Aqueous ink wetting and leveling agent composition, and method of making and using same
By combining acetylenic glycol ether-modified polysiloxane, isoallyl butyl polyether-modified heptamethyltrisiloxane, and biosurfactants, the wetting and leveling problems of water-based inks on non-absorbent substrates were solved, achieving efficient printing effects and improved printing quality.
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- GUANGDONG JINLONGYUAN PRINTING MATERIAL CO LTD
- Filing Date
- 2024-02-02
- Publication Date
- 2026-05-05
AI Technical Summary
Water-based inks have poor wetting and leveling effects on non-absorbent substrates, and are prone to surface defects such as floating color, blooming, and pinholes. Existing silicone wetting and leveling agents have insufficient dynamic surface tension balancing ability during high-speed printing.
A ternary composition consisting of acetylation glycol ether-modified polysiloxane, isoallyl butyl polyether-modified heptamethyltrisiloxane, and a biosurfactant is used to improve wetting and leveling properties by rapidly balancing the dynamic surface tension of the aqueous system.
It enables rapid wetting and leveling of water-based inks on low-energy surfaces, improving printing quality, reducing the risk of bubbling, enhancing pigment dispersion performance, and achieving high smoothness and gloss.
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Figure CN118048067B_ABST
Abstract
Description
Technical Field
[0001] This invention belongs to the field of fine chemical technology, specifically relating to a water-based ink wetting and leveling agent composition, its preparation method, and its application. Background Technology
[0002] Water-based inks primarily use water as a diluent, resulting in high surface tension, difficulty wetting on non-absorbent substrates, especially low surface energy thin film substrates (PP, PE, PET), and a tendency to develop surface defects such as pinholes, edge shrinkage, orange peel, and floating color during film formation. During the production and use of water-based inks, the circulation of pigments within the system leads to floating color and color blooming issues. Different pigments interact due to their varying fluidities. With these flows and turbulence within the coating film, different pigments, due to differences in particle size and density, severely separate in the eddies, resulting in distinct patterns due to color variations. This is particularly noticeable in light gray water-based inks. Floating color refers to the horizontal, layered separation of pigments in the wet film of water-based inks; color blooming refers to the vertical separation of pigments in the wet film, typically appearing as streaks or honeycomb patterns. Some pigments may concentrate at the hexagonal boundaries of the Bénard vortex, making the hexagonal arrangement clearly visible.
[0003] There are many reasons for floating and mottling in water-based inks, including differences in pigment particle size and density, variations in the hydrophilicity and charge of different substances, and the compatibility between resin and pigment. Smaller pigment particles tend to adsorb much more resin and solvent than larger pigment particles, generally resulting in a lower density for smaller particles and a higher density for larger particles. This increased density of larger pigment particles causes them to sink, while smaller particles float, thus creating the floating phenomenon in printing inks.
[0004] To overcome the problem of poor wetting and leveling of water-based inks on non-absorbent substrates, especially low surface energy film substrates (PP, PE, PET), and to obtain a smooth and clear pattern after the wet film flows and dries, the addition of wetting and leveling agents is absolutely necessary. This is because without these wetting and leveling agents, it would be impossible to obtain a continuous, clear and smooth surface paint film.
[0005] Among the many types of leveling agents, silicone wetting and leveling agents are the most widely used water-based coating and ink wetting and leveling agents because they have the ability to efficiently and quickly balance surface tension, solve paint film defects caused by Bénard vortex, and also have the ability to wet and disperse pigments and fillers as well as certain waterproof properties.
[0006] The related technology discloses the preparation of a polyether polyester modified silicone leveling agent with a number average molecular weight of 100315 by stirring and reacting side-chain hydrogen-containing silicone oil with allyl polyether under methyl isobutyl ketone solvent conditions. However, this method uses methyl isobutyl ketone as a solvent, and the molecular weight of the silicone leveling agent with this structure exceeds 100,000, which greatly limits its migration ability in coating and ink systems. This results in a very weak ability to dynamically balance surface tension, and it does not have the ability to quickly reduce the surface tension of the system during high-speed printing of water-based inks or high-speed spraying of coatings.
[0007] The effectiveness of silicone wetting and leveling agents in water-based ink printing on non-absorbent substrates depends on their ability to reduce the static surface tension of the system and their ability to quickly balance the dynamic surface tension (dynamic surface activity). Specifically, the molecular weight of the polysiloxane, the type, size, position, and number of organic groups, and the linkage method of the organic-modified polysiloxane all affect its effectiveness.
[0008] Therefore, how to develop water-based ink wetting and leveling agents with low surface tension and high dynamic surface activity for use in low-energy surface printing through technological innovation and compatibility technology application, and apply them in water-based inks, water-based coatings, water-based varnishes and other systems, is an urgent problem to be solved. Summary of the Invention
[0009] This invention proposes a water-based ink wetting and leveling agent composition, its preparation method, and its application, in order to solve one or more technical problems existing in the prior art, and at least provide a beneficial option or create conditions.
[0010] To overcome the above-mentioned technical problems, a first aspect of the present invention is to provide a water-based ink wetting and leveling agent composition.
[0011] The present invention also provides a method for preparing the above-mentioned water-based ink wetting and leveling agent composition.
[0012] The present invention also provides the application of the above-described water-based ink wetting and leveling agent composition.
[0013] The first aspect of the present invention provides a water-based ink wetting and leveling agent composition, the raw materials of which include acetylenic glycol ether-modified polysiloxane, isoallyl butyl polyether-modified heptamethyltrisiloxane and biosurfactant;
[0014] The acetylenic diol ether-modified polysiloxane has the following structure:
[0015]
[0016] R has the following structure:
[0017]
[0018] Wherein, R1 is -CH3 or -CH2CH3, n is 5 to 60, m is 8 to 10, and k is 10 to 16;
[0019] The isobutyl polyether-modified heptamethyltrisiloxane has the following structure:
[0020]
[0021] Where Y is -CH2C(CH3)2(OCH(CH3)CH2)e(OCH2CH2)fOCH3, e is 0~3, and f is 6~10.
[0022] The biosurfactant includes one or more of rhamnolipids, sophorolipids, and lipopeptides.
[0023] According to some embodiments of the present invention, the raw materials for preparation include 30 to 70 parts by weight of acetylation diol ether-modified polysiloxane.
[0024] Preferably, the raw materials for preparation include 40-50 parts by weight of acetylation diol ether-modified polysiloxane.
[0025] According to some embodiments of the present invention, the raw materials for preparation include 20 to 50 parts by weight of isobutyl polyether modified heptamethyltrisiloxane.
[0026] Preferably, the raw materials for preparation include 30-40 parts by weight of isobutyl polyether modified heptamethyltrisiloxane.
[0027] In some embodiments of the invention, the raw materials for preparation include 10 to 30 parts by weight of a biosurfactant.
[0028] Preferably, the raw materials for preparation include 15 to 25 parts by weight of a biosurfactant.
[0029] A second aspect of the present invention provides a method for preparing the above-mentioned water-based ink wetting and leveling agent composition, wherein the acetylacetonate diol ether-modified polysiloxane, isoallyl butyl polyether-modified heptamethyltrisiloxane, and a biosurfactant are mixed uniformly to obtain the water-based ink wetting and leveling agent of the present invention.
[0030] According to some embodiments of the present invention, the mixing is carried out at room temperature of 10°C to 40°C.
[0031] According to some embodiments of the present invention, the reaction is subjected to stirring at a speed of 100 rpm to 300 rpm.
[0032] According to some embodiments of the present invention, the stirring time during the reaction process is 0.5h to 1h.
[0033] A third aspect of the present invention provides the application of the above-described water-based ink wetting and leveling agent composition in water-based inks.
[0034] According to some embodiments of the present invention, the water-based ink includes rosin-based water-based ink, acrylic-based water-based ink, polyurethane-based water-based ink color ink, and water-based varnish.
[0035] According to some embodiments of the present invention, the water-based ink wetting and leveling agent can be used in different stages such as pigment grinding, ink preparation and post-printing addition.
[0036] When using the water-based ink wetting and leveling agent of the present invention, the addition amount is 0.1% to 1% of the mass of the water-based ink.
[0037] Compared with the prior art, the above-described technical solution of the present invention has at least the following technical effects or advantages:
[0038] The water-based ink wetting and leveling agent composition of the present invention has at least the following beneficial effects:
[0039] (1) This invention uses a ternary synergistic effect of a linear ABC structure acetylenic diol ether single-end modified polysiloxane with rapid balancing of dynamic surface tension in aqueous systems, an isoallyl butyl polyether modified heptamethyltrisiloxane surfactant with high efficiency in reducing static surface tension in aqueous systems, and a biosurfactant with high system compatibility as a highly efficient wetting and leveling agent for water-based inks. An addition of 0.3% can achieve the continuous low surface tension (high dynamic surface activity) of water-based inks when printing rapidly on low-energy surfaces, thus achieving excellent surface wetting and leveling performance on film substrates and obtaining high-quality printing.
[0040] (2) The present invention uses linear ABC structure acetylenic diol ether with appropriate end-capping structure to modify polysiloxane at one end and isoallyl butyl polyether modified heptamethyltrisiloxane surfactant with EO / PO ratio to achieve high surface activity while having low self-foaming stability, which can effectively reduce the foaming problem of water-based inks, while improving the smoothness and water resistance of the coating film.
[0041] (3) The present invention uses isoallyl polyether modified heptamethyltrisiloxane with large steric hindrance as the main material of super wetting agent for water-based ink. Compared with conventional allyl polyether modified heptamethyltrisiloxane, it has higher pH stability and can greatly avoid the failure of wetting and leveling agents in water-based ink systems.
[0042] (4) This invention employs a ternary synergistic effect of a linear ABC structure acetylenic diol ether single-end modified polysiloxane with rapid balancing of dynamic surface tension in water-based systems, an isobutyl polyether modified heptamethyltrisiloxane surfactant with high efficiency in reducing static surface tension in water-based systems, and a biosurfactant with high system compatibility. This effectively improves the dispersion performance of each pigment and filler, greatly reduces the defects of Bénard vortex paint film caused by differences in density and surface properties between pigments and fillers in water-based ink systems, such as floating color, blooming, and pinholes, and obtains printed materials with high smoothness. Attached Figure Description
[0043] Figure 1 Examples and Comparative Dynamic Surface Tension Tests
[0044] Figure 2 wettability test results
[0045] Figure 3 Foam stability test results Detailed Implementation
[0046] The present invention will be specifically described below through embodiments to facilitate understanding of the present invention by those skilled in the art. It is important to note that the embodiments are only for further illustration of the present invention and should not be construed as limiting the scope of protection of the present invention. Non-essential improvements and adjustments made to the present invention by those skilled in the art based on the above-described invention should still fall within the scope of protection of the present invention. In addition, the raw materials mentioned below that are not described in detail are all commercially available products, and the process steps or preparation methods not mentioned in detail are all process steps or preparation methods known to those skilled in the art.
[0047] The following are the main raw materials used in the examples and comparative examples and their manufacturers: the acetylenic diol ether-modified polysiloxane was purchased from the Chemical Research Institute of Guangdong Academy of Sciences; the isobutyl polyether-modified heptamethyltrisiloxane was purchased from Guangdong Jinbo Chemical Co., Ltd.
[0048] Example 1
[0049] This embodiment prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0050] In a 1000 mL glass beaker, 320 g of acetylacetonate diol ether-modified polysiloxane ED-1007, 280 g of isobutyl polyether-modified heptamethyltrisiloxane SW-316, and 200 g of rhamnolipid (50% solid content) were added respectively, and stirred at 100 r / min for 1 h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0051] The structural formula of the acetylenic diol ether-modified polysiloxane is shown below:
[0052]
[0053] The structural formula for R is:
[0054]
[0055] R1 is -CH3, n is 5, m is 8, k is 14;
[0056] The structure of isobutyl polyether modified heptamethyltrisiloxane is shown in the following formula:
[0057]
[0058] Wherein, Y is -CH2C(CH3)2(OCH(CH3)CH2)3(OCH2CH2)10OCH3.
[0059] Example 2
[0060] This embodiment prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0061] In a 1000mL glass beaker, 400g of acetylacetonate diol ether-modified polysiloxane ED-1025, 240g of isobutyl polyether-modified heptamethyltrisiloxane SW-370, and 160g of sophorolipid (50% solid content) were added respectively, and stirred at 200r / min for 1h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0062] The structural formula of the acetylenic diol ether-modified polysiloxane is shown below:
[0063]
[0064] The structural formula for R is:
[0065]
[0066] R1 is -CH2CH3, n is 35, m is 9, k is 10;
[0067] The structure of isobutyl polyether modified heptamethyltrisiloxane is shown in the following formula:
[0068]
[0069] Wherein, Y is -CH2C(CH3)2(OCH2CH2)6OCH3.
[0070] Example 3
[0071] This embodiment prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0072] In a 1000 mL glass beaker, 360 g of acetylacetonate diol ether-modified polysiloxane ED-1013, 320 g of isobutyl polyether-modified heptamethyltrisiloxane SW-385, and 120 g of lipopeptide (100% solid content) were added respectively, and stirred at 300 r / min for 0.5 h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0073] The structural formula of the acetylenic diol ether-modified polysiloxane is shown below:
[0074]
[0075] The structural formula for R is:
[0076]
[0077] R1 is -CH3, n is 60, m is 10, k is 16;
[0078] The structure of isobutyl polyether modified heptamethyltrisiloxane is shown in the following formula:
[0079]
[0080] Wherein, Y is -CH2C(CH3)2(OCH(CH3)CH2)2(OCH2CH2)8OCH3.
[0081] Comparative Example 1
[0082] This comparative example prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0083] In a 1000 mL glass beaker, 320 g of acetylacetonate diol ether-modified polysiloxane ED-1007, 280 g of allyl polyether-modified heptamethyltrisiloxane, and 200 g of rhamnolipid (50% solid content) were added respectively, and stirred at 100 r / min for 1 h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0084] The structural formula of the acetylenic diol ether-modified polysiloxane is shown below:
[0085]
[0086] The structural formula for R is:
[0087]
[0088] R1 is -CH3, n is 5, m is 8, k is 14;
[0089] The structure of allyl polyether-modified heptamethyltrisiloxane is shown in the following formula:
[0090]
[0091] Wherein, Y is -(CH2)3(OCH(CH3)CH2)3(OCH2CH2)10OCH3.
[0092] Comparative Example 2
[0093] This comparative example prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0094] In a 1000 mL glass beaker, 320 g of terminal polyether modified polysiloxane, 280 g of isobutyl polyether modified heptamethyltrisiloxane SW-316 and 200 g of rhamnolipid (solid content 50%) were added respectively, and stirred at 100 r / min for 1 h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0095] The structural formula of the polyether-terminated polysiloxane is shown below:
[0096]
[0097] R is -(CH2)3(OCH(CH3)CH2)3(OCH2CH2)10OCH3, n=5;
[0098] The structure of isobutyl polyether modified heptamethyltrisiloxane is shown in the following formula:
[0099]
[0100] Wherein, Y is -CH2C(CH3)2(OCH(CH3)CH2)3(OCH2CH2)10OCH3.
[0101] Comparative Example 3
[0102] This comparative example prepared a water-based ink wetting and leveling agent composition, and the specific process is as follows:
[0103] In a 1000 mL glass beaker, 400 g of acetylacetonate diol ether-modified polysiloxane ED-1025 and 240 g of isobutyl polyether-modified heptamethyltrisiloxane SW-370 were added respectively, and stirred at 200 r / min for 1 h at room temperature to obtain the water-based ink wetting and leveling agent composition of the present invention.
[0104] The structural formula of the acetylenic diol ether-modified polysiloxane is shown below:
[0105]
[0106] The structural formula for R is:
[0107]
[0108] R1 is -CH2CH3, n is 35, m is 9, k is 10;
[0109] The structure of isobutyl polyether modified heptamethyltrisiloxane is shown in the following formula:
[0110]
[0111] Wherein, Y is -CH2C(CH3)2(OCH2CH2)6OCH3.
[0112] Comparative Example 4
[0113] Allyl polyether-modified heptamethyltrisiloxane is used as a wetting and leveling agent for water-based inks, and its structural formula is shown below:
[0114]
[0115] Wherein, Y is -(CH2)3(OCH(CH3)CH2)3(OCH2CH2)10OCH3.
[0116] Comparative Example 5
[0117] OT-75 was used as the wetting and leveling agent for water-based inks, with a solid content of 75%.
[0118] Comparative Example 6
[0119] JFC was used as the wetting and leveling agent for water-based inks, with a solid content of 100%.
[0120] Performance testing
[0121] The following performance tests were conducted using the water-based ink wetting and leveling agents from Examples 1-3 and Comparative Examples 1-6:
[0122] Add 200g of white acrylic ink and 0.6g of water-based ink wetting and leveling agent to a 500mL beaker, disperse at 300r / min for 5min, adjust the pH to 8.5 with monoethanolamine, stop stirring, and perform the following tests:
[0123] (1) Foaming test: Within 5 minutes, the density of the water-based ink after grinding was tested by weighing.
[0124] (2) Substrate wettability test: A 20μm wire rod was used to scrape and coat the ground water-based ink onto a black PET film substrate. The wet film wettability and the smoothness of the paint film were observed. Based on the overall wetting results of the coating film, the wettability was divided into 10 levels, where level 1 = completely unwettable and level 10 = fully wettable with no paint film defects. At the same time, the dry film gloss and dynamic friction coefficient were tested.
[0125] (3) Leveling test: The leveling instrument was used to determine the 2D flow state of water-based ink on black PET film when the wet film was in a horizontal state. According to the flow results, the leveling was divided into 10 levels, of which level 1 = the worst leveling and level 10 = the best leveling.
[0126] (4) Static surface tension test: Dilute the white water-based ink with deionized water at a mass ratio of 1:1, and test the static surface tension of the diluted water-based ink;
[0127] (5) Dynamic surface tension test: Dilute the white water-based ink with deionized water at a mass ratio of 1:1, and test the dynamic surface tension of the diluted water-based ink at 10ms, 100ms and 400ms.
[0128] (6) Storage stability test: Take 50g of white acrylic water-based ink dispersed with wetting and leveling agent, seal it, put it in a 54℃ oven and keep it at a constant temperature for 14 days, then add 50g of tap water to dilute it, and test the dynamic surface tension of the system and the dynamic surface tension at 10ms, 100ms and 400ms respectively.
[0129] (7) Waterproof test: A 20μm wire rod was used to scrape and coat the ground water-based ink on the black PET film substrate. After the paint film dried naturally, 0.1mL of deionized water was dropped on the surface of the paint film. After 5 minutes, the deionized water was wiped dry. The results were observed whether tap water penetrated into the surface of the coating and whether the coating swelled and fell off.
[0130] (8) Foam stability test: Dilute the wetting and leveling agent with deionized water to prepare a 0.5% aqueous solution of 40g, pour it into a 100mL graduated stoppered cylinder, stopper it, shake it vigorously up and down 20 times, let it stand for 5 minutes, and record the foam height. The higher the foam, the more stable the wetting and leveling agent itself is, which is less conducive to the ease of use of water-based inks.
[0131] Table 1. Comparison of performance test results of wetting and leveling agent samples from various embodiments and comparative examples.
[0132]
[0133] As shown in Table 1, the water-based ink wetting and leveling agents prepared by Examples 1-3 of this invention exhibit excellent wetting and leveling properties, as well as storage stability and pH stability. They effectively improve the dispersion performance of various pigments and fillers, significantly reducing Bénard vortex film defects such as floating color, blooming, and pinholes caused by differences in density and surface properties among pigments and fillers in the water-based ink system. This results in printed materials with high smoothness and a silky feel, effectively enhancing the gloss and water resistance of the printed materials without increasing the foam stability of the system. The overall performance is significantly better than that of Comparative Examples 1-6. Details are as follows:
[0134] The density test results show that the densities of Examples 1-3 range from 0.97 g / mL to 1.01 g / mL, which is comparable to the blank sample. The densities of Comparative Examples 1-6, except for Comparative Example 3, are all less than 0.95 g / mL, demonstrating a certain degree of foam stability. The foam height test data shows that the foam heights of Examples 1-3 are all below 50 mL, slightly lower than the blank sample, while the densities of Comparative Examples 1-6, except for Comparative Example 3, are all greater than 70 mL, indicating significant foam stability.
[0135] The wetting and leveling ability test results show that, compared with the blank sample, the wetting and leveling performance of the water-based inks on PET film substrates was significantly improved after adding 0.3% by weight of Examples 1-3 of this invention. The wetting and leveling ability of Examples 1-3 was significantly better than that of Comparative Examples 1-6. Compared with Example 1, Comparative Example 1 used polyether-modified heptamethyltrisiloxane instead of isoallyl butyl polyether-modified heptamethyltrisiloxane. Although it also achieved certain wetting and leveling properties, its storage stability and pH stability were poor. Polyether-modified heptamethyltrisiloxane was easily hydrolyzed in alkaline systems, causing the correlation energy to disappear rapidly in the system, and it also had foam stability problems. This indicates that the linear ABC structure acetylenic diol ether single-end modified polysiloxane with a suitable end-capping structure and the isoallyl butyl polyether-modified heptamethyltrisiloxane surfactant with an EO / PO ratio used in this invention achieves high surface activity while having low self-foam stability, which can effectively reduce the foaming problem of water-based inks, while improving the smoothness and water resistance of the coating film.
[0136] Comparative Examples 2 and 4-6 did not use ABC-structured acetylacetonate-modified polysiloxane with high dynamic surface activity, so their dynamic surface tension at 400ms reached between 39.1mN / m and 43.1mN / m, which is much higher than the data of Examples 1-3. Consequently, their wetting and leveling properties, water resistance and foam stability also decreased significantly.
[0137] Compared to Example 2, Comparative Example 3, lacking the use of a ternary compound formulation of highly surface-active biosurfactants, exhibited inferior gloss, water resistance, and smoothness compared to Example 2. This indicates that biosurfactants can effectively promote the dispersion and arrangement of water-based ink pigments and fillers in the system, resulting in a highly smooth and dense coating. Furthermore, its 400ms dynamic surface tension was significantly higher than the 27.3mN / m of Example 2, leading to significantly inferior wetting and leveling properties. This demonstrates that biosurfactants, due to their extremely high surface activity and system compatibility, can achieve a synergistic effect with the highly dynamically surface-active ABC-structured acetylenic glycol ether-modified polysiloxane and the isoallyne butyl polyether-modified heptamethyltrisiloxane with super wetting and spreading properties.
[0138] Therefore, this invention employs a ternary synergistic effect of a linear ABC structure acetylenic glycol ether-modified polysiloxane that rapidly balances the dynamic surface tension of the water-based system, an isoallyl butyl polyether-modified heptamethyltrisiloxane surfactant that efficiently reduces the static surface tension of the water-based system, and a biosurfactant with high system compatibility. This synergistic effect serves as a highly efficient wetting and leveling agent for water-based inks, effectively improving the dispersion performance of various pigments and fillers in the water-based ink system. It greatly reduces Bénard vortex film defects such as floating color, blooming, and pinholes caused by differences in density and surface properties among various pigments and fillers in the water-based ink system, resulting in printed materials with high smoothness.
[0139] The present invention has been described in detail above with reference to the embodiments. However, the present invention is not limited to the above embodiments. Within the scope of knowledge possessed by those skilled in the art, various changes can be made without departing from the spirit of the present invention.
Claims
1. A water-based ink wetting and leveling agent composition, characterized in that... The leveling agent composition is made of 30-70 parts by weight of acetylation glycol ether-modified polysiloxane, 20-50 parts by weight of isobutyl polyether-modified heptamethyltrisiloxane and 10-30 parts by weight of biosurfactant. The acetylenic diol ether-modified polysiloxane has the following structure: , R has the following structure: Wherein, R1 is -CH3 or -CH2CH3, n is 5 to 60, m is 8 to 10, and k is 10 to 16; The isobutyl polyether-modified heptamethyltrisiloxane has the following structure: , Wherein, Y is -CH2C(CH3)2(OCH(CH3)CH2)e(OCH2CH2)fOCH3, e is 0~3, and f is 6~10; The biosurfactant includes one or more of rhamnolipids, sophorolipids, and lipopeptides.
2. The water-based ink wetting and leveling agent composition according to claim 1, characterized in that, The application of the water-based ink wetting and leveling agent composition in water-based ink wetting and leveling agents is as follows: the acetylacetonate diol ether-modified polysiloxane, isoallyl butyl polyether-modified heptamethyltrisiloxane and biosurfactant are mixed and stirred evenly to obtain the water-based ink wetting and leveling agent.
3. The application of the water-based ink wetting and leveling agent composition according to claim 2 in water-based ink wetting and leveling agents, characterized in that, The temperature for thorough mixing is 10℃~40℃.
4. The application of the water-based ink wetting and leveling agent composition according to claim 2 in water-based ink wetting and leveling agents, characterized in that, The mixing speed should be 100 rpm to 300 rpm to achieve a uniform consistency.
5. The application of the water-based ink wetting and leveling agent composition according to claim 2 in water-based ink wetting and leveling agents, characterized in that, The mixing and stirring time is 0.5h~1h.
Citation Information
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