramido PEG-2 sulfosuccinate, disodium lauramido PEG-5 sulfosuccinate, disodium laureth-5 carboxyamphodiacetate, disodium laureth-7 citrate, disodium laureth sulfosuccinate, disodium laureth-6 sulfosuccinate, disodium laureth-9 sulfosuccinate, disodium laureth-12 sulfosuccinate, disodium laurimidobishydroxypropyl sulfonate, disodium laurimidodiacetate, disodium laurimidodipropionate, disodium laurimidodipropionate tocopheryl phosphate, disodium lauroamphodiacetate, disodium lauroamphodipropionate, Disodium N-lauroyl Aspartate, Disodium Lauroyl Glutamate, Disodium Laureth Phenyl Ether Disulfate, Diammonium Laureth Sulfosuccinate, Disodium Myristamide MEA Sulfosuccinate, Disodium Nonylphenol Eth-10 Sulfosuccinate, Disodium Oleamide MEA Sulfosuccinate, Disodium Oleamide MIPA Sulfosuccinate, Disodium Oleamide PEG-2 Sulfosuccinate, Disodium Oleoamphodipropionate, Disodium Oleth-3 Sulfosuccinate, Disodium Oleyl Phosphate, Disodium Oleyl Sulfosuccinate, Disodium Palmitamide PEG-2 Sulfosuccinate, Disodium Palmitamide PEG-2 Sulfosuccinate, Disodium PEG-4 Cocamide MIPA Sulfosuccinate, PEG-12 Dimethicone Sulfonate Disodium PEG-8 Palm Glycerides Sulfosuccinate, PPG-2-Isodecyl Polyether-7 Carboxyamphodiacetate, Disodium Ricinoleamide MEA Sulfosuccinate, Disodium Sitostereth-14 Sulfosuccinate, Disodium Soybean Amphodiacetate, Disodium Stearamide MEA Sulfosuccinate, Disodium Stearoyl Dipropionate, Disodium Stearoyl Amphodiacetate, Disodium Stearoyl Glutamate, Disodium Sulfosuccinic Acid Monoacylated Stearylamine, Disodium Stearyl Sulfosuccinate, Disodium 2-Sulfolaurate, Disodium 2-Sulfopalmitate, Disodium Tallamide MEA Sulfosuccinate, Disodium Tallowamide MEA Sulfosuccinate, Disodium Tallowamphodiacetate, Disodium Tallowiminodipropionic Acid Sodium, Disodium Monoacyl Tallowamine Sulfosuccinate, Disodium Tridecyl Sulfosuccinate, Disodium Undecylenamide MEA Sulfosuccinate, Disodium Undecylenamide PEG-2 Sulfosuccinate, Disodium Undecylenoyl Glutamate, Disodium Monowheatgerm Oleoyl MEA Sulfosuccinate, Disodium Monowheatgerm Oleoyl PEG-2 Sulfosuccinate, Disodium Wheatgerm Oleoylamphodiacetate, Cocamide Diacetate Di-TEA, Oleamido PEG-2 Sulfosuccinate Di-TEA, Palmitoyl Aspartate Di-TEA, Sodium Tridecyl Sulfosuccinate, Dodecylbenzenesulfonic Acid, Erucamidopropyl Hydroxysultaine, Ethylhexyl Ethylhexyl Ether-3 Carboxylic Acid, Ethyl PEG-15 Cocoamine Sulfate, Caprylyl Glyceryl Ether, Hexyl Decanoate,Hydrogenated Coconut Acid, Hydrogenated Lanolin Eth-25, Hydrogenated Menhaden Oil Fatty Acid, Hydrogenated Palmitoleic Acid, Hydrogenated Palm Kernelamine Oxide, Hydrogenated Tallow Acid, Hydrogenated Tallowamine Oxide, Hydrogenated Tallow Betaine, Hydrogenated Tallow Eth-25, Hydrogenated Tallowyl Glutamate, Hydrogenated Candida Extract, Hydroxycetetrasodium PG-Dimethicone, Hydroxyethyl Butylamine Laureth Sulfate, Hydroxyethyl Carboxymethyl Cocamidopropylamine, Hydroxyethyl Hydroxypropyl C12-15 Alkoxypropylamine Oxide, Hydroxylauryl / Hydroxymyristyl Betaine, Hydroxystearic Acid, Amidohydroxysuccinimide C10-40 Ethylhexyl Isoalkanoate, Amidohydroxysuccinimide C21-22 Ethylhexyl Isoalkanoate, Hydroxy Sultaine, IPDI / PEG-15 Soyamine Oxide, IPDI / PEG-15 Soyamine Ethanol Methylsulfate Copolymer, IPDI / PEG-15 Soybean Glycinate Copolymer, Isoceteth-30, Isolaureth-4 Phosphate, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethicone, Isopropylamine Lanolinate, Isopropylamine Dodecylbenzenesulfonate, Isostearamidopropylamine Oxide, Isostearamidopropyl Betaine, Isostearamidopropyl Morpholine Oxide, Isosteareth-8, Isosteareth-16, Isosteareth-22, Isosteareth-25, Isosteareth-50, Isostearic Acid, Isostearyl Hydrolyzed Collagen, Jojoba Oil PEG-150 Esters, Jojoba Wax PEG-80 Esters, Jojoba Wax PEG-120 Esters, Lanoleth-20, Lanoleth-25, Lanoleth-40, Lanoleth-50, Lanoleth-60, Lanoleth-75, Lanolin Acid, Lauramidopropylamine Oxide, Lauramidopropyl Betaine, Lauramidopropyl Hydroxysultaine, Lauramine Oxide, Laurylaminopropionic Acid, Lauryldimethyl Hydroxypropyl Decyl Glucoside Hydroxypropyl Ammonium Chloride, Lauryldimethyl Lauryl Glucoside Hydroxypropyl Ammonium Chloride, Laureth-16, Laureth-20, Laureth-21, Laureth-23, Laureth-25, Laureth-30, Laureth-38 , Laureth-40, Laureth-3 Carboxylic Acid, Laureth-4 Carboxylic Acid, Laureth-5 Carboxylic Acid, Laureth-6 Carboxylic Acid, Laureth-8 Carboxylic Acid, Laureth-10 Carboxylic Acid, Laureth-11 Carboxylic Acid, Laureth-12 Carboxylic Acid, Laureth-13 Carboxylic Acid, Laureth-14 Carboxylic Acid, Laureth-17 Carboxylic Acid, Laureth-6 Citrate, Laureth-7 Citrate, Laureth-1 Phosphate, Laureth-2 Phosphate, Laureth-3 Phosphate, Laureth-4 Phosphate, Laureth-7 Phosphate, Laureth-8 Phosphate, Laureth-7 Tartrate, Lauric Acid, Lauryl Iminodipropylene Glycol, Lauryl Iminodipropionic Acid,Lauroyl Amphoteric Dipropionic Acid, Lauroyl Beta-Alanine, Lauroyl Collagen Amino Acids, Lauroyl Ethyltrimonium Methosulfate, Lauroyl Hydrolyzed Collagen, Lauroyl Hydrolyzed Elastin, Lauroyl Methyl Glucoamide, Lauroyl Sarcosine, Lauroyl Silk Amino Acids, Lauryl Betaine, Lauryl Dimethicone / Polyglyceryl-3 Crosspolymer, Lauryl Dimethyl Hydroxypropyl Cocoyl Glucoside Ammonium Chloride, Lauryl Glucoside, Lauryl Glucoside Hydroxypropyltrimonium Chloride, Lauryl Glycol Hydroxypropyl Ether, Lauryl Hydroxysultaine, Lauryl Malamide, Lauryl Methyl Glucosamine, Lauryl Glycol Hydroxypropyl Ether, Lauryl Wheat Bran / Straw Glycosides, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Polydimethylsiloxyethyl Methicone, Lauryl Pyrrolidone, Laurdimethyl Sultaine, Linoleic Acid, Linolenic Acid, Linolenic Acid, Lysine Cocoate, Macadamia Ternifolia Seed Oil Glycereth-8 Esters, Magnesium Cocoeth Sulfate, Magnesium Cocoyl Sulfate, Magnesium Isododecylphenyl Sulfonate, Magnesium Laureth-11 Carboxylate, Magnesium Laureth Sulfate, Magnesium Laureth-5 Sulfate, Magnesium Laureth-8 Sulfate, Magnesium Laureth-16 Sulfate, Magnesium Laureth-3 Sulfosuccinate, Magnesium Lauryl Hydroxypropyl Sulfate, Magnesium Lauryl Sulfate, Magnesium Methyl Cocoyl Taurate, Magnesium Myristeth Sulfate, Magnesium Oleth Sulfate, Magnesium Cocoyl Sulfate / TEA, Manigault Root Glacial Mud, MEA Cocoate, Laureth-6 Carboxylate Acid MEA, Lauryl Sulfate MEA Salt, Lauryl Sulfate MEA Salt, PPG-6-Laureth-7 Carboxylic Acid MEA Salt, PPG-8-Steareth-7 Carboxylic Acid MEA Salt, Undecylenic Acid MEA Salt, Meroxapol 108, Meroxapol 174, Meroxapol 178, Meroxapol 254, Meroxapol 255, Meroxapol 258, Meroxapol 314, Methoxy PEG-450 Amidoglutaryl Succinamide, Methoxy PEG-450 Amidohydroxysuccinimide Succinate, Methoxy PEG-450 Maleimide, Methylmorpholine Oxide, Milk Amidopropylamine Oxide, Milk Amidopropyl Betaine, Mink Amidopropylamine Oxide, Mink Amidopropyl Betaine, C12 -15 Alkyl Polyether Sulfate MIPA Salt, Dodecylbenzenesulfonic Acid MIPA Salt, Laureth Sulfate MIPA Salt, Lauryl Sulfate MIPA Salt, Mixed Isopropylamine Lanolin Salt, Mixed Isopropylamine Lauryl Sulfate, Mixed Isopropylamine Myristate, Morpholine Oleate, Morpholine Stearate, Myristeth-3 Carboxylic Acid, Myristeth-5 Carboxylic Acid, Myristyl Benzyldimonium Chloride, Myristamidopropylamine Oxide, Myristamidopropyl Betaine, Myristamidopropyl Dimethylamine Phosphate, Myristamidopropyl Hydroxysulfobetaine, Myristamidopropyl PG-Dimonium Chloride Phosphate, Myristamine Oxide, Myristylaminopropionic Acid, Myristic Acid, Myristoyl Ethyltrimonium Methylsulfate,Myristoyl Glutamate, Myristoyl Hydrolyzed Collagen, Myristoyl Sarcosine, Myristyl Betaine, Myristyl / Cetylamine Oxide, Myristyl Dimethyl Hydroxypropyl Cocoyl Glucoside Ammonium Chloride, Myristyl Glucoside, Myristyl Alcohol Phosphate, Nonylphenol Eth-20, Nonylphenol Eth-23, Nonylphenol Eth-25, Nonylphenol Eth-30, Nonylphenol Eth-35, Nonylphenol Eth-40, Nonylphenol Eth-44, Nonylphenol Eth-50, Nonylphenol Eth-100, Nonylphenol Eth-120, Nonylphenol Eth-5 Carboxylic Acid, Nonylphenol Eth-8 Carboxylic Acid, Nonylphenol Eth-10 Carboxylic Acid, Nonylphenol Eth-3 Phosphate, Nonylphenol Eth-4 Phosphate, Nonylphenol Eth-6 Phosphate, Nonylphenol Eth-9 Phosphate Acid ester, nonylphenol ether-10 phosphate, dinonylphenol ether-30, dinonylphenol ether-49, dinonylphenol ether-100, dinonylphenol ether-150, dinonylphenol ether-7 phosphate, dinonylphenol ether-8 phosphate, dinonylphenol ether-9 phosphate, dinonylphenol ether-10 phosphate, dinonylphenol ether-11 phosphate, dinonylphenol ether-15 phosphate, dinonylphenol ether-24 phosphate, oatamidopropyl betaine, octylphenol ether-16, octylphenol ether-25, octylphenol ether-30, octylphenol ether-33, octylphenol ether-40, octylphenol ether-70, octylphenol ether-20 carboxylic acid, octyldodecanol polyether-20, octyldodecanol polyether-25, octyldodecanol Oleth-30, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Oleamidopropyl (Hydroxysulfonyl)propyldimonium, Oleamine Oxide, Oleic Acid, Oleoyl Hydrolyzed Collagen, Oleoyl Sarcosine, Oleth-20, Oleth-23, Oleth-24, Oleth-25, Oleth-30, Oleth-35, Oleth-40, Oleth-44, Oleth-50, Oleth-3 Carboxylic Acid, Oleth-6 Carboxylic Acid, Oleth-10 Carboxylic Acid, Oleyl Betaine, Oleamidopropylamine Oxide, Oleamidopropyl Betaine, Olive Acid, Oleoyl Hydrolyzed Wheat Protein, Ophiopogon Japonicus Extract Stearate, Ozonated Oleth-10, Ozonated PEG-10 Oleate, Ozonated PEG-14 oleate, ozonated polysorbate 80, palmitoleic acid, palmitoleamidopropyl betaine, palmitoleth-2 phosphate, palmitamidopropylamine oxide, palmitamidopropyl betaine, palmitamine oxide, palmitic acid, palmitoyl collagen amino acids, palmitoyl glycine, palmitoyl hydrolyzed collagen, palmitoyl hydrolyzed milk protein, palmitoyl hydrolyzed wheat protein, palmitoyl keratin amino acids, palmitoyl oligopeptide, palmitoyl silk amino acids, palm kernel oleic acid, palm kernel oleamidopropyl betaine, peach kernel oil glyceryl polyether-8 esters, arachidonic acid, PEG-10 castor oil, PEG-40 castor oil, PEG-44 castor oil, PEG-50 castor oil, PEG-54 castor oil, PEG-55 castor oil,PEG-60 Castor Oil, PEG-80 Castor Oil, PEG-100 Castor Oil, PEG-200 Castor Oil, PEG-11 Cocamide, PEG-6 Cocamide Phosphate, PEG-4 Cocoamine, PEG-8 Cocoamine, PEG-12 Cocoamine, PEG-150 Dibehenate, PEG-90 Diisostearate, PEG-75 Dilaurate, PEG-150 Dilaurate, PEG-75 Dioleate, PEG-150 Dioleate, PEG-75 Distearate, PEG-120 Distearate, PEG-150 Distearate, PEG-175 Distearate, PEG-190 Distearate, PEG-250 Distearate, PEG- PEG-30 Glyceryl Cocoate, PEG-40 Glyceryl Cocoate, PEG-78 Glyceryl Cocoate, PEG-80 Glyceryl Cocoate, PEG-30 Glyceryl Isostearate, PEG-40 Glyceryl Isostearate, PEG-50 Glyceryl Isostearate, PEG-60 Glyceryl Isostearate, PEG-90 Glyceryl Isostearate, PEG-23 Glyceryl Laurate, PEG-30 Glyceryl Laurate, PEG-25 Glyceryl Oleate, PEG-30 Glyceryl Oleate, PEG-30 Glyceryl Soybean Oleate, PEG-25 Glyceryl Stearate, PEG-30 Glyceryl Stearate, PEG-40 Glyceryl Stearate, PEG-120 Glyceryl Stearate, PEG-200 Glyceryl Stearate, P EG-28 Glyceryl Tallowate, PEG-80 Glyceryl Tallowate, PEG-82 Glyceryl Tallowate, PEG-130 Glyceryl Tallowate, PEG-200 Glyceryl Tallowate, PEG-45 Hydrogenated Castor Oil, PEG-50 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil, PEG-55 Hydrogenated Castor Oil, PEG-60 Hydrogenated Castor Oil, PEG-80 Hydrogenated Castor Oil, PEG-100 Hydrogenated Castor Oil, PEG-200 Hydrogenated Castor Oil, PEG-30 Hydrogenated Lanolin, PEG-70 Hydrogenated Lanolin, PEG-50 Hydrogenated Palmitamide, PEG-2 Isostearate, PEG-3 Isostearate, PEG-4 Isostearate, PEG-6 Isostearate , PEG-8 Isostearate, PEG-10 Isostearate, PEG-12 Isostearate, PEG-20 Isostearate, PEG-30 Isostearate, PEG-40 Isostearate, PEG-26 Jojoba Acid, PEG-40 Jojoba Acid, PEG-15 Jojoba Alcohol, PEG-26 Jojoba Alcohol, PEG-40 Jojoba Alcohol, PEG-35 Lanolin, PEG-40 Lanolin, PEG-50 Lanolin, PEG-55 Lanolin, PEG-60 Lanolin, PEG-70 Lanolin, PEG-75 Lanolin, PEG-85 Lanolin, PEG-100 Lanolin, PEG-150 Lanolin, PEG-75 Lanolin Oil, PEG-2 Lauramide,PEG-3 lauramine oxide, PEG-20 laurate, PEG-32 laurate, PEG-75 laurate, PEG-150 laurate, PEG-70 mango seed oil glycerides, PEG-20 mannide laurate, PEG-8 methyl ether polydimethylsiloxane, PEG-120 methyl glucose dioleate, PEG-80 methyl glucose laurate, PEG-120 methyl glucose trioleate, PEG-4 montanate, PEG-30 oleamine, PEG-20 oleate, PEG-23 oleate, PEG-32 oleate, PEG-36 oleate, PEG-75 oleate, PEG-150 oleate, PEG-20 palmitate, PEG-15 0 Polyglyceryl-2 Tristearate, PEG / PPG-28 / 21 Acetate Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-3 / 17 Copolymer, PEG / PPG-5 / 35 Copolymer, PEG / PPG-8 / 55 Copolymer, PEG / PPG-10 / 30 Copolymer, PEG / PPG-10 / 65 Copolymer, PEG / PPG-12 / 35 Copolymer, PEG / PPG-16 / 17 Copolymer, PEG / PPG-20 / 9 Copolymer, PEG / PPG-20 / 20 Copolymer, PEG / PPG-20 / 60 Copolymer, PEG / PPG-20 / 65 Copolymer, PEG / PPG -22 / 25 copolymer, PEG / PPG-28 / 30 copolymer, PEG / PPG-30-35 copolymer, PEG / PPG-30 / 55 copolymer, PEG / PPG-35 / 40 copolymer, PEG / PPG-50 / 40 copolymer, PEG / PPG-150 / 35 copolymer, PEG / PPG-160 / 30 copolymer, PEG / PPG-190 / 60 copolymer, PEG / PPG-200 / 40 copolymer, PEG / PPG-300 / 55 copolymer, PEG / PPG-20 / 22 methyl ether polydimethylsiloxane, PEG-26-PPG-30 phosphate, PEG / PPG-4 / 2 propylheptyl ether, PEG / PPG -6 / 2 Propylheptyl Ether, PEG-7 / PPG-2 Propylheptyl Ether, PEG / PPG-8 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Propylheptyl Ether, PEG / PPG-14 / 2 Propylheptyl Ether, PEG / PPG-40 / 2 Propylheptyl Ether, PEG / PPG-10 / 2 Ricinoleate, PEG / PPG-32 / 3 Ricinoleate, PEG-55 Propylene Glycol Oleate, PEG-25 Propylene Glycol Stearate, PEG-75 Propylene Glycol Stearate, PEG-120 Propylene Glycol Stearate, PEG-5 Rapeseed Sterol, PEG-10 Rapeseed Sterol, PEG-40 Ricinoleamide, PEG-75 Shea Butter Glycerides, PEG-75 Solomon's Dimethicone Glycerides,PEG-20 Sorbitan Cocoate, PEG-20 Sorbitan Isostearate, PEG-40 Sorbitan Lanolinate, PEG-75 Sorbitan Lanolinate, PEG-10 Sorbitan Laurate, PEG-40 Sorbitan Laurate, PEG-44 Sorbitan Laurate, PEG-75 Sorbitan Laurate, PEG-80 Sorbitan Laurate, PEG-20 Sorbitan Oleate, PEG-80 Sorbitan Palmitate, PEG-40 Sorbitan Stearate, PEG-60 Sorbitan Stearate, PEG-160 Sorbitan Triisostearate, PEG-40 Soy Sterols, PEG-2 Stearamide Carboxylic acid, PEG-9 stearamide carboxylic acid, PEG-20 stearate, PEG-23 stearate, PEG-25 stearate, PEG-30 stearate, PEG-32 stearate, PEG-35 stearate, PEG-36 stearate, PEG-40 stearate, PEG-45 stearate, PEG-50 stearate, PEG-55 stearate, PEG-75 stearate, PEG-90 stearate, PEG-100 stearate, PEG-120 stearate, PEG-150 stearate, PEG-45 stearate phosphate, PEG-20 tallow esters, PEG-50 tallowamide, PEG-2 tallowamide DEA, PEG -20 tallow ester, PEG-66 trihydroxystearin, PEG-200 trihydroxystearin, PEG-60 camellia oleate glycerides, nonanoic acid, pentadecylphenol polyether-200, phenol polyether-6 phosphate, poloxamer 105, poloxamer 108, poloxamer 182, poloxamer 183, poloxamer 184, poloxamer 188, poloxamer 217, poloxamer 234, poloxamer 235, poloxamer 237, poloxamer 238, poloxamer 288, poloxamer 334, poloxamer 335, poloxamer 338, poloxamine 908, poloxamine 1508, polydimethylsiloxy PEG / PPG-24 / 19 butyl ether silsesquioxane, polydimethylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-6 Caprate, Polyglyceryl-10 Dilaurate, Polyglyceryl-20 Heptaoctanoate, Polyglyceryl-20 Hexaoctanoate, Polyglyceryl-2 Laureth Ether, Polyglyceryl-10 Laureth Ether, Polyglyceryl-20 Octaisononanoate, Polyglyceryl-6 Pentaoctanoate, Polyglyceryl-10 Pentaoctanoate, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Polyglyceryl-6 Tetraoctanoate, Polyglyceryl-10 Tetralaurate, Polyglyceryl-6 Trioctanoate, Polyglyceryl-10 Trilaurate, Polyquaternium-77, Polyquaternium-78, Polyquaternium-79, Polyquaternium-80, Polyquaternium-81, Polyquaternium-82,Poria cocos (PO-MADERRIS KUMERAHOU) flower / leaf extract, Poria cocos (PORIA COCOS) Extract, Potassium Abietic Acid Hydrolyzed Collagen, Potassium Babassu Oleate, Potassium Behenate, Potassium C9-15 Alkyl Phosphate, Potassium C11-15 Alkyl Phosphate, Potassium C12-13 Alkyl Phosphate, Potassium C12-14 Alkyl Phosphate, Potassium Caprate, Dipotassium Capryloyl Glutamate, Potassium Capryloyl Hydrolyzed Rice Protein, Potassium Ricinoleate, Potassium Cocoate, Potassium Cocoyl Glutamate, Potassium Cocoyl Glycinate, Potassium Cocoyl Hydrolyzed Casein, Potassium Cocoyl Hydrolyzed Collagen, Potassium Cocoyl Hydrolyzed Corn Protein, Potassium Cocoyl Hydrolyzed Keratin, Potassium Cocoyl Hydrolyzed Oat Protein, Potassium Cocoyl Hydrolyzed Potato Protein, Potassium Cocoyl Hydrolyzed Rice Bran Protein, Potassium Cocoyl Hydrolyzed Rice Protein, Potassium Cocoyl Hydrolyzed Silk, Potassium Cocoyl Hydrolyzed Soy Protein, Cocoyl Hydrolyzed Potassium Wheat Protein, Potassium Cocoyl Hydrolyzed Yeast Protein, Potassium Cocoyl PCA, Potassium Cocoyl Sarcosinate, Potassium Cocoyl Taurate, Potassium Corn Oleate, Potassium Cyclopentasiloxane, Potassium Dihydroxyethyl Cocoamine Oxide Phosphate, Potassium Dimethicone PEG-7 Phosphate, Potassium Dodecylbenzenesulfonate, Potassium Hemp Seed Oil, Potassium Hydrogenated Cocoate, Potassium Hydrogenated Palm Oleate, Potassium Hydroxystearate, Potassium Hydroxystearate, Potassium Lanolin Oxide, Potassium Laureth-3 Carboxylate, Potassium Laureth-4 Carboxylate, Potassium Laureth-5 Carboxylate, Potassium Laureth-6 Carboxylate, Potassium Laureth-10 Carboxylate, Potassium Laureth Phosphate, Potassium Lauroyl Collagen Amino Acids, Potassium Lauroyl Glutamate, Lauroyl Water Potassium Lauryl Hydrolyzed Pea Protein, Potassium Lauryl Hydrolyzed Soy Protein, Potassium Lauryl PCA, Potassium Lauryl Pea Amino Acids, Potassium Lauryl Sarcosinate, Potassium Lauryl Silk Amino Acids, Potassium Lauryl Wheat Amino Acids, Potassium Lauryl Phosphate, Potassium Lauryl Sulfate, Potassium Linoleate, Potassium Metaphosphate, Potassium Methyl Cocoyl Taurate, Potassium Myristate, Potassium Myristoyl Glutamate, Potassium Myristoyl Hydrolyzed Collagen, Potassium Octylphenol Eth-12 Phosphate, Potassium Oleate, Potassium Oleoyl Hydrolyzed Collagen, Potassium Olivate, Potassium Olivate Hydrolyzed Oat Protein, Potassium Olivate Hydrolyzed Wheat Protein, Potassium Olivate / Lauroyl Wheat Amino Acids, Potassium Olivate PCA, Potassium Palmitoleate, Potassium Palmitate, Potassium Palmitoyl Hydrolyzed Corn Protein, Palm Oil Potassium Palmitoyl Hydrolyzed Oat Protein, Potassium Palmitoyl Hydrolyzed Rice Protein, Potassium Palmitoyl Hydrolyzed Sweet Almond Protein, Potassium Palmitoyl Hydrolyzed Wheat Protein, Potassium Palm Kernel Oleate, Potassium Peanut Oleate, Potassium Rapeseed Oleate, Potassium Ricinoleate, Potassium Safflower Oleate, Potassium Soybean Oleate, Potassium Stearate, Potassium Stearoyl Hydrolyzed Collagen, Potassium Taloilate, Potassium Tallowate, Potassium Taurate, Potassium Taurate Laurate, Potassium Trideceth-3 Carboxylate, Potassium Trideceth-4 Carboxylate, Potassium Trideceth-7 Carboxylate, Potassium Trideceth-15 Carboxylate, Potassium Trideceth-19 Carboxylate, Potassium Trideceth-6 Phosphate, Potassium Trideceth-7 Phosphate, Potassium Camellia Oleate, Potassium Undecylenate, Potassium Undecylenoyl Hydrolyzed Collagen, Potassium Undecylenoyl Hydrolyzed Rice Protein,PPG-30-Buteth-30, PPG-36-Buteth-36, PPG-38-Buteth-37, PPG-30-Octeth-4 Phosphate, PPG-10 Cetyl Ether Phosphate, PPG-2C9-11 Alcohol Ether-8, PPG-1-Decaneth-5, PPG-3-Decaneth-2 Carboxylic Acid, PPG-30-Ethylhexyl Ether-4 Phosphate, PPG-20-Glycereth-30, PPG-2 Hydroxyethyl Coconut Oil / Isostearate Amide, PPG-2-isodecyl ether-8, PPG-2-isodecyl ether-10, PPG-2-isodecyl ether-18, PPG-2-decyl ether-25, PPG-4-decyl ether-10, Propyltrimonium Hydrolyzed Collagen, Quaternium-24, Quaternium-52, Quaternium-87, Rapeseed Oil Acid, Rice Fur Acid, Rice Oil Glyceryl Ether-8 Esters, Ricinoleic Acid Amidopropyl Betaine, Ricinoleic Acid, Ricinoleth-40, Safflower Oleic Acid, Sapindus Oahuen-sis Fruit Extract, SAPONARIA OFFICINALIS Root Powder, Saponins, Potassium Soap, Sodium / Potassium Soap, Soap Base, Potassium Soap Base, Sesame Oil Glycereth-8 Esters, Sesame Oil Amidopropylamine Oxide, Sesame Amidopropyl Betaine, Shea Butter Amidopropyl Betaine, Shea Butter Glycereth-8 Esters, Sodium Arachidate, Sodium Arganam-pohoacetate, Sodium Murumuru Palm Oil, Sodium Avocado Oil, Sodium Babassu Amphoacetate, Sodium Babassu Oil, Sodium Babassu Oil Sulfate, Sodium Behenate, Sodium Diethylene Glycol Ricinoleyl Sulfosuccinate, Sodium Bis-Hydroxyethyl Glycinate Cocoyl Glucoside Crosspolymer, Sodium Bis-Hydroxyethyl Glycinate Lauryl Glucoside Crosspolymer, Sodium Borage Amidopropyl PG-Dimonium Chloride Phosphate, Sodium Butylphenol Eth-12 Sulfate, Sodium Butyl Glucoside Hydroxypropyl Phosphate, Sodium C13-17 Alkane Sulfonate, Sodium C14-18 Alkane Sulfonate, Sodium C12-15 Alkoxypropyliminodipropionate, Sodium C10-16 Alkyl Sulfate, Sodium C11-15 Alkyl Sulfate, Sodium C12-13 Alkyl Sulfate, Sodium C12-15 Alkyl Sulfate Sodium, Sodium C12-18 Alkyl Sulfate, Sodium C16-20 Alkyl Sulfate, Sodium C9-22 Secondary Alkyl Sulfonate, Sodium C14-17 Secondary Alkyl Sulfonate, Sodium Caprate, Sodium Capryloylamphoacetate, Sodium Capryloylamphohydroxypropylsulfonate, Sodium Capryloylamphopropionate, Sodium Capryloyl Methyl Taurate, Sodium Caprylate, Sodium Capryleth-2 Carboxylate, Sodium Capryleth-9 Carboxylate, Sodium Capryloylamphoacetate, Sodium Capryloylamphohydroxypropylsulfonate, Sodium Capryloylamphopropionate, Disodium Capryloyl Glutamate, Sodium Capryloyl Hydrolyzed Wheat Protein, Sodium Capryl PG-Sulfonate, Sodium Capryl Sulfonate, Sodium Ricinoleate, Sodium Ceteareth-13 Carboxylate, Sodium Cetearyl Sulfate, Sodium Ceteth-13 Carboxylate, Sodium Cetyl Sulfate, Sodium Cocamidopropyl PG-Dimonium Chloride Phosphate, Sodium Cocoyl Alanine,Sodium Cocoeth Sulfate, Sodium Cocoeth-30 Sulfate, Sodium Cocoamphoacetate, Sodium Cocoyl Cocoate, Sodium Cocoamphoacetate, Sodium Cocoamphohydroxypropylsulfonate, Sodium Cocoamphopropionate, Sodium Cocoate, Sodium Cocoyl / Babassu / Andylabacetic Acid Sulfate, Sodium Cocoyl / Babassu Sulfate, Sodium Cocoyl Glucoside Hydroxypropyl Phosphate, Sodium Cocoyl Glucoside Hydroxypropylsulfonate, Sodium Coco-Glucoside Tartrate, Sodium Cocoglyceryl Ether Sulfonate, Sodium Cocoyl / Hydrogenated Tallow Alcohol Sulfate, Sodium Cocoiminodiacetate, Sodium Cocomonoglyceride Sulfate, Sodium Cocomonoglyceride Sulfate, Sodium Cocoyl PG-Dimonium Chloride Phosphate, Sodium Cocoyl Sulfate, Sodium Cocoyl Sulfoacetate, Coconut Oil Sodium amidopropionate, sodium cocoyl amino acids, sodium cocoyl collagen amino acids, disodium cocoyl glutamate, sodium cocoyl glutamate, sodium cocoyl glycinate, sodium cocoyl / hydrogenated tallow glutamate, sodium cocoyl hydrolyzed collagen, sodium cocoyl hydrolyzed keratin, sodium cocoyl hydrolyzed rice protein, sodium cocoyl hydrolyzed silk, sodium cocoyl hydrolyzed soy protein, sodium cocoyl hydrolyzed sweet almond protein, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl hydrolyzed wheat protein glutamate, sodium cocoyl isethionate, sodium cocoyl methylaminopropionate, sodium cocoyl oat amino acids, sodium cocoyl / palmitoleoyl / sunfloweroyl glutamate, sodium cocoyl proline, sodium cocoyl sarcosinate, sodium cocoyl taurate, sodium cocoyl threonine, coconut oil Sodium Oleyl Wheat Amino Acids, Sodium C12-14 Olefin Sulfonate, Sodium C14-16 Olefin Sulfonate, Sodium C14-18 Olefin Sulfonate, Sodium C16-18 Olefin Sulfonate, Sodium Corn Oleylamphopropionate, Sodium Cottonseed Oleylamphoacetate, Sodium C13-15 Pareth-8 Butyl Phosphate, Sodium C9-11 Pareth-6 Carboxylate, Sodium C11-15 Pareth-7 Carboxylate, Sodium C12-13 Pareth-5 Carboxylate, Sodium C12-13 Pareth-8 Carboxylate, Sodium C12-13 Pareth-12 Carboxylate, Sodium C12-15 Pareth-6 Carboxylate, Sodium C12-15 Pareth-7 Carboxylate, Sodium C12-15 Pareth-8 Carboxylate, Sodium C14-15 Pareth-8 Carboxylate, C12-14 Sodium secondary pareth-8 carboxylate, sodium C14-15 pareth-PG sulfonate, sodium C12-13 pareth-2 phosphate, sodium C13-15 pareth-8 phosphate, sodium C9-15 pareth-3 sulfate, sodium C10-15 pareth sulfate, sodium C10-16 pareth-2 sulfate, sodium C12-13 pareth sulfate, sodium C12-15 pareth sulfate, sodium C12-15 pareth-3 sulfate, sodium C12-15 pareth-3 sulfate, sodium C13-15 pareth-3 sulfate, secondary C12-14 pareth-3 sulfate, sodium C12-15 pareth-3 sulfonate, sodium C12-15 pareth-7 sulfonate, sodium C12-15 pareth-15 sulfonate, sodium decaneth-2 carboxylate, sodium decaneth sulfate,Sodium Decylbenzenesulfonate, Sodium Decyl Glucoside Hydroxypropyl Phosphate, Sodium Decyl Glucoside Hydroxypropyl Sulfonate, Sodium Dilaureth-7 Citrate, Sodium Dilaureth-10 Phosphate, Sodium Dilinoleamidopropyl PG-Dimonium Chloride Phosphate, Sodium Dilinoleate, Sodium Dioleth-8 Phosphate, Sodium Dodecylbenzenesulfonate, Sodium Ethyl 2-Sulfolaurate, Sodium Glyceryl Oleate Phosphate, Sodium Grapeseed Amidopropyl PG-Dimonium Chloride Phosphate, Sodium Grapeseed Amphoacetate, Sodium Grapeseed Amphoacetate, Sodium Hexyl Ethyl Isethionate, Sodium Hydrogenated Coconut Oil, Sodium Hydrogenated Cocoyl Methyl Isethionate, Sodium Hydrogenated Palm Oil, Sodium Hydrogenated Tallow Acid, Sodium Hydrogenated Tallowyl Glutamate, Sodium Hydroxylauryldimonium Ethyl Phosphate, Sodium Hydroxypropyl Palm Kernel Sulfonate, Sodium Hydroxypropyl Decyl Glucoside Phosphate Crosspolymer, Sodium Hydroxypropyl Lauryl Glucoside Phosphate Crosspolymer, Sodium Hydroxypropyl Cocoyl Glucoside Sulfonate Crosspolymer, Sodium Hydroxypropyl Decyl Glucoside Sulfonate Crosspolymer, Sodium Hydroxypropyl Lauryl Glucoside Sulfonate Crosspolymer, Sodium Hydroxystearate, Sodium Isostearate, Sodium Isosteareth-6 Carboxylate, Sodium Isosteareth-11 Carboxylate, Sodium Isostearylamphoacetate, Sodium Isostearylamphopropionate, Sodium N-Isostearyl Methyl Taurate, Sodium Lanolin Alcohol Sulfate, Sodium Lanolin Acid, Sodium Lardate, Sodium Lauramidodiacetate, Sodium Lauryl Propionate, Sodium Laurate, Sodium Laureth-3 Carboxylate, Laureth -4 Carboxylate, Sodium Laureth-5 Carboxylate, Sodium Laureth-6 Carboxylate, Sodium Laureth-8 Carboxylate, Sodium Laureth-11 Carboxylate, Sodium Laureth-12 Carboxylate, Sodium Laureth-13 Carboxylate, Sodium Laureth-14 Carboxylate, Sodium Laureth-16 Carboxylate, Sodium Laureth-17 Carboxylate, Sodium Laureth Sulfate, Sodium Laureth-5 Sulfate, Sodium Laureth-7 Sulfate, Sodium Laureth-8 Sulfate, Sodium Laureth-12 Sulfate, Sodium Laureth-40 Sulfate, Sodium Laureth-7 Tartrate, Disodium Lauriminodipropionate, Disodium Lauriminodipropionate, Sodium Lauroamphohydroxypropyl Sulfonate, Sodium Lauroampho PG-Acetate Phosphate, Sodium Lauroamphopropionate, Sodium Lauroyl Aspartate, Sodium Lauroyl Collagen Amino Acids, Sodium Lauroyl Glycine Propionate, Sodium Lauroyl Hydrolyzed Collagen, Sodium Lauroyl Hydrolyzed Silk, Sodium Lauroyl Hydroxypropyl Sulfonate, Sodium Lauroyl Isethionate, Sodium Lauroyl Methylaminopropionate, Sodium Lauroyl Methyl Isethionate, Sodium Lauroyl Millet Amino Acids, Sodium Lauroyl / Myristoyl Aspartate, Sodium Lauroyl Oat Amino Acids, Sodium Lauroyl Sarcosinate, Sodium Lauroyl Silk Amino Acids, Sodium Lauroyl Taurate, Sodium Lauroyl Wheat Amino Acids, Sodium Lauryl Di(Ethylenediamino) Glycine, Sodium Lauryl Glucose Carboxylate, Sodium Lauryl Glucoside Hydroxypropyl Phosphate, Sodium Lauryl Glucoside Hydroxypropyl Sulfonate, Sodium Lauryl Glycol Carboxylate, Sodium Lauryl Glycol Hydroxyethylamide Sulfate,Disodium Lauryl Phosphate, Sodium Lauryl Sulfate, Sodium Lauryl Sulfoacetate, Sodium Linoleate, Sodium Macadamia Ternifolia Seed Oil, Sodium Mango Amphoacetate, Sodium Mango Seed Esters, Sodium Laureth-2 Sulfosuccinate / MEA, Sodium Methoxy PPG-2 Acetate, Sodium Methyl Cocoyl Taurate, Sodium Methyl Lauroyl Taurate, Sodium Methyl Myristoyl Taurate, Sodium Methyl Oleyl Taurate, Sodium Methyl Palmitoyl Taurate, Sodium Methyl Stearoyl Taurate, Sodium Methyl 2-Sulfolaurate, Sodium Methyl 2-Sulfalmitate, Sodium Methyl Isopalmitoyl Taurate, Methyl Cocoyl Taurate Sodium Myristyl Ester Sulfate, Sodium Myristate, Sodium Myristoyl Amphoacetate, Sodium Myristoyl Glutamate, Sodium Myristoyl Hydrolyzed Collagen, Sodium Myristoyl Isethionate, Sodium Myristoyl Sarcosinate, Sodium Myristyl Sulfate, Sodium Nonylphenoleth-6 Phosphate, Sodium Nonylphenoleth-9 Phosphate, Sodium Nonylphenoleth-1 Sulfate, Sodium Nonylphenoleth-3 Sulfate, Sodium Nonylphenoleth-4 Sulfate, Sodium Nonylphenoleth-6 Sulfate, Sodium Nonylphenoleth-8 Sulfate, Sodium Nonylphenoleth-10 Sulfate, Sodium Nonylphenoleth-25 Sulfate, Sodium Octylphenoleth-2 Ethylsulfonate, Octylphenoleth Sodium Pheneth-2 Sulfate, Sodium Octaneth-6 Sulfate, Sodium Octaneth-9 Sulfate, Sodium Oleate, Sodium Oleoamphoacetate, Sodium Oleoamphohydroxypropyl Sulfonate, Sodium Oleoamphopropionate, Sodium Oleoyl Hydrolyzed Collagen, Sodium Oleoyl Isethionate, Sodium Oleth Sulfate, Sodium Oleoyl Methyl Isethionate, Sodium Oleoyl Sulfate, Sodium Oleoamphoacetate, Sodium Olive Oil, Sodium Olive Oil, Sodium Oleoyl Glutamate, Sodium Palmitoleoamphoacetate, Sodium Palmitoleate, Sodium Palmitoleyl Glyceryl Sulfonate, Sodium Palmitate, Sodium Palmitoyl Hydrolyzed Collagen, Sodium Palmitoyl Hydrolyzed Wheat Protein, Sodium Palmitoyl Sarcosinate, Palm Kernel Oil Sodium Palmitate, Sodium Palmitoleyl Isethionate, Sodium Palmitoleyl Glutamate, Sodium Passionflower Seed Oil, Sodium Peanut Amphoacetate, Sodium Peanut Acid, Sodium PEG-6 Cocamide Carboxylate, Sodium PEG-8 Cocamide Carboxylate, Sodium PEG-4 Cocamide Sulfate, Sodium PEG-3 Lauramide Carboxylate, Sodium PEG-4 Lauramide Carboxylate, Sodium PEG-8 Palm Glycerides Carboxylate, Sodium Pentaerythrityl Hydroxypropylimidodiacetate Dendrimer, Sodium Propoxylated PPG-2 Acetate, Sodium Rapeseed Oil, Sodium Rice Bran Amphoacetate, Sodium Ricinoleate, Sodium Ricinoleamide Amphoacetate, Sodium Rose Hipsamphoacetate, Sodium Rosinate, Sodium Safflower Oleate, Sodium Saffloweroyl Hydrolyzed Soy Protein, Sodium Sesame Seed Oleate, Sodium Sesame Amphoacetate, Sodium Shea Butter Amphoacetate, Sodium Soy Oleate, Sodium Soy Hydrolyzed Collagen, Sodium Stearate, Sodium Stearoyl Amphoacetate, Sodium Stearoyl Amphopropyl Sulfonate, Sodium Stearoyl Amphopropionate, Sodium Stearoyl Casein, Sodium Stearoyl Glutamate, Sodium Stearoyl Hyaluronate, Sodium Stearoyl Hydrolyzed Collagen, Sodium Stearoyl Hydrolyzed Zein, Sodium Stearoyl Hydrolyzed Silk,Sodium stearoyl hydrolyzed soy protein, sodium stearoyl hydrolyzed wheat protein, sodium stearoyl whey protein, sodium stearoyl methyl isethionate, sodium stearoyl oat protein, sodium stearoyl pea protein, sodium stearoyl soy protein, sodium stearyl dimethyl glycinate, sodium stearyl sulfate, sodium sunflower oil acyl amphoacetate, sodium subtilisin, sodium sweet almond acyl amphoacetate, sodium sweet almond acyl oleate, sodium tallow acyl propionate, sodium tallow acid acid, sodium tallow acyl oleate, sodium tallow sulfate, callophyllostachys chinensis (CALLOPHYLLUM INOPHYLLUM) seed oil sodium, sodium taurate, sodium cocoyl methyl taurate, sodium laurate taurate, sodium lauroyl collagen amino acid / TEA salt, sodium lauroyl hydrolyzed collagen / TEA salt, sodium lauroyl hydrolyzed keratin salt / TEA salt, sodium lauroyl keratin amino acid / TEA salt, sodium undecylenyl collagen amino acid / TEA salt, sodium undecylenyl hydrolyzed collagen / TEA salt, sodium undecylenyl hydrolyzed corn protein / TEA salt, sodium undecylenyl hydrolyzed soy protein / TEA salt, sodium undecylenyl hydrolyzed wheat protein / TEA salt, Theobroma grandiflora GRANDIFLORUM) seed oil, sodium trideceth-3 carboxylate, sodium trideceth-4 carboxylate, sodium trideceth-6 carboxylate, sodium trideceth-7 carboxylate, sodium trideceth-8 carboxylate, sodium trideceth-12 carboxylate, sodium trideceth-15 carboxylate, sodium trideceth-19 carboxylate, sodium trideceth sulfate, sodium tridecylbenzenesulfonate, sodium tridecyl sulfate, sodium trimethylolpropane hydroxypropyliminodiacetate dendrimer, sodium undeceth-5 carboxylate, sodium undecylenate, sodium undecylenoamphoacetate, sodium undecylenoamphopropionate, disodium undecylenoyl glutamate, sodium wheat germ oleoamphoacetate, sorbitan-160 tristearate, soy oleic acid, soyamidopropylamine oxide, soyamidopropyl betaine, soy glyceryl ether-8 esters, isostearamidopropylamine oxide, Stearamidopropyl Betaine, Stearamine Oxide, Steareth-15, Steareth-16, Steareth-20, Steareth-21, Steareth-25, Steareth-27, Steareth-30, Steareth-40, Steareth-50, Steareth-80, Steareth-100, Steareth-2 Phosphate, Steareth-3 Phosphate, Stearic Acid, Stearoxypropyl Trimethylolpropane Ammonium chloride, stearoyl glutamic acid, stearoyl sarcosine, stearyl betaine, stearyl dimethyl butyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl decyl glucoside hydroxypropyl ammonium chloride, stearyl dimethyl lauryl glucoside hydroxypropyl ammonium chloride, sulfated castor oil, sulfated coconut oil, sulfated glyceryl oleate, sulfated olive oil, sulfated peanut oil, sunflower oleamide MEA, sunflower oil acid, sunflower oil amidopropyl hydroxyethyl dimonium chloride,Sunflower Seed Oil Glyceryl Polyether-8 Esters, Tall Oil Acid, Tallow Acid, Tallowamidopropylamine Oxide, Tallowamidopropyl Betaine, Tallowamidopropyl Hydroxysultaine, Tallowamine Oxide, Tallow Betaine, Tallow Dihydroxyethyl Betaine, Tallowyl Ethyl Glucoside, Abietic Hydrolyzed Collagen TEA Salt, C12-14 Alkyl Phosphate TEA Salt, C10-15 Alkyl Sulfate TEA Salt, C11-15 Alkyl Sulfate TEA Salt, C12-13 Alkyl Sulfate TEA Salt, TEA-C12-14 Alkyl Sulfate TEA Salt, TEA-C12-15 Alkyl Sulfate TEA Salt, TEA C14-17 secondary alkyl sulfonate TEA, rapeseed oil TEA, cocamide diacetate TEA, coconut oil acid TEA, coconut oil alcohol sulfate TEA, cocoyl alanine TEA, cocoyl glutamate TEA, cocoyl glutamine TEA, cocoyl glycinate TEA, cocoyl hydrolyzed collagen TEA, cocoyl hydrolyzed soy protein TEA, cocoyl sarcosine TEA, polydimethylsiloxane PEG-7 phosphate TEA, dodecylbenzenesulfonate TEA, hydrogenated coconut oil TEA, hydrogenated tallow glutamate TEA salt, TEA isostearate, TEA-isostearoyl hydrolyzed collagen TEA salt, lauryl aminopropionic acid TEA salt, lauric acid TEA salt, lauric acid / myristic acid TEA salt, laureth sulfate TEA salt, lauroyl collagen amino acid TEA salt, lauroyl glutamic acid TEA salt, lauroyl hydrolyzed collagen TEA salt, lauroyl keratin amino acid TEA salt, lauroyl methylaminopropionic acid TEA salt, lauroyl / myristic acid aspartic acid TEA salt, lauroyl sarcosine TEA salt, lauryl phosphate TEA salt, lauryl sulfate TEA salt, meat TEA myristyl propionate, TEA myristate, TEA myristoyl hydrolyzed collagen, TEA oleate, TEA oleoyl hydrolyzed collagen, TEA oleoyl sarcosinate, TEA oleyl sulfate, TEA palmitate, TEA palm kernel sarcosinate, TEA PEG-3 cocamide sulfate, TEA rosinate, TEA stearate, TEA tallate, TEA tridecylbenzenesulfonate, TEA undecylenate, TEA undecylenyl hydrolyzed collagen, tetramethyldecynediol, tetrasodium dicarboxyethyl stearyl sulfosuccinamate, laurate Alcohol polyether sulfate TIPA salt, lauryl sulfate TIPA salt, myristic acid TIPA salt, stearic acid TIPA salt, tocopheryl phosphate, trehalose undecylenate, TM-C12-15 pareth-2 phosphate, TM-C12-15 pareth-6 phosphate, TM-C12-15 pareth-8 phosphate, TM-C12-15 pareth-10 phosphate, trideceth-20, trideceth-50, trideceth-3 carboxylic acid, trideceth-4 carboxylic acid, trideceth-7 carboxylic acid, trideceth-8 carboxylic acid,Trideceth-15 Carboxylic Acid, Trideceth-19 Carboxylic Acid, Trideceth-10 Phosphate, Tridecylbenzenesulfonic Acid, Trilaureth-9 Citrate, Trimethylolpropane Hydroxypropyl Bis(hydroxyethyl)amine Dendrimer, Tri(Sodium Lauroampho PG-Acetate Chloride) Phosphate, Undecanoic Acid, Undeceth-5 Carboxylic Acid, Undecylenamidopropylamine Oxide, Undecylenamidopropyl Betaine, Undecylenic Acid, Undecylenoyl Collagen Amino Acids, Undecylenoyl Glycine, Undecylenoyl Hydrolyzed Collagen, Undecylenoyl Wheat Amino Acids, Undecyl Glucoside, Wheat Germ Acid ...

[0077] Preferred are one or more compounds selected from the group consisting of sodium laureth sulfate, cocamidopropyl betaine, sodium cocoamphoacetate, coco-glucoside and ammonium lauryl sulfosuccinate.

[0078] The surfactant may be contained in the formulation in an amount of 0.1 to 10% by weight, and preferably in an amount of 0.5 to 5% by weight, based on the formulation.

[0079] Oil bodies

[0080] The composition may also contain oil bodies, also known as lipids, such as:

[0081] (i) linear or branched saturated paraffin waxes having 15 or more carbon atoms, especially 18 to 45 carbon atoms

[0082] (mineral oil);

[0083] (ii) a linear or branched fatty acid having 6 to 30 carbon atoms and a linear or branched fatty acid having 3 to 30 carbon atoms

[0084] Lined, saturated or unsaturated mono-, di- or tri-alcohol esters having 12 or more carbon atoms, these esters having no free

[0085] hydroxyl group;

[0086] (iii) esters of benzoic acid and straight-chain or branched, saturated or unsaturated monoalkanols having 8 to 20 carbon atoms;

[0087] (iv) monoesters or diesters of alcohols having 3 to 30 carbon atoms with naphthalene-mono- or dicarboxylic acids; in particular naphthalene-monocarboxylic acids C6-C 18 Ester and naphthalene dicarboxylic acid di-C6-C 18 ester;

[0088] (v) Straight or branched, saturated or unsaturated di-C6-C 18 -alkyl ethers;

[0089] (vi) silicone oil;

[0090] (vii) 2-Alkyl-1-alkanol of general formula (III)

[0091]

[0092] in

[0093] Q1 is a linear or branched alkyl group having 6 to 24 carbon atoms, and

[0094] Q2 is a linear or branched alkyl group having 4 to 16 carbon atoms.

[0095] The oil phase or oil component in the narrow (and preferred) sense of the present invention, i.e. the oil phase or oil component of the substances defined herein or of substances present only in a minor part, comprises the following substance groups:

[0096] (i) a linear or branched saturated alkanes having 20 to 32 carbon atoms;

[0097] (ii) esters of linear or branched saturated fatty acids having 8 to 24 carbon atoms and of linear or branched, saturated or unsaturated mono-, di- or triols having 3 to 24 carbon atoms, having at least 14 carbon atoms, these esters containing no free hydroxyl groups;

[0098] (iii) Esters of benzoic acid and straight-chain or branched saturated monoalkanols having 10 to 18 carbon atoms;

[0099] (iv) alkyl glycol dicaprylate / dicaprate, especially propylene glycol dicaprylate / dicaprate;

[0100] (v) linear or branched saturated di-C6-C18-alkyl ethers, in particular (linear) di-C6-C12-alkyl ethers;

[0101] (vi) a silicone oil selected from cyclotrisiloxane, cyclopentasiloxane, dimethylpolysiloxane, diethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, and mixtures thereof;

[0102] (vii) 2-Alkyl-1-alkanols having 12 to 32 C atoms of the formula (III), wherein Q1 is a (preferably linear) alkyl group having 6 to 18 C atoms and Q2 is a (preferably linear) alkyl group having 4 to 16 C atoms.

[0103] The oil phase in the narrowest (and most preferred) sense of the invention comprises the following groups of substances:

[0104] (i) a straight-chain or branched saturated alkane having 20 to 32 carbon atoms, such as isoeicosane or squalane;

[0105] (ii) esters of linear or branched saturated fatty acids having 8 to 18 carbon atoms and linear or branched saturated mono-, di- or triols having 3 to 18 carbon atoms, having at least 16 carbon atoms, these esters containing no free hydroxyl groups;

[0106] (iii) esters of benzoic acid and straight-chain or branched saturated monoalkanols having 12 to 15 carbon atoms, especially benzoic acid C 12-15 -alkyl esters;

[0107] (iv) alkyl glycol dicaprylate / dicaprate, especially propylene glycol dicaprylate / dicaprate;

[0108] (v) Straight chain di-C6-C 10 - alkyl ethers, especially di-n-octyl ether (dioctyl ether);

[0109] (vi) silicone oils selected from the group consisting of undecamethylcyclotrisiloxane, cyclomethicone, decamethylcyclopentasiloxane, dimethylpolysiloxane, diethylpolysiloxane, methylphenylpolysiloxane and diphenylpolysiloxane;

[0110] (vii) 2-Alkyl-1-alkanols having 12 to 32 C atoms of the formula (III), wherein Q1 is a (preferably linear) alkyl group having 6 to 18 C atoms and Q2 is a (preferably linear) alkyl group having 4 to 16 C atoms.

[0111] Particularly preferred components of type (i) in the oil phase are as follows: isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl oleate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl laurate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, 2-ethylhexyl isostearate, isotridecyl isononanoate, 2-ethylhexyl cocoate, caprylic / capric triglyceride, alkyl glycol dicaprylate / dicaprate, in particular propylene glycol dicaprylate / dicaprate; and synthetic, semisynthetic and natural mixtures of these esters, for example jojoba oil.

[0112] The fatty acid triglycerides (oil component of type (i) in the oil phase) may also be in the form of or components of synthetic, semi-synthetic and / or natural oils, such as olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, palm kernel oil and mixtures thereof.

[0113] Particularly preferred oil components of type (vii) in the oil phase are as follows: 2-butyl-1-octanol, 2-hexyl-1-decanol, 2-octyl-1-dodecanol, 2-decyltetradecyl alcohol, 2-dodecyl-1-hexadecanol and 2-tetradecyl-1-octadecanol.

[0114] A particularly preferred oil component in the oil phase is one containing benzoic acid C 12 -C 15 - A mixture of alkyl esters and 2-ethylhexyl isostearate, containing benzoic acid C 12 -C 15 - a mixture of alkyl esters and isotridecyl isononanoate, containing benzoic acid C 12 -C 15 -alkyl esters, a mixture of 2-ethylhexyl isostearate and isotridecyl isononanoate, a mixture containing cyclomethicone and isotridecyl isononanoate, and a mixture containing cyclomethicone and 2-ethylhexyl isostearate.

[0115] Preferred oil bodies, which are components of O / W emulsions, are based, for example, on Guerbet alcohols having 6 to 18, preferably 8 to 10, carbon atoms, on esters of linear C6-C22-fatty acids with linear or branched C6-C22-fatty alcohols or on esters of branched C6-C13-carboxylic acids with linear or branched C6-C22-fatty alcohols, such as, for example, myristyl myristate, myristyl palmitate, myristyl stearate, myristyl isostearate, myristyl oleate, myristyl behenate, myristyl erucate, cetyl myristate, cetyl palmitate, cetyl stearate, cetyl isostearate, cetyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, isostearyl oleate, cetyl behenate, cetyl erucate, stearyl myristate, stearyl palmitate, stearyl stearate, isostearyl oleate, Stearyl stearate, stearyl oleate, stearyl behenate, stearyl erucate, isostearyl myristate, isostearyl palmitate, isostearyl stearate, isostearyl isostearate, isostearyl oleate, isostearyl behenate, isostearyl oleate, oleyl myristate, oleyl palmitate, oleyl stearate, oleyl isostearate, oleyl oleate, oleyl behenate, oleyl erucate, behenyl myristate, behenyl palmitate, behenyl stearate, behenyl isostearate, behenyl oleate, behenyl behenate, behenyl erucate, erucyl myristate, erucyl palmitate, erucyl stearate, erucyl isostearate, erucyl oleate, erucyl behenate, and erucyl erucate. Furthermore suitable are esters of linear C6-C22 fatty acids with branched alcohols, in particular 2-ethylhexanol, esters of C18-C38-alkylhydroxycarboxylic acids with linear or branched C6-C22-aliphatic alcohols, in particular dioctyl malate, esters of linear and / or branched fatty acids with polyols (such as, for example, propylene glycol, dimerdiol or trimertriol) and / or Guerbet alcohols, triglycerides based on C6-C10 fatty acids, Esters, liquid mono- / di- / triglyceride mixtures based on C6-C18 fatty acids, esters of C6-C22-aliphatic alcohols and / or Guerbet alcohols with aromatic carboxylic acids, in particular benzoic acid, esters of C2-C12-dicarboxylic acids with linear or branched alcohols having 1 to 22 carbon atoms or polyols having 2 to 10 carbon atoms and 2 to 6 hydroxyl groups, vegetable oils, branched primary alcohols, substituted cyclohexanes, carbonates of linear and branched C6-C22-aliphatic alcohols, such as, for example, dicaprylyl carbonate ( CC), Guerbet carbonates based on aliphatic alcohols having 6 to 18, preferably 8 to 10, carbon atoms, esters of benzoic acid with linear and / or branched C6-C22-alcohols (e.g. TN), linear or branched, symmetrical or asymmetrical dialkyl ethers each of which has 6 to 22 carbon atoms, such as, for example, dicaprylyl ether ( OE), ring-opening products of epoxidized fatty acid esters with polyols, silicone oils (cyclodimethicone, silicone methicone grades, etc.) and / or aliphatic or cycloalkanes, such as, for example, squalane, squalene or dialkylcyclohexanes.

[0116] emulsifiers

[0117] Other nonionic or cationic surfactants can also be added to the formulation as emulsifiers, including for example:

[0118] ● 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide with linear C 8-22 Aliphatic alcohols, and C 12-22 fat

[0119] Addition products of fatty acids and alkylphenols having 8 to 15 carbon atoms in the alkyl group;

[0120] · C of addition products of 1 to 30 mol of ethylene oxide onto glycerol 12 / 18 fatty acid monoesters and diesters;

[0121] Glycerol monoesters and diesters and sorbitan monoesters of saturated and unsaturated fatty acids containing 6 to 22 carbon atoms

[0122] and diesters and their ethylene oxide addition products;

[0123] Addition products of 15 to 60 mol of ethylene oxide onto castor oil and / or hydrogenated castor oil;

[0124] Polyol esters, especially polyglycerol esters such as polyglycerol polyricinoleate, polyglycerol poly-12-hydroxystearate

[0125] Ester or polyglycerol dimer oil isostearate. Also suitable are mixtures of multiple such compounds;

[0126] Addition products of 2 to 15 mol of ethylene oxide onto castor oil and / or hydrogenated castor oil;

[0127] Based on straight chain, branched, unsaturated or saturated C 6 / 22 Fatty acids, ricinoleic acid, 12-hydroxystearic acid and glycerol

[0128] Partially soluble in water, polyglycerol, pentaerythritol, dipentaerythritol, sugar alcohols (such as sorbitol), alkyl glucosides (such as methyl glucoside, butyl glucoside, lauryl glucoside) and polyglucosides (such as cellulose)

[0129] ester;

[0130] Mono-, di- and tri-alkyl phosphates and mono-, di- and / or tri-PEG alkyl phosphates and their salts;

[0131] ●Wool wax alcohols;

[0132] ●Polysiloxane / polyalkyl polyether copolymers and corresponding derivatives;

[0133] ● Pentaerythritol, fatty acid, citric acid and fatty alcohol mixture and / or C 6-22 Fatty acids, methyl glucose and

[0134] Polyols, preferably glycerol or polyglycerol mixtures;

[0135] ●Polyglycols and

[0136] ●Glyceryl carbonate.

[0137] Commercially available products include addition products of ethylene oxide and / or propylene oxide with aliphatic alcohols, fatty acids, and alkylphenols, as well as mono- and diesters of glycerol and sorbitan with fatty acids or castor oil. These are homologous mixtures whose average degree of alkoxylation corresponds to the ratio of the amount of ethylene oxide and / or propylene oxide to the substrate used in the addition reaction. C12 / 18 fatty acid mono- and diesters of ethylene oxide addition products with glycerol are known for use as refatting agents in cosmetic preparations. Preferred emulsifiers are listed in detail below:

[0138] Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride, and technical mixtures thereof which may still contain small amounts of triglycerides originating from the production process. Addition products of 1 to 30, and preferably 5 to 10, mol of ethylene oxide to the aforementioned partial glycerides are also suitable.

[0139] Partial glycerides. Typical examples of suitable partial glycerides are hydroxystearic acid monoglyceride, hydroxystearic acid diglyceride, isostearic acid monoglyceride, isostearic acid diglyceride, oleic acid monoglyceride, oleic acid diglyceride, ricinoleic acid monoglyceride, ricinoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, linoleic acid monoglyceride, linoleic acid diglyceride, erucic acid monoglyceride, erucic acid diglyceride, tartaric acid monoglyceride, tartaric acid diglyceride, citric acid monoglyceride, citric acid diglyceride, malic acid monoglyceride, malic acid diglyceride, and technical mixtures thereof which may still contain small amounts of triglycerides originating from the production process. Addition products of 1 to 30, and preferably 5 to 10, mol of ethylene oxide to the aforementioned partial glycerides are also suitable.

[0140] Polyglycerol esters. A typical example of a suitable polyglycerol ester is polyglyceryl-2 dipolyhydroxystearate (Dehy-

[0141] PGPH), polyglyceryl-3-diisostearate ( TGI), Polyglyceryl-4 Isostearate (Iso- GI 34), Polyglyceryl-3 Oleate, Polyglyceryl-3 Diisostearate ( PDI), Polyglyceryl-3 Methyl Glucose Distearate (Tego 450), Polyglyceryl-3 Beeswax (Cera ), Polyglyceryl-4 Caprate (Polyglyceryl Caprate T2010 / 90), Polyglyceryl-3 Cetyl Ether ( NL), Polyglyceryl-3 Distearate ( GS32) and polyglycerol polyricinoleate ( WOL 1403), polyglyceryl diisostearate, and mixtures thereof. Other examples of suitable polyol esters are the monoesters, diesters, and triesters of lauric acid, coconut acid, tallow acid, palmitic acid, stearic acid, oleic acid, behenic acid, etc., optionally reacted with 1 to 30 mol of ethylene oxide, and trimethylolpropane or pentaerythritol.

[0142] Tetraalkyl quaternary ammonium salts. Cationic surfactants contain hydrophobic polymer groups that are required to have surface activity in cations by dissociating in aqueous solution. An important group of cationic surfactants is the general formula (R 1 R 2 R 3 R 4 N + )X - tetraalkyl quaternary ammonium salt. Here, R 1 represents a C1-C8 alkane (alkenyl) group, R 2 、R 3 and R 4 Each of the following independently represents an alk(en)yl group containing 1 to 22 carbon atoms. X is a counterion, preferably selected from the group consisting of halides, alkyl sulfates and alkyl carbonates. Particularly preferred are cationic surfactants in which the nitrogen group is substituted by two long acyl groups and two short alk(en)yl groups.

[0143] Esterquats. A group of cationic surfactants particularly useful as cosurfactants according to the present invention are the so-called esterquats. Esterquats generally refer to quaternized fatty acid triethanolamine ester salts. They are known compounds and can be obtained by methods of preparative organic chemistry. Reference is made in this regard to International Patent Application WO 91 / 01295 A1, in which triethanolamine is partially esterified with fatty acids in the presence of hypophosphorous acid, air is passed through the reaction mixture, and the whole is subsequently quaternized with dimethyl sulfate or ethylene oxide. Furthermore, German Patent DE 4308794 C1 describes a process for preparing solid esterquats, in which the quaternization of the triethanolamine ester is carried out in the presence of a suitable dispersant, preferably a fatty alcohol.

[0144] Typical examples of esterquats suitable for use in the present invention are products whose acyl component is derived from a monocarboxylic acid of the formula RCOOH—wherein RCO is an acyl group containing 6 to 10 carbon atoms—and whose amine component is triethanolamine (TEA). Examples of such monocarboxylic acids are caproic acid, caprylic acid, capric acid, and technical mixtures thereof, such as so-called head-fractionated fatty acids. Preference is given to using esterquats whose acyl component is derived from a monocarboxylic acid containing 8 to 10 carbon atoms. Other esterquats are those whose acyl component is derived from a dicarboxylic acid, such as malonic acid, succinic acid, maleic acid, fumaric acid, glutaric acid, sorbic acid, pimelic acid, azelaic acid, sebacic acid and / or dodecanedioic acid, but preferably adipic acid. In general, preference is given to using esterquats whose acyl component is derived from a mixture of a monocarboxylic acid containing 6 to 22 carbon atoms and adipic acid. The molar ratio of monocarboxylic acid to dicarboxylic acid in the final esterquat is 1:99 to 99:1, preferably 50:50 to 90:10, and more particularly 70:30 to 80:20. In addition to quaternized fatty acid triethanolamine ester salts, other suitable esterquats are quaternized ester salts of mono- and dicarboxylic acid mixtures with diethanolalkylamine or 1,2-dihydroxypropyldialkylamine. Esterquats can be obtained from fatty acids and the corresponding triglycerides mixed with the corresponding dicarboxylic acids. One such method, representative of the relevant prior art, is described in European Patent EP 0 750 606 B1. To prepare the quaternized esters, mixtures of mono- and dicarboxylic acids with triethanolamine can be used in a molar ratio of 1.1:1 to 3:1, based on the available carboxyl functional groups. Considering the properties of the esterquat, ratios of 1.2:1 to 2.2:1, and in particular 1.5:1 to 1.9:1, have proven particularly advantageous. Preferred esterquats are technical mixtures of mono-, di- and triesters having an average degree of esterification of 1.5 to 1.9.

[0145] It is further advantageous to use a combination of anionic and / or amphoteric surfactants with one or more nonionic surfactants. In a preferred embodiment according to the present invention, the composition further comprises an emulsifier selected from the group consisting of:

[0146] ●Alkyl phosphate derivatives

[0147] ●Glyceryl oleate citrate derivative

[0148] ●Glyceryl Stearate Citrate Derivative

[0149] Stearate

[0150] Sorbitol esters

[0151] ·Ethoxylated sorbitan esters

[0152] Ethoxylated mono-, di-, and triglycerides

[0153] Methyl glucose ester

[0154] Superfatting agents and consistency factors

[0155] Superfatting agents may be selected from substances such as, for example, lanolin and lecithin and polyethoxylated or acylated lanolin and lecithin derivatives, polyol fatty acid esters, monoglycerides and fatty acid alkanolamides, the latter also serving as foam stabilizers.

[0156] The main thickeners used are fatty alcohols or hydroxyaliphatic alcohols containing 12 to 22 and preferably 16 to 18 carbon atoms, as well as partial glycerides, fatty acids or hydroxyfatty acids. Preference is given to using combinations of these substances with alkyl oligoglucosides and / or N-methylglucamides of fatty acids of the same chain length and / or polyglycerol poly-12-hydroxystearate.

[0157] Thickeners and rheology additives

[0158] Suitable thickeners are polymeric thickeners, such as of hydrophilic silicas), polysaccharides, more particularly xanthan gum, guar gum, agar, alginates and tyloses, carboxymethylcellulose and hydroxyethyl and hydroxypropylcellulose, and relatively high molecular weight polyethylene glycol monoesters and diesters of fatty acids, polyacrylates (e.g. [Goodrich] or [Sigma]), polyacrylamide, polyvinyl alcohol and polyvinylpyrrolidone, surfactants such as, for example, ethoxylated fatty acid glycerides, esters of fatty acids with polyols such as pentaerythritol or trimethylolpropane, fatty alcohol ethoxylates with narrow homolog distribution and electrolytes such as sodium chloride and ammonium chloride.

[0159] polymer

[0160] Suitable polymers are to improve the spreadability of the composition on the skin or hair, or to improve the water and / or perspiration and / or abrasion resistance of the formulation and to improve the protection factor of the composition. Examples of such polymers are: VP / eicosene copolymers sold under the trade name Antaron V-220 by International Specialty Products, VP / hexadecene copolymers sold under the trade names Antaron V-216 and Antaron V-516 by International Specialty Products, Tricontanyl PVP sold under the trade name Antaron WP-660 by International Specialty Products, isohexadecane and ethylene / propylene / styrene copolymers and butylene / styrene copolymers sold under the trade names Versagel MC and MD by Penreco, hydrogenated polyisobutylene and ethylene / propylene / styrene copolymers and butylene / styrene copolymers sold under the trade name Versagel ME by Penreco, acrylates / octylacrylamide copolymers sold under the trade names Dermacryl 79, Dermacryl AQF and Dermacryl LT by AkzoNobel, Avalure UR sold by Noveon, Polyurethanes sold under the tradenames Avalure UR-405, -410, -425, -430 and -445525 by Noveon, polyurethanes 5 and butyl acetate and isopropyl alcohol sold under the tradenames Avalure UR-510 and -525 by Noveon, polyurethanes 1 and -6 sold under the tradename Luviset PUR by BASF, hydrogenated dimer dilinoleyl / dimethyl carbonate copolymer sold under the tradename Cosmedia DC by Cognis.

[0161] Of course, as those skilled in the art of cosmetic, dermatological and pharmacological compositions know, this is not an exhaustive list and other suitable polymers not listed here may be used. Examples of such polymers may be found in the latest edition of the CTFA International Cosmetic Ingredient Dictionary.

[0162] The amount of polymer used to obtain the desired effect in the formulation is from 0.10% to 5.0% by weight of the composition, especially from 0.25% to 3.0% by weight of the composition.

[0163] Pearlescent wax

[0164] Suitable pearlescent waxes are, for example, alkanediol esters, especially ethylene glycol distearate; fatty acid alkanolamides, especially coconut fatty acid diethanolamide; partial glycerides, especially stearic acid monoglyceride; esters of polybasic, optionally hydroxy-substituted carboxylic acids with fatty alcohols having 6 to 22 carbon atoms, especially long-chain esters of tartaric acid; fatty substances having a total of at least 24 carbon atoms, such as, for example, fatty alcohols, fatty ketones, fatty aldehydes, fatty ethers and fatty carbonates, especially laurone and distearyl ether; fatty acids such as stearic acid, hydroxystearic acid or behenic acid, ring-opening products of olefin oxides having 12 to 22 carbon atoms with fatty alcohols having 12 to 22 carbon atoms and / or polyols having 2 to 15 carbon atoms and 2 to 10 hydroxyl groups, and mixtures thereof.

[0165] silicone

[0166] Suitable silicones are selected from the group consisting of: theophylline methylsilanol mannuronate, acetylmethionylmethylsilanol elastin esters, acrylates / behenyl acrylate, acrylates / behenyl methacrylate / dimethicone methacrylate copolymer, acrylates / behenyl methacrylate / dimethicone methacrylate copolymer, acrylates / bishydroxypropyl dimethicone crosspolymer, acrylates / dimethicone copolymer, acrylates / dimethicone methacrylate / ethylhexyl acrylate copolymer, acrylates / dimethiconol acrylate copolymer, acrylates / ethylhexyl acrylate / dimethicone crosspolymer. Methylsilicone Methacrylate Copolymer, Acrylates / Octylacrylamide / Diphenyl Amodimethicone Copolymer, Acrylates / Polytrimethicone Methacrylate Copolymer, Acrylates / Propyl Polytrimethicone Methacrylate Copolymer, Acrylates / Stearyl Acrylate / Polydimethicone Methacrylate Copolymer, Acrylates / Tridecyl Acrylate / Triethoxysilylpropanol Methacrylate / Polydimethicone Methacrylate Copolymer, Acrylates / Trifluoropropyl Methacrylate / Polytrimethicone Methacrylate Copolymer, Aminobispropyl Dimethicone, Aminoethylaminopropyl Dimethicone, Aminopropyl Poly Dimethicone, Aminopropyl Phenyl Trimethicone, Aminopropyl Triethoxysilane, Dimethicone PEG-7 Ammonium Sulfate, Amodimethicone, Amodimethicone Hydroxystearate, Amodimethicone / Silsesquioxane Copolymer, Ascorbyl Carboxydecyl Trisiloxane, Ascorbyl Methylsilanol Pectate, Behenoxy Dimethicone, Behentrimonium Dimethicone PEG-8 Phthalate, Behenyl Dimethicone, Bis-AminoPEG / PPG-41 / 3 Aminoethyl PG-Propyl Dimethicone, Bis-Aminopropyl / Ethoxyaminopropyl Dimethicone, Bis-Butyl Paraben, Diaminotriazine Aminopropyl Trisiloxane, Bis-Butyl Dimethicone Oxyalkyl Polyglyceryl-3, Bis-Butoxy Amodimethicone / PEG-60 Copolymer, Bis (C13-15 Alkoxy) Hydroxybutamido Amodimethicone, Bis (C13-15 Alkoxy) PG-Amodimethicone, Bis-(C1-8 Alkyl Lauroyl Lysine Decyl Carboxamide) Dimethicone, Bis-Cetyl Cetyl Dimethicone, Bis-Cetyl / PEG-8 Cetyl PEG-8 Dimethicone, Bis-Diphenylethyl Disiloxane, Bis-Ethylethyl Methicone, Bis-Glucoamidoethyl-Aminopropyl Disiloxane, Bis-Hydrogen Dimethicone, Bis-Hydroxyethoxypropyl Disiloxane Bis-Hydroxylauryl, Dimethicone / IPDI Copolymer,Bis-Hydroxy / Methoxyamodimethicone, Bis-Hydroxypropyl Dimethicone Behenate, Bis-Hydroxypropyl Dimethicone / SMDI Copolymer, Bis-Isobutyl PEG-14 / Dimethicone Copolymer, Bis-Isobutyl PEG-15 / Dimethicone Copolymer, Bis-Isobutyl PEG / PPG-20 / 35 / Dimethicone Copolymer, Bis-Isobutyl PEG / PPG-10 / 7 / Dimethicone Copolymer, Bis-Isobutyl PEG-24 / PPG-7 / Dimethicone Copolymer, Bis-PEG-1 Dimethicone, Bis-PEG-4 Dimethicone, Bis-PEG-8 Dimethicone, Bis-PEG-12 Dimethicone Methicone, Bis-PEG-20 Dimethicone, Bis-PEG-12 Dimethicone Beeswax, Bis-PEG-12 Dimethicone Candelilla Cetearate, Bis-PEG-15 Dimethicone / IPDI Copolymer, Bis-PEG-15 Methyl Ether Dimethicone, Bis-PEG-18 Methyl Ether Dimethicone, Bis-PEG / PPG-14 / 14 Dimethicone, Bis-PEG / PPG-15 / 5 Dimethicone, Bis-PEG / PPG-18 / 6 Dimethicone, Bis-PEG / PPG-20 / 20 Dimethicone, Bis-PEG / PPG-16 / 16 PEG / PPG-16 / 16 Dimethicone Dimethicone, Bis-PEG / PPG-20 / 5PEG / PPG-20 / 5 Dimethicone, Bis-phenylenedimethicone, Bis-phenylpropyldimethicone, Bis-polyethylenedimethicone, Bis-polyglyceryl-3 hydroxyphenylpropyldimethicone, Bis-(polyglyceryl-7 hydroxyphenylpropyl)dimethicone, Bis-PPG-15 dimethicone / IPDI copolymer, Bis-(PPG-7 undecenylether-21) dimethicone, Bis-stearyl dimethicone, Bis-trimethoxysilylethyltetramethyldisiloxyethyl dimethicone, Bis-vinyl dimethicone, Bis-vinyl dimethicone / dimethicone copolymer, Borago officinalis seed oil PEG- 7 Polydimethylsiloxane Esters, Butyl Acrylate / C6-14 Perfluoroalkyl Alcohol Acrylate / Mercaptopropyl Dimethicone Copolymer, Butyl Acrylate / Hydroxypropyl Dimethicone Acrylate Copolymer, Butyl Dimethicone Acrylate / Cyclohexyl Methacrylate / Ethylhexyl Acrylate Copolymer, Butyl Dimethicone Methacrylate / Methyl Methacrylate Crosspolymer, T-Butyldimethylsilane Grape Seed Extract, Butyl Dimethicone Ethylene / Propylene / Ethylene Norbornene Copolymer, C6-8 Alkyl C3-6 Alkyl Glucoside Dimethicone, C20-24 Alkyl Dimethicone, C24-28 Alkyl Dimethicone, C26-28 Alkyl Dimethicone,C30-45 Alkyl Dimethicone, C30-60 Alkyl Dimethicone, C32 Alkyl Dimethicone, C30-45 Alkyl Dimethicone / Polycyclohexene Oxide Crosspolymer, C26-28 Alkyl Dimethyl Silane Polypropyl Silsesquioxane, C30-45 Alkyl Dimethyl Silane Polypropyl Silsesquioxane, C20-24 Alkyl Methicone, C24-28 Alkyl Methicone, C26-28 Alkyl Methicone, C30-45 Alkyl Methicone, C20-28 Alkyl Methicone Fluordecyl Ethoxydimethicone, C26-54 Alkyl Tetradecane Dimethicone, Caprylyl Dimethicone, Caprylyl Dimethicone Ethoxyglucoside, Caprylyl Methicone, Caprylyl Trimethicone, Carboxydecyl Trisiloxane, Castor Oil Bis-Hydroxypropyl Dimethicone Esters, Wax Dimethicone, Cetearyl Dimethicone Crosspolymer, Cetearyl Dimethicone / Vinyl Dimethicone Crosspolymer, Cetearyl Methicone, Cetrimonium Carboxydecyl PEG-8 Polydimethylsiloxysilicate Dimethicone, Cetrimonium Dimethicone PEG-7 Phthalate, Cetyl Behenyl Dimethicone, Cetyl Dimethicone, Cetyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Cetyl Dimethicone, Cetyl PEG-8 Dimethicone, Cetyl PEG / PPG-15 / 15 Butyl Ether Dimethicone, Cetyl PEG / PPG-7 / 3 Dimethicone, Cetyl PEG / PPG-10 / 1 Dimethicone Methicone, Cetyl Triethylammonium Dimethicone PEG-8 Phthalate, Cetyl Triethylammonium Dimethicone PEG-8 Succinate, Acetyl Tyrosinate Copper Methylsilanol, PCA Methylsilanol Copper, C4-14 Perfluoroalkyl Ethoxydimethylsiloxane, Cycloethoxydimethylsiloxane, Cycloheptasiloxane, Cyclohexasiloxane, Cyclodimethicone, Cyclopentasiloxane, Cyclophenyl Methicone, Cyclotetramethicone, Cyclovinyl Polymethoxysilane, Cysteine Bis-PG-propyl Silanetriol, DEA PG-Propyl PEG / PPG-18 / 21 Dimethicone, Diisostearyl Trimethylolpropane Siloxysilicate, Dilauroyl Trimethylolpropane Siloxysilicate, Dilinoleamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Dimethicone, Dimethicone Crosspolymer, Dimethicone Crosspolymer-3, Dimethicone / Divinyl Dimethicone / Silsesquioxane Crosspolymer, Dimethicone Ethoxyglucoside, Dimethicone Hydroxypropyltrimonium Chloride, Dimethicone / Mercaptopropyl Methicone Copolymer, Dimethicone PEG-15 Acetate,Dimethicone PEG-8 Adipate, Dimethicone PEG-7 Avocado Oil, Dimethicone PEG-8 Avocado Oil, Dimethicone PEG-8 Beeswax, Dimethicone PEG-8 Benzoate, Dimethicone PEG-8 Borage Oil, Dimethicone PEG-7 Cocoate, Dimethicone / PEG-10 Crosspolymer, Dimethicone PEG-10 / 15 Crosspolymer, Dimethicone PEG-15 Crosspolymer, Dimethicone PEG-7 Isostearate, Dimethicone PEG-8 Isostearate, Dimethicone PEG-7 Lactate, Dimethicone PEG- 8 Lanolin Acid, Dimethicone PEG-8 Laurate, Dimethicone PEG-8 Limnanthes Alba Seed Oil Acid, Dimethicone PEG-7 Octyldodecanol Citrate, Dimethicone PEG-7 Olivate, Dimethicone PEG-8 Olivate, Dimethicone PEG-7 Phosphate, Dimethicone PEG-8 Phosphate, Dimethicone PEG-10 Phosphate, Dimethicone PEG-7 Phthalate, Dimethicone PEG-8 Phthalate, Dimethicone PEG-8 Polyacrylate, Dimethicone PEG / PPG-20 / 23 Benzoate, Dimethicone PEG / PPG- 7 / 4 Phosphate, Dimethicone PEG / PPG-12 / 4 Phosphate, Dimethicone PEG-7 Succinate, Dimethicone PEG-8 Succinate, Dimethicone PEG-7 Sulfate, Dimethicone PEG-7 Undecanoate, Dimethicone PG-Diethylmethylmonium Chloride, Dimethicone / Phenyl Vinyl Dimethicone Crosspolymer, Dimethicone / Polyglyceryl-3 Crosspolymer, Dimethicone / PPG-20 Crosspolymer, Dimethicone Propyl Ethylenediamine Behenate, Dimethicone Propyl PG-Betaine, Dimethicone / Silsesquioxane Copolymer, Dimethicone Silylate, Dimethicone Silicone / Vinyl Dimethicone Crosspolymer, Dimethicone / Vinyl Trimethylsiloxysilicate Crosspolymer, Dimethicone, Dimethicone Arginine, Dimethicone Beeswax, Dimethicone Behenate, Dimethicone Boragonate, Dimethicone Candelilla Cetearate, Dimethicone Carnauba Palmitate, Dimethicone Cysteine, Dimethicone Drupalate, Dimethicone Fluoroalcohol Dimer Dilinoleate Polyester, Dimethicone Hydroxystearate, Dimethicone Indian Hematite Resinate, Dimethicone / IPDI Copolymer, Dimethicone Isostearate,Dimethicone Candlenut Butter, Dimethicone Lactate, Dimethicone Limnanthes Alba Seed Oil, Dimethicone Methionine, Dimethicone / Methicone / Silicate Crosspolymer, Dimethicone Chenopodium Elatior, Dimethicone Panthenol, Dimethicone Leuconostoc Stearate, Dimethicone / Silica Crosspolymer, Dimethicone / Silsesquioxane Copolymer, Dimethicone Stearate, Dimethicone / Stearyl Methicone / Phenyl Trimethicone Copolymer, Dimethoxysilyl Ethylene Diaminopropyl Dimethicone, Dimethylaminopropionamido PCA Siloxane, Dimethyloxybenzodioxane, Dimethylsilanol Hyaluronate, Dioleyl Tocopheryl Methylsilanol, Diphenyl Amodimethicone, Diphenyl Dimethicone, Diphenyl Dimethicone Crosspolymer, Diphenyl Dimethicone / Vinyl Diphenyl Dimethicone / Silsesquioxane Crosspolymer, Diphenylethyl Benzyloxydimethyldisiloxane, Diphenyl Isopropyl Dimethicone, Diphenylsiloxy Phenyl / Propyl Trimethicone, Diphenylsiloxy Phenyl Trimethicone, Dimethicone, Amodimethicone / Disodium Disuccinimide, PEG-12 Polydimethylsiloxane Sulfosuccinate Disodium -8 Disodium Lauryl Dimethicone Sulfosuccinate, Divinyl Dimethicone / Dimethicone Copolymer, Divinyl Dimethicone / Dimethicone Crosspolymer, Drometrizole Trisiloxane, Ethylhexyl Acrylate / VP / Dimethicone Methacrylate Copolymer, Ethyl Methicone, Ethyl Trisiloxane, Fluorinated C2-8 Alkyl Dimethicone, Glucamidopropyl Aminopropyl Dimethicone, 4-(2-β-pyranosylmethylsiloxy) Propoxy-2-Hydroxybenzophenone, Glyceryl Undecyl Dimethicone, Glycidoxy Dimethicone, Polyhexyl Methicone, Hexyl Dimethicone, Hexyl Methicone, Hexyl Trimethoxysilane, Hydrogen Dimethicone, Hydrogen Dimethicone / Capryl Silsesquioxane Copolymer, Hydrolyzed Collagen PG-Propyl Dimethicone, Hydrolyzed Collagen PG-Propyl Methylsilanediol, Hydrolyzed Collagen PG-Propyl Silanetriol, Hydrolyzed Keratin PG-Propyl Methylsilanediol, Hydrolyzed Sesame Protein PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol, Hydrolyzed Silk PG-Propyl Methylsilanediol Crosspolymer, Hydrolyzed Soy Protein / Dimethicone PEG-7 Acetate, Hydrolyzed Soy Protein PG-Propyl Methylsilanediol, Hydrolyzed Vegetable Protein PG-Propyl Silanetriol, Hydrolyzed Wheat (Triticum Vulgaris) Protein / Cystine Bis-PG-Propyl Silanetriol Copolymer, Hydrolyzed Wheat Protein / Dimethicone PEG-7 Acetate,Hydrolyzed Wheat Protein / Dimethicone PEG-7 Phosphate Copolymer, Hydrolyzed Wheat Protein PG-Propyl Methylsilanediol, Hydrolyzed Wheat Protein PG-Propyl Silanetriol, Hydroxyethyl Acetoxymethylmonium PG-Dimethicone, Hydroxypropyl Dimethicone, Hydroxypropyl Dimethicone Behenate, Hydroxypropyl Dimethicone Isostearate, Hydroxypropyl Dimethicone Stearate, Isobutyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isobutyl Methacrylate / Trifluoroethyl Methacrylate / Bis-Hydroxypropyl Dimethicone Acrylate Copolymer, Isoamyl Trimethoxycinnamate Trisiloxane, Isopolyglyceryl-3 Dimethicone, Isopolyglyceryl-3 Dimethicone Alcohol, Isopropyl Titanium Triisostearate / Triethoxysilylethyl, Polydimethylsiloxyethyl Dimethicone Crosspolymer, Isostearyl Carboxydecyl PEG-8 Dimethicone, Lactyl Methicone Elastin Esters, Lauryl Dimethicone, Lauryl Dimethicone PEG-15 Crosspolymer, Lauryl Dimethicone PEG-10 Phosphate, Lauryl Dimethicone / Polyglyceryl-3 Crosspolymer, Lauryl Methicone, Lauryl PEG-8 Dimethicone, Lauryl PEG-10 Methyl Ether Dimethicone, Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone, Lauryl PEG / PPG-18 / 18 Methicone, Lauryl Benzyl Alcohol Propyl Methicone, Lauryl Phenylpropyl Methicone, Lauryl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Lauryl Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone, Lauryl Trimethicone, Linoleamidopropyl PG-Dimonium Chloride Phosphate Dimethicone, Methacryloylpropyl Trimethoxysilane, Methicone, Methoxyamodimethicone / Silsesquioxane Copolymer, Methoxycinnamamidopropyl Polysilsesquioxane, Methoxycinnamamidopropyl Silsesquioxane Silicate, Methoxy PEG-13 Ethyl Polysilsesquioxane, Methoxy PEG / PPG-7 / 3 Aminopropyl Dimethicone, Methoxy PEG / PPG- 25 / 4 Dimethicone, Methoxy PEG-10 Propyl Trimethoxy Silane, Methyl Eugenol PEG-8 Dimethicone, Methyl Polysilicone Emulsion, Methylsilanol Acetyl Methionine Esters, Methylsilanol Acetyl Tyrosine Esters, Methylsilanol Ascorbic Acid, Methylsilanol Carboxymethyl Theophylline, Methylsilanol Carboxymethyl Theophylline Alginate, Methylsilanol Elastin Esters, Methylsilanol Glycyrrhizate, Methylsilanol Hydroxyproline Esters, Methylsilanol Hydroxyproline Esters Aspartate, Methylsilanol Mannouronate, Methylsilanol PCA Esters, Methylsilanol PEG-7 Glyceryl Cocoate, Methylsilanol / Silicate Crosspolymer, Methylsilanol Spirulina Protein Esters, Methylsilanol Tri-PEG-8 Glyceryl Cocoate,Methyl Trimethicone, Methyl Trimethoxysilane, Myristamidopropyl Dimethylamine Dimethicone PEG-7 Phosphate, Myristyl Methicone, Myristyl Trisiloxane, Nylon-611 / Dimethicone Copolymer, PCA Dimethicone, PEG-7 Amodimethicone, PEG-8 Amodimethicone, PEG-8 Cetyl Dimethicone, PEG-3 Dimethicone, PEG-6 Dimethicone, PEG-7 Dimethicone, PEG-8 Dimethicone, PEG-9 Dimethicone, PEG-10 Dimethicone, PEG-12 Dimethicone, PEG-14 Dimethicone Dimethicone, PEG-10 Dimethicone Crosspolymer, PEG-12 Dimethicone Crosspolymer, PEG-8 Dimethicone Dimer Dilinoleate, PEG-8 Dimer Dilinoleate / Dimer Dilinoleic Acid Copolymer, PEG-10 Dimethicone / Vinyl Dimethicone Crosspolymer, PEG-8 Distearyl Methylmonium Chloride PG-Dimethicone, PEG-10 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-15 / Lauryl Dimethicone Crosspolymer, PEG-8 Methicone, PEG-6 Polymethylsiloxysilane PEG-6 Methyl Ether Dimethicone, PEG-7 Methyl Ether Dimethicone, PEG-8 Methyl Ether Dimethicone, PEG-9 Methyl Ether Dimethicone, PEG-10 Methyl Ether Dimethicone, PEG-11 Methyl Ether Dimethicone, PEG-32 Methyl Ether Dimethicone, PEG-8PEG-8 Methyl Ether Triethoxysilane, PEG-10 Nonafluorohexyl Dimethicone Copolymer, PEG-4PEG-12 Dimethicone, PEG-8PG Cocoyl Glucoside Dimethicone, PEG-9 Polydimethylsiloxyethyl Dimethicone, PEG / PPG-20 / 22 Butyl Ether Dimethicone, PEG / P PG-22 / 22 Butyl Ether Dimethicone, PEG / PPG-23 / 23 Butyl Ether Dimethicone, PEG / PPG-24 / 18 Butyl Ether Dimethicone, PEG / PPG-27 / 9 Butyl Ether Dimethicone, PEG / PPG-3 / 10 Dimethicone, PEG / PPG-4 / 12 Dimethicone, PEG / PPG-6 / 4 Dimethicone, PEG / PPG-6 / 11 Dimethicone, PEG / PPG-8 / 14 Dimethicone, PEG / PPG-8 / 26 Dimethicone, PEG / PPG-10 / 2 Dimethicone, PEG / PPG-12 / 16 Dimethicone,PEG / PPG-12 / 18 Dimethicone, PEG / PPG-14 / 4 Dimethicone, PEG / PPG-15 / 5 Dimethicone, PEG / PPG-15 / 15 Dimethicone, PEG / PPG-16 / 2 Dimethicone, PEG / PPG-16 / 8 Dimethicone, PEG / PPG-17 / 18 Dimethicone, PEG / PPG-18 / 6 Dimethicone, PEG / PPG-18 / 12 Dimethicone, PEG / PPG-18 / 18 Dimethicone, PEG / PPG-19 / 19 Dimethicone, PEG / PPG-20 / 6 Dimethicone, PE PEG / PPG-20 / 15 Dimethicone, PEG / PPG-20 / 20 Dimethicone, PEG / PPG-20 / 23 Dimethicone, PEG / PPG-20 / 29 Dimethicone, PEG / PPG-22 / 23 Dimethicone, PEG / PPG-22 / 24 Dimethicone, PEG / PPG-23 / 6 Dimethicone, PEG / PPG-25 / 25 Dimethicone, PEG / PPG-27 / 27 Dimethicone, PEG / PPG-30 / 10 Dimethicone, PEG / PPG-25 / 25 Dimethicone / Acrylates Copolymer, PEG / PPG-2 0 / 22 Methyl Ether Dimethicone, PEG / PPG-24 / 24 Methyl Ether Glycidoxy Dimethicone, PEG / PPG-10 / 3 Oleyl Ether Dimethicone, PEG / PPG-5 / 3 Trisiloxane, PEG-4 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trifluoropropyl Dimethicone Copolymer, PEG-10 Trifluoropropyl Dimethicone Copolymer, PEG-8 Trisiloxane, Perfluorooctyl Triethoxysilylethyl Methicone, Perfluorononyl Dimethicone, Perfluorononyl Dimethicone / Methicone / Amodimethicone Crosspolymer, Perfluorononyl Ethyl Carboxydecyl Behenyl Dimethicone, Perfluorononyl Ethyl Carboxydecyl Hexadecyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl / Behenyl Dimethicone, Perfluorononylethyl Carboxydecyl Lauryl Dimethicone, Perfluorononylethyl Carboxydecyl PEG-8 Dimethicone, Perfluorononylethyl Carboxydecyl PEG-10 Dimethicone, Perfluorononylethyl Dimethicone / Methicone Copolymer, Perfluorononylethyl PEG-8 Dimethicone, Perfluorononylethyl Stearyl Dimethicone, Perfluorooctylethyl / Diphenyl Dimethicone Copolymer, Perfluorooctylethyl Triethoxysilane, Perfluorooctylethanol Trimethoxysilane, Perfluorooctylethyl Trisiloxane, Perfluorooctyl Triethoxysilane, PG-Amodimethicone,Phenyl Dimethicone, Phenyl Ethyl Disiloxane, Diphenyl Dimethicone, Diphenyl Isopropyl Dimethicone, Phenyl Methicone, Phenyl Methiconol, Phenylpropyl Dimethylsiloxysilicate, Phenylpropyl Ethyl Methicone, Phenyl Propyl Trimethicone, Phenyl Propyl Trimethicone / Diphenyl Methicone, Phenyl Trimethicone, Platinum Divinyl Disiloxane, Polyacrylate-6, Polydiethylsiloxane, Polydimethylsiloxyethyl Dimethicone / Bis-Vinyl Dimethicone Crosspolymer, Polydimethylsiloxyethyl Dimethicone / Methicone Copolymer, Dimethicone PEG / PPG-24 / 19 Butyl Ether Silsesquioxane, Polydimethylsiloxy Methylsiloxy PPG-13 Butyl Ether Silsesquioxane, Polyglyceryl-3 Disiloxane Dimethicone, Polyglyceryl-3 / Lauryl Polydimethylsiloxyethyl Dimethicone Crosspolymer, Polyglyceryl-3 Polydimethylsilyl Hydroxyethyl Dimethicone, Poly(Ethylene Glycol Adipate) / Bis-Hydroxyethoxypropyl Dimethicone Copolymer, Polymethyl Silsesquioxane, Polymethyl Silsesquioxane / Trimethylsiloxysilicate, Polyphenyl Silsesquioxane, Polypropyl Silsesquioxane, Polysilicone-1, Polysilicone-2, Polysilicone-3, Polysilicone-4, Polysilicone-5, Polysilicone-6, Polysilicone-7, Polysilicone-8, Polysilicone-9, Polysilicone-10, Polysilicone-11, Polysilicone- 12, Polysilicone-13, Polysilicone-14, Polysilicone-15, Polysilicone-16, Polysilicone-17, Polysilicone-18, Polysilicone-19, Polysilicone-20, Polysilicone-21, Polysilicone-18 Cetyl Phosphate, Polysilicone-1 Crosspolymer, Polysilicone-18 Stearate Polyurethane-10, Methylsilicone PEG-7 Panthenol Potassium Phosphate, Dimethicone PEG-7 Potassium Phosphate, PPG-12 Butyl Ether Dimethicone, PPG-2 Dimethicone, PPG-12 Dimethicone, PPG-27 Dimethicone, PPG-4 Oleth-10 Dimethicone, Propoxytetramethylpiperidinyl Dimethicone , Propyl trimethicone, Quaternium-80, Retinoxytrimethylsilane, Silanediol Salicylate, Silanetriol, Silanetriol Arginine Ester, Silanetriol Glutamate, Silanetriol Lysine Ester, Silanetriol Melanin Ester, Silanetriol Trehalose Ether, Silica, Polydimethylsiloxane Silylate, Silica Dimethyl Silylate, Silica Silylate, Silicon Carbide, Polysilicone Quaternium-1, Polysilicone Quaternium-2, Polysilicone Quaternium-2 Panthenol Succinate, Polysilicone Quaternium-3, Polysilicone Quaternium-4, Polysilicone Quaternium-5, Polysilicone Quaternium-6, Polysilicone Quaternium-7, Polysilicone Quaternium-8, Polysilicone Quaternium-9, Polysilicone Quaternium-10,Polysilicone Quaternium-11, Polysilicone Quaternium-12, Polysilicone Quaternium-15, Polysilicone Quaternium-16, Polysilicone Quaternium-16 / Glycidoxydimethicone Crosspolymer, Polysilicone Quaternium-17, Polysilicone Quaternium-18, Polysilicone Quaternium-19, Polysilicone Quaternium-20, Polysilicone Quaternium-21, Polysilicone Quaternium-22, Polysilicone Quaternium-24, Polysilicone Quaternium-25, Siloxanetriol Alginate, Siloxanetriol Phytate, Silicone Resin, Sodium Carboxydecyl PEG-8 Dimethicone, Sodium Dimethicone PEG-7 Acetyl Methyl Taurate, Sodium Dimethicone Hyaluronate, Sodium Methylsilanol Lactate, Mannaldehyde Sodium PCA Methicone, Sodium PCA Methicone, Sodium PG-Propyl Dimethicone Thiosulfate Copolymer, Sodium PG-Propyl Thiosulfate Dimethicone, Sodium Propoxypropyl Thiosulfate Silica, Sorbitan Silanediol, Triethoxysilylpropyldimonium Chloride Soybean, Stearalkonium Chloride Dimethicone PEG-8 Phthalate, Stearamidopropyl Dimethicone, Stearyldimonium Hydroxypropyl Panthenol PEG-7 Dimethicone Phosphate Chloride, Stearyldimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearyldimonium Hydroxypropyl PEG-7 Dimethicone Phosphate Chloride, Stearyldimethicone, Stearyloxydimethicone / Dimethicone Copolymer, Stearyltrimethylsilane, Stearylaminopropyl Methicone Alkane, Stearyl Dimethicone, Stearyl Alcohol / Lauryl Methacrylate Crosspolymer, Stearyl Methicone, Stearyl Triethoxysilane, Stearyl Trimethicone, Styrene / Acrylates / Dimethicone Acrylate Crosspolymer, Styrene / Acrylates / Dimethicone Copolymer, Dimethicone PEG-7 Phosphate TEA, (Tetrabutoxy)propyl Trisiloxane, Tetramethyl Hexaphenyl Tetrasiloxane, Tetramethyl Tetraphenyl Trisiloxane, Tocopheryl Oxypropyl Trisiloxane, Trideceth-9PG-Amodimethicone, Triethoxycaprylylsilane, Dimethicone / Methicone Copolymer, Triethoxysilylethyl Polydimethylsiloxyethyl Dimethicone Siloxane, Triethoxysilylethyl Polydimethicone, Ethylhexyl Dimethicone, Triethoxysilylpropyl Carbamoylethoxypropyl Butyl Dimethicone, Trifluoromethyl C1-4 Alkyl Dimethicone, Trifluoropropyl Cyclopentasiloxane, Trifluoropropyl Cyclotetrasiloxane, Trifluoropropyl Dimethicone, Trifluoropropyl Dimethicone / PEG-10 Crosspolymer, Trifluoropropyl Dimethicone / Trifluoropropyl Divinyl Dimethicone Crosspolymer, Trifluoropropyl Dimethicone / Vinyl Trifluoropropyl Dimethicone / Silsesquioxane Crosspolymer, Trifluoropropyl Dimethiconol, Trifluoropropyl Dimethyl / Trimethylsiloxysilicate, Trifluoropropyl Methicone,Trimethoxycaprylylsilane, trimethoxysilyl dimethicone, trimethyl pentaphenyl trisiloxane, trimethylsiloxyamodimethicone, trimethylsiloxyphenyl dimethicone, trimethylsiloxysilicate, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilicate / dimethicone crosspolymer, trimethylsiloxysilylcarbamoyl pullulan, trimethylsilyl hydrolyzed conchiolin protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed silk PG-propyl methylsilanediol crosspolymer, trimethylsilyl hydrolyzed wheat protein PG-propyl methylsilanediol crosspolymer, trimethylsilyl pullulan, Trimethylsilanol Trisiloxyglycolate, Trimethylsilanol Trisiloxylactate, Trimethylsilanol Trisiloxysalicylates, Polytriphenyl Trimethicone, Trisiloxane, Tris(tributoxysiloxy)methylsilane, Undecylene Dimethicone, Vinyl Dimethicone, Vinyl Dimethicone / Lauryl Dimethicone Crosspolymer, Vinyl Dimethicone / Methicone Silsesquioxane Crosspolymer, Vinyl Dimethicone / Trimethylsiloxysilicate / Stearyl Dimethicone Crosspolymer, VP / Dimethylaminoethyl Methacrylate / Polyethylene Glycol Polyurethane, Zinc Carboxydecyl Trisiloxane and Dimethicone PEG-8 Zinc Succinate, and mixtures thereof.

[0167] The silicones contained in the mixture according to the invention are more preferably dimethicone, cyclomethicone, phenyl trimethicone, cyclohexasiloxane and cyclopentasiloxane. A detailed description of suitable volatile silicone compounds is given in Todd et al. in Cosm. Toil. 91, 27 (1976).

[0168] Waxes and stabilizers

[0169] In addition to the natural oils used, the preparations may also contain waxes, in particular natural waxes such as, for example, candelilla wax, carnauba wax, Japan wax, espartograss wax, cork wax, guaruma wax, rice oil wax, sugar cane wax, ouricury wax, montan wax, beeswax, shellac wax, spermaceti, wool wax, uropygial fat, ozokerite, paraffin wax, petrolatum, petrolatum and microwaxes; chemically modified waxes (hard waxes) such as, for example, montan ester waxes, sasol waxes, hydrogenated jojoba waxes and synthetic waxes such as, for example, polyalkylene waxes and polyethylene glycol waxes.

[0170] Stabilizers that can be used are metal salts of fatty acids, such as, for example, magnesium, aluminum and / or zinc stearate or ricinoleate.

[0171] 1,2-Alkanediol

[0172] In a particularly preferred embodiment, the composition may contain 1,2-alkanediol having up to 12 carbon atoms, such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol, a mixture of 1,2-hexanediol and 1,2-octanediol, a mixture of 1,2-hexanediol and 1,2-decanediol, a mixture of 1,2-octanediol and 1,2-decanediol, 1,2-hexanediol, 1,2-octanediol and 1,2-decanediol, preferably in an amount of 0.1 to about 10, preferably about 1 to about 8, wt. %.

[0173] fatty alcohols

[0174] Composition can also comprise fatty alcohol with 6 to 30 C atoms.The fatty alcohol here can be saturated or unsaturated and straight or branched.In addition, these fatty alcohols can be a part of oil phase (III) in some cases, if they meet the definition given there.Operable alcohol is for example decyl alcohol, decenol, octanol, octenol, dodecanol, dodecenol, octadienol, decadienol, dodecadienol, oleyl alcohol, ricinoleyl alcohol, sinapyl alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, octanol, linolenyl alcohol, linolenic acid and behenyl alcohol, and its Guerbet alcohol, for example, 2-octyl-1-dodecanol, in fact can be expanded to other alcohols possessing relevant structural chemistry by upper table as needed.Fatty alcohol is preferably derived from natural fatty acid, usually prepared by the corresponding ester of fatty acid through reduction. It is further possible to use fatty alcohol fractions formed by the reduction of natural fats and fatty oils, such as tallow, peanut oil, rapeseed oil, cottonseed oil, soybean oil, sunflower oil, palm kernel oil, linseed oil, corn oil, castor oil, rapeseed oil, sesame oil, cocoa butter and coconut fat.

[0175] Main sunscreens

[0176] Essential sunscreens in the context of the present invention are, for example, organic substances (light filters) which are liquid or crystalline at room temperature and are able to absorb UV radiation and release the absorbed energy again in the form of long-wave radiation, for example heat.

[0177] The preparations according to the invention advantageously contain at least one UV-A filter and / or at least one UV-B filter and / or a broadband filter and / or at least one inorganic dye. The preparations according to the invention preferably contain at least one UV-B filter or a broadband filter, more particularly at least one UV-A filter and at least one UV-B filter.

[0178] Preferred cosmetic compositions, preferably topical preparations according to the present invention contain one, two, three or more sunscreen agents selected from the group consisting of 4-aminobenzoic acid and derivatives, salicylic acid derivatives, benzophenone derivatives, dibenzoylmethane derivatives, diphenyl acrylate, 3-imidazolyl-4-yl acrylic acid and its esters, benzofuran derivatives, benzylmalonate derivatives, polymeric UV absorbers containing one or more organosilicon radicals, cinnamic acid derivatives, camphor derivatives, triphenylamino-s-triazine derivatives, 2-hydroxyphenylbenzotriazole derivatives, phenylbenzimidazolesulfonic acid derivatives and salts thereof, menthyl anthranilate, benzotriazole derivatives and indole derivatives.

[0179] Furthermore, it is advantageous to combine the compounds of formula (I) with active ingredients that penetrate the skin and protect skin cells from the inside against sun-induced damage and reduce the levels of matrix metalloproteinases in the skin. Preferred ingredients, so-called aryl hydrocarbon receptor antagonists, are described in WO 2007 / 128723, which is incorporated herein by reference. 2-Benzylidene-5,6-dimethoxy-3,3-dimethylindan-1-one is preferred.

[0180] The UV filter substances cited below which can be used in the present invention are preferred, but are not limited to these substances.

[0181] Preferably used UV filters are selected from the group consisting of:

[0182] · Para-aminobenzoic acid

[0183] Ethoxylated (25 mol) ethyl p-aminobenzoate (INCI name: PEG-25PABA)

[0184] 2-Ethylhexyl p-dimethylaminobenzoate

[0185] ·N-propoxylated (2 mol) ethyl p-aminobenzoate

[0186] · Glyceryl p-aminobenzoate

[0187] Homomenthyl Salicylate (Homosalate) (Neo HMS

[0188] ·2-Ethylhexyl Salicylate (Neo OS)

[0189] ●Triethanolamine salicylate

[0190] 4-Isopropylbenzyl salicylate

[0191] Menthyl anthranilate (Neo MA)

[0192] ·Ethyl diisopropylcinnamate

[0193] ●2-Ethylhexyl methoxycinnamate (Neo AV)

[0194] Methyl diisopropylcinnamate

[0195] Isoamyl p-methoxycinnamate (Neo E 1000)

[0196] ·Diethanolamine p-methoxycinnamate

[0197] Isopropyl p-methoxycinnamate

[0198] 2-phenylbenzimidazole sulfonic acid and salts (Neo Hydro)

[0199] ·3-(4'-Trimethylammonium)-benzylidene-2-borneol methyl sulfate

[0200] β-Imidazole-4(5)-propenoic acid (urocanic acid)

[0201] ●3-(4'-sulfo)benzylidene-2-camphenyl-one and salts

[0202] ·3-(4'-Methylbenzylidene)-D,L-camphor (Neo MBC)

[0203] ·3-Benzylidene-D,L-camphor

[0204] N-[(2 and 4)-[2-(Oxobornylene-3-yl)methyl]benzyl]-acrylamide polymer

[0205] ●4,4'-[(6-[4-(1,1-dimethyl)-aminocarbonyl)phenylamino]-1,3,5-triazine-2,4-diyl)diimino]-bis-(benzoic acid-2-ethylhexyl ester) HEB)

[0206] ●Benzalkonium Malonate-Polysilicone( SLX)

[0207] ●Glyceryl ethylhexanoate dimethoxycinnamate

[0208] ●Dipropylene glycol salicylate

[0209] ●4,4',4"-(1,3,5-triazine-2,4,6-triyltriimino)-tris-benzoic acid tris(2-ethylhexyl ester) (=2,4,6-trianilino-(p-carbonyl-2'-ethylhexyl-1'-oxy)-1,3,5-triazine) T150)

[0210] In the preparations according to the invention, preferably the broadband filter substances combined with one or more compounds of formula (I) are selected from the group consisting of

[0211] 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate (Neo 303)

[0212] ●2-cyano-3,3'-diphenylacrylate ethyl ester

[0213] 2-Hydroxy-4-methoxybenzophenone (Neo BB)

[0214] 2-Hydroxy-4-methoxybenzophenone-5-sulfonic acid

[0215] ·Dihydroxy-4-methoxybenzophenone

[0216] 2,4-Dihydroxybenzophenone

[0217] Tetrahydroxybenzophenone

[0218] 2,2'-Dihydroxy-4,4'-dimethoxybenzophenone

[0219] ·2-Hydroxy-4-octyloxybenzophenone

[0220] ·2-Hydroxy-4-methoxy-4'-methylbenzophenone

[0221] Sodium Hydroxymethoxybenzophenone Sulfonate

[0222] ·2,2'-Dihydroxy-4,4'-dimethoxy-5,5'-disulfo-benzophenone disodium

[0223] Phenol, 2-(2H-benzotriazol-2-yl)-4-methyl-6-(2-methyl-3(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)-dimethylsilyloxy)-propyl)( XL)

[0224] ●2,2′-methylene-bis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol)( M)

[0225] ●2,4-bis-[4-(2-ethylhexyloxy)-2-hydroxyphenyl]-1,3,5-triazine

[0226] ·2,4-bis-[{(4-(2-ethyl-hexyloxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine ( S)·2,4-bis-[{(4-(3-sulfonic acid)-2-hydroxypropoxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine sodium salt●2,4-bis-[{(3-(2-propoxy)-2-hydroxypropoxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine●2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}phenyl]-6-[4-(2-methoxyethylcarbonyl)phenylamino]-1,3,5-triazine·2,4-bis-[{4-(3-(2-propoxy)-2-hydroxypropoxy)-2-hydroxy}phenyl]-6-[4-(2-ethylcarbonyl)phenylamino]-1,3,5-triazine

[0227] ·2,4-bis-[{4-(2-ethylhexyloxy)-2-hydroxy}phenyl]-6-(1-methylpyrrol-2-yl)-1,3,5-triazine ·2,4-bis-[{4-tris-(trimethylsilyloxysilylpropoxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine

[0228] 2,4-bis-[{4-(2″-methylpropoxyenyl)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine 2,4-bis-[{4-(1′,1′,1′,3′,5′,5′,5′-heptamethylsilyloxy-2″-methylpropoxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine

[0229] The compositions may contain other typical cleaning and detergent composition ingredients such as UV-A filters, which in the formulations according to the invention are preferably combined with one or more compounds of formula (I) and selected from the group consisting of

[0230] 4-Isopropyldibenzoylmethane

[0231] ● Terephthalidene-dibornane sulfonic acid and salts ( SX)

[0232] ●4-tert-Butyl-4′-methoxydibenzoylmethane (Avobenzone) / (Neo 357)

[0233] · Phenylene-bis-benzimidazolyl-tetrasulfonic acid disodium salt (Neo AP)

[0234] 2,2'-(1,4-phenylene)-bis-(1H-benzimidazole-4,6-disulfonic acid), monosodium salt

[0235] ·2-(4-Diethylamino-2-hydroxybenzoyl)-benzoic acid hexyl ester ( A Plus)

[0236] Indanylidene compounds according to DE 100 55 940 A1 (= WO 2002038537)

[0237] The compositions may contain other typical cleaning and detergent composition ingredients such as UV filters, which in the formulations according to the invention are preferably combined with one or more compounds of formula (I) and selected from the group consisting of

[0238] ● Para-aminobenzoic acid

[0239] ·3-(4'-Trimethylammonium)-benzylidenebornyl-2-one methyl sulfate

[0240] · Homomenthyl Salicylate (Neo HMS

[0241] ·2-Hydroxy-4-methoxybenzophenone (Neo BB)

[0242] 2-phenylbenzimidazolesulfonic acid (Neo Hydro)

[0243] Terephthalene-dibornanesulfonic acid and salts ( SX)

[0244] ·4-tert-Butyl-4'-methoxydibenzoylmethane (Neo 357)

[0245] ·3-(4'-sulfo)benzylidene-2-camphenyl-one and salts

[0246] 2-Ethylhexyl 2-cyano-3,3-diphenylacrylate (Neo 303)

[0247] N-[(2 and 4)-[2-(Oxobornylene-3-yl)methyl]benzyl]-acrylamide polymer

[0248] ●2-Ethylhexyl methoxycinnamate (Neo AV)

[0249] Ethoxylated (25 mol) ethyl p-aminobenzoate (INCI name: PEG-25 PABA)

[0250] Isoamyl p-methoxycinnamate (Neo E1000)

[0251] ·2,4,6-Triphenylamino-(p-carbonyl-2'-ethylhexyl-1'-oxy)-1,3,5-triazine ( T150)

[0252] Phenol, 2-(2H-benzotriazol-2-yl)-4-methyl-6-(2-methyl-3(1,3,3,3-tetramethyl-1-(trimethylsilyl)oxy)-dimethylsilyloxy)-propyl)( XL)

[0253] 4,4'-[(6-[4-(1,1-dimethyl)-aminocarbonyl)phenylamino]-1,3,5-triazine-2,4-diyl)diimino]-bis-(2-ethylhexyl benzoate) (Uvasorb HEB)

[0254] ·3-(4'-Methylbenzylidene)-D,L-camphor (Neo MBC)

[0255] ·3-Benzylidene-camphor

[0256] ●2-Ethylhexyl Salicylate (Neo OS)

[0257] 2-Ethylhexyl 4-dimethylaminobenzoate (Padimate O)

[0258] ●Hydroxy-4-methoxybenzophenone-5-sulfonic acid and sodium salt

[0259] ·2,2'-methylene-bis-(6-(2H-benzotriazol-2-yl)-4-1,1,3,3-tetramethylbutyl)-phenol)( M)

[0260] ● Phenylene-bis-benzimidazolyl-tetrasulfonic acid disodium salt (Neo AP)

[0261] ·2,4-bis-[{(4-(2-ethylhexyloxy)-2-hydroxy}phenyl]-6-(4-methoxyphenyl)-1,3,5-triazine ( S)

[0262] Benzalmalonate-polysiloxane ( SLX)

[0263] Menthyl anthranilate (Neo MA)

[0264] ·2-(4-Diethylamino-2-hydroxybenzoyl)-benzoic acid hexyl ester ( A Plus)

[0265] • Indanidene compounds according to DE 100 55 940 (= WO 02 / 38537).

[0266] Advantageous primary and secondary sunscreens are described in WO 2005 123101 A1. Advantageously, these preparations contain at least one UVA filter and / or at least one UVB filter and / or at least one inorganic pigment. The preparations according to the present invention can be in various forms, as are customary for sunscreen preparations. Thus, they can be in the form of solutions, water-in-oil (W / O) or oil-in-water (O / W) emulsions or multiple emulsions, for example water-in-oil-in-water (W / O / W) emulsions, gels, aqueous dispersions, solid sticks or aerosols.

[0267] In a further preferred embodiment, the preparations according to the invention contain sunscreens, i.e., in particular UV filters and / or inorganic pigments (UV filter pigments) in such a total amount that the preparations according to the invention have a light protection factor of greater than or equal to 2 (preferably greater than or equal to 5). The preparations according to the invention are particularly suitable for protecting the skin and hair.

[0268] Secondary sunscreen

[0269] In addition to the above-mentioned main groups of sunscreens, secondary sunscreens of the antioxidant type can also be used. Secondary sunscreens of the antioxidant type block the photochemical reaction chain initiated when ultraviolet rays penetrate into the skin. Typical examples are amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides such as D,L-carnosine, D-carnosine, L-carnosine and its derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and its glycosyl, N-acetyl, methyl, ethyl, propyl, amyl, butyl and lauryl, palmitoyl, oleyl, α-linoleoyl, cholesteryl and their glycerides) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low tolerance doses of sulfoximine compounds (such as buthionine sulfoximine, homocysteine sulfoximine, buthionine sulfone, penta-, hexa- and heptathionine sulfoximine), and (metal) chelators (such as α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids citric acid, lactic acid, malic acid), humic acid, bile acid, bile extract, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (such as linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and their derivatives, vitamin C and its derivatives (such as ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (such as vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate), as well as benzoyl benzoate of benzoin resin, rutinic acid and its derivatives, glycosyl rutin, ferulic acid, fusin sorbitol, carnosine, butylhydroxytoluene, butylhydroxyanisole, nordihydroguaiaretic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, superoxide dismutase, titanium dioxide (for example, dispersion in ethanol), zinc and its derivatives (for example, ZnO, ZnSO4), selenium and its derivatives (for example, methionine selenium), stilbenes and their derivatives (for example, stilbene oxide, trans-stilbene oxide) and derivatives of these active compounds suitable for the purposes of the present invention (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids).

[0270] Advantageous inorganic secondary photoprotective factors are pigments, preferably inorganic pigments based on finely dispersed metal oxides and / or other metal compounds that are insoluble or slightly soluble in water, in particular oxides of titanium (TiO2), zinc (ZnO), iron (e.g. Fe2O3), zirconium (ZrO2), silicon (SiO2), manganese (e.g. MnO), aluminum (Al2O3), cerium (e.g. Ce2O3), mixed oxides of the corresponding metals and mixtures of these oxides. These pigments are X-ray amorphous or non-X-ray amorphous. X-ray amorphous oxide pigments are metal oxides or semimetal oxides that have no or no identifiable crystal structure in X-ray diffraction experiments. Such pigments can usually be obtained by flame reaction, for example by reacting metal or semimetal halides with hydrogen and air (or pure oxygen) in a flame.

[0271] X-ray amorphous oxide pigments are used as thickeners and thixotropic agents, flow aids for stabilizing emulsions and dispersions, and as carrier substances (e.g. for increasing the volume of finely divided powders). X-ray amorphous oxide pigments known and frequently used in cosmetic or dermatological galenical preparations are, for example, high-purity silicon oxides. Preferably, the pigments have a particle size in the range of 5 to 40 nm and a particle size of 50 to 400 nm. 2 / g, preferably 150 to 300m 2 / g active surface area (BET) of high purity, X-ray amorphous silica pigment, in which the particles are seen as spherical particles of very uniform size. Macroscopically, silica pigment is a loose white powder. Silica pigment is It is commercially available under the name of (CAS-No. 7631-85-9) or Carb-O-Sil.

[0272] Favorable The levels are, e.g. 0X50, 130, 150, 200, 300, 380, MQX 80, MOX 170, COK 84, R 202, R 805, R 812, R 972, R 974, R976.

[0273] The composition according to the invention may comprise from 0.1 to 20% by weight, advantageously from 0.5 to 10% by weight and more preferably from 1 to 5% by weight of X-ray-amorphous oxide pigments, based on the total weight of the composition.

[0274] According to the invention, the non-X-ray amorphous inorganic pigment is advantageously in hydrophobic form, i.e., it has been surface-treated to be repellent to water. This surface treatment may comprise providing the pigment with a thin hydrophobic layer by methods known per se. Such methods include, for example, producing a hydrophobic surface layer by the reaction n TiO2 + m(RO)3Si-R' → n TiO2(surf.)

[0275] Here n and m are the stoichiometric parameters used as required, and R and R' are the desired organic radicals. For example, hydrophobic pigments prepared analogously to DE A 33 14 742 are advantageous.

[0276] The total amount of inorganic pigments, in particular hydrophobic inorganic micropigments, in the finished cosmetic, dermatological and pharmaceutical compositions according to the invention can advantageously be selected from the range of 0.1 to 30% by weight, preferably 0.1 to 10.0% by weight, preferably 0.5 to 6.0% by weight, based on the total weight of the composition.

[0277] antioxidants

[0278] It is generally preferred that the compositions according to the invention contain additional amounts of antioxidants. Advantageous antioxidants that can be used according to the invention are all conventional antioxidants or those suitable for cosmetic, dermatological and pharmaceutical preparations. Antioxidants are preferably selected from the group consisting of amino acids (e.g. glycine, histidine, tyrosine, tryptophan) and their derivatives, imidazoles (e.g. urocanic acid) and their derivatives, peptides, such as D, L-carnosine, D-carnosine, L-carnosine and their derivatives (e.g. anserine), carotenoids, carotenes (e.g. α-carotene, β-carotene, lycopene) and their derivatives, chlorogenic acid and its derivatives, lipoic acid and its derivatives (e.g. dihydrolipoic acid), aurothioglucose, propylthiouracil and other thiols (e.g. thioredoxin, glutathione, cysteine, cystine, cystamine and glycosyl, N-acetyl, methyl, ethyl, propyl, pentyl, butyl and octyl groups). lauryl, palmitoyl, oleyl, γ-linoleyl, cholesteryl and their oligoglycerides) and their salts, dilauryl thiodipropionate, distearyl thiodipropionate, thiodipropionic acid and its derivatives (esters, ethers, peptides, lipids, nucleotides, nucleosides and salts) and very low tolerable doses (e.g. pmol to μmol / kg) of sulfoximine compounds (e.g. buthionine sulfoximine, homocysteine sulfoximine, buthionine sulfone, penta-, hexa- and heptathionine sulfoximine), as well as (metal) chelators (e.g. α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin), α-hydroxy acids (e.g. citric acid, lactic acid, malic acid), humic acid, Bile acids, bile extracts, bilirubin, biliverdin, EDTA, EGTA and its derivatives, unsaturated fatty acids and their derivatives (preferably γ-linolenic acid, linoleic acid, oleic acid), folic acid and its derivatives, ubiquinone and ubiquinol and its derivatives, vitamin C and its derivatives (such as ascorbyl palmitate, magnesium ascorbyl phosphate, ascorbyl acetate), tocopherol and its derivatives (such as vitamin E acetate), vitamin A and its derivatives (vitamin A palmitate) and benzoyl benzoate of benzoin resin, rutinic acid and its derivatives, α-glucosylrutin, ferulic acid, furfurylideneglucitol, myoglobin According to the invention, peptides, butylated hydroxytoluene, butylated hydroxyanisole, desdihydroguaiaretic acid, nordihydroguaiaretic acid, trihydroxybutyrophenone, uric acid and its derivatives, mannose and its derivatives, zinc and its derivatives (e.g. ZnO, ZnSO4), selenium and its derivatives (e.g. selenomethionine), stilbenes and their derivatives (e.g. stilbene oxide, trans-stilbene oxide) and their derivatives (salts, esters, ethers, sugars, nucleotides, nucleosides, peptides and lipids), derivatives of acetophenone, e.g. hydroxyacetophenone and its mixtures with phenoxyethanol and / or pentane 1,2 diol and / or hexane 1,2 diol and / or octane 1,2 diol are suitable.

[0279] The amount of the above antioxidant (compound(s)) in the composition is preferably 0.001 to 30 wt%, more preferably 0.05 to 20 wt%, most preferably 1 to 10 wt%, based on the total weight of the composition.

[0280] vitamins

[0281] In a preferred embodiment, the composition according to the invention may also advantageously contain vitamins and vitamin precursors. All vitamins and vitamin precursors suitable or commonly used for cosmetic and / or dermatological applications can be used. Particularly noteworthy here are vitamins and vitamin precursors, such as tocopherol, vitamin A, niacin, and niacinamide, other vitamins of the B complex, in particular biotin, as well as vitamin C and panthenol and its derivatives, in particular panthenol esters and ethers, and cationically derivatized panthensols, such as panthenol triacetate, panthenol monoethyl ether and its monoacetate, and cationic panthenol derivatives. If vitamin E and / or its derivatives represent the antioxidant, their respective concentrations are advantageously selected within the range of 0.001 to 10% by weight, based on the total weight of the composition. If vitamin A or a vitamin A derivative, or carotene or its derivatives represent the antioxidant, their respective concentrations are advantageously selected within the range of 0.001 to 10% by weight, based on the total weight of the antioxidant.

[0282] Plant extracts

[0283] The compositions according to the invention may comprise plant extracts which are usually prepared by extraction from the whole plant, but in individual cases may also be prepared from only the flowers and / or leaves, wood, bark or roots of the plant. As regards plant extracts which can be used, reference is made in particular to the extracts listed in the Industrieverband Frankfurt am Main. Extracts listed in the table starting on page 44 of the Manual of Declaration of the Constituents of Cosmetic Compositions, 3rd edition, published by Cosmetic Products GmbH & Co. KG (Holland GmbH). Particularly advantageous plant extracts are derived from the following plants: aloe vera, witch hazel, algae, oak bark, rose bay willow herb, nettle, wild sesame, hops, chamomile, yarrow, arnica, calendula, burdock root, horsetail, hawthorn, linden flower, almond, pine needle, horse chestnut, sandalwood, juniper, coconut, mango, apricot, orange, lemon, lime, grapefruit, apple, green tea, grapefruit fruit, wheat, oats, barley, sage, thyme, wild thyme, rosemary, birch, mallow, wood sorrel, willow bark, stolonifera, coltsfoot, hibiscus, ginseng, and ginger root.

[0284] Particularly preferred herein are extracts of aloe vera, chamomile, algae, rosemary, calendula, ginseng, cucumber, sage, nettle, linden flower, arnica, and witch hazel. Mixtures of two or more plant extracts may also be used. Extractants used to prepare the plant extracts may be water, alcohols, and mixtures thereof. Among the alcohols, preferred herein are not only lower alcohols such as ethanol and isopropanol, but also polyols such as ethylene glycol, propylene glycol, and butylene glycol, particularly as extractants, either alone or mixed with water. Plant extracts may be used in pure or diluted form.

[0285] Skin lightening agents

[0286] It is also possible to include additional amounts of skin-lightening ingredients in the composition according to the invention. Examples of such skin-lightening ingredients that can be used include, but are not limited to, kojic acid (5-hydroxy-2-hydroxymethyl-4-pyrone), kojic acid derivatives such as kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, kojic acid dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, resorcinol derivatives such as 4-(1-phenylethyl)1,3-resorcinol, sulfur-containing molecules such as glutathione or cysteine, α-hydroxy acids (e.g. citric acid, lactic acid, malic acid) and their derivatives, sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids , benzofuranones, for example, ligustic acid, benzoyl benzoate, benzophenones, for example, linalool, benzophenones ... acids), such as octadecenedioic acid and azelaic acid, inhibitors of nitrogen oxide synthesis, such as L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelators (such as α-hydroxy fatty acids, palmitic acid, phytic acid, lactoferrin, humic acid, gallic acid, bile extracts, bilirubin, biliverdin), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, these compounds are used in the form of extracts from plants, such as bearberry extract, rice extract, papaya extract, liquorice root extract or concentrated fractions of these substances, such as glabridin or licochalcone A, cinnamon wood extract, extracts from Rumex and Ramulus species, extracts of Pinus (pine trees), extracts of Vitis vinifera or stilbene derivatives concentrated therefrom, Saxifrage, mulberry, Scutellaria baicalensis and / or grape extracts.

[0287] Active substances that regulate hair pigmentation

[0288] Preferred active ingredients for hair lightening are selected from the group consisting of: kojic acid (5-hydroxy-2-hydroxymethyl-4-pyrone), kojic acid derivatives, preferably 122178 dipalmitate, arbutin, ascorbic acid, ascorbic acid derivatives, preferably magnesium ascorbyl phosphate, hydroquinone, hydroquinone derivatives, resorcinol, resorcinol derivatives, preferably 4-alkylresorcinol and 4-(1-phenylethyl)1,3-resorcinol (phenethylresorcinol), cyclohexylcarbamates (preferably WO 2010 / 122178 and WO One or more cyclohexyl carbamates disclosed in 2010 / 097480), sulfur-containing molecules, preferably glutathione or cysteine, α-hydroxy acids (preferably citric acid, lactic acid, malic acid), their salts and esters, N-acetyl tyrosine and derivatives, undecylenoylphenylalanine, gluconic acid, chromone derivatives, preferably aloesin, flavonoids, 1-aminoethylphosphinic acid, thiourea derivatives, ellagic acid, niacinamide, zinc salts, preferably zinc chloride or zinc gluconate, thujacin and derivatives, triterpenes, preferably maslinic acid, sterols, preferably ergosterol, benzofuranones, preferably ligustolide, vinylguaiacol, ethylguaiacol, dionic acid acids), preferably octadecenedioic acid and / or azelaic acid, inhibitors of nitrogen oxide synthesis, preferably L-nitroarginine and its derivatives, 2,7-dinitroindazole or thiocitrulline, metal chelators (preferably α-hydroxy fatty acids, phytic acid, humic acid, bile acid, bile extract, EDTA, EGTA and its derivatives), retinoids, soy milk and extracts, serine protease inhibitors or lipoic acid or other synthetic or natural active ingredients for skin and hair lightening, the latter preferably in the form of extracts from plants, preferably bearberry extract, rice extract, papaya extract, turmeric extract, mulberry extract, jacaranda extract, cyperus rotundus extract, liquorice root extract or components concentrated or isolated therefrom, preferably glabridin or licochalcone A, cinnamon wood extract, extracts of Rumex spp., extracts of Pinus spp. (pine tree), extracts of Vitis spp. or stilbene derivatives isolated or concentrated therefrom, Saxifrage extract, Scutellaria baicalensis extract (scutelleria ulmoides extract), extract), grape extract and / or microalgae extract, in particular Tetrascelis quadrangularis extract.

[0289] Active ingredients for tanning the skin and hair that are advantageous in this context are substrates or substrate analogs for tyrosinase, such as L-tyrosine, N-acetyltyrosine, L-DOPA or L-dihydroxyphenylalanine, xanthine alkaloids, such as caffeine, theobromine and theophylline and their derivatives, proopiomelanocortin peptides, such as ACTH, α-MSH, their peptide analogs, and other substances that bind to melanocortin receptors, peptides such as Val-Gly-Val-Ala-Pro-Gly, Lys- Ile-Gly-Arg-Lys or Leu-Ile-Gly-Lys, purines, pyrimidine compounds, folic acid, copper salts such as copper gluconate, copper chloride or copper pyrrolidinoate, 1,3,4-oxadiazole-2-thiol such as 5-pyrazin-2-yl-1,3,4-oxadiazole-2-thiol, curcumin, zinc diglycinate (Zn(GIy)2)), manganese(II) dicarbonate complexes ("pseudocat-alases"), such as, for example, EP 0584178, tetrasubstituted cyclohexene derivatives, for example as described in WO 2005 / 032501, isoprenoids, as described in WO 2005 / 102252 and WO 2006 / 010661, melanin derivatives such as Melasyn-100 and MelanZe, diacylglycerols, aliphatic or cyclic diols, psoralens, prostaglandins and their analogs, activators of adenylate cyclase and compounds that activate the conversion of hair melanosomes into keratinocytes, such as serine proteases or PAR-2 receptor agonists, extracts of plants and plant parts of the genus Chrysanthemum, extracts of plants and plant parts of the genus Sanguisorba officinalis, walnut extract, urucum extract, rhubarb extract, microalgae extracts, in particular Isochrysis galbana, trehalose, erythrulose and dihydroxyacetone. Flavonoids that cause skin and hair staining or browning (e.g., quercetin, rhamnoside, kaempferol, fisetin, genistein, daidzein, chrysin and apigenin, epicatechin, diosmin and dicanthin, morin, quercetin, naringenin, hesperidin, phloridzin, phloretin) may also be used.

[0290] The amount of the aforementioned examples of further active ingredients (one or more compounds) for regulating skin and hair pigmentation in the products according to the invention is preferably from 0.00001 to 30% by weight, preferably from 0.0001 to 20% by weight, particularly preferably from 0.001 to 5% by weight, based on the total preparation.

[0291] Hair growth activators or inhibitors

[0292] Preparations and products according to the invention may also contain one or more hair growth activators, ie agents which stimulate hair growth. The hair growth activator is preferably selected from the group consisting of pyrimidine derivatives such as 2,4-diaminopyrimidine-3-oxide (Aminexil), 2,4-diamino-6-piperidopyrimidine-3-oxide (Minoxidil) and its derivatives, 6-amino-1,2-dihydro-1-hydroxy-2-imino-4-piperidopyrimidine and its derivatives, xanthine alkaloids such as caffeine, theobromine and theophylline and their derivatives, quercetin and its derivatives, dihydroquercetin (taxifolin) and its derivatives, potassium channel openers, antiandrogen drugs, synthetic or natural 5-reductase inhibitors, nicotinate esters such as tocopheryl nicotinate, benzyl nicotinate and C1-C6 alkyl nicotinates, proteins such as the tripeptide Lys-Pro-Val, diphencypren, hormones, finasteride, dutasteride, flutamide, bicalutamide, pregnane derivatives, progesterone and its derivatives, cycloacetic acid Progesterone, spironolactone and other diuretics, calcineurin inhibitors such as FK506 (Tacrolimus, Fujimycin) and its derivatives, cyclosporin A and its derivatives, zinc and zinc salts, tea polyphenols, proanthocyanidins, proanthocyanidins, phytosterols such as β-sitosterol, biotin, eugenol, (±)-β-citronellol, panthenol, glycogen, for example from mussels, from microorganisms, marine Algae, plants and plant parts, such as plants of the genus: dandelion (genus Leontopodium or Taraxacum), Ginseng, Vitex, Coffee, Paulownia, Theobroma cacao, Asarum, Cucurbita or Sophora, Saw Palmetto (Saw Palmetto), Sophora flavescens, Pygeum africanum, Panicum foetida, Cimicifuga foetida, Soybean, Clove, Cotinus coggygria, Hibiscus rosa-sinensis, Camellia sinensis, Yerba Mate, Isochrysis galbana, Licorice, Grape, Apple, Barley or Hops extracts, or / and rice or wheat hydrolysates.

[0293] Optionally, the formulations and products according to the invention may also contain one or more hair growth inhibitors (as described above), i.e., agents that slow down or prevent hair growth. The hair growth inhibitors are preferably selected from the group consisting of activin, activin derivatives or activin agonists, ornithine decarboxylase inhibitors, such as α-difluoromethylornithine or pentacyclic triterpenoids such as ursolic acid, betulin, betulinic acid, oleanolic acid and its derivatives, 5α-reductase inhibitors, androgen receptor antagonists, S-adenosylmethionine decarboxylase inhibitors, γ-glutamyl transpeptidase inhibitors, transglutaminase inhibitors, serine protease inhibitors of soybean origin, extracts from microorganisms, seaweed, different microalgae or plants and plant parts, such as Leguminosae, Solanaceae, Gramineae, Asclepiadaceae or Cucurbitaceae, Chondrus crispus, Hemerocallis, Ceropegia, Dulvilla, Glycine max, Sanguisorba officinalis, Calendula, Hamamelis, Arnica montana, Salix alba, Hypericum perforatum or Gymnema sylvestre.

[0294] anti-inflammatory preparations

[0295] The composition can also include active anti-inflammatory compounds and / or alleviate redness and / or alleviate itching compounds (anti-irritants). All active anti-inflammatory compounds or alleviate redness and / or alleviate itching compounds that are suitable for or commonly used in cosmetic, dermatological and pharmaceutical compositions can be used herein. Advantageously used active anti-inflammatory compounds and alleviate redness and / or alleviate itching compounds are steroidal anti-inflammatory substances of corticosteroids, for example, hydrocortisone, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone, and this list can be expanded by adding other steroidal anti-inflammatory agents. Non-steroidal anti-inflammatory agents can also be used. Illustrated examples here are oxicams, such as piroxicam or tenoxicam; salicylates, such as aspirin, disalcid, solprin or fendosal; acetic acid derivatives, such as diclofenac, clofenac, indomethacin, sulindac, tolmetin or clindanac; fenamates, such as mefenamic acid, meclofenamic acid, flufenamic acid or niflumic acid; propionic acid derivatives, such as ibuprofen, naproxen, benoxaprofen; or pyrazoles, such as phenylbutazone, oxybutazone, febrazone or azapropazone.

[0296] Alternatively, natural anti-inflammatory substances or substances that relieve redness and / or relieve itching can be used. Plant extracts, in particular highly active plant extract fractions and highly pure active substances isolated from plant extracts can be used. Extracts, fractions and active substances are from chamomile, aloe, myrrh, madder, willow, rose bay willow herb, oats, and also especially from pure substances, such as bisabolol, apigenin-7-glucoside, boswellic acid, phytosterols, glycyrrhizin, glabridin and licochalcone A are particularly preferred. The preparations of the present invention can also include a mixture of two or more active anti-inflammatory compounds. Bisabolol, boswellic acid, and extracts from oats and Echinacea and highly pure active compounds isolated therefrom are particularly preferably used as anti-inflammatory substances and substances that relieve redness and / or relieve itching in the present invention, and α-bisabolol and extracts from oats and highly pure active compounds isolated therefrom are particularly preferred.

[0297] Preferred anti-inflammatory agents may be selected from the group consisting of:

[0298] (i) steroidal anti-inflammatory substances of the corticosteroid class, in particular hydrocortisone, hydrocortisone derivatives such as hydrocortisone 17-butyrate, dexamethasone, dexamethasone phosphate, methylprednisolone or cortisone,

[0299] (ii) nonsteroidal anti-inflammatory substances, in particular oxicams such as piroxicam or tenoxicam, salicylates such as aspirin, salsalate, solprin or fendosal, acetic acid derivatives such as diclofenac, fenclofenac, indomethacin, sulindac, tolmetin or clindanac, fenamic esters such as mefenamic acid, meclofenamic acid, flufenamic acid or niflumic acid, propionic acid derivatives such as ibuprofen, naproxen or benoxaprofen, pyrazoles such as phenylbutazone, oxyphenbutazone, febrazone or azapropazone,

[0300] (iii) natural or naturally occurring anti-inflammatory substances or substances that relieve redness and / or itching, in particular extracts or fractions of chamomile, aloe vera, myrrh, madder, willow, willowherb, oats, calendula, arnica, St. John's wort, honeysuckle, rosemary, passionflower (Passiflora incarnata), witch hazel, ginger or echinacea, or the single active compounds thereof,

[0301] (iv) histamine receptor antagonists, serine protease inhibitors (e.g., soybean extract), TRPV1 antagonists (e.g., 4-tert-butylcyclohexanol), NK1 antagonists (e.g., aprepitant, hydroxyphenylpropionamide benzoic acid), cannabinoid receptor agonists (e.g., palmitoylethanolamide), and TRPV3 antagonists.

[0302] The amount of anti-irritant (compound(s)) in the composition is preferably 0.0001 to 20% by weight, particularly preferably 0.0001 to 10% by weight, in particular 0.001 to 5% by weight, based on the total weight of the composition.

[0303] antimicrobial agents

[0304] Suitable antimicrobial agents are theoretically all substances which are capable of acting against Gram-positive bacteria, such as, for example, 4-hydroxybenzoic acid and its salts and esters, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 2,4,4'-trichloro-2'-hydroxy-diphenyl ether (triclosan), 4-chloro-3,5-dimethyl-phenol, 2,2'-methylenebis(6-bromo-4-chlorophenol), 3-methyl-4-(1-methylethyl)phenol, 2-benzyl-4-chloro-phenol, 3-( 4-chlorophenoxy)-1,2-propanediol, 3-iodo-2-propynylcarbamic acid butyl ester, chlorhexidine, 3,4,4'-trichlorocarbanilide (TTC), antibacterial fragrance, thymol, thyme oil, eugenol, clove oil, menthol, peppermint oil, farnesol, phenoxyethanol, glyceryl monocaprate, glyceryl monocaprylate, glyceryl monolaurate (GML), diglyceryl monocaprate (DMC), salicylic acid N-alkylamine, for example, n-octyl salicylic acid amide or n-decyl salicylic acid amide.

[0305] enzyme inhibitors

[0306] Suitable enzyme inhibitors are, for example, esterase inhibitors. These enzyme inhibitors are preferably trialkyl citrates, such as trimethyl citrate, tripropyl citrate, triisopropyl citrate, tributyl citrate and, in particular, triethyl citrate (HydagenCAT). These substances inhibit enzyme activity, thereby reducing the generation of odors. Other substances suitable as esterase inhibitors are sterol sulfates or sterol phosphates, for example, lanosterol sulfate or phosphate, cholesterol sulfate or phosphate, campesterol sulfate or phosphate, stigmasterol sulfate or phosphate and sitosterol sulfate or phosphate; dicarboxylic acids and esters thereof, for example glutaric acid, monoethyl glutarate, diethyl glutarate, adipic acid, monoethyl adipate, diethyl adipate, malonic acid and diethyl malonate; hydroxycarboxylic acids and esters thereof, for example citric acid, malic acid, tartaric acid or diethyl tartrate, and zinc glycinate.

[0307] Odor absorbers and antiperspirant actives

[0308] Suitable odor absorbers are substances that can absorb and largely retain odor-forming compounds. They reduce the partial pressure of the various components, thereby also reducing their diffusion rate. It is important that the fragrances remain intact during this process. Odor absorbers have no effect on bacteria. They contain, for example, complex zinc salts of ricinoleic acid as a main component, or specific, primarily odor-neutralizing fragrances known to those skilled in the art as "fixatives," such as extracts of labdanum or styrax, or some rosin acid derivatives. Odor masking agents are fragrances or fragrance oils that, in addition to their function as odor masking agents, also provide their respective fragrance to the deodorant. Fragrance oils that can be mentioned are, for example, mixtures of natural and synthetic fragrances. Natural fragrances include extracts of flowers, stems and leaves, fruits, peels, roots, wood, herbs and grasses, pine needles and branches, as well as resins and balsams. Also suitable are animal products, such as civet and castoreum. Typical synthetic aromatic compounds are esters, ethers, aldehydes, ketones, alcohols, and hydrocarbon products. Ester fragrance compounds include, for example, benzyl acetate, p-tert-butylcyclohexyl acetate, linalyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, allyl cyclohexylpropionate, styraxyl propionate, and benzyl salicylate. Ethers include, for example, benzyl ethyl ether; aldehydes include, for example, linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilyral, and bourgeonal; ketones include, for example, ionone and methyl cedarone; alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol, and terpineol; hydrocarbons mainly include terpenes and balsams. Less volatile essential oils commonly used as fragrance ingredients are also suitable as fragrance oils, such as sage oil, chamomile oil, clove oil, melissa oil, peppermint oil, cinnamon leaf oil, linden flower oil, juniper berry oil, vetiver oil, frankincense oil, galbanum oil, labdanum oil, and lavender oil. Preference is given to using bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, α-hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, ethoxymethoxycycloundecane (boisambrene forte), ambroxan, indole, methyl dihydrojasmonate, sandelice, lemon oil, mandarin oil, orange oil, allyl isopentoxyacetate, cyclovertal, lavender oil, clary sage oil, β-damascone, bourbon geranium oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, 2-ethyl-ethyl hexanoate (irotyl) and 2-tert-butylcyclohexylethyl carbonate (floramat), alone or in mixtures.

[0309] Suitable astringent antiperspirant active ingredients are primarily salts of aluminum, zirconium or zinc. Suitable antihydrotic active ingredients of this type are, for example, aluminum chloride, aluminum hydrochlorate, aluminum dihydrochlorate, aluminum sesquihydrochlorate and their complexes, for example with 1,2-propylene glycol, aluminum hydroxyallantoinate, aluminum chlorotartrate, aluminum zirconium trihydrochloride, aluminum zirconium tetrahydrochloride, aluminum zirconium pentahydrochloride and their complexes, for example with amino acids such as glycine.

[0310] Film formers and anti-dandruff agents

[0311] Standard film formers are, for example, chitosan, microcrystalline chitosan, quaternary chitosan, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymers, acrylic polymers, quaternary cellulose derivatives, collagen, hyaluronic acid and its salts and similar compounds.

[0312] Suitable antidandruff agents are Pirocton Olamin (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2-(1H)-pyridinone monoethanolamine salt), (Climbazole), (4-acetyl-1-{4-[2-(2,4-dichlorophenyl)r-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolane-c-4-ylmethoxyphenyl}-piperazine, ketoconazole, neoconazole, selenium disulfide, colloidal sulfur, sulfur polyethylene glycol dehydrated sorbitan monooleate, sulfur ricinoleyl polyethoxylate, sulfur tar fraction, salicylic acid (or combined with hexachlorophene), undecylenic acid, monoethanolamide sulfosuccinate sodium salt, UD (protein / undecylenic acid concentrate), zinc pyrithione, aluminum pyrithione and magnesium pyrithione / dipyrithione magnesium sulfate, salicylic acid and mixtures thereof.

[0313] Carriers, hydrotropes and moisturizing regulators

[0314] Preferred cosmetic carrier materials are solid or liquid (including high-viscosity substances) at 25° C. and 1013 mbar, for example, glycerol, 1,2-propylene glycol, 1,2-butylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, ethanol, water, and mixtures of two or more of these liquid carrier substances with water. Optionally, these formulations according to the invention can be prepared using preservatives or cosolvents. Other preferred liquid carrier substances that can be used as ingredients of the formulations according to the invention are selected from the group consisting of oils, for example, vegetable oils, neutral oils, and mineral oils.

[0315] Preferred solid carrier substances that can be used as components of the preparations according to the invention are hydrocolloids, for example starch, degraded starch, chemically or physically modified starch, dextrin, (powdered) maltodextrin (preferably with a dextrose value of 5 to 25, preferably 10-20), lactose, silicon dioxide, glucose, modified cellulose, gum arabic, gum ghatti, tragacanth, gum karaya, carrageenan, pullulan, curdlan, xanthan gum, gellan gum, guar gum, carob powder, alginates, agar, pectin and inulin, and mixtures of two or more of these solid substances, in particular maltodextrin (preferably with a dextrose value of 15 to 20), lactose, silicon dioxide and / or glucose.

[0316] In addition, hydrotropes, such as ethanol, isopropanol or polyols, can be used to improve fluidity. Suitable polyols preferably contain 2 to 15 carbon atoms and at least two hydroxyl groups. Such polyols may contain other functional groups, more particularly amino groups, or may be nitrogen-modified. Typical examples are:

[0317] ·glycerin;

[0318] Alkanediols, for example ethylene glycol, diethylene glycol, propylene glycol, butylene glycol, hexylene glycol and polyethylene glycols having an average molecular weight of 100 to 1000 daltons;

[0319] Technical oligoglycerol mixtures having a degree of self-condensation of 1.5 to 10, such as technical diglycerol mixtures having a diglycerol content of 40 to 50% by weight;

[0320] methylol compounds, such as, in particular, trimethylolethane, trimethylolpropane, trimethylolbutane, pentaerythritol and dipentaerythritol;

[0321] ● lower alkyl glycosides, especially those containing 1 to 8 carbon atoms in the alkyl group, such as methyl glycoside and butyl glycoside;

[0322] Sugar alcohols containing 5 to 12 carbon atoms, such as sorbitol or mannitol;

[0323] Sugars containing 5 to 12 carbon atoms, such as glucose or sucrose;

[0324] Amino sugars, such as glucosamine;

[0325] • Diolamines, such as diethanolamine or 2-aminopropane-1,3-diol.

[0326] Preferred moisturizing regulators include sodium lactate, urea, alcohols, sorbitol, glycerol, propylene glycol, aliphatic 1,2-diols with 5-10 C atoms, collagen, elastin or hyaluronic acid, diacyl adipate, petrolatum, ectoin, urocanic acid, lecithin, panthenol, phytantriol, lycopene, algae extracts, ceramides, cholesterol, glycolipids, chitosan, chondroitin sulfate, polyamino acids and polyamino sugars, lanolin, lanolin esters, amino acids, α-hydroxy acids (such as citric acid, lactic acid, maleic acid) and their derivatives, sugars (such as inositol), α-hydroxy fatty acids, phytosterols, triterpene acids, such as betulinic acid or ursolic acid, and seaweed extracts.

[0327] preservative

[0328] Preferred preservatives herein are, for example, benzoic acid, its esters and salts, propionic acid and its salts, salicylic acid and its salts, 2,4-hexadienoic acid (sorbic acid) and its salts, formaldehyde and paraformaldehyde, 2-hydroxydiphenyl ether and its salts, 2-zincsulphidopyridine-N-oxide, inorganic sulfites and bisulfites, sodium iodide, chlorobutanolum, 4-ethylmercury(II)-5-amino-1,3-bis(2-hydroxybenzoic acid) and its salts and esters, dehydrated Hexadecanoic acid, formic acid, 1,6-bis(4-amidino-2-bromophenoxy)-n-hexane and its salts, sodium salt of ethylmercury(II)-thiosalicylic acid, phenylmercury and its salts, 10-undecenoic acid and its salts, 5-amino-1,3-bis(2-ethylhexyl)-5-methyl-hexahydropyridine, 5-bromo-5-nitro-1,3-dioxane, 2-bromo-2-nitro-1,3-propanediol, 2,4-dichlorobenzyl alcohol, N-(4-chlorophenyl)-N'-(3,4-dichlorophenyl)urea, 4-chloro-m-cresol, 2,4,4'-trichloro-2'- Hydroxy-diphenyl ether, 4-chloro-3,5-dimethylphenol, 1,1'-methylene-bis(3-(1-hydroxymethyl-2,4-dioximidazolidin-5-yl)urea), poly-(hexamethylenebiguanide) hydrochloride, 2-phenoxyethanol, hexamethylenetetramine, 1-(3-chloroallyl)-3,5,7-triaza-1-azoniaadamantane chloride, 1-(4-chlorophenoxy)-1-(1H-imidazol-1-yl)-3,3-dimethyl-2-butanone, 1,3-bis(hydroxymethyl)-5,5- Dimethyl-2,4-imidazolidinedione, benzyl alcohol, pyridinone ethanolamine salt (Octopirox), 1,2-dibromo-2,4-dicyanobutane, 2,2'-methylene-bis(6-bromo-4-chloro-phenol), bromochlorobenzene, a mixture of 5-chloro-2-methyl-3(2H)-isothiazolinone and 2-methyl-3(2H)-isothiazolinone with magnesium chloride and magnesium nitrate, 2-benzyl-4-chlorophenol, 2-chloroacetamide, chlorhexidine, chlorhexidine acetate, chlorhexidine gluconate, chlorhexidine hydrochloride, 1-phenoxy-propan-2-ol, N-alkyl(C 12 -C 22 )trimethylammonium bromide and N-alkyl (C 12 -C 22 ) trimethyl-ammonium chloride, 4,4-dimethyl-oxazolidine, N-hydroxymethyl-N-(1,3-bis(hydroxymethyl)-2,5-dioximidazolin-4-yl)-N'-hydroxymethylurea, 1,6-bis(4-amidino-phenoxy)-n-hexane and its salts, glutaraldehyde, 5-ethyl-1-aza-3,7-dioxabicyclo(3.3.0)octane, 3-(4-chlorophenoxy)-1,2-propylene glycol, benzylethoxyamine chloride, alkyl-(C8-C18 )-dimethyl-benzylammonium chloride, alkyl-(C8-C 18 )-dimethyl-benzylammonium bromide, alkyl-(C8-C 18 )-dimethyl-benzylammonium saccharide, benzyl hemiformal, 3-iodo-2-propynyl-butylcarbamate, sodium hydroxymethyl-aminoacetate and sodium hydroxymethyl-aminoacetate.

[0329] In various cases, it is also advantageous to use substances in the compositions of the present invention that are primarily used to inhibit the growth of undesirable microorganisms on or in animal organisms. In this regard, in addition to conventional preservatives, other active compounds worth mentioning, in addition to a large number of conventional antibiotics, are particularly relevant to cosmetic products, such as triclosan, climbazol, octoxyglycerol, Octopirox (1-hydroxy-4-methyl-6-(2,4,4-trimethylpentyl)-2(1H)-pyridone, 2-aminoethanol), chitosan, farnesol, glyceryl monolaurate, or combinations of such substances. Ingredients with multifunctional properties, including the ability to reduce the growth of bacteria, yeasts, and molds, can also be used in the compositions encompassed by the present invention. These ingredients include, but are not limited to, pentane 1,2-diol, hexane 1,2-diol, octyl 1,2-diol, decyl 1,2-diol, tropolone, hydroxyacetophenone, ethylhexylglycerol, phenoxyethanol, as individual ingredients or as mixtures of two or more ingredients.

[0330] In addition, the composition of the present invention may also contain substances with a cooling effect. The individual active cooling compounds preferably used in the context of the present invention are listed below. The skilled person will be able to supplement the following list with a large number of other active cooling compounds; the active cooling compounds listed may also be used in combination with one another: l-menthol, d-menthol, racemic menthol, menthone glycerol acetal (trade name: MGA), Menthyl Lactate (trade name: ML, menthyl lactate is preferably l-menthyl lactate, especially l-menthyl lactate), menthol ethylamino oxalate ( X-Cool), substituted menthyl-3-carboxylic acid amides (e.g., menthyl-3-carboxylic acid N-acetamide), 2-isopropyl-N-2,3-trimethylbutyramide, substituted cyclohexanecarboxylic acid amides, 3-menthoxypropane-1,2-diol, 2-hydroxyethyl menthyl carbonate, 2-hydroxypropyl menthyl carbonate, N-acetylglycine menthyl, isopulegol, menthyl hydroxycarboxylates (e.g., menthyl-3-hydroxybutyrate), menthyl monosuccinate, 2-mercaptocyclodecanone, menthyl-2-pyrrolidino-5-one carboxylate, 2,3-dihydroxy-p-menthanyl, 3,3,5-trimethylcyclohexanone glycerol ketal, 3-menthyl-3,6-di-trioxanyl, 3-menthyl methoxyacetate, icilin.

[0331] In a particularly preferred embodiment, the composition may comprise a preservative selected from 4-hydroxyacetophenone, o-cymen-5-ol or a mixture thereof.

[0332] Fragrance oils and fragrances

[0333] Suitable fragrance oils are mixtures of natural and synthetic fragrances. Natural fragrances include extracts of flowers (lily, lavender, rose, jasmine, orange blossom, ylang-ylang), stems and leaves (geranium, patchouli, bitter orange), fruits (fennel, coriander, caraway, juniper), peels (bergamot, lemon, orange), roots (nutmeg, angelica, celery, cardamom, costus, iris, calamus), wood (pine, sandalwood, guaiac wood, cedarwood, rosewood), herbs and grasses (tarragon, lemongrass, sage, thyme), pine needles and branches (spruce, fir, pine, dwarf pine), resins and balsams (galbanum, elemi, benzoin, myrrh, frankincense, red myrrh). Animal raw materials, such as civet and castoreum, can also be used. Typical synthetic fragrance compounds are esters, ethers, aldehydes, ketones, alcohols, and hydrocarbon products. Examples of ester fragrance compounds include benzyl acetate, phenoxyethyl isobutyrate, p-tert-butyl cyclohexyl acetate, linalyl acetate, dimethyl benzyl carbinyl acetate, phenylethyl acetate, linalyl benzoate, benzyl formate, phenylglycine ethyl methyl ester, allyl cyclohexyl propionate, styroyl propionate, and benzyl salicylate. Ethers include, for example, benzyl ethyl ether; while aldehydes include, for example, linear alkanals containing 8 to 18 carbon atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, hydroxycitronellal, lilyral, and borax aldehyde. Examples of suitable ketones include ionone, α-isomethyl ionone, and methyl cedarwood ketone. Suitable alcohols include anethole, citronellol, eugenol, isoeugenol, geraniol, linalool, phenylethyl alcohol, and terpineol. Hydrocarbons primarily include terpenes and balsams. However, it is preferred to use mixtures of different fragrance compounds which together produce a pleasant aroma. Other suitable fragrance oils are the less volatile essential oils which are mostly used as fragrance ingredients. Examples are sage oil, chamomile oil, clove oil, melissa oil, peppermint oil, cinnamon leaf oil, lime flower oil, juniper berry oil, vetiver oil, frankincense oil, galbanum oil, labdanum oil, and lavender oil. The following substances are preferably used alone or in a mixture: bergamot oil, dihydromyrcenol, lilial, lyral, citronellol, phenylethyl alcohol, hexylcinnamaldehyde, geraniol, benzylacetone, cyclamen aldehyde, linalool, ethoxymethoxycycloundecane, ambroxan, indole, hedione, sandelice, citrus essential oils, mandarin oil, orange oil, allyl amyl glycolate, cyclovertal, lavender oil, clary sage oil, damascenone, bourbon geranium oil, cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, Fixolide NP, evernyl, iraldein gamma, phenylacetic acid, geranyl acetate, benzyl acetate, rose oxide, romilat, 2-ethyl-hexanoic acid ethyl ester (irotyl) and 2-tert-butylcyclohexylethyl carbonate (floramat).

[0334] dye

[0335] Suitable dyes are, for example, the publication "Kosmetische Any of the substances suitable and approved for use in cosmetics listed in "Chemie des Chemistry", Verlag Chemie, Weinheim, 1984, pages 81 to 106. Examples include carmine A (CI 16255), patent blue V (CI 42051), indigo (CI 73015), chlorophyllin (CI 75810), quinoline yellow (CI 47005), titanium dioxide (CI 77891), indanthrene blue RS (CI 69800) and madder red (CI 58000). Luminol can also be used as a fluorescent dye. Advantageous coloring pigments are, for example, titanium dioxide, mica, iron oxides (e.g., Fe2O3, Fe3O4, FeO(OH)) and / or tin oxide. Advantageous dyes are, for example, carmine, Berlin blue, chromium oxide green, ultramarine and / or manganese violet.

[0336] preparation

[0337] Preferred compositions according to the invention are chosen from products for treating, protecting, caring for and cleaning the skin and / or hair or as cosmetic products, preferably as leave-on products (meaning that compared to rinse-off products, one or more compounds of formula (I) remain on the skin and / or hair for a longer time, thereby making their moisturizing and / or anti-aging and / or wound healing promoting effects more pronounced).

[0338] The preparations according to the invention are preferably in the form of emulsions, for example W / O (water-in-oil), O / W (oil-in-water), W / O / W (water-in-oil-in-water), O / W / O (oil-in-water-in-oil) emulsions, PIT emulsions, Picking emulsions, emulsions with a low oil content, microemulsions or nanoemulsions, solutions, for example in oils (fatty oils or fatty acid esters, in particular C6-C32 fatty acid C2-C30 esters) or silicone oils, dispersions, suspensions, creams, emulsions or milks, depending on the preparation method and the ingredients, gels (including hydrogels, hydrodispersible gels, oleogels), sprays (for example pump sprays or sprays containing propellants) or foams or impregnation solutions for wipe-off cosmetics, detergents, for example soaps, synthetic detergents, washing liquids, shower and bath preparations, bath products (capsules, oils, tablets, salts, bath salts, soaps, etc.); effervescent preparations, skin care products such as emulsions (as described above) , ointments, pastes, gels (as described above), oils, balms, serums, powders (e.g., face powders, body powders), facial masks, eyebrow pencils, lipsticks, roll-ons, pumps, aerosols (foaming, non-foaming, or post-foaming), deodorants and / or antiperspirants, mouthwashes and mouth rinses, foot care products (including exfoliants, deodorants), insect repellents, sunscreens, after-sun products, shaving products, aftershave balms, pre- and after-shave washes, depilatories, hair care products, such as Shampoo (including 2-in-1 shampoo, anti-dandruff shampoo, baby shampoo, shampoo for dry hair, concentrated shampoo), conditioner, hair tonic, hair tonic, hair dye, styling cream, pomade, perming and curling solutions, hair spray, styling aids (such as gel or wax), hair smoothing agents (conditioners, relaxers), hair dye such as short-term direct hair dye, semi-permanent hair dye, permanent hair dye, conditioner, hair mousse, eye care products, make-up, make-up removers or baby products.

[0339] The preparations of the present invention are particularly preferably in the form of emulsions, in particular W / O, O / W, W / O / W, O / W / O emulsions, PIT emulsions, Pickering emulsions, low oil emulsions, microemulsions or nanoemulsions, gels (including hydrogels, hydrodispersible gels, oleogels), solutions, for example in oils (fatty oils or fatty acid esters, in particular C6-C 32 Fatty acids C2-C 30 esters) or silicone oil, or as a solution, or as a spray (e.g. a pump spray or a spray with a propellant).

[0340] The content of auxiliary substances and additives is 5 to 99% bw, preferably 10 to 80% bw, based on the total amount of the preparation. The amount of cosmetic or skin care auxiliary substances and additives and fragrances to be used in each case can be easily determined by a person skilled in the art by simple trial and error depending on the properties of the specific product.

[0341] The preparation may also contain up to 99% bw, preferably 5 to 80% bw, of water, based on the total preparation.

[0342] Oral composition

[0343] Another subject of the present invention relates to oral compositions containing the cooling agent as described above, preferably in an amount of about 0.1 to about 8% by weight, preferably about 0.5 to 5% by weight, and more preferably about 1 to about 2% by weight, based on the final composition.

[0344] Typical examples of suitable oral compositions include (hard high temperature cooking) candies, compressed tablets, chewing gum, toothpaste and mouthwash. The preparation and composition of the oral composition are described below:

[0345] candy

[0346] According to the present invention, preferred candies are so-called hard, high-temperature boiled candies. Their substrate is typically prepared from a mixture of sugar and other carbohydrates and maintained in an amorphous or glassy state. This form can be considered to be a solid syrup of saccharides typically containing up to about 4.5% by weight of water, based on the weight of the sugar substrate, preferably about 0.5 to about 2.5% by weight, and most preferably about 1.0 to about 1.5% by weight. Such materials typically contain up to about 65% by weight corn syrup, up to 80% by weight of sugar, and 0.1 to 5.0% by weight of water. Typically, the ratio between sugar (or other sweeteners suitable for saccharide formulations) and corn syrup is in the range of about 70:25 to about 45:55, preferably about 60:40. The syrup component is typically prepared from high fructose corn syrup, but may also include other materials. Other ingredients, such as spices, sweeteners, acidulants, pigments, etc., may also be added.

[0347] Hard, high-temperature cook candy bases can also be prepared from non-fermentable sugars such as sorbitol, mannitol, xylitol, maltitol, hydrogenated starch hydrolysates, hydrogenated corn syrup, and mixtures thereof. The candy base can contain up to about 95% by weight sorbitol, a mixture of sorbitol and mannitol in a ratio of about 9.5 to 0.5, or up to about 7.5 to 2.5, and a syrup component of up to about 55% hydrogenated corn syrup.

[0348] Compressed tablets

[0349] Oral formulations according to the present invention are compressed tablets, typically containing from about 0.1 to about 0.6 weight percent, and preferably about 0.5 weight percent, of liquid flavoring.

[0350] chewing gum

[0351] Chewing gum is generally composed of a water-insoluble base ingredient and a water-soluble ingredient and additives that provide, for example, a particular flavor.

[0352] Water-insoluble substrate, it is also referred to as " gum base ", contains natural or synthetic elastomer, resin, fat and oil body, plasticizer, filler, softener, dye and optional wax conventionally.The ratio of substrate in total formulation is 5 to 95 weight %, preferably 10 to 50 weight % and particularly 20 to 35 weight %.In typical embodiments of the present invention, substrate is made up of 20 to 60 weight % synthetic elastomer, 0 to 30 weight % natural elastomer, 5 to 55 weight % plasticizer, 4 to 35 weight % filler and a small amount of additives such as dye, antioxidant etc., prerequisite is that a small amount of them are water-soluble under all circumstances.

[0353] Suitable synthetic elastomers are, for example, polyisobutylene having an average molecular weight (according to GPC) of from 10,000 to 100,000, and preferably from 50,000 to 80,000, isobutylene / isoprene copolymers ("butyl elastomers"), styrene / butadiene copolymers (styrene:butadiene ratio, for example, 1:3 to 3:1), polyvinyl acetate having an average molecular weight (according to GPC) of from 2,000 to 90,000, and preferably from 10,000 to 65,000, polyisoprene, polyethylene, vinyl acetate / vinyl laurate copolymers, and mixtures thereof. Examples of suitable natural elastomers are rubbers, such as smoked or liquid latex or guayule, and natural rubbers such as jelutong, lechi caspi, perillo, sorva, massaranduba balata, massaranduba chocolate, nispero, rosindinha, chicle, gutta-percha, and mixtures thereof. The choice of synthetic and natural elastomers and the proportions in which they are mixed depend primarily on whether the chewing gum is to produce bubbles ("bubble gum"). Preferably, an elastomer mixture containing jelutong, chicle, sorva, and massaranduba is used.

[0354] In most cases, elastomers are too hard or lack the plasticity to be satisfactorily processed. Therefore, it has been found advantageous to use specific plasticizers, which must, of course, meet all requirements for food additive approval. Particularly suitable in this regard are esters of resin acids, such as esters of low-fat alcohols or polyols with fully or partially hardened monomeric or oligomeric resin acids. Methyl, glycerol, or pentaerythritol esters, or mixtures thereof, are particularly useful for this purpose. Alternatively, terpene resins derived from α-pinene, β-pinene, δ-limonene, or mixtures thereof, may also be used.

[0355] Suitable fillers or thickeners are magnesium or calcium carbonate, ground foam rock, silicates, in particular magnesium or aluminum silicate, clay, aluminum oxide, talc, titanium dioxide, mono-, dicalcium and tricalcium phosphate and cellulose polymers.

[0356] Suitable softeners or emulsifiers are tallow, hardened tallow, hardened or partially hardened vegetable oils, cocoa butter, partial glycerides, lecithin, triacetin and saturated or unsaturated fatty acids containing 6 to 22, preferably 12 to 18, carbon atoms, and mixtures thereof.

[0357] Suitable dyes and bleaching agents are for example the FD and C plant and fruit extracts approved for food colouring and titanium dioxide.The gum base may be wax-containing or wax-free.

[0358] In addition to the water-insoluble gum base, chewing gum compositions typically contain water-soluble ingredients, which may be composed of, for example, softeners, sweeteners, fillers, taste substances, flavor enhancers, emulsifiers, dyes, acidulants, antioxidants, etc., provided that these ingredients are at least sufficiently water-soluble. Depending on the water solubility of a particular representative substance, a single component may belong to either the water-insoluble phase or the water-soluble phase. However, a combination of, for example, a water-soluble emulsifier and a water-insoluble emulsifier may also be used, wherein the single representative substance is located in a different phase. Typically, the water-insoluble component constitutes 5 to 95% by weight of the formulation, and preferably about 20 to 80% by weight.

[0359] Water-soluble softeners or plasticizers are added to chewing gum compositions to improve chewiness and chewing feel, and are typically used in amounts of 0.5 to 15% by weight of the mixture. Typical examples are glycerol, lecithin, and aqueous solutions of sorbitol, hardened starch hydrolysates, or corn syrup.

[0360] In particular, for the production of low-calorie chewing gum, suitable fillers are selected from polydextrose, fructooligosaccharides (raf-tilose), inulin (raftilin), fructooligosaccharides (NutraFlora), palatinose oligosaccharides (palatinose oligosaccharides), guar gum hydrolysate (SunFiber) and dextrin.

[0361] In addition, chewing gum may contain other adjuvants and additives suitable for dental care, in particular for combating plaque and gingivitis, such as chlorhexidine, CPC or triclosan. It may also contain pH regulators (e.g. buffers or urea), anti-caries active substances (e.g. phosphates or fluoride), biologically active ingredients (antibodies, enzymes, caffeine, plant extracts), as long as these substances are allowed for use in food and do not react with each other in an undesirable manner.

[0362] Toothpaste and mouthwash

[0363] Toothpaste generally refers to a paste-like preparation of water, a thickener, a humectant, an abrasive or polishing agent, a surfactant, a sweetener, a fragrance, a deodorant, and an active agent for combating oral and dental diseases. Any conventional polishing agent can be used in the toothpaste according to the present invention, such as chalk, dicalcium phosphate, insoluble sodium metaphosphate, aluminum silicate, calcium pyrophosphate, fine-particle synthetic resins, silica, alumina, and alumina trihydrate. Particularly suitable polishing agents for the toothpaste according to the present invention are fine-particle xerogel silica, hydrogel silica, precipitated silica, alumina trihydrate, and fine-particle α-alumina, or mixtures of these polishing agents. Such polishing agents are preferably used in an amount of about 15-40% by weight of the toothpaste. Preferred humectants for use in toothpastes according to the present invention include low molecular weight polyethylene glycol, glycerin, sorbitol, or mixtures thereof, in an amount of up to about 50% by weight of the toothpaste. Among the known thickeners for toothpaste of the present invention, particularly preferred are thickening, fine-grained gel silica and nonionic hydrocolloids, such as hydroxyethylcellulose, hydroxypropyl guar gum, hydroxyethyl starch, polyvinyl pyrrolidone, high molecular weight polyethylene glycol and plant gums, such as tragacanth, agar, carrageenan, gum arabic and xanthan gum. By adding component (a) and / or (b) and optional (c), the required flavor and fragrance of the preparation according to the present invention can be obtained. It is also advantageous to add, to the oral preparation, for example, a caries inhibitor in the form of an alkali metal salt of an alkali metal fluoride, an alkali metal monofluorophosphonate or an organic phosphonic acid. In addition, the oral preparation according to the present invention can contain other standard auxiliaries, such as dyes, preservatives and sunscreens, such as titanium dioxide. For mouthwashes, the oral preparation according to the present invention can be mixed with a water-alcohol solution containing various amounts of ether oils, emulsifiers, astringents and conditioning drug extracts, caries inhibition additives and flavorings.

[0364] additive

[0365] The oral formulations according to the invention may contain additional additives such as sweeteners or vitamins in an amount of about 0.1 to about 10% by weight. These additives may also be components of the corresponding medicaments.

[0366] sweeteners

[0367] Suitable sweetening substances include natural sources of these substances (component e5), such as sweet carbohydrates or sugars (e.g. sucrose), trehalose, lactose, maltose, melizitose, raffinose, palatinose, lactulose, D-fructose, D-glucose, D-galactose, L-rhamnose, D-sorbose, D-mannose, D-tagatose, D-arabinose, L-arabinose, D-ribose, D-glyceraldehyde, maltodextrin) or plant preparations containing mainly these carbohydrates (e.g. sugars from beet (Betavulgaris ssp., sugars, syrups, molasses, from sugar cane (Saccharum officinarum ssp., such as molasses, syrup), from maple syrup (Acer truncatum), for example). ssp. ), from agave (agave concentrate), synthetic / enzymatic hydrolysates of starch or sucrose (e.g., invert sugar syrup, high fructose concentrate made from corn starch), fruit concentrates (e.g., from apples or pears, apple syrup, pear syrup), sugar alcohols (e.g., erythritol, threitol, arabitol, ribitol, xylitol, sorbitol, mannitol, dulcitol, lactitol), proteins (e.g., miraculin, monellin, tulsimin, curculin, brazzein), sweeteners (magap, sodium cyclamate, acesulfame potassium, neohesperidin dihydrochalcone, sodium saccharin, Super aspartame, neotame, alitam, sucralose, stevioside, rebaudioside, lugduname, carrelame, sucrononate, sucrooctate, monatin, phyllotoxin, certain sweet amino acids (glycine, D-leucine, D-threonine, D-aspartic acid, D-phenylalanine, D-tryptophan, L-proline), other sweet small molecules (e.g., hernandulcin, dihydrochalcone glycosides), glycyrrhizin, ammonium glycyrrhizate or other glycyrrhizic acid derivatives, liquorice extract (Glycyrrhizza glabra ssp.), Lippia dulcis extract, Momordica grosvenori (Lo Han Guo) extract or single substances (particularly Momordica grosvenori and mogrosides derived therefrom), Hydrangea dulcis or Stevia ssp. (e.g. Stevia) extracts or single substances.

[0368] vitamins

[0369] In another embodiment of the invention, the composition may contain vitamins (ingredient e1). Vitamins have different biochemical functions. Some have hormone-like functions as regulators of mineral metabolism (such as vitamin D) or regulators of cell and tissue growth and differentiation (such as some forms of vitamin A). Others act as antioxidants (such as vitamin E and sometimes vitamin C). Most vitamins (such as the B complex vitamins) act as precursors of enzyme cofactors, helping the enzymes to act as catalysts of metabolism. In this role, the vitamin may be tightly bound to the enzyme as part of a prosthetic group: for example, biotin is part of an enzyme involved in making fatty acids. Vitamins may also be less tightly bound to the enzyme, functioning as coenzymes, detachable molecules that carry chemical groups or electrons between molecules. For example, folic acid carries various forms of carbon groups - methyl, formyl and methylene - in the cell. Although these roles of assisting enzyme-substrate reactions are the best-known functions of vitamins, other vitamin functions are equally important. Suitable vitamins for use in the present invention are selected from the group consisting of

[0370] ●Vitamin A (retinol, retinal, beta-carotene),

[0371] Vitamin B1 (thiamine),

[0372] Vitamin B2 (riboflavin),

[0373] Vitamin B3 (niacin, niacinamide),

[0374] Vitamin B5 (pantothenic acid),

[0375] Vitamin B6 (pyridoxine, pyridoxamine, pyridoxal),

[0376] Vitamin B7 (biotin),

[0377] Vitamin B9 (folic acid, folinic acid),

[0378] Vitamin B 12 (cyanocobalamin, hydroxocobalamin, methylcobalamin),

[0379] Vitamin C (ascorbic acid),

[0380] Vitamin D (cholecalciferol),

[0381] Vitamin E (tocopherols, tocotrienols), and

[0382] Vitamin K (phylloquinone, menaquinone).

[0383] Preferred vitamins are ascorbic acid and tocopherol.The vitamins are present in the food composition in an amount of about 0.1 to about 5% by weight, and preferably about 0.5 to about 1% by weight.

[0384] Industrial Applicability

[0385] Another subject matter of the present invention relates to a method for providing a cooling sensation to human skin, comprising the following steps:

[0386] (a) providing a cooling preparation or a cosmetic or personal care composition as described above, and

[0387] (b) topically applying the formulation or composition to human skin.

[0388] Also provided is a method for providing a cooling sensation to human mucosa, comprising the steps of (a) providing a cooling preparation or oral composition as described above, and (b) orally administering the preparation or composition.

[0389] Finally, the present invention also relates to the use of the formulation according to the invention for preparing cosmetic, personal care and oral compositions, in particular for providing a cooling sensation to human skin or mucous membranes.

[0390] For the sake of good order, it is stated that all preferred combinations, mixtures, compositions, ranges etc. disclosed above also apply to the methods and uses without having to repeat them again. Example

[0391] Example 1

[0392] Long-lasting cooling sensation: Phenyl enal and homovanillate were added individually to a standard toothpaste composition. A panel of five experienced testers evaluated the composition for the initial cooling effect during brushing, the immediate effect after brushing, and the long-lasting effect after 5 and 10 minutes. The evaluation was based on a scorecard ranging from 1 = almost no cooling effect to 10 = intense cooling sensation. The results are provided in Table 1. Example 1 is according to the present invention, and Examples C1 to C3 are provided for comparison.

[0393] Table 1 Cooling sensation

[0394]

[0395] Phenylbutenal and propylphenyl homovanillate are commercially available as 5% solutions in propylene glycol from Symrise AG.

[0396] Adding phenylbutenal to standard toothpaste improved the immediate cooling sensation during and after brushing, but did not have any lasting effect. A 5% solution of propylphenyl homovanillate in propylene glycol provided a warming agent that had no effect when used alone.

[0397] However, combining phenylbutenal and propylphenyl homovanillate resulted in a significant improvement in the long-lasting cooling sensation after 5 and 10 minutes.

[0398] Formulation Examples of Cosmetic Compositions

[0399] The following Examples F1 to F59 show various formulations for cosmetic and oral compositions: Formulation 1 represents a mixture of 48% menthol, 1.6% phenylbutenal and 0.2% propylphenyl homovanillate and 51.2% fragrance or fragrance composition.

[0400] Table F1

[0401] Liquid soap; transparent (dosage % bw)

[0402]

[0403] Table F2

[0404] Synthetic soap, liquid (dosage % bw)

[0405]

[0406] Table F3

[0407] Cosmetic lotion for bathing (dosage % bw)

[0408]

[0409] Table F4

[0410] Cosmetic lotion containing triclosan for bathing (dosage % bw)

[0411]

[0412] Table F5

[0413] Sensitive area cleaning solution (dosage % bw)

[0414]

[0415] Table F6

[0416] Liquid soap (dosage % bw)

[0417]

[0418] Table F7

[0419] Shampoo (dosage % bw)

[0420]

[0421]

[0422] Table F8

[0423] 2-in-1 shampoo (dosage % bw)

[0424]

[0425] Table F9

[0426] Anti-dandruff shampoo (dosage % bw)

[0427]

[0428]

[0429] Table F10

[0430] Conditioner containing Crinipan, rinse out (dosage % bw)

[0431]

[0432] Table F11

[0433] Sprayable conditioner with zinc pyrithione, leave-in (% bw)

[0434]

[0435] Table F12

[0436] Conditioner containing UV protection factor (dosage % bw)

[0437]

[0438]

[0439] Table 13

[0440] Shower gel (dosage % bw)

[0441]

[0442] Table F14

[0443] Shaving cream (dosage % bw)

[0444]

[0445]

[0446] Table F15

[0447] Hair removal cream (dosage % bw)

[0448]

[0449] Table F16

[0450] Aftershave (dosage % bw)

[0451]

[0452]

[0453] Table F17

[0454] Deodorant preparation in roll-on gel form (dosage % bw)

[0455]

[0456] Table F18

[0457] Deodorant and antiperspirant roll-on (dosage % bw)

[0458]

[0459]

[0460] Table F19

[0461] Deodorant stick (dosage % bw)

[0462]

[0463] Table F20

[0464] Zirconium suspension colloid antiperspirant stick (dosage % bw)

[0465]

[0466]

[0467] Table F21

[0468] Deodorant spray containing SymClariol (dosage % bw)

[0469]

[0470] Table F22

[0471] Antiperspirant preparations (dosage % bw)

[0472]

[0473]

[0474] Table F23

[0475] Deodorant spray containing triclosan (dosage % bw)

[0476]

[0477] Table F24

[0478] O / W emulsion (dosage % bw)

[0479]

[0480]

[0481] Table F25

[0482] Body lotion (dosage % bw)

[0483]

[0484] Table F26

[0485] Ointment (dosage % bw)

[0486]

[0487] Table F27

[0488] Ointment (dosage % bw)

[0489]

[0490] Table F28

[0491] Hand and body cream (dosage % bw)

[0492]

[0493]

[0494] Table F29

[0495] Face cream (dosage % bw)

[0496]

[0497]

[0498] Table F30

[0499] Moisturizing body cream (dosage % bw)

[0500]

[0501] Table F31

[0502] Anti-wrinkle cream (dosage % bw)

[0503]

[0504] Table F32

[0505] Functional skin disinfectant oil (dosage % bw)

[0506]

[0507]

[0508] Table F33

[0509] Ointment for infected wounds (dosage % bw)

[0510]

[0511] Table F34

[0512] Moisturizing and disinfecting mask (dosage % bw)

[0513]

[0514]

[0515] Table F35

[0516] Sprayable disinfectant gel (dosage % bw)

[0517]

[0518] Table F36

[0519] Mineral Wash and Cleansing Gel (dosage % bw)

[0520]

[0521] Table F37

[0522] Anti-acne lotion (dosage % bw)

[0523]

[0524]

[0525] Table F38

[0526] Cosmetic sunscreen composition (amount in % bw)

[0527]

[0528] Table F39

[0529] Sunscreen spray (dosage % bw)

[0530]

[0531] Table F40

[0532] Sunscreen spray O / W.SPF 15-20 (dosage % bw)

[0533]

[0534] Table F41

[0535] Sunscreen ointment (W / O), SPF 40 (dosage % bw)

[0536]

[0537]

[0538] Table F42

[0539] Sunscreen lotion (W / O) (dosage % bw)

[0540]

[0541] Table F43

[0542] After-sun gel (dosage % bw)

[0543]

[0544] Table F44

[0545] After-sun lotion (dosage % bw)

[0546]

[0547]

[0548] Table F45

[0549] Hair styling gel (dosage % bw)

[0550]

[0551] Table F46

[0552] Silicone oil emulsion (dosage % bw)

[0553]

[0554]

[0555] Table F47

[0556] Microemulsion gel (dosage % bw)

[0557]

[0558] Table F48

[0559] Chewing gum, sugar-free, by weight

[0560]

[0561]

[0562] Table F49

[0563] Toothpaste, by weight

[0564]

[0565] Table F50

[0566] Mouthwash concentrate; by weight

[0567]

[0568] Table F51

[0569] Hard high-temperature boiled candies, sugar-free, by weight

[0570]

[0571] Table F52

[0572] Hard high-temperature boiled candies, by weight

[0573]

Claims

1. A cooling preparation, characterized in that It contains the following ingredients: (a) at least one phenylenal selected from the group consisting of 2-phenyl-but-2-enal represented by the following formula I-1 and 2-phenyl-pent-2-enal represented by I-2: (b) at least one homovanillic acid ester selected from the group consisting of 2-phenylethyl-2-(4-hydroxy-3-methoxyphenyl) acetate represented by the following formula II-1, 3-phenylpropyl-2-(4-hydroxy-3-methoxyphenyl) acetate represented by II-22, and 4-phenylbutyl-2-(4-hydroxy-3-methoxyphenyl) acetate represented by II-23: and optionally, (c) at least one physiological cooling agent different from components (a) and (b); The weight ratio of components (a) and (b) is 90:10-75:

25.

2. The preparation according to claim 1, characterized in that The invention also comprises as component (c) a physiological cooling agent selected from menthol and menthol derivatives, menthyl ethers, menthyl esters, menthyl carbonate, half esters of menthol with dicarboxylic acids or derivatives thereof, menthanecarboxylic acid amides, menthone and menthone derivatives, 2,3-dimethyl-2-(2-propyl)-butyric acid derivatives, isopulegol or its esters, menthane derivatives, cubebol or tetrahydropyrimidin-2-one oxalate and mixtures thereof.

3. The preparation according to claim 2, characterized in that The physiological cooling agent is selected from the group consisting of menthol, menthyl lactate, menthyl acetate, L-menthone glycerol acetal / ketal and mixtures thereof.

4. A cosmetic or personal care composition comprising the cooling preparation of claim 1.

5. An oral composition comprising the cooling preparation according to claim 1.

6. A method for providing a cooling sensation to human skin, characterized in that The following steps are involved: (a) providing a cooling preparation according to claim 1 or a cosmetic or personal care composition according to claim 4, and (b) topically applying the formulation or composition to human skin.

7. A method for providing a cooling sensation to human mucous membranes, characterized in that The following steps are included (a) providing a cooling preparation according to claim 1 or an oral composition according to claim 5, and (b) administering the preparation or composition orally.

8. Use of the formulation of claim 1 for preparing cosmetic, personal care and oral compositions.

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