A lead electrolyte rapid impurity removal device

By introducing a filtration system consisting of a purification cartridge and a filter screen into the lead electrolyte and combining it with a transmission mechanism to stir the electrolyte, the problem of high impurity content in the electrolyte is solved, efficient filtration of the electrolyte and miniaturization of the equipment are achieved, making it easier for small factories to use.

CN117604577BActive Publication Date: 2025-09-23江西金德铅业股份有限公司
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Patent Information

Application Number
CN202311511445.1
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-11-14
Publication Date
2025-09-23
Estimated Expiration
2043-11-14

AI Technical Summary

Technical Problem

In existing lead electrolyte production technology, higher impurities, especially bismuth-containing crude lead, are added to the electrolyte during the electrolysis process through the waste liquid after washing the anode mud, resulting in the lead quality being lower than 99.994%. In addition, the equipment is large in size and complex in structure, making it unsuitable for use in small factories.

Method used

A rapid impurity removal device for lead electrolyte was designed, which includes a purification cylinder and a filter screen. The electrolyte is initially filtered through the filter screen in the purification cylinder, and then filtered twice through the filter screen. The transmission mechanism drives the spoiler to stir the electrolyte to avoid precipitation, thereby realizing circulating filtration and convenient replacement of the electrolyte.

Benefits of technology

Significantly reduce the impurity content in the electrolyte, improve the service life and quality of the electrolyte, facilitate small factory operation, the equipment has a compact structure and strong adaptability.

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Abstract

The present invention relates to the technical field of impurity removal, and in particular to a device for rapid impurity removal from lead electrolyte, comprising a shell, wherein left and right edges of an upper end face of the shell are provided with a card slot, a plug post is fixedly connected to the bottom of an inner cavity of the card slot, a mounting bracket is slidably connected to the inner cavity of the card slot, an anode sheet and a cathode sheet are respectively mounted on the outside of the mounting bracket, the left and right end faces of the shell are fixedly connected to a fixed cylinder, a lower end face of the fixed cylinder is fixedly connected to a conduit, an end of the conduit away from the fixed cylinder is fixedly connected to the shell, and a transmission mechanism is provided on the front face of the shell. The present invention simplifies the structure of the device, improves the convenience of operation for workers, can be used in different factories, and makes it more practical.
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Description

Technical Field

[0001] The invention relates to the technical field of impurity removal, in particular to equipment for rapid impurity removal from lead electrolyte. Background Art

[0002] In recent years, my country's lead smelting capacity and output have grown significantly, further exacerbating structural contradictions in the lead industry and leading to increasingly fierce competition. With the increasing depletion of mineral resources and the continuous increase in lead smelting production costs, many lead smelters have changed their mindsets and are now focusing on high-value-added lead impurities such as high-silver, high-antimony, and high-bismuth raw materials. This produces a lower-grade (around 90%) crude lead with high levels of arsenic, antimony, bismuth, copper, gold, and silver. This is then subjected to electrolytic refining to comprehensively recover the valuable metals and improve the company's overall recovery efficiency. However, existing lead electrolysis technology, for crude lead with high impurities (especially bismuth), causes impurity ions to enter the electrolyte through the wastewater after washing the anode mud during the electrolysis process, resulting in the precipitation of impurity metals at the cathode, causing the electrolytic lead quality to fall below 99.994%.

[0003] Patent document with announcement number CN213113542U discloses a lead electrolyte rapid impurity removal device, comprising a housing, a metal detector, a feed port and a connecting column installed on the top of the housing, a sealing ring clamped on the top of the connecting column, an electrolytic cell liquid inlet pipe clamped on the top of the sealing ring, an acid pump installed at the bottom of the side of the electrolytic cell liquid inlet pipe, the bottom of the acid pump is connected to a waste liquid concentration tank, the top of the waste liquid concentration tank is connected to the electrolytic cell return pipe, the bottom of the electrolytic cell return pipe is installed with a first valve, the side of the electrolytic cell return pipe is connected to a connecting main pipe, the connecting A second valve is installed on the front of the main pipe, a drive motor and a pull plate are installed on the front of the shell, an electrolytic cell is provided inside the shell, an overflow baffle, an anode plate and a cathode plate are installed inside the electrolytic cell, a sedimentation tank and an installation tank are provided at the bottom of the electrolytic cell, a filter is clamped on the top of the installation tank, and a fan blade is installed at the bottom of the installation tank. This document solves the problem that for crude lead with higher impurities (especially bismuth), impurity ions in the electrolysis process are replenished into the electrolyte through the waste liquid after washing the anode mud, resulting in the precipitation of impurity metals at the cathode, causing the quality of the electrolytic lead to be lower than 99.994%.

[0004] However, the above patent documents still have the following deficiencies in practical application:

[0005] The equipment is large in size and has a complex structure. The large size of the equipment easily affects the workers' operation and is inconvenient to use in small factories. Summary of the Invention

[0006] The object of the present invention is to provide a lead electrolyte rapid impurity removal device to solve the problems raised in the above background technology.

[0007] To achieve the above object, the present invention provides the following technical solutions:

[0008] A device for rapidly removing impurities from lead electrolyte comprises a shell, wherein a slot is provided at the left and right edges of the upper end face of the shell, a plug post is fixedly connected to the bottom of the inner cavity of the slot, a mounting bracket is slidably connected to the inner cavity of the slot, an anode sheet and a cathode sheet are respectively mounted on the outside of the mounting bracket, the left and right end faces of the shell are fixedly connected to a fixing cylinder, the lower end face of the fixing cylinder is fixedly connected to a conduit, the end of the conduit away from the fixing cylinder is fixedly connected to the shell, and a transmission mechanism is provided on the front end face of the shell.

[0009] Furthermore, the lower end face of the shell is fixedly connected to a supporting foot, the lower end face of the shell is provided with a drain port, the inner cavity of the drain port is provided with a valve, the outside of the plug is provided with a power-carrying piece, the inside of the mounting frame is provided with a carbon brush, and the plug is energized by the external power-carrying piece and the carbon brush to the external anode and cathode plates of the mounting frame.

[0010] Furthermore, the front end surface of the shell is slidably connected to a sealing cover, the rear end surface of the sealing cover is fixedly connected to a scraper, the inner cavity of the shell is provided with an electrolytic cell, and the front end surface of the sealing cover is fixedly connected to a handle.

[0011] Furthermore, a purification cylinder is slidably connected to the interior of the upper end surface of the fixed cylinder, a liquid inlet is provided on the upper end surface of the purification cylinder, a filter screen is evenly fixedly connected to the inner cavity of the purification cylinder, and filter mesh holes are evenly provided on the lower end surface of the purification cylinder.

[0012] Furthermore, the transmission mechanism includes a worm, a fixed block, a support column, a driving bevel gear, a driven bevel gear and a worm wheel. A driving motor is provided inside the front end face of the shell. The driving motor is fixedly connected to the worm through the output shaft, and the worm is meshedly connected to the worm wheel.

[0013] Furthermore, a support column is fixedly connected inside the worm gear, a fixed block is evenly fixedly connected to the front end surface of the shell, the support column is rotatably connected inside the fixed block through a bearing, and both ends of the support column are fixedly connected to a transmission bevel gear, and the transmission bevel gear is meshed with a driven bevel gear.

[0014] Furthermore, the rear end face of the driven bevel gear is fixedly connected to a transmission column, and the transmission column is rotatably connected to the inside of the shell through a bearing. The transmission column is located at one end of the inner cavity of the shell and is evenly fixedly connected to a spoiler frame. The inner cavity of the spoiler frame is evenly fixedly connected to a fixed column, and the outside of the fixed column is rotatably connected to a stirring blade.

[0015] Compared with the prior art, the present invention has the following beneficial effects:

[0016] 1. In the present invention, personnel use the liquid inlet to add electrolyte into the inner cavity of the purification cylinder, and use the filter plate in the inner cavity of the purification cylinder to filter the electrolyte to purify the impurity metal ions inside. The purified and filtered electrolyte is discharged into the inner cavity of the filter cover through the fixed cylinder and the conduit, and then the filter cover is used to filter the internal impurities for a second time, thereby greatly reducing the content of impurities inside the electrolyte. In addition, the electrolytic waste liquid can be discharged through the drain port, and at the same time, the electrolytic waste liquid is discharged into the inner cavity of the purification cylinder through the liquid inlet through the delivery pipe, and then the electrolytic waste liquid is purified and filtered by the purification cylinder, and then discharged into the inner cavity of the filter cover through the conduit, so that the electrolyte can be circulated and filtered for use. After the electrolyte is circulated and filtered for a fixed number of times, the personnel removes the purification cylinder from the inner cavity of the fixed cylinder for cleaning and replacement, thereby making the impurity removal equipment convenient to use. Then, the plug is used to energize the anode and cathode plates outside the mounting frame through the external power supply plate and the carbon brush, and the anode and cathode plates energize the electrolyte in the inner cavity of the electrolytic cell.

[0017] 2. In the present invention, when using the electrolyte, personnel start the driving motor to rotate the worm, and make the worm drive the worm gear to rotate the support column to drive the transmission bevel gear, and at the same time make the transmission bevel gear drive the driven bevel gear to drive the transmission column, and then make the transmission column drive the spoiler to stir and flip the electrolyte in the inner cavity of the electrolytic cell, and at the same time use the stirring blades in the inner cavity of the spoiler to increase the efficiency of the electrolyte flipping and stirring, thereby avoiding the precipitation of the chemical liquid in the electrolyte to affect the effect of the electrolyte, and when the electrolyte is used for a long time, personnel use the drain port in conjunction with the water pump and the pipeline to extract the electrolyte from the inner cavity of the electrolytic cell, and then cooperate with the liquid inlet to discharge it into the inner cavity of the fixed cylinder for filtration and purification, and discharge it into the inner cavity of the filter mesh cover through the conduit, thereby effectively improving the service life of the electrolyte. BRIEF DESCRIPTION OF THE DRAWINGS

[0018] Figure 1 This is a schematic diagram of the main three-dimensional structure of the present invention;

[0019] Figure 2 This is a bottom-up perspective structural diagram of the present invention;

[0020] Figure 3 This is a schematic diagram of a partial cross-sectional structure of the housing of the present invention;

[0021] Figure 4 This is a schematic diagram of a half-section structure of the housing of the present invention;

[0022] In the accompanying drawings, the components represented by the reference numerals are as follows:

[0023] In the figure: 1. Housing; 2. Sealing cover; 3. Handle; 4. Slot; 5. Mounting bracket; 6. Fixing cylinder; 7. Liquid inlet; 8. Insertion column; 9. Anode plate; 10. Transmission mechanism; 101. Worm; 102. Fixing block; 103. Support column; 104. Transmission bevel gear; 105. Driven bevel gear; 106. Worm gear; 11. Drain port; 12. Support foot; 13. Conduit; 14. Filter screen; 15. Purification cylinder; 16. Filter screen plate; 17. Transmission column; 18. Turbine frame; 19. Fixing column; 20. Stirring blade; 21. Cathode plate; 22. Electrolytic cell DETAILED DESCRIPTION

[0024] The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, rather than all the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative work are within the scope of protection of the present invention.

[0025] To facilitate understanding of the present invention, the present invention will be described more fully below with reference to the accompanying drawings. The drawings illustrate several embodiments of the present invention. However, the present invention may be implemented in many different forms and is not limited to the embodiments described herein. Rather, these embodiments are provided to provide a more thorough and comprehensive understanding of the present invention.

[0026] See also Figure 1-4 , the present invention provides a technical solution:

[0027] A device for rapidly removing impurities from a lead electrolyte comprises a housing 1. A card slot 4 is provided at the left and right edges of the upper end face of the housing 1. A plug post 8 is fixedly connected to the bottom of the inner cavity of the card slot 4. A mounting bracket 5 is slidably connected to the inner cavity of the card slot 4. An anode plate 9 and a cathode plate 21 are respectively mounted on the outside of the mounting bracket 5. A fixed cylinder 6 is fixedly connected to the left and right end faces of the housing 1. A conduit 13 is fixedly connected to the lower end face of the fixed cylinder 6. The end of the conduit 13 away from the fixed cylinder 6 is fixedly connected to the housing 1. A transmission mechanism 10 is provided on the front end face of the housing 1.

[0028] In this embodiment, the lower end face of the outer shell 1 is fixedly connected to a supporting foot 12, the lower end face of the outer shell 1 is provided with a drain port 11, the inner cavity of the drain port 11 is provided with a valve, the outside of the plug post 8 is provided with a power-carrying plate, and the inside of the mounting frame 5 is provided with a carbon brush. The plug post 8 energizes the external anode plate 9 and the cathode plate 21 of the mounting frame 5 through the external power-carrying plate and the carbon brush. The electrolyte is added into the inner cavity of the purification cylinder 15 by personnel through the liquid inlet 7, and the electrolyte is filtered and purified by the filter plate 16 in the inner cavity of the purification cylinder 15 to remove the impurity metal ions inside. The purified and filtered electrolyte is discharged into the inner cavity of the filter screen 14 through the fixed cylinder 6 in conjunction with the conduit 13, and then the filter screen 14 is used to filter the internal impurities for a second time, thereby greatly reducing the content of impurities inside the electrolyte, and the electrolytic waste liquid can be discharged through the drain port 11, and at the same time, the electrolytic waste liquid is discharged into the inner cavity of the purification cylinder 15 through the liquid inlet 7 by the conveying pipeline, and then the electrolytic waste liquid is purified and filtered by the purification cylinder 15, and then discharged through the conduit 13. Into the inner cavity of the filter screen cover 14, so that the electrolyte can be circulated and filtered for use, and after the electrolyte is circulated and filtered for a fixed number of times, the personnel removes the purification cylinder 15 from the inner cavity of the fixed cylinder 6 for cleaning and replacement, thereby making the de-impurity equipment convenient to use, and then the plug 8 is used to energize the anode plate 9 and the cathode plate 21 outside the mounting frame 5 through the external power-on plate in conjunction with the carbon brush, and the anode plate 9 and the cathode plate 21 are used to energize the electrolyte in the inner cavity of the electrolytic cell 22, the front end face of the shell 1 is slidably connected to the sealing cover 2, the rear end face of the sealing cover 2 is fixedly connected to the scraper, the inner cavity of the shell 1 is provided with an electrolytic cell 22, and the front end face of the sealing cover 2 is fixedly connected to the handle 3.

[0029] In this embodiment, the upper end surface of the fixed cylinder 6 is slidably connected to the purification cylinder 15, the upper end surface of the purification cylinder 15 is provided with a liquid inlet 7, the inner cavity of the purification cylinder 15 is evenly fixedly connected with a filter screen plate 16, and the lower end surface of the purification cylinder 15 is evenly provided with filter mesh holes. When using the electrolyte, the personnel starts the driving motor to rotate the worm 101, and the worm 101 drives the worm gear 106 to rotate the support column 103 to drive the transmission bevel gear 104, and at the same time, the transmission bevel gear 104 drives the driven bevel gear 105 to drive the transmission column 17, and then the transmission column 17 drives the spoiler 18 to stir and flip the electrolyte in the inner cavity of the electrolytic cell 22, and at the same time, the stirring blades 20 in the inner cavity of the spoiler 18 are used to increase the efficiency of the electrolyte flipping and stirring, thereby preventing the chemical liquid in the electrolyte from precipitating and affecting the effect of the electrolyte. When the electrolyte is used for a long time, the personnel use the drain port 11 to cooperate with the water pump and the pipeline to extract the electrolyte from the inner cavity of the electrolytic cell 22, and then cooperate with the liquid inlet 7 to discharge it into the inner cavity of the fixed cylinder 6 for filtration and purification, and discharge it into the inner cavity of the filter screen cover 14 through the conduit 13, thereby effectively improving the service life of the electrolyte.

[0030] In this embodiment, the transmission mechanism 10 includes a worm 101, a fixed block 102, a support column 103, a transmission bevel gear 104, a driven bevel gear 105 and a worm wheel 106. A driving motor is provided inside the front end surface of the housing 1. The driving motor is fixedly connected to the worm 101 through the output shaft. The worm 101 is meshed with the worm wheel 106. The worm wheel 106 is fixedly connected to the support column 103. The front end surface of the housing 1 is evenly fixedly connected to the fixed block 102. The fixed block 102 rotates inside through the bearing. It is connected to a support column 103, both ends of the support column 103 are fixedly connected to a transmission bevel gear 104, the transmission bevel gear 104 is meshed with a driven bevel gear 105, the rear end face of the driven bevel gear 105 is fixedly connected to a transmission column 17, and the transmission column 17 is rotatably connected to the inside of the shell 1 through a bearing, the transmission column 17 is located at one end of the inner cavity of the shell 1 and is evenly fixedly connected to a spoiler frame 18, the inner cavity of the spoiler frame 18 is evenly fixedly connected to a fixed column 19, and the outside of the fixed column 19 is rotatably connected to a stirring blade 20.

[0031] The working principle of the present invention is as follows: personnel use the liquid inlet 7 to add electrolyte into the inner cavity of the purification cylinder 15, and use the filter plate 16 in the inner cavity of the purification cylinder 15 to filter the electrolyte and purify the impurity metal ions inside. The purified and filtered electrolyte is discharged into the inner cavity of the filter cover 14 through the fixed cylinder 6 and the conduit 13, and then the filter cover 14 is used to filter the internal impurities for the second time, thereby greatly reducing the content of impurities inside the electrolyte, and the electrolytic waste liquid can be discharged through the drain port 11, and at the same time, the electrolytic waste liquid is discharged into the inner cavity of the purification cylinder 15 through the conveying pipe through the liquid inlet 7, and then the electrolytic waste liquid is purified and filtered by the purification cylinder 15, and then discharged into the inner cavity of the filter cover 14 through the conduit 13, so that the electrolyte can be circulated and filtered for use, and after the electrolyte is circulated and filtered for a fixed number of times, the personnel removes the purification cylinder 15 from the inner cavity of the fixed cylinder 6 for cleaning and replacement, thereby making the decontamination equipment convenient to use, and then the plug 8 is installed through the external power sheet and the carbon brush. The anode plate 9 and the cathode plate 21 outside the frame 5 are energized, and the anode plate 9 and the cathode plate 21 are energized for the electrolyte in the inner cavity of the electrolytic cell 22. When the electrolyte is used, the personnel start the drive motor to rotate the worm 101, and the worm 101 drives the worm gear 106 to rotate the support column 103 to drive the transmission bevel gear 104, and at the same time, the transmission bevel gear 104 drives the driven bevel gear 105 to drive the transmission column 17, and then the transmission column 17 drives the spoiler frame 18 to stir the electrolyte in the inner cavity of the electrolytic cell 22. At the same time, the stirring blades 20 in the inner cavity of the spoiler 18 are used to increase the efficiency of the electrolyte flipping and stirring, thereby avoiding the precipitation of the chemical liquid in the electrolyte and affecting the effect of the electrolyte. When the electrolyte is used for a long time, the personnel use the drain port 11 to cooperate with the water pump and the pipeline to extract the electrolyte from the inner cavity of the electrolytic cell 22, and then cooperate with the liquid inlet 7 to discharge it into the inner cavity of the fixed cylinder 6 for filtration and purification, and discharge it into the inner cavity of the filter screen cover 14 through the conduit 13, thereby effectively improving the service life of the electrolyte.

[0032] While embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions, and variations may be made to these embodiments without departing from the principles and spirit of the invention, and that the scope of the invention is defined by the appended claims and their equivalents.

Claims

1. A lead electrolyte rapid impurity removal device, comprising a housing (1), characterized in that: The left and right edges of the upper end face of the shell (1) are both provided with a card slot (4), the bottom of the inner cavity of the card slot (4) is fixedly connected to a plug post (8), the inner cavity of the card slot (4) is slidably connected to a mounting frame (5), and the outside of the mounting frame (5) is respectively installed with an anode plate (9) and a cathode plate (21), the left and right end faces of the shell (1) are both fixedly connected to a fixed cylinder (6), the lower end face of the fixed cylinder (6) is fixedly connected to a conduit (13), the end of the conduit (13) away from the fixed cylinder (6) is fixedly connected to the shell (1), and the front end face of the shell (1) is provided with a transmission mechanism (10); The upper end surface of the fixed cylinder (6) is slidably connected to a purification cylinder (15), the upper end surface of the purification cylinder (15) is provided with a liquid inlet (7), the inner cavity of the purification cylinder (15) is evenly fixedly connected to a filter screen plate (16), and the lower end surface of the purification cylinder (15) is evenly provided with filter mesh holes; The transmission mechanism (10) comprises a worm (101), a fixed block (102), a support column (103), a driving bevel gear (104), a driven bevel gear (105) and a worm wheel (106). A driving motor is provided inside the front end surface of the housing (1). The driving motor is fixedly connected to the worm (101) via an output shaft. The worm (101) is meshedly connected to the worm wheel (106). The worm wheel (106) is fixedly connected to the support column (103). The front end surface of the housing (1) is evenly fixedly connected to the fixed block (102). The fixed block (102) is rotatably connected to the inside via a bearing. A support column (103) is provided, both ends of the support column (103) are fixedly connected to a transmission bevel gear (104), the transmission bevel gear (104) is meshedly connected to a driven bevel gear (105), the rear end face of the driven bevel gear (105) is fixedly connected to a transmission column (17), and the transmission column (17) is rotatably connected to the inside of the housing (1) through a bearing, the transmission column (17) is located at one end of the inner cavity of the housing (1) and is evenly fixedly connected to a spoiler frame (18), the inner cavity of the spoiler frame (18) is evenly fixedly connected to a fixed column (19), and the fixed column (19) is rotatably connected to a stirring blade (20) on the outside.

2. The lead electrolyte rapid impurity removal device according to claim 1, characterized in that: The lower end surface of the shell (1) is fixedly connected to a supporting foot (12), the lower end surface of the shell (1) is provided with a drain port (11), the inner cavity of the drain port (11) is provided with a valve, the outside of the plug post (8) is provided with a power supply plate, the inside of the mounting frame (5) is provided with a carbon brush, and the plug post (8) is used to energize the external anode plate (9) and cathode plate (21) of the mounting frame (5) through the external power supply plate and the carbon brush.

3. The lead electrolyte rapid impurity removal device according to claim 1, characterized in that: The front end surface of the housing (1) is slidably connected to a sealing cover (2), the rear end surface of the sealing cover (2) is fixedly connected to a scraper, an electrolytic cell (22) is provided in the inner cavity of the housing (1), and the front end surface of the sealing cover (2) is fixedly connected to a handle (3).

Citation Information

Patent Citations

  • Rapid impurity removal device for lead electrolyte

    CN213113542U

  • Multi-station electrolytic copper device

    CN210886261U

  • Circulating device for analyzing and controlling deposition electrolyte

    CN218880071U