Preparation method of bio-based thermoplastic polyurethane elastomer

By introducing daily ammonium molten rosin chain expanders in biological armal plastic polyurethane elastomers, a new type of polymer with a hydrogenation three -Fei ring structure and a ductinium salt group is formed, which solves the heat resistance and antibacterial performance of polyurethane elastic body The deficiencies have achieved higher mechanical properties and heat resistance.

CN119081043BActive Publication Date: 2025-01-24兴邦新材料(山东)有限公司
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Patent Information

Application Number
CN202411562151.6
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2024-11-05
Publication Date
2025-01-24
Estimated Expiration
2044-11-05

AI Technical Summary

Technical Problem

The existing bio-based thermoplastic polyurethane elastomers have shortcomings in their heat resistance and antibacterial properties.

Method used

Quaternized rosin acid ester chain extender is used to perform polymerization chain extension reaction with polyol and diisocyanate to form a new bio-based thermoplastic polyurethane elastomer with hydrogenated triphenanthrene ring structure and quaternary ammonium salt group.

Benefits of technology

It improves the stretching strength of polyurethane elastic bodies, the elongation rate, thermal decomposition temperature and the diameter of the hemorrhage, which significantly improves its mechanical performance, thermal resistance and antibacterial performance.

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Abstract

The present invention relates to the technical field of polyurethane elastomers, and discloses a preparation method of a bio-based thermoplastic polyurethane elastomer, wherein dried and dehydrated polyols and diisocyanates are added to a reaction flask, a quaternized rosin ester chain extender is added after the reaction, stirring forms a gel, and the mixture is added to a mold, demoulding after placement, and ripening to obtain a bio-based thermoplastic polyurethane elastomer. The present invention introduces a hydrogenated triphenanthrene ring structure with high structural stability and strong heat resistance, and a quaternary ammonium salt group with antibacterial property into a polyurethane elastomer, thereby improving the tensile strength and elongation at break of the elastomer, and showing higher mechanical properties. At the same time, the thermal decomposition temperature and the antibacterial zone diameter of the elastomeric material are improved, and better heat resistance and antibacterial properties are obtained.
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Citation Information

Patent Citations

  • A rosin-based polyurethane and its synthesis method

    CN114133517B

  • Bromine-containing room-temperature phosphorescent waterborne polyurethane and preparation method thereof

    CN107987010A

  • Method of preparing quaternized esters of carboxylic acids and aminoalcohols

    SU793998A1