A low altitude bird and animal repelling agent and a method of preparing the same
By using a combination of carbomer 940 and promoters such as DL-α-phosphatidylcholine, a highly effective and environmentally friendly bird repellent is formed, solving the problems of unsatisfactory bird repellency and environmental risks in existing technologies, and achieving long-term effective bird repellency and environmental protection.
Patent Information
- Application Number
- CN202411044483.5
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-08-01
- Publication Date
- 2026-01-20
- Estimated Expiration
- 2044-08-01
AI Technical Summary
Existing bird repellents are not very effective, have poor long-term efficacy, and may pose potential risks to the environment and human health.
Using Carbomer 940 as a matrix, combined with methyl anthranilate, camphor oil, capsaicin and other ingredients, and adding promoters such as DL-α-phosphatidylcholine and cholesterol, the drug affects birds through physical and chemical means to form a stable mixture that improves the repelling effect and environmental stability.
It significantly improved the bird-repelling effect, enhanced the stability and durability of the agent, reduced the need for repeated treatments, reduced the impact on the environment, and protected birds and ecological balance.
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Abstract
Description
TECHNICAL FIELD
[0001] The present application relates to the technical field of chemical compositions, in particular to a low-altitude bird and animal repelling agent and a preparation method thereof. BACKGROUND
[0002] With the development of urbanization and industrialization, human activities intersect with natural ecological environments more and more frequently, and birds and some small animals use low-altitude areas, which causes many conflicts with human activities. In particular, in places such as power facilities, airports, farms, and residential areas, the presence of birds and animals not only may cause disturbances to human activities, but also may pose potential threats to the facilities themselves. For example, in power systems, the nesting behavior of birds may cause short circuits or other failures, affecting the stability and safety of power supply.
[0003] Traditional bird repelling methods, such as physical isolation, sound repelling, and chemical agents, have certain limitations. Physical isolation may affect the operating efficiency of the facilities, sound repelling may cause noise pollution to the surrounding environment, and the use of chemical agents may pose risks to the ecological environment and human health. Therefore, it is of great significance to develop a safe, environmentally friendly, and efficient bird repelling agent to solve the above problems.
[0004] Chinese granted patent CN101361495B discloses a bird repelling composition including the following components in total weight percentage: a bird repelling fragrance selected from one or both of methyl anthranilate 1% to 50%, Houttuynia cordata essential oil 0.1% to 5%, or musk T 10% to 21%; an antioxidant selected from one or both of 2,6-di-tert-butyl-p-cresol or sodium ascorbate, 0.02% to 0.5%, and the rest is a slow-release carrier. A bird repelling colloidal mixture is prepared from the bird repelling composition, and the slow-release carrier includes organic or inorganic bases, unsaturated fatty acids, preservatives, emulsifiers, stabilizers, and anti-freezing agents. A bird repelling colloidal suspension is prepared from the bird repelling composition, and the slow-release carrier includes sodium octenyl succinate starch or β-cyclodextrin, and also includes preservatives, emulsifiers, stabilizers, and anti-freezing agents. The invention uses a dilution spraying method to use the smell of the bird repelling fragrance to cause an allergic reaction of the trigeminal nerve of birds and an aversion reaction after pecking, is convenient to use, has good repelling effect, is harmless to birds and plants, and is an environmentally friendly biological agent product. However, the bird repelling composition prepared by the invention has unsatisfactory bird repelling effect and poor long-term efficacy. SUMMARY
[0005] In view of the defects of the prior art, the present application aims to provide a safe, environmentally friendly, and efficient low-altitude bird and animal repelling agent and a preparation method thereof. The agent can effectively repel birds and animals away from human facilities and specific areas without harming them or polluting the environment, reducing disturbances and damages caused by birds and animals.
[0006] To achieve the above-mentioned purposes of the application, the technical solutions adopted by the present application are as follows:
[0007] A preparation method of the low-altitude bird and animal repelling agent is as follows, in terms of weight parts:
[0008] 4-6 parts of carbomer 940 are mixed with 70-90 parts of water, and stirred at room temperature until uniformly dispersed; 15-30 parts of bird repelling spices are added into the solution, and continue to stir; 20-30 parts of geranyl acetate are added into the mixture during the stirring process to ensure sufficient mixing; 1-2 parts of Tween 20 are added, and stirred until the mixture is uniformly emulsified; 0.5-2 parts of a stabilizer, 4-6 parts of an antifreezing agent, and 4-6 parts of a promoting agent are added into the mixture, and stirred and mixed; then, the mixture is cooled at room temperature and left to stand for 12-48 hours; the final mixture is filtered to remove insoluble substances, and the low-altitude bird and animal repelling agent is obtained.
[0009] The bird repelling spices are at least one of methyl anthranilate, camphor oil, dimethylbenzoic acid, cinnamaldehyde, cinnamamide, musk, capsaicin, dihydrocapsaicin, and camphor oil.
[0010] The stabilizer is at least one of sodium benzoate and sodium tripolyphosphate.
[0011] The antifreezing agent is at least one of ethylene glycol and glycerol.
[0012] A preparation method of the promoting agent is as follows, in terms of weight parts:
[0013] S1, 0.5-2 parts of sodium isopropylate, 80-100 parts of ester substances, 5-10 parts of 3,7,16-trihydroxy stigmasta-5-ene, 3-5 parts of polyols, and 3-4 parts of amine compounds are put into a reaction kettle and uniformly mixed to obtain a pretreated product, and the temperature is raised to 100℃ for 1-3 hours of dehydration; the temperature is controlled at 120-150℃, and resorcinol diglycidyl ether is introduced, and the amount of resorcinol diglycidyl ether accounts for 50%-100% of the mass of the pretreated product; curing is performed at 120-140℃ until the curing pressure is 0.013-0.018 MPa, nitrogen is introduced to keep the pressure at 0.15-0.25 MPa, until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 1-3 hours; vacuum is applied at 120-130℃ for 1-3 hours, the temperature is lowered to 60-70℃, and citric acid is added to adjust the pH to 5-6.5 to obtain a post-treated product;
[0014] S2, the post-treated product prepared in step S1 is mixed with 10-20 parts of cholesterol, 2-4 parts of Tween 80, and 3-5 parts of butylated hydroxyanisole at 60-75℃ for 10-50 minutes of stirring to obtain the promoting agent.
[0015] The ester substance is at least one of soybean phospholipid, phosphatidic acid, flaxseed phospholipid, phosphatidylserine, and DL-α-phosphatidylcholine.
[0016] The polyol is at least one of sorbitol, xylitol, mannitol, and erythritol.
[0017] The amine compound is at least one of L-hydroxyproline and N,N-dihydroxyethyl aniline.
[0018] In the preparation method of the low-altitude bird and animal repelling agent, the roles of the respective substances are as follows:
[0019] Carbomer 940 serves as a base, helping to form a stable agent mixture and forming a uniform protective layer after being applied.
[0020] Water serves as a solvent, enabling carbomer 940 to be uniformly dispersed and providing a medium for the mixing of other ingredients.
[0021] Methyl anthranilate serves as one of the active ingredients and can have a repelling effect on birds and animals.
[0022] Camphor oil has a special aroma and can have a repellent effect on birds and animals.
[0023] Capsaicin is a stimulating ingredient and can have a repelling effect on birds and animals through its pungent taste.
[0024] Cinnamamide can have a repelling effect on birds and animals due to its special chemical properties.
[0025] Musk has a strong odor and is often used in repellents to have a repellent effect on animals.
[0026] Geraniol has a special aroma and can enhance the effect of the repellent.
[0027] Tween 20 serves as an emulsifier, helping to form a uniform emulsion and improving the stability and dispersibility of the agent.
[0028] Sodium tripolyphosphate can serve as a chelating agent or stabilizer to improve the physicochemical properties of the agent.
[0029] Ethylene glycol can serve as a solvent or plasticizer to help other ingredients mix better and function better.
[0030] The accelerator contains various ingredients and can enhance the overall repelling effect of the agent and improve its application performance in the environment.
[0031] Sodium isopropyl alcohol serves as a catalyst and can play a key role in the preparation of the accelerator.
[0032] DL-α-phosphatidylcholine, as a phospholipid, can help form stable lipid structures.
[0033] 3,7,16-trihydroxy stigmast-5-ene can be used as an active ingredient to provide specific biological activity.
[0034] Mannitol can be used as a stabilizer or humectant to improve the physical properties of the medicament.
[0035] N,N-dihydroxyethyl aniline can be used as a reducing agent or stabilizer to improve the stability of the medicament.
[0036] Resorcinol diglycidyl ether can be used as a crosslinking agent to enhance the molecular structure of the accelerator.
[0037] Cholesterol can enhance the biological activity and stability of the medicament.
[0038] Tween 80 as an emulsifying agent, improves the dispersibility of the accelerator.
[0039] Butylated hydroxyanisole as an antioxidant, improves the stability of the accelerator.
[0040] The combination of these ingredients aims to create an effective repellent agent that affects birds and animals through physical and chemical means, reducing their stay in undesirable areas.
[0041] Compared with the prior art, it has the following advantages:
[0042] 1) The repellent agent of the present application significantly improves the bird-repelling effect by optimizing the ingredient formula, especially by adding the accelerator, making it more difficult for birds to access the target area, thereby effectively reducing the problem of bird damage.
[0043] 2) The repellent agent of the present application has enhanced stability and durability in natural environments due to the addition of the accelerator, ensuring that the bird-repelling effect is sustained effectively for a longer period of time, reducing the need for repeated treatment and improving maintenance efficiency.
[0044] 3) The formula of the present application avoids the use of harmful chemicals, reducing the potential impact on the environment, while indirectly protecting birds by reducing their contact with power facilities, reflecting the consideration of ecological balance. DETAILED DESCRIPTION
[0045] Main material sources:
[0046] The substances used in the following examples and comparative examples are commercially available.
[0047] Carbomer 940: Guangzhou Bo Feng Chemical Technology Co., Ltd., brand: BF.
[0048] The design idea of the present application is to develop an efficient and long-lasting low-altitude bird and animal repelling agent. Through careful selection and combination of various active ingredients, including carbomer 940, geraniol, tween 20, etc., and a specially designed accelerator containing DL-α-phosphatidylcholine, cholesterol and antioxidants, etc., the penetration, adhesion and oxidation resistance of the agent are improved. This comprehensive formula not only shows a high bird repelling rate in the short term, but also ensures the sustained effectiveness of the repelling effect in the long term through the stability and durability of the accelerator, thereby providing a more reliable and environmentally friendly solution for power facilities and other places that need to repel birds.
[0049] Example 1
[0050] A preparation method of a low-altitude bird and animal repelling agent is as follows:
[0051] Mix 5g carbomer 940 with 80g water and stir at room temperature until evenly dispersed; add 10g methyl o-aminobenzoate, 1g camphor oil, 0.5g capsaicin, 5g cinnamamide, 4g musk to the solution and continue stirring; add 25g geraniol to the mixture during stirring to ensure thorough mixing; add 1.5g tween 20 and stir until the mixture is evenly emulsified; add 1g sodium tripolyphosphate, 5g ethylene glycol and 5g accelerator to the mixture and stir to mix; then cool at room temperature and stand for 24 hours; filter the final mixture to remove insoluble matter to obtain the repelling agent.
[0052] A preparation method of the accelerator is as follows:
[0053] S1, put 1g sodium isopropylate, 90g DL-α-phosphatidylcholine, 8g 3,7,16-trihydroxy stigmasta-5-ene, 4g mannitol, 3g N,N-dihydroxyethyl aniline into a reaction kettle and mix evenly to obtain a pretreated material, heat to 100℃ and dehydrate for 1 hour; control the temperature at 130℃, and pass in resorcinol diglycidyl ether, the amount of which accounts for 80% of the mass of the pretreated material; mature at 130℃ until the maturation pressure is 0.015MPa, pass in nitrogen to maintain the pressure at 0.2MPa until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the maturation time is about 2 hours, vacuumize at 125℃ for 1.5 hours, cool to 70℃, and add citric acid to adjust the pH to 6 to obtain a post-treated material;
[0054] S2, mix the post-treated material prepared in step S1 with 15g cholesterol, 3g tween 80 and 4g butylhydroxyanisole at 70℃ and stir for 30 minutes to obtain the accelerator.
[0055] Example 2
[0056] A preparation method of a low-altitude bird and animal repelling agent is basically the same as that in Embodiment 1, and the only difference is that the preparation method of the accelerator is different.
[0057] The preparation method of the accelerator is as follows:
[0058] S1, 1g of sodium isopropylate, 90g of phosphatidylserine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline are uniformly mixed in a reaction kettle to obtain a pretreated material, the temperature is raised to 100℃, and dehydration is performed for 1 hour; the temperature is controlled at 130℃, and resorcinol diglycidyl ether is introduced, and the amount of resorcinol diglycidyl ether accounts for 80% of the mass of the pretreated material; curing is performed at 130℃ until the curing pressure is 0.015MPa, nitrogen is introduced to maintain the pressure at 0.2MPa, until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours, vacuum is extracted at 125℃ for 1.5 hours, the temperature is lowered to 70℃, citric acid is added to adjust the pH to 6, and a post-treated material is obtained;
[0059] S2, the post-treated material prepared in step S1 is mixed with 15g of cholesterol, 3g of Tween 80, and 4g of butylhydroxyanisole under the condition of 70℃ for 30 minutes to obtain an accelerator.
[0060] Embodiment 3
[0061] A preparation method of a low-altitude bird and animal repelling agent is basically the same as that in Embodiment 1, and the only difference is that the preparation method of the accelerator is different.
[0062] The preparation method of the accelerator is as follows:
[0063] S1, 1g of sodium isopropylate, 90g of phosphatidylserine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline are uniformly mixed in a reaction kettle to obtain a pretreated material, the temperature is raised to 100℃, and dehydration is performed for 1 hour; the temperature is controlled at 130℃, and resorcinol diglycidyl ether is introduced, and the amount of resorcinol diglycidyl ether accounts for 80% of the mass of the pretreated material; curing is performed at 130℃ until the curing pressure is 0.015MPa, nitrogen is introduced to maintain the pressure at 0.2MPa, until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours, vacuum is extracted at 125℃ for 1.5 hours, the temperature is lowered to 70℃, citric acid is added to adjust the pH to 6, and a post-treated material is obtained;
[0064] S2, the post-treated material prepared in step S1 is mixed with 15g of cholesterol, 3g of Tween 80, and 4g of butylhydroxyanisole under the condition of 70℃ for 30 minutes to obtain an accelerator.
[0065] Embodiment 4
[0066] A method for preparing a low-altitude bird and animal repelling agent is substantially the same as that of Example 1, except that the preparation method of the accelerator is different.
[0067] The preparation method of the accelerator is as follows:
[0068] S1, put 1g of sodium isopropylate, 90g of DL-α-phosphatidylcholine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline into a reaction kettle and mix uniformly to obtain a pretreated material, heat to 100℃, and dehydrate for 1 hour; control the temperature at 130℃, and introduce glycidyl methacrylate, the amount of which accounts for 80% of the mass of the pretreated material; cure between 130℃ until the curing pressure is 0.015MPa, introduce nitrogen to keep the pressure at 0.2MPa until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours, vacuumize at 125℃ for 1.5 hours, cool to 70℃, add citric acid to adjust the pH to 6, and obtain a post-treated material;
[0069] S2, mix the post-treated material prepared in step S1 with 15g of cholesterol, 3g of Tween 80, and 4g of butylhydroxyanisole at 70℃ and stir for 30 minutes to obtain an accelerator.
[0070] Example 5
[0071] A method for preparing a low-altitude bird and animal repelling agent is substantially the same as that of Example 1, except that the preparation method of the accelerator is different.
[0072] The preparation method of the accelerator is as follows:
[0073] S1, put 1g of sodium isopropylate, 90g of DL-α-phosphatidylcholine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline into a reaction kettle and mix uniformly to obtain a pretreated material, heat to 100℃, and dehydrate for 1 hour; control the temperature at 130℃, and introduce glycidyl methacrylate, the amount of which accounts for 80% of the mass of the pretreated material; cure between 130℃ until the curing pressure is 0.015MPa, introduce nitrogen to keep the pressure at 0.2MPa until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours, vacuumize at 125℃ for 1.5 hours, cool to 70℃, add citric acid to adjust the pH to 6, and obtain a post-treated material;
[0074] S2, mix the post-treated material prepared in step S1 with 15g of cholesterol, 3g of Tween 80, and 4g of butylhydroxyanisole at 70℃ and stir for 30 minutes to obtain an accelerator.
[0075] Example 6
[0076] A preparation method of a low-altitude bird and animal repelling agent is basically the same as that in Embodiment 1, and the only difference is that the preparation method of the accelerator is different.
[0077] The preparation method of the accelerator is as follows:
[0078] S1, 1g of sodium isopropoxide, 90g of DL-α-phosphatidylcholine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline are uniformly mixed in a reaction kettle to obtain pretreated material, the temperature is raised to 100°C, and dehydration is performed for 1 hour; the temperature is controlled at 130°C, and oxymethylene is introduced, and the amount of oxymethylene accounts for 80% of the mass of the pretreated material; curing is performed at 130°C until the curing pressure is 0.015MPa, nitrogen is introduced to keep the pressure at 0.2MPa until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours; vacuum is extracted at 125°C for 1.5 hours, the temperature is lowered to 70°C, citric acid is added to adjust the pH to 6, and post-treated material is obtained;
[0079] S2, the post-treated material prepared in step S1 is mixed with 15g of cholesterol, 3g of Tween 80, and 4g of butylhydroxyanisole at 70°C for 30 minutes to obtain an accelerator.
[0080] Comparative Example 1
[0081] A preparation method of a low-altitude bird and animal repelling agent is basically the same as that in Embodiment 1, and the only difference is that the preparation method of the accelerator is different.
[0082] The preparation method of the accelerator is as follows:
[0083] 1g of sodium isopropoxide, 90g of DL-α-phosphatidylcholine, 8g of 3,7,16-trihydroxy stigmasta-5-ene, 4g of mannitol, and 3g of N,N-dihydroxyethyl aniline are uniformly mixed in a reaction kettle to obtain pretreated material, the temperature is raised to 100°C, and dehydration is performed for 1 hour; the temperature is controlled at 130°C, and resorcinol diglycidyl ether is introduced, and the amount of resorcinol diglycidyl ether accounts for 80% of the mass of the pretreated material; curing is performed at 130°C until the curing pressure is 0.015MPa, nitrogen is introduced to keep the pressure at 0.2MPa until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is about 2 hours; vacuum is extracted at 125°C for 1.5 hours, the temperature is lowered to 70°C, citric acid is added to adjust the pH to 6, and the accelerator is obtained.
[0084] Comparative Example 2
[0085] A preparation method of a low-altitude bird and animal repelling agent is as follows:
[0086] Mix 5 g Carbomer 940 with 80 g water and stir until evenly dispersed at room temperature; add 10 g methyl anthranilate, 1 g camphor oil, 0.5 g capsaicin, 5 g cinnamamide, 4 g musk to the solution and continue stirring; add 25 g geranium alcohol to the mixture during stirring to ensure thorough mixing; add 1.5 g Tween 20 and stir until the mixture is evenly emulsified; add 1 g sodium tripolyphosphate, 5 g ethylene glycol to the mixture and stir to mix; then cool at room temperature and stand for 24 hours; filter the final mixture to remove insoluble matter to obtain the repellent agent.
[0087] Test Example 1
[0088] Bird Repellent Effect Test
[0089] To evaluate the effectiveness of the repellent agent developed by the present application, the following test procedure was conducted to ensure effective management of bird damage problems on 15KV transmission lines. The test involved repellent agent samples including Examples 1-6 and Comparative Examples 1-2, which were applied to specific power facilities.
[0090] The specific steps of the test procedure are as follows:
[0091] 1. The selected test area is a 15KV voltage level transmission line, each area is 1 kilometer long, and contains 20 power towers. Each tower has one single cross arm and two double cross arms as the main area for birds to rest.
[0092] 2. A specially designed mortar knife is fixed to the front end of a long stick to facilitate the operator to evenly apply the repellent agent to the outer surface of the cross arm. Ensure that the repellent agent is applied to a thickness of 3 mm and covers the entire outer surface of the cross arm to form an effective bird repellent layer.
[0093] 3. Count the number of birds that fall on the test area lines and their accessories, with the counting standard being only the landing of birds, without limiting the time they stay. Before applying the bird repellent, the number of birds that fall in the corresponding area has been recorded for 30 consecutive days as control data for the test. The observation period for each test area is set to 30 days per cycle, and two consecutive cycles are observed to ensure the reliability of the data and the durability of the bird repellent effect.
[0094] After the test is completed, the data is collected and analyzed, and the number of birds that fall before and after the bird repellent is applied is compared to evaluate the effect of the bird repellent.
[0095] The test results are shown in Table 1.
[0096] Table 1
[0097]
[0098] Test Example 2
[0099] The stability of the repellent was evaluated by calculating the decline rate of the bird repellency percentage according to the bird repellency percentage in Test Example 1, to determine the long-term effectiveness of the developed repellent.
[0100] Decline rate = (bird repellency of the first period - bird repellency of the second period) / bird repellency of the first period x 100%
[0101] The test results are shown in Table 2.
[0102] Table 2
[0103]
[0104]
[0105] As can be seen from the data in Table 1 and Table 2, the repellent prepared in Example 1 has good bird repellency, and the bird repellency effect declines at a low rate during long-term use, and has good long-term effectiveness.
[0106] The enhancer added in Example 1. The enhancer enhances the biological activity and environmental stability of the bird repellent through its unique chemical composition and preparation process. The components such as DL-α-phosphatidylcholine, cholesterol, Tween 80 and butylated hydroxyanisole in the enhancer not only improve the permeability and adhesion of the repellent, making it easier to contact the visual organs of birds, but also enhance the antioxidant capacity of the repellent, reducing the negative impact of environmental factors on the effectiveness of the repellent. In addition, the introduction of the enhancer may also improve the uniform distribution of the repellent on the tower surface and enhance its durability, thereby maintaining a high bird repellency effect during long-term use. In contrast, the absence of these key components in Comparative Example 2 results in a lower bird repellency effect and stability than Example 1.
[0107] The DL-α-phosphatidylcholine used in Example 1, as a key ingredient, can have an impact on the visual and nervous systems of birds due to its unique molecular structure and biological activity, thus providing better bird repellent effects. DL-α-phosphatidylcholine is an important phospholipid widely present in biological cell membranes, which has the function of promoting cell membrane fluidity and function. In bird repellent agents, it can enhance the penetration of other active ingredients, helping these ingredients to more effectively contact the sensory organs of birds, especially the eyes. In addition, the antioxidant activity of DL-α-phosphatidylcholine can help improve the stability and durability of the agent, making it less susceptible to decomposition in the natural environment, thus maintaining long-term effectiveness. The amphiphilic nature of this phospholipid (both hydrophilic and lipophilic) can help the uniform distribution and adhesion of the agent components on the tower surface, reducing the loss of the agent due to environmental factors such as wind and rain. In contrast, phosphatidylserine in Example 2 and soybean phospholipid in Example 3, although they also have certain biological activity, may not be as good as DL-α-phosphatidylcholine in terms of penetration, stability, or synergistic effects with other ingredients in the agent. This may be one of the reasons why Example 1 has a higher bird repellent rate and a lower rate of effectiveness decline.
[0108] The resorcinol diglycidyl ether used in Example 1 as an active ingredient, with its unique chemical structure containing two epoxy groups, can provide enhanced effectiveness and stability to the bird repellent agent. This structure can give the agent better penetration, helping the agent components penetrate deep into the visual organs of birds, affecting their visual perception, thus producing a strong repellent effect. At the same time, it can also enhance the antioxidant activity of the agent, improving its stability and durability in the natural environment. In contrast, glycidyl methacrylate in Example 4, butylene oxide in Example 5, and ethylene oxide in Example 6, although they also contain epoxy groups, their molecular structures and physicochemical properties may differ from those of resorcinol diglycidyl ether, which can affect their performance in terms of penetration, synergistic effects with other ingredients in the agent, and stability. For example, glycidyl methacrylate may not be as good as resorcinol diglycidyl ether in terms of penetration; butylene oxide and ethylene oxide, although they also provide epoxy groups, may have limitations in terms of interaction with other agent components or environmental adaptability. In addition, the introduction of resorcinol diglycidyl ether can also promote the interaction of agent components with the visual organs of birds, enhancing the repellent effect of the agent. This enhanced effect may be related to the polarity, molecular size, and shape of resorcinol diglycidyl ether, which together improve the agent's impact on bird behavior.
[0109] The superior performance of the repellent agent in Example 1 can also be attributed to the addition of cholesterol, Tween 80 and butylated hydroxyanisole in the formulation of the enhancer. Cholesterol can enhance the interaction and penetration of the agent with the avian sensory organs, Tween 80 as a surfactant reduces the surface tension, improves the spreading and adhesion of the agent, while the antioxidant effect of butylated hydroxyanisole helps to protect the components of the agent and prolong its effective action time. The synergistic effect of these components can improve the biological activity and environmental adaptability of the agent, thus showing significant advantages in bird repellent effect and stability compared to the comparative example 1 without the addition of these components.
Claims
1. A method of preparing a low altitude bird and animal repelling agent, characterized in that, The method is as follows, in parts by weight: 4~6 parts of carbomer 940 are mixed with 70~90 parts of water, and stirred at room temperature until uniformly dispersed; 15~30 parts of bird repellent flavor is added to the solution, and continues to be stirred; 20~30 parts of geranyl acetate is added to the mixture during stirring, to ensure thorough mixing; 1~2 parts of Tween 20 is added, and stirred until the mixture is uniformly emulsified; 0.5~2 parts of stabilizer, 4~6 parts of antifreeze agent, and 4~6 parts of promoter are added to the mixture, and stirred and mixed; then cooled at room temperature and stand for 12~48 hours; the final mixture is filtered to remove insoluble substances, to obtain the repellent agent; The preparation method of the promoter is as follows, in parts by weight: S1, 0.5~2 parts of sodium isopropylate, 80~100 parts of ester substance, 5~10 parts of 3,7,16-trihydroxy stigmasta-5-ene, 3~5 parts of polyol, and 3~4 parts of amine compound are put into a reaction kettle and uniformly mixed to obtain a pretreated material, and heated to 100℃ and dehydrated for 1~3 hours; the temperature is controlled at 120~150℃, and resorcinol diglycidyl ether is introduced, and the amount of resorcinol diglycidyl ether is 50%~100% of the mass of the pretreated material; curing is carried out at 120~140℃ until the curing pressure is 0.013~0.018 MPa, nitrogen is introduced to maintain the pressure at 0.15~0.25 MPa, until the pressure in the reaction kettle remains unchanged, the reaction is completed, and the curing time is 1~3 hours, vacuum is extracted at 120~130℃ for 1~3 hours, the temperature is lowered to 60~70℃, citric acid is added to adjust the pH to 5~6.5, to obtain a post-treated material; S2, the post-treated material prepared in step S1 is mixed with 10~20 parts of cholesterol, 2~4 parts of Tween 80, and 3~5 parts of butylated hydroxyanisole at 60~75℃ and stirred for 10~50 minutes, to obtain the promoter; The ester substance is DL-α-phosphatidylcholine; The bird repellent flavor is at least one of methyl anthranilate, camphor oil, dimethyl benzoic acid, cinnamaldehyde, cinnamamide, musk, capsaicin, capsaicin dihydrobase, and camphor oil; The stabilizer is at least one of sodium benzoate and sodium tripolyphosphate; The antifreeze agent is at least one of ethylene glycol and glycerol; The polyol is at least one of sorbitol, xylitol, mannitol, and erythritol; The amine compound is at least one of L-hydroxyproline and N,N-dihydroxyethyl aniline.
2. A low flying bird and animal repelling agent, characterized in that, Prepared by the preparation method of claim 1.
Citation Information
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